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Deformation Characteristics and Mechanical Constitutive Model of Coal Under Stress Wave Action 应力波作用下煤炭的变形特征和力学结构模型
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-22 DOI: 10.1007/s11053-024-10388-4
Zhoujie Gu, Rongxi Shen, Siqing Zhang, Xin Zhou, Zhentang Liu, Enlai Zhao, Xiulei Wang, Jianbin Jia

The three-dimensional (3D) stress waves of coal samples were studied using a true triaxial split Hopkinson pressure bar compression rod. The results indicate that the 3D strain of the coal samples increased gradually under vibration load. The 3D stress wave of coal samples showed attenuation characteristics, and the change amplitude of the stress wave of coal samples along the direction of dynamic load was the most obvious. The amplitude of stress wave was the largest in the axial direction constrained by pre-stressing 3 MPa, while the amplitude of stress wave in the lateral 2 MPa pre-stressing was smaller than that under the constraint of 1 MPa. The results showed that the main deformation of coal samples was along the impact direction, while the larger horizontal and vertical lateral binding forces limited the deformation of coal samples. The Fourier transform was performed on the 3D stress wave of the coal samples, and the change in the amplitude of the stress wave spectrum was correlated positively with the vibration. The spectrum amplitude of the coal samples under the pre-stressed 3 MPa constraint (axial) direction was the largest, while the spectrum amplitude of the coal samples under the lateral 2 MPa pre-stressed constraint was smaller than that under the binding 1 MPa. However, the main frequency of the three-way stress wave was distributed in 0–10 kHz. By calculating the energy consumption rate and wave velocity decay rate, it was verified that the damage of coal samples increased with increase in dynamic load. This experimental testing provides an effective testing method for studying the 3D stress waves of coal samples under complex stress medium conditions. In addition, a dynamic constitutive model of coal was constructed according to the mechanical behavior of coal and rock mass and the measured data.

使用真正的三轴分裂霍普金森压杆压缩棒研究了煤样的三维(3D)应力波。结果表明,在振动载荷作用下,煤样的三维应变逐渐增加。煤样的三维应力波呈现衰减特征,煤样应力波沿动载荷方向的变化幅度最为明显。轴向预应力3 MPa约束下的应力波幅最大,而横向2 MPa预应力约束下的应力波幅小于1 MPa约束下的应力波幅。结果表明,煤样的主要变形是沿冲击方向的,而较大的水平和垂直横向约束力限制了煤样的变形。对煤样的三维应力波进行了傅立叶变换,应力波频谱振幅的变化与振动呈正相关。煤样在 3 兆帕预应力约束(轴向)下的频谱振幅最大,而煤样在横向 2 兆帕预应力约束下的频谱振幅小于约束 1 兆帕下的频谱振幅。不过,三向应力波的主频分布在 0-10 kHz。通过计算能量消耗率和波速衰减率,验证了煤样的破坏随动载荷的增加而增加。该实验测试为研究复杂应力介质条件下煤样的三维应力波提供了一种有效的测试方法。此外,还根据煤和岩体的力学行为以及测量数据,构建了煤的动力构成模型。
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引用次数: 0
Interpretable SHAP Model Combining Meta-learning and Vision Transformer for Lithology Classification Using Limited and Unbalanced Drilling Data in Well Logging 结合元学习和视觉转换器的可解释 SHAP 模型,利用测井中有限且不平衡的钻井数据进行岩性分类
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-19 DOI: 10.1007/s11053-024-10396-4
Youzhuang Sun, Shanchen Pang, Zhiyuan Zhao, Yongan Zhang

Recent advances in geological exploration and oil and gas development have highlighted the critical need for accurate classification and prediction of subterranean lithologies. To address this, we introduce the Meta-Vision Transformer (Meta-ViT) method, a novel approach. This technique synergistically combines the adaptability of meta-learning with the analytical prowess of ViT. Meta-learning excels in identifying nuanced similarities across tasks, significantly enhancing learning efficiency. Simultaneously, the ViT leverages these meta-learning insights to navigate the complex landscape of geological exploration, improving lithology identification accuracy. The Meta-ViT model employs a support set to extract crucial insights through meta-learning, and a query set to test the generalizability of these insights. This dual-framework setup enables the ViT to detect various underground rock types with unprecedented precision. Additionally, by simulating diverse tasks and data scenarios, meta-learning broadens the model's applicational scope. Integrating the SHAP (SHapley Additive exPlanations) model, rooted in Shapley values from cooperative game theory, greatly enhances the interpretability of rock type classifications. We also utilized the ADASYN (Adaptive Synthetic Sampling) technique to optimize sample representation, generating new samples based on existing densities to ensure uniform distribution. Our extensive testing across various training and testing set ratios showed that the Meta-ViT model outperforms dramatically traditional machine learning models. This approach not only refines learning processes but it also adeptly addresses the inherent challenges of geological data analysis.

地质勘探和油气开发领域的最新进展凸显了对地下岩性进行精确分类和预测的迫切需要。为此,我们引入了一种新方法--元视觉转换器(Meta-ViT)方法。这项技术将元学习的适应性与 ViT 的分析能力协同结合在一起。元学习擅长识别不同任务之间的细微相似性,从而显著提高学习效率。同时,ViT 利用这些元学习的洞察力来驾驭地质勘探的复杂局面,提高岩性识别的准确性。Meta-ViT 模型采用一个支持集,通过元学习提取关键见解,并采用一个查询集来测试这些见解的通用性。这种双框架设置使 ViT 能够以前所未有的精度检测各种地下岩石类型。此外,通过模拟不同的任务和数据场景,元学习拓宽了模型的应用范围。SHAP(SHapley Additive exPlanations)模型植根于合作博弈论中的 Shapley 值,它大大提高了岩石类型分类的可解释性。我们还利用 ADASYN(自适应合成采样)技术优化样本代表性,根据现有密度生成新样本,以确保分布均匀。我们对各种训练集和测试集比例进行的广泛测试表明,Meta-ViT 模型的性能大大优于传统的机器学习模型。这种方法不仅完善了学习过程,还巧妙地解决了地质数据分析所面临的固有挑战。
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引用次数: 0
Strength Evolution Characteristics of Coal with Different Pore Structures and Mineral Inclusions Based on CT Scanning Reconstruction 基于 CT 扫描重建的不同孔隙结构和矿物夹杂物煤炭的强度演变特征
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-16 DOI: 10.1007/s11053-024-10397-3
Cun Zhang, Sheng Jia, Zhaopeng Ren, Qingsheng Bai, Lei Wang, Penghua Han

Water–rock interactions affect mineral inclusions and the pore structure of rock, subsequently affecting its mechanical and seepage properties. A method for quantitative analysis of the pore and mineral inclusion evolution characteristics of coal samples based on CT scanning is proposed. Accordingly, numerical model construction and block division of mineral inclusions and pores in coal samples were realized. The effects of mineral inclusions and the pore structure on coal failure were simulated and analyzed. The results showed that the porosity and pore distribution in coal influence its strength. The development of plastic zones in coal affected by pores can be divided into three stages: (1) tensile failure initiation stage, (2) shear failure penetration stage, and (3) failure rapid expansion stage. The higher the fractal dimension of the pores is, the greater the strength of coal. Pores and mineral inclusions degrade the strength of coal and accelerate the development of plastic zones. In the loading process, plastic zones preferentially emerge around pores and mineral inclusions. The plastic zones around mineral inclusions connect gradually with those around pores, thus accelerating coal failure.

水与岩石的相互作用会影响岩石中的矿物包裹体和孔隙结构,进而影响岩石的力学和渗流特性。本文提出了一种基于 CT 扫描定量分析煤样孔隙和矿物包裹体演化特征的方法。据此,实现了煤样中矿物包裹体和孔隙的数值模型构建和区块划分。模拟并分析了矿物夹杂物和孔隙结构对煤炭失效的影响。结果表明,煤中的孔隙率和孔隙分布影响煤的强度。煤中受孔隙影响的塑性区的发展可分为三个阶段:(1)拉伸破坏起始阶段;(2)剪切破坏渗透阶段;(3)破坏快速扩展阶段。孔隙的分形维数越高,煤的强度越大。孔隙和矿物夹杂物会降低煤的强度,加速塑性区的形成。在加载过程中,塑性区优先出现在孔隙和矿物夹杂物周围。矿物夹杂物周围的塑性区与孔隙周围的塑性区逐渐相连,从而加速了煤的破坏。
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引用次数: 0
Mineral Reconnaissance Through Scientific Consensus: First National Prospectivity Maps for PGE–Ni–Cu–Cr and Witwatersrand-type Au Deposits in South Africa 通过科学共识进行矿产勘探:南非 PGE-Ni-Cu-Cr 和 Witwatersrand 型金矿床的首批国家远景图
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-14 DOI: 10.1007/s11053-024-10390-w
Glen T. Nwaila, Steven E. Zhang, Julie E. Bourdeau, Emmanuel John M. Carranza, Stephanie Enslin, Musa S. D. Manzi, Fenitra Andriampenomanana, Yousef Ghorbani

We present here the first experimental science (consensus)-based mineral prospectivity mapping (MPM) method and its validation results in the form of national prospectivity maps and datasets for PGE–Ni–Cu–Cr and Witwatersrand-type Au deposits in South Africa. The research objectives were: (1) to develop the method toward applicative uses; (2) to the extent possible, validate the effectiveness of the method; and (3) to provide national MPM products. The MPM method was validated by targeting mega-deposits within the world’s largest and best exploited geological systems and mining districts—the Bushveld Complex and the Witwatersrand Basin. Their incomparable knowledge and mega-deposit status make them the most useful for validating MPM methods, serving as “certified reference targets”. Our MPM method is built using scientific consensus via deep ensemble construction, using workflow experimentation that propagates uncertainty of subjective workflow choices by mimicking the outcome of an ensemble of data scientists. The consensus models are a data-driven equivalent to expert aggregation, increasing confidence in our MPM products. By capturing workflow-induced uncertainty, the study produced MPM products that not only highlight potential exploration targets but also offer a spatial consensus level for each, de-risking downstream exploration. Our MPM results agree qualitatively with exploration and geological knowledge. In particular, our method identified areas of high prospectivity in known exploration regions and geologically and geospatially corresponding to the known extents of both mineral systems. The convergence rate of the ensemble demonstrated a high level of statistical durability of our MPM products, suggesting that they can guide exploration at a national scale until significant new data emerge. Potential new exploration targets for PGE–Ni–Cu–Cr are located northwest of the Bushveld Complex; for Au, promising areas are west of the Witwatersrand Basin. The broader implications of this work for the mineral industry are profound. As exploration becomes more data-driven, the question of trust in MPM products must be addressed; it can be done using the proposed scientific method.

Graphical Abstract

我们在此介绍第一种基于实验科学(共识)的矿产远景规划(MPM)方法及其验证结果,即南非 PGE-Ni-Cu-Cr 和 Witwatersrand 型金矿床的国家远景规划图和数据集。研究目标是(1) 开发应用性方法;(2) 尽可能验证该方法的有效性;(3) 提供国家 MPM 产品。通过对世界上最大、开采最好的地质系统和矿区--布什维尔德复合区和威特沃特斯兰德盆地--内的特大型矿床进行研究,验证了多金属结核方法。它们无与伦比的知识和超大型矿床的地位使其成为 "认证参考目标",对验证 MPM 方法最为有用。我们的 MPM 方法是通过深度集合构建科学共识,利用工作流程实验,通过模仿数据科学家的集合结果来传播主观工作流程选择的不确定性。共识模型相当于专家汇总的数据驱动模型,从而增强了对我们的 MPM 产品的信心。通过捕捉工作流程引起的不确定性,该研究产生的 MPM 产品不仅突出了潜在的勘探目标,还为每个目标提供了空间共识水平,从而降低了下游勘探的风险。我们的 MPM 结果在质量上与勘探和地质知识一致。特别是,我们的方法确定了已知勘探区域内的高勘探前景区域,并且在地质和地球空间上与两个矿物系统的已知范围相对应。集合的收敛率表明,我们的 MPM 产品具有很高的统计持久性,这表明它们可以指导全国范围内的勘探工作,直到出现重要的新数据。对于 PGE-Ni-Cu-Cr 而言,潜在的新勘探目标位于布什维尔德复合体西北部;对于 Au 而言,有希望的区域位于威特沃特斯兰德盆地西部。这项工作对矿产行业具有深远的影响。随着勘探变得越来越以数据为驱动,必须解决对 MPM 产品的信任问题;可以使用所提出的科学方法来解决这个问题。
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引用次数: 0
Uncertainty Quantification in Mineral Resource Estimation 矿产资源估算中的不确定性量化
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-11 DOI: 10.1007/s11053-024-10394-6
Oltingey Tuya Lindi, Adeyemi Emman Aladejare, Toochukwu Malachi Ozoji, Jukka-Pekka Ranta

Mineral resources are estimated to establish potential orebody with acceptable quality (grade) and quantity (tonnage) to validate investment. Estimating mineral resources is associated with uncertainty from sampling, geological heterogeneity, shortage of knowledge and application of mathematical models at sampled and unsampled locations. The uncertainty causes overestimation or underestimation of mineral deposit quality and/or quantity, affecting the anticipated value of a mining project. Therefore, uncertainty is assessed to avoid any likely risks, establish areas more prone to uncertainty and allocate resources to scale down potential consequences. Kriging, probabilistic, geostatistical simulation and machine learning methods are used to estimate mineral resources and assess uncertainty, and their applicability depends on deposit characteristics, amount of data available and expertise of technical personnel. These methods are scattered in the literature making them challenging to access when needed for uncertainty quantification. Therefore, this review aims to compile information about uncertainties in mineral resource estimation scatted in the literature and develop a knowledge base of methodologies for uncertainty quantification. In addition, mineral resource estimation comprises different interdependent steps, in and through which uncertainty accumulates and propagates toward the final estimate. Hence, this review demonstrates stepwise uncertainty propagation and assessment through various phases of the estimation process. This can broaden knowledge about mineral resource estimation and uncertainty assessment in each step and increase the accuracy of mineral resource estimates and mining project viability.

矿产资源量的估算是为了确定具有可接受质量(品位)和数量(吨位)的潜在矿体,以验证投资的有效性。矿产资源量的估算与取样、地质异质性、知识短缺以及在取样和未取样地点应用数学模型的不确定性有关。不确定性会导致高估或低估矿床质量和/或数量,影响采矿项目的预期价值。因此,要对不确定性进行评估,以避免任何可能的风险,确定更容易出现不确定性的区域,并分配资源以减少潜在的后果。克里金法、概率法、地质统计模拟法和机器学习法被用于估算矿产资源和评估不确定性,其适用性取决于矿床特征、可用数据量和技术人员的专业知识。这些方法散见于文献中,在需要进行不确定性量化时很难获取。因此,本综述旨在汇编散见于文献中的矿产资源估算不确定性信息,并建立一个不确定性量化方法知识库。此外,矿产资源估算包括不同的相互依存步骤,在这些步骤中,不确定性不断累积并向最终估算结果传播。因此,本综述通过估算过程的各个阶段展示了不确定性的逐步传播和评估。这可以拓宽对矿产资源估算和各步骤不确定性评估的认识,提高矿产资源估算的准确性和采矿项目的可行性。
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引用次数: 0
Sand Production Prediction with Machine Learning using Input Variables from Geological and Operational Conditions in the Karazhanbas Oilfield, Kazakhstan 利用来自哈萨克斯坦卡拉赞巴斯油田地质和作业条件的输入变量,通过机器学习预测采砂量
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-09 DOI: 10.1007/s11053-024-10389-3
Ainash Shabdirova, Ashirgul Kozhagulova, Yernazar Samenov, Nguyen Minh, Yong Zhao

This paper describes a comprehensive approach to predict sand production in the Karazhanbas oilfield using machine learning (ML) techniques. By analyzing data from 2000 wells, the research uncovered the complex dynamics of sand production and emphasized the critical need for accurately predicting the peak sand mass and its occurrence time. ML techniques can have a significant impact on prediction of sand production and on the optimization of oilfield operation, which can be improved with the combined use of enriched training data and domain-specific knowledge. The research underscored the influence of geological factors, especially fault proximity, on prediction accuracy. Domain and field knowledge is needed to formulate different production scenarios for prediction purposes such that the relevant data can be selected for the training of ML models. Moreover, new metrics are needed to evaluate model performance as the applied method is tailored for different operational strategies. As the peak sand mass is considered a pivotal event in field operation, new metrics in terms of peak prediction accuracy and peak time prediction accuracy were introduced to evaluate the performance of ML models. A suite of ML algorithms was employed in the study, which demonstrated notable accuracy in the classification of sand-producing wells.

本文介绍了一种利用机器学习(ML)技术预测卡拉赞巴斯油田产砂量的综合方法。通过分析 2000 口油井的数据,研究揭示了产砂的复杂动态,并强调了准确预测峰值砂量及其出现时间的迫切需要。结合使用丰富的训练数据和特定领域的知识,ML 技术可以对预测产砂量和优化油田运营产生重大影响。研究强调了地质因素(尤其是断层邻近性)对预测精度的影响。需要领域和现场知识来制定不同的预测生产方案,以便选择相关数据来训练 ML 模型。此外,还需要新的指标来评估模型的性能,因为所应用的方法是为不同的操作策略量身定制的。由于峰值砂量被认为是油田作业中的关键事件,因此引入了峰值预测精度和峰值时间预测精度等新指标来评估 ML 模型的性能。研究中采用了一套 ML 算法,这些算法在产砂井分类中表现出了显著的准确性。
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引用次数: 0
An Interpretable Multi-Model Machine Learning Approach for Spatial Mapping of Deep-Sea Polymetallic Nodule Occurrences 用于深海多金属结核分布空间绘图的可解释多模型机器学习方法
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-07 DOI: 10.1007/s11053-024-10393-7
Iason-Zois Gazis, Francois Charlet, Jens Greinert

High-resolution mapping of deep-sea polymetallic nodules is needed (a) to understand the reasons behind their patchy distribution, (b) to associate nodule coverage with benthic fauna occurrences, and (c) to enable an accurate resource estimation and mining path planning. This study used an autonomous underwater vehicle to map 37 km2 of a geomorphologically complex site in the Eastern Clarion–Clipperton Fracture Zone. A multibeam echosounder system (MBES) at 400 kHz and a side scan sonar at 230 kHz were used to investigate the nodule backscatter response. More than 30,000 seafloor images were analyzed to obtain the nodule coverage and train five machine learning (ML) algorithms: generalized linear models, generalized additive models, support vector machines, random forests (RFs) and neural networks (NNs). All models ML yielded similar maps of nodule coverage with differences occurring in the range of predicted values, particularly at parts with irregular topography. RFs had the best fit and NNs had the worst spatial transferability. Attention was given to the interpretability of model outputs using variable importance ranking across all models, partial dependence plots and domain knowledge. The nodule coverage is higher on relatively flat seafloor ( < 3°) with eastward-facing slopes. The most important predictor was the MBES backscatter, particularly from incident angles between 25 and 55°. Bathymetry, slope, and slope orientation were important geomorphological predictors. For the first time, at a water depth of 4500 m, orthophoto-mosaics and image-derived digital elevation models with 2-mm and 5-mm spatial resolutions supported the geomorphological analysis, interpretation of polymetallic nodules occurrences, and backscatter response.

需要对深海多金属结核进行高分辨率测绘,以便:(a) 了解其成片分布的原因;(b) 将结核覆盖范围与底栖动物的出现联系起来;(c) 进行准确的资源评估和采矿路径规划。这项研究使用自动潜航器对克拉里昂-克利珀顿东部断裂带 37 平方公里地貌复杂的地点进行了测绘。使用频率为 400 千赫的多波束回声测深仪(MBES)和频率为 230 千赫的侧扫声纳来研究结核的反向散射响应。对 30,000 多张海底图像进行了分析,以获得结核覆盖范围并训练五种机器学习(ML)算法:广义线性模型、广义加法模型、支持向量机、随机森林(RF)和神经网络(NN)。所有 ML 模型都得出了相似的结核覆盖图,但在预测值范围上存在差异,特别是在地形不规则的部分。RF 的拟合效果最好,而 NN 的空间转移性最差。利用所有模型的变量重要性排序、部分依存图和领域知识,对模型输出的可解释性进行了关注。在朝东倾斜的相对平坦的海底(3°),结核覆盖率较高。最重要的预测因素是 MBES 后向散射,尤其是入射角度在 25 至 55°之间的情况。水深、坡度和坡向是重要的地貌预测因素。在水深 4500 米处,空间分辨率分别为 2 毫米和 5 毫米的正射影像镶嵌图和源自图像的数字高程模型首次为地貌分析、多金属结核矿点解释和反向散射响应提供了支持。
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引用次数: 0
A Prediction Method for Surface Subsidence at Deep Mining Areas with Thin Bedrock and Thick Soil Layer Considering Consolidation Behavior 考虑固结行为的薄基岩厚土层深部采矿区地表沉降预测方法
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-03 DOI: 10.1007/s11053-024-10395-5
Jiachen Wang, Shanxi Wu, Zhaohui Wang, Shenyi Zhang, Boyuan Cheng, Huashun Xie

Among the various hazards induced by underground coal mining, surface subsidence tends to cause structural damage to the ground. Therefore, accurate prediction and evaluation of surface subsidence are significant for ensuring mining security and sustainable development. Traditional methods like the probability integral method provide effective predictions. However, these methods do not take into account the consolidation behavior of thick soil layers. In this study, based on the principle of superposition, an improved probability integral method that includes surface subsidence caused by rock layer movement and the consolidation behavior of thick soil layers is developed. The proposed method was applied in the Zhaogu No. 2 coal mine, located in the Jiaozuo mining area. Utilizing unmanned surface vehicle measurement technology, it was found that the maximum subsidence values of the two survey lines were 5.441 m and 4.842 m, with maximum subsidence rate of 62.9 mm/day at observation points. Experimental tests have shown that surface subsidence in deep mining areas with thin bedrock and thick soil layers exhibited a large subsidence coefficient and a wide range of subsidence, closely related to the consolidation behavior of thick soil layers. After verification, compared to the probability integral method, the improved probability integral method incorporating soil consolidation showed a 14.7% reduction in average error and a 22% reduction in maximum error. Therefore, the improved probability integral method proposed can be a very promising tool for forecasting and evaluating potential geohazards in coal mining areas.

在地下采煤引发的各种危害中,地表沉降往往会对地面结构造成破坏。因此,准确预测和评估地表沉降对确保采矿安全和可持续发展意义重大。概率积分法等传统方法可以提供有效的预测。然而,这些方法没有考虑到厚土层的固结行为。本研究基于叠加原理,开发了一种改进的概率积分法,其中包括岩层运动引起的地表沉降和厚土层的固结行为。所提出的方法被应用于焦作矿区的赵固二号煤矿。利用无人地表车测量技术,发现两条测量线的最大下沉值分别为 5.441 米和 4.842 米,观测点的最大下沉速率为 62.9 毫米/天。实验测试表明,基岩薄、土层厚的深部采空区地表沉降表现出沉降系数大、沉降范围广的特点,这与厚土层的固结行为密切相关。经过验证,与概率积分法相比,包含土壤固结的改进概率积分法的平均误差减少了 14.7%,最大误差减少了 22%。因此,所提出的改进概率积分法可以作为一种非常有前途的工具,用于预测和评估煤矿开采区潜在的地质灾害。
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引用次数: 0
Ultrasonic-Induced Changes in Nanopores: Molecular Insights into Effects on CH4/CO2 Adsorption in Coal 超声波引起的纳米孔变化:对煤中 CH4/CO2 吸附影响的分子见解
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-08-01 DOI: 10.1007/s11053-024-10392-8
Liang Wang, Wei Yang, Kang Yang, Chenhao Tian

The nanometer-sized pores within coal are the primary sites for CH4 adsorption and competitive adsorption with CO2. Reasonable modification of the nanopore structure to enhance CH4 desorption, diffusion rates, and CO2 competitive adsorption effects can enhance significantly coalbed methane (CBM) production. However, ultrasonic synchronous modification of multiple features of nanopores leads to complex and variable gas adsorption behaviors in coal. To reveal the effect of ultrasonic modification of coal nanopores on gas adsorption, pore measurement experiments and molecular simulation studies were conducted. The results showed that the volume ratio of diffusion pores to adsorption pores (V2/V1) decreased significantly after ultrasonic excitation. In the original coal sample, V2/V1 was 3.05, while in the coal sample after ultrasonic treatment, V2/V1 ranged from 0 to 2.54. With decrease in the proportion of the volume of diffusion pores, the proportion of CH4 migration from the pore walls of the adsorption pores increased continuously. The proportion of CH4 migration from the pore walls of the diffusion pores to the pore space of the diffusion pores decreased continuously. The results of gas–solid interaction energy calculation showed that ultrasonic treatment of coal decreases the V2/V1 ratio, leading to 7.1–23.3% increase in CO2 competitive adsorption effect. It also resulted in 4–49% improvement in competitive adsorption efficiency. Additionally, based on gas–solid interaction energy data, an adsorption capacity evaluation model for coal under different gas compositions and pore volume ratios was constructed. The findings can guide ultrasonic-enhanced CBM.

煤炭中的纳米级孔隙是吸附 CH4 和与 CO2 竞争吸附的主要场所。对纳米孔结构进行合理改性,以提高 CH4 解吸、扩散速率和 CO2 竞争吸附效果,可显著提高煤层气产量。然而,对纳米孔的多种特征进行超声波同步改性会导致煤中气体吸附行为复杂多变。为了揭示超声波改性煤纳米孔对气体吸附的影响,研究人员进行了孔隙测量实验和分子模拟研究。结果表明,超声波激发后,扩散孔与吸附孔的体积比(V2/V1)显著下降。在原始煤样中,V2/V1 为 3.05,而在超声波处理后的煤样中,V2/V1 在 0 至 2.54 之间。随着扩散孔体积比例的降低,CH4 从吸附孔孔壁迁移的比例不断增加。CH4从扩散孔孔壁向扩散孔孔隙迁移的比例持续下降。气固相互作用能计算结果表明,超声处理煤炭可降低 V2/V1 比,使 CO2 竞争吸附效果提高 7.1-23.3%。它还使竞争吸附效率提高了 4-49%。此外,基于气固相互作用能数据,构建了不同气体成分和孔隙体积比条件下煤的吸附能力评价模型。研究结果可为超声波增强煤层气提供指导。
{"title":"Ultrasonic-Induced Changes in Nanopores: Molecular Insights into Effects on CH4/CO2 Adsorption in Coal","authors":"Liang Wang, Wei Yang, Kang Yang, Chenhao Tian","doi":"10.1007/s11053-024-10392-8","DOIUrl":"https://doi.org/10.1007/s11053-024-10392-8","url":null,"abstract":"<p>The nanometer-sized pores within coal are the primary sites for CH<sub>4</sub> adsorption and competitive adsorption with CO<sub>2</sub>. Reasonable modification of the nanopore structure to enhance CH<sub>4</sub> desorption, diffusion rates, and CO<sub>2</sub> competitive adsorption effects can enhance significantly coalbed methane (CBM) production. However, ultrasonic synchronous modification of multiple features of nanopores leads to complex and variable gas adsorption behaviors in coal. To reveal the effect of ultrasonic modification of coal nanopores on gas adsorption, pore measurement experiments and molecular simulation studies were conducted. The results showed that the volume ratio of diffusion pores to adsorption pores (V<sub>2</sub>/V<sub>1</sub>) decreased significantly after ultrasonic excitation. In the original coal sample, V<sub>2</sub>/V<sub>1</sub> was 3.05, while in the coal sample after ultrasonic treatment, V<sub>2</sub>/V<sub>1</sub> ranged from 0 to 2.54. With decrease in the proportion of the volume of diffusion pores, the proportion of CH<sub>4</sub> migration from the pore walls of the adsorption pores increased continuously. The proportion of CH<sub>4</sub> migration from the pore walls of the diffusion pores to the pore space of the diffusion pores decreased continuously. The results of gas–solid interaction energy calculation showed that ultrasonic treatment of coal decreases the V<sub>2</sub>/V<sub>1</sub> ratio, leading to 7.1–23.3% increase in CO<sub>2</sub> competitive adsorption effect. It also resulted in 4–49% improvement in competitive adsorption efficiency. Additionally, based on gas–solid interaction energy data, an adsorption capacity evaluation model for coal under different gas compositions and pore volume ratios was constructed. The findings can guide ultrasonic-enhanced CBM.</p>","PeriodicalId":54284,"journal":{"name":"Natural Resources Research","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141862405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of Main Controlling Factors for Quantitative Evaluation of a Favorable Carbonate Oil- and Gas-Bearing Area in the Pre-exploration Stage: Lianglitage Formation in the Central Uplift Belt of the Tarim Basin 应用主要控制因素对勘探前阶段有利的碳酸盐岩含油气区进行定量评价:塔里木盆地中央隆起带梁里塔格地层
IF 5.4 2区 地球科学 Q1 GEOSCIENCES, MULTIDISCIPLINARY Pub Date : 2024-07-31 DOI: 10.1007/s11053-024-10382-w
Bin Li, Junshuai Ran, Tao Tang, Taiyu Deng, Suju Yang, Haitao Lv

The evaluation of oil- and gas-bearing areas (OGBAs) during the pre-exploration stage has always posed challenges due to the lack of an effective geological evaluation model and validation data. This paper introduces a novel quantitative evaluation method based on the vectorization of key geological factors related to hydrocarbon accumulation. In this study, we focused on the Lianglitage Formation in the Central Uplift Belt and aimed to evaluate the application of the proposed method to the OGBA in the Tarim Basin. First, the reservoir-forming parameters were quantified based on geological analysis and expert experience. Second, the weights of the main parameters were determined using a combination of the gray correlation method and expert knowledge. Finally, the OGBA was evaluated using a multifactor fusion method. The comprehensive evaluation results indicate that the platform margin in the northeastern part of the Katake Uplift shows promise for exploration, while the southern region has a good potential for future exploration. This study emphasizes the significance of selecting key factors and vectorizing evaluation parameter mapping for accurate and quantitative evaluation of an OGBA. The results of this study provide a valuable foundation for evaluating the OGBAs in the Lianglitage Formation within the Tarim Basin and offer a valuable reference for OGBAs in similar regions during the pre-exploration stage.

由于缺乏有效的地质评价模型和验证数据,勘探前期的含油气区(OGBAs)评价工作一直面临挑战。本文介绍了一种基于油气聚集相关关键地质因素矢量化的新型定量评价方法。在本研究中,我们以中央隆起带的梁里塔格地层为研究对象,旨在评估所提出的方法在塔里木盆地 OGBA 中的应用。首先,根据地质分析和专家经验对成藏参数进行了量化。其次,结合灰色关联法和专家知识确定了主要参数的权重。最后,采用多因素融合法对 OGBA 进行了评估。综合评价结果表明,片岳隆起东北部的平台边缘显示出勘探前景,而南部地区则具有良好的未来勘探潜力。本研究强调了选择关键因素和矢量化评价参数图对于准确和定量评价 OGBA 的重要意义。本研究的结果为塔里木盆地梁里塔格地层的 OGBA 评价奠定了宝贵的基础,并为类似地区的 OGBA 在勘探前期阶段提供了有价值的参考。
{"title":"Application of Main Controlling Factors for Quantitative Evaluation of a Favorable Carbonate Oil- and Gas-Bearing Area in the Pre-exploration Stage: Lianglitage Formation in the Central Uplift Belt of the Tarim Basin","authors":"Bin Li, Junshuai Ran, Tao Tang, Taiyu Deng, Suju Yang, Haitao Lv","doi":"10.1007/s11053-024-10382-w","DOIUrl":"https://doi.org/10.1007/s11053-024-10382-w","url":null,"abstract":"<p>The evaluation of oil- and gas-bearing areas (OGBAs) during the pre-exploration stage has always posed challenges due to the lack of an effective geological evaluation model and validation data. This paper introduces a novel quantitative evaluation method based on the vectorization of key geological factors related to hydrocarbon accumulation. In this study, we focused on the Lianglitage Formation in the Central Uplift Belt and aimed to evaluate the application of the proposed method to the OGBA in the Tarim Basin. First, the reservoir-forming parameters were quantified based on geological analysis and expert experience. Second, the weights of the main parameters were determined using a combination of the gray correlation method and expert knowledge. Finally, the OGBA was evaluated using a multifactor fusion method. The comprehensive evaluation results indicate that the platform margin in the northeastern part of the Katake Uplift shows promise for exploration, while the southern region has a good potential for future exploration. This study emphasizes the significance of selecting key factors and vectorizing evaluation parameter mapping for accurate and quantitative evaluation of an OGBA. The results of this study provide a valuable foundation for evaluating the OGBAs in the Lianglitage Formation within the Tarim Basin and offer a valuable reference for OGBAs in similar regions during the pre-exploration stage.</p>","PeriodicalId":54284,"journal":{"name":"Natural Resources Research","volume":null,"pages":null},"PeriodicalIF":5.4,"publicationDate":"2024-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141862123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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Natural Resources Research
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