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Fe/C co-Doped ZnO Electrospun Ultrafine Nanofibers as a Promising Energy Storage Material Fe/C共掺杂ZnO电纺丝超细纳米纤维作为一种有前途的储能材料
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-25 DOI: 10.1007/s13369-025-10451-z
Faiqa Sabeen, Muhammad Ali Raza, Muhammad Imran Yousaf

The electrospinning technique is quite a prominent method for forming nanofibers due to its facile synthesis, wide adjustability, high controllability, and low cost. In the present study, the ultrafine nanofibers are fabricated by electrospinning Fe/C co-doped ZnO nanofibers (NFs). XRD results of Fe/C co-doped ZnO show that all samples have hexagonal wurtzite crystal structures with no additional contamination phases. SEM results reveal that the morphology of these randomly oriented nanofibers has a long and continuous formation with consistent diameters (200–450 nm), and the samples are well scattered. Fe3+ and C effectively replace the lactic sites of Zn2+. The findings demonstrate that Fe/C doping significantly increased ZnO storage activity, which may be related to generating new energy states, which could minimize the bandgap of ZnO due to NF’s shape and improve crystallinity. CV results show that the conductivity of ZnO NFs is substantially enhanced, and the electrochemical reaction mechanism of electrode materials is greatly facilitated by co-doping moderate C and Fe on them. ZnOFe(0.03wt.%)C electrode shows a specific capacitance (Cs) of 1418.081F/g with 89% retention at the current density of 2 mA/cm2 and a competent capacity rate of 98.1% at 5 mA/cm2, 96.2% at 10 mA/cm2 due to improvement in electron mobility. ZnOFe(0.03wt.%)C electrode shows a 76.65% drop of its actual capacitance at a high charge/discharge current density of 20 mA/cm2 compared to the ZnOFe(0.01wt.%)C and ZnOFe(0.02wt.%)C. This work shows that the Fe/C co-doped ZnO electrode has a high potential for use in energy storage gadget technologies.

静电纺丝技术具有合成简单、可调性广、可控性强、成本低等优点,是纳米纤维制备的重要方法。本研究采用静电纺丝法制备了Fe/C共掺杂ZnO纳米纤维。Fe/C共掺杂ZnO的XRD结果表明,所有样品都具有六方纤锌矿晶体结构,没有额外的污染相。SEM结果表明,这些随机取向的纳米纤维具有长而连续的结构,直径一致(200 ~ 450 nm),样品分散良好。Fe3+和C有效取代了Zn2+的乳酸位点。研究结果表明,Fe/C掺杂显著提高了ZnO的储存活性,这可能与产生新的能态有关,这可以最小化由于NF形状导致的ZnO带隙并提高结晶度。CV结果表明,共掺杂适量的C和Fe大大提高了ZnO NFs的电导率,大大促进了电极材料的电化学反应机理。ZnOFe (0.03 wt。%)C电极的比电容(Cs)为1418.081F/g,在电流密度为2 mA/cm2时保持率为89%,在5 mA/cm2时有效容量率为98.1%,在10 mA/cm2时有效容量率为96.2%。ZnOFe (0.03 wt。%)C电极在20 mA/cm2的高充放电电流密度下,其实际电容比ZnOFe(0.01wt. 2)降低了76.65%。ZnOFe(0.02wt.%)C。这项工作表明,Fe/C共掺杂ZnO电极在储能器件技术中具有很高的应用潜力。
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引用次数: 0
Thermal and Mechanical Enhancement of PVC Composites with Functionalized Asphaltene Fillers 功能化沥青烯填料增强PVC复合材料的热力学性能
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-25 DOI: 10.1007/s13369-025-10425-1
Mohammad Nahid Siddiqui, Muhammad Faizan, Abdul Gani Abdul Jameel

The limited thermal and mechanical stability of polyvinyl chloride (PVC) restricts its application in more advanced industrial sectors. These limitations are overcome in the present research by adding up to 5 wt. % asphaltenes from crude oil, in its pristine or acid-functionalized form, enhancing compatibility with PVC. The material is prepared by dispersing asphaltene in tetrahydrofuran and combining it with PVC in the same solvent. After solvent removal, the composite is formed. Analysis shows successful integration of asphaltene, improving its thermal stability and mechanical strength. Mechanical testing showed that the tensile strength increased from 68.4 MPa (pure PVC) to 77 MPa at 2 wt.% pristine asphaltene, and to 71 MPa at 1 wt.% functionalized asphaltene, representing improvements of 12.6% and 9.6%, respectively. Elongation at break also improved, reaching 58.6% for 2 wt.% asphaltene compared to 4.99% for pure PVC. Optimal performance was observed at 2 wt.% asphaltene, with acid-functionalized asphaltene performing better at 1 wt.%. Microscopic imaging indicates homogeneous distribution at ideal concentrations, but larger loadings result in aggregation. This composite has potential uses in construction, automotive, and packaging.

聚氯乙烯(PVC)有限的热稳定性和机械稳定性限制了它在更先进的工业领域的应用。在目前的研究中,通过从原油中添加高达5wt . %的原始或酸功能化形式的沥青质,提高了与PVC的相容性,克服了这些限制。该材料是将沥青烯分散在四氢呋喃中,并与PVC在相同的溶剂中结合而成的。溶剂去除后,形成复合材料。分析表明沥青质的成功整合,提高了沥青的热稳定性和机械强度。力学测试表明,当原始沥青质含量为2 wt.%时,抗拉强度从68.4 MPa(纯PVC)提高到77 MPa,当功能化沥青质含量为1 wt.%时,抗拉强度提高到71 MPa,分别提高了12.6%和9.6%。断裂伸长率也有所提高,2 wt.%沥青质的断裂伸长率达到58.6%,而纯PVC的断裂伸长率为4.99%。沥青质含量为2 wt.%时性能最佳,酸功能化沥青质含量为1 wt.%时性能更好。显微镜成像显示理想浓度下的均匀分布,但较大的负荷会导致聚集。这种复合材料在建筑、汽车和包装方面有潜在的用途。
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引用次数: 0
Comparative Study of Synthesis Methods for YVO4:Eu3+ as a Luminescent Down-Shifting Layer in Improving the Performance of Commercial Si-based Solar Cells YVO4:Eu3+发光降移层合成方法在提高商用硅基太阳能电池性能中的比较研究
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-24 DOI: 10.1007/s13369-025-10449-7
A. H. Nosouhi, S. M. Rafiaei, M. Ebrahimi, A. Kermanpur, H. Rezvani Sichani

Luminescent down-shifting (LDS) materials, which absorb ultraviolet (UV) radiation and re-emit visible photons, are being explored as promising coatings for enhancing solar cell efficiency. This study investigates the effects of spin-coated YVO4:Eu3+ LDS layer on the performance of commercial silicon (Si) solar cells. The YVO4:Eu3+ nanoparticles were successfully synthesized using both combustion and hydrothermal methods, each producing high-purity powders with well-defined crystallinity. Photoluminescence results confirmed the effective UV-to-visible photon conversion of the synthesized powders when used as an LDS material. UV–Vis spectroscopy revealed enhanced absorption in both the UV and visible regions for LDS-coated cells. Device performance was significantly influenced by the synthesis method and the concentration of the precursor solution. At the optimal concentration, the combustion-synthesized YVO4:Eu3+ (Comb-2:10) improved power conversion efficiency (PCE) by ~ 4.45% (from 8.97 to 9.37%) compared to the uncoated cell. However, higher concentrations led to reduced performance due to particle agglomeration, non-uniform film coverage, and increased light scattering. In contrast, the hydrothermal-synthesized YVO4:Eu3+ precursor enabled the formation of a uniform, transparent, and defect-free LDS layer at its optimal concentration (Hydro-2), effectively enhancing antireflection and down-shifting performance. The champion device (Hydro-2) demonstrated a short-circuit current density (JSC), open-circuit voltage (VOC), and fill factor (FF) of 32.57 mA cm−2, 0.57 V, and 0.51, respectively, corresponding to a PCE of 9.47%, representing a 5.6% improvement over the uncoated cell and a 1.1% gain over Comb-2:10. These findings highlight the strong potential of spin-coated YVO4:Eu3+ layers as effective antireflection and down-shifting coatings for enhancing photovoltaic device efficiency.

发光下移(LDS)材料是一种吸收紫外线并重新发射可见光子的材料,是一种有前途的提高太阳能电池效率的涂层。本文研究了自旋涂覆YVO4:Eu3+ LDS层对商用硅(Si)太阳能电池性能的影响。采用燃烧法和水热法成功合成了YVO4:Eu3+纳米颗粒,每一种方法都生产出高纯度的粉末,结晶度明确。光致发光结果证实了合成的粉末作为LDS材料时具有有效的紫外-可见光子转换。紫外可见光谱显示,lds包被的细胞在紫外区和可见光区吸收增强。合成方法和前驱体溶液浓度对器件性能有显著影响。在最佳浓度下,燃烧合成的YVO4:Eu3+ (Comb-2:10)电池的功率转换效率(PCE)比未涂覆电池提高了约4.45%(从8.97提高到9.37%)。然而,较高的浓度会导致颗粒聚集、膜覆盖不均匀以及光散射增加,从而降低性能。相比之下,水热合成的YVO4:Eu3+前驱体能够在最佳浓度(氢-2)下形成均匀、透明、无缺陷的LDS层,有效增强了抗反射和降移性能。冠军器件(氢-2)的短路电流密度(JSC)、开路电压(VOC)和填充因子(FF)分别为32.57 mA cm−2、0.57 V和0.51,对应的PCE为9.47%,比未涂覆的电池提高5.6%,比Comb-2:10提高1.1%。这些发现强调了自旋涂覆YVO4:Eu3+层作为有效的抗反射和下移涂层的强大潜力,可以提高光伏器件的效率。
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引用次数: 0
Adaptive Artificial Rabbit Optimization for 3D Localization of Swarm War Robots in Forested Terrain 森林地形下群战机器人三维定位的自适应人工兔子优化
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-24 DOI: 10.1007/s13369-025-10414-4
Erhan Sesli

This study introduces the adaptive artificial rabbit optimization (AARO) algorithm for the 3D localization of swarm war robots (SWRs) deployed in forested terrain, where traditional GPS-based solutions are unreliable. The aim is to utilize received signal strength indicator (RSSI) information from a mobile anchor node (drone) to determine the positions of the SWRs. The AARO algorithm improves localization accuracy and time efficiency by leveraging the foraging and hiding behaviors of rabbits, allowing it to dynamically adapt its search strategies in the presence of noise. Simulation studies demonstrate that AARO outperforms established algorithms such as particle swarm optimization (PSO) and artificial rabbit optimization (ARO), achieving results close to the theoretical Cramer–Rao Lower Bound (CRLB). The results indicate that AARO achieves a maximum improvement of approximately 1.15% over ARO in terms of the average localization error and 24.43% over ARO in terms of execution time. Additionally, a general execution time enhancement in performance of about 10.02% was observed across all results.

本文介绍了一种自适应人工兔子优化(AARO)算法,用于部署在森林地形中的群战机器人(swr)的三维定位,传统的基于gps的解决方案在森林地形中不可靠。目的是利用从移动锚节点(无人机)接收到的信号强度指示器(RSSI)信息来确定swr的位置。AARO算法利用兔子的觅食和隐藏行为,在存在噪声的情况下动态调整搜索策略,提高了定位精度和时间效率。仿真研究表明,AARO优于粒子群优化(PSO)和人工兔子优化(ARO)等现有算法,其结果接近理论的Cramer-Rao下界(CRLB)。结果表明,AARO在平均定位误差方面比ARO提高了约1.15%,在执行时间方面比ARO提高了24.43%。此外,在所有结果中观察到性能的一般执行时间提高了约10.02%。
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引用次数: 0
Experimental Study on High-Strength Concrete with Hybrid Limestone Calcined Clay Cement Blends 石灰石煅烧粘土水泥混合掺合高强混凝土试验研究
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-23 DOI: 10.1007/s13369-025-10423-3
Abbas Albu Shaqraa, Ahmad Moein Abdali, Shamsad Ahmad, Mohammed A. Al-Osta, Hammad R. Khalid, Saheed Kolawole Adekunle

The high demand for sustainable alternatives to ordinary Portland cement (OPC), due to its high share of global CO2 emissions, has led to research to new low-carbon binders. One such binder is limestone calcined clay (LC3) which provides environmental benefits while preserving similar structural and durability qualities. This study explores the viability of using calcined clay and limestone to partially replace OPC in high-strength LC3 concrete, while using polycarboxylate-based superplasticizers. Two types (Fluidum PC314 and PCE CT50) of superplasticizers were employed at (0.5%, 1%, and 2%) dosages by mass of the binders. Several experiments were carried out including calorimetry test to evaluate hydration behavior at various temperature (23, 30, and 40 °C) to observe the changes in hydration behavior, measurement of fresh properties by slump, evaluation of hardened properties such as compressive strength, tensile strength, density, water absorption, chloride migration, drying shrinkage and SEM for microstructural analysis. According to the results, the LC3 concrete mixes attained a high compressive strength of around 70 MPa and 90 MPa at 7 and 28 days, respectively, which were comparable or even higher than those of the control OPC mixtures. Fluidum PC314 containing mixtures performed better mechanically and in terms of endurance than PCE CT50. In LC3 combinations, improved microstructural densification and decreased chloride permeability were noted, indicating their potential for long-lasting, high-strength uses in environmentally friendly building, which validates the research hypothesis recommending LC3 binder for use in the construction industry requiring high-strength concrete.

由于普通硅酸盐水泥(OPC)在全球二氧化碳排放中所占的比例很高,因此对其可持续替代品的需求很高,这导致了对新型低碳粘合剂的研究。其中一种粘合剂是石灰石煅烧粘土(LC3),它在保持类似结构和耐用性的同时具有环境效益。本研究探讨了在高强度LC3混凝土中使用煅烧粘土和石灰石部分替代OPC的可行性,同时使用聚羧酸基高效减水剂。两种类型的高效减水剂(fluum PC314和PCE CT50)分别以0.5%、1%和2%的质量剂量使用。在不同温度(23℃、30℃和40℃)下,通过量热法评估水化行为,观察水化行为的变化;通过坍落度测量新鲜性能;评估硬化性能,如抗压强度、抗拉强度、密度、吸水率、氯化物迁移、干燥收缩率和SEM进行微观结构分析。结果表明,LC3混凝土混合料在7天和28天的抗压强度分别达到70 MPa和90 MPa左右,与对照OPC混合料相当甚至更高。含有PC314的流体混合物在机械性能和耐久性方面优于PCE CT50。在LC3组合中,微结构致密性得到改善,氯离子渗透性降低,这表明它们在环保建筑中具有持久、高强度用途的潜力,这验证了研究假设,建议LC3粘合剂用于需要高强度混凝土的建筑行业。
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引用次数: 0
Dual-Tube Configuration of FBG Sensors For Monitoring Internal Strains and Deformation of Soil Slope Through Laboratory Model Tests 双管结构FBG传感器监测土坡内部应变和变形的室内模型试验
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-22 DOI: 10.1007/s13369-025-10324-5
Qurratu Aini Sirat, Asrul Izam Azmi, Azman Kassim, Raja Kamarulzaman Raja Ibrahim, Nur Azlin Baharudin

The occurrence of rainfall results in a rise in pore-water pressure and a reduction of the soil’s shear resistance, thereby triggering slope failures that could pose hazardous risks to human life and infrastructure loss. To mitigate and minimise such catastrophic events, the employment of advanced instruments such as fibre Bragg grating (FBG) has captured attention in geo-structures monitoring. This is primarily attributed to their characteristics such as high capacity for multiplexing and compact size. This study developed soil strain sensors using FBG technology to monitor the soil behaviour of rainfall-induced soil slopes by evaluating the overall deformation from the internal strain monitored in both vertical and horizontal directions. The FBG sensors were multiplexed and protected by a dual-layer tube. The packaged FBG sensors are constructed with measured strain and temperature sensitivity to evaluate the responses of the packaged FBG towards both mechanical and thermal properties. The interaction between the soil slope and the packaged FBG was also evaluated in the pull-out test. The feasibility of the developed FBG monitoring system for real-time monitoring of strains has been presented through experimental and numerical analysis conducted on a non-homogenous residual soil slope subjected to 6.67 × 10–6 m/s rainfall intensity. The data show that direct installation of FBG sensors is extremely sensitive to soil movement, measuring soil strain at microstrain levels in both horizontal and vertical orientations. These findings from both analyses reveal that strain distribution data are associated with the direction of the force applied.

降雨的发生导致孔隙水压力升高,土壤抗剪能力降低,从而引发边坡破坏,对人类生命和基础设施的损失构成危险。为了减轻和减少这种灾难性事件,采用先进的仪器,如光纤布拉格光栅(FBG)在地质结构监测中引起了人们的注意。这主要归功于它们的特点,如高容量的多路复用和紧凑的尺寸。本研究开发了使用FBG技术的土壤应变传感器,通过评估垂直和水平方向监测的内部应变的整体变形来监测降雨引起的土壤斜坡的土壤行为。光纤光栅传感器采用多路复用,并采用双层管保护。封装的光纤光栅传感器采用测量应变和温度灵敏度来评估封装的光纤光栅对机械和热性能的响应。在拉拔试验中,还评估了土坡与封装光纤光栅之间的相互作用。通过对6.67 × 10-6 m/s强降雨条件下非均质残余土边坡的试验和数值分析,验证了所开发的FBG监测系统实时监测应变的可行性。数据表明,直接安装FBG传感器对土壤运动非常敏感,可以在水平和垂直方向上测量微应变水平的土壤应变。这两种分析的结果表明,应变分布数据与施加力的方向有关。
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引用次数: 0
AI-Driven ANFIS Modeling for Smart Drilling to Maximize the Utilization of the Cutting Tools—I4.0 Application ai驱动的ANFIS智能钻井建模,以最大限度地利用切削工具- i4.0应用
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-21 DOI: 10.1007/s13369-025-10471-9
Ahmed Aly Diaa Sarhan

The aim of this research is to develop an ANFIS modeling for smart drilling to maximize the utilization of cutting tools. In this study, first, the tool wear behavior is investigated and clearly recognized. Second, the torque and thrust force signals are measured through a series of experiments at different drilling parameters conditions (flank wear, spindle speed, feed rate, and drill diameter to be used as an indicator of the drilling performance). The relationships between these independent parameters and the torque and force signals are statistically evaluated using (MANOVA) to determine the importance of each parameter in the response. Third, two adaptive neuro-fuzzy inference system (ANFIS) models are established to accurately predict the values of the drilling thrust force and torque at various drilling conditions and to accurately identify the thrust force and torque values at the maximum tool wear corresponding to the end of tool service life where it is necessary to change the tool to avoid tool deficiency and workpiece surface damage. The developed ANFIS models are verified through a series of verification tests. Finally, the Tool Condition Monitoring (TCM) architecture is proposed to be established in future as a smart way to maximize the utilization of the tool for smart drilling operation. This not only guarantees the minimum possible production cost related to the utilization of the tool but also guarantees the best possible dimensional and surface finish accuracy avoiding surface damage correlated with the use of worn tool exceeding the tool service life.

本研究的目的是开发智能钻井的ANFIS模型,以最大限度地利用切削工具。在本研究中,首先对刀具的磨损行为进行了研究并得到了清晰的认识。其次,通过一系列实验测量不同钻孔参数条件下的扭矩和推力信号(以侧面磨损、主轴转速、进给速度和钻头直径作为钻孔性能指标)。这些独立参数与扭矩和力信号之间的关系使用(MANOVA)进行统计评估,以确定每个参数在响应中的重要性。第三,建立了两个自适应神经模糊推理系统(ANFIS)模型,准确预测各种钻孔工况下的钻孔推力和扭矩值,准确识别刀具使用寿命结束时对应的刀具最大磨损时的推力和扭矩值,避免刀具不足和工件表面损伤。通过一系列的验证试验,验证了所开发的ANFIS模型。最后,提出了未来将建立工具状态监测(TCM)架构,作为最大限度地利用工具进行智能钻井作业的智能方式。这不仅保证了与刀具使用相关的尽可能低的生产成本,而且保证了尽可能好的尺寸和表面光洁度精度,避免了与使用磨损刀具超过刀具使用寿命相关的表面损伤。
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引用次数: 0
An Exhaustive Review of Research and Development of Tesla Turbine Technology 特斯拉涡轮技术研究与发展综述
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-16 DOI: 10.1007/s13369-025-10409-1
Mayank Bhardwaj, Sunil Nain, Upender Dhull

This review presents a comprehensive synthesis of recent advancements in Tesla disc turbine technology, with an emphasis on both theoretical modelling and experimental validation across diverse energy applications. Analytical frameworks and CFD simulations have been extensively employed to investigate the viscous-dominated, complex flow dynamics within the rotor, highlighting the influence of centrifugal, Coriolis, inertial, and viscous forces in power extraction. Performance is highly sensitive to disc geometry, spacing, and nozzle design, with isentropic efficiencies exceeding 0.75 under idealized conditions. Experimental studies complement these findings by introducing novel low-loss nozzles, torque measurement techniques, and demonstrating up to 30% power enhancement using nanofluids. Similitude and scaling laws have been developed to support accurate prototyping. In parallel, surface roughness, unavoidable at microscale, has been investigated numerically via 3D conical peak models, revealing its substantial impact on pressure drop and highlighting the need for precise hydraulic diameter characterization in design models. Extending beyond internal flow systems, Tesla turbine principles have also been validated in marine energy research through a 300 W counter-rotating horizontal axis tidal turbine (HATT). Designed via blade element momentum theory and tested using a novel large-radius rotating arm tank, the HATT demonstrated strong agreement between CFD and experimental data, validating its hydrodynamic design and performance potential. Collectively, these efforts underscore the Tesla turbine’s viability in organic Rankine cycles, micro-CHP systems, tidal power extraction, and small-scale renewable energy applications, where cost-effectiveness, scalability, and design flexibility are critical.

本文综述了特斯拉盘式涡轮技术的最新进展,重点介绍了不同能源应用的理论建模和实验验证。分析框架和CFD模拟已被广泛用于研究转子内以粘性为主导的复杂流动动力学,突出了离心力、科里奥利力、惯性和粘性力对动力提取的影响。性能对圆盘几何形状、间距和喷嘴设计高度敏感,在理想条件下等熵效率超过0.75。实验研究补充了这些发现,引入了新型低损耗喷嘴、扭矩测量技术,并证明使用纳米流体可将功率提高30%。相似和缩放定律已经被开发出来,以支持精确的原型设计。同时,在微观尺度下不可避免的表面粗糙度通过三维锥形峰值模型进行了数值研究,揭示了其对压降的重大影响,并强调了在设计模型中精确的水力直径表征的必要性。除了内部流动系统之外,特斯拉的涡轮原理也通过300w的反向旋转水平轴潮汐涡轮机(HATT)在海洋能源研究中得到了验证。HATT采用叶片单元动量理论进行设计,并使用新型大半径旋转臂槽进行测试,结果表明CFD和实验数据非常吻合,验证了其流体动力设计和性能潜力。总的来说,这些努力强调了特斯拉涡轮机在有机朗肯循环、微型热电联产系统、潮汐能提取和小规模可再生能源应用中的可行性,在这些应用中,成本效益、可扩展性和设计灵活性至关重要。
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引用次数: 0
Enhancing Hydrogen Recovery in Sorption Enhancement Membrane Reactors (SEMR): A CFD Study 提高吸附强化膜反应器(SEMR)氢气回收率的CFD研究
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-15 DOI: 10.1007/s13369-025-10385-6
Alaa H. Theban, Tahseen A. Al-Hattab

Hydrogen is a promising sustainable energy carrier due to its eco-friendly features. Approximately 96% of global hydrogen production is produced using carbon-based methods, such as natural gas (NG) steam reforming, which releases significant amounts of CO2 as a byproduct. To produce H2 more efficiently, a membrane reactor (MR) is introduced, and while some attempts have been made to improve the hydrogen yield in MR coupled with membranes, a sorption-enhanced membrane reactor (SEMR) has been proposed as a next-generation process for simultaneous H2 production and CO2 capture. A two-dimensional (2D) axisymmetric computational fluid dynamics (CFD) model is developed for a hydrogen-permeable membrane reactor that employs a Pd-Ru membrane with a Ni (/{text{MgAl}}_{2}{text{O}}_{3}) catalyst and calcium oxide (CaO) as a CO2 adsorbent to produce high-purity hydrogen utilizing actual (Amara Field) natural gas steam reforming. This work simulates a model for NG steam reforming using real composition data under varying heating gas temperatures (500–800 K). A comparison is made for the performance of the SEMR to that of a conventional membrane reactor (MR). At 800 K and a pressure difference of 1 bar, SEMR achieves a 3.3% higher H₂ concentration, a 2.4% higher CH₄ conversion, and a 23.9% lower CO₂ concentration compared to MR. These findings demonstrate the potential of SEMR to contribute meaningfully to cleaner and more efficient hydrogen production technologies.

氢具有生态友好的特点,是一种很有前途的可持续能源载体。大约96% of global hydrogen production is produced using carbon-based methods, such as natural gas (NG) steam reforming, which releases significant amounts of CO2 as a byproduct. To produce H2 more efficiently, a membrane reactor (MR) is introduced, and while some attempts have been made to improve the hydrogen yield in MR coupled with membranes, a sorption-enhanced membrane reactor (SEMR) has been proposed as a next-generation process for simultaneous H2 production and CO2 capture. A two-dimensional (2D) axisymmetric computational fluid dynamics (CFD) model is developed for a hydrogen-permeable membrane reactor that employs a Pd-Ru membrane with a Ni (/{text{MgAl}}_{2}{text{O}}_{3}) catalyst and calcium oxide (CaO) as a CO2 adsorbent to produce high-purity hydrogen utilizing actual (Amara Field) natural gas steam reforming. This work simulates a model for NG steam reforming using real composition data under varying heating gas temperatures (500–800 K). A comparison is made for the performance of the SEMR to that of a conventional membrane reactor (MR). At 800 K and a pressure difference of 1 bar, SEMR achieves a 3.3% higher H₂ concentration, a 2.4% higher CH₄ conversion, and a 23.9% lower CO₂ concentration compared to MR. These findings demonstrate the potential of SEMR to contribute meaningfully to cleaner and more efficient hydrogen production technologies.
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引用次数: 0
Review of Recent Advances in Origami-Inspired Structures for Enhanced Energy Absorption: Trends and Engineering Applications 用于增强能量吸收的折纸结构的最新进展综述:趋势和工程应用
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-09 DOI: 10.1007/s13369-025-10411-7
Khaja Fayaz Hussain, W. J. Cantwell, Kamran A. Khan

Recently, novel structures inspired by origami principles have emerged, leveraging their lightweight and foldable characteristics for diverse applications. These structures also exhibit higher strength and stiffness, making them suitable for structural applications. Consequently, the use of the origami approach for designing innovative structures with excellent energy absorption capabilities has been increasing in engineering fields. This paper provides a comprehensive overview of recent advances in the development of origami-inspired structures for energy absorption applications. The unique features and remarkable mechanical properties of various origami structures, including metamaterials, honeycombs, thin-walled tubes, and foldcores fabricated from metals, polymers, composites, and multi-materials under different loading conditions, are critically discussed. Initially, the performance evaluation indexes and loading conditions for energy absorption of origami structures are summarized. The paper then classifies various types of origami structures and examines their incorporation into crash boxes, thin-walled tubes, cellular lattices, metamaterials, and sandwich structures, discussing their deformation behavior and energy absorption capabilities under different loading conditions. Finally, future research directions on energy absorption in origami structures are discussed. This review offers a valuable platform for researchers and engineers to develop novel designs based on origami-inspired structures for energy absorption applications.

最近,受折纸原理启发的新颖结构出现了,利用它们的轻量化和可折叠特性用于各种应用。这些结构还具有更高的强度和刚度,使其适用于结构应用。因此,利用折纸方法设计具有优异能量吸收能力的创新结构在工程领域越来越多。本文提供了一个全面的概述,在折纸启发结构的能量吸收应用的发展的最新进展。重点讨论了不同载荷条件下由金属、聚合物、复合材料和多种材料制成的各种折纸结构(包括超材料、蜂窝、薄壁管和折纸芯)的独特特征和显著的力学性能。首先总结了折纸结构吸能性能评价指标和加载条件。然后对各种类型的折纸结构进行分类,并研究了它们在碰撞盒、薄壁管、细胞格、超材料和夹层结构中的结合情况,讨论了它们在不同载荷条件下的变形行为和能量吸收能力。最后,对未来折纸结构能量吸收的研究方向进行了展望。这一综述为研究人员和工程师开发基于折纸启发的能量吸收结构的新设计提供了一个有价值的平台。
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引用次数: 0
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Arabian Journal for Science and Engineering
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