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Removal of Copper(Cu) from Wastewater Using Modified Recycle Carbon Black (RCB) Waste Tyre 利用改性回收炭黑 (RCB) 废轮胎去除废水中的铜 (Cu)
Pub Date : 2024-02-16 DOI: 10.4028/p-hkx3rb
Mohamad Amirul Izat Nordin, Nur Azrie Hizad Ab Aziz, U. M. Md. Ali, Anis Atikah Ahmad, M. I. Dzahir
In this century, sustainability has become an essential element in any project to ensure a safe environment. The conversion of waste materials is an important step towards achieving sustainability. Moreover, converting these materials into adsorbents to treat wastewater shows great potential, especially due to its cost-effectiveness and the reduction of solid waste disposal. This research study aims to investigate the removal of Copper (Cu) from wastewater using waste tyre-recycled carbon black (WT-rCB) and modified waste tyre-recycled carbon black (WT-dAC) to determine their adsorption capability. The removal of Copper using WT-rCB and WT-dAC were investigated with various parameters: pH value, adsorbent dosage, and contact time. The chemical-physical activation process was employed to produce the WT-dAC. First, WT-rCB was impregnated with 1:5 wt% of 1 M KOH solution, then physically activated at 650 °C for 1 hr with flowing Nitrogen gas at 1 L/min. The adsorption study observed a removal efficiency of up to 65% using WT-dAC, while WT-rCB showed a removal efficiency of 22% under the optimum conditions. Eventually, the study demonstrates the employability of WT-dAC in the removal of Copper (Cu) from wastewater.
在本世纪,可持续性已成为任何项目确保安全环境的基本要素。废料转化是实现可持续发展的重要一步。此外,将这些材料转化为吸附剂来处理废水显示出巨大的潜力,特别是由于其成本效益和减少固体废物的处置。本研究旨在调查使用废轮胎再生炭黑(WT-rCB)和改性废轮胎再生炭黑(WT-dAC)去除废水中铜(Cu)的情况,以确定它们的吸附能力。研究了使用 WT-rCB 和 WT-dAC 去除铜的不同参数:pH 值、吸附剂用量和接触时间。生产 WT-dAC 采用了化学物理活化过程。首先,用 1:5 wt% 的 1 M KOH 溶液浸渍 WT-rCB,然后在 650 °C 下以 1 L/min 的氮气流速物理活化 1 小时。吸附研究发现,在最佳条件下,WT-dAC 的去除率高达 65%,而 WT-rCB 的去除率为 22%。这项研究最终证明了 WT-dAC 在去除废水中的铜(Cu)方面的适用性。
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引用次数: 0
Effects of Cupric Ion Adsorption onto the Modified Pineapple Pulp as a Biochar Adsorbent 改性菠萝浆作为生物炭吸附剂对铜离子吸附的影响
Pub Date : 2024-02-16 DOI: 10.4028/p-obven0
P. Charnkeitkong, S. Sripiboon
The cupric ion is toxic for humans and is contained in many industrial wastewater that should be effectively removed with adsorption before discharging into the natural water source. In this study, pineapple pulp was obtained from canned pineapple juice manufacturing for drying (DPP) and carbonization (CPP) for 2 h. at 400 °C as the fine biochar adsorbents. The specific surface area of DPP and CPP were 45.3 and 60.2 m2/g, respectively. A high surface area of the carbonized pineapple pulp as a fine adsorbent was found to effectively cupric ion adsorption capacity, the maximum cupric ion removal efficiency of 83.4% and 41.9 mg/g of adsorption capacity at a pH of 6.0 was attained after 30 minutes to equilibrium reach, initial feed concentration of copper (II) sulfate 5-hydrate (CuSO4 . 5H2O) 250 ppm and temperature 50 °C. From these results can be applied to remove the cupric ion from the wastewater treatment.
铜离子对人体有毒,许多工业废水中都含有铜离子,在排入天然水源之前,应通过吸附有效地去除铜离子。在这项研究中,从罐装菠萝汁生产中获得的菠萝果肉作为精细生物炭吸附剂,分别在 400 °C 下干燥(DPP)和碳化(CPP)2 小时。DPP 和 CPP 的比表面积分别为 45.3 和 60.2 m2/g。在 pH 值为 6.0、初始进料浓度为 5- 水合硫酸铜 (CuSO4 . 5H2O) 250 ppm、温度为 50 °C 的条件下,经过 30 分钟达到平衡后,铜离子的最大去除率为 83.4%,吸附容量为 41.9 mg/g。从这些结果来看,该方法可用于去除废水中的铜离子。
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引用次数: 0
Investigation on the Effect of Blank Holder Force and Initial Blank Size on the Thinning Problem of the Fuel Tank Part Made from Aluminum Alloy Sheet 5754-O under Deep Drawing Process 坯料夹持力和初始坯料尺寸对深拉工艺下由 5754-O 铝合金板材制成的油箱部件减薄问题的影响研究
Pub Date : 2024-02-09 DOI: 10.4028/p-xx1iug
Jidapa Leelaseat, Phiraphong Larpprasoetkun, Aekkapon Sunanta, A. Nakwattanaset, S. Suranuntchai
Deep drawing process is a common sheet metal forming technique in motor vehicle manufacturing. There are three primary defects that could be occur in deep-drawn parts: tearing, wrinkling, and thinning. When the thinning is difficulty detected by visual inspection. As a result, this study aims to address the thinning issue in a fuel tank part made from an aluminum alloy sheet AA5754-O 1.5 mm thick under cold working deep drawing process, while the manufacturer's desired upper limit for thinning is 20%. Two influential parameters viz. blank holder force and initial size of blank, were investigated and optimized by using Finite Element Analysis (FEA) through PAM-STAMP simulation software with the validated material model was based on Hill’s 1948 anisotropic yield criterion with Swift hardening law. The mechanical parameters in the mentioned model were derived from the results of uniaxial tensile tests. In conclusion, both the hydraulic cushion's blank holder pressure and the initial size of the blank were found to influence the thinning of the part, either individually or in combination. Despite optimizing both parameters, they were unable to consistently achieve the desired limit.
深冲工艺是汽车制造中一种常见的钣金成型技术。深冲零件可能出现三种主要缺陷:撕裂、起皱和变薄。当减薄很难通过目视检查检测出来时,就会出现撕裂、起皱和变形。因此,本研究旨在解决在冷加工深冲工艺下,由厚度为 1.5 mm 的 AA5754-O 铝合金板材制成的油箱零件的减薄问题,而制造商要求的减薄上限为 20%。通过 PAM-STAMP 模拟软件使用有限元分析 (FEA) 对两个影响参数(即坯料夹持力和坯料初始尺寸)进行了研究和优化,验证的材料模型基于希尔 1948 各向异性屈服准则和斯威夫特硬化定律。上述模型中的机械参数来自单轴拉伸试验的结果。总之,液压垫的坯料夹持压力和坯料的初始尺寸都会单独或共同影响零件的减薄。尽管对这两个参数进行了优化,但仍无法持续达到所需的极限。
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引用次数: 0
Method for the Determination of Rational Constructional and Technological Parameters for the Processes of Powder Materials Forming 粉末材料成型工艺合理结构和技术参数的确定方法
Pub Date : 2024-02-09 DOI: 10.4028/p-n63szt
A. Mikhailov, Ye. Shtefan, O. Mikhailov, Mikhail Shtern
The main theoretical aspects of porous and powder materials technological processing is worked out. The proposed material model is based on: - the four-parameter plasticity theory, which reflect the influence of porosity, resistance and the presence of dilatancy of solid phase deformation regime; - the dissipative potential and the load surface expression, that allow to take account such materials elastic - viscous - plastic properties; - the solid phase energy deformation speed with its subsequent over the representative element volume averaging. The peculiarity of this model is that the equilibrium flow concept elastic-viscous-plastic material is an alternative to its elastic-plastic deformation. The proposed equations are suitable for their effective practical using for digital models creation that based on existent software for the of equilibrium processes of compact materials deformation finite–element analysis. The practical use of the proposed methodologies made it possible to determine: - the regularities of the different modules material layers interaction during stamping of bimetallic blanks with an conical working surface; - the porosity distribution over the product volume at the final stage of radial extrusion of the bushings with an internal flange; - the effect of powder material decompression during reverse extrusion of cylindrical products.
研究了多孔和粉末材料技术加工的主要理论方面。提出的材料模型基于:- 四参数塑性理论,反映了多孔性、阻力和固相变形机制中存在的扩张性的影响;- 耗散势能和载荷面表达式,允许考虑此类材料的弹性-粘性-塑性特性;- 固相能量变形速度及其随后的代表元素体积平均值。该模型的特点是,弹性-粘性-塑性材料的平衡流动概念可替代其弹性-塑性变形。所提出的方程适用于在现有软件的基础上建立数字模型,以有效地实际应用于紧凑材料变形平衡过程的有限元分析。通过实际使用所提出的方法,可以确定- 带锥形工作面的双金属坯料在冲压过程中不同模块材料层相互作用的规律; - 带内法兰的轴套在径向挤压的最后阶段在产品体积上的孔隙率分布; - 圆柱形产品在反向挤压过程中粉末材料减压的影响。
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引用次数: 0
Effect of Powdered Swarf on Self-Adhesive Moldings with Machining Center Extracted Bamboo Fiber 加工中心提取的竹纤维粉屑对自粘成型的影响
Pub Date : 2024-02-09 DOI: 10.4028/p-ljj4fo
Kaito Tanaka, Reo Kitazaki, T. Hirogaki, E. Aoyama, H. Nobe
To address global environmental challenges and mitigate bamboo-related ecological damage, this study focuses on the development of self-adhesive molded products utilizing solely bamboo fibers and powder obtained through machining center extraction. However, the mechanical properties of these molded products remain inadequate. This study utilizes Scanning Electron Microscope (SEM) and Fourier transform infrared spectrometer (FTIR) analyses to explore the disparities associated with chip size as raw materials for molded products. Bamboo fiber, characterized by its substantial cellulose content and high strength, is contrasted with bamboo powder, which contains significant amounts of lignin and exhibits potential adhesive properties. Building upon these findings, the powder was added to the conventional fiber alone, with results demonstrating that a predetermined ratio (20%) of the powder yields optimal mechanical properties. Moreover, employing a parameter representing the degree of lignin flow utilized in previous molding studies, the study establishes the optimum molding conditions (PD'=1.031) to maximize tensile strength (37.8 MPa) when incorporating a 20% powder mixture.
为应对全球环境挑战,减轻与竹子有关的生态破坏,本研究重点关注仅利用加工中心提取的竹纤维和竹粉开发自粘性模塑产品。然而,这些成型产品的机械性能仍然不足。本研究利用扫描电子显微镜(SEM)和傅立叶变换红外光谱仪(FTIR)分析,探讨了竹纤维作为模塑产品原材料与竹屑尺寸之间的差异。竹纤维的特点是纤维素含量高、强度大,而竹粉则含有大量木质素,具有潜在的粘合性。在这些研究成果的基础上,将竹粉单独添加到传统纤维中,结果表明竹粉的预定比例(20%)可产生最佳机械性能。此外,该研究还采用了之前成型研究中使用的代表木质素流动程度的参数,确定了最佳成型条件(PD'=1.031),以便在加入 20% 的粉末混合物时最大限度地提高拉伸强度(37.8 兆帕)。
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引用次数: 0
Features of Microstructural Evolution and Corrosion Behavior of Ti6Al4V Titanium Alloy Fabricated from Elemental Powder Blends 用元素粉末混合物制造的 Ti6Al4V 钛合金的微结构演变和腐蚀行为特征
Pub Date : 2024-02-09 DOI: 10.4028/p-gvgzk5
Serhii Lavrys, Iryna Pohrelyuk, D. Savvakin, Khrystyna Shliakhetka, M. Danyliak
Sintered Ti6Al4V titanium alloys prepared from TiH2/60Al40V powder blends under various technological conditions were studied. The microstructural evolution was investigated by X-ray diffraction, scanning electron microscopy, optical microscopy, and energy dispersive X-ray analysis. The corrosion resistance of sintered titanium alloy was evaluated by the static immersion test in 40 wt.% H2SO4 acid, according to ASTM standard G31-72(2004). Depending on powder metallurgy processing parameters (compaction pressure or sintering temperature), the Ti6Al4V alloy was obtained with various structural features (porosity and structural heterogeneity). It was shown that those structural features of sintered Ti6Al4V titanium alloy are a key microstructural factor that determines their corrosion resistance. For instance, an increase in porosity leads to enhanced corrosion resistance. Based on the current research, the optimal manufacturing regimes of powder metallurgy of Ti6Al4V titanium alloy ensure the achievement of characteristics sufficient for practical use in aggressive conditions of the chemical industry were obtained.
研究了由 TiH2/60Al40V 粉末混合物在不同工艺条件下制备的烧结 Ti6Al4V 钛合金。通过 X 射线衍射、扫描电子显微镜、光学显微镜和能量色散 X 射线分析研究了微观结构的演变。根据 ASTM 标准 G31-72(2004),通过在 40 wt.% H2SO4 酸中的静态浸泡试验评估了烧结钛合金的耐腐蚀性。根据不同的粉末冶金加工参数(压实压力或烧结温度),得到的 Ti6Al4V 合金具有不同的结构特征(孔隙率和结构异质性)。研究表明,烧结 Ti6Al4V 钛合金的这些结构特征是决定其耐腐蚀性的关键微结构因素。例如,孔隙率的增加会导致耐腐蚀性的增强。在当前研究的基础上,获得了 Ti6Al4V 钛合金粉末冶金的最佳制造机制,以确保获得足以在化学工业侵蚀性条件下实际使用的特性。
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引用次数: 0
Peculiarities Formation of Welded Joints under the External Electromagnetic Influence 外部电磁影响下焊接接头的形成特点
Pub Date : 2024-02-09 DOI: 10.4028/p-72tvpo
S. Maksimov, O. Berdnikova, Olena A. Prilipko, Tetiana Alekseenko, Yevhen Polovetskyi
Controlling the movement of liquid metal by selecting the parameters of an external electromagnetic effect makes it possible to change the conditions of dynamic equilibrium of the weld pool and, as a result, the formation of a weld. Magnetic process control has advantages over mechanical control methods, since it is carried out without contact with the welding zone. The study of processes leading to a decrease in the concentration of defects in metals, recombination of dislocations, polygonization, recrystallization, defect healing, etc., is an urgent task for technologists. The purpose of the work is to study the laws of formation of phase composition, microhardness, grain, lath, subgrain, dislocation structures of low-alloy steel welds in underwater welding and the relationship of structural parameters with the properties of strength and crack resistance of these joints. Microstructure studies were carried out by light, scanning, and transmission electron microscopy. Mathematical modelling was carried out to optimize the research efficiency. The developed computer application implements the idea of sequential calculation of quantities, where the value of the welding current and the current in the inductor is selected by the researcher. The influence of structural factors at the dislocation level on local internal stresses, which determine the deformation localization zones in the structures of the upper and lower bainites in the deposited metal, is analyzed. The conditions for obtaining high-quality welded joints in the welding of low-alloy steels, which ensure their strength and crack resistance, are established.
通过选择外部电磁效应的参数来控制液态金属的运动,可以改变焊接熔池的动态平衡条件,从而形成焊缝。与机械控制方法相比,磁性过程控制具有优势,因为它是在不接触焊接区的情况下进行的。研究导致金属缺陷浓度降低、位错重组、多边形化、再结晶、缺陷愈合等过程是技术专家的一项紧迫任务。这项工作的目的是研究低合金钢焊缝在水下焊接时的相组成、显微硬度、晶粒、板条、亚晶粒、位错结构的形成规律,以及结构参数与这些接头的强度和抗裂性能之间的关系。通过光镜、扫描电子显微镜和透射电子显微镜对微观结构进行了研究。为优化研究效率,还进行了数学建模。开发的计算机应用程序实现了数量顺序计算的理念,其中焊接电流和感应器中的电流值由研究人员选择。分析了位错层面的结构因素对局部内应力的影响,内应力决定了熔敷金属上下贝氏体结构中的变形局部区域。确定了在低合金钢焊接中获得高质量焊点的条件,以确保其强度和抗裂性。
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引用次数: 0
A Comparative Study of Lubrication Performance for Bs 080M46 Medium Carbon Steel Using Ring Compression Test and Finite Element Simulation 利用环压试验和有限元模拟对 Bs 080M46 中碳钢的润滑性能进行比较研究
Pub Date : 2024-02-09 DOI: 10.4028/p-4n5lyd
Raschanan Poungprasert, Nattarawee Siripath, S. Suranuntchai
This study investigates the impact of lubrication on friction factors during the hot ring compression test of BS 080M46 medium carbon steel. Hot forging processes are crucial in industries due to the strength and durability of forged products, but friction-related issues can arise. Four lubrication conditions are focused: dry, oil to black graphite, water to black graphite, and water to colorless graphite. The ring compression test procedure, including sample dimensions and lubrication application, is explained. By employing predictive calibration curves generated through FEM which monitored height and internal diameter changes during compression. The study successfully aligns FEM simulation results with experimental data, thereby enhancing the accuracy of friction factor estimations and visualizing material behavior under various lubrication conditions. Results indicate that lubrication significantly affects friction factors, with oil to black graphite performing the best, yielding a friction factor of 0.15. A comparison between theoretical and experimental friction factors shows varying agreement levels, with water-to-black graphite, and water-to-colorless graphite respectively demonstrating excellent alignment with 0.990% and 0.971%. This study has practical implications for selecting lubricants in industrial applications, potentially enhancing manufacturing processes and product quality.
本研究调查了 BS 080M46 中碳钢热环压缩试验过程中润滑对摩擦因素的影响。由于锻造产品的强度和耐用性,热锻工艺在工业中至关重要,但也可能出现与摩擦相关的问题。重点研究了四种润滑条件:干燥、油与黑色石墨、水与黑色石墨以及水与无色石墨。对环压测试程序进行了说明,包括样品尺寸和润滑应用。通过使用有限元生成的预测校准曲线来监测压缩过程中的高度和内径变化。该研究成功地将有限元模拟结果与实验数据进行了比对,从而提高了摩擦因数估算的准确性,并使各种润滑条件下的材料行为可视化。结果表明,润滑对摩擦因数有很大影响,其中油与黑石墨的摩擦因数为 0.15,表现最佳。理论摩擦因数与实验摩擦因数的比较显示出不同的吻合程度,水对黑石墨和水对无色石墨的吻合程度分别为 0.990% 和 0.971%。这项研究对在工业应用中选择润滑油具有实际意义,有可能改进制造工艺和产品质量。
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引用次数: 0
Peculiarities Formation of Welded Joints under the External Electromagnetic Influence 外部电磁影响下焊接接头的形成特点
Pub Date : 2024-02-09 DOI: 10.4028/p-72tvpo
S. Maksimov, O. Berdnikova, Olena A. Prilipko, Tetiana Alekseenko, Yevhen Polovetskyi
Controlling the movement of liquid metal by selecting the parameters of an external electromagnetic effect makes it possible to change the conditions of dynamic equilibrium of the weld pool and, as a result, the formation of a weld. Magnetic process control has advantages over mechanical control methods, since it is carried out without contact with the welding zone. The study of processes leading to a decrease in the concentration of defects in metals, recombination of dislocations, polygonization, recrystallization, defect healing, etc., is an urgent task for technologists. The purpose of the work is to study the laws of formation of phase composition, microhardness, grain, lath, subgrain, dislocation structures of low-alloy steel welds in underwater welding and the relationship of structural parameters with the properties of strength and crack resistance of these joints. Microstructure studies were carried out by light, scanning, and transmission electron microscopy. Mathematical modelling was carried out to optimize the research efficiency. The developed computer application implements the idea of sequential calculation of quantities, where the value of the welding current and the current in the inductor is selected by the researcher. The influence of structural factors at the dislocation level on local internal stresses, which determine the deformation localization zones in the structures of the upper and lower bainites in the deposited metal, is analyzed. The conditions for obtaining high-quality welded joints in the welding of low-alloy steels, which ensure their strength and crack resistance, are established.
通过选择外部电磁效应的参数来控制液态金属的运动,可以改变焊接熔池的动态平衡条件,从而形成焊缝。与机械控制方法相比,磁性过程控制具有优势,因为它是在不接触焊接区的情况下进行的。研究导致金属缺陷浓度降低、位错重组、多边形化、再结晶、缺陷愈合等过程是技术专家的一项紧迫任务。这项工作的目的是研究低合金钢焊缝在水下焊接时的相组成、显微硬度、晶粒、板条、亚晶粒、位错结构的形成规律,以及结构参数与这些接头的强度和抗裂性能之间的关系。通过光镜、扫描电子显微镜和透射电子显微镜对微观结构进行了研究。为优化研究效率,还进行了数学建模。开发的计算机应用程序实现了数量顺序计算的理念,其中焊接电流和感应器中的电流值由研究人员选择。分析了位错层面的结构因素对局部内应力的影响,内应力决定了熔敷金属上下贝氏体结构中的变形局部区域。确定了在低合金钢焊接中获得高质量焊点的条件,以确保其强度和抗裂性。
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引用次数: 0
Investigation on the Effect of Blank Holder Force and Initial Blank Size on the Thinning Problem of the Fuel Tank Part Made from Aluminum Alloy Sheet 5754-O under Deep Drawing Process 坯料夹持力和初始坯料尺寸对深拉工艺下由 5754-O 铝合金板材制成的油箱部件减薄问题的影响研究
Pub Date : 2024-02-09 DOI: 10.4028/p-xx1iug
Jidapa Leelaseat, Phiraphong Larpprasoetkun, Aekkapon Sunanta, A. Nakwattanaset, S. Suranuntchai
Deep drawing process is a common sheet metal forming technique in motor vehicle manufacturing. There are three primary defects that could be occur in deep-drawn parts: tearing, wrinkling, and thinning. When the thinning is difficulty detected by visual inspection. As a result, this study aims to address the thinning issue in a fuel tank part made from an aluminum alloy sheet AA5754-O 1.5 mm thick under cold working deep drawing process, while the manufacturer's desired upper limit for thinning is 20%. Two influential parameters viz. blank holder force and initial size of blank, were investigated and optimized by using Finite Element Analysis (FEA) through PAM-STAMP simulation software with the validated material model was based on Hill’s 1948 anisotropic yield criterion with Swift hardening law. The mechanical parameters in the mentioned model were derived from the results of uniaxial tensile tests. In conclusion, both the hydraulic cushion's blank holder pressure and the initial size of the blank were found to influence the thinning of the part, either individually or in combination. Despite optimizing both parameters, they were unable to consistently achieve the desired limit.
深冲工艺是汽车制造中一种常见的钣金成型技术。深冲零件可能出现三种主要缺陷:撕裂、起皱和变薄。当减薄很难通过目视检查检测出来时,深冲零件就会发生变形。因此,本研究旨在解决在冷加工深冲工艺下,由厚度为 1.5 mm 的 AA5754-O 铝合金板材制成的油箱零件的减薄问题,而制造商要求的减薄上限为 20%。通过 PAM-STAMP 模拟软件使用有限元分析 (FEA) 对两个影响参数(即坯料夹持力和坯料初始尺寸)进行了研究和优化,验证的材料模型基于希尔 1948 各向异性屈服准则和斯威夫特硬化定律。上述模型中的机械参数来自单轴拉伸试验的结果。总之,液压垫的坯料夹持压力和坯料的初始尺寸都会单独或共同影响零件的减薄。尽管对这两个参数进行了优化,但仍无法持续达到所需的极限。
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引用次数: 0
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Key Engineering Materials
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