首页 > 最新文献

ECS Journal of Solid State Science and Technology最新文献

英文 中文
The Dependence on Temperature of the Mn4+ Emission Intensity and Lifetime in Na2SiF6 Na2SiF6 中 Mn4+ 发射强度和寿命与温度的关系
Pub Date : 2024-06-10 DOI: 10.1149/2162-8777/ad561b
William Beers, Mikhail Brik, Chong-Geng Ma, Willian E. Cohen, Alok Srivastava
We have measured the dependence of the Mn4+ lifetime and intensity on temperature of commercial Na2SiF6: Mn4+ phosphor. The data are fitted to existing physical models to extract the activation energy for thermal quenching. The parameters of our fitting are compared with those reported for laboratory synthesized Na2SiF6:Mn4+ and commercial K2SiF6:Mn4+ phosphors that is sold under the trade name, TriGain®. This comparative analysis sheds light on the mechanism of thermal quenching of the Mn4+ ion luminescence in M2SiF6 (M=K, Na) compounds. We show that the activation energy and the onset temperature of thermal quenching for the 2E 4T2 4A2 crossover process is correlated with the energy of the 4T2 level and argue that this is a robust electronic structure-property relationship in fluoride hosts with low defect density. The study provides, therefore, an understanding of the factors responsible for non-radiative relaxation processes, which is fundamental to the understanding of phosphor quantum efficiency and performance.
我们测量了商用 Na2SiF6: Mn4+ 荧光粉的 Mn4+ 寿命和强度与温度的关系。我们将这些数据与现有的物理模型进行了拟合,以提取热淬火的活化能。我们的拟合参数与实验室合成的 Na2SiF6:Mn4+ 和以 TriGain® 商标名销售的商用 K2SiF6:Mn4+ 荧光粉的拟合参数进行了比较。这项比较分析揭示了 M2SiF6(M=K、Na)化合物中 Mn4+ 离子发光的热淬灭机制。我们的研究表明,2E 4T2 4A2 交叉过程的活化能和热淬灭的起始温度与 4T2 电平的能量相关,并认为这是低缺陷密度氟化物宿主中一种稳健的电子结构-性质关系。因此,这项研究提供了对造成非辐射弛豫过程的因素的理解,这对理解荧光粉的量子效率和性能至关重要。
{"title":"The Dependence on Temperature of the Mn4+ Emission Intensity and Lifetime in Na2SiF6","authors":"William Beers, Mikhail Brik, Chong-Geng Ma, Willian E. Cohen, Alok Srivastava","doi":"10.1149/2162-8777/ad561b","DOIUrl":"https://doi.org/10.1149/2162-8777/ad561b","url":null,"abstract":"\u0000 We have measured the dependence of the Mn4+ lifetime and intensity on temperature of commercial Na2SiF6: Mn4+ phosphor. The data are fitted to existing physical models to extract the activation energy for thermal quenching. The parameters of our fitting are compared with those reported for laboratory synthesized Na2SiF6:Mn4+ and commercial K2SiF6:Mn4+ phosphors that is sold under the trade name, TriGain®. This comparative analysis sheds light on the mechanism of thermal quenching of the Mn4+ ion luminescence in M2SiF6 (M=K, Na) compounds. We show that the activation energy and the onset temperature of thermal quenching for the 2E 4T2 4A2 crossover process is correlated with the energy of the 4T2 level and argue that this is a robust electronic structure-property relationship in fluoride hosts with low defect density. The study provides, therefore, an understanding of the factors responsible for non-radiative relaxation processes, which is fundamental to the understanding of phosphor quantum efficiency and performance.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141361474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic and Magnetocaloric Properties of C56 like-Fullerene Structure: A Monte Carlo Study C56 类富勒烯结构的磁性和磁致性:蒙特卡罗研究
Pub Date : 2024-06-03 DOI: 10.1149/2162-8777/ad522d
S. Idrissi, A. Jabar, L. Bahmad
We explored the magnetic and magnetocaloric properties of the C56 Fullerene-like system formed by the mixed spins 2 and 3/2. We applied Monte Carlo simulations using the Metropolis algorithm and show the effects of different physical parameters. We also established the ground state phase diagrams, at zero reduced temperature, in different planes formed by the reduced external magnetic field, the reduced coupling interaction between the mixed spins, and the reduced crystal field. We found that the total magnetizations predict a specific reduced critical temperature value, confirmed by the peaks observed in the magnetic susceptibilities. To elucidate the behavior of the magnetic entropy changes -ΔSm, of the C56 system, for several external magnetic field values we show that the reduced critical temperature value tC increases when increasing the reduced external magnetic field. In addition, we show the dependency of the maximum “magnetic entropy change” as a function of the reduced external magnetic field. We found an almost linear increase for this parameter when increasing the reduced external magnetic field values. The obtained hysteresis cycles of the studied system showed a decreasing effect of the reduced crystal field followed by a decrease of the magnetic hysteresis surface cycles, as well as the corresponding reduced coercive magnetic field values.
我们探索了由混合自旋 2 和 3/2 形成的 C56 富勒烯类体系的磁性和磁致性。我们使用 Metropolis 算法进行了蒙特卡罗模拟,并展示了不同物理参数的影响。我们还建立了零还原温度下不同平面的基态相图,这些平面由还原的外部磁场、还原的混合自旋之间的耦合相互作用以及还原的晶体场形成。我们发现,总磁化率预示了一个特定的还原临界温度值,这一点通过在磁感应强度中观察到的峰值得到了证实。为了阐明 C56 体系的磁熵变化 -ΔSm 的行为,在几个外磁场值下,我们发现还原临界温度值 tC 随还原外磁场的增加而增加。此外,我们还展示了最大 "磁熵变 "与还原外磁场的函数关系。我们发现,当增加外磁场降低值时,该参数几乎呈线性增长。所研究系统的磁滞周期显示,晶体场减小后,磁滞表面周期以及相应的减小矫顽磁场值随之减小。
{"title":"Magnetic and Magnetocaloric Properties of C56 like-Fullerene Structure: A Monte Carlo Study","authors":"S. Idrissi, A. Jabar, L. Bahmad","doi":"10.1149/2162-8777/ad522d","DOIUrl":"https://doi.org/10.1149/2162-8777/ad522d","url":null,"abstract":"We explored the magnetic and magnetocaloric properties of the C56 Fullerene-like system formed by the mixed spins 2 and 3/2. We applied Monte Carlo simulations using the Metropolis algorithm and show the effects of different physical parameters. We also established the ground state phase diagrams, at zero reduced temperature, in different planes formed by the reduced external magnetic field, the reduced coupling interaction between the mixed spins, and the reduced crystal field. We found that the total magnetizations predict a specific reduced critical temperature value, confirmed by the peaks observed in the magnetic susceptibilities. To elucidate the behavior of the magnetic entropy changes -ΔSm, of the C56 system, for several external magnetic field values we show that the reduced critical temperature value tC increases when increasing the reduced external magnetic field. In addition, we show the dependency of the maximum “magnetic entropy change” as a function of the reduced external magnetic field. We found an almost linear increase for this parameter when increasing the reduced external magnetic field values. The obtained hysteresis cycles of the studied system showed a decreasing effect of the reduced crystal field followed by a decrease of the magnetic hysteresis surface cycles, as well as the corresponding reduced coercive magnetic field values.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141388996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and Characterization of Functionally Graded Nanocomposites: Impact of Graphene and Vanadium Carbide on Aluminum Matrix 功能分级纳米复合材料的制备与表征:石墨烯和碳化钒对铝基体的影响
Pub Date : 2024-05-16 DOI: 10.1149/2162-8777/ad4c96
Essam B. Moustafa, Mohamed Said, Abdulrahman Aljabri, Mohammed A. Taha, Rasha Youness, Hossameldin Hussein
Functional graded nanocomposites (FGNCs) based on Al are artificially tailored heterogeneous materials intended to serve the demand for diverse and contradicting properties used in various industrial applications. FGNCs and hybrid FGNCs (HFGNCs) based on Al reinforced with graphene and vanadium carbide (VC) were prepared using powder metallurgy techniques and investigated. Both samples were designed with a gradient composition, where the bottom layer consisted of 100% pure Al, followed by three consecutive layers containing progressively increasing amounts of reinforcement. The incorporation of graphene and VC into layer powders resulted in a decrease in both particle and crystal dimensions compared to pure Al. Adding graphene has a negative effect on bulk density samples, while VC has a positive effect. Reinforcing materials led to a decrease in thermal conductivity that reached 26.7 % for samples reinforced with VC reinforcement, except for FGNCs reinforced with graphene, which increased by ~3.3 compared to Al. The samples’ CTE and electrical conductivity values decreased, although adding graphene alone led to a slight decrease in electrical conductivity. A significant improvement in all mechanical properties was noted with additional. The HFGCNs reinforced with the largest amount of hybrid reinforcement recorded an improvement in CTE value, Young's modulus, and compressive strength by about 38.1%, 22.2%, and 20.5%, respectively, compared to Al
基于铝的功能分级纳米复合材料(FGNCs)是一种人工定制的异质材料,旨在满足各种工业应用对多样化和相互矛盾特性的需求。我们采用粉末冶金技术制备并研究了以石墨烯和碳化钒(VC)增强的铝为基础的 FGNCs 和混合 FGNCs(HFGNCs)。这两种样品均采用梯度成分设计,即底层由 100% 的纯铝组成,然后连续三层含有逐渐增加的增强成分。与纯铝相比,在层粉末中加入石墨烯和 VC 会导致颗粒和晶体尺寸减小。添加石墨烯对体积密度样品有负面影响,而添加 VC 则有正面影响。增强材料导致热导率降低,使用 VC 增强材料的样品热导率降低了 26.7%,但使用石墨烯增强的 FGNC 除外,其热导率比纯铝增加了约 3.3%。虽然单独添加石墨烯会导致导电率略有下降,但样品的 CTE 值和导电率都有所下降。添加石墨烯后,所有机械性能都有明显改善。与铝相比,添加了最大量混合增强材料的 HFGCN 的 CTE 值、杨氏模量和抗压强度分别提高了约 38.1%、22.2% 和 20.5%。
{"title":"Fabrication and Characterization of Functionally Graded Nanocomposites: Impact of Graphene and Vanadium Carbide on Aluminum Matrix","authors":"Essam B. Moustafa, Mohamed Said, Abdulrahman Aljabri, Mohammed A. Taha, Rasha Youness, Hossameldin Hussein","doi":"10.1149/2162-8777/ad4c96","DOIUrl":"https://doi.org/10.1149/2162-8777/ad4c96","url":null,"abstract":"\u0000 Functional graded nanocomposites (FGNCs) based on Al are artificially tailored heterogeneous materials intended to serve the demand for diverse and contradicting properties used in various industrial applications. FGNCs and hybrid FGNCs (HFGNCs) based on Al reinforced with graphene and vanadium carbide (VC) were prepared using powder metallurgy techniques and investigated. Both samples were designed with a gradient composition, where the bottom layer consisted of 100% pure Al, followed by three consecutive layers containing progressively increasing amounts of reinforcement. The incorporation of graphene and VC into layer powders resulted in a decrease in both particle and crystal dimensions compared to pure Al. Adding graphene has a negative effect on bulk density samples, while VC has a positive effect. Reinforcing materials led to a decrease in thermal conductivity that reached 26.7 % for samples reinforced with VC reinforcement, except for FGNCs reinforced with graphene, which increased by ~3.3 compared to Al. The samples’ CTE and electrical conductivity values decreased, although adding graphene alone led to a slight decrease in electrical conductivity. A significant improvement in all mechanical properties was noted with additional. The HFGCNs reinforced with the largest amount of hybrid reinforcement recorded an improvement in CTE value, Young's modulus, and compressive strength by about 38.1%, 22.2%, and 20.5%, respectively, compared to Al","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140969843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review—Recent Advancements in Perovskites Solar Cell Materials and the Investigation of Transition Metal Oxide-Based Nanocomposites for Usage in Perovskites Solar Cells 综述--过氧化物太阳能电池材料的最新进展以及用于过氧化物太阳能电池的过渡金属氧化物基纳米复合材料的研究
Pub Date : 2024-05-16 DOI: 10.1149/2162-8777/ad4c95
G. AlZaidy, Hamdah T.A. Alanazi
Perovskite solar cells (PSC) have drawn interest in recent years due to their progressively improving power conversion efficiency (PCE), lightweight and wearable properties, straightforward solution fabrication process, suitability for flight, potential for deployment in ultra-lightweight space applications, and low-cost material constituents, among other factors. The efficiency of perovskite solar cells has exceeded 25% by developing novel low-cost synthesis methods and advancements in interface and electrode materials, enhancing the production of high-quality perovskite films. Moreover, perovskite solar cells' stability has been the focus of several studies. This review primarily examines recent advances in perovskite solar cells concerning their properties, composition, and synthesis methods. The main focus is to study transition metal oxide (TMO)-based nanocomposites for various PSC layers, including electron transport layers (ETLs), hole transport layers (HTLs), and other layers. These TMO-based nanocomposites were employed in perovskite solar cells, considering their band gap, carrier mobility, transmittance, and other relevant factors. The prospects of different TMO (iron, titanium, copper, nickel, etc.) -based perovskite solar cells and their potential for commercialization feasibility have also been examined.
近年来,包光体太阳能电池(PSC)因其功率转换效率(PCE)的逐步提高、轻质和耐磨特性、直接的溶液制造工艺、适合飞行、在超轻型空间应用中的部署潜力以及低成本材料成分等因素而备受关注。通过开发新型低成本合成方法以及改进界面和电极材料,提高了高质量包晶体薄膜的生产,包晶体太阳能电池的效率已超过 25%。此外,过氧化物太阳能电池的稳定性也是多项研究的重点。本综述主要探讨了最近在包晶体太阳能电池的特性、组成和合成方法方面取得的进展。主要重点是研究用于各种 PSC 层(包括电子传输层 (ETL)、空穴传输层 (HTL) 和其他层)的基于过渡金属氧化物 (TMO) 的纳米复合材料。考虑到它们的带隙、载流子迁移率、透射率和其他相关因素,这些基于 TMO 的纳米复合材料被应用于过氧化物太阳能电池。此外,还研究了基于不同 TMO(铁、钛、铜、镍等)的透晶石太阳能电池的前景及其商业化的可行性潜力。
{"title":"Review—Recent Advancements in Perovskites Solar Cell Materials and the Investigation of Transition Metal Oxide-Based Nanocomposites for Usage in Perovskites Solar Cells","authors":"G. AlZaidy, Hamdah T.A. Alanazi","doi":"10.1149/2162-8777/ad4c95","DOIUrl":"https://doi.org/10.1149/2162-8777/ad4c95","url":null,"abstract":"\u0000 Perovskite solar cells (PSC) have drawn interest in recent years due to their progressively improving power conversion efficiency (PCE), lightweight and wearable properties, straightforward solution fabrication process, suitability for flight, potential for deployment in ultra-lightweight space applications, and low-cost material constituents, among other factors. The efficiency of perovskite solar cells has exceeded 25% by developing novel low-cost synthesis methods and advancements in interface and electrode materials, enhancing the production of high-quality perovskite films. Moreover, perovskite solar cells' stability has been the focus of several studies. This review primarily examines recent advances in perovskite solar cells concerning their properties, composition, and synthesis methods. The main focus is to study transition metal oxide (TMO)-based nanocomposites for various PSC layers, including electron transport layers (ETLs), hole transport layers (HTLs), and other layers. These TMO-based nanocomposites were employed in perovskite solar cells, considering their band gap, carrier mobility, transmittance, and other relevant factors. The prospects of different TMO (iron, titanium, copper, nickel, etc.) -based perovskite solar cells and their potential for commercialization feasibility have also been examined.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140968128","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Circuit Level Implementation of Negative Capacitance Source Pocket Double Gate Tunnel FET for Low Power Applications 用于低功耗应用的负电容源插座双栅极隧道场效应晶体管的电路级实现
Pub Date : 2024-05-14 DOI: 10.1149/2162-8777/ad4b9c
K. M. C. Babu, Ekta Goel
This manuscript presents a pioneering study on enhancing analog and radio frequency performance through the implementation of negative capacitance source pocket double gate tunnel field-effect transistor. By integrating a ferroelectric material into the gate stack and introducing a fully depleted n-type pocket near the source/channel junction, we achieved significant enhancements in key metrics such as ON current (ION), switching ratio, subthreshold swing (SS), and various analog/RF parameters like transconductance (gm), cutoff frequency (fT) when compared to existing literature. Additionally, we extend our analysis to circuit-level applications such as inverter and 5-stage ring oscillator. Our findings reveal an impressive inverter delay of 1.09 ps with a gain of 104, as well as a ring oscillator operating at a frequency of 500 GHz. These results position the proposed device as an ideal candidate for high-speed, low-power applications.
本手稿介绍了一项关于通过实施负电容源极袋双栅隧道场效应晶体管来提高模拟和射频性能的开创性研究。通过将铁电材料集成到栅极堆栈中,并在源极/沟道结附近引入一个完全耗尽的 n 型口袋,与现有文献相比,我们在导通电流 (ION)、开关比、次阈值摆幅 (SS) 等关键指标,以及跨导 (gm) 和截止频率 (fT) 等各种模拟/射频参数方面取得了显著提升。此外,我们还将分析扩展到逆变器和 5 级环形振荡器等电路级应用。我们的研究结果表明,在增益为 104 的情况下,逆变器的延迟时间为 1.09 ps,环形振荡器的工作频率为 500 GHz。这些结果将所提出的器件定位为高速、低功耗应用的理想候选器件。
{"title":"Circuit Level Implementation of Negative Capacitance Source Pocket Double Gate Tunnel FET for Low Power Applications","authors":"K. M. C. Babu, Ekta Goel","doi":"10.1149/2162-8777/ad4b9c","DOIUrl":"https://doi.org/10.1149/2162-8777/ad4b9c","url":null,"abstract":"\u0000 This manuscript presents a pioneering study on enhancing analog and radio frequency performance through the implementation of negative capacitance source pocket double gate tunnel field-effect transistor. By integrating a ferroelectric material into the gate stack and introducing a fully depleted n-type pocket near the source/channel junction, we achieved significant enhancements in key metrics such as ON current (ION), switching ratio, subthreshold swing (SS), and various analog/RF parameters like transconductance (gm), cutoff frequency (fT) when compared to existing literature. Additionally, we extend our analysis to circuit-level applications such as inverter and 5-stage ring oscillator. Our findings reveal an impressive inverter delay of 1.09 ps with a gain of 104, as well as a ring oscillator operating at a frequency of 500 GHz. These results position the proposed device as an ideal candidate for high-speed, low-power applications.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140980969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-Induced Ge-Doped HfO2 Applied to Ge Stacked Nanowires Ferroelectric Gate-all-Around Field-Effect Transistor with Steep Subthreshold Slope Under O3 Treatment with GeO2 as Interfacial Layer 在以 GeO2 为界面层的 O3 处理条件下,应用于 Ge 叠层纳米线的具有陡峭次阈值斜率的自诱导 Ge 掺杂 HfO2 铁电栅极全方位场效应晶体管
Pub Date : 2024-05-14 DOI: 10.1149/2162-8777/ad4b9d
Yi-Wen Lin, Yu-Hsien Huang, Shan-Wen Lin, Guang-Li Luo, YuHsien Lin, Yung-Chun Wu, Fu-Ju Hou
This study reports a self-induced ferroelectric Ge-doped HfO2 (Ge:HfO2) thin film through interface reactions. In the first experiment, three treatments for forming interfacial layer (IL) were discussed through TiN/2-nm-thick Al2O3/2-nm-thick Ge:HfO2/GeO2/Ge metal-ferroelectric-insulator-semiconductor capacitors. The remnant polarization (Pr), leakage current, and interface trap density (Dit) were compared to select the most appropriate IL treatment. The results show that the in-situ ozone treatment under the standard atomic layer deposition process had the second highest 2Pr value as well as lower Dit values. Next, the thicknesses of Al2O3/Ge:HfO2 would be changed to 4/2 nm and 3/3 nm to investigate the ferroelectricity and leakage current. Although the 3-nm-thick Al2O3/3-nm-thick Ge:HfO2 shows a lower 2Pr value, the leakage current is much lower than 2-nm-thick Al2O3/2-nm-thick Ge:HfO2. The self-induced ferroelectric 3-nm-thick Ge:HfO2 thin film was then applied to fabricate Ge stacked nanowires gate-all-around field-effect transistor. The results show a steep subthreshold slope of 58 mV/dec for pFET and on-off current ratio > 105 and have high potential in low-power IC applications.
本研究报告了通过界面反应自诱导铁电 Ge 掺杂 HfO2(Ge:HfO2)薄膜。在第一个实验中,通过 TiN/2-nm 厚的 Al2O3/2-nm 厚的 Ge:HfO2/GeO2/Ge 金属-铁电-绝缘体-半导体电容器,讨论了形成界面层(IL)的三种处理方法。比较了残余极化(Pr)、漏电流和界面陷阱密度(Dit),以选择最合适的电介质处理方法。结果表明,在标准原子层沉积工艺下的原位臭氧处理具有第二高的 2Pr 值和较低的 Dit 值。接下来,Al2O3/Ge:HfO2 的厚度将变为 4/2 nm 和 3/3 nm,以研究铁电性和漏电流。虽然 3 nm 厚的 Al2O3/3 nm 厚的 Ge:HfO2 显示出较低的 2Pr 值,但漏电流却远低于 2 nm 厚的 Al2O3/2 nm 厚的 Ge:HfO2。然后,将 3nm 厚的 Ge:HfO2 自诱导铁电薄膜用于制造 Ge 叠层纳米线全栅极场效应晶体管。结果显示,pFET 的陡峭次阈值斜率为 58 mV/dec,导通电流比大于 105,在低功耗集成电路应用中具有很大潜力。
{"title":"Self-Induced Ge-Doped HfO2 Applied to Ge Stacked Nanowires Ferroelectric Gate-all-Around Field-Effect Transistor with Steep Subthreshold Slope Under O3 Treatment with GeO2 as Interfacial Layer","authors":"Yi-Wen Lin, Yu-Hsien Huang, Shan-Wen Lin, Guang-Li Luo, YuHsien Lin, Yung-Chun Wu, Fu-Ju Hou","doi":"10.1149/2162-8777/ad4b9d","DOIUrl":"https://doi.org/10.1149/2162-8777/ad4b9d","url":null,"abstract":"\u0000 This study reports a self-induced ferroelectric Ge-doped HfO2 (Ge:HfO2) thin film through interface reactions. In the first experiment, three treatments for forming interfacial layer (IL) were discussed through TiN/2-nm-thick Al2O3/2-nm-thick Ge:HfO2/GeO2/Ge metal-ferroelectric-insulator-semiconductor capacitors. The remnant polarization (Pr), leakage current, and interface trap density (Dit) were compared to select the most appropriate IL treatment. The results show that the in-situ ozone treatment under the standard atomic layer deposition process had the second highest 2Pr value as well as lower Dit values. Next, the thicknesses of Al2O3/Ge:HfO2 would be changed to 4/2 nm and 3/3 nm to investigate the ferroelectricity and leakage current. Although the 3-nm-thick Al2O3/3-nm-thick Ge:HfO2 shows a lower 2Pr value, the leakage current is much lower than 2-nm-thick Al2O3/2-nm-thick Ge:HfO2. The self-induced ferroelectric 3-nm-thick Ge:HfO2 thin film was then applied to fabricate Ge stacked nanowires gate-all-around field-effect transistor. The results show a steep subthreshold slope of 58 mV/dec for pFET and on-off current ratio > 105 and have high potential in low-power IC applications.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140978905","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Point-of-Care Detection of HER2 and CA 15-3 in Breast Cancer Patients: Dual-Channel Biosensor Implementation 乳腺癌患者 HER2 和 CA 15-3 的护理点检测:双通道生物传感器的实现
Pub Date : 2024-05-13 DOI: 10.1149/2162-8777/ad4ac4
Hsiao-Hsuan Wan, Haochen Zhu, Chao-Ching Chiang, Xinyi Xia, Jian-Sian Li, Fan Ren, Cheng-Tse Tsai, Yu-Te Liao, Tai-Cheng Chou, D. Neal, J. Esquivel-Upshaw
Breast cancer remains a considerable health challenge, affecting numerous individuals annually. This research introduces an innovative method for detecting breast cancer utilizing dual-channel test strips capable of simultaneously assessing two key biomarkers—HER2 and CA 15-3. The test strip utilized in this study is not only cost-effective but also entirely non-invasive. The reusable device employs a printed circuit board with metal-oxide-semiconductor field-effect transistor amplification and Arduino-based control to convert voltage signals from test strips into digital readings efficiently. The device utilizes double-pulse measurement instead of direct current, effectively mitigating the screening effect. The detection limit for both biomarkers is exceptionally low at 10-15 g/mL, surpassing commercial enzyme-linked immunoassay kits by four orders of magnitude. The sensor demonstrates remarkable sensitivity, with 78/dec for HER2 and 56/dec for CA 15-3. Human sample tests were conducted to validate the efficacy of the dual-channel strip, successfully distinguishing between healthy and cancerous groups. The results reveal significant p-values for both HER2 and CA 15-3 tests, underscoring the significance of this research. Note that this is a rapid testing process, completed in less than 2 seconds. These findings offer a promising avenue for swift and accurate breast cancer detection, furnishing crucial insights for early diagnosis and subsequent treatment.
乳腺癌仍然是一项巨大的健康挑战,每年影响着无数人。这项研究介绍了一种利用双通道试纸检测乳腺癌的创新方法,这种试纸能够同时评估两种关键的生物标志物--HER2 和 CA 15-3。这项研究中使用的试纸不仅具有成本效益,而且完全无创。这种可重复使用的设备采用了带金属氧化物半导体场效应晶体管放大功能的印刷电路板和基于 Arduino 的控制,能有效地将试纸上的电压信号转换成数字读数。该设备采用双脉冲测量而非直流电,有效地减轻了筛选效应。这两种生物标记物的检测限极低,仅为 10-15 克/毫升,比商用酶联免疫测定试剂盒高出四个数量级。该传感器灵敏度极高,HER2 为 78/dec,CA 15-3 为 56/dec。为了验证双通道条带的功效,我们进行了人体样本测试,成功区分了健康组和癌症组。结果显示,HER2 和 CA 15-3 测试的 p 值都很明显,突出了这项研究的意义。请注意,这是一个快速检测过程,不到 2 秒钟即可完成。这些研究结果为快速、准确地检测乳腺癌提供了一个很好的途径,为早期诊断和后续治疗提供了重要依据。
{"title":"Point-of-Care Detection of HER2 and CA 15-3 in Breast Cancer Patients: Dual-Channel Biosensor Implementation","authors":"Hsiao-Hsuan Wan, Haochen Zhu, Chao-Ching Chiang, Xinyi Xia, Jian-Sian Li, Fan Ren, Cheng-Tse Tsai, Yu-Te Liao, Tai-Cheng Chou, D. Neal, J. Esquivel-Upshaw","doi":"10.1149/2162-8777/ad4ac4","DOIUrl":"https://doi.org/10.1149/2162-8777/ad4ac4","url":null,"abstract":"\u0000 Breast cancer remains a considerable health challenge, affecting numerous individuals annually. This research introduces an innovative method for detecting breast cancer utilizing dual-channel test strips capable of simultaneously assessing two key biomarkers—HER2 and CA 15-3. The test strip utilized in this study is not only cost-effective but also entirely non-invasive. The reusable device employs a printed circuit board with metal-oxide-semiconductor field-effect transistor amplification and Arduino-based control to convert voltage signals from test strips into digital readings efficiently. The device utilizes double-pulse measurement instead of direct current, effectively mitigating the screening effect. The detection limit for both biomarkers is exceptionally low at 10-15 g/mL, surpassing commercial enzyme-linked immunoassay kits by four orders of magnitude. The sensor demonstrates remarkable sensitivity, with 78/dec for HER2 and 56/dec for CA 15-3. Human sample tests were conducted to validate the efficacy of the dual-channel strip, successfully distinguishing between healthy and cancerous groups. The results reveal significant p-values for both HER2 and CA 15-3 tests, underscoring the significance of this research. Note that this is a rapid testing process, completed in less than 2 seconds. These findings offer a promising avenue for swift and accurate breast cancer detection, furnishing crucial insights for early diagnosis and subsequent treatment.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140984704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Threshold Voltage Instability After Double Pulse Test Under Different OFF-State Drain Voltages and ON-State Drain Currents in p-GaN Gate AlGaN/GaN HEMT p-GaN 栅 AlGaN/GaN HEMT 在不同离态漏极电压和 ON 态漏极电流条件下进行双脉冲测试后的阈值电压不稳定性
Pub Date : 2024-05-10 DOI: 10.1149/2162-8777/ad49d6
Chih-wei Chen, Hao-Hsuan Lo, Y. Hsin
This study investigated threshold voltage (VTH) instability in a Schottky p-GaN gate AlGaN/GaN high-electron-mobility transistor (HEMT) by using the double pulse test (DPT) with a 1-µs pulse width in the ON-state and OFF-state. OFF-state drain biases (VDS,OFF) of 100–400 V and ON-state drain currents of ID,ON 1–16 A were applied in the DPT to observe the post-DPT VTH shift. The ON-state currents did not strongly influence the device's characteristics after the DPT. However, the OFF-state voltages, particularly VDS,OFF = 100 and 200 V, exerted notable effects. A TCAD simulation was conducted to investigate the mechanism underlying the VTH shift after the DPT at various VDS,OFF and ID,ON levels.
本研究通过在导通和关断状态使用脉冲宽度为 1µs 的双脉冲测试 (DPT),研究了肖特基 p-GaN 栅 AlGaN/GaN 高电子迁移率晶体管 (HEMT) 的阈值电压 (VTH) 不稳定性。在 DPT 中施加了 100-400 V 的关态漏极偏置 (VDS,OFF) 和 1-16 A 的导通态漏极电流 ID,ON,以观察 DPT 后的 VTH 漂移。在 DPT 之后,导通态电流对器件特性的影响不大。然而,关断态电压,尤其是 VDS,OFF = 100 和 200 V,却产生了显著的影响。我们进行了 TCAD 仿真,以研究在不同 VDS,OFF 和 ID,ON 电平下 DPT 后 VTH 漂移的基本机制。
{"title":"Threshold Voltage Instability After Double Pulse Test Under Different OFF-State Drain Voltages and ON-State Drain Currents in p-GaN Gate AlGaN/GaN HEMT","authors":"Chih-wei Chen, Hao-Hsuan Lo, Y. Hsin","doi":"10.1149/2162-8777/ad49d6","DOIUrl":"https://doi.org/10.1149/2162-8777/ad49d6","url":null,"abstract":"\u0000 This study investigated threshold voltage (VTH) instability in a Schottky p-GaN gate AlGaN/GaN high-electron-mobility transistor (HEMT) by using the double pulse test (DPT) with a 1-µs pulse width in the ON-state and OFF-state. OFF-state drain biases (VDS,OFF) of 100–400 V and ON-state drain currents of ID,ON 1–16 A were applied in the DPT to observe the post-DPT VTH shift. The ON-state currents did not strongly influence the device's characteristics after the DPT. However, the OFF-state voltages, particularly VDS,OFF = 100 and 200 V, exerted notable effects. A TCAD simulation was conducted to investigate the mechanism underlying the VTH shift after the DPT at various VDS,OFF and ID,ON levels.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140992587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Red Photoluminescence from Fe-Doped MgAl2O4 Crystals 掺杂铁的 MgAl2O4 晶体发出红色光致发光
Pub Date : 2024-05-09 DOI: 10.1149/2162-8777/ad497b
Ami Hitomi, Arisa Mori, Ririka Watanabe, Toru Katsumata, Hiroaki Aizawa
The influence of variations in composition (x = MgO/Al2O3 = 0.3–1.0), Fe2O3 concentrations (0.05 mol%–2.0 mol%), and O2 concentrations (100 vol% and 0 vol%) in the atmosphere on the PL characteristics of Fe-doped MgAl2O4 crystals were investigated using single phase spinel crystals grown by FZ technique. The peak wavelength shift of photoluminescence at around 730 nm are observed depending on the Fe2O3 concentration and composition. Concentration quenching of red PL occurred at Fe2O3 concentration above 0.1 mol%. PL intensity was higher in samples grown in 100 vol% O2 compared to those grown in 100 vol% Ar. PL intensity from Fe-doped MgAl2O4 increased with increasing compositions x from 0.3 to 1.0. MgAl2O4 doped with 0.1 mol% Fe2O3, and a stoichiometric composition (x = 1.0) grown in 100 vol% O2, demonstrated strong red PL with ultraviolet-C (UVC) lights excitation.
利用 FZ 技术生长的单相尖晶石晶体,研究了大气中成分(x = MgO/Al2O3 = 0.3-1.0)、Fe2O3 浓度(0.05 mol%-2.0 mol%)和 O2 浓度(100 vol% 和 0 vol%)的变化对 Fe 掺杂 MgAl2O4 晶体的光致发光特性的影响。根据 Fe2O3 的浓度和成分,在 730 nm 左右观察到了光致发光峰值波长的移动。当 Fe2O3 的浓度超过 0.1 摩尔%时,红色 PL 出现浓度淬灭。与在 100 vol% Ar 中生长的样品相比,在 100 vol% O2 中生长的样品的聚光强度更高。随着成分 x 从 0.3 到 1.0 的增加,掺杂铁的 MgAl2O4 的聚光强度也随之增加。掺杂了 0.1 mol% Fe2O3 的 MgAl2O4 和在 100 vol% O2 中生长的化学成分(x = 1.0)在紫外线-C(UVC)灯的激发下显示出强烈的红色聚光。
{"title":"Red Photoluminescence from Fe-Doped MgAl2O4 Crystals","authors":"Ami Hitomi, Arisa Mori, Ririka Watanabe, Toru Katsumata, Hiroaki Aizawa","doi":"10.1149/2162-8777/ad497b","DOIUrl":"https://doi.org/10.1149/2162-8777/ad497b","url":null,"abstract":"\u0000 The influence of variations in composition (x = MgO/Al2O3 = 0.3–1.0), Fe2O3 concentrations (0.05 mol%–2.0 mol%), and O2 concentrations (100 vol% and 0 vol%) in the atmosphere on the PL characteristics of Fe-doped MgAl2O4 crystals were investigated using single phase spinel crystals grown by FZ technique. The peak wavelength shift of photoluminescence at around 730 nm are observed depending on the Fe2O3 concentration and composition. Concentration quenching of red PL occurred at Fe2O3 concentration above 0.1 mol%. PL intensity was higher in samples grown in 100 vol% O2 compared to those grown in 100 vol% Ar. PL intensity from Fe-doped MgAl2O4 increased with increasing compositions x from 0.3 to 1.0. MgAl2O4 doped with 0.1 mol% Fe2O3, and a stoichiometric composition (x = 1.0) grown in 100 vol% O2, demonstrated strong red PL with ultraviolet-C (UVC) lights excitation.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140995449","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Controllable Fabrication of Silicon Solar Cells with Inverted or Upright Pyramid Structures by a One-Step Copper Catalysis Method 通过铜催化一步法可控制造具有倒置或直立金字塔结构的硅太阳能电池
Pub Date : 2024-05-09 DOI: 10.1149/2162-8777/ad497a
Chenliang Huo
Silicon has garnered significant attention as the primary material for solar cell preparation. Traditional alkaline etching solutions are limited to creating an upright pyramid structure on monocrystalline silicon surfaces. However, research indicates that an inverted pyramid structure exhibits superior light-trapping properties compared to the upright pyramid structure. In this study, we employed a one-step copper ion metal-assisted chemical etching process to fabricate an inverted pyramid structure on monocrystalline silicon wafers. This method allows for the customization of either inverted or upright pyramid structures by adjusting the concentration of specific solution components. Characterization of the textured silicon wafers reveals that the inverted pyramid structure exhibits lower reflectivity than both the upright pyramid structure and polished silicon. By integrating this texturing technique into the solar cell production line, we successfully produced solar cells with both inverted and upright pyramid structures. Evaluation of various solar cell parameters demonstrates that the inverted pyramid structure outperforms the upright pyramid structure, showcasing lower reflectivity and higher photoelectric conversion efficiency.
硅作为制备太阳能电池的主要材料,已经引起了广泛关注。传统的碱性蚀刻解决方案仅限于在单晶硅表面形成直立的金字塔结构。然而,研究表明,与直立金字塔结构相比,倒金字塔结构具有更优越的光捕获特性。在这项研究中,我们采用了一步式铜离子金属辅助化学蚀刻工艺,在单晶硅片上制造出了倒金字塔结构。这种方法可以通过调整特定溶液成分的浓度来定制倒置或直立的金字塔结构。纹理硅片的特性分析表明,倒金字塔结构的反射率低于直立金字塔结构和抛光硅片。通过将这种制绒技术集成到太阳能电池生产线中,我们成功地生产出了具有倒金字塔结构和直立金字塔结构的太阳能电池。对各种太阳能电池参数的评估表明,倒金字塔结构优于直立金字塔结构,具有更低的反射率和更高的光电转换效率。
{"title":"Controllable Fabrication of Silicon Solar Cells with Inverted or Upright Pyramid Structures by a One-Step Copper Catalysis Method","authors":"Chenliang Huo","doi":"10.1149/2162-8777/ad497a","DOIUrl":"https://doi.org/10.1149/2162-8777/ad497a","url":null,"abstract":"\u0000 Silicon has garnered significant attention as the primary material for solar cell preparation. Traditional alkaline etching solutions are limited to creating an upright pyramid structure on monocrystalline silicon surfaces. However, research indicates that an inverted pyramid structure exhibits superior light-trapping properties compared to the upright pyramid structure. In this study, we employed a one-step copper ion metal-assisted chemical etching process to fabricate an inverted pyramid structure on monocrystalline silicon wafers. This method allows for the customization of either inverted or upright pyramid structures by adjusting the concentration of specific solution components. Characterization of the textured silicon wafers reveals that the inverted pyramid structure exhibits lower reflectivity than both the upright pyramid structure and polished silicon. By integrating this texturing technique into the solar cell production line, we successfully produced solar cells with both inverted and upright pyramid structures. Evaluation of various solar cell parameters demonstrates that the inverted pyramid structure outperforms the upright pyramid structure, showcasing lower reflectivity and higher photoelectric conversion efficiency.","PeriodicalId":504734,"journal":{"name":"ECS Journal of Solid State Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140996403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
期刊
ECS Journal of Solid State Science and Technology
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1