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Comparative study on the flame retardancy of CO2 and N2 during coal adiabatic oxidation process 煤绝热氧化过程中CO2和N2的阻燃性比较研究
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-25 DOI: 10.1007/s40789-023-00652-y
Xiyang Fang, Bo Tan, Haiyan Wang

To test the effectiveness of N2 and CO2 in preventing coal from spontaneously combusting, researchers used an adiabatic oxidation apparatus to conduct an experiment with different temperature starting points. Non-adsorbed helium (He) was used as a reference gas, and coal and oxygen concentration temperature variations were analyzed after inerting. The results showed that He had the best cooling effect, N2 was second, and CO2 was the worst. At 70℃ and 110℃, the impact of different gases on reducing oxygen concentration and the cooling effect was the same. However, at the starting temperature of 150℃, CO2 was less effective in lowering oxygen concentration at the later stage than He and N2. N2 and CO2 can prolong the flame retardation time of inert gas and reduce oxygen displacement with an initial temperature increase. When the starting temperature is the same, N2 injection cools coal samples and replaces oxygen more effectively than CO2 injection. The flame retardancy of inert gas is the combined result of the cooling effect of inert gas and the replacement of oxygen. These findings are essential for using inert flame retardant technology in the goaf.

为了测试N2和CO2阻止煤自燃的有效性,研究人员使用绝热氧化装置进行了不同温度起点的实验。以未吸附的氦(He)为参比气体,分析惰化后煤和氧浓度温度的变化。结果表明,He的冷却效果最好,N2次之,CO2最差。在70℃和110℃时,不同气体对氧的还原浓度和冷却效果的影响是相同的。但在起始温度为150℃时,CO2对后期氧浓度的降低效果不如He和N2。N2和CO2可以延长惰性气体的阻燃时间,并随着初始温度的升高而减少氧的置换。在起始温度相同的情况下,注入N2比注入CO2更能有效地冷却煤样并替代氧气。惰性气体的阻燃性是惰性气体的冷却作用和氧气的替代作用共同作用的结果。这些发现对于在采空区应用惰性阻燃技术具有重要意义。
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引用次数: 0
Water–rock two-phase flow model for water inrush and instability of fault rocks during mine tunnelling 矿井掘进中断层岩突水失稳的水-岩两相流模型
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-20 DOI: 10.1007/s40789-023-00612-6
Dan Ma, Hongyu Duan, Qiang Li, Jiangyu Wu, Wen Zhong, Zhen Huang

Water inrush hazard is one of the major threats in mining tunnel construction. Rock particle migration in the seepage process is the main cause of water inrush pathway and rock instability. In this paper, a radial water–rock mixture flow model is established to study the evolution laws of water inrush and rock instability. The reliability of the proposed model is verified by the experimental data from a previous study. Through the mixture flow model, temporal-spatial evolution laws of different hydraulic and mechanical properties are analysed. And the proposed model’s applicability and limitations are discussed by comparing it with the existing water inrush model. The result shows that this model has high accuracy both in temporal evolution and spatial distribution. The accuracy of the model is related to the fluctuation caused by particle migration and the deviation of the set value. During the seepage, the porosity, permeability, volume discharge rate and volume concentration of the fluidized particle increase rapidly due to the particle migration, and this phenomenon is significant near the fluid outlet. As the seepage progresses, the volume concentration at the outlet decreases rapidly after reaching the peak, which leads to a decrease in the growth rate of permeability and porosity, and finally a stable seepage state can be maintained. In addition, the pore pressure is not fixed during radial particle migration and decreases with particle migration. Under the effect of particle migration, the downward radial displacement and decrease in effective radial stress are observed. In addition, both cohesion and shear stress of the rock material decreased, and the rock instability eventually occurred at the outlet.

突水灾害是矿山隧道施工的主要威胁之一。岩石颗粒在渗流过程中的运移是造成突水通道和岩石失稳的主要原因。本文建立了径向水岩混合流动模型,研究了突水和岩石失稳的演化规律。通过前人的实验数据验证了该模型的可靠性。通过混合流动模型,分析了不同水力力学性能的时空演化规律。并通过与现有突水模型的比较,讨论了该模型的适用性和局限性。结果表明,该模型在时间演化和空间分布上都具有较高的精度。模型的精度与粒子迁移引起的波动和设定值的偏差有关。在渗流过程中,由于颗粒的迁移,流化颗粒的孔隙度、渗透率、体积排出率和体积浓度迅速增大,且在流体出口附近这一现象较为明显。随着渗流的进行,出口处的体积浓度在达到峰值后迅速下降,导致渗透率和孔隙度的增长率下降,最终保持稳定的渗流状态。此外,孔隙压力在颗粒径向迁移过程中并不固定,而是随着颗粒的迁移而减小。在颗粒迁移的作用下,径向位移向下,有效径向应力减小。此外,岩石材料的黏聚力和剪应力均降低,最终在出口发生岩石失稳。
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引用次数: 0
Elimination mechanism of coal and gas outburst based on geo-dynamic system with stress–damage–seepage interactions 基于应力-损伤-渗流相互作用地球动力系统的煤与瓦斯突出消除机制
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-18 DOI: 10.1007/s40789-023-00651-z
Lingjin Xu, Chaojun Fan, Mingkun Luo, Sheng Li, Jun Han, Xiang Fu, Bin Xiao

Coal and gas outburst is a complex dynamic disaster during coal underground mining. Revealing the disaster mechanism is of great significance for accurate prediction and prevention of coal and gas outburst. The geo-dynamic system of coal and gas outburst is proposed. The framework of geo-dynamic system is composed of gassy coal mass, geological dynamic environment and mining disturbance. Equations of stress–damage–seepage interaction for gassy coal mass is constructed to resolve the outburst elimination process by gas extraction with boreholes through layer in floor roadway. The results show the occurrence of outburst is divided into the evolution process of gestation, formation, development and termination of geo-dynamic system. The scale range of outburst occurrence is determined, which provides a spatial basis for the prevention and control of outburst. The formation criterion and instability criterion of coal and gas outburst are established. The formation criterion F1 is defined as the scale of the geo-dynamic system, and the instability criterion F2 is defined as the scale of the outburst geo-body. According to the geo-dynamic system, the elimination mechanism of coal and gas outburst—‘unloading + depressurization’ is established, and the gas extraction by boreholes through layer in floor roadway for outburst elimination is given. For the research case, when the gas extraction is 120 days, the gas pressure of the coal seam is reduced to below 0.4 MPa, and the outburst danger is eliminated effectively.

煤与瓦斯突出是煤矿井下开采中一种复杂的动力灾害。揭示灾害机理对准确预测和防治煤与瓦斯突出具有重要意义。提出了煤与瓦斯突出的地球动力系统。瓦斯煤体、地质动力环境和采矿扰动构成了地球动力系统的框架。建立了瓦斯煤体应力-损伤-渗流相互作用方程,求解了底板巷道钻孔穿层抽采消突过程。结果表明:突出的发生可分为地球动力系统孕育、形成、发展和终止的演化过程;确定了突出发生的尺度范围,为突出防治提供了空间依据。建立了煤与瓦斯突出的形成判据和失稳判据。将形成判据F1定义为地球动力系统的尺度,将失稳判据F2定义为突出地质体的尺度。根据地球动力系统,建立了煤与瓦斯突出消除机制——“卸荷+降压”,并给出了煤层底板巷道穿层抽放瓦斯消除突出的方法。研究案例在抽采120 d时,煤层瓦斯压力降至0.4 MPa以下,有效消除了突出危险。
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引用次数: 0
Numerical analysis of water-alternating-CO2 flooding for CO2-EOR and storage projects in residual oil zones 剩余油区co2提高采收率和储油工程水- co2交替驱数值分析
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-18 DOI: 10.1007/s40789-023-00647-9
Boyu Liu, Jun Yao, Tunan Sun

Residual oil zones (ROZs) have high residual oil saturation, which can be produced using CO2 miscible flooding. At the same time, these zones are good candidates for CO2 sequestration. To evaluate the coupled CO2-EOR and storage performance in ROZs for Water-Alternating-CO2 (WAG) flooding, a multi-compositional CO2 miscible model with molecular diffusion was developed. The effects of formation parameters (porosity, permeability, temperature), operation parameters (bottom hole pressure, WAG ratio, pore volume of injected water), and diffusion coefficient on the coupled CO2-EOR and storage were investigated. Five points from the CO2 sequestration curve and the oil recovery factor curve were selected to help better analyze coupled CO2-EOR and storage. The results demonstrate that enhanced performance is observed when formation permeability is higher and a larger volume of water is injected. On the other hand, the performance diminishes with increasing porosity, molecular diffusion of gas, and the WAG ratio. When the temperature is around 100 °C, coupled CO2-EOR and storage performance is the worst. To achieve optimal miscible flooding, it is recommended to maintain the bottom hole pressure (BHP) of the injection well above 1.2 minimum miscibility pressure (MMP), while ensuring that the BHP of the production well remains sufficiently high. Furthermore, the tapered WAG flooding strategy proves to be profitable for enhanced oil recovery, as compared to a WAG ratio of 0.5:1, although it may not be as effective for CO2 sequestration.

剩余油区(ROZs)剩余油饱和度高,可采用CO2混相驱开采。同时,这些区域是二氧化碳固存的良好候选者。为了评价水-CO2交替驱(WAG)在roz内的CO2- eor和储气耦合性能,建立了具有分子扩散的多组分CO2混相模型。研究了地层参数(孔隙度、渗透率、温度)、作业参数(井底压力、WAG比、注入水孔隙体积)和扩散系数对CO2-EOR和储量耦合的影响。从CO2固存曲线和采收率曲线中选取5个点,以更好地分析CO2- eor和储量的耦合关系。结果表明,地层渗透率越高,注水量越大,效果越好。另一方面,随着孔隙度、气体分子扩散和WAG比的增加,性能下降。当温度在100℃左右时,CO2-EOR和存储性能最差。为了实现最佳的混相驱,建议将注入井的井底压力(BHP)保持在1.2以上,同时确保生产井的BHP保持足够高。此外,与0.5:1的WAG比例相比,锥形WAG驱油策略在提高采收率方面是有利的,尽管它在二氧化碳封存方面可能不那么有效。
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引用次数: 0
Apparent activation energy of mineral in open pit mine based upon the evolution of active functional groups 基于活性官能团演变的露天矿矿物表观活化能
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-18 DOI: 10.1007/s40789-023-00650-0
Shipng Lu, Jingyu Zhao, Jiajia Song, Jiaming Chang, Chi-Min Shu
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引用次数: 0
Evaluation of roof cutting by directionally single cracking technique in automatic roadway formation for thick coal seam mining 厚煤层自动成巷定向单裂技术切顶效果评价
IF 8.3 1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-18 DOI: 10.1007/s40789-023-00642-0
Yubing Gao, Qiukai Gai, Xingxing Zhang, Xun Xi, Manchao He

Automatic roadway formation by roof cutting is a sustainable nonpillar mining method that has the potential to increase coal recovery, reduce roadway excavation and improve mining safety. In this method, roof cutting is the key process for stress relief, which significantly affects the stability of the formed roadway. This paper presents a directionally single cracking (DSC) technique for roof cutting with considerations of rock properties. The mechanism of the DSC technique was investigated by explicit finite element analyses. The DSC technique and roof cutting parameters were evaluated by discrete element simulation and field experiment. On this basis, the optimized DSC technique was tested in the field. The results indicate that the DSC technique could effectively control the blast-induced stress distribution and crack propagation in the roof rock, thus, achieve directionally single cracking on the roadway roof. The DSC technique for roof cutting with optimized parameters could effectively reduce the deformation and improve the stability of the formed roadway. Field engineering application verified the feasibility and effectiveness of the evaluated DSC technique for roof cutting.

切顶自动造巷是一种可持续的无矿柱采矿方法,具有提高采煤回收率、减少巷道开挖、提高开采安全性的潜力。在该方法中,顶板切割是消除应力的关键工序,对巷道的稳定性有重要影响。本文提出了一种考虑岩石性质的定向单裂(DSC)顶板切割技术。通过显式有限元分析探讨了DSC技术的作用机理。通过离散元模拟和现场试验,对DSC技术和顶板切割参数进行了评价。在此基础上,对优化后的DSC技术进行了现场试验。结果表明,DSC技术可以有效控制顶板围岩的爆破应力分布和裂纹扩展,从而实现巷道顶板定向单裂纹。采用优化参数的DSC切顶技术可以有效地减小巷道变形,提高巷道的稳定性。现场工程应用验证了所评价的DSC切顶技术的可行性和有效性。
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引用次数: 0
Effect of CO2 dilution on laminar burning velocities, combustion characteristics and NOx emissions of CH4/air mixtures CO2稀释对CH4/空气混合物层流燃烧速度、燃烧特性和NOx排放的影响
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-13 DOI: 10.1007/s40789-023-00655-9
Wenlong Dong, Longkai Xiang, Jian Gao, Bingbing Qiu, Huaqiang Chu
Abstract The laminar combustion characteristics of CH 4 /air premixed flames with CO 2 addition are systemically studied. Experimental measurements and numerical simulations of the laminar burning velocity (LBV) are performed in CH 4 /CO 2 /Air flames with various CO 2 doping ratio under equivalence ratios of 1.0–1.4. GRI 3.0 mech and Aramco mech are employed for predicting LBV, adiabatic flame temperature (AFT), important intermediate radicals (CH 3 , H, OH, O) and NO x emissions (NO, NO 2 , N 2 O), as well as the sensitivity analysis is also conducted. The detail analysis of experiment and simulation reveals that as the CO 2 addition increases from 0% to 40%, the LBVs and AFTs decrease monotonously. Under the same CO 2 doping ratio, the LBVs and AFTs increase first and then decrease with the increase of equivalence ratio, and the maximum of LBV is reached at equivalence ratio of 1.05. The mole fraction tendency of important intermediates and NO x with equivalence ratio and CO 2 doping ratio are similar to the LBVs and AFTs. Reaction H + O 2 ⇔ O + OH is found to be responsible for the promotion of the generation of important intermediates and NO x under the equivalence ratios and CO 2 addition through sensitivity analysis. The sensitivity coefficients of elementary reactions that the increasing of CO 2 doping ratio promotes or inhibits formation of intermediate radicals and NO x decreases. Graphical abstract
系统研究了添加co2的ch4 /空气预混火焰的层流燃烧特性。在当量比为1.0 ~ 1.4的条件下,对不同co2掺杂比的ch4 / co2 /Air火焰层流燃烧速度(LBV)进行了实验测量和数值模拟。采用GRI 3.0模型和Aramco模型对LBV、绝热火焰温度(AFT)、重要中间自由基(CH 3、H、OH、O)和nox排放量(NO、NO 2、n2o)进行预测,并进行敏感性分析。实验和模拟的详细分析表明,随着co2添加量从0%增加到40%,LBVs和AFTs单调降低。在相同CO 2掺杂比下,随着等效比的增大,LBV和aft先增大后减小,在等效比为1.05时达到最大值。等效比和CO 2掺杂比下,重要中间体和NO x的摩尔分数趋势与LBVs和AFTs相似。通过敏感性分析,发现反应H + o2⇔O + OH促进了重要中间体和NO x在等比值和CO 2加入下的生成。随着CO 2掺杂比例的增加,促进或抑制中间自由基和NO x生成的元素反应敏感性系数减小。图形抽象
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引用次数: 0
Simulation study of hydrogen sulfide removal in underground gas storage converted from the multilayered sour gas field 多层含硫气田改造地下储气库硫化氢脱除模拟研究
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-11-04 DOI: 10.1007/s40789-023-00631-3
Yi Yang, Longxin Li, Xia Wang, Nan Qin, Ruihan Zhang, Yulong Zhao, Ye Tian
Abstract A simulation study was carried out to investigate the temporal evolution of H 2 S in the Huangcaoxia underground gas storage (UGS), which is converted from a depleted sulfur-containing gas field. Based on the rock and fluid properties of the Huangcaoxia gas field, a multilayered model was built. The upper layer Jia-2 contains a high concentration of H 2 S (27.2 g/m 3 ), and the lower layer Jia-1 contains a low concentration of H 2 S (14.0 mg/m 3 ). There is also a low-permeability interlayer between Jia-1 and Jia-2. The multi-component fluid characterizations for Jia-1 and Jia-2 were implemented separately using the Peng-Robinson equation of state in order to perform the compositional simulation. The H 2 S concentration gradually increased in a single cycle and peaked at the end of the production season. The peak H 2 S concentration in each cycle showed a decreasing trend when the recovery factor (RF) of the gas field was lower than 70%. When the RF was above 70%, the peak H 2 S concentration increased first and then decreased. A higher reservoir RF, a higher maximum working pressure, and a higher working gas ratio will lead to a higher H 2 S removal efficiency. Similar to developing multi-layered petroleum fields, the operation of multilayered gas storage can also be divided into multi-layer commingled operation and independent operation for different layers. When the two layers are combined to build the storage, the sweet gas produced from Jia-1 can spontaneously mix with the sour gas produced from Jia-2 within the wellbore, which can significantly reduce the overall H 2 S concentration in the wellstream. When the working gas volume is set constant, the allocation ratio between the two layers has little effect on the H 2 S removal. After nine cycles, the produced gas’s H 2 S concentration can be lowered to 20 mg/m 3 . Our study recommends combining the Jia-2 and Jia-1 layers to build the Huangcaoxia underground gas storage. This plan can quickly reduce the H 2 S concentration of the produced gas to 20 mg/m 3 , thus meeting the gas export standards as well as the HSE (Health, Safety, and Environment) requirements in the field. This study helps the engineers understand the H 2 S removal for sulfur-containing UGS as well as provides technical guidelines for converting other multilayered sour gas fields into underground storage sites.
摘要以含硫枯竭气田改造的黄草峡地下储气库(UGS)为研究对象,研究了地下储气库中硫化氢的演化规律。根据黄草峡气田的岩石和流体性质,建立了多层模型。上层Jia-2含有高浓度的h2s (27.2 g/m 3),下层Jia-1含有低浓度的h2s (14.0 mg/m 3)。甲1层和甲2层之间也存在低渗夹层。利用Peng-Robinson状态方程分别对佳1号和佳2号进行多组分流体表征,进行组分模拟。h2s浓度在单周期内逐渐升高,在生产季末达到峰值。当气田采收率(RF)低于70%时,各循环的峰值h2s浓度呈下降趋势。当RF大于70%时,峰值h2s浓度先升高后降低。较高的储层RF、较高的最大工作压力和较高的工作气比将导致较高的h2s去除效率。与开发多层油田类似,多层储气库的作业也可分为多层混合作业和分层独立作业。当两层组合建造储气库时,甲-1产的含硫气可以在井筒内与甲-2产的含硫气自发混合,从而显著降低井流中整体h2s浓度。当工作气量一定时,两层分配比例对h2s去除率影响不大。经过9次循环后,产气的h2s浓度可降至20 mg/ m3。研究建议将甲2层与甲1层结合建设黄草峡地下储气库。该方案可将采出气体的h2s浓度快速降低至20 mg/ m3,从而满足天然气出口标准以及该领域的HSE(健康、安全与环境)要求。该研究有助于工程师了解含硫UGS的h2s去除,并为其他多层含硫气田转化为地下储存场所提供技术指导。
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引用次数: 0
Building 3D CityGML models of mining industrial structures using integrated UAV and TLS point clouds 利用集成无人机和TLS点云构建矿业产业结构的三维CityGML模型
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-30 DOI: 10.1007/s40789-023-00645-x
Canh Le Van, Cuong Xuan Cao, Anh Ngoc Nguyen, Chung Van Pham, Long Quoc Nguyen
Abstract Mining industrial areas with anthropogenic engineering structures are one of the most distinctive features of the real world. 3D models of the real world have been increasingly popular with numerous applications, such as digital twins and smart factory management. In this study, 3D models of mining engineering structures were built based on the CityGML standard. For collecting spatial data, the two most popular geospatial technologies, namely UAV-SfM and TLS were employed. The accuracy of the UAV survey was at the centimeter level, and it satisfied the absolute positional accuracy requirement of creating all levels of detail (LoD) according to the CityGML standard. Therefore, the UAV-SfM point cloud dataset was used to build LoD 2 models. In addition, the comparison between the UAV-SfM and TLS sub-clouds of facades and roofs indicates that the UAV-SfM and TLS point clouds of these objects are highly consistent, therefore, point clouds with a higher level of detail and accuracy provided by the integration of UAV-SfM and TLS were used to build LoD 3 models. The resulting 3D CityGML models include 39 buildings at LoD 2, and two mine shafts with hoistrooms, headframes, and sheave wheels at LoD 3.
具有人为工程结构的矿业工业区是现实世界最显著的特征之一。现实世界的3D模型在许多应用中越来越受欢迎,例如数字双胞胎和智能工厂管理。本研究基于CityGML标准建立了矿山工程构筑物的三维模型。为了收集空间数据,采用了两种最流行的地理空间技术,即UAV-SfM和TLS。无人机测量精度为厘米级,满足CityGML标准创建各级细节(LoD)的绝对位置精度要求。因此,采用UAV-SfM点云数据集构建LoD 2模型。此外,通过对正立面和屋顶的无人机- sfm和TLS子云的对比发现,这些目标的无人机- sfm和TLS点云高度一致,因此,使用无人机- sfm和TLS集成提供的更高细节和精度的点云来构建LoD 3模型。由此产生的3D CityGML模型包括位于LoD 2的39座建筑物,以及位于LoD 3的带有吊装室、井架和滑轮的两个矿井。
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引用次数: 0
Experimental study on the slip evolution of planar fractures subjected to cyclic normal stress 循环正应力作用下平面裂缝滑移演化的实验研究
1区 工程技术 Q2 ENERGY & FUELS Pub Date : 2023-10-27 DOI: 10.1007/s40789-023-00654-w
Kang Tao, Wengang Dang, Xian Liao, Xingling Li
Abstract The frictional rupture mechanisms of rock discontinuities considering the dynamic load disturbance still remain unclear. This paper investigates the transitional behaviors of slip events happened on a planar granite fracture under cyclic normal stress with different oscillation amplitudes. The experimental results show that the activations of fast slips always correlate with unloading of normal stress. Besides, the intensive normal stress oscillation can weaken the shear strength which is recoverable when the normal stress return to constant. The rupture patterns are quantified by stress drop, slip length and slip velocity. With the effect of small oscillation amplitudes, the slip events show chaotic shapes, compared to the regular and predictable style under constant normal stress. When the amplitude is large enough, the big and small slip events emerge alternately, showing a compound slip style. Large amplitude of the cyclic normal stress also widens the interval differences of the slip events. This work provides experimental supports for a convincible link between the dynamic stress disturbance and the slip behavior of rock fractures.
考虑动荷载扰动的岩体结构面摩擦破裂机制尚不清楚。本文研究了在不同振荡幅值的循环正应力作用下,平面花岗岩断裂上发生滑动事件的过渡行为。实验结果表明,快滑块的激活总是与法向应力的卸载有关。此外,剧烈的法向应力振荡会削弱抗剪强度,当法向应力恢复到恒定时,抗剪强度可恢复。破裂模式通过应力降、滑移长度和滑移速度来量化。在较小的振荡幅值的作用下,滑移事件呈现出混乱的形状,而在恒定的正应力下,滑移事件呈现出规则和可预测的形式。当振幅足够大时,大小滑动事件交替出现,表现为复合滑动类型。大的循环正应力幅值也扩大了滑移事件的间隔差。这一工作为在动应力扰动与岩石裂隙滑移行为之间建立可信的联系提供了实验支持。
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引用次数: 0
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International Journal of Coal Science & Technology
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