Van der Waals heterostructures with incommensurate contact interfaces show excellent tribological performance, which provides solutions for the development of new solid lubricants. In this paper, a facile electrostatic layer-by-layer self-assembly (LBL) technique was proposed to prepare multi-layer van der Waals heterostructures tungsten disulfide/hexagonal boron nitride (vdWH WS2/h-BN). The h-BN and WS2 were modified with poly (diallyldimethylammonium chloride) (PDDA) and sodium dodecyl benzene sulfonate (SDBS) to obtain the positively charged PDDA@h-BN and the negatively charged SDBS@WS2, respectively. When the mass ratio of PDDA to h-BN and SDBS to WS2 were both 1:1 and the pH was 3, the zeta potential of PDDA@h-BN and SDBS@WS2 were 60.0 mV and −50.1 mV, respectively. Under the electrostatic interaction, the PDDA@h-BN and SDBS@WS2 attracted each other and stacked alternately along the (002) crystal plane forming the multi-layer (four-layer) vdWH WS2/h-BN. The addition of the multi-layer vdWH WS2/h-BN (1.0 wt%) to the base oil resulted in a significant reduction of 33.8% in the friction coefficient (0.104) and 16.8% in the wear rate (4.43 × 10−5 mm3/(N·m)). The excellent tribological property of the multi-layer vdWH WS2/h-BN arose from the lattice mismatch (26.0%), a 15-fold higher interlayer slip possibility, and the formation of transfer film at the contact interface. This study provided an easily accessible method for the multi-layer vdWH with excellent tribological properties.
{"title":"Preparation and Tribological Performance of Multi-Layer van der Waals Heterostructure WS2/h-BN","authors":"Yunqi Fang, Yang Sun, Fengqin Shang, Jing Zhang, Jiayu Yao, Zihan Yan, Hangyan Shen","doi":"10.3390/lubricants12050163","DOIUrl":"https://doi.org/10.3390/lubricants12050163","url":null,"abstract":"Van der Waals heterostructures with incommensurate contact interfaces show excellent tribological performance, which provides solutions for the development of new solid lubricants. In this paper, a facile electrostatic layer-by-layer self-assembly (LBL) technique was proposed to prepare multi-layer van der Waals heterostructures tungsten disulfide/hexagonal boron nitride (vdWH WS2/h-BN). The h-BN and WS2 were modified with poly (diallyldimethylammonium chloride) (PDDA) and sodium dodecyl benzene sulfonate (SDBS) to obtain the positively charged PDDA@h-BN and the negatively charged SDBS@WS2, respectively. When the mass ratio of PDDA to h-BN and SDBS to WS2 were both 1:1 and the pH was 3, the zeta potential of PDDA@h-BN and SDBS@WS2 were 60.0 mV and −50.1 mV, respectively. Under the electrostatic interaction, the PDDA@h-BN and SDBS@WS2 attracted each other and stacked alternately along the (002) crystal plane forming the multi-layer (four-layer) vdWH WS2/h-BN. The addition of the multi-layer vdWH WS2/h-BN (1.0 wt%) to the base oil resulted in a significant reduction of 33.8% in the friction coefficient (0.104) and 16.8% in the wear rate (4.43 × 10−5 mm3/(N·m)). The excellent tribological property of the multi-layer vdWH WS2/h-BN arose from the lattice mismatch (26.0%), a 15-fold higher interlayer slip possibility, and the formation of transfer film at the contact interface. This study provided an easily accessible method for the multi-layer vdWH with excellent tribological properties.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"29 16","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141005442","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-07DOI: 10.3390/lubricants12050162
P. Johns-Rahnejat, N. Dolatabadi, Homer Rahnejat
Machines operate under increasingly harsher contact conditions, causing significant wear and contact fatigue. Sub-surface stresses are responsible for the premature contact fatigue of rolling element bearings, meshing gears, and cam–follower pairs. Surface protection measures include hard, wear-resistant coatings. Traditionally, contact integrity has been predicted using classical Hertzian contact mechanics. However, the theory is only applicable when the contact between a pair of ellipsoidal solids of revolution may be considered as a rigid indenter penetrating a semi-infinite elastic half-space. Many coatings act as thin bonded elastic layers that undergo considerably higher pressures than those predicted by the classical theory. Furthermore, inelastic deformation of bonded solids can cause plastic flow, work-hardening, and elastoplastic behaviour. This paper presents a comprehensive, integrated contact mechanics analysis that includes induced sub-surface stresses in concentrated counterformal finite line contacts for all the aforementioned cases. Generated pressures and deformation are predicted for hard coated surfaces, for which there is a dearth of relevant analysis. The contact characteristics, which are of particular practical significance, of many hard, wear-resistant advanced coatings are also studied. The paper clearly demonstrates the importance of using efficient semi-analytical, detailed holistic contact mechanics rather than the classical idealised methods or empirical numerical ones such as FEA. The novel approach presented for the finite line contact of thin-layered bonded solids has not hitherto been reported in the open literature.
{"title":"Elastic and Elastoplastic Contact Mechanics of Concentrated Coated Contacts","authors":"P. Johns-Rahnejat, N. Dolatabadi, Homer Rahnejat","doi":"10.3390/lubricants12050162","DOIUrl":"https://doi.org/10.3390/lubricants12050162","url":null,"abstract":"Machines operate under increasingly harsher contact conditions, causing significant wear and contact fatigue. Sub-surface stresses are responsible for the premature contact fatigue of rolling element bearings, meshing gears, and cam–follower pairs. Surface protection measures include hard, wear-resistant coatings. Traditionally, contact integrity has been predicted using classical Hertzian contact mechanics. However, the theory is only applicable when the contact between a pair of ellipsoidal solids of revolution may be considered as a rigid indenter penetrating a semi-infinite elastic half-space. Many coatings act as thin bonded elastic layers that undergo considerably higher pressures than those predicted by the classical theory. Furthermore, inelastic deformation of bonded solids can cause plastic flow, work-hardening, and elastoplastic behaviour. This paper presents a comprehensive, integrated contact mechanics analysis that includes induced sub-surface stresses in concentrated counterformal finite line contacts for all the aforementioned cases. Generated pressures and deformation are predicted for hard coated surfaces, for which there is a dearth of relevant analysis. The contact characteristics, which are of particular practical significance, of many hard, wear-resistant advanced coatings are also studied. The paper clearly demonstrates the importance of using efficient semi-analytical, detailed holistic contact mechanics rather than the classical idealised methods or empirical numerical ones such as FEA. The novel approach presented for the finite line contact of thin-layered bonded solids has not hitherto been reported in the open literature.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"134 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141002103","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-06DOI: 10.3390/lubricants12050161
Yan Li, Yongcun Cui, Sier Deng
(1) Background: To better understand the dynamic characteristics of a ball bearing with an elastic ring squeeze film damper (ERSFD) under sudden unbalance, a novel dynamic model was established by fully considering the coupling between the ERSFD, bearing outer ring (the journal), rotor, and disc (loading bearing); (2) Methods: An improved secant method was developed to determine the initial eccentricity values of the bearing’s outer ring and the disc. The dynamic response of the outer ring under different speed ratios, damping ratios, and mass ratios was solved using the variable-step Runge–Kutta method; (3) Results: In comparison, a low-speed ratio, high damping ratio, and low mass ratio were more conducive to suppressing the bearing vibration. When the imbalance was suddenly introduced, the displacement amplitude of the eccentricity, transmissibility, amplitude–frequency response, and the radius of the outer ring center locus increased; (4) Conclusions: This work provides a reference for further studying the nonlinear vibration of rolling bearings coupled with an ERSFD.
{"title":"Research on Sudden Unbalance Response of Rigid-Elastic-Oil Coupled Ball Bearings","authors":"Yan Li, Yongcun Cui, Sier Deng","doi":"10.3390/lubricants12050161","DOIUrl":"https://doi.org/10.3390/lubricants12050161","url":null,"abstract":"(1) Background: To better understand the dynamic characteristics of a ball bearing with an elastic ring squeeze film damper (ERSFD) under sudden unbalance, a novel dynamic model was established by fully considering the coupling between the ERSFD, bearing outer ring (the journal), rotor, and disc (loading bearing); (2) Methods: An improved secant method was developed to determine the initial eccentricity values of the bearing’s outer ring and the disc. The dynamic response of the outer ring under different speed ratios, damping ratios, and mass ratios was solved using the variable-step Runge–Kutta method; (3) Results: In comparison, a low-speed ratio, high damping ratio, and low mass ratio were more conducive to suppressing the bearing vibration. When the imbalance was suddenly introduced, the displacement amplitude of the eccentricity, transmissibility, amplitude–frequency response, and the radius of the outer ring center locus increased; (4) Conclusions: This work provides a reference for further studying the nonlinear vibration of rolling bearings coupled with an ERSFD.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"1 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141006352","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-06DOI: 10.3390/lubricants12050160
Xuan Zheng, Lihong Su, Guanyu Deng
In this work, large-scale molecular dynamics (MD) computational simulations were performed in order to explore the sliding contact responses of rough surfaces with hexadecane lubricant and added nanoparticles. Simulation results revealed that the frictional state was dependent on the fluid, nanoparticle, and surface roughness. Three lubricating conditions were compared based on considerations of different amounts of fluid molecules. The lubricant was not able to separate the frictional contact surfaces if the quantity of lubricant molecules was insufficient. Particularly, there were no lubricating contributions when the amount of lubricant was too low, and the lubricant therefore only filled the pits in the surface roughness. Thus, the normal load was primarily supported by the contact between the two surfaces and nanoparticles, leading to significant surface morphology changes. In contrast, the frictional contact surfaces were able to be completely separated by the lubricant when there was a sufficient amount of fluid, and a very good lubricating effect could thus be achieved, resulting in a smaller friction force. In addition, the changes in surface morphology, contact area, and RMS are discussed in this paper, in order to reveal the dynamic frictional process.
{"title":"Influence of Nanoparticles in Lubricant on Sliding Contact of Atomic Rough Surfaces—A Molecular Dynamics Study","authors":"Xuan Zheng, Lihong Su, Guanyu Deng","doi":"10.3390/lubricants12050160","DOIUrl":"https://doi.org/10.3390/lubricants12050160","url":null,"abstract":"In this work, large-scale molecular dynamics (MD) computational simulations were performed in order to explore the sliding contact responses of rough surfaces with hexadecane lubricant and added nanoparticles. Simulation results revealed that the frictional state was dependent on the fluid, nanoparticle, and surface roughness. Three lubricating conditions were compared based on considerations of different amounts of fluid molecules. The lubricant was not able to separate the frictional contact surfaces if the quantity of lubricant molecules was insufficient. Particularly, there were no lubricating contributions when the amount of lubricant was too low, and the lubricant therefore only filled the pits in the surface roughness. Thus, the normal load was primarily supported by the contact between the two surfaces and nanoparticles, leading to significant surface morphology changes. In contrast, the frictional contact surfaces were able to be completely separated by the lubricant when there was a sufficient amount of fluid, and a very good lubricating effect could thus be achieved, resulting in a smaller friction force. In addition, the changes in surface morphology, contact area, and RMS are discussed in this paper, in order to reveal the dynamic frictional process.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"5 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141008036","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-05-03DOI: 10.3390/lubricants12050159
Sihang Liu, Baojun Zhang, Long Cai, Weiguang Wang, Taihe Liang, Mingkai Lei
The effect of the microstructure of siliconized graphite on tribological properties is investigated by using a high-temperature and high-pressure water-lubricated tribometer on a self-mated ring-on-ring configuration under an applied load of 500–1500 N with a spindle speed of 100–5000 rpm in both 90 °C (5 MPa) and 25 °C (1 MPa) water environments, respectively. The Stribeck curves measurement and continuous wear tests are performed and analyzed in both water environments. The wear behaviors of the graphite, SiC, and free-silicon phases in siliconized graphite are demonstrated to explore the wear mechanism. The larger wear depths of a low-worn surface roughness on the three phases contribute to the boundary lubrication. The shallower wear depths are observed on the SiC and Si phases under the mixed lubrication, corresponding to partial contact wear of surface asperities. The wavy surface of the SiC phase and uniform flow-oriented striae of the Si phase are attributed to hydrodynamic lubrication, caused by full water film scouring the worn surface. Finally, an integrated evaluation method of G duty parameters is successfully used to identify the lubrication regimes of siliconized graphite from the boundary, mixed, to hydrodynamic lubrications for a water-lubricated thrust bearing application in the main coolant pump of a nuclear power plant.
在 90 °C（5 兆帕）和 25 °C（1 兆帕）的水环境中，使用高温高压水润滑摩擦磨损试验机，在施加 500-1500 牛顿的载荷和 100-5000 转/分钟的主轴转速下，研究了硅化石墨的微观结构对摩擦学特性的影响。在这两种水环境中都进行了斯特里贝克曲线测量和连续磨损试验，并对其进行了分析。证明了石墨、SiC 和硅化石墨中游离硅相的磨损行为，以探索磨损机理。三相低磨损表面粗糙度的磨损深度较大，这有助于边界润滑。在混合润滑条件下，SiC 相和 Si 相的磨损深度较浅，这与表面尖角的部分接触磨损有关。SiC 相的波浪形表面和 Si 相的均匀流向条纹归因于流体动力润滑，这是由全水膜冲刷磨损表面造成的。最后，在核电站主冷却剂泵的水润滑推力轴承应用中，成功使用了 G duty 参数的综合评估方法来确定硅化石墨从边界润滑、混合润滑到流体动力润滑的润滑状态。
{"title":"High-Temperature and High-Pressure Tribological Properties of Siliconized Graphite for Water-Lubricated Thrust Bearing Application in Main Coolant Pump","authors":"Sihang Liu, Baojun Zhang, Long Cai, Weiguang Wang, Taihe Liang, Mingkai Lei","doi":"10.3390/lubricants12050159","DOIUrl":"https://doi.org/10.3390/lubricants12050159","url":null,"abstract":"The effect of the microstructure of siliconized graphite on tribological properties is investigated by using a high-temperature and high-pressure water-lubricated tribometer on a self-mated ring-on-ring configuration under an applied load of 500–1500 N with a spindle speed of 100–5000 rpm in both 90 °C (5 MPa) and 25 °C (1 MPa) water environments, respectively. The Stribeck curves measurement and continuous wear tests are performed and analyzed in both water environments. The wear behaviors of the graphite, SiC, and free-silicon phases in siliconized graphite are demonstrated to explore the wear mechanism. The larger wear depths of a low-worn surface roughness on the three phases contribute to the boundary lubrication. The shallower wear depths are observed on the SiC and Si phases under the mixed lubrication, corresponding to partial contact wear of surface asperities. The wavy surface of the SiC phase and uniform flow-oriented striae of the Si phase are attributed to hydrodynamic lubrication, caused by full water film scouring the worn surface. Finally, an integrated evaluation method of G duty parameters is successfully used to identify the lubrication regimes of siliconized graphite from the boundary, mixed, to hydrodynamic lubrications for a water-lubricated thrust bearing application in the main coolant pump of a nuclear power plant.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"121 24","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141017370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study explored the crucial relationship between base fluids and polyamide, a prevalent polymer in electric vehicle (EV) components, with the aim of enhancing the longevity and performance of EVs in the context of thermal management by immersion cooling. Focusing on polyalphaolefin and polyol ester as base fluids, an immersion test was conducted to assess their interaction with polyamide 6 using adapted ASTM standards. The results revealed the significant influences of both fluids on the physical properties and chemical structure of polyamide. Polyol ester demonstrated a lesser impact on the chemical and mechanical properties of polyamide 6.
{"title":"Compatibility Study of Polyamide (PA6) with Lubricant Bases for Electric Vehicle Applications","authors":"Bernardo Tormos, Vicente Bermúdez, Adbeel Balaguer, Enrique Giménez","doi":"10.3390/lubricants12020054","DOIUrl":"https://doi.org/10.3390/lubricants12020054","url":null,"abstract":"This study explored the crucial relationship between base fluids and polyamide, a prevalent polymer in electric vehicle (EV) components, with the aim of enhancing the longevity and performance of EVs in the context of thermal management by immersion cooling. Focusing on polyalphaolefin and polyol ester as base fluids, an immersion test was conducted to assess their interaction with polyamide 6 using adapted ASTM standards. The results revealed the significant influences of both fluids on the physical properties and chemical structure of polyamide. Polyol ester demonstrated a lesser impact on the chemical and mechanical properties of polyamide 6.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"6 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139774152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study explored the crucial relationship between base fluids and polyamide, a prevalent polymer in electric vehicle (EV) components, with the aim of enhancing the longevity and performance of EVs in the context of thermal management by immersion cooling. Focusing on polyalphaolefin and polyol ester as base fluids, an immersion test was conducted to assess their interaction with polyamide 6 using adapted ASTM standards. The results revealed the significant influences of both fluids on the physical properties and chemical structure of polyamide. Polyol ester demonstrated a lesser impact on the chemical and mechanical properties of polyamide 6.
{"title":"Compatibility Study of Polyamide (PA6) with Lubricant Bases for Electric Vehicle Applications","authors":"Bernardo Tormos, Vicente Bermúdez, Adbeel Balaguer, Enrique Giménez","doi":"10.3390/lubricants12020054","DOIUrl":"https://doi.org/10.3390/lubricants12020054","url":null,"abstract":"This study explored the crucial relationship between base fluids and polyamide, a prevalent polymer in electric vehicle (EV) components, with the aim of enhancing the longevity and performance of EVs in the context of thermal management by immersion cooling. Focusing on polyalphaolefin and polyol ester as base fluids, an immersion test was conducted to assess their interaction with polyamide 6 using adapted ASTM standards. The results revealed the significant influences of both fluids on the physical properties and chemical structure of polyamide. Polyol ester demonstrated a lesser impact on the chemical and mechanical properties of polyamide 6.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"596 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139833820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-14DOI: 10.3390/lubricants12020053
J. Horng, Thi-Na Ta, R. Kreivaitis, J. Treinytė, A. Kupčinskas, M. Gumbytė
For over two decades, ionic liquids have been among the most exciting lubrication topics. Ionic liquids were investigated by using them as neat lubricants and lubricity-enhancing additives. However, new and unique features were revealed by introducing new ionic liquids. This paper compares the tribological properties of two ionic liquids with the same trihexyltetradecylphosphonium [P 6,6,6,14] cation and different anions—dicyanamide [DCN] and bis(2,4,4-trimethylpentyl)phosphinate. The widely investigated 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIM] [PF6] ionic liquid was used as a reference. The lubricity was comprehensively investigated using two testing modes: reciprocation in a ball-on-plate tribometer and continuous sliding in a ball-on-disc tribometer. The tests were performed at temperatures of 30 and 80 °C. The friction, wear, and film thickness were evaluated, and a worn surface analysis was conducted. It was found that in the case of reciprocation, anion has a significant effect on the lubricity. The difference was particularly evident when the results at two temperatures were compared. The ability to build a low-friction tribo-film was suggested as the primer source of lubricity. In the case of continuous sliding, the differences were not as noticeable. In this case, viscosity was assigned to be the leading property.
{"title":"A Comparison of the Tribological Properties of Two Phosphonium Ionic Liquids","authors":"J. Horng, Thi-Na Ta, R. Kreivaitis, J. Treinytė, A. Kupčinskas, M. Gumbytė","doi":"10.3390/lubricants12020053","DOIUrl":"https://doi.org/10.3390/lubricants12020053","url":null,"abstract":"For over two decades, ionic liquids have been among the most exciting lubrication topics. Ionic liquids were investigated by using them as neat lubricants and lubricity-enhancing additives. However, new and unique features were revealed by introducing new ionic liquids. This paper compares the tribological properties of two ionic liquids with the same trihexyltetradecylphosphonium [P 6,6,6,14] cation and different anions—dicyanamide [DCN] and bis(2,4,4-trimethylpentyl)phosphinate. The widely investigated 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIM] [PF6] ionic liquid was used as a reference. The lubricity was comprehensively investigated using two testing modes: reciprocation in a ball-on-plate tribometer and continuous sliding in a ball-on-disc tribometer. The tests were performed at temperatures of 30 and 80 °C. The friction, wear, and film thickness were evaluated, and a worn surface analysis was conducted. It was found that in the case of reciprocation, anion has a significant effect on the lubricity. The difference was particularly evident when the results at two temperatures were compared. The ability to build a low-friction tribo-film was suggested as the primer source of lubricity. In the case of continuous sliding, the differences were not as noticeable. In this case, viscosity was assigned to be the leading property.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"40 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139779624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-14DOI: 10.3390/lubricants12020053
J. Horng, Thi-Na Ta, R. Kreivaitis, J. Treinytė, A. Kupčinskas, M. Gumbytė
For over two decades, ionic liquids have been among the most exciting lubrication topics. Ionic liquids were investigated by using them as neat lubricants and lubricity-enhancing additives. However, new and unique features were revealed by introducing new ionic liquids. This paper compares the tribological properties of two ionic liquids with the same trihexyltetradecylphosphonium [P 6,6,6,14] cation and different anions—dicyanamide [DCN] and bis(2,4,4-trimethylpentyl)phosphinate. The widely investigated 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIM] [PF6] ionic liquid was used as a reference. The lubricity was comprehensively investigated using two testing modes: reciprocation in a ball-on-plate tribometer and continuous sliding in a ball-on-disc tribometer. The tests were performed at temperatures of 30 and 80 °C. The friction, wear, and film thickness were evaluated, and a worn surface analysis was conducted. It was found that in the case of reciprocation, anion has a significant effect on the lubricity. The difference was particularly evident when the results at two temperatures were compared. The ability to build a low-friction tribo-film was suggested as the primer source of lubricity. In the case of continuous sliding, the differences were not as noticeable. In this case, viscosity was assigned to be the leading property.
{"title":"A Comparison of the Tribological Properties of Two Phosphonium Ionic Liquids","authors":"J. Horng, Thi-Na Ta, R. Kreivaitis, J. Treinytė, A. Kupčinskas, M. Gumbytė","doi":"10.3390/lubricants12020053","DOIUrl":"https://doi.org/10.3390/lubricants12020053","url":null,"abstract":"For over two decades, ionic liquids have been among the most exciting lubrication topics. Ionic liquids were investigated by using them as neat lubricants and lubricity-enhancing additives. However, new and unique features were revealed by introducing new ionic liquids. This paper compares the tribological properties of two ionic liquids with the same trihexyltetradecylphosphonium [P 6,6,6,14] cation and different anions—dicyanamide [DCN] and bis(2,4,4-trimethylpentyl)phosphinate. The widely investigated 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIM] [PF6] ionic liquid was used as a reference. The lubricity was comprehensively investigated using two testing modes: reciprocation in a ball-on-plate tribometer and continuous sliding in a ball-on-disc tribometer. The tests were performed at temperatures of 30 and 80 °C. The friction, wear, and film thickness were evaluated, and a worn surface analysis was conducted. It was found that in the case of reciprocation, anion has a significant effect on the lubricity. The difference was particularly evident when the results at two temperatures were compared. The ability to build a low-friction tribo-film was suggested as the primer source of lubricity. In the case of continuous sliding, the differences were not as noticeable. In this case, viscosity was assigned to be the leading property.","PeriodicalId":502914,"journal":{"name":"Lubricants","volume":"370 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-02-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139839280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pub Date : 2024-02-13DOI: 10.3390/lubricants12020052
S. Kandemir, Sibel Yöyler, Rahul Kumar, Maksim Antonov, H. Dieringa
Magnesium (Mg) and graphene in alloy formulations are of paramount importance for lightweight engineering applications. In the present study, ZE10 Mg-alloy-based nanocomposites reinforced with graphene nanoplatelets (GNPs) having a thickness of 10–20 nm were fabricated via ultrasound-assisted stir casting. The effect of GNP contents (0.25, 0.5, and 1.0 wt.%) on the microstructure, Vickers hardness, and tensile properties of nanocomposites was investigated. Further, tribological studies were performed under a ball-on-disc sliding wear configuration against a bearing ball counterbody, at room and elevated temperatures of 100 °C and 200 °C, to comprehend temperature-induced wear mechanisms and friction evolution. It was revealed that the GNP addition resulted in grain coarsening and increased porosity rate of the Mg alloy. While the composites exhibited improved hardness by 20–35% at room temperature and 100 °C, a minor change was observed in their hardness and tensile yield strength values at 200 °C with respect to the GNP-free alloy. A notable improvement in lowering and stabilizing friction (coefficient of friction at 200 °C~0.25) and wear values was seen for the self-lubricating GNP-added composites at all sliding temperatures. The worn surface morphology indicated a simultaneous occurrence of abrasive and adhesive wear mode in all samples at room temperature and 100 °C, while delamination and smearing along with debris compaction (tribolayer protection) were the dominant mechanisms of wear at 200 °C. Inclusively, the results advocate steady frictional conditions, improved wear resistance, and favorable wear-protective mechanisms for the Mg alloy–GNP nanocomposites at room and elevated temperatures.
合金配方中的镁（Mg）和石墨烯对于轻质工程应用至关重要。在本研究中，通过超声辅助搅拌铸造法制造了厚度为 10-20 纳米的石墨烯纳米板（GNPs）增强 ZE10 镁合金基纳米复合材料。研究了 GNP 含量（0.25、0.5 和 1.0 wt.%）对纳米复合材料微观结构、维氏硬度和拉伸性能的影响。此外，还在 100 ℃ 和 200 ℃ 的室温和高温条件下进行了球盘滑动摩擦研究，以了解温度引起的磨损机制和摩擦演变。结果表明，添加 GNP 会导致镁合金的晶粒粗化和孔隙率增加。虽然复合材料在室温和 100 °C 下的硬度提高了 20-35%，但与不含 GNP 的合金相比，在 200 °C 下的硬度和拉伸屈服强度值变化不大。在所有滑动温度下，添加了 GNP 的自润滑复合材料在降低和稳定摩擦（200 °C 时的摩擦系数~0.25）和磨损值方面都有显著改善。磨损表面形态表明，在室温和 100 °C 时，所有样品都同时出现了研磨和粘着磨损模式，而在 200 °C 时，分层和涂抹以及碎屑压实（摩擦层保护）是磨损的主要机制。总之，这些结果表明镁合金-GNP 纳米复合材料在室温和高温下具有稳定的摩擦条件、更好的耐磨性和有利的磨损保护机制。
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