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Smart Crosslinked Polymer Gels for Water Shutoff in Oil Reservoir: A Comprehensive Review on Materials, Mechanisms, and Field Applications 用于油藏堵水的智能交联聚合物凝胶:材料、机理和现场应用综述
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-09-04 DOI: 10.1007/s13369-025-10595-y
Parth Parmar, Bhaskarjyoti Khanikar, Rahul Saha, Lakhsmanarao Jeeru, Akhil Agarwal, Achinta Bera

Excess production of water from oil and gas reservoirs is one of the major concerns in the hydrocarbon industry because of the handling of unwanted produced water uneconomically. Polymer gel treatment can be considered as one of the remedies to control excess water production. This review presents a detailed discussion on advancements in research for crosslinked polymer gel systems, covering their mechanisms, types, and field applications. Mainly in situ crosslinked gels, preformed particle gels, foamed gels, and nanoparticle-enhanced gels were examined with a focus on their stability and efficiency. The importance of these systems in profile modification and water shutoff was highlighted. Different factors affecting polymer gel systems like high temperature and high-salinity environments, types of accelerators, pH, polymer concentration, gel degradation, injectivity control, and types of nanoparticles were discussed in detail. New technologies, such as resin-based gels and hybrid crosslinked systems, were introduced. The kinetics of the polymer gel formation and its gelation time control mechanisms were also deliberated. The main focus of the review is on how feasible the modification of polymer gels can be in water shutoff over field application, permeability modification, and conformance control. A comparative analysis of various global projects utilizing polymer gel systems was conducted to assess their real-world applications.

由于不经济地处理不需要的产出水,油气储层的过量产出水是油气行业关注的主要问题之一。聚合物凝胶处理可以被认为是控制过量产水的补救措施之一。本文综述了交联聚合物凝胶体系的研究进展,包括交联聚合物凝胶体系的机理、类型和现场应用。主要考察了原位交联凝胶、预成型颗粒凝胶、泡沫凝胶和纳米颗粒增强凝胶的稳定性和效率。强调了这些系统在剖面修正和堵水方面的重要性。详细讨论了影响聚合物凝胶体系的不同因素,如高温和高盐度环境、促进剂类型、pH、聚合物浓度、凝胶降解、注入性控制和纳米颗粒类型。介绍了树脂基凝胶和杂化交联体系等新技术。探讨了聚合物凝胶形成动力学及其凝胶时间控制机理。本次综述的主要重点是聚合物凝胶的改性在堵水、渗透率改性和井眼控制方面的可行性。对利用聚合物凝胶体系的各种全球项目进行了比较分析,以评估其实际应用。
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引用次数: 0
Meerkat-Optimized SENet Approach: Advancements in Retinal Fundus Image Augmentation and Classification 猫鼬优化SENet方法:视网膜眼底图像增强和分类的进展
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-26 DOI: 10.1007/s13369-025-10548-5
Annapareddy V. N. Reddy, Pradeep Kumar Mallick, Sachin Kumar, Debahuti Mishra, P. Ashok Reddy, Sambasivarao Chindam

This manuscript explores the dynamic field of retinal fundus image classification, harnessing diverse machine and deep learning (DL) techniques. It emphasizes the transformative potential of transformer-based architectures, originally designed for natural language processing, in reshaping image classification tasks. These architectures excel in capturing long-range dependencies within images, enhancing the comprehension of complex patterns. The research addresses the persistent challenge of limited training data by introducing innovative data augmentation strategies. A pioneering stacked augmentation approach, incorporating DL-based techniques, refines images at the pixel level, producing nuanced augmented counterparts. Notably, this approach systematically stacks augmented images along the third dimension, enhancing model accuracy while significantly reducing the sample size, expediting the training process. Additionally, the manuscript introduces the Meerkat optimizer, a cooperative multi-agent optimization technique, to enhance the classification accuracy of the squeeze-and-excitation network (SENet). Inspired by Meerkat social behavior, this optimization strategy navigates the solution space efficiently, leading to robust model configurations. Comparative evaluations with traditional optimization techniques validate the superior performance of Meerkat-optimized SENet. In a broader context, the study sheds light on the nuanced behaviors of various transformer networks in retinal fundus image classification, including pyramid vision transformer, bottleneck transformer, convolutional vision transformer, swin transformer, ViT, spatial transformer network (STNet), and SENet. Furthermore, an in-depth analysis of augmentation insights highlights consistent performance improvement across transformer networks when coupled with DL-based augmentation. SENet emerges as a standout performer, showcasing exceptional learning and generalization in diverse augmentation scenarios and datasets. The investigation into decision variables optimization for SENet through the Meerkat optimizer provides detailed insights into the network's behavior, including the selection of squeeze type ((S)), excitation operator ((E)), and reduction ratio ((r)), showcasing the adaptability and efficiency of the Meerkat optimization strategy.

本文探讨了视网膜眼底图像分类的动态领域,利用各种机器和深度学习(DL)技术。它强调了最初为自然语言处理设计的基于转换器的架构在重塑图像分类任务中的变革潜力。这些体系结构擅长于捕获图像中的远程依赖关系,增强对复杂模式的理解。该研究通过引入创新的数据增强策略来解决训练数据有限的持续挑战。一种开创性的堆叠增强方法,结合基于dl的技术,在像素级别上细化图像,产生细微的增强对应。值得注意的是,这种方法系统地沿着第三维叠加增强图像,在显著减少样本量的同时提高了模型精度,加快了训练过程。此外,本文还介绍了Meerkat优化器,一种多智能体协作优化技术,以提高挤压-激励网络(SENet)的分类精度。受Meerkat社会行为的启发,这种优化策略可以有效地导航解决方案空间,从而实现健壮的模型配置。通过与传统优化技术的对比评估,验证了meerkat优化SENet的优越性能。在更广泛的背景下,本研究揭示了各种变压器网络在视网膜眼底图像分类中的细微行为,包括金字塔视觉变压器、瓶颈变压器、卷积视觉变压器、旋转变压器、ViT、空间变压器网络(STNet)和SENet。此外,对增强洞察的深入分析强调了在与基于dl的增强相结合时,整个变压器网络的一致性能改进。SENet表现出色,在不同的增强场景和数据集中展示了卓越的学习和泛化能力。通过Meerkat优化器对SENet的决策变量优化进行研究,详细了解了网络的行为,包括挤压类型((S))、激励算子((E))和约简比((r))的选择,展示了Meerkat优化策略的适应性和效率。
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引用次数: 0
Impact of Temperature and MgO on Cordierite Ceramics Prepared Through Conventional Reaction Sintering of Nano-powders of Al2O3, SiO2, and MgO 温度和MgO对Al2O3、SiO2和MgO纳米粉体常规反应烧结制备堇青石陶瓷的影响
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-25 DOI: 10.1007/s13369-025-10570-7
N. Saheb, S. F. Hassan, R. Mahgoub, K. Djilat, F. Sahnoune, E. Dhahri

This study examined, for the first time, the impact of excess magnesia (0–8 wt%) on phase formation and transformation in non-stoichiometric cordierite ceramics prepared through conventional reaction sintering of nano-powders of Al2O3, SiO2, and MgO. Diffraction and thermal analysis methods were used to characterize the formed phases and their subsequent transformations. Activation energy (Ea) values for the formation of enstatite and cordierite were determined through non-isothermal analysis using the Kissinger equation. The density, coefficient of thermal expansion (CTE), and hardness of sintered samples were measured using a densimeter, dilatometer, and hardness tester, respectively. Additionally, the fracture surface of sintered specimens was characterized using a field emission scanning electron microscope (FE-SEM) coupled with energy dispersive spectroscopy (EDS). It was found that the temperatures at which enstatite and cordierite form increase with heating rate and decrease with the increase in excess magnesia. The formation of enstatite in sample (MAS0M) requires an activation energy of 655 kJ mol−1. This energy increased to 748 and 698 kJ mol−1 for samples MAS2M and MAS4M, and then decreased to 644 and 645 kJ mol−1 for samples MAS8M and MAS8M. The formation of α-cordierite in sample MAS0M requires an activation energy of 684 kJ mol−1. This energy increases to 869, 904, 950, and 894 kJ mol−1 for samples MAS2M, MAS4M, MAS6M, and MAS8M. The prepared materials demonstrated similar phase transformations, ultimately resulting in the formation of α-cordierite single phase from the alumina-silica-magnesia powder mixture of stoichiometric composition. Cordierite, sapphirine, and enstatite were formed in the mixtures with an excess of magnesia. The bulk density of samples sintered at 1350 °C for 2 h increased from 2.58 to 2.88 g cm−3 as the excess magnesia content increased from 0 to 8 wt%, and the CTE also increased from 1.16 × 10–6 to 2.53 × 10–6 K−1. The sample with 4 wt% excess magnesia exhibited the highest hardness of 10 GPa.

本研究首次考察了过量氧化镁(0-8 wt%)对Al2O3、SiO2和MgO纳米粉体常规反应烧结制备的非化学计量堇青石陶瓷相形成和转变的影响。采用衍射和热分析方法表征了所形成的相及其随后的转变。采用Kissinger方程,通过非等温分析确定了顽辉石和堇青石形成的活化能。用密度计、膨胀仪和硬度计分别测定烧结试样的密度、热膨胀系数(CTE)和硬度。此外,利用场发射扫描电镜(FE-SEM)和能谱仪(EDS)对烧结试样的断口形貌进行了表征。结果表明,长辉石和堇青石的形成温度随升温速率升高而升高,随过量镁含量的增加而降低。样品(MAS0M)中顽辉石的形成需要655 kJ mol−1的活化能。MAS2M和MAS4M样品的能量分别为748和698 kJ mol−1,MAS8M和MAS8M样品的能量分别为644和645 kJ mol−1。样品MAS0M中α-堇青石的形成需要684 kJ mol−1的活化能。对于样品MAS2M、MAS4M、MAS6M和MAS8M,该能量分别增加到869,904,950和894 kJ mol−1。制备的材料表现出相似的相变,最终由化学计量组成的铝-硅-镁粉混合物形成α-堇青石单相。堇青石、蓝宝石和顽辉石是在过量氧化镁的混合物中形成的。当过量镁含量从0 wt%增加到8 wt%时,试样在1350℃下烧结2 h后的容重从2.58 g cm−3增加到2.88 g cm−3,CTE也从1.16 × 10-6增加到2.53 × 10-6 K−1。镁含量过量4 wt%的试样硬度最高,达10 GPa。
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引用次数: 0
Analyzing Heat Transfer and Irreversibility via Aggregation Dynamics in Darcy-Forchheimer Flow and Nonlinear Thermal Radiation Effects Utilizing Artificial Neural Networks 利用人工神经网络分析Darcy-Forchheimer流聚集动力学中的传热和不可逆性及非线性热辐射效应
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-21 DOI: 10.1007/s13369-025-10547-6
Zafar Mahmood, Khadija Rafique, Mushtaq Ahmad Ansari, Naveed Ahmed, Umar Khan, Abhinav Kumar

Artificial neural networks (ANNs) are becoming more popular because they can solve complex, nonlinear mathematical problems. The complicated domains of biotechnology, fluid dynamics, and cellular computation all find applications for artificial neural networks. This study uses machine learning techniques to analyze heat transfer and entropy production in unsteady ({text{TiO}}_{2}/text{EG}) nanofluid flow, taking into account nonlinear thermal radiation, Darcy–Forchheimer effects, and mass suction on a spinning sphere. This study examines aggregation and non-aggregation phenomena in terms of dynamic viscosity and thermal conductivity. Skin friction coefficient, heat transfer rate, entropy generation, velocity, and temperature-related nonlinear versions of classic mathematical problems may be solved using the bvp4c solver in MATLAB. Data selection, network creation, training, and performance evaluation using the mean square error metric are all part of the model's artificial neural network architecture. Tables and graphics demonstrate the impact of parameters on subjective profiles. The velocity profile in the x-direction increases with nanoparticle volume fraction (phi), unsteadiness (A), porous media permeability (K,) and magnetic parameter (M), but decreases with the Darcy–Forchheimer coefficient (delta) parameter. The z-direction velocity profile declines with increasing (phi , A, K, M) and (delta). As (A) grows, the temperature profile lowers, but bigger values of the radiation parameter, Biot number, Eckert number, and temperature ratio parameter increase. Skin friction in the x-direction increases with higher ((K, M, phi), and (S)) but decreases with (delta). Similarly, skin friction in the z-direction rises with higher values of (K, phi , M, delta .) As (Ec) increases, the local Nusselt number decreases and rises with (Bi, phi , Rd), and ({theta }_{w}.) As Brinkmann numbers and radiation parameters grow, entropy production increases, showing dual behavior for the magnetic parameter.

人工神经网络(ann)正变得越来越流行,因为它们可以解决复杂的非线性数学问题。生物技术、流体动力学和细胞计算等复杂领域都有人工神经网络的应用。本文利用机器学习技术分析了非定常条件下的传热和熵产 ({text{TiO}}_{2}/text{EG}) 纳米流体的流动,考虑了非线性热辐射、达西-福希海默效应和旋转球体的质量吸力。本研究从动态粘度和热导率的角度考察了聚集和非聚集现象。经典数学问题的表面摩擦系数、换热率、熵产、速度和温度相关的非线性版本可以使用MATLAB中的bvp4c求解器来求解。数据选择、网络创建、训练和使用均方误差度量的性能评估都是模型人工神经网络架构的一部分。表格和图形显示了参数对主观概况的影响。随着纳米颗粒体积分数的增加,x方向的速度分布增大 (phi),不稳定 (A),多孔介质渗透率 (K,) 磁性参数 (M),但随着Darcy-Forchheimer系数的减小而减小 (delta) 参数。z向速度剖面随增大而减小 (phi , A, K, M) 和 (delta). As (A) 随着温度剖面的增大,温度剖面减小,而辐射参数、Biot数、Eckert数和温度比参数的较大值增大。皮肤在x方向上的摩擦力随((K, M, phi),和 (S)),但随 (delta). 同样,z方向上的表面摩擦力也随着值的增大而增大 (K, phi , M, delta .) As (Ec) 增加时,局部努塞尔数随 (Bi, phi , Rd),和 ({theta }_{w}.) 随着布林克曼数和辐射参数的增加,熵产增加,磁参数表现出双重行为。
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引用次数: 0
A Novel Self-Sufficient Model Integrating LNG Regasification and Air Separation Unit: Energy and Exergy Analysis LNG再气化与空分装置的新型自给自足模型:能量与火用分析
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-21 DOI: 10.1007/s13369-025-10524-z
Umar Farooq, Javed Khan, Abubakar Saleem, Arif Hussain, Amjad Riaz, Abdullah A. Alarfaj, Faisal Ahmed

This study presents a novel integration of self-sufficient LNG regasification (LNG-R) with a cryogenic air separation unit (ASU), aimed at reducing overall energy demands and enhancing efficiency of the integrated plant. Through a rigorous parametric analysis and optimization using the Teaching–Learning Self-study Optimization (TLSO) algorithm, the integrated self-sufficient LNG-R and ASU system demonstrated significant reductions in energy consumption and reliance on external utilities. The proposed integrated system achieves a specific energy consumption of 0.0221 kWh/kg-Air, with a 0.765 Air/LNG ratio, separating 2754 kg/hr of air and yielding gaseous nitrogen and liquid oxygen with a purity of 99.9%. The process exhibits a coefficient of performance (COP) of 1.33 and an overall exergetic efficiency of 91.2%. This novel LNG-R and ASU integration enhances energy, exergy, and economic efficiency, offering a competitive strategy for optimizing LNG cold energy utilization.

本研究提出了一种新型的自给式LNG再气化(LNG- r)与低温空分装置(ASU)的集成,旨在降低整体能源需求并提高集成装置的效率。通过严格的参数分析和使用教学自学优化(TLSO)算法的优化,集成的自给自足LNG-R和ASU系统显着降低了能源消耗和对外部公用设施的依赖。该集成系统的比能耗为0.0221 kWh/kg-Air,空气/LNG比为0.765,分离空气2754 kg/hr,产生纯度为99.9%的气态氮和液氧。该工艺的性能系数(COP)为1.33,总火用效率为91.2%。这种新型LNG- r和ASU的集成提高了能源、能源和经济效率,为优化LNG冷能利用提供了一种有竞争力的策略。
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引用次数: 0
Lateritic Ore Reduction Using Ammonia Gas as an Alternative to Reduce CO2 Emission in Ferronickel Production 利用氨气还原红土矿以减少镍铁生产中二氧化碳的排放
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-18 DOI: 10.1007/s13369-025-10539-6
Sungging Pintowantoro, Muhammad Ghiffary Soenredi, Danendra Aryaseta, Sri Harjanto, Mohammad Fahrurrozi, Fahny Ardian, Yuli Setiyorini, Muhammad Bagas Ananda, Fakhreza Abdul

The ferronickel industry requires energy for processing and emits large amounts of CO2. The enormous energy requirement in the ferronickel industry is due to the low nickel content and high impurities in laterite nickel ore. Furthermore, the ferronickel industry’s high CO2 emissions can be attributed to the need for reducing agents, such as coal, to reduce nickel and iron oxides. This research aims to study the reduction process of lateritic nickel ore, specifically when NH3 gas is used as the reduction agent. Several process variables were studied, such as the effects of temperature and time. In addition, thermodynamic analysis was also carried out to determine the possibility of reactions that occurred during the reduction process. Many types of tests were also conducted, including X-ray diffractometer (XRD), inductively coupled plasma (ICP), and scanning electron microscope-energy dispersive X-ray (SEM–EDX) observations. Finally, the higher the temperature and the longer the time used, the higher the reduction degree obtained. It was also possible to obtain the ferronickel phase after the reduction process, which was predicted by thermodynamic calculations and confirmed by XRD. Other impurity minerals such as Fe3O4, SiO2, (Fe, Mg)2SiO4, and MgSiO3 were also found in the reduced product. The best reduction degree in this study was 77.8% when using a temperature of 900 °C and a duration of 120 min. Considering the successful reduction of nickel laterite ore using NH3 gas, it is theoretically estimated that CO2 can be reduced by about 22%.

镍铁工业需要能源来进行加工,并排放大量的二氧化碳。镍铁工业的巨大能源需求是由于红土镍矿石中镍含量低,杂质含量高。此外,镍铁工业的高二氧化碳排放量可归因于需要还原剂,如煤来还原镍和铁的氧化物。本研究旨在研究红土镍矿的还原过程,特别是以NH3气体为还原剂时的还原过程。研究了温度、时间等工艺变量对反应的影响。此外,还进行了热力学分析,以确定在还原过程中发生反应的可能性。还进行了多种类型的测试,包括x射线衍射仪(XRD)、电感耦合等离子体(ICP)和扫描电子显微镜-能量色散x射线(SEM-EDX)观察。最后,温度越高,使用时间越长,获得的还原程度越高。通过热力学计算和x射线衍射分析证实,在还原过程中也可以得到铁镍相。还原产物中还发现了Fe3O4、SiO2、(Fe, Mg)2SiO4、MgSiO3等杂质矿物。当温度为900℃,时间为120 min时,本研究的最佳还原度为77.8%。考虑到利用NH3气体成功还原红土镍矿,理论上估计CO2可还原22%左右。
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引用次数: 0
A Comprehensive Review of Failure Modes in Electrical Submersible Pumps: Diagnosis, Predictive Maintenance, and Engineer’s Guide 电潜泵故障模式的全面回顾:诊断,预测性维护和工程师指南
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-13 DOI: 10.1007/s13369-025-10536-9
Yasin Khalili, Mohammad Ahmadi, Mostafa Keshavarz Moraveji

Electrical Submersible Pumps (ESPs) are a critical component of artificial lift systems in the oil and gas industry, valued for their efficiency in high-volume production and adaptability to a wide range of reservoir conditions. However, their performance is often compromised by frequent failures arising from mechanical degradation, electrical faults, operational stresses, and harsh environmental factors. This review provides a comprehensive and systematic evaluation of ESP failure mechanisms and their root causes, with particular emphasis on diagnostic methodologies and predictive maintenance strategies. Recent advancements in machine learning such as XGBoost, Long Short-Term Memory (LSTM) networks, and Principal Component Analysis (PCA) are explored for their applicability in early fault detection and condition-based monitoring. The review also presents best practices in ESP installation, material selection, and real-time surveillance to enhance system reliability. Field-based case studies are included to illustrate the practical implementation of Root Cause Analysis (RCA) and predictive analytics, demonstrating substantial reductions in failure rates, extended pump run lives, and significant cost savings. The findings underscore the necessity of integrating advanced diagnostics and intelligent maintenance frameworks to ensure sustained ESP performance in increasingly complex and demanding production environments.

电潜泵(esp)是油气行业人工举升系统的重要组成部分,因其在大批量生产中的效率和对各种油藏条件的适应性而受到重视。然而,由于机械退化、电气故障、操作应力和恶劣的环境因素,它们的性能经常受到影响。本文对ESP故障机制及其根本原因进行了全面、系统的评估,特别强调了诊断方法和预测性维护策略。机器学习的最新进展,如XGBoost、长短期记忆(LSTM)网络和主成分分析(PCA),探讨了它们在早期故障检测和基于状态的监测中的适用性。该综述还介绍了ESP安装、材料选择和实时监控方面的最佳实践,以提高系统的可靠性。基于现场的案例研究说明了根本原因分析(RCA)和预测分析的实际实施,证明了故障率的大幅降低,延长了泵的运行寿命,并显著节省了成本。研究结果强调了集成先进诊断和智能维护框架的必要性,以确保在日益复杂和苛刻的生产环境中保持ESP的性能。
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引用次数: 0
On-Chip Integration of Micro-supercapacitor in VLSI Design for Power Management in Artificial Intelligence Processors and Memory Chips: A Review of Methods and Materials 用于人工智能处理器和存储芯片电源管理的VLSI设计中微型超级电容器的片上集成:方法和材料综述
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-11 DOI: 10.1007/s13369-025-10372-x
Faheem Dastageer, Anu Shaju Areeckal

Supercapacitors can act as an instant energy source to quickly supply electric power to any connected system because they are energy storage devices with high power densities. This feature of the supercapacitor can be used to reduce power fluctuations and access latency in cache memories in the VLSI (very-large-scale integration) design of quickly operating artificial intelligence (AI) processors and memory chips. High-performance computing with the best data throughput is produced by this high-power stability and instantaneous power delivery. This article reviews various thin film micro-supercapacitor integration techniques, fabrication processes, and electrode and electrolyte materials, applicable for on-chip integration of micro-supercapacitors on AI processors and memory chips. This review extends the discussion of the thin film versions of supercapacitors in planar and vertically stacked configurations and their relative advantages in mediating ionic conduction. On-chip fabrication of micro-supercapacitor by laser micropatterning, laser surface roughening, carbonization by pyrolysis, laser-induced reduction, and carbon MEMS to scribe electrode patterns with different materials are reviewed. For the on-chip integration of micro-supercapacitors, this examines various fabrication techniques including photolithography, such as monolithic integration, heterogeneous integration, and 3D stacking. The synthesis and implementation of various carbon-based, transition metal oxide-based, and conducting polymer-based electrode materials in both their pure and composite forms are reviewed.

超级电容器是一种具有高功率密度的能量存储装置,可以作为一种即时能量源,快速向任何连接的系统提供电力。超级电容器的这一特性可用于在快速运行的人工智能(AI)处理器和存储芯片的VLSI(超大规模集成)设计中减少缓存存储器中的功率波动和访问延迟。具有最佳数据吞吐量的高性能计算是由这种高功率稳定性和瞬时功率交付产生的。本文综述了适用于人工智能处理器和存储芯片上微超级电容器片上集成的各种薄膜微超级电容器集成技术、制造工艺、电极和电解质材料。本文进一步讨论了薄膜型超级电容器的平面和垂直堆叠结构,以及它们在介导离子传导方面的相对优势。综述了用激光微图像化、激光表面粗化、热解碳化、激光诱导还原以及用碳MEMS刻录不同材料电极图案等方法在片上制备微型超级电容器的方法。对于微型超级电容器的片上集成,本文探讨了各种制造技术,包括光刻,如单片集成,异质集成和3D堆叠。综述了各种碳基、过渡金属氧化物基和导电聚合物基电极材料的纯和复合形式的合成和实现。
{"title":"On-Chip Integration of Micro-supercapacitor in VLSI Design for Power Management in Artificial Intelligence Processors and Memory Chips: A Review of Methods and Materials","authors":"Faheem Dastageer,&nbsp;Anu Shaju Areeckal","doi":"10.1007/s13369-025-10372-x","DOIUrl":"10.1007/s13369-025-10372-x","url":null,"abstract":"<div><p>Supercapacitors can act as an instant energy source to quickly supply electric power to any connected system because they are energy storage devices with high power densities. This feature of the supercapacitor can be used to reduce power fluctuations and access latency in cache memories in the VLSI (very-large-scale integration) design of quickly operating artificial intelligence (AI) processors and memory chips. High-performance computing with the best data throughput is produced by this high-power stability and instantaneous power delivery. This article reviews various thin film micro-supercapacitor integration techniques, fabrication processes, and electrode and electrolyte materials, applicable for on-chip integration of micro-supercapacitors on AI processors and memory chips. This review extends the discussion of the thin film versions of supercapacitors in planar and vertically stacked configurations and their relative advantages in mediating ionic conduction. On-chip fabrication of micro-supercapacitor by laser micropatterning, laser surface roughening, carbonization by pyrolysis, laser-induced reduction, and carbon MEMS to scribe electrode patterns with different materials are reviewed. For the on-chip integration of micro-supercapacitors, this examines various fabrication techniques including photolithography, such as monolithic integration, heterogeneous integration, and 3D stacking. The synthesis and implementation of various carbon-based, transition metal oxide-based, and conducting polymer-based electrode materials in both their pure and composite forms are reviewed.</p></div>","PeriodicalId":54354,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"50 19","pages":"15219 - 15234"},"PeriodicalIF":2.9,"publicationDate":"2025-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13369-025-10372-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210276","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoparticle-Stabilized CO2 Foam in Porous Media for EOR and CCUS: A State-of-the-Art Review involving Mechanisms, Challenges, Influencing Parameters, and Research Opportunities 多孔介质中用于EOR和CCUS的纳米颗粒稳定CO2泡沫:涉及机制、挑战、影响参数和研究机会的最新综述
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-11 DOI: 10.1007/s13369-025-10512-3
Eugene N. Ngouangna, Iskandar B. Dzulkarnain, Mohd Zaidi Jaafar, M. N. A. M. Norddin, Jeffrey O. Oseh, Funsho A. Afolabi, Faruk Yakasai, Afeez O. Gbadamosi, Muftahu N. Yahya, Bamidele Victor Ayodele, Stanley C. Mamah, Ellora Priscille N. Ntone, Augustine Agi

Several trials have used nanoparticles (NPs) to stabilize foam, improve carbon capture, utilization, and storage (CCUS), and enhanced oil recovery (EOR). Nonetheless, previous research has been unable to differentiate between hydrophilic and hydrophobic/modified NPs to determine their role in foam stabilization. This study explores the regulatory factors and mechanisms of NP-stabilized CO2 foams and describes techniques for evaluating foam stability. The difficulties encountered, potential directions for future research, and limitations on applicability were all covered while describing how NPs stabilize foam. The efficacy of NP-stabilized foam is contingent upon the types of NPs, modifiers, temperature, salinity, and characteristics of the NPs. Both hydrophilic and hydrophobic NPs stabilize foam networks and enhance detachment energy. The synergistic effects of NPs on surfactants and lamellae are variable. NP foam can emulsify crude oil, enhance reservoir sweep efficiency, and infiltrate low-permeability pores by redirecting fluid. Optimization is necessary to identify the ideal modifier and production technique for modified NPs. Cost-effective, environmentally sustainable NPs may stabilize foam; nevertheless, further work is required to ascertain the control parameters of NP-stabilized foam.

一些试验已经使用纳米颗粒(NPs)来稳定泡沫,改善碳捕获、利用和储存(CCUS),并提高石油采收率(EOR)。然而,之前的研究无法区分亲水性和疏水性/改性NPs,以确定它们在泡沫稳定中的作用。本研究探讨了np稳定CO2泡沫的调控因素和机制,并描述了泡沫稳定性评价技术。在描述NPs如何稳定泡沫时,涵盖了遇到的困难,未来研究的潜在方向以及适用性的限制。np稳定泡沫的效果取决于NPs的类型、改性剂、温度、盐度和NPs的特性。亲水性和疏水性NPs都能稳定泡沫网络并提高脱离能。NPs对表面活性剂和片层的协同作用是可变的。NP泡沫可以乳化原油,提高油藏波及效率,并通过重定向流体渗透低渗透孔隙。优化是确定理想的改性剂和生产工艺的必要条件。经济高效、环境可持续的NPs可以稳定泡沫;然而,需要进一步的工作来确定np稳定泡沫的控制参数。
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引用次数: 0
Toward Efficient Bio-jet Fuel Production via Atmospheric Hydrotreating: Insight into the Effect of Co/HZSM-5, Mo/HZSM-5, and CoMo/HZSM-5 Catalyst Arrangements 通过常压加氢处理实现高效生物喷气燃料生产:Co/HZSM-5、Mo/HZSM-5和CoMo/HZSM-5催化剂配置的影响
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-08 DOI: 10.1007/s13369-025-10510-5
Dina Asnawati, Aldino Javier Saviola, Karna Wijaya, Indriana Kartini, Suryo Purwono, Rodiansono Rodiansono, Ady Mara, Won-Chun Oh, Anis Kristiani, Sudiyarmanto Sudiyarmanto, Wega Trisunaryanti

Growing environmental concerns associated with fossil-based jet fuel have spurred intensive research into renewable alternatives for the green aviation industry. In this study, HZSM-5 catalysts impregnated with cobalt (Co) and/or molybdenum (Mo) were successfully synthesized via a simple and eco-friendly spray impregnation method, forming mono- and bimetallic catalysts. For the first time, these catalysts were evaluated in a double-bed reactor system using customized monolayer and bilayer configurations for the atmospheric hydrotreating of crude palm oil into bio-jet fuel. The incorporation of Co and/or Mo modified the physicochemical properties of HZSM-5, reducing its specific surface area and total pore volume while increasing the average pore diameter and total acidity. Among the configurations, the Mo/Z (top)–Co/Z (bottom) bilayer catalyst demonstrated superior performance, achieving a 45.75% liquid product conversion and a 44.97% bio-jet fuel yield with 99.14% selectivity at 350–450 °C. This arrangement effectively promoted hydrodeoxygenation and hydrocracking reactions, producing bio-jet fuel with a freezing point of − 52 °C after vacuum distillation, in compliance with ASTM aviation fuel standards. The catalyst maintained stable performance over five consecutive runs with minimal yield decline, underscoring its durability. Overall, this study presents a promising, cost-effective approach for sustainable aviation fuel production with strong potential for industrial-scale application.

与化石燃料相关的环境问题日益严重,促使人们对绿色航空业的可再生替代品进行了深入研究。本研究通过简单环保的喷雾浸渍法成功合成了钴(Co)和钼(Mo)浸渍的HZSM-5催化剂,形成了单金属和双金属催化剂。这些催化剂首次在双床反应器系统中进行了评估,采用定制的单层和双层配置,用于将粗棕榈油常压加氢处理为生物喷气燃料。Co和/或Mo的掺入改变了HZSM-5的物理化学性质,降低了其比表面积和总孔容,同时增加了平均孔径和总酸度。其中,Mo/Z(上)-Co /Z(下)双层催化剂表现出优异的性能,在350 ~ 450℃的温度下,液体产物转化率为45.75%,生物喷气燃料收率为44.97%,选择性为99.14%。这种安排有效地促进了加氢脱氧和加氢裂化反应,生产出真空蒸馏后凝固点为- 52℃的生物喷气燃料,符合ASTM航空燃料标准。该催化剂在连续5次运行中保持稳定的性能,产量下降最小,突出了其耐久性。总的来说,这项研究为可持续航空燃料生产提供了一种有前景的、具有成本效益的方法,具有强大的工业规模应用潜力。
{"title":"Toward Efficient Bio-jet Fuel Production via Atmospheric Hydrotreating: Insight into the Effect of Co/HZSM-5, Mo/HZSM-5, and CoMo/HZSM-5 Catalyst Arrangements","authors":"Dina Asnawati,&nbsp;Aldino Javier Saviola,&nbsp;Karna Wijaya,&nbsp;Indriana Kartini,&nbsp;Suryo Purwono,&nbsp;Rodiansono Rodiansono,&nbsp;Ady Mara,&nbsp;Won-Chun Oh,&nbsp;Anis Kristiani,&nbsp;Sudiyarmanto Sudiyarmanto,&nbsp;Wega Trisunaryanti","doi":"10.1007/s13369-025-10510-5","DOIUrl":"10.1007/s13369-025-10510-5","url":null,"abstract":"<div><p>Growing environmental concerns associated with fossil-based jet fuel have spurred intensive research into renewable alternatives for the green aviation industry. In this study, HZSM-5 catalysts impregnated with cobalt (Co) and/or molybdenum (Mo) were successfully synthesized via a simple and eco-friendly spray impregnation method, forming mono- and bimetallic catalysts. For the first time, these catalysts were evaluated in a double-bed reactor system using customized monolayer and bilayer configurations for the atmospheric hydrotreating of crude palm oil into bio-jet fuel. The incorporation of Co and/or Mo modified the physicochemical properties of HZSM-5, reducing its specific surface area and total pore volume while increasing the average pore diameter and total acidity. Among the configurations, the Mo/Z (top)–Co/Z (bottom) bilayer catalyst demonstrated superior performance, achieving a 45.75% liquid product conversion and a 44.97% bio-jet fuel yield with 99.14% selectivity at 350–450 °C. This arrangement effectively promoted hydrodeoxygenation and hydrocracking reactions, producing bio-jet fuel with a freezing point of − 52 °C after vacuum distillation, in compliance with ASTM aviation fuel standards. The catalyst maintained stable performance over five consecutive runs with minimal yield decline, underscoring its durability. Overall, this study presents a promising, cost-effective approach for sustainable aviation fuel production with strong potential for industrial-scale application.</p></div>","PeriodicalId":54354,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"50 24","pages":"21123 - 21144"},"PeriodicalIF":2.9,"publicationDate":"2025-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145601003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Arabian Journal for Science and Engineering
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