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Advanced Integration of Microwave Kiln Technology in Enhancing the Lost-Wax Glass Casting Process: A Study on Methodological Innovations and Practical Implications 微波窑技术在改进失蜡玻璃铸造工艺中的先进集成:方法创新与实践意义研究
Pub Date : 2024-05-01 DOI: 10.3390/jcs8050168
Shu-Chen Cheng, Ming-Shan Kao, Jiunn-Jer Hwang
Lost-wax glass casting, an esteemed yet technically demanding art form, traditionally relies on specialized, costly kiln equipment, presenting significant barriers to artists regarding equipment affordability, energy efficiency, and the technical mastery required for temperature control. Therefore, this study introduces an innovative approach by integrating a microwave kiln with standard household microwave ovens, thus facilitating the lost-wax glass casting process. This methodological adaptation allows artists to employ readily available home appliances for glass creation, significantly reducing the process’s cost and complexity. Our experimental investigations reveal that, by using a 500W household microwave oven for heating, the silicon carbide (SiC) in microwave kilns can efficiently absorb microwave energy, allowing the kilns to reach temperatures exceeding 700 °C, a critical threshold for casting glass softening. We further demonstrate that by adjusting the number of heating cycles, producing high-quality, three-dimensional(3D) glass artworks is feasible, even for large-scale projects. In addition, the microwave kiln can be used as an effective cooling tool to uniformly cool the formed casting glass. This study presents a possible alternative to conventional kiln technology and marks a paradigm shift in glassmaking, offering a more accessible and sustainable avenue for artists and practitioners.
失蜡玻璃铸造是一种备受推崇但技术要求极高的艺术形式,传统上依赖于专业、昂贵的窑炉设备,在设备的可负担性、能源效率以及温度控制所需的技术掌握方面给艺术家造成了巨大障碍。因此,本研究引入了一种创新方法,将微波窑与标准家用微波炉相结合,从而简化了失蜡玻璃铸造工艺。这种方法上的调整使艺术家们能够使用现成的家用电器进行玻璃创作,大大降低了工艺的成本和复杂性。我们的实验研究表明,通过使用 500 瓦家用微波炉加热,微波窑中的碳化硅(SiC)可以有效吸收微波能量,使窑炉温度超过 700 °C,这是铸造玻璃软化的临界点。我们进一步证明,通过调整加热周期的次数,即使是大型项目,也能制作出高质量的三维(3D)玻璃艺术品。此外,微波窑还可以作为一种有效的冷却工具,均匀冷却已成型的铸造玻璃。这项研究为传统窑炉技术提供了一种可能的替代方案,标志着玻璃制造领域的范式转变,为艺术家和从业人员提供了一种更方便、更可持续的途径。
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引用次数: 0
A Review of Biomass Wood Ash in Alkali-Activated Materials: Treatment, Application, and Outlook 碱活性材料中的生物质木灰综述:处理、应用和展望
Pub Date : 2024-04-25 DOI: 10.3390/jcs8050161
Yiying Du, I. Pundienė, J. Pranckevičienė, M. Kligys, G. Girskas, A. Korjakins
The utilisation of Portland cement has aroused tremendous concerns owing to its production exerting a lot of pressure on the environment. Alternative eco-binders have been developed to replace it, among which alkali-activated materials (AAMs) have drawn great attention, especially due to the possibility of encompassing industrial and agricultural waste, which significantly improves the sustainability and cost-efficiency of the material. Biomass wood ash (BWA) is a by-product generated from power plants and, along with the advocation for biomass fuel as a renewable energy resource, there have been increasing applications of BWA in building and construction materials. This review examines the use of BWA as a precursor source in AAMs. Due to its low chemical and hydraulic reactivity, more active binary precursors are usually introduced to guarantee mechanical properties. Whereas the increment of BWA content can have a negative influence on material strength development, it is still a promising and feasible material, and new approaches should be developed to improve the effectiveness of its utilisation. Currently, study of BWA-based AAMs is still in the beginning stages and more research is needed to investigate the effects of BWA characteristics on the property evolution of AAMs, focusing on the durability and analysis of eco-efficiency. Overall, this review provides a comprehensive overview of the characterisation of BWA and its potential applications in AAMs, and meanwhile, based on the analysis of present research trends, proposes some prospective directions for future research.
硅酸盐水泥的使用引起了人们的极大关注,因为其生产对环境造成了巨大压力。人们开发了替代性生态粘合剂来取代波特兰水泥,其中碱活性材料(AAMs)引起了人们的极大关注,尤其是因为它可以包含工业和农业废料,从而大大提高了材料的可持续性和成本效益。生物质木灰(BWA)是发电厂产生的一种副产品,随着生物质燃料作为可再生能源的推广,BWA 在建筑和构造材料中的应用也越来越多。本综述探讨了将 BWA 用作 AAM 的前驱体来源。由于其化学和水力反应活性较低,通常需要引入活性更高的二元前驱体来保证其机械性能。虽然增加 BWA 的含量会对材料强度的发展产生负面影响,但它仍然是一种前景广阔的可行材料,因此应开发新的方法来提高其利用效率。目前,对基于 BWA 的 AAMs 的研究仍处于起步阶段,需要开展更多研究来探讨 BWA 特性对 AAMs 性能演变的影响,重点是耐久性和生态效益分析。总之,本综述全面概述了 BWA 的特性及其在 AAM 中的潜在应用,同时在分析当前研究趋势的基础上,提出了一些未来研究的前瞻性方向。
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引用次数: 0
Hot-Dip Galvanizing Process and the Influence of Metallic Elements on Composite Coatings 热浸镀锌工艺和金属元素对复合涂层的影响
Pub Date : 2024-04-25 DOI: 10.3390/jcs8050160
Qi Liu, Yuqing Cao, Shuai Chen, Xinye Xu, Mutian Yao, Jie Fang, Kuan Lei, Guiqun Liu
The corrosion of steel materials has become a global issue, causing significant socio-economic losses and safety concerns. Hot-dip galvanizing is currently one of the most widely used steel anti-corrosion processes. With the rapid advancement of science and technology and emerging industries, the performance of pure galvanized products struggles to meet the demands of practical applications in various environments. Consequently, researchers have begun introducing various metals into the zinc solution to form high-performance alloy coatings. This article primarily explains the process flow of hot-dip galvanizing and the impact of metal elements such as Al, Mg, Sn, and Bi on the coating, as well as outlining the major issues currently faced by the hot-dip galvanizing process. The objective is to offer a more comprehensive introduction to those new to the field of hot-dip galvanizing and to provide theoretical insights for addressing production issues.
钢铁材料的腐蚀已成为一个全球性问题,造成了重大的社会经济损失和安全隐患。热镀锌是目前应用最广泛的钢铁防腐工艺之一。随着科学技术和新兴产业的快速发展,纯镀锌产品的性能难以满足各种环境下的实际应用需求。因此,研究人员开始在锌溶液中引入各种金属,形成高性能的合金镀层。本文主要解释了热镀锌的工艺流程以及 Al、Mg、Sn 和 Bi 等金属元素对镀层的影响,并概述了热镀锌工艺目前面临的主要问题。目的是为热镀锌领域的新手提供更全面的介绍,并为解决生产问题提供理论见解。
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引用次数: 0
Simulation of the Dynamic Responses of Layered Polymer Composites under Plate Impact Using the DSGZ Model 利用 DSGZ 模型模拟层状聚合物复合材料在平板冲击下的动态响应
Pub Date : 2024-04-23 DOI: 10.3390/jcs8050159
Huadian Zhang, A. M. Rajendran, Manoj K. Shukla, S. Nouranian, Ahmed Al-Ostaz, Steven Larson, Shan Jiang
This paper presents a numerical study on the dynamic response and impact mitigation capabilities of layered ceramic–polymer–metal (CPM) composites under plate impact loading, focusing on the layer sequence effect. The layered structure, comprising a ceramic for hardness and thermal resistance, a polymer for energy absorption, and a metal for strength and ductility, is analyzed to evaluate its effectiveness in mitigating the impact loading. The simulations employed the VUMAT subroutine of DSGZ material models within Abaqus/Explicit to accurately represent the mechanical behavior of the polymeric materials in the composites. The VUMAT implementation incorporates the explicit time integration scheme and the implicit radial return mapping algorithm. A safe-version Newton–Raphson method is applied for numerically solving the differential equations of the J2 plastic flow theory. Analysis of the simulation results reveals that specific layer configurations significantly influence wave propagation, leading to variations in energy absorption and stress distribution within the material. Notably, certain layer sequences, such as P-C-M and C-P-M, exhibit enhanced impact mitigation with a superior ability to dissipate and redirect the impact energy. This phenomenon is tied to the interactions between the material properties of the ceramic, polymer, and metal, emphasizing the necessity of precise material characterization and enhanced understanding of the layer sequencing effect for optimizing composite designs for impact mitigation. The integration of empirical data with simulation methods provides a comprehensive framework for optimizing composite designs in high-impact scenarios. In the general fields of materials science and impact engineering, the current research offers some guidance for practical applications, underscoring the need for detailed simulations to capture the high-strain-rate dynamic responses of multilayered composites.
本文针对层序效应,介绍了分层陶瓷-聚合物-金属(CPM)复合材料在平板冲击荷载下的动态响应和冲击缓解能力的数值研究。分层结构包括用于提高硬度和热阻的陶瓷、用于吸收能量的聚合物以及用于提高强度和延展性的金属,研究分析了分层结构在减轻冲击载荷方面的有效性。模拟采用了 Abaqus/Explicit 中 DSGZ 材料模型的 VUMAT 子程序,以准确表示复合材料中聚合物材料的机械行为。VUMAT 实现了显式时间积分方案和隐式径向返回映射算法。在数值求解 J2 塑性流动理论的微分方程时,采用了安全版牛顿-拉夫逊方法。对模拟结果的分析表明,特定的层配置会显著影响波的传播,从而导致材料内部能量吸收和应力分布的变化。值得注意的是,某些层序(如 P-C-M 和 C-P-M)显示出更强的冲击缓解能力,具有更强的消散和重定向冲击能量的能力。这种现象与陶瓷、聚合物和金属的材料特性之间的相互作用有关,因此需要对材料进行精确表征,并加强对层序效应的理解,以优化复合材料的冲击缓解设计。经验数据与模拟方法的整合为优化高冲击情景下的复合材料设计提供了一个综合框架。在材料科学和冲击工程的一般领域,目前的研究为实际应用提供了一些指导,强调了进行详细模拟以捕捉多层复合材料的高应变速率动态响应的必要性。
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引用次数: 0
Numerical Simulation of Transverse Crack on Composite Structure Using Cohesive Element 使用内聚元素对复合材料结构上的横向裂纹进行数值模拟
Pub Date : 2024-04-22 DOI: 10.3390/jcs8040158
Heri Heriana, Rebecca Mae Merida Catalya Marbun, B. K. Hadi, D. Widagdo, Muhammad Kusni
Due to their anisotropic behavior, composite structures are weak in transverse direction loading. produces transverse cracks, which for a laminated composite, may lead to delamination and total failure. The transition from transverse crack to delamination failure is important and the subject of recent studies. In this paper, a simulation of transverse crack and its transition to delamination on cross-ply laminate was studied extensively using a cohesive element Finite Element Method (FEM). A pre-cracked [0/90] composite laminate made of bamboo was modeled using ABAQUS/CAE. The specimen was in a three-point bending configuration. Cohesive elements were inserted in the middle of the 90° layer and in the interface between the 0° and 90° layer to simulate transverse crack propagation and its transition to delamination. A load–displacement graph was extracted from the simulation and analyzed. As the loading was given to the specimen, stress occurred in the laminates, concentrating near the pre-cracked region. When the stress reached the tensile transverse strength of the bamboo, transverse crack propagation initiated, indicated by the failure of transverse cohesive elements. The crack then propagated towards the interface of the [0/90] laminates. Soon after the crack reached the interface, delamination propagated along the interface, represented by the failure of the longitudinal cohesive elements. The result of the numerical study in the form of load–displacement graph shows a consistent pattern compared with the data found in the literature. The graph showed a linear path as the load increased and the crack propagated until a point where there was a load-drop in the graph, which showed that the crack was unstable and propagated quickly before it turned into delamination between the 0o and 90° plies.
由于各向异性,复合材料结构在横向荷载作用下很脆弱,会产生横向裂缝,对于层状复合材料来说,这可能会导致分层和完全破坏。从横向裂纹到分层破坏的过渡非常重要,也是近期研究的主题。本文使用内聚元素有限元法(FEM)对横向裂纹及其向分层的过渡进行了广泛的模拟研究。使用 ABAQUS/CAE 对竹子制成的预开裂 [0/90] 复合材料层压板进行建模。试样为三点弯曲结构。在 90° 层中间以及 0° 层和 90° 层之间的界面上插入了内聚元素,以模拟横向裂纹扩展及其向分层的过渡。从模拟中提取并分析了载荷-位移图。在对试样施加荷载时,层压板中产生了应力,并集中在预裂纹区域附近。当应力达到竹材的横向拉伸强度时,横向裂纹开始扩展,表现为横向内聚元素的破坏。裂纹随后向 [0/90] 层板的界面扩展。裂纹到达界面后不久,分层沿界面扩展,表现为纵向内聚元素失效。数值研究结果以载荷-位移图的形式显示,与文献中的数据相比,两者的模式一致。图形显示,随着荷载的增加,裂纹呈线性轨迹扩展,直到图形中出现荷载下降的点,这表明裂纹不稳定,并在 0° 和 90° 层之间变成分层之前迅速扩展。
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引用次数: 0
Quantification of Irgafos P-168 and Degradative Profile in Samples of a Polypropylene/Polyethylene Composite Using Microwave, Ultrasound and Soxhlet Extraction Techniques 利用微波、超声波和索氏提取技术定量聚丙烯/聚乙烯复合材料样品中的伊尔加福斯 P-168 和降解曲线
Pub Date : 2024-04-21 DOI: 10.3390/jcs8040156
J. Hernández‐Fernández, Jaime Pérez-Mendoza, Rodrigo Ortega-Toro
In polypropylene/polyethylene composite (C-PP/PE) production, stabilizing additives such as Irgafos P-168 are essential as antioxidant agents. In this study, an investigation was carried out that covers different solid–liquid extraction methods (Soxhlet, ultrasound, and microwaves); various variables were evaluated, such as temperature, extraction time, the choice of solvents, and the type of C-PP/PE used, and the gas chromatography coupled to mass spectrometry (GC-MS) technique was used to quantify the presence of Irgafos P-168 in the C-PP/PE samples. The results revealed that microwave extraction was the most effective in recovering Irgafos P-168. A recovery of 96.7% was achieved when using dichloromethane as a solvent, and 92.83% was achieved when using limonene as a solvent. The ultrasound technique recovered 91.74% using dichloromethane and 89.71% using limonene. The Soxhlet extraction method showed the lowest recovery percentages of 57.39% using dichloromethane as a solvent and 55.76% with limonene, especially when the C-PP/PE was in the form of pellets. The degradation products that obtained the highest degradation percentages were Bis (di-test-butyl phenyl) phosphate and Mono (di-test-butyl phenyl) phosphate using the microwave method with dichloromethane as a solvent and PP in film. Finally, the possible mechanisms for forming the degradation compounds of Irgafos P-168 were postulated.
在聚丙烯/聚乙烯复合材料(C-PP/PE)生产中,Irgafos P-168 等稳定添加剂作为抗氧化剂是必不可少的。本研究对不同的固液萃取方法(索氏提取法、超声波提取法和微波提取法)进行了调查;对温度、萃取时间、溶剂的选择和使用的 C-PP/PE 类型等各种变量进行了评估,并使用气相色谱-质谱联用(GC-MS)技术对 C-PP/PE 样品中的伊尔加福斯 P-168 进行了定量。结果表明,微波萃取是回收伊尔加福斯 P-168 的最有效方法。以二氯甲烷为溶剂的回收率为 96.7%,以柠檬烯为溶剂的回收率为 92.83%。超声波技术使用二氯甲烷的回收率为 91.74%,使用柠檬烯的回收率为 89.71%。索氏提取法的回收率最低,以二氯甲烷为溶剂时为 57.39%,以柠檬烯为溶剂时为 55.76%,尤其是当 C-PP/PE 为颗粒状时。在以二氯甲烷为溶剂、聚丙烯为薄膜的微波法中,降解率最高的降解产物是磷酸二(二试丁基苯基)酯和磷酸单(二试丁基苯基)酯。最后,对 Irgafos P-168 降解化合物的可能形成机制进行了推测。
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引用次数: 0
Enhancing Sustainability in Construction: Investigating the Thermal Advantages of Fly Ash-Coated Expanded Polystyrene Lightweight Concrete 增强建筑业的可持续性:研究粉煤灰包裹膨胀聚苯乙烯轻质混凝土的热优势
Pub Date : 2024-04-21 DOI: 10.3390/jcs8040157
A. Wibowo, M. Saidani, M. Khorami
This study investigates a sustainable coating method for modified expanded polystyrene (MEPS) beads to improve the thermal insulation of lightweight concrete intended for wall application. The method employed in this study is based on a novel coating technique that represents a significant advancement in modifying Expanded Polystyrene (EPS) beads for enhanced lightweight concrete. This study experimentally assessed the energy-saving capabilities of MEPS concrete in comparison to control groups of uncoated EPS beads and normal concrete by analysing early-stage temperature, thermal conductivity, specific heat capacity, heat flux, and thermal diffusivity. The thermal conductivity of MEPS concrete is approximately 40% lower than that of normal concrete, demonstrating its usefulness in enhancing insulation. The heat flux calculated for MEPS concrete is significantly reduced (approximately 35%), and it has a 20% lower specific heat capacity than ordinary concrete, indicating a reduction in energy transfer through the material and, thus, potential energy-efficiency benefits. Furthermore, the study discovered that all test objects have very low thermal diffusivity values (less than 0.5 × 10−6 m2/s), indicating a slower heat transport through the material. The sustainable coating method utilized fly ash-enhanced thermal efficiency and employed recycled materials, hence decreasing the environmental impact. MEPS concrete provides a practical option for creating sustainable and comfortable buildings through the promotion of energy-efficient wall construction. Concrete incorporating coated EPS can be a viable option for constructing walls where there is a need to balance structural integrity and adequate insulation.
本研究探讨了一种可持续的改性发泡聚苯乙烯(MEPS)微珠涂层方法,以提高轻质混凝土墙体的隔热性能。本研究采用的方法基于一种新颖的涂层技术,该技术在改性发泡聚苯乙烯(EPS)微珠用于增强轻质混凝土方面取得了重大进展。本研究通过分析早期温度、导热系数、比热容、热通量和热扩散率,评估了 MEPS 混凝土与未涂层 EPS 珠和普通混凝土对照组相比的节能能力。MEPS 混凝土的导热系数比普通混凝土低约 40%,这证明了它在增强隔热性能方面的作用。计算得出的 MEPS 混凝土热通量显著降低(约 35%),比热容比普通混凝土低 20%,这表明通过该材料传递的能量减少,因此具有潜在的节能效益。此外,研究还发现,所有测试对象的热扩散值都非常低(小于 0.5 × 10-6 m2/s),这表明通过材料的热传递速度较慢。可持续涂层方法利用粉煤灰提高了热效率,并采用了可回收材料,从而减少了对环境的影响。通过推广节能墙体建筑,MEPS 混凝土为创造可持续发展的舒适建筑提供了一个实用的选择。对于需要兼顾结构完整性和足够隔热性能的墙体建筑,含有涂层发泡聚苯乙烯的混凝土是一种可行的选择。
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引用次数: 0
A Review on the Recent Trends in Forming Composite Joints Using Spot Welding Variants 使用点焊变体形成复合材料接头的最新趋势综述
Pub Date : 2024-04-19 DOI: 10.3390/jcs8040155
Aravinthan Arumugam, A. Pramanik
Traditional resistance spot welding (RSW) has been unsuccessful in forming quality composite joints between steel– or aluminum–polymer-based composites. This has led to the development of spot welding variants such as friction stir spot welding (FFSW), ultrasonic spot welding (USW), and laser spot welding (LSW). The paper reviewed the differences in the bonding mechanisms, spot weld characteristics, and challenges involved in using these spot welding variants. Variants of RSW use series electrode arrangement, co-axial electrodes, metallic inserts, interlayers, or external energy to produce composite joints. FFSW and USW use nanoparticles, interlayers, or energy directors to create composite spot welds. Mechanical interlocking is the common composite joint mechanism for all variants. Each spot welding variant has different sets of weld parameters and distinct spot weld morphologies. FFSW is the most expensive variant but is commonly used for composite spot weld joints. USW has a shorter welding cycle compared to RSW and FFSW but can only be used for small components. LSW is faster than the other variants, but limited work was found on its use in composite spot weld joining. The use of interlayers in FFSW and USW to form composite joints is a potential research area recommended in this review.
传统的电阻点焊(RSW)无法在钢基或铝基聚合物复合材料之间形成高质量的复合接头。因此,搅拌摩擦点焊 (FFSW)、超声波点焊 (USW) 和激光点焊 (LSW) 等点焊变体应运而生。本文回顾了这些点焊变体在粘接机制、点焊特性和使用挑战方面的差异。RSW 的变体使用串联电极排列、同轴电极、金属嵌件、夹层或外部能量来生产复合接头。全自动点焊机和全自动点焊机使用纳米粒子、夹层或能量导向器来制造复合点焊。机械互锁是所有变体的共同复合接头机制。每种点焊变体都有不同的焊接参数集和独特的点焊形态。全频点焊是最昂贵的变体,但常用于复合点焊缝。与 RSW 和 FFSW 相比,USW 的焊接周期更短,但只能用于小型部件。LSW 比其他变体更快,但将其用于复合材料点焊连接的工作却很有限。本综述建议在全熔焊和全熔焊中使用夹层来形成复合焊点,这是一个潜在的研究领域。
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引用次数: 0
Hydrogel Composites for Multifunctional Biomedical Applications 用于多功能生物医学应用的水凝胶复合材料
Pub Date : 2024-04-19 DOI: 10.3390/jcs8040154
Hamid Omidian, Arnavaz Akhzarmehr, Sumana Dey Chowdhury
Hydrogel composites are pivotal in biomedical research, showing promise across various applications. This review aims to thoroughly examine their significance and versatile roles in regenerative medicine, tissue engineering, and drug delivery systems. Key areas of investigation include integrating growth factor delivery systems, overcoming structural limitations in tissue engineering, exploring innovations in clinical applications, and addressing challenges in achieving bioactivity and biomechanical compatibility. Furthermore, the review will discuss controlled release mechanisms for drug delivery, advancements in biocompatibility and mechanical stability, recent progress in tissue regeneration and wound healing, and future prospects such as smart hydrogels, personalized treatments, and integration with wearable technology. Ultimately, the goal is to provide a comprehensive understanding of how hydrogel composites impact biomedical research and clinical practice.
水凝胶复合材料在生物医学研究中举足轻重,在各种应用领域都大有可为。本综述旨在深入研究水凝胶复合材料在再生医学、组织工程和药物输送系统中的重要意义和多功能作用。主要研究领域包括整合生长因子输送系统、克服组织工程中的结构限制、探索临床应用中的创新,以及应对在实现生物活性和生物力学兼容性方面的挑战。此外,综述还将讨论药物递送的控释机制、生物相容性和机械稳定性方面的进展、组织再生和伤口愈合方面的最新进展,以及智能水凝胶、个性化治疗和与可穿戴技术整合等未来前景。最终目标是全面了解水凝胶复合材料如何影响生物医学研究和临床实践。
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引用次数: 0
Preparation of New Sm-Doped CuO/ZnO/CuMn2O4 Tri-Composite for Photoremoval of Dissolved Organic Waste and Dielectric-Energy Storage 制备新型掺杂 Sm 的 CuO/ZnO/CuMn2O4 三复合材料,用于溶解有机废物的光去除和电能存储
Pub Date : 2024-04-18 DOI: 10.3390/jcs8040152
Hanan Althikrallah, Ghayah M. Alsulaim, S. Alsharif, Kholoud M. Alnahdi
Photocatalysis is considered as simple, green, and the best strategy for elimination of hazardous organic contaminants from wastewater. Herein, new broad spectrum photocatalysts based on pure and Sm-doped CuO/ZnO/CuMn2O4 ternary composites were simply prepared by co-precipitation approach. The X-ray diffraction results proved the formation of a composite structure. The transmission electron microscope (TEM) images displayed that most particles have a spherical shape with average mean sizes within 26–29 nm. The optical properties of both samples signified that the addition of Sm ions significantly improves the harvesting of the visible light spectrum of CuO/ZnO/CuMn2O4 ternary composites. The photocatalytic study confirmed that 97% of norfloxacin and 96% of methyl green pollutants were photo-degraded in the presence of the Sm-doped CuO/ZnO/CuMn2O4 catalyst after 50 and 40 min, respectively. The total organic carbon analysis revealed the high mineralization efficiency of the Sm-doped CuO/ZnO/CuMn2O4 catalyst to convert the norfloxacin and methyl green to carbon dioxide and water molecules. During three cycles, this catalyst presented a high removal efficiency for norfloxacin and methyl green contaminants. As a dielectric energy storage material, the Sm-doped CuO/ZnO/CuMn2O4 ternary composite has large dielectric constant values, mainly at low frequencies, with low dielectric loss compared to a pure CuO/ZnO/CuMn2O4 composite.
光催化被认为是消除废水中有害有机污染物的简单、绿色和最佳策略。本文采用共沉淀法制备了基于纯铜和掺杂Sm的CuO/ZnO/CuMn2O4三元复合材料的新型广谱光催化剂。X 射线衍射结果证明了复合结构的形成。透射电子显微镜(TEM)图像显示,大多数颗粒呈球形,平均尺寸在 26-29 nm 之间。两种样品的光学特性表明,Sm 离子的加入大大提高了 CuO/ZnO/CuMn2O4 三元复合材料对可见光光谱的捕获能力。光催化研究证实,在掺杂 Sm 的 CuO/ZnO/CuMn2O4 催化剂存在下,50 分钟和 40 分钟后,分别有 97% 的诺氟沙星和 96% 的甲基绿污染物被光降解。总有机碳分析表明,掺杂 Sm 的 CuO/ZnO/CuMn2O4 催化剂将诺氟沙星和甲基绿转化为二氧化碳和水分子的矿化效率很高。在三个循环过程中,这种催化剂对诺氟沙星和甲基绿污染物的去除率很高。作为一种电介质储能材料,与纯 CuO/ZnO/CuMn2O4 复合材料相比,掺杂 Sm 的 CuO/ZnO/CuMn2O4 三元复合材料具有较大的介电常数值(主要在低频)和较低的介电损耗。
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引用次数: 0
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Journal of Composites Science
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