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Atomic layer deposition in the design of functional materials for sensing/removing toxic gases 原子层沉积在传感/去除有毒气体功能材料设计中的应用
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-13 DOI: 10.1016/j.coesh.2023.100517
Qingmin Hu , Jiaqiang Xu , Dengsong Zhang , Shuhui Sun , Gaixia Zhang

Toxic gases including volatile organic compounds (VOCs), industrial inorganic gases (H2S, NOx, SOx, etc.) and pesticides show great harm to the environment and high risk to human health. Effective nanomaterials play a key role in real-time sensitive identification of the concentration of toxic gases and removing the toxic gases. Atomic layer deposition has emerged as a powerful and precise technique to design effective nanomaterials for sensing and removing toxic gases. Therefore, in this review, we first present the sensing mechanism and removing mechanism of nanomaterials to understand the structure–performance relationship. Then, we review the application of state-of-the-art ALD in the design and fabrication of high sensing and removing materials in recent years. Finally, we provide perspectives and opportunities about the design of effective materials and directions of ALD for sensing/removing toxic gases in the future.

挥发性有机化合物(VOCs)、工业无机气体(H2S、NOx、SOx等)和农药等有毒气体对环境危害极大,对人体健康危害很大。有效的纳米材料在实时灵敏识别有毒气体浓度和清除有毒气体方面发挥着关键作用。原子层沉积已经成为一种强大而精确的技术,用于设计有效的纳米材料来传感和去除有毒气体。因此,在本文中,我们首先介绍了纳米材料的传感机制和去除机制,以了解其结构-性能关系。然后,我们回顾了近年来最先进的ALD在高传感和去除材料的设计和制造中的应用。最后,我们对未来ALD传感/去除有毒气体的有效材料设计和方向提出了展望和机会。
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引用次数: 0
Current research on gaseous ammonia detecting and capture technologies 气氨检测与捕获技术研究现状
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-04 DOI: 10.1016/j.coesh.2023.100515
Aamer Akhand , Xiao-Yu Wu

Ammonia is currently widely used for fertilizers, and it continues to grow as a potential green fuel source or hydrogen carrier which may result in growing ammonia emissions. Increasing anthropogenic ammonia emissions raises concerns such as disrupting the global nitrogen cycle and negating greenhouse gas reduction. This review article outlines and compiles recent studies on gaseous ammonia detecting and absorption/adsorption, which could alert or reduce rogue emissions, i.e., unintended releases of ammonia. Different sensors and their characteristics are outlined with a focus on the more popular chemoresistive technologies. Several absorption/adsorption methods for ammonia capture using metal-organic frameworks (MOFs) and deep eutectic solvents (DESs) are described and certain research highlighted.

氨目前被广泛用于化肥,它作为一种潜在的绿色燃料来源或氢载体继续增长,这可能导致氨排放量的增加。不断增加的人为氨排放引发了诸如破坏全球氮循环和抵消温室气体减排等担忧。这篇综述文章概述和汇编了最近关于气体氨检测和吸收/吸附的研究,这些研究可以警告或减少流氓排放,即氨的意外释放。概述了不同的传感器及其特性,重点介绍了比较流行的化学电阻技术。介绍了几种利用金属有机骨架(MOFs)和深度共晶溶剂(DESs)进行氨捕获的吸收/吸附方法,并重点介绍了一些研究成果。
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引用次数: 0
Evaluating treatment solutions: Critical review on technologies employed for microplastic removal from water matrices 评价处理方案:从水基质中去除微塑料的关键技术综述
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-04 DOI: 10.1016/j.coesh.2023.100516
Almeenu Rasheed , Neha Sharma , Rao Y. Surampalli , Sovik Das

The emerging environmental concerns and the subsequent surge in microplastic (MP) research can be linked to their extensive presence and the subsequent adverse impact on the ecosystem, necessitating the identification of efficacious, environmentally conscious and economically feasible MP mitigating technologies. In this veneration, different technological approaches are compared based on removal efficiencies, environmental impacts and economic feasibility. Critical comparison of existing technologies by using life cycle assessment, techno-economic and strength-weakness-opportunity-threat analysis showed that the chemical methods exhibit better removal efficiencies, whereas the hybrid methods exhibited better environmental and economic feasibility. The secondary pollution caused by the existing physical and biological treatment methods is also highlighted along with the focus on the need for further research in developing sustainable and efficient MP removal technology.

新出现的环境问题和随后的微塑料(MP)研究激增可能与它们的广泛存在及其对生态系统的不利影响有关,因此有必要确定有效、环保和经济上可行的MP缓解技术。在此基础上,根据去除效率、环境影响和经济可行性对不同的技术方法进行了比较。通过生命周期评价、技术经济和优势-劣势-机会-威胁分析对现有技术进行了关键性比较,结果表明化学方法具有更好的去除效率,而混合方法具有更好的环境和经济可行性。强调了现有物理和生物处理方法造成的二次污染,并强调需要进一步研究开发可持续和高效的MP去除技术。
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引用次数: 0
Linking hydrological connectivity to sustainable watershed management in the Loess Plateau of China 将水文连通性与黄土高原流域可持续管理联系起来
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100493
Yang Yu , Juanlong Feng , Hu Liu , Chuandong Wu , Jianjun Zhang , Zhengze Wang , Chan Liu , Jiongchang Zhao , Jesús Rodrigo-Comino

Water shortages in arid and semi-arid ecosystems can cause changes to the structures and functions of landscapes and respective ecosystem services. A useful framework for understanding the effects of land use changes at the watershed scale and, therefore, allowing us to provide efficient management strategies to decision-makers is hydrological connectivity. In the context of sustainable development, the implementation of vegetation and engineering strategies for watershed management is crucial, particularly in the Loess Plateau region of China. Here, we briefly review the application of hydrological connectivity in integrated watershed management, specifically applied to the Chinese ones. A case study is presented to put forward a potential way to optimize the current environmental patterns with connectivity situations. Our proposal posits that hydrological connectivity can serve as a nature-based solution to meet the growing need for scientifically informed integrated watershed management in water-scarce ecosystems, particularly in light of the escalating effects of climate change.

干旱和半干旱生态系统缺水可能导致景观结构和功能以及各自的生态系统服务发生变化。水文连通性是一个有用的框架,可以理解流域范围内土地利用变化的影响,从而使我们能够为决策者提供有效的管理策略。在可持续发展的背景下,实施植被和流域管理工程战略至关重要,尤其是在中国黄土高原地区。在此,我们简要回顾了水文连通性在流域综合管理中的应用,特别是在中国的应用。通过一个案例研究,提出了一种在连通性情况下优化当前环境模式的潜在方法。我们的提案认为,水文连通性可以作为一种基于自然的解决方案,以满足缺水生态系统对科学知情的综合流域管理日益增长的需求,特别是在气候变化影响不断升级的情况下。
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引用次数: 3
Reducing pollution to levels not harming biodiversity and ecosystem functions: A perspective on the post-2020 Global Biodiversity Framework 将污染降至不损害生物多样性和生态系统功能的水平:2020年后全球生物多样性框架展望
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100495
Alexander Feckler , Jakob Wolfram , Ralf Schulz , Mirco Bundschuh

Currently, there are more than 350,000 chemicals in use, while their ecological effects are not fully understood. In this review, we focus on pesticides, pharmaceuticals, and personal care products and discuss their potential impact on aquatic biodiversity and ecosystem functions. We critically reflect on strategies to reduce their environmental release and mitigate potential effects. Various mitigation strategies are available to reduce contaminant concentrations in surface waters, but their efficiency varies under the current procedures. Intervening at the start of chemicals' life cycles or reducing their diversity and production amounts holds promise for reducing surface water exposure. This approach could facilitate appropriate environmental risk assessments for each authorized chemical.

目前,有超过350000种化学品在使用,但其生态影响尚未完全了解。在这篇综述中,我们关注农药、药品和个人护理产品,并讨论它们对水生生物多样性和生态系统功能的潜在影响。我们认真思考减少其环境释放和减轻潜在影响的战略。有各种缓解策略可用于降低地表水中的污染物浓度,但在当前程序下,其效率各不相同。在化学品生命周期开始时进行干预或减少其多样性和产量有望减少地表水暴露。这种方法可以促进对每种经批准的化学品进行适当的环境风险评估。
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引用次数: 2
Mitochondrial biomarkers for airborne particulate matter–associated cardiovascular diseases 空气中颗粒物相关心血管疾病的线粒体生物标志物
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100494
Pradyumna Kumar Mishra, Prasan Kaur

Airborne particulate matter pollution has become a significant global health concern due to its detrimental effects on human health, including cardiovascular diseases (CVDs). Mitochondrial epigenetics hold enormous potential for developing biomarkers that discern the effects of air pollution–associated CVDs risk and emergence. A reliable approach to characterize mtDNA is essential as omics-based tools to profile cell-free circulating mtDNA copy number, heteroplasmic mutations, and methylation. Investigating regulatory mechanisms for methylated mtDNA in CVDs patients requires unique molecular epidemiological insights. With a focus on the negative effects of PM exposure on mitochondrial dynamics, protein expression, and metabolomic profiles that underlie the molecular mechanisms, this article aims to provide an in-depth assessment of the current knowledge on mitochondrial biomarkers as potential indicators of PM-associated CVDs. Furthermore, we examine the potential of cell-free circulating mtDNA and cellular entities detected in circulation as a predictive biomarker to mitigate the more severe effects of ambient air pollution on cardiovascular disorders.

空气中的颗粒物污染因其对包括心血管疾病在内的人类健康的有害影响,已成为全球关注的重大健康问题。线粒体表观遗传学在开发识别空气污染影响的生物标志物方面具有巨大潜力,这些影响与心血管疾病的风险和出现有关。作为基于组学的工具来分析无细胞循环mtDNA拷贝数、异源突变和甲基化,表征mtDNA的可靠方法至关重要。研究CVDs患者甲基化mtDNA的调控机制需要独特的分子流行病学见解。本文的重点是PM暴露对线粒体动力学、蛋白质表达和代谢组学特征的负面影响,这些都是分子机制的基础,旨在深入评估线粒体生物标志物作为PM相关心血管疾病潜在指标的现有知识。此外,我们研究了循环中检测到的无细胞循环mtDNA和细胞实体作为预测生物标志物的潜力,以减轻环境空气污染对心血管疾病的更严重影响。
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引用次数: 2
Emerging nanomaterials in the detection and degradation of air pollutants 检测和降解空气污染物的新兴纳米材料
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100497
Samriti , Marina Rumyantseva , Shuhui Sun , Andrej Kuznetsov , Jai Prakash

Air pollution implies significant threats for the human health and the surrounding environment. In recent years, a great deal of research has been carried out on the detection and removal of air pollutants through the development of novel multifunctional nanomaterials. In this paper, such emerging nanomaterials (e.g. metal oxide, metal–organic framework, graphene, MXenes, quantum dots, plasmonic, etc. based nanostructures) with high stability, sensitivity down to parts-per-billion level and excellent removal efficiency for air pollutants have been discussed. The focus is on specific strategies and recent highlights of the development of emerging nanomaterials for environmental and health monitoring. Furthermore, the challenges and future prospects are discussed.

空气污染意味着对人类健康和周围环境的重大威胁。近年来,通过开发新型多功能纳米材料,对空气污染物的检测和去除进行了大量研究。本文讨论了这些新兴的纳米材料(如金属氧化物、金属-有机框架、石墨烯、MXenes、量子点、等离子体等纳米结构),它们具有高稳定性、低至十亿分之一的灵敏度和优异的空气污染物去除效率。重点是开发用于环境和健康监测的新兴纳米材料的具体战略和最新亮点。此外,还讨论了挑战和未来前景。
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引用次数: 1
Editorial overview: Emerging contaminants in soil 编辑综述:土壤中新出现的污染物
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100505
Fang Wang
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引用次数: 0
Recent progress in photocatalysts for oxidation of As(III) and photocatalyst-impregnated adsorbents for removing aqueous arsenic As(III)氧化光催化剂及含砷吸附剂的研究进展
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100498
Keisuke Kuroda , Bing Lu , Yuna Hama , Yu Yang

Arsenic (As) in drinking water remains a major challenge to public health globally. Since aqueous As is often present as As(III), oxidation of As(III) to As(V) by photocatalysis is an efficient and low-cost treatment method for As removal from water, as As(V) is readily removed by adsorption. Novel photocatalysts such as C/TiO2@Fe3O4, WO3/TiO2, Fe/TiO2, Bi2.15WO6, and g-C3N4 can efficiently (100% or close) oxidize As(III) in 6–150 min under UV irradiation, and in 12–180 min under visual light irradiation. Furthermore, impregnating nanoscale photocatalysts into adsorbents such as metal oxides (e.g., Fe2O3, Fe3O4), activated carbon, and chitosan enables both As(III) oxidation and adsorption of the resulting As(V) in up to 90 min by using these integrated materials, which can be separated from water by sedimentation or magnetism. These novel technologies provide economically feasible and environmentally friendly options for As abatement, particularly in decentralized water systems in developing communities.

饮用水中的砷仍然是全球公众健康面临的一大挑战。由于水性As通常以As(III)的形式存在,因此通过光催化将As(III。新型光催化剂,如C/TiO2@Fe3O4、WO3/TiO2、Fe/TiO2、Bi2.15WO6和g-C3N4在紫外线照射下可在6–150分钟内有效(100%或接近)氧化As(III),在可见光照射下可有效(12–180分钟)氧化As。此外,将纳米级光催化剂浸渍到吸附剂中,如金属氧化物(如Fe2O3、Fe3O4)、活性炭和壳聚糖,通过使用这些集成材料,可以在长达90分钟内氧化和吸附as(III),这些集成材料可以通过沉淀或磁性与水分离。这些新技术为减少砷提供了经济可行和环境友好的选择,特别是在发展中社区的分散供水系统中。
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引用次数: 0
Review on the removal of Arsenic in groundwater using laterite adsorbent 红土吸附剂去除地下水中砷的研究进展
Q1 ENVIRONMENTAL SCIENCES Pub Date : 2023-10-01 DOI: 10.1016/j.coesh.2023.100496
Vien Vinh Phat, Tran Le Luu

Contaminated removal in groundwater by adsorption studies on red earth material or laterite concrete is one of the cost-effective method in recent days. The objective of this study is to discuss the using of laterite in its natural or modified forms for removing arsenic from contaminated groundwater and its effects on key removal process variables like adsorbent dosage, pH, …It has advantages in cost, and popularity of laterite in some regions. Natural laterite materials could be treated in arsenic-contaminated groundwater with an efficacy of nearly 90%. Moreover, these materials may be chemically modified which enhanced the adsorption efficiency better than the raw ones 40 times in some situations and the removal efficacy is nearly 99% which passed the WHO safe limit standard for arsenic-contaminated groundwater (<10 μg L−1). In addition, they can be also reused after the desorption process. Also, the research using available and easy access in developing regions requires less capital investment and has a smaller environmental impact.

通过对红土材料或红土混凝土的吸附研究来去除地下水中的污染是近年来成本效益高的方法之一。本研究的目的是讨论天然或改良形式的红土用于去除污染地下水中的砷,以及其对吸附剂用量、pH值等关键去除过程变量的影响。红土在成本和某些地区的受欢迎程度方面具有优势。天然红土材料可以在砷污染的地下水中进行处理,处理效果接近90%。此外,这些材料可以进行化学改性,在某些情况下比原材料提高了40倍的吸附效率,去除效率接近99%,通过了世界卫生组织砷污染地下水安全限值标准(<10μg L−1)。此外,它们也可以在解吸过程之后重复使用。此外,在发展中地区利用现有和方便的途径进行的研究需要较少的资本投资,对环境的影响较小。
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引用次数: 0
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Current Opinion in Environmental Science and Health
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