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The Iron-Carbon System: Genesis and Morphology of the Eutectic Involving Hyper-Cementite Carbide 铁碳体系:超硬质合金共晶的成因和形态
Pub Date : 2024-02-09 DOI: 10.4028/p-ftv8w5
Vladyslav Mazur
A straightforward technology for the thermal cyclic processing of the Fe-C melt has been developed to induce significant super-cooling before crystallization. Eutectic crystallization of pro-eutectic alloys under substantial super-cooling is demonstrated to be a complex process, comprising several partial crystallization processes and the synchronous dissolution of crystalline phases: austenite and two metastable carbides, Fe3C and Fe7C3. The kinetics of the eutectic transformation L→L+Fe7C3 in its microscopic and thermal (DSC) imaging has been studied. In general, crystallization proceeds according to the scheme L→L+Fe7C3+γ→L+Fe7C3+γ+Fe3C→ Fe7C3+γ+Fe3C. Consequently, plate-like eutectic (Fe7C3+γ) with an austenite matrix and ledeburite (Fe3C+γ) with a cementite matrix are formed. A schematic diagram of the metastable phase equilibria in the Fe-C system is provided. In the conducted experiments, phase transformations occur in two subsystems: Fe-Fe3C (at low supercooling) and Fe-Fe7C3 (a subsystem of metastable equilibria of the second, higher degree of metastability at large supercooling). This is confirmed by the replacement of the carbide phase and different equilibrate concentrations of austenite in metastable equilibrium with each of the carbides.
已开发出一种对铁-碳熔体进行热循环处理的直接技术,可在结晶前引起显著的过冷。在显著过冷条件下,原共晶合金的共晶结晶是一个复杂的过程,包括几个部分结晶过程和结晶相的同步溶解:奥氏体和两种可转移碳化物(Fe3C 和 Fe7C3)。我们对 L→L+Fe7C3 共晶转变的显微和热成像(DSC)动力学进行了研究。一般来说,结晶按照 L→L+Fe7C3+γ→L+Fe7C3+γ+Fe3C→ Fe7C3+γ+Fe3C 的方案进行。因此,形成了以奥氏体为基体的板状共晶(Fe7C3+γ)和以雪明体为基体的斑晶(Fe3C+γ)。图中提供了 Fe-C 体系中蜕变相平衡的示意图。在所进行的实验中,相变发生在两个子系统中:Fe-Fe3C(在低过冷度时)和 Fe-Fe7C3(在高过冷度时的第二种较高蜕变度的蜕变平衡子系统)。碳化物相的置换以及与每种碳化物处于可转移平衡状态的奥氏体的不同平衡浓度证实了这一点。
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引用次数: 0
Experimental Bench Tests on the Corrosion Resistance and the Environmental Safety of Structural Materials of the Cooling System of Nuclear Power Plant 核电站冷却系统结构材料的耐腐蚀性和环境安全性实验台试验
Pub Date : 2024-02-09 DOI: 10.4028/p-s6mjb7
P. Kuznietsov, Olha Biedunkova
Biological pollution creates significant obstacles in the operation of power plants' technical water supply cooling systems (SCS). To minimize biological pollution, methods of corrective treatment with biocides are implemented. While these biocides effectively prevent fouling of the cooling system, they can also adversely affect the environment and structural materials. By evaluating structural materials' corrosion resistance and biocides' environmental safety for the cooling water during biocide treatment, any potential issues can be identified and addressed before they become a safety or operational concern. The paper presents the results of bench tests of the corrosion resistance of structural materials SCS, corrosion aggressiveness of the biocides: sodium hypochlorite NaClO and 2, 2-dibromo-3-nitriloropionamide (DBNPA), and the results of measurements of the concentration of biocides and their decomposition products to assess compliance with environmental standards when discharging return water when applying from biocides treatment. The cooling water SCS of the Rivne NPP (Nuclear Power Plant) was chosen as the research object. Bench corrosion tests were carried out using samples of corrosion indicators from materials: steels Ст20, 08Х18Н10Т; copper alloy МНЖ-5-1 and aluminum, which are defined as analogs of structural materials of the technical water supply system of the Rivne NPP. The conditions of operation of the technical water SCS of the Rivne NPP were simulated on the test bench, and corrosion rate measurement was carried out by the gravimetric method.
生物污染对发电厂技术供水冷却系统(SCS)的运行造成了极大的障碍。为了最大限度地减少生物污染,采用了使用杀菌剂进行纠正处理的方法。虽然这些杀菌剂能有效防止冷却系统结垢,但也会对环境和结构材料造成不利影响。在生物杀灭剂处理过程中,通过评估结构材料的耐腐蚀性和生物杀灭剂对冷却水的环境安全性,可以在任何潜在问题成为安全或运行问题之前将其识别出来并加以解决。本文介绍了结构材料 SCS 的耐腐蚀性、杀菌剂(次氯酸钠 NaClO 和 2,2-二溴-3-次氮基丙酰胺 (DBNPA))的腐蚀侵蚀性的台架试验结果,以及杀菌剂及其分解产物浓度的测量结果,以评估在应用杀菌剂处理后排放回水时是否符合环境标准。研究对象选择了罗夫诺核电站(Rivne NPP)的冷却水 SCS。使用下列材料的腐蚀指标样本进行了台架腐蚀试验:Ст20、08Х18Н10Т钢;МНЖ-5-1铜合金和铝,这些材料被定义为罗夫诺核电站技术供水系统结构材料的类似物。在试验台上模拟了罗夫诺核电站技术供水系统的运行条件,并采用重量法测量了腐蚀率。
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引用次数: 0
Advanced Materials and Metalworking 先进材料与金属加工
Pub Date : 2024-02-09 DOI: 10.4028/b-zb4err
Steven Y. Liang, Oleksandr Vasiliev
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引用次数: 0
Experimental Bench Tests on the Corrosion Resistance and the Environmental Safety of Structural Materials of the Cooling System of Nuclear Power Plant 核电站冷却系统结构材料的耐腐蚀性和环境安全性实验台试验
Pub Date : 2024-02-09 DOI: 10.4028/p-s6mjb7
P. Kuznietsov, Olha Biedunkova
Biological pollution creates significant obstacles in the operation of power plants' technical water supply cooling systems (SCS). To minimize biological pollution, methods of corrective treatment with biocides are implemented. While these biocides effectively prevent fouling of the cooling system, they can also adversely affect the environment and structural materials. By evaluating structural materials' corrosion resistance and biocides' environmental safety for the cooling water during biocide treatment, any potential issues can be identified and addressed before they become a safety or operational concern. The paper presents the results of bench tests of the corrosion resistance of structural materials SCS, corrosion aggressiveness of the biocides: sodium hypochlorite NaClO and 2, 2-dibromo-3-nitriloropionamide (DBNPA), and the results of measurements of the concentration of biocides and their decomposition products to assess compliance with environmental standards when discharging return water when applying from biocides treatment. The cooling water SCS of the Rivne NPP (Nuclear Power Plant) was chosen as the research object. Bench corrosion tests were carried out using samples of corrosion indicators from materials: steels Ст20, 08Х18Н10Т; copper alloy МНЖ-5-1 and aluminum, which are defined as analogs of structural materials of the technical water supply system of the Rivne NPP. The conditions of operation of the technical water SCS of the Rivne NPP were simulated on the test bench, and corrosion rate measurement was carried out by the gravimetric method.
生物污染对发电厂技术供水冷却系统(SCS)的运行造成了极大的障碍。为了最大限度地减少生物污染,采用了使用杀菌剂进行纠正处理的方法。虽然这些杀菌剂能有效防止冷却系统结垢,但也会对环境和结构材料造成不利影响。在生物杀灭剂处理过程中,通过评估结构材料的耐腐蚀性和生物杀灭剂对冷却水的环境安全性,可以在任何潜在问题成为安全或运行问题之前将其识别出来并加以解决。本文介绍了结构材料 SCS 的耐腐蚀性、杀菌剂(次氯酸钠 NaClO 和 2,2-二溴-3-次氮基丙酰胺 (DBNPA))的腐蚀侵蚀性的台架试验结果,以及杀菌剂及其分解产物浓度的测量结果,以评估在应用杀菌剂处理后排放回水时是否符合环境标准。研究对象选择了罗夫诺核电站(Rivne NPP)的冷却水 SCS。使用下列材料的腐蚀指标样本进行了台架腐蚀试验:Ст20、08Х18Н10Т钢;МНЖ-5-1铜合金和铝,这些材料被定义为罗夫诺核电站技术供水系统结构材料的类似物。在试验台上模拟了罗夫诺核电站技术供水系统的运行条件,并采用重量法测量了腐蚀率。
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引用次数: 0
Weldability and Joining of Dissimilar Metal Welding between Low Carbon Steel and Ferritic Stainless Steel 低碳钢和铁素体不锈钢之间异种金属焊接的可焊性和接合性
Pub Date : 2024-02-09 DOI: 10.4028/p-kgyq7t
J. Luijan, K. Eidhed, P. Surin
This paper is to study weldability and joining characteristics of dissimilar metal welding between low carbon steel and ferritic stainless steel using ER308L and ER309L filler wires. Weldability and welded joints were evaluated by microstructure analysis and bend test. It was observed that the microstructure of the fusion zone and the bend test of the welded joint were significantly affected by welding parameters and filler wire. A welded joint prepared with high heat input using the ER309L filler wire exhibited a significant delta ferrite and austenite microstructure. In contrast, when employing the ER308L filler wire with a high intensity welding current, martensite, and carbide formed at the fusion zone. The bend property was acceptable for all the specimens, and there was no evidence of solidification cracking.
本文旨在研究使用 ER308L 和 ER309L 填充焊丝对低碳钢和铁素体不锈钢进行异种金属焊接时的可焊性和连接特性。通过微观结构分析和弯曲试验对焊接性和焊接接头进行了评估。结果表明,焊接参数和填充焊丝对熔合区的微观结构和焊接接头的弯曲试验有显著影响。使用 ER309L 焊丝在高热输入下制备的焊接接头显示出明显的三角铁素体和奥氏体微观结构。相反,当使用 ER308L 焊丝和高强度焊接电流时,熔合区形成了马氏体和碳化物。所有试样的弯曲性能都是合格的,没有凝固开裂的迹象。
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引用次数: 0
Optimization and Evaluation of Mechanical and Electrochemical Properties of Ferritic Stainless Steel Welding Using Taguchi Design 利用田口设计优化和评估铁素体不锈钢焊接的机械和电化学性能
Pub Date : 2024-02-09 DOI: 10.4028/p-oqmgc5
M. F. Benlamnouar, N. Bensaid, Mohammed Oubelkacem Azzoug, T. Saadi, M. Zidani, R. Badji
The main objective of this work is to optimize welding parameters of AISI 430 FSS welds, focused to minimization of ferrite grains size using Taguchi’s design. Two input parameters of speed and welding current; were chosen to select the minimum grain size and to ascertain their effects on ferrite grain size. ANOVA method was used to evaluate the influence of varying factors on the overall quality of welds. Optimal combination of the parameters were be predicted by S/N analyses, it was accessed on employing an 80 A with 6mm/s. Experimental characterizations of optimum weld joint were performed by using tensile test assisted by image correlations, optical and electronic microscopy. As a result, welding speed had the main influence on grain size by 84.30%. Optimum welding parameter offered finest microstructure with low rate of martensite precipitates in both fusion zone and heat affected zone, and best combination of strength and ductility, it presented a homogeneous distribution of tensile stresses that caused a ductile fracture in base material. ,it is found that that optimized welding parameters permit to give greater resistance to corrosion, which exhibit a lower corrosion current, indicating that coarse ferrite grains are more susceptible to corrosion compared to fine grains.
这项工作的主要目的是优化 AISI 430 FSS 焊缝的焊接参数,重点是使用田口设计法最大限度地减小铁素体晶粒尺寸。选择速度和焊接电流这两个输入参数来选择最小晶粒尺寸,并确定它们对铁素体晶粒尺寸的影响。采用方差分析法评估了不同因素对焊缝整体质量的影响。通过信噪比分析预测了参数的最佳组合,它是在使用 80 A、6mm/s 的情况下获得的。在图像相关性、光学和电子显微镜的辅助下,通过拉伸试验对最佳焊点进行了实验表征。结果表明,焊接速度对晶粒大小的影响最大,达 84.30%。最佳焊接参数提供了最精细的微观结构,熔合区和热影响区的马氏体析出率低,强度和延展性结合得最好,拉应力分布均匀,导致母材发生韧性断裂。此外,研究还发现,优化的焊接参数可以获得更强的抗腐蚀性,表现出更低的腐蚀电流,这表明与细晶粒相比,粗铁素体晶粒更容易受到腐蚀。
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引用次数: 0
Study on the Material Models of the Forming Limit Curves Development for Predicting a Fracture Behavior of AA5754-O in Automotive Parts 用于预测汽车零件中 AA5754-O 断裂行为的成形极限曲线材料模型开发研究
Pub Date : 2024-02-09 DOI: 10.4028/p-qme3i9
Phiraphong Larpprasoetkun, Jidapa Leelaseat, A. Nakwattanaset, Aekkapon Sunanta, S. Suranuntchai
The forming limit curve (FLC) is commonly used to predict the formability behavior of sheet metal after the forming process. In this research, the forming limit curve generated from the Materials Model was applied to analyze and predict the fracture behavior of the fuel tank workpiece, a motorcycle part made of AA5754-O material, using the deep drawing process simulated by the finite element method. The research involved a comparison with actual cracks that occur in the automotive industry after molding. To determine the mechanical properties of the AA5754-O material for use in the forming limit curve, a specimen with a thickness of 1.5 mm was subjected to a tensile strength test, providing the necessary input for the mechanical properties in the forming limit curve based on the Keeler-Beizer equation. The forming limit curve is a correlation graph between major strain and minor strain. When the FLC is created from the Materials Model, it is utilized in conjunction with deep drawing drag simulation in the PAM-STAMP program to predict the fracture point. The accuracy of the mathematically generated FLC in predicting fracture behavior was verified after the deep drawing process. The study found that the FLC based on the Keeler-Beizer equation can accurately predict the cracking behavior of AA5754-O sheet metal, enabling identification of the fracture location during the deep drawing process. One advantage of creating the FLC from the material models is its compatibility with the same material but with different workpiece shapes, allowing its use in conjunction with molding simulations using various programs. This approach saves costs associated with testing to obtain the FLC.
成形极限曲线(FLC)通常用于预测金属板材在成形过程后的可成形性。在这项研究中,应用材料模型生成的成形极限曲线,分析并预测了油箱工件(一种由 AA5754-O 材料制成的摩托车零件)的断裂行为,该工件使用有限元法模拟了深拉工艺。该研究涉及与汽车行业中成型后出现的实际裂纹进行比较。为了确定 AA5754-O 材料的机械性能以用于成形极限曲线,对厚度为 1.5 毫米的试样进行了拉伸强度测试,为基于 Keeler-Beizer 方程的成形极限曲线提供了必要的机械性能输入。成形极限曲线是主要应变和次要应变之间的相关图形。从材料模型创建 FLC 后,它将与 PAM-STAMP 程序中的拉深拖拽模拟相结合,用于预测断裂点。经过拉深过程后,验证了数学生成的 FLC 在预测断裂行为方面的准确性。研究发现,基于 Keeler-Beizer 方程的 FLC 可以准确预测 AA5754-O 板材的开裂行为,从而在拉深过程中确定断裂位置。根据材料模型创建 FLC 的一个优点是,它与相同材料但不同形状的工件兼容,因此可与使用各种程序的成型模拟结合使用。这种方法节省了为获得 FLC 而进行测试的相关成本。
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引用次数: 0
Application of Origami Engineering in the Formation of Complex Spring Shapes of Thin Steel Plates via Laser Quenching Forming 折纸工程在通过激光淬火成型形成薄钢板复杂弹簧形状中的应用
Pub Date : 2024-02-09 DOI: 10.4028/p-b4vtqc
Yusuke Mima, T. Hirogaki, E. Aoyama
In this study, the controllability of the spring performance of complex sheet spring shapes was investigated to develop complex sheet spring shapes that are based on origami engineering, with the aim of integrating laser hardening formation with origami engineering. The number of forms generated during the same development was predicted from an origami engineering perspective, and two forms that agreed with the experimental results were generated. Consequently, the rigid-body origami simulation showed that the deformation behavior differs from that of the measured values, which is considered to be in accordance with elastic-body origami. Moreover, springs with arbitrary performances could be produced by varying the processing time and form.
本研究调查了复杂片状弹簧性能的可控性,以开发基于折纸工程的复杂片状弹簧,目的是将激光硬化成型与折纸工程相结合。从折纸工程学的角度预测了同一开发过程中产生的形状数量,并产生了两种与实验结果一致的形状。因此,刚体折纸模拟显示,变形行为与测量值不同,这被认为符合弹性体折纸。此外,通过改变加工时间和形式,还可以制作出具有任意性能的弹簧。
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引用次数: 0
The Role of Cell Collapse Mechanism in Mechanical Performance of Aluminium Foam Fabricated by Melt Processing 细胞塌缩机制在熔融加工制造的铝泡沫机械性能中的作用
Pub Date : 2024-02-09 DOI: 10.4028/p-03cmzt
O. Byakova, S. Gnyloskurenko, Andrey Vlasov, Yan Yevych, N. Semenov, Dmytro Kytranov
The study presents mechanical performance metrics, especially, energy absorption, of aluminium foams fabricated by melt processing with CaCO3 blowing agent without Ca additive. Relatively ductile Al1Mg0.6Si alloy and high strength Al6Zn2.3Mg alloy comprising brittle eutectic domains were employed for the foams manufacture and then examined in conditions of uniaxial quasi-static compression. It was recognized that mechanical response of the foams and energy absorption is radically defined by the mechanism of cell collapse which, in turn, depends on the nature of structural constituents of the cell wall material. In particular, the presence of brittle eutectic domains in the cell wall material of foam based on Al6Zn2.3Mg alloy results in reducing the compressive strength and energy absorption compared to those of foam processed with Al1Mg0.6Si alloy, both deviate markedly from the theoretical predictions. In spite of this experimental verification of foams cell collapse is considered to be strongly required before their engineering application.
本研究介绍了使用 CaCO3 发泡剂(不含 Ca 添加剂)熔融加工制造的铝泡沫的机械性能指标,尤其是能量吸收指标。研究采用了韧性相对较好的 Al1Mg0.6Si 合金和高强度的 Al6Zn2.3Mg 合金(包含脆性共晶畴)来制造泡沫,然后在单轴准静态压缩条件下进行了检验。人们认识到,泡沫的机械响应和能量吸收从根本上取决于细胞塌陷的机理,而细胞塌陷的机理又取决于细胞壁材料结构成分的性质。特别是,与使用 Al1Mg0.6Si 合金加工的泡沫相比,使用 Al6Zn2.3Mg 合金加工的泡沫的细胞壁材料中存在脆性共晶畴,导致抗压强度和能量吸收能力降低,两者都明显偏离理论预测。尽管如此,在工程应用之前,仍需对泡沫的细胞塌陷进行实验验证。
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引用次数: 0
Optimization and Evaluation of Mechanical and Electrochemical Properties of Ferritic Stainless Steel Welding Using Taguchi Design 利用田口设计优化和评估铁素体不锈钢焊接的机械和电化学性能
Pub Date : 2024-02-09 DOI: 10.4028/p-oqmgc5
M. F. Benlamnouar, N. Bensaid, Mohammed Oubelkacem Azzoug, T. Saadi, M. Zidani, R. Badji
The main objective of this work is to optimize welding parameters of AISI 430 FSS welds, focused to minimization of ferrite grains size using Taguchi’s design. Two input parameters of speed and welding current; were chosen to select the minimum grain size and to ascertain their effects on ferrite grain size. ANOVA method was used to evaluate the influence of varying factors on the overall quality of welds. Optimal combination of the parameters were be predicted by S/N analyses, it was accessed on employing an 80 A with 6mm/s. Experimental characterizations of optimum weld joint were performed by using tensile test assisted by image correlations, optical and electronic microscopy. As a result, welding speed had the main influence on grain size by 84.30%. Optimum welding parameter offered finest microstructure with low rate of martensite precipitates in both fusion zone and heat affected zone, and best combination of strength and ductility, it presented a homogeneous distribution of tensile stresses that caused a ductile fracture in base material. ,it is found that that optimized welding parameters permit to give greater resistance to corrosion, which exhibit a lower corrosion current, indicating that coarse ferrite grains are more susceptible to corrosion compared to fine grains.
这项工作的主要目的是优化 AISI 430 FSS 焊缝的焊接参数,重点是使用田口设计法最大限度地减小铁素体晶粒尺寸。选择速度和焊接电流这两个输入参数来选择最小晶粒尺寸,并确定它们对铁素体晶粒尺寸的影响。采用方差分析法评估了不同因素对焊缝整体质量的影响。通过信噪比分析预测了参数的最佳组合,它是在使用 80 A、6mm/s 的情况下获得的。在图像相关性、光学和电子显微镜的辅助下,通过拉伸试验对最佳焊点进行了实验表征。结果表明,焊接速度对晶粒大小的影响最大,达 84.30%。最佳焊接参数提供了最精细的微观结构,熔合区和热影响区的马氏体析出率低,强度和延展性结合得最好,拉应力分布均匀,导致母材发生韧性断裂。此外,研究还发现,优化的焊接参数可以获得更强的抗腐蚀性,表现出更低的腐蚀电流,这表明与细晶粒相比,粗铁素体晶粒更容易受到腐蚀。
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引用次数: 0
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Key Engineering Materials
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