Natural Resources Research最新文献

Low-permeability coal seams are widely distributed in China, with significant differences in coal ranks and properties. Identifying an effective method for nitrogen fracturing is an urgent challenge. To study the impact of coal ranks on fracturing, lignite, bituminous coal, and anthracite were used in liquid nitrogen freeze–thaw experiments. Low-field nuclear magnetic resonance was used to measure T₂ curves, porosity, and pore throat distribution during the freeze–thaw process. The fractal characteristics of pore microstructure and the dynamic evolution of unfrozen water were analyzed. The results indicate that liquid nitrogen freeze–thaw promotes pore development in coal of all ranks. Lignite, with its high moisture content and abundant pore structure, showed the most significant transformation effect, followed by bituminous coal and anthracite. After a single freezing–thawing cycle, the pore growth rates of lignite, bituminous coal, and anthracite are 135.98%, 104.17%, and 53.65%, respectively. Additionally, the transformation effect on different types of pores shows different characteristics. The distribution of adsorption pore throats slightly decreases, while the increase in distribution of permeable pore throats follows the order: lignite > bituminous coal > anthracite. The fractal dimension D_A of adsorption pores is less than 2, indicating no fractal characteristics, while the fractal dimension D_S of permeable pores is greater than 2.9, showing significant fractal characteristics. During the freezing process, lignite exhibits the greatest decrease in unfrozen water content, while during the thawing process, all three coal samples show a sudden increase in unfrozen water content, with bituminous coal showing the smallest increase, only 1836.49.

Research on the effects of acidic and alkaline solutions and stress on coal’s pore structure has traditionally focused on larger scales, leaving a gap in understanding nanoscale impacts. This study utilized a self-developed small-angle X-ray scattering (SAXS) miniature loading system and in situ synchrotron SAXS to investigate nanopore evolution under varying pH conditions and external stress. By analyzing the scattering data obtained, we investigated the changes in the internal nanopore structures of coal soaked in solutions with different pH values and subjected to external loading. The results showed that all coal samples exhibited negative Porod deviations. The degree of negative Porod deviation decreased after the coal samples were soaked in acidic solutions, while it increased after soaking in alkaline solutions. Negative Porod deviations increased notably under destructive loading. There are significant differences in the changes of internal nanopore structures in coal samples treated with chemical solutions of different pH values. The porosity and specific surface area of coal samples decreased significantly after soaking in acidic solutions, while coal samples treated with alkaline solutions showed substantial increases in both parameters. During subsequent loading, the samples soaked in acidic solutions exhibited minimal changes, whereas those treated with alkaline solutions experienced notable alterations. Chemically treated coal samples also showed increased sensitivity to external stress, especially in smaller nanopores. The study identifies three stages of nanopore evolution under stress: minor damage, compression, and rupture.

Coalbed methane (CBM) storage and transport are facilitated by an intricate multi-scale pore structure. It is of great significance to study the characteristics of the pore structure and its role in CBM storage and transport in order to enhance CBM extraction, prevent CBM disasters, and improve the efficiency of CO₂ geological storage. Here, we review the current progress in coal reservoir pore structure research worldwide based on 8199 published papers on "coal pore structure" identified from the Web of Science Core Collection database. Using a bibliometric method with high-frequency core keywords as important database quantitative indices, five clusters with high-frequency keywords were selected as the core content to provide a comprehensive review of the progress of research on the pore structure of the coal body. The findings indicate that, with global attention focused on the storage of greenhouse gases, such as CO₂, and clean energy extraction of CBM, research on pore structure of coal rock reservoirs has increased rapidly since 2010, with studies from China, the USA, Australia, Poland, and Japan the most abundant. With the development of testing technology, research on the basic parameters of coal pore structure, the intrinsic mechanism of pore formation, and the factors influencing the evolution of pore structure has evolved from the macroscopic to the micromolecular level, and from qualitative descriptions to quantitative or semi-quantitative characterization. From keyword analysis, it is evident that the control mechanisms of pore structures with regard to adsorption–desorption–diffusion–seepage of CBM in coal reservoirs have received considerable attention. The development of technologies such as molecular simulation provides important technological support for analyzing the intrinsic mechanisms competitive CO₂, CH₄, and N₂ adsorption in coal–rock reservoirs at the molecular level. The development of molecular dynamics simulations and digital imaging technology will provide crucial support for the quantitative in situ characterization of pore structures and other physical parameters of unconventional reservoirs, such as coal and rock. Moreover, studying the microscopic mechanisms of gas adsorption and fluid flow in porous systems under extreme conditions (e.g., high temperature, high pressure, ultra-microscale) has become a research frontier in this field.

Dig-limits optimization is one of the most important steps in the grade control process at open-pit mines. It aims to send blasted materials to their optimal destinations to maximize the profitability of mining projects. Grade and blast movement are key uncertainties that affect the optimal determination of dig-limits. This paper presents an integrated workflow for optimizing dig-limits under grade and blast movement uncertainties. The proposed methodology incorporates these uncertainties into the grade control process to enhance material classification and destination optimization, thereby minimizing ore loss and dilution. A multivariate geostatistical simulation workflow is developed to capture spatial uncertainties in grade distribution and blast movement distance and direction. By applying projection pursuit multivariate transformation and sequential Gaussian simulation for modeling blast movement distances at all locations and flitches within the bench section, the anticipated D-like shape from blasting is reproduced, and uncertainty is quantified. The maximum expected profit method effectively determines optimal material destinations under uncertainty improving overall mining profitability. The proposed risk-based dig-limits optimization model accounts for mining equipment selectivity, irregular bench shapes, and varying orebody orientations, resulting in operational and economically viable dig-limits. A case study on a porphyry copper deposit demonstrated the significant impact of blast movement on ore loss and dilution, emphasizing the need for accurate blast movement modeling and its integration into grade control procedures. By accounting for differential blast movement, the proposed workflow ensures reliable post-blast material classifications, reducing suboptimal decisions, thus improving project profitability and operational efficiency.

Coal and gas desorption, as a major form of gas energy release, is a key factor in triggering coal and gas outbursts. Therefore, studying the physical characteristics during coal and gas desorption is essential for understanding the development process of coal and gas outbursts. Based on gas dynamics during coal particle gas desorption, this study established a connection between gas desorption and infrasound signals, elaborating on the generation mechanism of infrasound signals during coal particle gas desorption and validating the feasibility of the theory through experimental data, thereby demonstrating the spontaneous occurrence of subsonic tremors during coal particle gas desorption. Combining observational data, it was found that the peak value of infrasound signals generated during desorption experiments is correlated positively with the initial pressure; while, the dominant frequency of infrasound signals is influenced by the proportion of intergranular pores and fractures within the experimental vessel. To further validate the theory of subsonic generation, a mathematical model describing pressure oscillations within intergranular pores, thereby explaining the mechanism of subsonic tremors, was established. The model confirms that the generation and characteristics of infrasound signals are controlled by the parameters of intergranular pores in coal samples. The model effectively simulates changes in the characteristics of infrasound signal tremors during desorption under different conditions, confirming that the physical properties of intergranular pores are crucial factors influencing the generation of infrasound signals and their characteristics during coal and gas desorption.

The surging demand for Ni and Co, driven by the acceleration of clean energy transitions, has sparked interest in the Lachlan Orogen of New South Wales for its potential lateritic Ni–Co resources. Despite recent discoveries, a substantial knowledge gap exists in understanding the full scope of these critical metals in this geological province. This study employed a machine learning-based framework, integrating multidimensional datasets to create prospectivity maps for lateritic Ni–Co deposits within a specific Lachlan Orogen segment. The framework generated a variety of data-driven models incorporating geological (rock units, metamorphic facies), structural, and geophysical (magnetics, gravity, radiometrics, and remote sensing spectroscopy) data layers. These models ranged from comprehensive models that use all available data layers to fine-tuned models restricted to high-ranking features. Additionally, two hybrid (knowledge-data-driven) models distinguished between hypogene and supergene components of the lateritic Ni–Co mineral systems. The study implemented data augmentation methods and tackled imbalances in training samples using the SMOTE–GAN method, addressing common machine learning challenges with sparse training data. The study overcame difficulties in defining negative training samples by translating geological and geophysical data into training proxy layers and employing a positive and unlabeled bagging technique. The prospectivity maps revealed a robust spatial correlation between high probabilities and known mineral occurrences, projecting extensions from these sites and identifying potential greenfield areas for future exploration in the Lachlan Orogen. The high-accuracy models developed in this study utilizing the Random Forest classifier enhanced the understanding of mineralization processes and exploration potential in this promising region.

Deep coalbed methane (CBM) extraction shows that coal body structure (CBS) influences the original pore and permeability conditions of a coal reservoir and that it has a significant effect on CBM production. CBS prediction by using logging curves has become an important aspect in CBM reservoir engineering. In this study, we identified vertical development of CBS in coal seam 8 of the Benxi Formation in 23 wells in the Ordos Basin based on core observation. Moreover, logging curves of all coal seams were collected to study the correlation between different logging parameters and CBS, and the logging curve parameters were then optimized. Principal component analysis was used to make a comprehensive evaluation of CBS. Subsequently, factors such as structural curvature, coal seam depth, thickness and sedimentary environment were explored to investigate the main controlling factors of CBS in the Benxi Formation of Mizhi area. The results were as follows. (1) The CBS of the target coal reservoir includes primary structured coal, fragmented structured coal and mylonite coal. As the damage degree of coal structure became stronger, the volume change of micro-pores was significantly stronger than that of the meso-pore volume, and the methane adsorption capacity gradually enhanced, which is more conducive to methane adsorption. (2) Natural potential, natural gamma, acoustic time difference, compensated neutron and density logging curves of different coal structures were quite different. The identification of CBS by using dual logging parameters had poor performance. The accuracy of coal structure recognition based on principal component analysis was better. (3) The identification results of logging curves indicate that mylonite coal was widely developed in the northeast of the Mizhi area, which is related to the larger structural curvature, resulting in an increased degree of coal seam deformation. (4) The development of mylonite coal in the central and eastern regions is due to the widespread development of intertidal gray flat facies in the area. The top and bottom floors are mainly composed of limestone and mudstone, and there are two layers of interbedded gangue in the thick coal seams. Therefore, the strong heterogeneity inside the coal seams and the similar mechanical properties of the top and bottom rocks lead to the development of mylonite coal in this area.

The stress wave propagation and energy evolution of coal and rock masses under complex stress states hold significant implications for the efficient extraction of deep resources and the prevention and management of dynamic disasters. To investigate the propagation characteristics of stress waves and the energy dissipation in raw coal under true triaxial conditions, this study employed the self-constructed true triaxial split Hopkinson pressure bar test system in conjunction with a scanning electron microscope. Dynamic and static combined impact tests were conducted on raw coal samples. The findings indicate that σ₂ and σ₃ under true triaxial prestress strengthen the sample's resistance, facilitating stress wave propagation but hampering energy conversion. Both σ₂ and σ₃ enhance transmission stress and strain, increasing from 11.0 MPa and 0.53 × 10⁻⁴ in sample tr#1 to 16.3 MPa and 0.78 × 10⁻⁴ in sample tr#5. Reflected energy constitutes the largest proportion of incident energy, followed by dissipation energy, with transmission energy being the smallest. Moreover, two inflection points in the change rate of energy ratio were observed in sample tr#2 (initial increase stage of intermediate principal stress) and sample tr#4 (initial increase stage of minimum principal stress). The spectrum of the stress wave exhibited an initial increase followed by a decrease, and the peak value of the reflected wave spectrum was an order of magnitude greater than that of the transmission wave. The frequency at which the transmission wave spectrum reached the peak point and the stationary phase was lower. The macroscopic failure degree of the sample exhibited a gradual weakening trend under the influence of σ₂ and σ₃. The micro-crack fracture pattern shifted from river-like cracks to steplike cracks, eventually forming herringbone macroscopic fractures, indicating that the coal body failure under stress waves was attributed to brittle fracture.

The utilization of horizontal wells to generate cavities and induce stress release is a potent technique for increasing deep coalbed methane (CBM) production. The evolution of pore-fracture structure (PFS) during stress release is crucial for the efficient development of deep CBM. Therefore, in this study, the unloading–seeping test system, nuclear magnetic resonance and X-ray computed tomography scanning technology were combined, and a conceptual model depicting the tensile rupture conditions and permeability evolution mechanism induced by the coupling effect of unloading–seeping was formulated. The results show that the evolution of PFS in deep coal reservoirs primarily depends on the fracture mechanism of compression–tension stress conversion, which manifests as rapid fractures propagation and contraction of micropores and mesopores. As for shallow coal reservoirs, the evolution of PFS is mainly decided by the non-uniform rebound of coal matrix, with its impact on the PFS limited to expansion and rebound of the pore system. Therefore, the increase in deep coal permeability under the stress release cannot be solely attributed to “stress release–coal expansion–permeability increase.” Rather, the coupling effect of unloading–seeping induces the transformation of tensile–compressive stress, resulting in the formation of macro- and microfractures which is the key factor controlling its evolution. However, the formation of fractures can also result in instantaneous collapse and closure of mesopores, making it difficult for CBM adsorbed in micropores to be produced through mesopores. Therefore, to prevent the sudden closure of a mesoporous system, the rapid generation of large caves on the coal seam roof should be avoided.