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J. R. LOGAN AND THE ORIGIN OF THE TROPICAL INSELBERGS KNOWN AS NUBBINS (OR KNOLLS) J.R.LOGAN和被称为NUBBINS(或KNOLLS)的热带昆虫的起源
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2022-01-01 DOI: 10.17704/1944-6187-41.1.107
C. Twidale
Pulau Ubin is located in the Johor Strait between the Malay Peninsula and Singapore Island. The topography shaped in a granitoid complex of Permo-Triassic age, comprises jungle covered and isolated blocky hills, a flat and marshy central valley floor, and a coastline in which grooved boulders are prominent. In papers published in 1847, 1849 and 1851 (but here reporting their content in modern terminology) J. B. Logan attributed the island landscape to deep differential chemical weathering, followed by exposure of the resulting bedrock morphology. This is characterized by massive blocks protruding between a saprolithic cover—in modern parlance a two-stage etch origin of a group of inselbergs of nubbin (or knoll) type covered by blocks and boulders derived from the breakdown of the outer shell or shells or sheet structures. The Pulau Ubin nubbins carry remnants of a saprolithic veneer and are of ‘wet’ type by contrast with the saprolith-free ‘dry’ forms of arid or seasonally arid climes. The conversion of nubbins to bornhardts in arid climes also is noted. Logan identified the crucial aspects of what is still a highly favoured hypothesis of inselberg origin based on field evidence from many parts of the world and articulated by Falconer in 1911. But there was in Logan’s time no agreed and appropriate technical terminology. Moreover, some of Logan’s reports such as that dated 1849 are disorganized and diffuse, but contain occasional insightful observations and deductions.
乌宾岛位于马来半岛和新加坡岛之间的柔佛海峡。地形形成于二叠纪-三叠纪的花岗岩复合体中,包括丛林覆盖和孤立的块状山丘、平坦沼泽的中央谷底和突出有沟槽的巨石的海岸线。在1847年、1849年和1851年发表的论文中(但此处用现代术语报道了其内容),J.B.Logan将岛屿景观归因于深度差异化学风化,随后暴露出由此产生的基岩形态。其特征是在腐泥土覆盖层之间突出的块状物——用现代说法,这是一组由外壳或外壳或片状结构破裂产生的块状物和巨石覆盖的块状(或knoll)嵌岩的两阶段蚀刻起源。乌宾岛(Pulau Ubin)的小块带有腐泥土贴面的残余物,与干旱或季节性干旱气候的无腐泥土“干燥”形式形成鲜明对比,属于“潮湿”类型。也注意到在干旱的气候下,牛蒡转变为龙脑草。洛根根据来自世界许多地方的实地证据,并由法尔科内于1911年阐述,确定了目前仍备受青睐的因斯伯格起源假说的关键方面。但在洛根的时代,没有达成一致的、适当的技术术语。此外,洛根的一些报告,如1849年的报告,杂乱无章,但偶尔也会有深刻的观察和推断。
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引用次数: 1
Statistical Regularity and Relation Between Small Earthquakes and Crustal Velocity Structure Beneath Bohai Sea and Its Surrounding Areas in China 渤海及周边地区小震与地壳速度结构的统计规律及关系
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-11-12 DOI: 10.11648/J.EARTH.20211006.13
Zhu Xinran, Xue Peng, Wang Wei, Ni Yingying, Pan Guanghua
The Bohai Sea is a seismically active region in China, and the studying of the velocity structure of Bohai Sea and its relationship with earthquake may be helpful to the analysis and prediction of earthquakes. Now, ambient noise tomography is an effective tool to obtain crust and upmost mantle structure. In this paper, the S-wave velocity model of the crust beneath the Bohai Sea and its surrouding areas in China was constructed applying ambient noise tomography method, with steps of calculating cross correlations of all possible vertical-component data recorded in 2013 year, retrieving Empirical Green’s Functions (EGFs) for Rayleigh wave, measuring and assessing phase velocity-dispersion curves, creating the phase-velocity maps for the 8-35 s period of the Rayleigh wave, constructing the phase velocity maps and inverting the S-wave velocity structure. We work on the statistics and analysis of the characteristic relationship between crustal S-wave velocity and the temporal and spatial distribution of small earthquakes. The results from all available vertical profiles along different directions reveal that small earthquakes usually occur at the edge of the low-velocity anomaly within the shallow crust in a certain velocity range and, under special conditions, even in a distinct velocity contour. The locations of occurrence are closely related to undulating changes of the corresponding Moho morphology and the locally high Vs anomalies within the middle crust.
渤海是中国的地震活动区,研究其速度结构及其与地震的关系有助于地震的分析和预报。目前,环境噪声层析成像是获取地壳和上地幔结构的有效工具。本文应用环境噪声层析成像方法构建了中国渤海及周边地壳s波速度模型,计算了2013年所有可能的垂向分量数据的相互关系,检索了Rayleigh波的经验格林函数(EGFs),测量并评估了相速度-频散曲线,绘制了Rayleigh波8 ~ 35s周期的相速度图。构造相速度图,反演横波速度结构。统计和分析了地壳横波速度与小地震时空分布的特征关系。所有不同方向垂直剖面的结果表明,小地震通常发生在一定速度范围内的浅层地壳低速异常边缘,在特殊条件下,甚至在不同的速度等值线上。其赋存位置与相应Moho形态的起伏变化和中地壳局部高v异常密切相关。
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引用次数: 0
Causes, Modeling and Mitigation of Urban Heat Island: A Review 城市热岛的成因、模拟与缓解:综述
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-11-10 DOI: 10.11648/J.EARTH.20211006.11
H. M. Imran, M. Shammas, Ataur Rahman, S. Jacobs, A. Ng, S. Muthukumaran
Urbanization leads to loss of vegetation and converting pervious areas into built-up and impervious areas, and consequently, urban areas expose higher temperatures as compared to surrounding rural areas, which is called Urban Heat Island (UHI). The UHI affects the urban environment and causes heat-related diseases and mortality that have increased over the last centuries. Considering the severity of the UHI problem, enormous research has been conducted and an extensive range of literature is available on this topic. This paper reviews the causes, modelling and mitigation strategies of the UHI. The urban infrastructure and anthropogenic heat sources are the main driving factors in developing the UHI in cities. Many approaches including observation and modelling techniques are used to understand the formation, causes and mitigation of the UHI. The formation and causes of the UHI largely depend on the size, shape and urban infrastructure of the cities as well as climatic conditions. Although various modelling techniques are used to study UHI, there are still lacks in all models to precisely represent the physical phenomena and complex urban infrastructure. Many UHI mitigation strategies are examined by numerous studies, while the increased urban vegetation is a more environmentally friendly solution. The study summarizes the important features and limitations of different modelling techniques and mitigation measures of the UHI. This study also identifies research gaps and proposes areas for further research.
城市化导致植被损失,并将透水区域转化为建筑和不透水区域,因此,与周围的农村地区相比,城市地区暴露的温度更高,这被称为城市热岛(UHI)。城市热岛影响城市环境,并导致与热有关的疾病和死亡率在过去几个世纪有所增加。考虑到全民健康保险问题的严重性,已经进行了大量的研究,并有广泛的文献可获得。本文综述了热岛的成因、建模和缓解战略。城市基础设施和人为热源是城市热岛发展的主要驱动因素。包括观测和建模技术在内的许多方法被用于了解热岛的形成、原因和缓解。城市热岛的形成和成因在很大程度上取决于城市的规模、形状和城市基础设施以及气候条件。虽然采用了各种建模技术来研究城市热岛,但在所有模型中仍然缺乏精确地表示物理现象和复杂的城市基础设施。许多研究审查了许多缓解热岛问题的战略,而增加城市植被是一种更有利于环境的解决办法。该研究总结了不同模拟技术和热岛热岛缓解措施的重要特点和局限性。本研究还确定了研究差距,并提出了进一步研究的领域。
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引用次数: 2
Statistical Analysis of Ozone Weekend Effect in the Largest Cities in Poland 波兰大城市臭氧周末效应的统计分析
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-11-10 DOI: 10.11648/J.EARTH.20211006.12
Izabela Pawlak
This study examines O3, NOx, NO2 and NO data from five large cities in Poland (Warszawa, Krakow, Łodź, Wroclaw and Poznan) over a three-year period (2015-2017) to quantify the phenomenon of ozone weekend effect. The seasonal and diurnal variations of O3 and NOx species, showing the interdependence these two gaseous species, were presented. The number of 8-hour running average values above the threshold of 60 ppb and 1-hour above 90 ppb shows that ozone exceeded amounts are more frequent on Saturday and Sunday compared to other days of the week. The analysis of day of the week variations of O3 indicates distinct, temporal pattern with maximum O3 concentrations during weekend (especially on Sunday) and minimum noted on Wednesday, Thursday and Friday (depending on the station). The analysis of existence of the ozone weekend effect was performed on the basis of average O3 concentration at the weekend and on the day of the lowest O3 concentration during the week. Calculations were performed for the period of the whole year and for individual seasons of the year. The results of performance the non-parametric U-Mann-Whitney test indicate that differences of O3 concentration between weekend and a specific day of the week were statistically significant for most cases, despite the significantly lower concentration of ozone precursors (NOx). The analysis of Ox concentrations indicates that limited processes of O3 titration by NO (ozone quenching hypothesis) are the main cause of the ozone weekend effect in the Polish cities.
本研究分析了波兰五个大城市(华沙、克拉科夫、Łodź、弗罗茨瓦夫和波兹南)三年(2015-2017年)的O3、NOx、NO2和NO数据,以量化臭氧周末效应现象。分析了大气中O3和NOx的季节和日变化特征,揭示了二者之间的相互依赖关系。超过60 ppb的8小时平均值和超过90 ppb的1小时平均值表明,与一周中的其他日子相比,臭氧超标的频率在周六和周日更高。对O3的逐日变化分析显示出明显的时间格局,O3浓度在周末(特别是周日)最高,在周三、周四和周五(取决于站点)最低。臭氧周末效应的存在依据是周末的平均臭氧浓度和一周中臭氧浓度最低的一天。对全年和一年中的各个季节进行了计算。非参数U-Mann-Whitney检验结果表明,尽管臭氧前体(NOx)浓度明显较低,但在大多数情况下,周末与一周中特定一天之间的O3浓度差异具有统计学意义。臭氧浓度分析表明,由NO滴定O3的限制过程(臭氧猝灭假说)是波兰城市臭氧周末效应的主要原因。
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引用次数: 0
Utilizing ERT and GPR to Distinguish Structures Maleficence the Constructions in the New Administrative Capital, Egypt 利用ERT和GPR识别埃及新行政首都建筑的结构危害
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-10-29 DOI: 10.11648/J.EARTH.20211005.15
Adel D. M. Kotb, A. Basheer, A. Nasser, Mohamed Ramah
The new administrative capital (NAC), as decided by the Egyptian government's proposed planning, is placed 45 kilometers east of Cairo. According to Egyptian government strategies, this city will be the country's future governmental and economic hub. Ministries, crucial government agencies, and sectors are all expected to be represented on the site. The future capital's total land area is around 700 square kilometers. It is projected that there are five million people living there, this population could rise to seven million people. The skyscrapers sector in the New Administrative Capital is the subject of the research. To detect near-surface structures at the chosen building site, nine Electrical Resistivity Tomography (ERT) profiles and twenty-four Ground Penetrating Radar (GPR) profiles were used in this study. After the necessary and appropriate processing, the results that extrapolated from all measured profiles of both tools, demonstrated that the research region can be separated into two different shallow layers. The (Higher Miocene) sandy limestone rock makes up the main first surface layer with thickness about 4 meters. The second layer consists of silty shale rock with thickness about 12 meters in some places. This The most obvious features that had an impact on building were normal faults in the WNW and ENE directions, with minor fractures between them, as well as a few shale lenses can reach diameters of 3 to 4 meters. Additionally, the retrieved findings from the two geophysical tools demonstrate that the shape and thickness of the inferred layers are in satisfactory correlation.
根据埃及政府提出的规划,新行政首都(NAC)位于开罗以东45公里处。根据埃及政府的战略,这座城市将成为该国未来的政府和经济中心。各部委、重要的政府机构和部门都将出席会议。未来首都的土地总面积约为700平方公里。据估计,目前有500万人居住在那里,这一人口可能会增加到700万人。此次调查的对象是新行政首都的摩天大楼。为了探测选定建筑场地的近地表结构,本研究使用了9条电阻率层析成像(ERT)剖面和24条探地雷达(GPR)剖面。经过必要和适当的处理,从两种工具的所有测量剖面推断的结果表明,研究区域可以分为两个不同的浅层。第一表层主要为砂质灰岩(上中新世),厚度约4米。第二层由粉质页岩组成,在某些地方厚度约为12米。对造城影响最明显的特征是WNW和ENE方向的正断层,正断层之间有较小的裂缝,以及少数直径可达3 ~ 4米的页岩透镜体。此外,两种地球物理工具的检索结果表明,推断层的形状和厚度具有令人满意的相关性。
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引用次数: 0
Natura 2000: The European Way Towards Sustainability 《自然2000:欧洲走向可持续发展之路》
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-10-29 DOI: 10.11648/J.EARTH.20211005.14
Jesús María Garayo Urruela
Since the entry into force of the Habitats Directive (92/43/EEC) on 9 June 1994, the Natura 2000 Network has become the tool conceived by the Community authorities to lead the implementation of the environmental commitments on European territory, to which they were bound in application of their accession to international conventions. Natura 2000 pursues the conservation of biodiversity in Europe by harmonizing the conservation of natural heritage with the support and promotion of traditional human activities. The Habitats Directive formulated the principles, objectives, management measures and procedures to preserve, maintain or, where appropriate, restore biological diversity, which each State was subsequently responsible for transferring to the jurisdiction. The standard does not impose any specific method to be used in the designation of the sites, the type of management to be developed or the measures to be implemented, but it does establish control mechanisms over their application. The designation of a Natura 2000 site provides an invaluable opportunity to stimulate the sustainable rural development of the area and to promote plans and activities compatible with the conservation of habitats and protected species. Dialogue and concertation are the mechanisms to be put into practice when it comes to resolving conflicts arising from the design of management models that articulate the recovery of the environmental heritage. The model by which the Natura 2000 Network has been implemented so far in Spain, and specifically in the Autonomous Community of the Basque Country, has been based on technocratic-formal processes. The inclusion of the area in the Natura 2000 network tends to be perceived by the inhabitants of the rural world as a bureaucratized process, disconnected from local plans and collective projects. The considerable delay in the designation of areas protected by the Natura 2000 network has contributed to the delay in adopting appropriate measures to promote biodiversity and achieve the objective of halting biodiversity loss in Europe in the short term. Despite having redoubled efforts in favor of conservation, the processes of environmental degradation have been increasing.
自从生境指令(92/43/EEC)于1994年6月9日生效以来,自然2000网络已成为共同体当局设想的工具,以领导在欧洲领土上执行环境承诺,它们在加入国际公约时受到这些承诺的约束。Natura 2000通过协调自然遗产的保护与支持和促进传统人类活动来保护欧洲的生物多样性。生境指令规定了保护、维持或在适当情况下恢复生物多样性的原则、目标、管理措施和程序,每个国家随后负责将其移交管辖范围。该标准没有规定指定场址时使用的任何具体方法、要发展的管理类型或要实施的措施,但它确实建立了对其应用的控制机制。“2000年自然保护区”的指定提供了一个宝贵的机会,以促进该地区的可持续农村发展,并促进与保护生境和受保护物种相一致的计划和活动。当涉及到解决因设计管理模式而产生的冲突时,对话和协商是要付诸实践的机制,这些模式阐明了环境遗产的恢复。到目前为止,在西班牙,特别是在巴斯克自治区实施的“自然2000”网络所采用的模式是以技术官僚-正式程序为基础的。将该地区纳入Natura 2000网络往往会被农村世界的居民视为一个官僚化的过程,与当地计划和集体项目脱节。在指定受“自然2000”网络保护的地区方面的相当拖延,导致在采取适当措施促进生物多样性和实现在短期内制止欧洲生物多样性丧失的目标方面的拖延。尽管已加倍努力保护环境,但环境退化的进程仍在加剧。
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引用次数: 0
Suitability Evaluation for Spatial Expansion and Identification of Land Use Conflicts in Mountainous Country Villages and Towns: Take for Example Suining County 山地乡镇土地利用空间扩展适宜性评价与冲突识别——以遂宁县为例
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-10-21 DOI: 10.11648/J.EARTH.20211005.13
Wangli Zhang, J. Peng, Y. Liu, Xiaonan Cheng
Suining County of Shaoyang City, Hunan Province, was used as a suitability evaluation system from two aspects of natural and human factors including 12 indicators. The analytic hierarchy process and multi-factor weighted evaluation model were adopted to carry out the evaluation of the suitability of the spatial expansion of villages and towns for county-level. On this basis, the propensity intensity of three types of land use for villages and towns, agriculture, and ecology was calculated. Then, the high, middle and low grades were classified by the natural break point method, and the land use conflict recognition matrix was listed. Finally, the results of land use conflict identification were obtained. The results showed that: Suining County has significant differences in the suitability of spatial expansion of villages and towns, and the spatial distribution characteristics of different levels were quite different. The areas of the most suitable area, more suitable area, basic suitable area, less suitable area and unsuitable area for spatial expansion of villages and towns were respectively 183.67 km2, 699.04 km2, 1072.281 km2, 1006.79 km2 and 576.47 km2. The suitability of spatial expansion of each township was obviously different. The predominant land use areas of villages and towns were mainly distributed in Zhaishi Miao and Dong Township and Changpu Town in the south, and Shuikou Township and Jinwutang in the north Towns, etc. Dominant agricultural land areas were mainly distributed in the northeast of Tangjiafang, Huangtu Mine, Hongyan and other towns. The dominant ecological land area was relatively large, and the distribution was relatively scattered. The types of areas with obvious potential land use conflicts were the general conflict areas and intensified conflict areas, among which the general conflict areas were the largest, accounting for nearly half of the total area, and the intense conflict areas were the smallest. The areas of intense conflicts between villages and towns and agriculture, and the areas with intense conflicts between ecology and agriculture were all relatively small.
以湖南省邵阳市遂宁县为例,从自然因素和人为因素两个方面,选取12个指标作为适宜性评价体系。采用层次分析法和多因素加权评价模型对县域乡镇空间扩展适宜性进行评价。在此基础上,计算了城镇、农业和生态三种土地利用类型的倾向性强度。然后,采用自然断点法划分高、中、低等级,列出土地利用冲突识别矩阵;最后,得到土地利用冲突识别的结果。结果表明:遂宁县乡镇空间扩展适宜性差异显著,不同层次的空间分布特征差异较大;乡镇空间扩展最适宜面积、较适宜面积、基本适宜面积、次适宜面积和不适宜面积分别为183.67 km2、699.04 km2、1072.281 km2、1006.79 km2和576.47 km2。各乡镇空间扩展适宜性存在明显差异。乡镇的优势土地利用区主要分布在南部的寨石苗侗乡和长浦乡,北部的水口乡和金武塘乡等。优势农用地区主要分布在东北唐家坊、黄土矿、红岩等镇。优势生态用地面积较大,分布较为分散。存在明显潜在土地利用冲突的区域类型为一般冲突区和冲突加剧区,其中一般冲突区面积最大,占总面积的近一半,冲突加剧区面积最小。乡镇与农业冲突严重的地区、生态与农业冲突严重的地区都比较小。
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引用次数: 0
Investigation of the Effect of Strength Anisotropy on Slope Stability of C.D.G.S 强度各向异性对地下震源边坡稳定性影响的研究
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-10-12 DOI: 10.11648/J.EARTH.20211005.12
T. Ham, Jin-hwan Lim, Man-Bok Ha
The weathering of the granite rock results in C.D.G.S (completely decomposed granite soil) in most land area. Therefore, the C.D.G.S is commonly encountered in construction field, such as riverbanks and embankments, including roads and railways, and has a stress history of compaction with their construction. In this process, the compacted soil possesses an anisotropic property. Measurement of stress-strain-strength behavior of anisotropic decomposed granite soil is very important for the analysis of deformation and stability of slopes, retaining walls and excavations. Therefore, Anisotropy of mechanical properties for C.D.G.S (compacted decomposed granite soil), a series of unsaturated and saturated-drained triaxial compression tests was performed in order to investigate the deformation and strength anisotropy of C.D.G.S (compacted decomposed granite soils). Three different orientation angles of the axial direction of samples with respect to the horizontal plane were investigated: d=0, 45 and 90 degrees. As the results showed, the compression strain of specimens subjected to an isotropic compression was influenced strongly by d. The effect of the angle d on the strength was more pronounced on unsaturated specimen as compared to saturated specimen. In addition, the time dependence was independent of the settling angle associated with the deformation behavior during the secondary compression process. The effect of settling angle on triaxial compressive strength and deformation was clearly demonstrated at low constraining stresses. Furthermore, to investigate the effect of strength anisotropy according to the height of the fill on the slope stability, slope stability analysis was performed assuming 10m, 20m, 50m, and 100m of the embankment. it became clear that by considering strength anisotropy, the stability of embankment decreased when water level within the embankment was low. In order to obtain more reliable results in the future, verification using various samples will be required.
花岗岩的风化作用在大部分陆地地区造成了花岗岩土的完全分解。因此,在包括公路和铁路在内的河堤和堤防等建筑领域,经常会遇到地下震源,并在其施工过程中具有压实应力史。在此过程中,压实土具有各向异性。各向异性分解花岗岩土的应力-应变-强度特性测量对边坡、挡土墙和基坑的变形和稳定性分析具有重要意义。为此,针对花岗岩土的力学特性的各向异性,进行了非饱和和饱和排水三轴压缩试验,研究了花岗岩土的变形和强度的各向异性。研究了样品轴向相对于水平面的三种不同取向角:d=0、45和90度。结果表明,d对各向同性压缩试件的压缩应变影响较大,且角d对非饱和试件强度的影响比饱和试件更为明显。此外,在二次压缩过程中,与变形行为相关的沉降角与时间依赖性无关。在低约束应力条件下,沉降角对三轴抗压强度和变形的影响较为明显。此外,为了研究填土高度的强度各向异性对边坡稳定性的影响,分别假设路堤10m、20m、50m、100m,进行边坡稳定性分析。可见,考虑强度各向异性,路堤内水位较低时,路堤稳定性下降。为了在将来获得更可靠的结果,将需要使用各种样品进行验证。
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引用次数: 0
Kinetics of Biodiesel Production from Soya Bean Soap Stock 大豆皂原液生产生物柴油的动力学研究
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-09-07 DOI: 10.11648/J.EARTH.20211005.11
Chinedu Gabriel Mbah, C. Esonye, D. Onukwuli
Low quality lipids such as soyabeanrsoapstock, a by-product of vegetable oil processing can be used as a viable feedstock for the production of biodiesel due to its high yield capacity, availability, and low cost. Sodium hydroxide and methanol were used as catalyst and solvent respectively while n–hexane was added as a co-solvent. Kinetics of the transesterification reaction mechanismfor soyabeansoapstock with and without co-solvent (n-hexane) was carried out using models proposed by Singh & Fernando, (2007) to determine the reaction order and rate constant at different temperatures (45°C, 55°C and 65°C). Similar rate constants were obtained (with and without co-solvent) though with slightly different R2 values showing that n-hexane does not distort the chemistry of the reaction. Negative and very low R2 values obtained at temperatures 45°C and 65°C further affirms 55°C as the optimum temperature for the reaction. An activation energy of 74 KJ/mol and frequency factor of 2.9 was also obtained. Findings from the studyshows that soyabeansoapstock is a viable feedstock for the production of biodiesel and n-hexane was a suitable co-solvent in the transesterification of low quality lipids (soyabean soap stock). A rate constant of 0.0008 min-1 and reaction order of 2 was obtained for the transesterification reaction.
作为植物油加工的副产品,低质量的油脂,如大豆或肥皂原液,由于其高产、易得和低成本,可以用作生产生物柴油的可行原料。以氢氧化钠为催化剂,甲醇为溶剂,正己烷为助溶剂。采用Singh & Fernando(2007)提出的模型,对有和无助溶剂(正己烷)的大豆皂原酯交换反应机理进行了动力学研究,以确定在不同温度(45°C、55°C和65°C)下的反应顺序和速率常数。得到了相似的速率常数(有和没有助溶剂),但R2值略有不同,表明正己烷不会扭曲反应的化学性质。在45°C和65°C温度下得到的负R2值和非常低的R2值进一步证实了55°C是反应的最佳温度。得到活化能为74 KJ/mol,频率因子为2.9。研究结果表明,大豆皂原液是生产生物柴油的可行原料,正己烷是低质量油脂(大豆皂原液)酯交换反应的合适助溶剂。酯交换反应的速率常数为0.0008 min-1,反应级数为2。
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引用次数: 0
ESD Operators: Roles and Duties for the Environmental Monitoring Activities of ARPA Puglia ESD操作员:ARPA普利亚环境监测活动的角色和职责
IF 0.3 4区 哲学 Q2 Arts and Humanities Pub Date : 2021-08-31 DOI: 10.11648/j.earth.20211004.15
Costantino Gaetano, Dalle Mura Ilaria, De Gioia Michele, Strippoli Giuseppe, Ungaro Nicola, G. Domenico
ARPA Puglia (Italy), the Regional Agency for the Environmental Prevention and Protection, has chosen to use the Scientific Diving Operator figure (ESD) in order to meet some of the environmental monitoring activities foreseen by European Directives, such as WFD-Water Framework Directive 2000/60/EC and the MSFD-Marine Strategy Framework Directive 2008/56/EC. Regarding the environmental monitoring obligations of the aforementioned Directives, many of them involve underwater operations. For example, both Directives (MSFD and WFD) require Posidonia oceanica monitoring in situ, by collecting data on shoot density and other eco-biometric parameters, also describing the main ecological aspect of seagrass meadows; about Pinna nobilis, the visual census of its distribution and abundance is carried out underwater; the non-indigenous species census provided by MSFD requires the qualitative and quantitative sampling of the benthic communities of hard bottoms in harbors performed by a scratching technique. All the described activities need operations by ESDs, so ARPA Puglia developed a path for the implementation of good practices on the subject: adopting the national Guide Lines "Good practices for the safe performance of the underwater activities” (ISPRA manual n. 94/2013; D.D.G. n.229/2016); identifying the diving equipment as Personal Protective Equipment (PPE); allowing the acquisition or renewal of ESD scientific license for the operational staff; allowing the annual medical check-up for the ESD operational staff; opening of a national call in order to acquire specialized figures, selected according to ESD Panel standards. Details of environmental monitoring activities carried out by ARPA Puglia ESDs are described in this document.
意大利普利亚地区环境预防和保护机构(ARPA Puglia)选择使用科学潜水操作员(ESD),以满足欧洲指令所预见的一些环境监测活动,如世界粮食计划署-水框架指令2000/60/EC和msfd -海洋战略框架指令2008/56/EC。关于上述指令的环境监测义务,其中许多涉及水下作业。例如,两个指令(MSFD和WFD)都要求对海洋波西多尼亚进行现场监测,通过收集有关芽密度和其他生态生物特征参数的数据,还描述海草草甸的主要生态方面;关于Pinna nobilis,它的分布和数量在水下进行了视觉普查;MSFD提供的非本地物种普查需要通过抓挠技术对港口硬底的底栖生物群落进行定性和定量采样。所有描述的活动都需要esd的操作,因此ARPA Puglia制定了实施这一主题的良好做法的途径:采用国家指导方针“水下活动安全性能的良好做法”(ISPRA手册n. 94/2013;D.D.G. n.229/2016);将潜水装备标识为个人防护装备(PPE);允许操作人员取得或更新ESD科学许可证;为公共服务电子化行动人员提供每年一次的健康检查;在全国范围内开放,以获取专业数字,根据ESD面板标准选择。本文件描述了ARPA Puglia ESDs开展的环境监测活动的细节。
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Earth Sciences History
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