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Removal of Antibiotics from Wastewater by Comparison of Coagulation, Membrane and Adsorption Methods 混凝法、膜法和吸附法去除废水中抗生素的比较
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.10
Saeed Safaei, Seyed Ahmad Mirbagheri, M. Ehteshami, E. Teymouri, M. Salari
In the present study, oxytetracycline (OTC) was selected as a medical contaminant with an organic structure to increase the efficiency and feasibility of comparison with other research studies. Therefore, the removal of OTC from medicinal effluents using different methods; namely, activated carbon, bentonite adsorption, iron(III) chloride coagulation, membrane filtration and reverse osmosis (RO), was investigated. Results indicated that the removal of soluble antibiotics in the factory wastewater by adsorption method was between 35% and 77%, at a pH of 6.5 and the total dissolved solids (TDS) and OTC concentration were reduced by 55% and 77%, respectively. In the coagulation method, where the suitable pH ranges from 5.5 to and 7.5, the optimal dosage of iron (III) chloride coagulation was between 40 and 100 mg/l, which resulted in 98.7% of OTC removal. It was concluded that the highest OTC adsorption of 98.7% in the RO membrane and TDS removal were obtained at a pressure of 9 bars. All the experiments on these membranes were performed within 4 months and the membranes still performed well. Therefore, it is concluded that long-term operation has little effect on the performance of the membrane and this membrane is a suitable membrane for the concentration of OTC. Finally, the RO is defined as the suitable method for OTC removal, after passing once through the membrane, while the other methods are proper to be used in the pre-treatment of medicinal wastewater. KEYWORDS: Antibiotics, Absorption, Coagulation, Membrane filtration, Reverse osmosis.
本研究选择土霉素(OTC)作为具有有机结构的医用污染物,以提高与其他研究比较的效率和可行性。因此,从医药废水中去除OTC采用不同的方法;对活性炭、膨润土吸附、氯化铁(III)混凝、膜过滤和反渗透(RO)进行了研究。结果表明,在pH为6.5的条件下,吸附法对工厂废水中可溶性抗生素的去除率为35% ~ 77%,总溶解固形物(TDS)和OTC浓度分别降低55%和77%。在适宜pH为5.5 ~ 7.5的混凝法中,氯化铁的最佳投加量为40 ~ 100 mg/l, OTC去除率为98.7%。结果表明,在9 bar压力下,反渗透膜的OTC吸附性最高,达到98.7%,TDS去除率最高。在4个月内对这些膜进行了所有实验,膜仍然具有良好的性能。因此,长期操作对膜的性能影响不大,该膜是一种适合于OTC浓度的膜。最后,将反渗透法定义为通过一次膜即可去除OTC的合适方法,而其他方法均适合用于医药废水的预处理。关键词:抗生素,吸收,凝血,膜过滤,反渗透
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引用次数: 0
Effects of Chute Block Geometry on the Performance of the USBR II Stilling Basin 槽块几何形状对USBR-II消力池性能的影响
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.12
Layla Ali Mohammed Saleh, Saleh Issa Khassaf
Stilling basins are designed to reduce the high kinetic energy of supercritical flow in a downstream spillway. The USBR II stilling basin is distinguished by chute blocks fixed at the upstream end and a dented sill at the downstream end, allowing for the effective dissipation of excess energy. This research investigates the effect of chute-block geometry on the hydraulic performance of the USBR II stilling basin. Six modified chute-blocks with identical dimensions and spacings as standard blocks were constructed and evaluated for six incoming Froude-number values. The results indicate that chute blocks containing stepped side walls are more effective than standard blocks, increasing energy dissipation by 1.47% and decreasing the sequent depth ratio by 3.91%. Blocks with gradually increased spacings lose 0.7% more energy than standard blocks and reduce the sequential depth ratio by 1.91%. However, blocks with prismatic spacings and top surface angles of 152 degrees, relative to the downstream slope of the spillway, are less effective than standard blocks with energy dissipation reduced by 2.73% and the depth ratio increased by 7.24%.
消力池的设计是为了降低下游溢洪道中超临界水流的高动能。USBR II型静水池的特点是上游端固定有溜槽块,下游端有凹陷的静水池,可以有效地消散多余的能量。研究了槽块几何形状对USBR II型消水池水力性能的影响。构建了六个与标准块具有相同尺寸和间距的改进斜槽块,并对六个传入的弗劳德值进行了评估。结果表明,带阶梯式侧壁的溜槽砌块比标准砌块更有效,能耗提高1.47%,序深比降低3.91%。间距逐渐增加的区块比标准区块损失的能量多0.7%,顺序深度比降低1.91%。而棱柱形间距、顶面角为152度的砌块相对于溢洪道下游坡面效果不如标准砌块,耗能降低2.73%,深度比提高7.24%。
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引用次数: 0
Bioremediation of Oil-contaminated Sand 含油砂的生物修复
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.05
S. Sathyapriya, R. Sharvesh, C. Natarajan
The energy demand is set to grow very rapidly and the potential demand for oil around the world is at its highest level. Apart from indigenous oil sources, crude oil is imported by water transportation to fulfill local demand. The occurrence of oil leakage during drilling and transportation in pipelines is a major concern. As a result of this, soil is getting polluted and its geotechnical properties are altered. In this study, the effect of engine oil and diesel contamination on the geotechnical parameters of sea sand has been studied. Further, to enhance the properties of oil-contaminated sand, the bioremediation method was adopted. Sea sand from Ganagalla Peta beach, Andhra Pradesh state, India was taken up for the study. In the laboratory, 4%, 8%, 12% and 16% of engine oil and diesel were used to artificially contaminate the sea sand and geotechnical parameters; namely, compaction, shear strength and permeability, were studied for oil-contaminated sand and compared with those of virgin sea sand. In the next stage, bioremediation of engine oil-and diesel-contaminated sand was carried out to improve the geotechnical properties. It has been found that the geotechnical properties had improved after three days of bioremediation. Fourier transform infrared spectroscopy (FTIR) analysis showed that the contaminated sand is of a lipopeptide nature and showed the presence of carboxyl groups, whereas the IR absorption pattern of the treated sand matches with N-Methyl-N-Vinyl Acetamide. KEYWORDS: Engine-oil contamination, Diesel contamination, Bioremediation, Bacillus subtilis, Geotechnical properties, Compaction characteristics, Shear-strength characteristics, Permeability, FTIR analysis.
能源需求将快速增长,全球对石油的潜在需求正处于最高水平。除本地石油来源外,原油通过水运进口以满足当地需求。在钻井和管道运输过程中,石油泄漏的发生一直是人们关注的焦点。因此,土壤受到污染,其岩土力学特性被改变。本文研究了发动机机油和柴油污染对海砂岩土参数的影响。为了提高油砂的性能,采用了生物修复的方法。印度安得拉邦Ganagalla Peta海滩的海砂被用于研究。在实验室中,分别使用4%、8%、12%和16%的机油和柴油对海砂和岩土参数进行人工污染;研究了含油污染砂的压实、抗剪强度和渗透性,并与原始海砂进行了比较。下一步,对机油和柴油污染砂进行生物修复,以改善其岩土性能。经过3天的生物修复,土工性能得到了改善。傅里叶变换红外光谱(FTIR)分析表明,污染砂具有脂肽性质,并存在羧基,而处理砂的红外吸收模式与n -甲基- n -乙烯基乙酰胺相匹配。关键词:机油污染,柴油污染,生物修复,枯草芽孢杆菌,岩土力学特性,压实特性,抗剪强度特性,渗透性,FTIR分析
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引用次数: 0
Economic and Time Risk Factors Influencing the Construction Projects: A Case Study of Lebanese Construction Projects 影响建设项目的经济和时间风险因素——以黎巴嫩建设项目为例
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.03
O. Ahmad, Fatemeh Nouban
In recent years, Lebanon has been grappling with a multitude of crises across all sectors, presenting numerous challenges that have hindered the progress of the construction industry. The construction industry in Lebanon is plagued by a complex array of risks that can lead to the downfall of construction projects. Therefore, this study is primarily concerned with identifying the most crucial economic and time risk factors influencing the Lebanese construction projects. To achieve the research aim, a questionnaire was initially developed from a review of various sources of literature and then refined to reflect the unique circumstances faced by Lebanon in recent years. In addition to that, some interviews to analyze the economic and time risk factors were conducted among expert respondents in the Lebanese construction industry. Then, the relative important index (RII) was applied in order to classify the major risk factors. The findings obtained from the study reveal that currency fluctuation, risk of war, geological risks, risk of pandemics and vendor failures are the most crucial risk factors that influence the time and cost of the Lebanese construction projects. Finally, in order to mitigate the occurrence of the most critical risk factors identified in this study and ensure successful construction projects in Lebanon, effective risk-management strategies should be implemented. KEYWORDS: Risk factors, Construction projects, Cost, Time, Lebanon.
近年来,黎巴嫩一直在努力应对各个部门的众多危机,这些危机带来了许多挑战,阻碍了建筑业的发展。黎巴嫩的建筑业受到一系列复杂风险的困扰,这些风险可能导致建筑项目的倒闭。因此,本研究主要关注确定影响黎巴嫩建筑项目的最关键的经济和时间风险因素。为了实现研究目标,最初根据对各种文献来源的审查编制了一份问卷,然后进行了改进,以反映黎巴嫩近年来面临的独特情况。除此之外,还对黎巴嫩建筑业的专家受访者进行了一些访谈,以分析经济和时间风险因素。然后,应用相对重要指数(RII)对主要危险因素进行分类。研究结果表明,货币波动、战争风险、地质风险、流行病风险和供应商倒闭是影响黎巴嫩建筑项目时间和成本的最关键风险因素。最后,为了减少本研究中确定的最关键风险因素的发生,并确保黎巴嫩的建筑项目取得成功,应实施有效的风险管理策略。关键词:风险因素,建设项目,成本,时间,黎巴嫩。
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引用次数: 0
Effective Use of Waste Plastic As Sand in Metakaolin/Brick-Powder Geopolymer Concrete 废塑料作砂在偏高岭土/砖粉土聚合物混凝土中的有效利用
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.09
Mahmood Fawzi Ahmed
This study proposes recycling waste clay brick and waste polyethylene terephthalate (PET) bottles as substitution materials in geopolymer concrete. To accomplish this goal, the control mix of geopolymer concrete was prepared based on blended metakaolin and waste clay brick powder (CBP) at a 1:1 mixture by weight. To evaluate the use of shredded PET particles as fine aggregate, three mixtures were made by replacing sand with PET aggregate at volumetric percentages (10%, 15% and 20%). The specimens containing PET aggregate were tested and compared against the control mix (0% PET), with emphasis on the fresh and dry densities, mechanical performance, water absorption and microstructure characteristics. The results indicated the inclusion of PET aggregate to slightly reduce density and improve mechanical properties. When compared to the control mix, the compressive strength of the 20% PET replacement increased to 28.1 MPa after 28 days. Moreover, the concrete with 20% PET obtained the lowest water-absorption rate. The scanning electron microscopy images revealed that the inclusion of waste PET as sand had a significant effect on the microstructure of Mk-CBP geopolymer concrete. When compared to the control mix, the matrix containing 20% PET had a denser microstructure, as well as fewer holes and microcracks, in addition to the packing of paste at the interfacial transition zone. KEYWORDS: Brick powder, Fine aggregate, Geopolymer concrete, Metakaolin, Polyethylene terephthalate (PET).
本研究提出回收废粘土砖和废聚对苯二甲酸乙二醇酯(PET)瓶作为地质聚合物混凝土的替代材料。为了实现这一目标,基于混合偏高岭土和废粘土砖粉末(CBP),以1:1重量的混合物制备了地质聚合物混凝土的控制混合物。为了评估切碎的PET颗粒作为细骨料的使用,通过用体积百分比(10%、15%和20%)的PET骨料代替沙子来制备三种混合物。测试含有PET骨料的试样,并将其与对照混合物(0%PET)进行比较,重点是新鲜和干燥密度、机械性能、吸水性和微观结构特征。结果表明,PET聚集体的加入略微降低了密度,改善了力学性能。与对照混合物相比,20%PET替代物的抗压强度在28天后增加到28.1MPa。此外,PET含量为20%的混凝土吸水率最低。扫描电子显微镜图像显示,废弃PET作为砂的掺入对Mk-CBP地质聚合物混凝土的微观结构有显著影响。与对照混合物相比,含有20%PET的基体除了在界面过渡区填充糊状物外,还具有更致密的微观结构以及更少的孔和微裂纹。关键词:砖粉,细骨料,土工聚合物混凝土,偏高岭土,聚对苯二甲酸乙二醇酯(PET)。
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引用次数: 0
CO2 Curing of Reactive Powder Concretes Modified by Waste Limestone Powder 废石灰石改性活性粉混凝土的CO2养护
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-10 DOI: 10.14525/jjce.v17i3.08
H. Rahmani, Nooshin Mohammadzade
Incorporating waste stone powders into the production of reactive powder concretes (RPCs) can be eco-friendly. Since high cementitious material content is used in producing RPCs, CO2, as a harmful greenhouse gas, was used for carbonation curing in this study. For this purpose, waste limestone powder was substituted by 0%, 18%, 36% and 54% of silica sand and the specimens were cured in water for up to 90 days in a CO2 chamber for up to 48 hours. The physical and mechanical properties of the concrete and the specimens' CO2 uptake were measured at different ages. Results showed that the 28-day compressive strength of the moist cured RPCs was higher than 100 MPa and the properties of the RPCs were improved by increasing limestone substitution. CO2 curing of the RPCs significantly increased the samples' compressive strength and limestone-powder substitution as silica sand significantly decreased the carbonation and autogenous shrinkages of the RPCs. Moreover, carbonation curing can make eco-friendly limestone-modified RPCs, where their properties are improved. KEYWORDS: CO2 curing, Reactive powder concrete, Waste limestone powder, Shrinkage.
将废石粉纳入活性粉末混凝土(RPC)的生产中可以是环保的。由于高胶凝材料含量用于生产RPC,因此本研究将CO2作为一种有害的温室气体用于碳酸化养护。为此,用0%、18%、36%和54%的硅砂代替废石灰石粉末,并将试样在水中在CO2室中固化长达90天长达48小时。测量了不同龄期混凝土的物理力学性能和试样的CO2吸收量。结果表明,湿固化RPC的28天抗压强度高于100MPa,并且通过增加石灰石的替代性来改善RPC的性能。RPC的CO2固化显著提高了样品的抗压强度,石灰石粉末的替代性显著降低了RPC的碳化和自收缩。此外,碳酸化固化可以制备环保的石灰石改性RPC,从而改善其性能。关键词:二氧化碳养护,活性粉末混凝土,废石灰石粉,收缩率。
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引用次数: 0
Regression Analysis for Predicting Soil Strength in Bangladesh 孟加拉国土壤强度预测的回归分析
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-08 DOI: 10.14525/jjce.v17i3.14
Shadman Rahman Sabab, H. Md. Shahin, Muftashin Muhim Bondhon, Md. Ehsan Kabir
This study focuses on establishing a robust relationship between Standard Penetration Test-N values (SPT-N), geotechnical parameters and unconfined compressive strength (qu) using regression analysis. The proposed relationship offers a reliable method for estimating qu based on SPT-N values. A comprehensive dataset comprising approximately 200 soil samples collected from various boreholes across Dhaka city was utilized. Multiple Linear Regression (MLR), Rando-forest Regression (RFR) and AdaBoost Regression techniques were employed to develop a unified correlation model. Evaluation metrics including R-squared (R2), Mean Absolute Error (MAE) and Root Mean Squared Error (RMSE), along with Trend-behavior Analysis were employed to assess and compare the performances of the models. Additionally, sensitivity analysis was carried out on the selected model in order to assess the importance of each parameter used to predict qu. Finally, the selected model was compared against the existing empirical models that were published in previous studies. In terms of evaluation metrics and Trend-behavior Analysis, the results showed that the RFR model performed better than the others. Additionally, the selected model outperformed the others, demonstrating the highest R2 score, the smallest RMSE and MAE values and lower residuals compared to the previous models. Hence, the proposed model provides accurate predictions of qu for clayey soil in Bangladesh. Its implementation could ensure more efficient geotechnical designs, specifically adjusted to the geological conditions of the Dhaka region. While previous studies have established regional equations for various parts of the world, our model uniquely has incorporated the Plasticity Index (PI) as a predictor for qu and is specifically calibrated for the geological characteristics of Dhaka city. The findings of this study highlight the effectiveness and applicability of regression analysis in predicting qu for Dhaka's soil properties, thus introducing a valuable tool for enhancing the accuracy and effectiveness of geotechnical assessments and design in the region. KEYWORDS: Unconfined compressive strength, Standard penetration test-N values, Plasticity index, Multiple linear regression, Random-forest regression, AdaBoost regression, Evaluation metrics, Trend-behavior analysis, Sensitivity analysis
本研究的重点是通过回归分析建立标准贯入试验-N值(SPT-N)、岩土参数和无侧限抗压强度(qu)之间的稳健关系。所提出的关系为基于SPT-N值估计qu提供了一种可靠的方法。使用了一个综合数据集,包括从达卡市各个钻孔采集的大约200个土壤样本。采用多元线性回归(MLR)、随机森林回归(RFR)和AdaBoost回归技术建立了统一的相关模型。评估指标包括R平方(R2)、平均绝对误差(MAE)和均方根误差(RMSE),以及趋势行为分析,用于评估和比较模型的性能。此外,还对所选模型进行了敏感性分析,以评估用于预测qu的每个参数的重要性。最后,将所选模型与先前研究中发表的现有经验模型进行了比较。在评价指标和趋势行为分析方面,结果表明RFR模型的表现优于其他模型。此外,所选模型的表现优于其他模型,与之前的模型相比,R2得分最高,RMSE和MAE值最小,残差更低。因此,所提出的模型为孟加拉国粘性土的qu提供了准确的预测。它的实施可以确保更有效的岩土工程设计,特别是根据达卡地区的地质条件进行调整。虽然之前的研究已经为世界各地建立了区域方程,但我们的模型独特地将塑性指数(PI)作为qu的预测因子,并专门针对达卡市的地质特征进行了校准。本研究的结果突出了回归分析在预测达卡土壤性质qu方面的有效性和适用性,从而为提高该地区岩土工程评估和设计的准确性和有效性提供了一个有价值的工具。关键词:无侧限抗压强度、标准贯入试验-N值、塑性指数、多元线性回归、随机森林回归、AdaBoost回归、评估指标、趋势行为分析、敏感性分析
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引用次数: 1
Identification and Assessment of Major Risks in Syrian Construction Projects: Lattakia-Syria Case 叙利亚建设项目主要风险的识别与评估:拉塔基亚-叙利亚案例
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-07-08 DOI: 10.14525/jjce.v17i3.13
Reem Ghanem Kattoub, J. Omran
The Syrian construction industry is plagued with risks that can be challenging to the overall success of any construction project. To minimize a project’s damage in terms of cost, time and quality, an authentic data-driven and expert-approved risk plan must be developed. This paper proposes a methodology to identify and assess major risks based on the personal evaluation of experienced civil engineers as a step in a comprehensive risk-management process. By combining a ranked risk magnitude index and an assigned risk zone, fifteen major risks were identified and assessed. Companies are advised to use the list to develop a resourceful general risk plan. Combining the two methods together makes the risk plan more representative and thus more reliable, as the two proposed methods can result in different rankings. The top fifteen risks in the Syrian construction industry were mainly management, financial and design risks. Locating in the zone of maximum risk came “an unprecedented increase in raw-material prices” and “the loss due to an increase in fuel prices” as number one and number two, respectively”. “Unavailability of resources” was next in the zone of high risk. “Improper cost estimation” and “losing critical work forces at a critical time” scored high in the final ranking. KEYWORDS: Risk identification, Risk assessment, Syria, Construction industry.
叙利亚建筑业风险重重,对任何建筑项目的整体成功都具有挑战性。为了最大限度地减少项目在成本、时间和质量方面的损失,必须制定一个真实的数据驱动和专家批准的风险计划。本文提出了一种基于经验丰富的土木工程师的个人评估来识别和评估重大风险的方法,作为全面风险管理过程中的一个步骤。通过将风险等级指数和指定的风险区域相结合,确定并评估了15个主要风险。建议各公司使用该列表来制定足智多谋的总体风险计划。将这两种方法结合在一起可以使风险计划更具代表性,从而更可靠,因为所提出的两种方法可能会导致不同的排名。叙利亚建筑业的前十五大风险主要是管理、财务和设计风险。位于最大风险区的是“原材料价格空前上涨”和“燃料价格上涨造成的损失”,分别排在第一和第二位。“资源不可用”是下一个高风险区域。“成本估算不当”和“在关键时刻失去关键劳动力”在最终排名中得分很高。关键词:风险识别,风险评估,叙利亚,建筑业。
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引用次数: 0
Damage Mechanism on Different Joint Types of Plain Concrete under Uniaxial Compression 不同节点类型素混凝土在单轴压缩下的损伤机理
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-04-01 DOI: 10.14525/jjce.v17i2.14
Shanshan Guo, D. Cui, Liang Lv
Excavation of tunnels or chambers causes crack initiation, propagation and coalescence, resulting in the instability and destruction of underground projects. Understanding the damage mechanism of joint rock-like materials is important for maintaining the stability of concrete construction. Based on the Mohr–Coulomb criterion and Lemaitre strain equivalence hypothesis, the coupling-damage constitutive model of rock masses was improved for application to plain concrete. Parameters including the mesoscopic and macro-meso coupling damage variables, as well as the fractal dimension, were calculated to realize the non-linear mechanical behaviour during damage evolution. The rationality of the model was verified by comparing experimental and theoretical parameters. Results revealed that the coupled-damage constitutive model of rock masses has a good applicability to plain concrete. Furthermore, two main factors affected the damage deformation: the number of joints and the inclination angle. As the number of joints increased, the early damage accumulation increased and the inflection point of the damage rate occurred in advance. The damage deformation varied significantly when the inclination angle was changed. The cumulative damage curve of the plain-concrete specimens is shown as the evolution law of an S-type curve. Both peak strength and elastic modulus were positively correlated with the damage variable. Moreover, a smaller peak strength resulted in a larger fractal dimension and coupling-damage variable. KEYWORDS: Rock mass, Joint inclination angle, Mesoscopic, Macroscopic, Fractal dimension, Coupling-damage constitutive model.
隧道或硐室的开挖引起裂缝萌生、扩展和合并,造成地下工程的失稳和破坏。了解节理类岩材料的损伤机理对维护混凝土结构的稳定性具有重要意义。基于Mohr-Coulomb准则和Lemaitre应变等效假设,改进了岩体的耦合-损伤本构模型,适用于素混凝土。计算了细观和宏观细观耦合损伤变量及分形维数,实现了损伤演化过程中的非线性力学行为。通过对比实验参数和理论参数,验证了模型的合理性。结果表明,岩体的耦合损伤本构模型对素混凝土具有较好的适用性。影响损伤变形的主要因素有两个:节理数和节理倾角。随着节理数量的增加,早期损伤积累增加,损伤速率拐点提前出现。随着倾角的变化,损伤变形变化明显。素混凝土试件的累积损伤曲线表现为s型曲线的演化规律。峰值强度和弹性模量均与损伤变量呈正相关。峰值强度越小,分形维数越大,耦合损伤变量越大。关键词:岩体,节理倾角,细观,宏观,分形维数,耦合-损伤本构模型
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引用次数: 0
Single and Ternary Removal of Heavy Metals from Aqueous Solution Using Fe3O4 Magnetic Nano-particles Fe3O4磁性纳米粒子对水溶液中重金属的一元和三元去除
IF 1.1 Q4 ENGINEERING, CIVIL Pub Date : 2023-04-01 DOI: 10.14525/jjce.v17i2.13
K. Al-Zboon
This research aims to investigate the use of magnetic iron nano-particles (FeN) for the removal of heavy metals under single and ternary scenarios. The methodology includes synthesis of FeN using chemical precipitation approach, batch experiments for single and ternary metals removal, isotherm and kinetic studies, thermos-dynamic study and assessing the effect of different parameters on the adsorption process. The results showed that the maximum removal for As and Hg was achieved at a pH of 7, while a pH of 6 provided a slightly higher removal of Cd than a pH of 7 at an optimum mixing time of 120 minutes. The optimum adsorption capacities of As, Cd and Hg at the initial concentration of 200 ppm were 260, 280 and 75.0 mg/g in the case of single metal removal against 91.5, 237.8 and 341.5 mg/g in the case of ternary combination, respectively. The removal of all metals increased with increasing the FeN dose and the mixing time, while it decreased with the increase of the initial concentration. The removal efficiency was affected strongly by the presence of multiple metals, while As removal decreased sharply and Hg removal increased significantly. Adsorption selectivity is affected negatively by the increase in atomic weight and atomic radius. In the case of single-metal removal, fitting of isotherm models can be ranked as Langmuir>Freundlich>Temkin>D-R for As and Cd and Temkin>Freundlich>D-R>Langmuir for Hg, while contradictory results were obtained in the case of ternary combination. Kinetic studies found that the adsorption follows the pseudo-second-order model with R2=0.99. For all metals, the adsorption process is highly favourable at higher temperatures and is endothermic in nature with (ΔHo) of 10.91, 23.86 and 0.163 for As, Cd and Hg, respectively. Coating of FeN with silica resulted in lower removal efficiency for all metals up to 50%. It can be concluded that FeN can be successfully used for the removal of heavy metals either through the single or ternary approach, but the single approach provides a higher performance. KEYWORDS: Nano-materials, Magnetite iron, Adsorption, Arsenic, Cadmium, Mercury, Lead.
本研究旨在研究磁性铁纳米粒子(FeN)在单一和三元情况下用于去除重金属。该方法包括使用化学沉淀法合成FeN、单金属和三元金属去除的分批实验、等温线和动力学研究、热动力学研究以及评估不同参数对吸附过程的影响。结果表明,在pH为7时对As和Hg的去除率最高,而在最佳混合时间为120分钟时,pH为6时对Cd的去除率略高于pH为7。在初始浓度为200ppm时,单一金属对As、Cd和Hg的最佳吸附量分别为260、280和75.0 mg/g,而三元组合对As、Cd和Hg的最优吸附量分别是91.5、237.8和341.5 mg/g。所有金属的去除率随着FeN剂量和混合时间的增加而增加,而随着初始浓度的增加而降低。多种金属的存在对去除效率有很大影响,而As的去除率急剧下降,Hg的去除率显著提高。吸附选择性受到原子量和原子半径增加的负面影响。在单一金属去除的情况下,对于as和Cd,等温线模型的拟合可以排序为Langmuir>Freundlich>Temkin>D-R,对于Hg,等温线模型可以排序为Temkin>Freundlich>D-R>Langmuir,而在三元组合的情况下得到了矛盾的结果。动力学研究发现,吸附遵循伪二阶模型,R2=0.99。对于所有金属,吸附过程在更高的温度下是非常有利的,并且本质上是吸热的,As、Cd和Hg的(ΔHo)分别为10.91、23.86和0.163。用二氧化硅涂覆FeN导致所有金属的去除效率降低,最高可达50%。可以得出结论,FeN可以通过单一或三元方法成功地用于去除重金属,但单一方法提供了更高的性能。关键词:纳米材料,磁铁,吸附,砷,镉,汞,铅。
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Jordan Journal of Civil Engineering
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