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Sustainable nanoadsorbents from lignocellulosic waste: A green approach to wastewater treatment 木质纤维素废弃物的可持续纳米吸附剂:废水处理的绿色途径
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-09-04 DOI: 10.1016/j.coesh.2025.100665
Parushi Nargotra , Mei-Ling Tsai , Cheng-Di Dong , Chia-Hung Kuo , Bijender Kumar Bajaj , Vishal Sharma
In the face of escalating water pollution, the development of innovative and sustainable processes for wastewater treatment has become imperative to safeguard ecosystems. The current review explores the integration of nanotechnology with lignocellulosic materials to develop cost-effective, high-performance nanoadsorbents for wastewater treatment. The nanostructured cellulose and lignin exhibit enhanced porosity, surface area, and functionalization capabilities, enabling efficient removal of environmental pollutants, including heavy metals. The advancements in using nanocellulose/nanolignin for removing water pollutants and understanding the underlying mechanisms, as well as life cycle analysis, are discussed. These bio-based nanomaterials reduce environmental impact, improve resource efficiency, and support sustainable development goals (SDGs).
面对不断升级的水污染,开发创新和可持续的废水处理工艺已成为保护生态系统的必要条件。本文综述了纳米技术与木质纤维素材料的结合,以开发具有成本效益、高性能的废水处理纳米吸附剂。纳米结构的纤维素和木质素表现出增强的孔隙度、表面积和功能化能力,能够有效地去除包括重金属在内的环境污染物。综述了纳米纤维素/纳米木质素在去除水污染物方面的研究进展,探讨了纳米纤维素/纳米木质素去除水污染物的机理,并对其生命周期进行了分析。这些生物基纳米材料减少了环境影响,提高了资源效率,并支持可持续发展目标(sdg)。
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引用次数: 0
Remediation of perfluorinated and polyfluorinated substances using biochar from contaminated soil and water ecosystems: Challenges and environmental sustainability 利用受污染土壤和水生态系统中的生物炭修复全氟和多氟物质:挑战和环境可持续性
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-10-30 DOI: 10.1016/j.coesh.2025.100686
Rakesh Kumar, Jasmeet Lamba
Prolonged contamination of soil and water ecosystems with per- and polyfluoroalkyl substances (PFAS) is reported globally due to their widespread use in various products. Hydrophobicity and strong covalent bonds in PFAS lead to interactions with surrounding media under varying environmental conditions, and PFAS exposure severely impacts human, animal, and environmental health. This opinion article presents novel insights on challenges and opportunities associated with biochar selection for PFAS remediation considering the influence of solution chemistry, batch/fixed-bed column sorption methods, pyrolysis temperature, and long-chain/short-chain length PFAS. Higher pyrolysis temperatures (>700 °C) lead to high PFAS sorption onto biochar surfaces due to pore filling, hydrophobic interactions, and electrostatic attractions. Long-chain PFAS shows higher affinity due to its strong hydrophobic nature, and π-π interactions enhance the aromaticity of biochar. Also, long-chain PFAS possess high sorption at the biochar–soil interface due to the hydrophobicity of soil; however, in situ sorption–desorption at varying soil chemistry still poses challenges to retain PFAS in soil and leads to groundwater contamination. Lastly, considering agricultural and environmental sustainability, this review concluded with challenges for PFAS removal remediation strategies, including soil washing technology and adsorption, which aim to stabilize PFAS within the soil and water matrix, ultimately hindering their bioavailability and mobility.
由于全氟烷基和多氟烷基物质在各种产品中的广泛使用,在全球范围内报告了土壤和水生态系统受到长期污染的情况。PFAS的疏水性和强共价键导致PFAS在不同的环境条件下与周围介质相互作用,PFAS暴露严重影响人类、动物和环境健康。考虑到溶液化学、间歇/固定床柱吸附方法、热解温度和PFAS长链/短链长度的影响,本文提出了与PFAS修复中生物炭选择相关的挑战和机遇的新见解。较高的热解温度(700°C)由于孔隙填充、疏水相互作用和静电吸引,导致PFAS在生物炭表面的高吸附。长链PFAS具有较强的疏水性,具有较高的亲和性,π-π相互作用增强了生物炭的芳香性。此外,由于土壤的疏水性,长链PFAS在生物炭-土壤界面具有较高的吸附性;然而,在不同土壤化学条件下的原位吸附-解吸仍然对PFAS在土壤中的保留提出了挑战,并导致地下水污染。最后,考虑到农业和环境的可持续性,本文总结了PFAS去除修复策略面临的挑战,包括土壤洗涤技术和吸附技术,旨在稳定土壤和水基质中的PFAS,最终阻碍其生物利用度和流动性。
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引用次数: 0
A review of the full-scale constructed wetlands for the treatment and management of winery wastewater 大规模人工湿地处理和管理葡萄酒废水的研究进展
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-10-28 DOI: 10.1016/j.coesh.2025.100680
Alessia Marzo , Juliano Rezende Mudadu Silva , Fabio Masi , Anacleto Rizzo , Giuseppe Luigi Cirelli
Constructed wetlands (CWs) have been demonstrated to be effective solution for treating winery wastewater (WWW). In this paper, worldwide experiences over the last 25 years of full-scale CWs for WWW treatment are gathered. In total, three CW types were identified: horizontal subsurface flow, vertical subsurface flow and hybrid CWs. The organic and hydraulic loading rate ranged between 15.74–315 gCODm−2d−1 and 13–313 mmd-1, respectively. The most common plant species were Phragmites australis, Typha spp., and Schoenoplectus tabernaemontani. In this review, treatment efficiency of CWs is presented as well as their operational challenges and opportunities.
人工湿地(CWs)已被证明是处理酒厂废水的有效解决方案。本文收集了近25年来世界范围内大规模化武治疗WWW的经验。总的来说,确定了三种连续流类型:水平地下流、垂直地下流和混合型连续流。有机和水力加载速率分别为15.74-315 gCODm−2d−1和13-313 mmd-1。最常见的植物种类为芦苇、田螺和雪蚤。本文介绍了水化液的处理效率,以及水化液在操作上面临的挑战和机遇。
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引用次数: 0
Which sources contribute more to nitrosamines and their precursors in water resources: The natural or the anthropogenic? 哪些来源对亚硝胺及其在水资源中的前体的贡献更大:自然的还是人为的?
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-08-27 DOI: 10.1016/j.coesh.2025.100664
Fan Zhou , Yuxuan Xie , Yu Wang , Xiaobin Liao , Chao Chen
This paper summarizes recent progress in identifying sources of nitrosamines (NAs) and their precursors in water resources. Natural sources include humic substances, microbial and algal metabolites, which will be exacerbated by natural disasters and extreme climate events. Anthropogenic sources include domestic wastewater, industrial wastewater and agricultural wastewater. Natural sources generally contribute a few to dozens of ng/L of precursors but provide minimal NAs, while anthropogenic sources provide a few to hundreds of ng/L of NAs and higher levels of precursors. These insights aid differentiation of natural vs. anthropogenic contributions, providing guidance for pollution control and sustainable management of water resources.
本文综述了近年来在水资源中亚硝胺及其前体来源鉴定方面的研究进展。自然来源包括腐殖质物质、微生物和藻类代谢物,自然灾害和极端气候事件会加剧这一问题。人为来源包括生活废水、工业废水和农业废水。天然来源通常提供几到几十ng/L的前体,但提供很少的NAs,而人为来源提供几到数百ng/L的NAs和更高水平的前体。这些见解有助于区分自然和人为的贡献,为污染控制和水资源的可持续管理提供指导。
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引用次数: 0
Constructed wetlands for combined sewer overflow treatment: A 30-year review, current trends and future projections 人工湿地联合污水溢流处理:30年回顾,当前趋势和未来预测
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-10-30 DOI: 10.1016/j.coesh.2025.100681
Ismael Vera-Puerto , Darja Istenič , Pascal Molle , Carmen Hernández-Crespo , Carlos A. Arias
Combined sewer overflow (CSO) discharges pose a significant challenge to urban water management. Constructed wetlands (CWs) are a promising blue-green infrastructure solution for CSO management and water quality improvement, with recognized economic, social, and environmental benefits. This review synthesizes the state-of-the-art in CSO treatment using CWs over the past 30 years and explores current trends and future projections. A bibliometric analysis of 68 papers from the Web of Science Core Collection revealed that although CWs have been applied at a full scale for CSO treatment since the 1990s, they remain an emerging research topic. Germany, France, Italy, the United Kingdom and the United States of America lead in literature production and application. However, there is a significant lack of information from the Global South (developing countries) and tropical/subtropical regions. Reports from temperate developed countries indicate good performance, with removal efficiencies above 70 % for conventional pollutants such as solids, organic matter, and nutrients (nitrogen and phosphorus). However, pathogen removal was limited. Contaminants of emerging concern such as pharmaceuticals, polycyclic aromatic hydrocarbons (PAHs), and microplastics, have also been investigated in CW-treated CSOs with divergent results. This review also discusses various aspects, including regulations, design, environmental performance, and trade-offs. While CWs demonstrate substantial potential for preventing surface water pollution, their application and associated knowledge must expand beyond developed temperate regions, mirroring the global adoption of CWs for domestic wastewater and stormwater treatment. This expansion is crucial for CWs to be considered a truly global solution for CSO treatment.
复合式污水溢流(CSO)排放对城市水管理提出了重大挑战。人工湿地(CWs)是一种很有前途的蓝绿色基础设施解决方案,用于公民社会组织的管理和水质改善,具有公认的经济、社会和环境效益。本综述综合了过去30年来使用化学武器治疗CSO的最新进展,并探讨了目前的趋势和未来的预测。对Web of Science核心合集68篇论文的文献计量分析表明,尽管自20世纪90年代以来,CWs已经全面应用于CSO治疗,但它们仍然是一个新兴的研究课题。德国、法国、意大利、英国和美国在文献生产和应用方面处于领先地位。然而,全球南方(发展中国家)和热带/亚热带地区的资料严重缺乏。来自温带发达国家的报告显示了良好的性能,对固体、有机物和营养物质(氮和磷)等常规污染物的去除效率超过70%。然而,病原菌的去除是有限的。新出现的关注污染物,如药物、多环芳烃(PAHs)和微塑料,也在化化水处理的公民社会组织中进行了研究,结果不同。本综述还讨论了各个方面,包括法规、设计、环境性能和权衡。虽然化粪池在防止地表水污染方面显示出巨大的潜力,但它们的应用和相关知识必须扩展到发达温带地区以外,反映出全球在生活废水和雨水处理中采用化粪池的情况。这一扩展对于将CWs视为CSO治疗的真正全球解决方案至关重要。
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引用次数: 0
Arsenic removal in constructed wetlands 人工湿地除砷研究
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-09-24 DOI: 10.1016/j.coesh.2025.100673
Katherine Lizama-Allende, Diego Bravo-Riquelme
Constructed wetlands are a promising arsenic removal technology. Laboratory-scale experiments have proved their arsenic removal capacity and identified the main factors affecting it. However, very few pilot and full-scale systems are reported. Most of the recent studies report on laboratory-scale systems operated during short periods, therefore lifespan, seasonal effects, and the long-term effects of vegetation cannot be evaluated. Recent work on mechanistic models could guide the development of design guidelines, which are not currently available. Confirming laboratory-scale results in pilot and full-scale systems remains a challenge, as well as the use of their data for future calibration and validation of models.
人工湿地是一种很有前途的除砷技术。实验室规模的实验证明了其除砷能力,并确定了影响其除砷能力的主要因素。然而,很少有试点和全尺寸系统的报道。最近的大多数研究报告的是实验室规模的系统在短时间内运行,因此无法评估植被的寿命、季节效应和长期效应。最近在机械模型上的工作可以指导设计指南的发展,这是目前还没有的。在中试和全尺寸系统中确认实验室规模的结果仍然是一个挑战,以及使用他们的数据进行未来的模型校准和验证。
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引用次数: 0
Nitrogen removal in constructed wetlands 人工湿地的氮去除
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-09-12 DOI: 10.1016/j.coesh.2025.100668
Jan Vymazal
The most important processes responsible for nitrogen removal in constructed wetlands (CWs) are nitrification and denitrification. These processes were well-described in the second part of the 19th century and are still valid. During the recent years, other processes responsible for nitrogen removal in CWs have been identified, namely anaerobic ammonia oxidation (Anammox), anaerobic ammonia-oxidation-coupled-to-dissimilatory ferric iron reduction (Feammox) and autotrophic denitrification. Also, bacteria that can perform complete oxidation of ammonia to nitrate (Comammox) have been discovered. This review is mostly aimed at these newly discovered processes in relation to wastewater treatment in CWs.
人工湿地中最重要的脱氮过程是硝化和反硝化。这些过程在19世纪下半叶得到了很好的描述,现在仍然有效。近年来,人们还发现了其他一些处理生化水脱氮的方法,如厌氧氨氧化(Anammox)、厌氧氨氧化-偶联异化铁还原(Feammox)和自养反硝化。此外,还发现了可以将氨完全氧化为硝酸盐的细菌(Comammox)。本文主要针对这些新发现的与化粪池废水处理有关的工艺进行综述。
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引用次数: 0
Applying effect-based methods to evaluate the mixture effects of disinfection by-products and other chemicals in disinfected water 应用基于效果的方法评价消毒副产物与其他化学物质在消毒液中的混合效果
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-10-11 DOI: 10.1016/j.coesh.2025.100678
Peta A. Neale , Beate I. Escher , Frederic D.L. Leusch
Effect-based methods (EBM) are increasingly used to assess disinfected water quality as they can detect the mixture effects of all bioactive chemicals, including disinfection by-products (DBPs). In this review, we discuss the application of EBM to extracts of disinfected water, with bioassays for cytotoxicity, genotoxicity and oxidative stress response being the most responsive to DBPs. The contribution of known DBPs to the mixture effect can be predicted from single DBPs’ effects using established mixture models. Regulated DBPs typically have a minor contribution to the observed effect. Effect-based trigger values can be used to determine if the treated water quality is acceptable.
基于效果的方法(EBM)越来越多地用于评估消毒水质,因为它们可以检测所有生物活性化学物质的混合效应,包括消毒副产物(DBPs)。在这篇综述中,我们讨论了EBM在消毒水提取物中的应用,其中dbp对细胞毒性、遗传毒性和氧化应激反应最敏感。已知dbp对混合效应的贡献可以利用已建立的混合模型从单个dbp的效应中预测出来。受调节的舒张压通常对观察到的效果贡献不大。基于效应的触发值可用于确定处理后的水质是否可接受。
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引用次数: 0
Disinfection byproducts in low-income communities 低收入社区的消毒副产品
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-12-01 Epub Date: 2025-11-01 DOI: 10.1016/j.coesh.2025.100683
Kirin Emlet Furst , Daniel Worthington Smith
Over one billion people gained access to disinfected drinking water in the last 25 years, which is a major public health achievement. However, this inadvertently expanded the population exposed to disinfection byproducts (DBPs). Conditions in low-income communities can exacerbate DBP formation but research is critically limited by 1) focus on trihalomethanes over likely toxicity drivers, 2) overabundance of case studies, 3) lack of epidemiologic studies in relevant communities, and 4) overemphasis on novel treatment technologies. Future research should prioritize the roles of institutional and individual behavior in DBP exposure and mitigation, and incorporating DBPs into global burden of waterborne disease calculations.
在过去25年中,超过10亿人获得了消毒饮用水,这是一项重大的公共卫生成就。然而,这无意中扩大了暴露于消毒副产物(DBPs)的人口。低收入社区的条件可能加剧DBP的形成,但研究受到以下因素的严重限制:1)关注三卤甲烷而不是可能的毒性驱动因素,2)案例研究过多,3)缺乏相关社区的流行病学研究,以及4)过度强调新的治疗技术。未来的研究应优先考虑机构和个人行为在DBP暴露和缓解中的作用,并将DBP纳入全球水传播疾病负担的计算中。
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引用次数: 0
Greenhouse gas emissions from municipal wastewater treatment: Global insights and Vietnam's approach 城市污水处理的温室气体排放:全球视角和越南的做法
IF 6.6 Q1 ENVIRONMENTAL SCIENCES Pub Date : 2025-10-01 Epub Date: 2025-08-13 DOI: 10.1016/j.coesh.2025.100655
Le Thi Lan Anh, Tran Le Luu
Greenhouse gas (GHG) emissions from wastewater treatment plants (WWTPs), including carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O), are significant contributors to global climate change. This study addresses the lack of data in Vietnam's fragmented and under-monitored wastewater systems by integrating field measurements, dynamic modeling, and life cycle assessment (LCA) to quantify GHG emissions from 29 centralized plants and multiple decentralized systems. The results indicate that CH4 and N2O emissions amount to 378 and 79.7 million tons of CO2-equivalent annually, with local emission factors significantly exceeding the IPCC Tier 1 defaults. Methane is primarily produced from anaerobic sludge digestion and septic tanks, while N2O arises from nitrogen removal processes under low dissolved oxygen (DO) conditions. Indirect CO2 emissions from electricity and fuel consumption contribute an additional 17 % to the sector's GHG footprint. Technologies such as Johkasou, Anammox, and biogas recovery demonstrate strong mitigation potential, with Johkasou reducing emissions by approximately 16 % and Anammox lowering N2O outputs. Additional solutions including photovoltaic (PV) systems, machine learning-based process optimization, and microbial fuel cells (MFCs) offer promising pathways for operational efficiency and long-term sustainability. These findings provide critical inputs for Vietnam's carbon market implementation and align with global efforts to improve the accuracy of GHG accounting in wastewater systems.
废水处理厂(WWTPs)排放的温室气体(GHG),包括二氧化碳(CO2)、甲烷(CH4)和氧化亚氮(N2O),是全球气候变化的重要贡献者。本研究通过整合现场测量、动态建模和生命周期评估(LCA)来量化29个集中式工厂和多个分散式系统的温室气体排放,解决了越南零散和监测不足的废水系统数据缺乏的问题。结果表明:年CH4和N2O排放量分别为3.78和7970万吨co2当量,当地排放因子显著超过IPCC一级违约值。甲烷主要由厌氧污泥消化和化粪池产生,而N2O则由低溶解氧(DO)条件下的脱氮过程产生。电力和燃料消耗产生的间接二氧化碳排放量占该行业温室气体足迹的17%。Johkasou、厌氧氨氧化和沼气回收等技术显示出强大的缓解潜力,Johkasou可减少约16%的排放量,而厌氧氨氧化可降低N2O的产量。其他解决方案包括光伏(PV)系统、基于机器学习的流程优化和微生物燃料电池(mfc),为提高运营效率和长期可持续性提供了有希望的途径。这些发现为越南的碳市场实施提供了重要的投入,并与全球提高废水系统温室气体核算准确性的努力保持一致。
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引用次数: 0
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Current Opinion in Environmental Science and Health
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