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Investigations and Optimization of Cold Metal Transfer-based WAAM Process Parameters for Fabrication of Inconel 718 Samples using Response Surface Methodology 利用响应面方法研究和优化基于冷金属转移的 WAAM 工艺参数,以制造铬镍铁合金 718 样品
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-06 DOI: 10.1007/s13369-024-08947-1
Rajendra Prasad Meena, N. Yuvaraj, Vipin Vipin

This article outlines techniques for optimizing input parameters for the welding process, such as welding current, speed, and gas flow rate in relation to weld bead geometry and Dilution, using Response Surface Methodology (RSM). In the wire arc additive manufacturing (WAAM) process, single-weld bead stability and quality play a prominent role in the final manufactured part's quality and shape. A single-bead geometry model was initially established using RSM, and experiments were carried out using a central composite design of experiments for depositing Inconel 718 in WAAM. The design factors and responses were analyzed using multiple regression equations, and the validity of the resulting regression equations was evaluated using ANOVA. The researchers fabricated a multi-layer structure with optimal parameters, including a welding current of 210 A, 6.91 mm/s speed, and a gas flow rate of 25 l/min. Optical microscopy characterized the microstructures, revealing small dendritic grains in the top layer, equiaxed in the middle and side regions, and columnar in the lower region. The current study benefits industrial applications for developing the Inconel 718 superalloy WAAM structure.

本文概述了利用响应面方法学(RSM)优化焊接工艺输入参数的技术,例如与焊珠几何形状和稀释度相关的焊接电流、速度和气体流速。在线弧快速成型制造(WAAM)工艺中,单焊珠的稳定性和质量对最终制造部件的质量和形状起着重要作用。最初使用 RSM 建立了单焊珠几何模型,并使用中心复合实验设计对在 WAAM 中沉积 Inconel 718 进行了实验。使用多元回归方程分析了设计因素和响应,并使用方差分析评估了所得回归方程的有效性。研究人员以最佳参数制造了多层结构,包括 210 A 的焊接电流、6.91 mm/s 的速度和 25 l/min 的气体流速。光学显微镜对微结构进行了表征,发现顶层为小树枝状晶粒,中间和侧面区域为等轴晶粒,下层区域为柱状晶粒。目前的研究有利于开发 Inconel 718 超级合金 WAAM 结构的工业应用。
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引用次数: 0
An FPGA-Based Balancing of Capacitor Voltage for a Five-Level CHB Inverter 基于 FPGA 的五级 CHB 逆变器电容器电压平衡方法
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-06 DOI: 10.1007/s13369-024-08972-0
Rajanikanta Sahoo, Molay Roy

This paper presents a unique five-level inverter consisting of one DC voltage source and one capacitor. Here the capacitor acts like another source and is fed to the inverter along with the DC voltage source. The DC voltage source is also used to charge the capacitor with the help of an additional switch used inside the converter circuit. An inductor is used in the charging path to reduce the peak of the charging current. The in-phase disposition sinusoidal pulse-width modulation technique is used to generate the gate pulse for the devices of the presented converter. The proposed topology operates in two modes. One is energy stored mode and another is energy release mode. By using both modes of operation, the additional switch is triggered to charge the capacitor. The capacitor’s charging and discharging mode and inverter power loss have been described thoroughly in this paper. The proposed five-level inverter topology has been developed and verified inside the laboratory. The controller of the converter has been implemented in the FPGA platform. The experimental results are obtained to evaluate the efficacy of the proposed inverter.

本文介绍了一种独特的五电平逆变器,由一个直流电压源和一个电容器组成。在这里,电容器就像另一个电源,与直流电压源一起馈入逆变器。直流电压源还借助转换器电路内部的附加开关为电容器充电。充电路径中使用了一个电感器,以降低充电电流的峰值。同相配置正弦脉宽调制技术用于为该转换器的设备生成栅极脉冲。所提出的拓扑结构可在两种模式下运行。一种是能量存储模式,另一种是能量释放模式。通过使用这两种工作模式,额外的开关被触发为电容器充电。本文对电容器的充电和放电模式以及逆变器的功率损耗进行了详细描述。本文提出的五电平逆变器拓扑结构已在实验室内开发和验证。转换器的控制器已在 FPGA 平台上实现。实验结果评估了拟议逆变器的功效。
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引用次数: 0
MHD Effects on the Peristaltic Transport of Non-Newtonian Eyring–Powell Fluid with Heat and Mass Transfer in an Inclined Uniform Channel MHD 对非牛顿艾林-鲍威尔流体在倾斜均匀通道中热量和质量传递的蠕动传输的影响
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-05 DOI: 10.1007/s13369-024-08920-y
Manjunatha Gudekote, Rajashekhar Choudhari, Prathiksha Sanil, Balachandra Hadimani, Hanumesh Vaidya, Kerehalli Vinayaka Prasad

The primary focus of the current study is to examine the effect of magnetohydrodynamics on the peristaltic motion of Eyring–Powell fluid. The Navier–Stokes equations, renowned for their intricate nature, form the foundation of the mathematical model utilised in this investigation. However, the model has been simplified through specific assumptions to facilitate analysis. The model assumes explicitly a long wavelength and a low Reynolds number. This study also investigates the effect of wall characteristics on peristalsis in the presence of a magnetic field. Additionally, variable liquid properties such as varying viscosity and thermal conductivity are also considered in the study. The governed nonlinear equations are solved with multiple slip conditions to obtain the velocity, temperature, concentration and streamline profiles. Different waveforms on velocity profiles are also studied. A parametric evaluation makes the analysis more accessible, and the results are graphically depicted using MATLAB R2023a software. The findings of this study shed light on the substantial impact of the magnetic parameter and varying viscosity on fluid properties.

当前研究的主要重点是研究磁流体力学对艾林-鲍威尔流体蠕动的影响。纳维-斯托克斯方程以其错综复杂的性质而闻名,它构成了本研究中使用的数学模型的基础。不过,为了便于分析,该模型通过特定假设进行了简化。模型明确假设了长波长和低雷诺数。本研究还探讨了在磁场存在的情况下,壁面特征对蠕动的影响。此外,研究中还考虑了不同的液体特性,如不同的粘度和热导率。在多重滑移条件下求解受控非线性方程,以获得速度、温度、浓度和流线剖面。还研究了速度剖面上的不同波形。参数评估使分析更易于理解,并使用 MATLAB R2023a 软件对结果进行了图形描述。这项研究的结果阐明了磁性参数和不同粘度对流体特性的重大影响。
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引用次数: 0
Tailoring the Microstructure using Quenching and Partitioning Processing in a Commercial Mn-Si-Cr Spring Steel to Improve Tensile Properties 在商用锰硅铬弹簧钢中使用淬火和分层工艺调整微观结构以改善拉伸性能
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-05 DOI: 10.1007/s13369-024-08888-9
Mohammad Masoumi, Dany Michell Andrade Centeno, Edwan Anderson Ariza Echeverri

This study explores a novel approach to quenching and partitioning (Q&P) heat treatment applied to AISI 9260 spring steel, comprising Fe-0.65C-1.58Mn-1.05Si-0.41Cr (wt.%). Our research focuses on balancing strength and ductility through optimized Q&P pathways, leading to a diverse microstructure that includes martensite, bainite, carbide, and retained austenite. Advanced X-ray diffraction and scanning electron microscopy techniques were employed to analyze the complexities of this microstructure. A key aspect of this study is the precise control of partitioning temperature and time, crucial for modulating lattice distortion and dislocation density within martensitic and bainitic structures. Optimal partitioning temperature promotes carbon distribution into austenite, tempering lattice distortions, and dislocation densities. Concurrently, carbide precipitation and segregation contribute to the refinement of the bainite phase. The sample quenched at 125 °C and partitioned at 350 °C (Q&P-125/350) demonstrates notable mechanical properties: a yield strength of 950 ± 15 MPa, an ultimate tensile strength of 1710 ± 15 MPa, and an elongation of approximately 9.7%. These results are partly attributed to the effect of silicon in preventing cementite coarsening and the effective distribution of carbide. Our findings highlight the potential of Q&P heat treatment in developing tailored microstructures with enhanced mechanical properties in steel, without relying on costly alloying elements. This approach presents new avenues for the design and application of high-performance materials.

本研究探索了一种新的淬火和分区(Q&P)热处理方法,该方法适用于 AISI 9260 弹簧钢,其成分为 Fe-0.65C-1.58Mn-1.05Si-0.41Cr(重量百分比)。我们的研究重点是通过优化 Q&P 途径平衡强度和延展性,从而获得包括马氏体、贝氏体、碳化物和残余奥氏体在内的多样化微观结构。我们采用了先进的 X 射线衍射和扫描电子显微镜技术来分析这种微观结构的复杂性。这项研究的一个关键方面是精确控制分割温度和时间,这对调节马氏体和贝氏体结构中的晶格畸变和位错密度至关重要。最佳的分割温度可促进碳分布到奥氏体、回火晶格畸变和位错密度。同时,碳化物的析出和偏析有助于贝氏体相的细化。在 125 °C 下淬火并在 350 °C 下分割的样品(Q&P-125/350)具有显著的机械性能:屈服强度为 950 ± 15 MPa,极限抗拉强度为 1710 ± 15 MPa,伸长率约为 9.7%。这些结果部分归功于硅在防止雪明碳酸盐粗化和碳化物有效分布方面的作用。我们的研究结果凸显了 Q&P 热处理在开发具有增强钢材机械性能的定制微结构方面的潜力,而无需依赖昂贵的合金元素。这种方法为高性能材料的设计和应用提供了新的途径。
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引用次数: 0
A Computational Investigation of the Influence of Seafloor Conditions on the Turbulent Flow Characteristics of an Autonomous Underwater Vehicle 海底条件对自主潜水器湍流特性影响的计算研究
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-04 DOI: 10.1007/s13369-024-08946-2
Mahdi Tabatabaei Malazi, Sergen Tumse, Muammer Ozgoren, Besir Sahin

The effect of the seabed on the hydrodynamics of three-dimensional autonomous underwater vehicles (AUVs) varies according to the physical conditions of the place where AUVs interact with the environmental conditions. This study examines the hydrodynamics of an AUV resembling a torpedo model while taking the influence of the seabed surface as a function of the dimensionless distances (G/D) between the torpedo and the seabed. Reynolds numbers, varying from 1 × 104 to 8 × 104, were considered. These Reynolds numbers were associated with various seabed distances falling within 0.25 ≤ G/D ≤ 1.5. To perform the simulations, governing equations were utilized and incorporated with the k–ω SST turbulence model. It has been observed that when AUVs or torpedo models operate in close proximity to the seabed surface, several key hydrodynamic parameters and flow characteristics are affected. These include the pressure coefficient (Cp), drag coefficient (CD), overall flow structures, maneuverability, and performance of the torpedo model. As the AUV or torpedo model approaches the seabed surface, the symmetrical flow pattern deteriorates. This deterioration is associated with changes in vortical flow structures under the influence of seabed surfaces. Additionally, the intensity of the shear stress (τ) near the seabed surface gradually increases as the AUV or torpedo model gets closer to it. In summary, the proximity of AUVs or torpedo models to the seabed surface causes disruptions in the flow patterns, increased shear stress, and alterations in key hydrodynamic parameters, ultimately affecting the system's performance and behavior.

海底对三维自主潜航器(AUV)流体力学的影响因 AUV 与环境条件相互作用的地点的物理条件而异。本研究考察了类似鱼雷模型的自动潜航器的流体力学,同时将海床表面的影响作为鱼雷与海床之间无量纲距离(G/D)的函数。考虑的雷诺数从 1 × 104 到 8 × 104 不等。这些雷诺数与 0.25 ≤ G/D ≤ 1.5 范围内的各种海底距离相关联。在进行模拟时,利用了 k-ω SST 湍流模型中的控制方程。据观察,当自动潜航器或鱼雷模型靠近海底表面运行时,几个关键的流体力学参数和流动特性会受到影响。这些参数包括压力系数 (Cp)、阻力系数 (CD)、整体流动结构、机动性以及鱼雷模型的性能。当自动潜航器或鱼雷模型接近海床表面时,对称流动模式会恶化。这种恶化与海床表面影响下的涡流结构变化有关。此外,随着 AUV 或鱼雷模型逐渐靠近海床表面,海床表面附近的剪应力强度(τ)也会逐渐增加。总之,自动潜航器或鱼雷模型靠近海床表面会导致流动模式紊乱、剪应力增加以及关键流体力学参数的改变,最终影响系统的性能和行为。
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引用次数: 0
Optimal Prediction for Patch Design Using YUKI-RANDOM-FOREST in a Cracked Pipeline Repaired with CFRP 利用 YUKI-RANDOM-FOREST 对使用 CFRP 修复的开裂管道进行补丁设计的最佳预测
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-04 DOI: 10.1007/s13369-024-08777-1
Abdelmoumin Oulad Brahim, Roberto Capozucca, Samir Khatir, Noureddine Fahem, Brahim Benaissa, Thanh Cuong-Le

This paper presents the effectiveness of a hybrid YUKI-RANDOM-FOREST, Particle Swarm Optimization-YUKI (PSO-YUKI), and balancing composite motion optimization algorithm (BCMO) based on artificial neural networks (ANN) for the best prediction of patch design considering the maximum principal stress. The study compares the maximum principal stress in a damaged pipe under different composite patch designs. Robust models have been developed and utilized in various applications. The research investigates the influence of cracks on the mechanical characteristics of API X70 steel in a test pipe under critical pressure. The numerical model employs the extended finite element method (XFEM) to simulate notches. Extending the optimization technique, the study examines the effect of crack presence in a pipeline section under internal pressure without and with composite repairs on the maximum principal stress. The sensitivity of stress is analyzed with respect to the design parameters of the composite patch. Finally, YUKI-RANDOM-FOREST, NN-PSO-YUKI, and NN-BCMO, with different parameters and hidden layer sizes are employed to predict the maximum principal stress under different composite patch designs, and yielding minimal error. Once the database was built, our model was prepared to predict various situations at the composite patch level. Compared to other methods, the obtained results with hybrid YUKI-RANDOM-FOREST are effective. The investigation technique is relevant to real-world engineering applications, structural safety control, and design processes.

本文介绍了基于人工神经网络(ANN)的混合 YUKI-RANDOM-FOREST、粒子群优化-YUKI(PSO-YUKI)和平衡复合运动优化算法(BCMO)对考虑最大主应力的补片设计进行最佳预测的有效性。该研究比较了不同复合材料补片设计下受损管道的最大主应力。已开发出鲁棒性模型并将其用于各种应用中。研究调查了在临界压力下,裂缝对 API X70 钢管机械特性的影响。数值模型采用扩展有限元法 (XFEM) 模拟缺口。该研究扩展了优化技术,考察了在无复合材料修复和有复合材料修复的情况下,内压下管道断面中裂纹的存在对最大主应力的影响。分析了应力对复合材料修补设计参数的敏感性。最后,采用了 YUKI-RANDOM-FOREST、NN-PSO-YUKI 和 NN-BCMO(具有不同的参数和隐藏层大小)来预测不同复合材料修补设计下的最大主应力,并将误差降到最低。数据库建立后,我们的模型就可以预测复合材料贴片层面的各种情况。与其他方法相比,混合 YUKI-RANDOM-FOREST 方法的结果非常有效。该研究技术与现实世界的工程应用、结构安全控制和设计过程息息相关。
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引用次数: 0
Incorporation of Nonlinear Control and SOSM Controller with Improved PSO Algorithm for OEWIM Fed by SVM Seven-Level Dual Inverter 利用改进的 PSO 算法为 SVM 七级双逆变器供电的 OEWIM 引入非线性控制和 SOSM 控制器
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-03 DOI: 10.1007/s13369-024-08894-x
Mohamed Lamine Ladjel, Abdelhakim Dendouga

This paper proposes a combination of a nonlinear feedback linearization control (FLC) and a second-order sliding mode (SOSM) controller to enhance the effectiveness and performance of variable speed control in an open-ended winding induction motor (OEWIM). The literature indicates that the traditional FLC with a PI controller is susceptible to disruptions from its internals as well as outside interference. The conventional sliding-mode controller can offer robust control. However, it suffers from the chattering phenomenon. The SOSMC, based on a super-twisting algorithm (STA), was designed and implemented to overcome all of these drawbacks. It is extremely difficult to obtain the optimum parameters for each FLC and SOSM controller that give good results using traditional methods due to the relatively large number of parameters. Moreover, a novel approach based on the linearly decreasing method for both inertia weight and learning constant of the particle swarm optimization (PSO) algorithm was presented to improve the variable speed control of the OEWIM. To maintain a constant switching frequency, decrease harmonic distortion, and reduce common-mode voltage (CMV), a space vector modulation technique of a seven-level inverter is suggested and implemented by supplying each end of an open-ended stator winding induction motor with three-level inverters. The advantages of the suggested control system have been confirmed using simulated results of various tests of the complete system.

本文提出了一种非线性反馈线性化控制(FLC)和二阶滑动模式(SOSM)控制器的组合,以提高开口绕组感应电机(OEWIM)变速控制的效果和性能。文献表明,传统的带有 PI 控制器的 FLC 容易受到其内部和外部干扰的影响。传统的滑动模式控制器可以提供稳健的控制。然而,它也存在颤振现象。基于超扭曲算法(STA)的 SOSMC 的设计和实施克服了所有这些缺点。由于参数相对较多,使用传统方法很难获得每个 FLC 和 SOSM 控制器的最佳参数,从而获得良好效果。此外,为改进 OEWIM 的变速控制,提出了一种基于惯性权重和粒子群优化算法学习常数线性递减法的新方法。为了保持恒定的开关频率、减少谐波失真和降低共模电压 (CMV),提出了七电平逆变器的空间矢量调制技术,并通过为开口定子绕组感应电动机的两端提供三电平逆变器来实现。通过对整个系统进行各种测试的模拟结果,证实了所建议控制系统的优势。
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引用次数: 0
Enhancing Heavy Crude Oil Flowability Using Vegetable Sesame Oil Extract as Bio-additives 利用植物芝麻油提取物作为生物添加剂提高重质原油流动性
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-03 DOI: 10.1007/s13369-024-08953-3
Asaad Salim Bded, Mohd Azmier Ahmad

The present study evaluated the effectiveness of a blend of dimethyl ketone (DMK) and methyl esters extracted from vegetable sesame oil (VSO) as a flow improver. The rheological impact of the additive on crude oil was assessed at various ratios (500, 1000, and 1500 ppm), shear rates (1.86–233 s−1), and temperatures (5–30 °C). This study employed three models, Bingham plastic, power law, and Herschel–Bulkley, to evaluate the experimental data and determine the consistency factor and flow index of the oil samples considered. The average viscosity reduction (VR), thermal effects, activation energy, and yield stress of the additive were also assessed. The findings revealed that the blend enhanced crude oil flowability at low temperatures. Furthermore, at 1500 ppm and 1.86 and 46.5 s−1 shear rates, the viscosity was diminished to 90.5% and 89.8%, respectively. The viscosity reduction was more significant at and over 100 s−1 shear rates at temperatures up to 30 °C. Increasing dosage and temperature decreased yield stress and activation energy, (E_{{text{a}}}), which reached 30.479 kJ mol−1. The experimental data obtained in this study fitted the Herschel–Bulkley and power law models, approaching Newtonian behaviour at 1000 ppm. Moreover, the consistency index (k) of the crude oil incorporated with the additive diminished to 0.10386 and 0.029712, respectively. At 1500 ppm, the flow behaviour index (n) of the crude oil improved to 0.9665 and 0.9894 at 5 °C and 30 °C, respectively. The results demonstrated that the additive derived from natural seeds was an eco-friendly alternative flow improver.

本研究评估了从植物芝麻油(VSO)中提取的二甲基酮(DMK)和甲酯混合物作为流动性改进剂的效果。在不同的比例(500、1000 和 1500 ppm)、剪切速率(1.86-233 s-1)和温度(5-30 °C)条件下,评估了添加剂对原油流变性的影响。本研究采用了宾汉塑性、幂律和赫歇尔-布克利三种模型来评估实验数据,并确定所考虑油样的稠度系数和流动指数。此外,还评估了添加剂的平均粘度降低率(VR)、热效应、活化能和屈服应力。研究结果表明,混合添加剂增强了原油在低温下的流动性。此外,在 1500 ppm、1.86 和 46.5 s-1 的剪切速率下,粘度分别降低到 90.5% 和 89.8%。在温度高达 30 °C、剪切速率超过 100 s-1 时,粘度的降低更为显著。增加用量和温度会降低屈服应力和活化能(E_{text{a}}),达到 30.479 kJ mol-1。本研究获得的实验数据符合赫歇尔-布克利模型和幂律模型,在 1000 ppm 时接近牛顿行为。此外,添加了添加剂的原油的稠度指数(k)分别降至 0.10386 和 0.029712。在 1500 ppm 时,原油在 5 °C 和 30 °C 下的流动性指数(n)分别提高到 0.9665 和 0.9894。结果表明,从天然种子中提取的添加剂是一种环保型流动性改进剂。
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引用次数: 0
Synergistic Effects of Carbon Nanotubes (CNTs) and White Graphite (h-BN) on the Microstructure and Mechanical Properties of Aluminum Matrix Composites 碳纳米管(CNT)和白石墨(h-BN)对铝基复合材料微观结构和力学性能的协同效应
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-03 DOI: 10.1007/s13369-024-08903-z
Muhammad Awais Khan, Atteeq Uz Zaman, Khurram Imran Khan, Muhammad Ramzan Abdul Karim, Azhar Hussain, Ehsan ul Haq

The increased demand for lightweight structural materials in the transport sector has compelled researchers to develop materials with high strength and reduced structural weight, aiming to enhance vehicle performance, minimize fuel and oil consumption and reduce CO2 emissions. However, their structural weight and strength still need to be improved. Herein, an attempt has been made to fabricate aluminum-based composites reinforced with hexagonal boron nitride (h-BN: 1,3,5,7 wt% ) and multi-walled carbon nanotubes (MWCNTs: 0.25, 0.5, 0.75, 1 wt%) through powder processing method. The results revealed that the 3BN/Al composite disclosed better densification (96.8%) and hardness (49 ± 1.5) among all BN/Al composites. Furthermore, the addition of 0.5 wt% CNTs to BN/Al composite significantly improved the densification (97.7%), Vickers hardness (106%) and tensile strength (189%) over pure Al. This improvement was attributed to homogeneously distributed h-BN and CNTs in the Al matrix and the formation of hard aluminum carbide (Al4C3) phase. The results demonstrate that BN/CNTs/Al composite exhibits superior mechanical strength, making them promising structural and functional materials for aerospace and automobile industries.

运输业对轻质结构材料的需求日益增加,迫使研究人员开发强度高、结构重量轻的材料,以提高汽车性能,最大限度地减少燃料和石油消耗,降低二氧化碳排放。然而,这些材料的结构重量和强度仍有待提高。在此,我们尝试通过粉末加工方法,制造出用六方氮化硼(h-BN:1,3,5,7 wt%)和多壁碳纳米管(MWCNTs:0.25, 0.5, 0.75, 1 wt%)增强的铝基复合材料。结果表明,在所有 BN/Al 复合材料中,3BN/Al 复合材料具有更好的致密性(96.8%)和硬度(49 ± 1.5)。此外,与纯铝相比,在 BN/Al 复合材料中添加 0.5 wt% 的 CNT 可显著提高致密性(97.7%)、维氏硬度(106%)和拉伸强度(189%)。这种改善归功于 h-BN 和 CNT 在铝基体中的均匀分布以及硬碳化铝(Al4C3)相的形成。研究结果表明,BN/CNTs/Al 复合材料具有优异的机械强度,因此有望成为航空航天和汽车行业的结构和功能材料。
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引用次数: 0
Zinc-Doping as a Strategy to Enhance Antimicrobial and Dye Degradation Properties of Magnesium Oxide Nanoparticles Sythesized from Sauropus androgynus (L.) Phytochemicals 以锌掺杂为策略,增强由 Sauropus androgynus (L.) 植物化学物质合成的氧化镁纳米粒子的抗菌和染料降解特性
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-02 DOI: 10.1007/s13369-024-08968-w
Josline Neetha D’Souza, G. K. Nagaraja, Meghana K. Navada, Sabia Kouser

The present work was designed to study the influence of zinc doping on the structural, biological and dye degradation properties of biogenic magnesium oxide nanoparticles (MgOSA NPs). Pure MgOSA and zinc doped MgOSA NPs were synthesized using S. androgynus leaf extract as fuel. The obtained NPs were scrutinized for their morphological and surface properties through various techniques. The results of FTIR, FESEM, HRTEM and EDS studies accompanied by elemental mapping analysis evidenced the formation of targeted NPs. Whereas the PXRD analysis substantiated the formation of pure and zinc doped NPs with crystallite size 24.29 and 17.47 nm respectively. Additionally, the refinement of obtained PXRD data through Rietveld refinement corroborated the changes in cell parameters after zinc doping. The BET analysis performed divulged the mesoporous nature of NPs having surface areas 30.245 and 10.058 m2g−1 respectively. The biocompatibility of NPs was confirmed via in-vitro anti-inflammatory study which exhibited % HRBCS up to 85.38 ± 0.003 and 87.42 ± 0.005 for MgOSA and ZnMgOSA NPs. The glucose-lowering potentiality via α-amylase inhibition assay manifested the appreciable in-vitro antidiabetic property of synthesized NPs (76.79 ± 0.001 and 77.24 ± 0.0005%). Also, the NPs exhibited antibacterial activity against Pseudomonas syringae, Escherichia coli, Pseudomonas aeroginosa, Staphylococcus aureus and Bacillus subtulis. Furthermore, the photocatalytic experiments performed on Methylene Blue dye have revealed an excellent degradation efficiency of MgOSA and ZnMgOSA NPs with high stability and reusability.

本研究旨在研究锌掺杂对生物源氧化镁纳米粒子(MgOSA NPs)的结构、生物和染料降解特性的影响。本研究以雄黄叶提取物为燃料,合成了纯 MgOSA 和掺锌 MgOSA NPs。通过各种技术对所获得的 NPs 的形态和表面特性进行了研究。傅立叶变换红外光谱(FTIR)、场发射电子显微镜(FESEM)、高分辨率场发射电子显微镜(HRTEM)和电致发光分析(EDS)的研究结果以及元素图谱分析证明了目标 NPs 的形成。而 PXRD 分析证实了纯 NPs 和掺锌 NPs 的形成,结晶尺寸分别为 24.29 纳米和 17.47 纳米。此外,通过里特维尔德细化法对获得的 PXRD 数据进行细化,证实了掺锌后电池参数的变化。进行的 BET 分析表明,NPs 具有介孔性质,其表面积分别为 30.245 和 10.058 m2g-1。体外抗炎研究证实了 NPs 的生物相容性,MgOSA 和 ZnMgOSA NPs 的 HRBCS% 分别达到 85.38 ± 0.003 和 87.42 ± 0.005。通过α-淀粉酶抑制实验进行的降糖潜力研究表明,合成的 NPs 具有显著的体外抗糖尿病特性(76.79 ± 0.001 和 77.24 ± 0.0005%)。此外,这些 NPs 还对丁香假单胞菌、大肠杆菌、绿脓杆菌、金黄色葡萄球菌和枯草芽孢杆菌具有抗菌活性。此外,对亚甲蓝染料进行的光催化实验表明,MgOSA 和 ZnMgOSA NPs 具有极佳的降解效率、高稳定性和可重复使用性。
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Arabian Journal for Science and Engineering
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