Yuhyeon Na, Seung Hyeon Weon, G. Lee, Hyung-Joo Kim, Sang Hyun Lee, Young-Hoo Kim, Ji Eun Kim, G. Kang, Saerom Park, Yong-Keun Choi
The present study reports the effective removal of benzene in aqueous phase onto biochar. The adsorption capacity of benzene onto biochars made at different pyrolytic temperatures (e.g., 350, 550, and 750 °C) and from various feedstocks (e.g., grape pomace, rice husk, and Kentucky bluegrass) were investigated. The adsorption capacity of Kentucky bluegrass-derived biochar (KB-BC) prepared at 550 °C for benzene was better than other biochars, owing to the higher surface area and functional groups. The adsorption isotherms and kinetics model for benzene by KB-BC550 fitted the Freundlich and pseudo-first order, respectively. In addition, the results of response surface methodology (RSM) designed with biochar dose, reaction time, and benzene concentration showed the maximum adsorption capacity (ca. 136 mg BZ/g BC) similar to that from kinetic study. KB-BCs obtained as waste grass biomass may be a valuable adsorbent, and RSM may be a useful tool for the investigation of optimal conditions and results.
{"title":"Evaluation of Benzene Adsorption onto Grass-Derived Biochar and Comparison of Adsorption Capacity via RSM (Response Surface Methodology)","authors":"Yuhyeon Na, Seung Hyeon Weon, G. Lee, Hyung-Joo Kim, Sang Hyun Lee, Young-Hoo Kim, Ji Eun Kim, G. Kang, Saerom Park, Yong-Keun Choi","doi":"10.3390/jcs8040132","DOIUrl":"https://doi.org/10.3390/jcs8040132","url":null,"abstract":"The present study reports the effective removal of benzene in aqueous phase onto biochar. The adsorption capacity of benzene onto biochars made at different pyrolytic temperatures (e.g., 350, 550, and 750 °C) and from various feedstocks (e.g., grape pomace, rice husk, and Kentucky bluegrass) were investigated. The adsorption capacity of Kentucky bluegrass-derived biochar (KB-BC) prepared at 550 °C for benzene was better than other biochars, owing to the higher surface area and functional groups. The adsorption isotherms and kinetics model for benzene by KB-BC550 fitted the Freundlich and pseudo-first order, respectively. In addition, the results of response surface methodology (RSM) designed with biochar dose, reaction time, and benzene concentration showed the maximum adsorption capacity (ca. 136 mg BZ/g BC) similar to that from kinetic study. KB-BCs obtained as waste grass biomass may be a valuable adsorbent, and RSM may be a useful tool for the investigation of optimal conditions and results.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"14 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140737576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Stelescu, O. Oprea, Ludmila Motelică, A. Ficai, Roxana Trusca, M. Sonmez, M. Nițuică, M. Georgescu
Significant interest is devoted to the development of new polymer blends by using concepts of the circular economy. Such materials have predetermined properties, are easy to recycle, ecological, and have a low carbon footprint. This research presents obtaining and characterization of polymer blends based on low-density polyethylene (LDPE) and thermoplastic starch (TPS). In the first stage, TPS was obtained through the gelatinization process, and, in the second stage, mixtures of LDPE and TPS were obtained through a melt mixing process at 150 °C for 7 min. The physical–mechanical characteristics of the samples, like hardness, elongation at break, rebound resilience, and tensile strength, were determined. The sample containing maleic anhydride grafted low-density polyethylene (LDPE-g-MA) as a compatibilizer shows improvements in elongation at break and tensile strength (by 6.59% and 40.47%, respectively) compared to the test sample. The FTIR microscopy maps show that samples containing LDPE-g-MA are more homogeneous. The SEM micrographs indicate that TPS-s is homogeneously dispersed as droplets in the LDPE matrix. From the thermal analysis, it was observed that both the degree of crystallinity and the mass loss at high temperature are influenced by the composition of the samples. The melt flow index has adequate values, indicating good processability of the samples by specific methods (such as extrusion or injection).
{"title":"Obtaining and Characterizing New Types of Materials Based on Low-Density Polyethylene and Thermoplastic Starch","authors":"M. Stelescu, O. Oprea, Ludmila Motelică, A. Ficai, Roxana Trusca, M. Sonmez, M. Nițuică, M. Georgescu","doi":"10.3390/jcs8040134","DOIUrl":"https://doi.org/10.3390/jcs8040134","url":null,"abstract":"Significant interest is devoted to the development of new polymer blends by using concepts of the circular economy. Such materials have predetermined properties, are easy to recycle, ecological, and have a low carbon footprint. This research presents obtaining and characterization of polymer blends based on low-density polyethylene (LDPE) and thermoplastic starch (TPS). In the first stage, TPS was obtained through the gelatinization process, and, in the second stage, mixtures of LDPE and TPS were obtained through a melt mixing process at 150 °C for 7 min. The physical–mechanical characteristics of the samples, like hardness, elongation at break, rebound resilience, and tensile strength, were determined. The sample containing maleic anhydride grafted low-density polyethylene (LDPE-g-MA) as a compatibilizer shows improvements in elongation at break and tensile strength (by 6.59% and 40.47%, respectively) compared to the test sample. The FTIR microscopy maps show that samples containing LDPE-g-MA are more homogeneous. The SEM micrographs indicate that TPS-s is homogeneously dispersed as droplets in the LDPE matrix. From the thermal analysis, it was observed that both the degree of crystallinity and the mass loss at high temperature are influenced by the composition of the samples. The melt flow index has adequate values, indicating good processability of the samples by specific methods (such as extrusion or injection).","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"13 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140737937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This paper is the first part of a two-part paper that discusses the development of a novel lightweight and cost-effective hybrid 3D composite material and its and utilization for constructing utility poles. The main objective was to generate a material/pole with a comparable performance to the commercially available poles made of 2D fiber-reinforced polymer (FRP) and examine its feasibility. The novel hybrid composite was configured using a recently developed and marketed 3D E-glass fabric–epoxy composite reinforced with wood dowels, referred to as 3D dowel-reinforced FRPs (3D-drFRPs) hereafter. Firstly, the compressive and flexural properties of the 3D-drFRPs are evaluated. Then, the development of the 3D pole is discussed followed by the fabrication details of two 3D-drFRPs using the standard test method, and their responses are compared. For the second part, robust finite element (FE) models were developed in an LS-DYNA environment and calibrated based on the experimental results. A sophisticated nonlinear FE model was used to simulate the performances of ASTM standard-size compression and three-point bending specimens and tapered 2D and prismatic 3D poles. Moreover, the responses of equivalent 2D and 3D poles were simulated numerically, as the task could not be accommodated experimentally due to our laboratory’s deficiencies. The integrity of the numerical simulation results was validated against experimental results, confirming the accuracy of the developed model. As an example, the stiffness values for the 3-pt bending specimens and the 3D poles obtained through the simulations were very close to the experimentally obtained results, with small margins of errors of 3.2% and 0.89%, respectively. Finally, a simplified analytical calculation method was developed so practicing engineers can determine the stiffnesses of 3D-DrFRP poles very accurately and quickly.
本文由两部分组成，第一部分讨论了新型轻质、高性价比混合三维复合材料的开发及其在电线杆建造中的应用。主要目的是开发出一种性能与二维纤维增强聚合物（FRP）制成的商用电线杆相当的材料/电线杆，并研究其可行性。新型混合复合材料是使用最近开发并上市的一种用木榫加固的三维 E 玻璃纤维织物-环氧树脂复合材料（以下简称三维木榫加固玻璃钢（3D-drFRPs））制成的。首先，对 3D-drFRP 的抗压和抗弯特性进行了评估。然后，讨论了三维杆的开发，随后使用标准测试方法详细介绍了两种三维 drFRP 的制造，并对它们的响应进行了比较。第二部分是在 LS-DYNA 环境中开发稳健的有限元 (FE) 模型，并根据实验结果进行校准。复杂的非线性 FE 模型用于模拟 ASTM 标准尺寸压缩和三点弯曲试样以及锥形 2D 和棱柱形 3D 杆件的性能。此外，还对等效二维和三维杆的响应进行了数值模拟，因为我们的实验室条件有限，无法在实验中完成这项任务。数值模拟结果的完整性与实验结果进行了验证，证实了所开发模型的准确性。例如，通过模拟获得的 3pt 弯曲试样和 3D 极点的刚度值与实验结果非常接近，误差分别为 3.2% 和 0.89%。最后，我们还开发了一种简化的分析计算方法，以便工程师能够非常准确、快速地确定三维-DrFRP 杆件的刚度。
{"title":"Development of a Novel Lightweight Utility Pole Using a New Hybrid Reinforced Composite—Part 1: Fabrication and Experimental Investigation","authors":"Qianjiang Wu, Farid Taheri","doi":"10.3390/jcs8040136","DOIUrl":"https://doi.org/10.3390/jcs8040136","url":null,"abstract":"This paper is the first part of a two-part paper that discusses the development of a novel lightweight and cost-effective hybrid 3D composite material and its and utilization for constructing utility poles. The main objective was to generate a material/pole with a comparable performance to the commercially available poles made of 2D fiber-reinforced polymer (FRP) and examine its feasibility. The novel hybrid composite was configured using a recently developed and marketed 3D E-glass fabric–epoxy composite reinforced with wood dowels, referred to as 3D dowel-reinforced FRPs (3D-drFRPs) hereafter. Firstly, the compressive and flexural properties of the 3D-drFRPs are evaluated. Then, the development of the 3D pole is discussed followed by the fabrication details of two 3D-drFRPs using the standard test method, and their responses are compared. For the second part, robust finite element (FE) models were developed in an LS-DYNA environment and calibrated based on the experimental results. A sophisticated nonlinear FE model was used to simulate the performances of ASTM standard-size compression and three-point bending specimens and tapered 2D and prismatic 3D poles. Moreover, the responses of equivalent 2D and 3D poles were simulated numerically, as the task could not be accommodated experimentally due to our laboratory’s deficiencies. The integrity of the numerical simulation results was validated against experimental results, confirming the accuracy of the developed model. As an example, the stiffness values for the 3-pt bending specimens and the 3D poles obtained through the simulations were very close to the experimentally obtained results, with small margins of errors of 3.2% and 0.89%, respectively. Finally, a simplified analytical calculation method was developed so practicing engineers can determine the stiffnesses of 3D-DrFRP poles very accurately and quickly.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"23 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140737119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. Malewska, A. Prociak, Natalia Świdzińska-Grela, M. Kurańska
In this study, polyurethane-polystyrene composites (RPURF-EPS) were obtained with the co-expansion method. This method consists of utilizing the heat of the exothermic reaction of polyurethane (PUR) formation to expand polystyrene beads (PSBs). The materials were obtained using polyurethane systems based on the selected blowing agents, such as cyclopentane, a mixture of fluorocarbons and water. The analysis of the foaming process was carried out using a special device called FOAMAT. The characteristic start, rise, gelation and curing times were defined. The rise profile, the reaction temperature, the pressure and the dielectric polarization were measured. The influence of selected blowing agents on the cell structure and physical–mechanical properties of reference rigid polyurethane foam (RPURF) and RPURF-EPS, such as apparent density, compressive strength and thermal conductivity, were evaluated. Based on the research, the blowing agents that have the most beneficial influence on the properties and structure of the composites and that provide the most efficient expansion of PSBs in a light porous composite were found.
{"title":"The Polyurethane-Polystyrene Composite—Influence of the Blowing Agent Type on the Foaming Process, the Structure and the Properties","authors":"E. Malewska, A. Prociak, Natalia Świdzińska-Grela, M. Kurańska","doi":"10.3390/jcs8040135","DOIUrl":"https://doi.org/10.3390/jcs8040135","url":null,"abstract":"In this study, polyurethane-polystyrene composites (RPURF-EPS) were obtained with the co-expansion method. This method consists of utilizing the heat of the exothermic reaction of polyurethane (PUR) formation to expand polystyrene beads (PSBs). The materials were obtained using polyurethane systems based on the selected blowing agents, such as cyclopentane, a mixture of fluorocarbons and water. The analysis of the foaming process was carried out using a special device called FOAMAT. The characteristic start, rise, gelation and curing times were defined. The rise profile, the reaction temperature, the pressure and the dielectric polarization were measured. The influence of selected blowing agents on the cell structure and physical–mechanical properties of reference rigid polyurethane foam (RPURF) and RPURF-EPS, such as apparent density, compressive strength and thermal conductivity, were evaluated. Based on the research, the blowing agents that have the most beneficial influence on the properties and structure of the composites and that provide the most efficient expansion of PSBs in a light porous composite were found.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"8 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140739528","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hongfu Li, Haoxuan Zhang, Guangquan Yue, Boyu Guo, Ying Wu
The investigation of the in-plane shear behavior of prepreg is crucial for understanding the generation of wrinkles of preforms in advanced composite manufacturing processes, such as automated fiber placement and thermoforming. Despite this significance, there is currently no standardized test method for characterizing uncured unidirectional (UD) prepreg. This paper introduces a ±45° off-axis tensile test designed to assess the in-plane shear behavior of UD carbon fiber-reinforced epoxy prepreg (CF/epoxy). Digital image correlation (DIC) was employed to quantitatively track the strains in three dimensions and the shear angle evolution during the stretching process. The influences of the temperature and stretching rate on the in-plane shear behavior of the prepreg were further investigated. The results reveal that four shear characteristic zones and wrinkling behaviors are clearly distinguished. The actual in-plane shear angle is significantly lower than the theoretical value due to fiber constraints from both the in-plane and out-of-plane aspects. When the off-axis tensile displacement (d) is less than 15.6 mm, the ±45° specimens primarily exhibit macroscale in-plane shear behavior, induced by interlaminar interface shear between the +45° ply and −45° ply at the mesoscale. The shear angle increases linearly with the d. However, when d > 15.6 mm, fiber squeezing and wrinkling begin to occur. When d > 29 mm, the in-plane shear disappears in the completely sheared zone (A). The reduction in the resin viscosity of the CF/epoxy prepreg caused by increased temperature is identified as the primary factor in lowering the in-plane shear force resistance, followed by the effect of the increasing resin curing degree. Higher shear rates can lead to a substantial increase in shear forces, eventually causing cracking failure in the prepreg. The findings demonstrate the feasibility of the test method for predicting and extracting uncured prepreg in-plane shear behaviors and the strain-rate and temperature dependency of the material response.
研究预浸料的面内剪切行为对于了解自动纤维铺放和热成型等先进复合材料制造工艺中预成型件皱纹的产生至关重要。尽管意义重大，但目前还没有用于表征未固化单向（UD）预浸料的标准化测试方法。本文介绍了一种 ±45° 离轴拉伸试验，旨在评估 UD 碳纤维增强环氧树脂预浸料（CF/环氧树脂）的面内剪切行为。采用数字图像相关技术（DIC）定量跟踪拉伸过程中的三维应变和剪切角演变。还进一步研究了温度和拉伸速率对预浸料平面内剪切行为的影响。研究结果表明，预浸料具有明显的四个剪切特征区和起皱行为。由于纤维在面内和面外两方面的限制，实际面内剪切角明显低于理论值。当离轴拉伸位移 (d) 小于 15.6 mm 时，±45° 试样主要表现出宏观的面内剪切行为，这是由 +45° 层和 -45° 层之间的层间界面剪切在中尺度上引起的。然而，当 d > 15.6 mm 时，开始出现纤维挤压和起皱。当 d > 29 mm 时，面内剪切在完全剪切区（A）消失。温度升高导致 CF/epoxy 预浸料的树脂粘度降低，被认为是降低面内剪切力阻力的主要因素，其次是树脂固化度升高的影响。较高的剪切速率会导致剪切力大幅增加，最终导致预浸料开裂失效。研究结果证明了预测和提取未固化预浸料平面内剪切行为以及材料响应的应变速率和温度依赖性的测试方法的可行性。
{"title":"Determination of the In-Plane Shear Behavior of and Process Influence on Uncured Unidirectional CF/Epoxy Prepreg Using Digital Image Correlation Analysis","authors":"Hongfu Li, Haoxuan Zhang, Guangquan Yue, Boyu Guo, Ying Wu","doi":"10.3390/jcs8040133","DOIUrl":"https://doi.org/10.3390/jcs8040133","url":null,"abstract":"The investigation of the in-plane shear behavior of prepreg is crucial for understanding the generation of wrinkles of preforms in advanced composite manufacturing processes, such as automated fiber placement and thermoforming. Despite this significance, there is currently no standardized test method for characterizing uncured unidirectional (UD) prepreg. This paper introduces a ±45° off-axis tensile test designed to assess the in-plane shear behavior of UD carbon fiber-reinforced epoxy prepreg (CF/epoxy). Digital image correlation (DIC) was employed to quantitatively track the strains in three dimensions and the shear angle evolution during the stretching process. The influences of the temperature and stretching rate on the in-plane shear behavior of the prepreg were further investigated. The results reveal that four shear characteristic zones and wrinkling behaviors are clearly distinguished. The actual in-plane shear angle is significantly lower than the theoretical value due to fiber constraints from both the in-plane and out-of-plane aspects. When the off-axis tensile displacement (d) is less than 15.6 mm, the ±45° specimens primarily exhibit macroscale in-plane shear behavior, induced by interlaminar interface shear between the +45° ply and −45° ply at the mesoscale. The shear angle increases linearly with the d. However, when d > 15.6 mm, fiber squeezing and wrinkling begin to occur. When d > 29 mm, the in-plane shear disappears in the completely sheared zone (A). The reduction in the resin viscosity of the CF/epoxy prepreg caused by increased temperature is identified as the primary factor in lowering the in-plane shear force resistance, followed by the effect of the increasing resin curing degree. Higher shear rates can lead to a substantial increase in shear forces, eventually causing cracking failure in the prepreg. The findings demonstrate the feasibility of the test method for predicting and extracting uncured prepreg in-plane shear behaviors and the strain-rate and temperature dependency of the material response.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"35 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140739725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The choice of material, manufacturing process, and molding tool significantly affects the quality, environmental impact, and cost efficiency of composite components. Producing one-piece hollow profiles with smooth inner surfaces and undercuts presents major challenges for conventional mold concepts. There is yet no thorough review of shape-variable mandrels in composite manufacturing to be found in the literature. This paper provides an overview of research on shape memory polymers and other shape-variable materials used in tooling applications for composite manufacturing. This work covers shape memory, heat shrink, and other deformable tooling concepts that enable the production of one-piece Type V pressure vessels, air intake ducts, or curved struts and tubes. A systematic literature review in combination with a state-of-the-art open-source active learning tool ASReview is conducted. Fifteen relevant studies were identified. Research on shape-variable tooling is mainly conducted by three research groups in the USA and the PRC. The tooling is mostly made of unreinforced thermosets, especially styrene-based ones. Thermoplastic resins are less common, and reinforcements limit the usable elongation in the temporary shape. The shape variability is either a shape memory and/or a softening process, which, in all studies, is activated by heating. Release agents are widely used to ease demolding. No ecological or economical assessment of the manufacturing methods was conducted in the reviewed studies. Three fields for further research that could be identified are as follows: (1) thorough ecological end economical assessment of shape-variable mandrels in comparison with conventional tooling; (2) thermoplastic shape memory polymer mandrels; and (3) further investigation of simulation capabilities for shape memory mandrels.
{"title":"Variable Shape Tooling for Composite Manufacturing: A Systematic Review","authors":"Fabian Neumann","doi":"10.3390/jcs8040131","DOIUrl":"https://doi.org/10.3390/jcs8040131","url":null,"abstract":"The choice of material, manufacturing process, and molding tool significantly affects the quality, environmental impact, and cost efficiency of composite components. Producing one-piece hollow profiles with smooth inner surfaces and undercuts presents major challenges for conventional mold concepts. There is yet no thorough review of shape-variable mandrels in composite manufacturing to be found in the literature. This paper provides an overview of research on shape memory polymers and other shape-variable materials used in tooling applications for composite manufacturing. This work covers shape memory, heat shrink, and other deformable tooling concepts that enable the production of one-piece Type V pressure vessels, air intake ducts, or curved struts and tubes. A systematic literature review in combination with a state-of-the-art open-source active learning tool ASReview is conducted. Fifteen relevant studies were identified. Research on shape-variable tooling is mainly conducted by three research groups in the USA and the PRC. The tooling is mostly made of unreinforced thermosets, especially styrene-based ones. Thermoplastic resins are less common, and reinforcements limit the usable elongation in the temporary shape. The shape variability is either a shape memory and/or a softening process, which, in all studies, is activated by heating. Release agents are widely used to ease demolding. No ecological or economical assessment of the manufacturing methods was conducted in the reviewed studies. Three fields for further research that could be identified are as follows: (1) thorough ecological end economical assessment of shape-variable mandrels in comparison with conventional tooling; (2) thermoplastic shape memory polymer mandrels; and (3) further investigation of simulation capabilities for shape memory mandrels.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"119 ","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140750649","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The relatively low melting point of a traditional Si bonding layer limits the upper servicing temperature of environmental barrier coatings (EBC). To explore suitable high temperature bonding layers and expedite the development of EBC, first-principles calculation was used to evaluate the mechanical properties and thermal conductivity of HfSi2, HfSi, Hf5Si4, Hf3Si2, and Hf2Si with much higher melting points than that of Si. Among them, HfSi2 has the lowest modulus capable of good modulus matching with SiC substrate. In addition, these Hf-Si compounds have much lower high temperature thermal conductivity with Hf2Si being the lowest of 0.63 W m−1 K−1, which is only half of Si, capable of improved heat insulation.
传统硅键合层的熔点相对较低，这限制了环境屏障涂层（EBC）的最高使用温度。为了探索合适的高温键合层并加快 EBC 的开发，我们利用第一性原理计算评估了熔点远高于硅的 HfSi2、HfSi、Hf5Si4、Hf3Si2 和 Hf2Si 的机械性能和导热性。其中，HfSi2 的模量最低，能与碳化硅基底实现良好的模量匹配。此外，这些 Hf-Si 化合物的高温热导率也低得多，其中 Hf2Si 的热导率最低，仅为 0.63 W m-1 K-1，仅为 Si 的一半，能够改善隔热性能。
{"title":"Mechanical and Thermal Properties of the Hf–Si System: First-Principles Calculations","authors":"Panxin Huang, Guifang Han, Huan Liu, Weibin Zhang, Kexue Peng, Jianzhang Li, Weili Wang, Jingde Zhang","doi":"10.3390/jcs8040129","DOIUrl":"https://doi.org/10.3390/jcs8040129","url":null,"abstract":"The relatively low melting point of a traditional Si bonding layer limits the upper servicing temperature of environmental barrier coatings (EBC). To explore suitable high temperature bonding layers and expedite the development of EBC, first-principles calculation was used to evaluate the mechanical properties and thermal conductivity of HfSi2, HfSi, Hf5Si4, Hf3Si2, and Hf2Si with much higher melting points than that of Si. Among them, HfSi2 has the lowest modulus capable of good modulus matching with SiC substrate. In addition, these Hf-Si compounds have much lower high temperature thermal conductivity with Hf2Si being the lowest of 0.63 W m−1 K−1, which is only half of Si, capable of improved heat insulation.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"80 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140751683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Finite element analyses of the propagation of damage such as fiber compressive failure and delamination have greatly contributed to the understanding of failure mechanisms of fiber-reinforced plastics owing to extensive studies on methodologies using Continuum Damage Mechanics and Fracture Mechanics. Problems without the need for consideration of inertia, such as Double-Cantilever Beam tests, are usually solved by implicit FE solvers, and explicit FE solvers are appropriate for phenomena that progress with very high velocity such as impact problems. However, quasi-static problems with unstable damage propagation observed in experiments such as Open-Hole Compression tests are still not easy to solve for both types of solvers. We propose a method to enable the static FE solver to solve problems with unstable propagation of damage. In the present method, an additional process of convergence checks on the averaged energy release rate of damaged elements is incorporated in a conventional Newton–Raphson scheme. The feasibility of the present method was validated by two numerical examples consisting of analyses of Open-Hole Compression tests and Double-Cantilever Beam tests. The results of the analyses of OHC tests showed that the present method was applicable to problems with unstable damage propagation. In addition, the results from the analyses of DCB tests with the present method indicated that mesh density and loading history are not significantly influential to the solution.
由于对连续破坏力学和断裂力学方法的广泛研究，对纤维压缩破坏和分层等破坏传播的有限元分析极大地促进了对纤维增强塑料破坏机理的理解。不需要考虑惯性的问题，如双悬臂梁试验，通常采用隐式 FE 求解器求解，而显式 FE 求解器则适用于速度非常快的现象，如冲击问题。然而，在开孔压缩试验等实验中观察到的具有不稳定损伤传播的准静态问题，对于这两种求解器来说都不容易求解。我们提出了一种方法，使静态 FE 求解器能够解决损伤不稳定传播的问题。在本方法中，在传统的牛顿-拉斐森方案中加入了对受损元素的平均能量释放率进行收敛检查的附加过程。本方法的可行性通过开孔压缩试验和双悬臂梁试验的两个数值实例进行了验证。开孔压缩试验的分析结果表明，本方法适用于不稳定的损伤传播问题。此外，使用本方法分析 DCB 试验的结果表明，网格密度和加载历史对求解的影响不大。
{"title":"A Numerical Method for Unstable Propagation of Damage in Fiber-Reinforced Plastics with an Implicit Static FE Solver","authors":"Atsushi Kondo, Yutaro Watanabe, Kentaro Sakai, Yutaka Iwahori, E. Hara, Hisaya Katoh","doi":"10.3390/jcs8040130","DOIUrl":"https://doi.org/10.3390/jcs8040130","url":null,"abstract":"Finite element analyses of the propagation of damage such as fiber compressive failure and delamination have greatly contributed to the understanding of failure mechanisms of fiber-reinforced plastics owing to extensive studies on methodologies using Continuum Damage Mechanics and Fracture Mechanics. Problems without the need for consideration of inertia, such as Double-Cantilever Beam tests, are usually solved by implicit FE solvers, and explicit FE solvers are appropriate for phenomena that progress with very high velocity such as impact problems. However, quasi-static problems with unstable damage propagation observed in experiments such as Open-Hole Compression tests are still not easy to solve for both types of solvers. We propose a method to enable the static FE solver to solve problems with unstable propagation of damage. In the present method, an additional process of convergence checks on the averaged energy release rate of damaged elements is incorporated in a conventional Newton–Raphson scheme. The feasibility of the present method was validated by two numerical examples consisting of analyses of Open-Hole Compression tests and Double-Cantilever Beam tests. The results of the analyses of OHC tests showed that the present method was applicable to problems with unstable damage propagation. In addition, the results from the analyses of DCB tests with the present method indicated that mesh density and loading history are not significantly influential to the solution.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"43 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140751997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Stir-casting with ultrasonic cavitation produced nano-Al2O3-filled AA7150 matrix composites in this study. The SEM microstructure study shows that all composites include nano-Al2O3 particles with consistent particle sizes and homogenous distribution. EDS and XRD showed no secondary phases or impurities in the composite. Optical microscopy showed intense ultrasonic cavitation effects, and nano-Al2O3 particles caused grain refinement in the AA7150 matrix. The composite’s mechanical characteristics improved when the Al2O3 nanoparticle weight percentage (wt.%) increased. With only 2.0 wt.% nano-Al2O3 particles, the composites yielded 232 MPa, 97.52% higher than the sonicated AA7150 matrix alloy. Multiple models were used to characterize the strength of the AA7150 nano-Al2O3 composite. The findings showed that thermal incongruity, Orowan strengthening, the Hall–Petch mechanism, and load transfer effects contributed the most towards the increased strength of the composite. Increasing the nano-Al2O3 wt.% in the AA7150 matrix improved hardness by 95.08%, yield strength by 90.34%, and sliding wear resistance by 46.52%. This enhancement may be attributed to the combined effects of better grain refinement, enhanced dispersion with dislocation strengthening, and better load transfer between the matrix and reinforcement, which are assisted by the inclusion of reinforcements. This result was confirmed by optical studies.
{"title":"Studies on the Mechanical, Strengthening Mechanisms and Tribological Characteristics of AA7150-Al2O3 Nano-Metal Matrix Composites","authors":"K. C. Maddaiah, G. B. Veeresh Kumar, R. Pramod","doi":"10.3390/jcs8030097","DOIUrl":"https://doi.org/10.3390/jcs8030097","url":null,"abstract":"Stir-casting with ultrasonic cavitation produced nano-Al2O3-filled AA7150 matrix composites in this study. The SEM microstructure study shows that all composites include nano-Al2O3 particles with consistent particle sizes and homogenous distribution. EDS and XRD showed no secondary phases or impurities in the composite. Optical microscopy showed intense ultrasonic cavitation effects, and nano-Al2O3 particles caused grain refinement in the AA7150 matrix. The composite’s mechanical characteristics improved when the Al2O3 nanoparticle weight percentage (wt.%) increased. With only 2.0 wt.% nano-Al2O3 particles, the composites yielded 232 MPa, 97.52% higher than the sonicated AA7150 matrix alloy. Multiple models were used to characterize the strength of the AA7150 nano-Al2O3 composite. The findings showed that thermal incongruity, Orowan strengthening, the Hall–Petch mechanism, and load transfer effects contributed the most towards the increased strength of the composite. Increasing the nano-Al2O3 wt.% in the AA7150 matrix improved hardness by 95.08%, yield strength by 90.34%, and sliding wear resistance by 46.52%. This enhancement may be attributed to the combined effects of better grain refinement, enhanced dispersion with dislocation strengthening, and better load transfer between the matrix and reinforcement, which are assisted by the inclusion of reinforcements. This result was confirmed by optical studies.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"38 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140077152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Continuous fiber reinforced thermoplastics (cFRTP) are one of the most promising lightweight materials. For their use in structural components, reproducible and comparable material values have to be evaluated, especially at high strain rates. Due to their high stiffness and outstanding strength properties, the evaluation of the material behavior at high strain rates is complex. In the presented work, a new tensile specimen geometry for strain rate testing is virtually optimized using a metamodel approach with an artificial neural network. The final specimen design is experimentally validated and compared with rectangular specimen results for a carbon fiber reinforced polycarbonate (CF-PC). The optimized specimen geometry leads to 100% valid test results in experimental validation of cross-ply laminates and reaches 9% higher tensile strength values than the rectangle geometry with applied end tabs at a strain rate of 40 s−1. Through the optimization, comparable material parameters can be efficiently generated for a successful cFRTP strain rate characterization.
{"title":"Optimization of a Tapered Specimen Geometry for Short-Term Dynamic Tensile Testing of Continuous Fiber Reinforced Thermoplastics","authors":"Florian Mischo, S. Schmeer","doi":"10.3390/jcs8030093","DOIUrl":"https://doi.org/10.3390/jcs8030093","url":null,"abstract":"Continuous fiber reinforced thermoplastics (cFRTP) are one of the most promising lightweight materials. For their use in structural components, reproducible and comparable material values have to be evaluated, especially at high strain rates. Due to their high stiffness and outstanding strength properties, the evaluation of the material behavior at high strain rates is complex. In the presented work, a new tensile specimen geometry for strain rate testing is virtually optimized using a metamodel approach with an artificial neural network. The final specimen design is experimentally validated and compared with rectangular specimen results for a carbon fiber reinforced polycarbonate (CF-PC). The optimized specimen geometry leads to 100% valid test results in experimental validation of cross-ply laminates and reaches 9% higher tensile strength values than the rectangle geometry with applied end tabs at a strain rate of 40 s−1. Through the optimization, comparable material parameters can be efficiently generated for a successful cFRTP strain rate characterization.","PeriodicalId":502935,"journal":{"name":"Journal of Composites Science","volume":"7 8","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140081279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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