The electrospinning technique is quite a prominent method for forming nanofibers due to its facile synthesis, wide adjustability, high controllability, and low cost. In the present study, the ultrafine nanofibers are fabricated by electrospinning Fe/C co-doped ZnO nanofibers (NFs). XRD results of Fe/C co-doped ZnO show that all samples have hexagonal wurtzite crystal structures with no additional contamination phases. SEM results reveal that the morphology of these randomly oriented nanofibers has a long and continuous formation with consistent diameters (200–450 nm), and the samples are well scattered. Fe3+ and C effectively replace the lactic sites of Zn2+. The findings demonstrate that Fe/C doping significantly increased ZnO storage activity, which may be related to generating new energy states, which could minimize the bandgap of ZnO due to NF’s shape and improve crystallinity. CV results show that the conductivity of ZnO NFs is substantially enhanced, and the electrochemical reaction mechanism of electrode materials is greatly facilitated by co-doping moderate C and Fe on them. ZnOFe(0.03wt.%)C electrode shows a specific capacitance (Cs) of 1418.081F/g with 89% retention at the current density of 2 mA/cm2 and a competent capacity rate of 98.1% at 5 mA/cm2, 96.2% at 10 mA/cm2 due to improvement in electron mobility. ZnOFe(0.03wt.%)C electrode shows a 76.65% drop of its actual capacitance at a high charge/discharge current density of 20 mA/cm2 compared to the ZnOFe(0.01wt.%)C and ZnOFe(0.02wt.%)C. This work shows that the Fe/C co-doped ZnO electrode has a high potential for use in energy storage gadget technologies.
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