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Effect of Mercerization on Mechanical Properties of Grewia Optiva Natural Fiber Polymer Composites 丝光处理对 Grewia Optiva 天然纤维聚合物复合材料机械性能的影响
Pub Date : 2024-05-14 DOI: 10.4028/p-bji4ez
S. Chauhan, P. C. Gope
The concerns towards sustainable development have triggered the need of adopting biodegradable products in different applications. The natural fibers are being widely explored in the field of composites for various applications. Sustainable architecture is also seeking the research and development of new materials to minimize the negative environmental effect of the traditional structural materials. A bast fiber obtained from Grewia Optiva (G.O.) tree is abundantly available in the sub-Himalayan terrains and is still underutilized in the field of biocomposites. The promotion of G.O. fiber in fabrication of biocomposites may give a source of income and employment to rural hilly populations. This research work utilizes the G.O. fiber collected from the Okhalkanda block of Nainital district of Uttarakhand to develop biocomposites. The effect of mercerization on the water absorption behavior and mechanical properties has been also studied. It is found that the treatment of fibers with NaOH reduces the water absorption tendency of G.O. Natural Fiber Reinforced Biocomposites (NFRB) upto 41.05% and the mechanical properties are also improved by appreciable amount. The tensile and flexural strength obtained are 141.45 MPa and 109.84 MPa respectively for mercerized fiber reinforcement. Impact strength and mode-I fracture toughness have been recorded as 11.97 KJ/m2 and 1.85 MPa√m respectively. SEM images of fractured surfaces indicate good bonding of mercerized fibers as compared to untreated fibers with epoxy matrix. Hence the Grewia Optiva biocomposites have potential to be used in different architectural applications like wall panels, false ceilings, doors, windows, etc.
对可持续发展的关注引发了在不同应用中采用可生物降解产品的需求。天然纤维正被广泛应用于各种复合材料领域。可持续建筑也在寻求新材料的研发,以尽量减少传统结构材料对环境的负面影响。从 Grewia Optiva(G.O.)树中提取的韧皮纤维在喜马拉雅山下的地形中大量存在,但在生物复合材料领域仍未得到充分利用。在生物复合材料制造中推广 G.O. 纤维可为农村丘陵地区的居民提供收入来源和就业机会。这项研究工作利用从北阿坎德邦奈尼塔尔县 Okhalkanda 区收集的 G.O. 纤维来开发生物复合材料。还研究了丝光处理对吸水性能和机械性能的影响。研究发现,用 NaOH 处理纤维后,G.O. 天然纤维增强生物复合材料(NFRB)的吸水率降低了 41.05%,机械性能也得到了明显改善。丝光纤维增强材料的拉伸强度和弯曲强度分别为 141.45 兆帕和 109.84 兆帕。冲击强度和 I 型断裂韧性分别为 11.97 KJ/m2 和 1.85 MPa√m。断裂表面的 SEM 图像显示,丝光纤维与环氧树脂基体的粘结性比未经处理的纤维要好。因此,Grewia Optiva 生物复合材料有望用于不同的建筑用途,如墙板、假天花板、门窗等。
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引用次数: 0
Comparative Review of Mechanical Properties of Rice Straw and RiceHusk Fiber Reinforced Polymer Composite 稻草和稻壳纤维增强聚合物复合材料力学性能对比综述
Pub Date : 2024-05-14 DOI: 10.4028/p-93j3hv
D. Patel, Sachin Kumar, Hari Om Sharma, S. Kumar
Rice straw and rice husk fibers (RS/RH) reinforced polymer-based composites have theability to conserve wood and petroleum resources. As natural filler, rice straw and rice husk offer asustainable material for the production of polymer-based composites. The application ofbiocomposite limits the burning of straw at the root and may further enhance the socioeconomicstatus of farmers and rural populations. This review mainly focuses on five different weightpercentage of reinforced RS and RH fiber content (5%, 10%, 15%, 20% and 25%) in polymercomposites. Nowadays, Epoxy, polyurethane, polyester, PVA, PLA and polyethylene are beingused as matrix material in polymer composites. This paper holds good with understanding themechanical properties, pretreatment methods and offer important insight into potential uses ofpolymer composites with biodegradable reinforce fiber.
稻草和稻壳纤维(RS/RH)增强聚合物基复合材料可节约木材和石油资源。作为天然填料,稻草和稻壳是生产聚合物基复合材料的可持续材料。生物复合材料的应用从根本上限制了秸秆的焚烧,可进一步提高农民和农村人口的社会经济地位。本综述主要关注聚合物复合材料中五种不同重量百分比的增强 RS 和 RH 纤维含量(5%、10%、15%、20% 和 25%)。目前,环氧树脂、聚氨酯、聚酯、PVA、聚乳酸和聚乙烯都被用作聚合物复合材料的基体材料。本文有助于了解生物可降解增强纤维聚合物复合材料的机械性能、预处理方法和潜在用途。
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引用次数: 0
Determining the Properties of Unfired Stabilized Kaolinitic Clay Brick for Sustainable Construction 确定用于可持续建筑的未烧制稳定高岭土粘土砖的特性
Pub Date : 2024-05-14 DOI: 10.4028/p-05qmwb
S. Odeyemi, Abdulqudus Adeyanju Adegun, Michael Oluwasegun Adisa
Kaolin is one of the most vital industrial minerals whose application is reliant on its chemistry and structural makeup. This research attempts to determine the properties of unfired kaolinitic clay bricks for sustainable construction. Samples of the material were pre-treated and analyzed to obtain their physical and refractory properties, such as chemical composition, microstructure, moisture content, dry density, linear shrinkage, plastic index, and crushing strength. The results revealed that the clay comprises high percentages of silicon and alumina oxides being 75.6% and 17.0% of the total oxide composition respectively. The clay also contained some residual impurities in the form of metallic oxides i.e., oxides of iron, sodium, calcium, potassium, manganese, and lead. Characterization tests on the clay presented a specific gravity of 2.66, liquid limit of 38, plastic limit of 25.9, and plasticity index of 12.1 which classifies the clay as low-plasticity clay based on the Unified Soil Classification System. The river sand used was distributed between 0.06 – 3 mm falling within the category of medium and fine sand. The aggregate fineness modulus was obtained as 3.03%. The coefficient of uniformity was lower than 4.0 and thus classified as being uniformly graded. Stabilization of the clay with sand and lime resulted in decreased compression and flexural strength but increased durability. The results imply that kaolinitic clay can be used in an unfired form for earth construction.
高岭土是最重要的工业矿物之一,其应用取决于其化学性质和结构组成。本研究试图确定用于可持续建筑的未烧制高岭土粘土砖的特性。对材料样本进行预处理和分析,以获得其物理和耐火特性,如化学成分、微观结构、含水量、干密度、线性收缩率、塑性指数和压碎强度。结果显示,粘土中硅和氧化铝的比例较高,分别占总氧化物成分的 75.6% 和 17.0%。粘土中还含有一些金属氧化物形式的残留杂质,即铁、钠、钙、钾、锰和铅的氧化物。粘土的特性测试表明,粘土的比重为 2.66,液限为 38,塑限为 25.9,塑性指数为 12.1,根据统一土壤分类系统,粘土属于低塑性粘土。使用的河砂分布在 0.06 - 3 毫米之间,属于中砂和细砂类别。集料细度模量为 3.03%。均匀系数低于 4.0,因此被归类为均匀级配。用沙子和石灰对粘土进行稳定处理后,压缩强度和抗折强度都有所下降,但耐久性却有所提高。这些结果表明,高岭土可以以未烧成的形式用于土方工程。
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引用次数: 0
Thermal Cycle Simulation of Heat Affected Zone in the Welded Mild Steel 焊接低碳钢热影响区的热循环模拟
Pub Date : 2024-05-14 DOI: 10.4028/p-4rswbo
I. Hamdi, Z. Boumerzoug, Oualid Bedjaoui, W. Melik, F. Delaunois
The aim of this work was to study the microstructure evolution of simulated heat affected zone in mild steel using thermal cycle simulation and it was compared to the heat affected zone in the real welded joint. The optical microscopy, micro-hardness measurements, X-ray diffraction were used as characterization techniques. The microstructures and mechanical properties of the simulated heat affected zone were also determined. The use of the thermal cycle simulation technique revealed in detail the different microstructures in the heat affected zone (HAZ) of the welded joint. Some similarities were observed between the heat affected zone obtained by the thermal cycle simulation technique and the heat affected zone observed in the real welded joint. The thermal cycle simulation technique revealed more details about the microstructure and mechanical behavior of the heat-affected zone. The HAZ microhardness values were lowest hardness in the welded joint. Moreover, the lowest hardness value is obtained for the HAZ simulated at 850°C.
这项工作的目的是利用热循环模拟研究低碳钢模拟热影响区的微观结构演变,并将其与实际焊接接头中的热影响区进行比较。表征技术包括光学显微镜、显微硬度测量和 X 射线衍射。还测定了模拟热影响区的微观结构和机械性能。热循环模拟技术详细揭示了焊接接头热影响区(HAZ)的不同微观结构。通过热循环模拟技术获得的热影响区与实际焊点中观察到的热影响区有一些相似之处。热循环模拟技术揭示了热影响区微观结构和机械行为的更多细节。热影响区的显微硬度值是焊点中最低的。此外,在 850°C 下模拟的热影响区硬度值最低。
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引用次数: 0
A Comparative Study on the Synthesis of Type NaX Zeolite Prepared from Kaolin for Builder Application in Detergent Production 以高岭土为原料合成 NaX 型沸石并将其应用于洗涤剂生产的比较研究
Pub Date : 2024-05-14 DOI: 10.4028/p-lvxdd1
I. Ekpe, H. Mgbemere, Lawal Ganiyu, Henry Ovri, Anna Lisa Sargent, Obioha Charles
Zeolites being used as builders in detergents are synthesized from expensive chemicals with a cumbersome production process. In this study, zeolite was synthesized from cheaper and readily available kaolin for possible use in detergent production. Kaolin from two sources namely Ajebo, Ogun State and Darazo, Bauchi State, Nigeria was used as starting materials while wet beneficiation followed by acid leaching was used to purify the kaolin and hydrothermal process was used to synthesize the zeolite. The chemical analysis confirms the presence of silica and alumina which are the precursors materials for zeolite synthesis. An increase in the amounts of the desired silica and alumina for both kaolin accompanied by a reduction in the amounts of the undesired oxides present in the kaolin as impurities are clear indications that the acid leaching was successful. The zeolites synthesized from both kaolin shows better water adsorption capacity and ion exchange capacity compared to those reported for zeolite synthesized from pure chemicals, this ability makes zeolite more suitable for the production of detergent. These results are indications that zeolites synthesized from kaolin can serve as a possible replacement for the more expensive zeolite synthesized from chemicals used as builders in detergent production.
用作洗涤剂添加剂的沸石是用昂贵的化学品合成的,生产过程繁琐。在这项研究中,沸石是用更便宜且容易获得的高岭土合成的,可能用于洗涤剂生产。研究使用了尼日利亚奥贡州 Ajebo 和包奇州 Darazo 这两个产地的高岭土作为起始材料,同时使用湿法选矿和酸浸法提纯高岭土,并使用水热法合成沸石。化学分析证实了二氧化硅和氧化铝的存在,它们是合成沸石的前体材料。两种高岭土所需的二氧化硅和氧化铝含量的增加,以及作为杂质存在于高岭土中的不需要的氧化物含量的减少,都清楚地表明酸浸法是成功的。与用纯化学品合成的沸石相比,用这两种高岭土合成的沸石具有更好的水吸附能力和离子交换能力。这些结果表明,用高岭土合成的沸石有可能取代用化学品合成的价格昂贵的沸石,用于生产洗涤剂。
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引用次数: 0
Evaluation of the Use of Adhesive Tape in Laser Welded Ultra-High-Strength Steel Lap Joints 评估在激光焊接超高强度钢搭接接头中使用胶带的情况
Pub Date : 2024-05-14 DOI: 10.4028/p-a9bpem
M. Hietala, M. Keskitalo, A. Järvenpää
In this study, use of adhesive double-sided tape in laser welded ultra-high-strength steel lap joints was evaluated. The test material in the study was abrasion resistant steel (AR400). Optical microscopy was used to investigate macroscopic morphologies of the welds and hardness profiles were measured. Static properties of the joints were evaluated by performing tensile shear strength tests. Fatigue strength of the joints were evaluated by conducting axial fatigue tests. The use of tape resulted in a gap between the welded plates which has several advantages. The gap between the plates markedly increased the width of the weld at the interface of the plates. According to the hardness measurements the hardness of the weld metal was 12% higher compared to the hardness of the AR steel base material. The gap between the plates increased the strength of the joint by up to 20%. The adhesive tape itself did not have a significant effect on the shear strength of the joints. The main advantages of using the tape were a constant air gap and its function as a fastener in welding, so that separate fasteners are not needed.
本研究评估了激光焊接超高强度钢搭接接头中粘合双面胶带的使用情况。研究中的测试材料是耐磨钢(AR400)。使用光学显微镜研究了焊缝的宏观形态,并测量了硬度曲线。通过拉伸剪切强度测试评估了接头的静态性能。通过轴向疲劳试验评估了接头的疲劳强度。使用胶带会在焊接板之间产生间隙,这有几个优点。钢板之间的间隙明显增加了钢板接口处的焊缝宽度。根据硬度测量结果,焊接金属的硬度比 AR 钢母材的硬度高 12%。钢板之间的间隙使接头强度提高了 20%。胶带本身对接头的剪切强度没有明显影响。使用胶带的主要优点是空气间隙恒定,并且在焊接时可用作紧固件,因此不需要单独的紧固件。
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引用次数: 0
Optimization, Sodium Hydroxide and Plantain Fibres: Mechanical Properties of Unsaturated Polyester Composites for Transtibial Prosthetic Socket 优化、氢氧化钠和车前草纤维:用于经胫骨假体插座的不饱和聚酯复合材料的力学性能
Pub Date : 2024-05-14 DOI: 10.4028/p-gx7c9i
C. O. Nwaiwu, Jervas Ekezie, O. T. Azeez, Ada, J., Daniel, Oluchi Blessing Igbokwe, Magdalene Nkeiru Akanbi
Low mechanical behaviors of natural fibres in the reinforcement of polymer composites have remain an issue of concern. This study is aimed at investigating the effect of NaOH treatment on the mechanical properties of plantain fiber for the transtibial prosthetic sockets made of polyester resin. Plantain fiber was extracted from the plantain bast using water retting techniques. The fibres were modified using alkaline treatment method of 5 – 25% for variable time of 30 to 150 minutes. It was optimized using 3-level Factorial design (3-LCD) of response surface methodology based on tensile properties of treated fibres. The polyester composites of plantain and glass fibers were prepared using hand-layup techniques. Instron Universal testing machine-3369 model was used to determine the tensile and impact properties of fibers and polyester composites. Rockwell hardness tester-RBHT/S-39 model was used to determine the hardness property. The optimum process conditions of 5 % NaOH for 119 minutes improved plantain fiber tensile strength, modulus, strain, energy, and extension by improved by 102.03, 208.07, 9.70, 210.52 and 205.73 %, respectively. The ultimate tensile strength and modulus was obtained at 10 and 12.5% fiber loading. The hardness and impact strength of NaOH modified unsaturated polyester composites was marginally more than 3.51 and 10.69% of glass fiber reinforced unsaturated composites, respectively, at 12.5% fiber loading. FTIR analysis revealed the improvement in mechanical properties. Thus, NaOH modified plantain fiber unsaturated polyester composites serves as a better alternative for making transtibial prosthetic socket.
天然纤维在聚合物复合材料加固中的低机械性能一直是一个令人担忧的问题。本研究旨在探讨 NaOH 处理对聚酯树脂制成的经胫假肢套筒中车前草纤维机械性能的影响。车前草纤维是从车前草韧皮部使用水甑技术提取的。使用 5 - 25% 的碱性处理方法对纤维进行改性,时间从 30 分钟到 150 分钟不等。根据处理后纤维的拉伸性能,采用响应面方法的 3 级因子设计(3-LCD)对其进行优化。车前草和玻璃纤维的聚酯复合材料是用手糊技术制备的。使用 Instron 通用试验机--3369 型测定纤维和聚酯复合材料的拉伸和冲击性能。洛氏硬度计-RBHT/S-39 型用于测定硬度性能。在最佳工艺条件下,5%的 NaOH 溶剂作用 119 分钟,可使车前草纤维的拉伸强度、模量、应变、能量和延伸率分别提高 102.03%、208.07%、9.70%、210.52% 和 205.73%。纤维负载量分别为 10% 和 12.5% 时,可获得极限拉伸强度和模量。在纤维负载量为 12.5% 时,NaOH 改性不饱和聚酯复合材料的硬度和冲击强度分别略高于玻纤增强不饱和复合材料的 3.51% 和 10.69%。傅立叶变换红外分析表明,这种复合材料的机械性能得到了改善。因此,NaOH 改性车前草纤维不饱和聚酯复合材料是制作经胫假肢插座的更好替代品。
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引用次数: 0
Structural and Functional Advanced Materials 结构性和功能性先进材料
Pub Date : 2024-05-14 DOI: 10.4028/b-k2h7ue
Cecilia Poletti, J. M. Torralba
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引用次数: 0
Eggshells Utilisation in Polymer Composites 蛋壳在聚合物复合材料中的应用
Pub Date : 2024-05-14 DOI: 10.4028/p-8o3v3t
Sachin Kumar, D. Patel, Hari Om Sharma, S. Kumar
The outer covering of a hard shelled egg is known as eggshell. These are obtained from various sources like egg stations, chicken hatcheries industries and homes in different weights. It is a kind of waste which is considered not be used anywhere. It can produce hydroxyapatite which is considered most effective component of bone. This can have applications in medical supplements, bone graft substitute, floor tiles and in cements in order to improve strength but here discussion is limited to polymer composite. In composite fabrication egg shell waste is utilized, as it not only enhances the strength of composite but also provides us solution for the proper disposal waste egg shell. This review paper presents the brief insight of utilization of egg shell waste in polymer composite so as to improve its strength. From this review paper it may be concluded that research on tribological behavior of egg shell is less so it can be implemented in different sectors like metal matrix composite etc.
硬壳鸡蛋的外壳被称为蛋壳。蛋壳可以从各种渠道获得,如蛋站、鸡孵化场、工业和家庭等,重量各不相同。蛋壳是一种废物,在任何地方都不能使用。它可以产生羟基磷灰石,而羟基磷灰石被认为是骨骼中最有效的成分。羟基磷灰石可应用于医疗补充剂、骨移植替代物、地砖和水泥,以提高强度,但这里的讨论仅限于聚合物复合材料。在复合材料制造中,蛋壳废料得到了利用,因为它不仅能增强复合材料的强度,还能为我们提供妥善处理蛋壳废料的解决方案。本文简要介绍了如何在聚合物复合材料中利用蛋壳废料来提高其强度。从这篇综述论文中可以得出结论,对蛋壳摩擦学行为的研究较少,因此可以将其应用于金属基复合材料等不同领域。
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引用次数: 0
Preparation of Silane-Treated Eggshells Polyvinyl Chloride Films by Co-Precipitation: Effect of Vinyltrimethoxysilane Surface Treatment on the Tensile Properties 用共沉淀法制备硅烷处理过的蛋壳聚氯乙烯薄膜:乙烯基三甲氧基硅烷表面处理对拉伸性能的影响
Pub Date : 2024-05-14 DOI: 10.4028/p-gl3hot
D. Kiryakova, Ganka Kolchakova
Waste eggshell powders with a particle size of less than 0.315 μm were surface treated with vinyltrimethoxysilane. XRD, FT-IR, BET and SEM analyses were used to determine the surface characteristics of eggshells before and after silane treatment. The preparation of films of unplasticized suspension polyvinyl chloride with untreated and silane-treated eggshells was done by co-precipitation of solutions from cyclohexanone. The tensile properties of obtained films containing vinyltrimethoxysilane-treated eggshell powders were investigated and analyzed relative to the compositions with untreated powders.
用乙烯基三甲氧基硅烷对粒径小于 0.315 μm 的废弃蛋壳粉进行表面处理。利用 XRD、FT-IR、BET 和 SEM 分析确定了硅烷处理前后蛋壳的表面特性。用环己酮溶液共沉淀法制备了未经塑化的悬浮聚氯乙烯薄膜和经硅烷处理的蛋壳。研究和分析了含有乙烯基三甲氧基硅烷处理过的蛋壳粉末的薄膜的拉伸性能,并将其与未处理过的蛋壳粉末进行比较。
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引用次数: 0
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Key Engineering Materials
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