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Photovoltaic-Based Dual Output DC–DC Converter Using Gravitational Search Algorithm-Tuned PI and Sliding Mode Controllers 使用重力搜索算法调整 PI 和滑动模式控制器的光伏双输出 DC-DC 转换器
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-02 DOI: 10.1007/s13369-024-08962-2
M. P. E. Rajamani, Murugappan Murugappan, N. B. Prakash, Gomesh Nair, Mohamed Trabelsi

This paper proposes a dual-output DC–DC power conversion system based on Photovoltaic (PV) technology. PV panels are connected to a series compensated Buck-Boost Converter (SCBBC) to harvest solar energy, while a sliding mode controller (SMC) ensures maximum power point tracking (MPPT). During the intermediate phase, a synchronized Buck-Boost Converter (SBBC) topology is used to ensure effective charging and discharging of batteries. Additionally, a PI-SMC hybrid control strategy is applied at the back end to the Super Lift Luo Converter (SLLC) to maintain the load voltage at a desired value. A Gravitational Search Algorithm (GSA)-based PI controller controls the input current, while the output voltage is controlled by the outer loop (SMC). We use a single-loop SMC approach to validate the performance of the proposed dual-loop control scheme. According to the presented results, the dual-loop control scheme demonstrated higher dynamic performance in controlling input current and output voltage.

摘要 本文提出了一种基于光伏(PV)技术的双输出 DC-DC 电源转换系统。光伏板与串联补偿降压-升压转换器(SCBBC)相连,以收集太阳能,而滑动模式控制器(SMC)则确保最大功率点跟踪(MPPT)。在中间阶段,同步降压-升压转换器(SBBC)拓扑结构用于确保电池的有效充放电。此外,在超级升降罗转换器(SLLC)的后端还采用了 PI-SMC 混合控制策略,以将负载电压保持在理想值。基于重力搜索算法(GSA)的 PI 控制器控制输入电流,而输出电压则由外环(SMC)控制。我们使用单回路 SMC 方法来验证所提出的双回路控制方案的性能。结果表明,双环控制方案在控制输入电流和输出电压方面表现出更高的动态性能。
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引用次数: 0
Construction of Ag/Bi7O9I3 Catalyst for Photocatalytic Degradation of Rhodamine B 构建用于光催化降解罗丹明 B 的 Ag/Bi7O9I3 催化剂
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-02 DOI: 10.1007/s13369-024-08931-9
Pooja Dhiman, Jayati Sharma, Amit Kumar, Gaurav Sharma, Elmuez A. Dawi

In this work, we fabricated an Ag/Bi7O9I3 composite and tested the composite for the photodegradation of Rhodamine B (RhB) dye under UV–vis light irradiation. XRD, FESEM, TEM, UV–visible absorbance, XPS studies, ESR, and electrochemical analysis were used to characterize the synthesized photocatalysts. The synthesized catalyst displayed a maximum degradation efficiency of 98.45% in the 150-min experiment, which is nearly 1.56 times higher than Bi7O9I3. The enhanced photocatalytic activity of Ag/Bi7O9I3 is attributed to the acceleration of charge separation and transfer of charge carriers with the inclusion of Ag. The improvement in photocatalytic efficiency of Ag/Bi7O9I3 can be attributed to Ag deposition, which acts as an electron sink to avoid recombination of photogenerated electrons and holes. Additionally, Ag nanoparticles may show plasmonic resonance producing more electron–hole pairs in Bi7O9I3. Furthermore, a variety of tests were carried out on Ag/Bi7O9I3 in order to clarify how different factors affect the photodegradation efficiency. The medium with pH = 3, catalyst loading = 35 mg, and Rhodamine B concentration = 10 ppm resulted in highest activity. Using a radical scavenging experiment and ESR studies, the effective radicals in promoting dye degradation have been identified, and ·O2 radicals turned out to be the main radicals in promoting photocatalysis. Additionally, the reusability and degradation mechanisms of the enhanced photodegradation on the specified photocatalyst were examined.

在这项研究中,我们制备了一种 Ag/Bi7O9I3 复合材料,并测试了该复合材料在紫外-可见光照射下对罗丹明 B (RhB) 染料的光降解作用。利用 XRD、FESEM、TEM、紫外-可见吸收率、XPS 研究、ESR 和电化学分析对合成的光催化剂进行了表征。在 150 分钟的实验中,合成催化剂的最高降解效率为 98.45%,是 Bi7O9I3 的近 1.56 倍。Ag/Bi7O9I3 光催化活性的增强归因于 Ag 的加入加速了电荷分离和电荷载流子的转移。Ag/Bi7O9I3光催化效率的提高可归因于Ag的沉积,Ag作为电子沉,可避免光生电子和空穴的重组。此外,Ag 纳米粒子可能会产生等离子共振,在 Bi7O9I3 中产生更多的电子-空穴对。此外,还对 Ag/Bi7O9I3 进行了各种测试,以明确不同因素对光降解效率的影响。在 pH = 3、催化剂负载 = 35 毫克、罗丹明 B 浓度 = 10 ppm 的培养基中,Ag/Bi7O9I3 的活性最高。通过自由基清除实验和 ESR 研究,确定了促进染料降解的有效自由基,发现 -O2- 自由基是促进光催化的主要自由基。此外,还研究了特定光催化剂的可重复使用性和增强光降解的降解机制。
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引用次数: 0
High-Speed Coding Unit Depth Identifications Using CU-VGG Deep Learning Architectures 使用 CU-VGG 深度学习架构进行高速编码单元深度识别
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-01 DOI: 10.1007/s13369-024-08928-4
Hari Pattimi, B. K. N. Srinivasarao

The quadtree partition process involves major complexity in high-efficiency video coding (HEVC/H.265). It divides the coding tree units (CTUs) recursively into coding units (CUs). Determining the coding unit partition depth based on rate-distortion optimisation is computationally difficult in HEVC. This article proposes a system based on a deep learning architecture for determining the coding unit partition depth with less time in HEVC intra-prediction. The proposed system minimises computing complexity by removing the rate-distortion optimisation. The proposed system comprises two main blocks: the pre-processing block and the deep learning block. During the pre-processing phase, the spatial resolution of the input data is drastically reduced, enabling the neural network model to quickly adapt to the input sample and extract more meaningful feature data. This paper proposes two distinct deep learning architectures, CU-VGG16 and CU-VGG19. Pre-processed coding units (16 (times ) 16) are the input for the deep learning architecture, and the corresponding coding units’ depths (0, 1, 2, 3) are the output. To compare the accuracy of coding unit depth prediction in the two proposed models, we have created a database with varying resolutions. The performance of the proposed models was observed by replacing the CU partition block of traditional HEVC with the proposed systems and comparing the bit rate and encoding time with traditional HEVC. The results demonstrated that the proposed architecture with CU-VGG16 and CU-VGG19 designs speeds up coding unit partitioning by 87.15% and 87.70%, respectively, as compared to standard HEVC.

在高效视频编码(HEVC/H.265)中,四叉树分割过程非常复杂。它将编码树单元(CTU)递归划分为编码单元(CU)。在 HEVC 中,基于速率-失真优化确定编码单元划分深度在计算上非常困难。本文提出了一种基于深度学习架构的系统,用于在 HEVC 内部预测中以更短的时间确定编码单元划分深度。该系统取消了速率-失真优化,从而最大限度地降低了计算复杂度。提议的系统包括两个主要模块:预处理模块和深度学习模块。在预处理阶段,输入数据的空间分辨率被大幅降低,从而使神经网络模型能够快速适应输入样本并提取更有意义的特征数据。本文提出了两种不同的深度学习架构:CU-VGG16 和 CU-VGG19。预处理后的编码单元(16 (times ) 16)是深度学习架构的输入,相应的编码单元深度(0、1、2、3)是输出。为了比较两种拟议模型中编码单元深度预测的准确性,我们创建了一个具有不同分辨率的数据库。将传统 HEVC 的 CU 分区块替换为建议的系统,并将比特率和编码时间与传统 HEVC 进行比较,从而观察建议模型的性能。结果表明,与标准 HEVC 相比,采用 CU-VGG16 和 CU-VGG19 设计的拟议架构将编码单元分区速度分别提高了 87.15% 和 87.70%。
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引用次数: 0
An Extensible Non-isolated Enhanced Gain DC–DC Converter Integrating Switched Capacitor Cell for FCEV 用于 FCEV 的集成开关电容电池的可扩展非隔离增强增益 DC-DC 转换器
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-04-01 DOI: 10.1007/s13369-024-08907-9
Sovit Kumar Pradhan, Sreejith Sekaran, Indrojeet Chakraborty

In this study, three different Switched-Capacitor Enhanced boost quasi Z source (SCEq-Zs) DC–DC converters are presented, out of which the converter having a switched capacitor network positioned in series with the enhanced boost q-Zs network (SCEq-Zs-3) provides the common ground path and less output capacitor stress. This converter has a high voltage conversion ratio with low voltage stress on active and passive devices like capacitors, diodes, and the power semiconductor switch in comparison to other converters. This unidirectional hybrid switched-capacitor with a quasi Z source combination provides continuous and ripple-free source current mostly suitable for fuel cell applications. This leads to reduced voltage fluctuations at the input, providing a steady source of power to the converter. The converter is comprehensively analyzed and the operating principle along with waveforms is presented in this paper. A systematic comparison with other DC–DC boost converters is brought to view. A scaled-down 200V/200W prototype for the suggested converter is developed to verify the results of the theoretical study. A maximum efficiency of 95.85 % is measured. To demonstrate the effectiveness of the suggested converter, detailed experimental findings are presented.

本研究提出了三种不同的开关电容器增强型升压准 Z 源(SCEq-Zs)直流-直流转换器,其中,具有与增强型升压 q-Zs 网络串联的开关电容器网络的转换器(SCEq-Zs-3)提供了公共接地路径和较小的输出电容器应力。与其他转换器相比,这种转换器的电压转换率高,对电容器、二极管和功率半导体开关等有源和无源器件的电压应力小。这种具有准 Z 源组合的单向混合开关电容器可提供连续、无纹波的源电流,主要适用于燃料电池应用。这就减少了输入端的电压波动,为转换器提供了稳定的电源。本文对该转换器进行了全面分析,并介绍了其工作原理和波形。本文还对该转换器与其他直流-直流升压转换器进行了系统比较。为了验证理论研究的结果,我们为建议的转换器开发了一个 200V/200W 的缩小原型。测得最高效率为 95.85%。为了证明所建议的转换器的有效性,本文介绍了详细的实验结果。
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引用次数: 0
Development and Evaluation of Ultrasound-Assisted Solvent Extraction of Polycyclic Aromatic Hydrocarbons from Membrane-Packed Biota Samples Followed by GC–MS/MS Analysis 开发和评估超声辅助溶剂萃取膜包生物群样本中的多环芳香烃并进行 GC-MS/MS 分析的方法
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-30 DOI: 10.1007/s13369-024-08763-7
Adeola Akeem Akinpelu, Muhammad Sajid, Mazen Khaled Nazal

In this study, a new method was developed for extraction and determination of polycyclic aromatic hydrocarbons (PAHs) in biota samples. The biota samples were packed inside a porous membrane bag and subjected to ultrasonication-assisted solvent extraction. This method showed good applicability to both low and high sample weights. The effect of various parameters such as type and volume of extraction solvent, ultrasonication time, sample weight, and dimensions of extraction device on extraction performance was evaluated. The developed method showed a good linear range from 12.5 to 100 ng/g for all the selected analytes with correlation coefficients ranging from 0.9907 to 0.9999. The limits of detection ranged from 0.97 to 3.47 ng/g. The method’s precision was assessed based on relative standard deviations, which were below 13.5% indicating an acceptable precision. The developed procedure used for determination of PAHs in biota samples is characterized by many positive features. The packing of dried biota samples inside the membrane bag is advantageous because it eliminates several steps such as filtration or centrifugation and further extract purification. As the samples are protected inside the membrane bag, they can be easily separated from the solvent extract after the completion of the extraction process by simply removing the membrane bag. Moreover, the membrane may hinder the transportation of macromolecules to the extract, thus resulting in a relatively cleaner extract. Due to its simplicity and excellent figures of merit, this method presents a better potential for routine analysis of polycyclic aromatic hydrocarbons in biota samples.

本研究建立了一种提取和测定生物群样品中多环芳烃(PAHs)的新方法。将生物群样品装入多孔膜袋中,进行超声辅助溶剂萃取。该方法对低重量和高重量样品均有良好的适用性。评估了各种参数对萃取性能的影响,如萃取溶剂的类型和体积、超声时间、样品重量和萃取装置的尺寸。所开发的方法在 12.5 至 100 纳克/克的范围内对所有选定的分析物均显示出良好的线性,相关系数在 0.9907 至 0.9999 之间。检测限为 0.97 至 3.47 纳克/克。根据相对标准偏差对该方法的精密度进行了评估,结果低于 13.5%,表明该方法的精密度可以接受。所开发的用于测定生物群样本中 PAHs 的程序具有许多积极的特点。将干燥的生物群样本装入膜袋中的优点是省去了过滤或离心以及进一步提取纯化等步骤。由于样本在膜袋中受到保护,因此在提取过程结束后,只需取下膜袋,就可以轻松地将样本与溶剂提取物分离。此外,膜还可以阻碍大分子向提取物的迁移,从而使提取物相对更洁净。由于该方法操作简单、性能优越,因此在生物群样本中的多环芳烃常规分析中具有较好的应用前景。
{"title":"Development and Evaluation of Ultrasound-Assisted Solvent Extraction of Polycyclic Aromatic Hydrocarbons from Membrane-Packed Biota Samples Followed by GC–MS/MS Analysis","authors":"Adeola Akeem Akinpelu,&nbsp;Muhammad Sajid,&nbsp;Mazen Khaled Nazal","doi":"10.1007/s13369-024-08763-7","DOIUrl":"10.1007/s13369-024-08763-7","url":null,"abstract":"<div><p>In this study, a new method was developed for extraction and determination of polycyclic aromatic hydrocarbons (PAHs) in biota samples. The biota samples were packed inside a porous membrane bag and subjected to ultrasonication-assisted solvent extraction. This method showed good applicability to both low and high sample weights. The effect of various parameters such as type and volume of extraction solvent, ultrasonication time, sample weight, and dimensions of extraction device on extraction performance was evaluated. The developed method showed a good linear range from 12.5 to 100 ng/g for all the selected analytes with correlation coefficients ranging from 0.9907 to 0.9999. The limits of detection ranged from 0.97 to 3.47 ng/g. The method’s precision was assessed based on relative standard deviations, which were below 13.5% indicating an acceptable precision. The developed procedure used for determination of PAHs in biota samples is characterized by many positive features. The packing of dried biota samples inside the membrane bag is advantageous because it eliminates several steps such as filtration or centrifugation and further extract purification. As the samples are protected inside the membrane bag, they can be easily separated from the solvent extract after the completion of the extraction process by simply removing the membrane bag. Moreover, the membrane may hinder the transportation of macromolecules to the extract, thus resulting in a relatively cleaner extract. Due to its simplicity and excellent figures of merit, this method presents a better potential for routine analysis of polycyclic aromatic hydrocarbons in biota samples.</p></div>","PeriodicalId":54354,"journal":{"name":"Arabian Journal for Science and Engineering","volume":"49 7","pages":"9569 - 9576"},"PeriodicalIF":2.6,"publicationDate":"2024-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140364660","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"综合性期刊","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An Injectable In Situ Forming Collagen/Alginate/CaSO4 Composite Hydrogel for Tissue Engineering Applications: Optimization, Characterization and In Vitro Assessments 用于组织工程应用的可注射原位成型胶原/海藻酸盐/CaSO4 复合水凝胶:优化、表征和体外评估
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-30 DOI: 10.1007/s13369-024-08922-w
Hamsa Ashraf, Samar A. Salim, Shahira H. EL-Moslamy, Samah A. Loutfy, Elbadawy A. Kamoun

In situ injectable hydrogels are effectively employed to fill irregular cavitary bone defects with initiating bone growth in targeted areas. Herein, an injectable composited hydrogel composed of collagen and alginate cross-linked in situ using different concentrations of calcium sulfate (0.15, 0.3 and 0.6%, wt./v) was synthesized. Recently, CaSO4 is frequently supported as a bone graft material for bone regeneration, owing to its biocompatibility and osteoconductive properties. Moreover, hydroxyapatite (Hap) after salinization-step by (3-Aminopropyl) triethoxysilane (APTES) was incorporated for further enhancing the osteoconductive property of injected hydrogels. All fabricated hydrogels were characterized by SEM, FTIR and XRD analyses. While physiochemical characteristics of hydrogels were assessed through swelling index, hydrolytic degradability and thermal stability measurements. In vitro bio-assessments, e.g., antimicrobial activity, cytotoxicity and cell adhesion tests using osteoblast-like cells (MG-63) were investigated. Results showed that addition of Hap offered better control of gelation time and formed uniform hydrogels, additionally improved significantly thermal stability, which leads to hindering of swelling index, prolonging hydrolytic degradability rates and significantly enhanced the antimicrobial activity of hydrogel; compared to hydrogel free-Hap. Hap-loaded Col–Alg–CaSO4 hydrogel with the highest concentration of CaSO4 recorded an enrichment of cell viability among all hydrogel samples. Notably, In vitro cell adhesion test showed that MG-63 cells adhered adequately with all hydrogels. The results support the approach of using an injectable Hap-loaded Col/Alg hydrogel cross-linked with CaSO4 as an alter and novel technique to enhance bone tissue regeneration, host–implant integration, quick/simple technique and easier for clinical handling.

原位注射水凝胶可有效填充不规则空洞骨缺损,并在目标区域启动骨生长。本文合成了一种可注射的复合水凝胶,它由胶原蛋白和海藻酸盐组成,并使用不同浓度的硫酸钙(0.15、0.3 和 0.6%,wt./v)进行原位交联。最近,由于具有生物相容性和骨诱导特性,硫酸钙经常被用作骨再生的骨移植材料。此外,通过(3-氨基丙基)三乙氧基硅烷(APTES)盐渍化步骤后,羟基磷灰石(Hap)也被加入其中,以进一步提高注射水凝胶的骨诱导特性。所有制成的水凝胶均通过扫描电镜、傅立叶变换红外光谱和 XRD 分析进行了表征。通过膨胀指数、水解降解性和热稳定性测量评估了水凝胶的理化特性。研究了体外生物评估,如抗菌活性、细胞毒性和使用成骨细胞(MG-63)进行的细胞粘附试验。结果表明,与不含 Hap 的水凝胶相比,添加 Hap 能更好地控制凝胶时间,形成均匀的水凝胶,还能显著提高热稳定性,从而降低膨胀指数,延长水解降解率,并显著增强水凝胶的抗菌活性。在所有水凝胶样品中,Hap负载的Col-Alg-CaSO4水凝胶的CaSO4浓度最高,细胞存活率也更高。值得注意的是,体外细胞粘附测试表明,MG-63 细胞能与所有水凝胶充分粘附。这些结果支持了使用与 CaSO4 交联的可注射 Hap 负载 Col/Alg 水凝胶的方法,它是一种可改变的新技术,可促进骨组织再生、宿主与植入物的整合、快速/简单的技术以及更易于临床处理。
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引用次数: 0
WEDM Characteristics of Stir-Cast Al-TiB2 Metal Matrix Composites 搅拌铸造 Al-TiB2 金属基复合材料的线切割加工特性
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-30 DOI: 10.1007/s13369-024-08885-y
Siraj Ali Khan, Suswagata Poria, Prasanta Sahoo

This article presents an experimental investigation of the WEDM (Wire Electrical Discharge Machining) performance of Al-TiB2 composites fabricated using ultrasonic vibration-assisted stir casting and containing four different weight percentages (1%, 2.5%, 4%, and 5.5%) of TiB2 particles. Key machining parameters, namely pulse-on time, wire feed rate, and pulse-off time, are varied at three levels suitable for machining aluminium base material while minimizing wire breakage. Cutting speed, material removal rate, and kerf width are observed individually for each selected level of these process parameters. Surface features are assessed using SEM (Scanning Electron Microscope), EDAX (Energy Dispersive X-ray Spectroscopy), 3D optical surface profilometer, and optical microscopy. Notably, the roughness values are lower in the 4% and 5.5% TiB2 composites compared to the base matrix. This reduction in roughness is due to the protective role of the particles, which shield the surface from melting during the WEDM process. Melting and re-welding phenomena were observed throughout the machining process. It is observed that higher pulse-on time generates harsh sparks, leading to rougher surfaces that include melted zones and pits. The WEDM operations performed on the 5.5 wt% reinforced composite surface result in a significant reduction in roughness, decreasing from around 5 µm to approximately 2.7 µm.

本文对使用超声波振动辅助搅拌铸造技术制造的铝-TiB2 复合材料的线切割放电加工(WEDM)性能进行了实验研究,该复合材料含有四种不同重量百分比(1%、2.5%、4% 和 5.5%)的 TiB2 颗粒。关键加工参数,即脉冲开启时间、金属丝进给速率和脉冲关闭时间,在三个适合加工铝基材的水平上变化,同时尽量减少金属丝断裂。在每个选定的工艺参数水平下,分别观察切削速度、材料去除率和切口宽度。使用 SEM(扫描电子显微镜)、EDAX(能量色散 X 射线光谱仪)、3D 光学表面轮廓仪和光学显微镜对表面特征进行评估。值得注意的是,与基体相比,4% 和 5.5% TiB2 复合材料的粗糙度值较低。粗糙度降低的原因是颗粒起到了保护作用,防止表面在线切割加工过程中熔化。在整个加工过程中都观察到了熔化和再焊接现象。据观察,脉冲导通时间越长,产生的火花越大,导致表面越粗糙,包括熔化区和凹坑。对 5.5 wt% 增强复合材料表面进行线切割加工后,粗糙度显著降低,从约 5 µm 降至约 2.7 µm。
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引用次数: 0
Diagnosing Faults in Suspension System Using Machine Learning and Feature Fusion Strategy 利用机器学习和特征融合策略诊断悬挂系统故障
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-30 DOI: 10.1007/s13369-024-08924-8
H. Leela Karthikeyan, Naveen Venkatesh Sridharan, P. Arun Balaji, Sugumaran Vaithiyanathan

Comfort and safety in automobiles can be enhanced with predictive maintenance by means of early problem detection and isolation, collectively referred to as fault diagnosis. To maintain a lead position in automotive industry, fleet managers are turning to predictive analysis. In this study, an attempt was made involving feature fusion to determine most significant features required to determine the suspension faults using vibration signals and machine learning approach. Three different features extraction techniques such as statistical, histogram and autoregressive moving average model (ARMA) were extracted from the acquired vibration signals for different fault conditions at the three different loads by means of a specially fabricated experimental setup. Feature selection was done for individual features using J48 decision tree algorithm. The performance of tree-based classifiers was assessed on the chosen individual features. Additionally, each individual feature was paired with others in four distinct combinations: statistical-histogram, statistical-ARMA, ARMA-histogram and ARMA-histogram-statistical, across three different loads. These combined features were then input into tree-based algorithms to identify the optimal classification algorithm, regardless of the load conditions. The results obtained in this study indicate that the combination of the ARMA-histogram-statistical feature with a random forest classifier yields optimal classification accuracy, regardless of load conditions, with values of 98.125%, 99.375% and 96.250%, respectively, and an average computational time of 0.10 s.

通过早期问题检测和隔离(统称为故障诊断),预测性维护可提高汽车的舒适性和安全性。为了保持在汽车行业的领先地位,车队经理们开始转向预测分析。在这项研究中,我们尝试通过特征融合来确定利用振动信号和机器学习方法确定悬挂故障所需的最重要特征。通过专门制作的实验装置,从获取的振动信号中提取了三种不同的特征提取技术,如统计、直方图和自回归移动平均模型(ARMA),用于三种不同负载下的不同故障条件。使用 J48 决策树算法对单个特征进行特征选择。根据所选的单个特征对基于树的分类器的性能进行了评估。此外,在三种不同负载下,每个单独特征都与其他特征配对,形成四种不同的组合:统计-柱状图、统计-ARMA、ARMA-柱状图和 ARMA-柱状图-统计。然后将这些组合特征输入基于树的算法,以确定最佳分类算法,而不论负载条件如何。研究结果表明,无论负载条件如何,ARMA-柱状图-统计特征与随机森林分类器的组合都能产生最佳分类准确率,分别为 98.125%、99.375% 和 96.250%,平均计算时间为 0.10 秒。
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引用次数: 0
Production and Optimization of Hydroxy and Methyl Phenolic Compounds Through Microwave-Assisted Catalytic Hydrogenolysis from Lignin Valorization 通过微波辅助催化水解木质素中的羟基和甲基酚类化合物的生产与优化
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-29 DOI: 10.1007/s13369-024-08897-8
Muhammad Arif Darmawan, Muhammad Yusuf Arya Ramadhan, Hens Saputra, Sri Djangkung Sumbogo Murti, Herman Hidayat, Heri Heriyanto,  Muryanto, Nizar Amir, Tania Surya Utami, Misri Gozan

The phenol-based antioxidants as free radical scavengers are expected to continue increasing as additives in industries. As an antioxidant, lignin has low oxidative stability in pure solid form, so stabilization is needed to produce lignin-based antioxidants. This research focuses on the valorization of alkaline lignin by hydrogenolysis using a Pt/C catalyst and formic acid as a hydrogen donor. Three treatment variables, namely the amount of formic acid (FA), the amount of ethanol (EtOH), and radiation time (T), were observed for their contribution to the three responses, namely the total phenol content (TPC), the degree of depolymerization (DD), and the IC50 value of DPPH as an antioxidants activity. This study found that the best results were obtained at operating conditions FA, EtOH, and T 5 mL, 100 mL, 3 min in sequence, producing TPC, DD, and IC50 worth 4792,055 mg/ L, 23.650%, and 35.860 mg/L, respectively. The results were optimized using the response surface methodology with the Design Expert 11 program with the optimized result being FA, EtOH, and T 10 mL, 100 mL, 3 min consecutively and resulted in TPC, DD, and IC50 of 4987.12 mg/L, 26.451%, and 33.865 mg/L, respectively. The results of this study indicate that OPFEB is a source of lignin that has the potential to produce phenolic compounds, which are sources of renewable fine chemicals based on biomass.

酚基抗氧化剂作为自由基清除剂,在工业中作为添加剂的使用量预计将继续增加。作为一种抗氧化剂,木质素在纯固体形式下的氧化稳定性较低,因此需要进行稳定化处理来生产木质素基抗氧化剂。本研究的重点是使用 Pt/C 催化剂和甲酸作为氢供体,通过氢解对碱性木质素进行价值化。观察了甲酸(FA)量、乙醇(EtOH)量和辐射时间(T)这三个处理变量对总酚含量(TPC)、解聚度(DD)和作为抗氧化剂的 DPPH 的 IC50 值这三个反应的贡献。研究发现,在 FA、EtOH 和 T 5 mL、100 mL、3 min 的操作条件下获得的结果最好,产生的 TPC、DD 和 IC50 值分别为 4792 055 mg/L、23.650% 和 35.860 mg/L。使用 Design Expert 11 程序,采用响应面法对结果进行了优化,优化结果为:FA、EtOH 和 T 10 mL、100 mL、3 min 连续进行,产生的 TPC、DD 和 IC50 分别为 4987.12 mg/L、26.451% 和 33.865 mg/L。该研究结果表明,OPFEB 是一种木质素来源,具有生产酚类化合物的潜力,而酚类化合物是基于生物质的可再生精细化学品的来源。
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引用次数: 0
Facile Synthesis of Benzene Tricarboxylate-Modified Cerium, Cobalt and Zinc Nanoparticles: Structural and Electrochemical Characterization 苯三羧酸盐修饰的铈、钴和锌纳米粒子的简便合成:结构和电化学特性分析
IF 2.6 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2024-03-28 DOI: 10.1007/s13369-024-08902-0
Sabah Haider, Maria Zaib, Umar Farooq

The research on metal oxide nanoparticles (MONs) has witnessed incredible growth in recent decades as they are promising electrode materials for multiple applications. This work presents the hydrothermal synthesis of morphologically different MONs based on zinc, cobalt and cerium metals and their modifications with benzene tricarboxylic acid (BTC) using layer-by-layer assembly method. The simple and modified nanoparticles were structurally characterized by FTIR, XRD, SEM–EDX and TGA. Modified carbon paste electrodes (1% w/w) were fabricated using each of the ZnO, ZnO–Cu–BTC, Co3O4, Co3O4–Cu–BTC, CeO2 and CeO2–Cu–BTC materials separately with graphite powder in paraffin oil using 3 cc portable plastic syringe. The XRD results showed 35.5, 10.8, 14.1, 11.6, 10.2 and 8.6 nm average crystal size for ZnO, ZnO–Cu–BTC, Co3O4, Co3O4–Cu–BTC, CeO2 and CeO2–Cu–BTC, respectively. The electrochemical characterizations of each electrode were performed by EIS as well as CV. The electrochemical surface area of electrodes fabricated from ZnO, ZnO–Cu–BTC, Co3O4, Co3O4–Cu–BTC, CeO2 and CeO2–Cu–BTC materials was calculated to be 153.4, 610.4, 746.1, 951.5, 161.7, and 951.8 cm2, respectively. The results from EIS plots indicated that electrodes based on modified metal oxide nanoparticles experienced lesser charge transfer resistance as compared to that in simple metal oxide-based electrodes. All the results indicated that electrodes based on modified MONs provide better surface area, surface coverage, charge transfer coefficients and rate constants as compared to those for simple MON-based electrodes. It is concluded that modification of simple MONs with BTC provided smaller particles size, better structural morphology and redox reactions assistance, making them suitable for better electrochemical applications.

近几十年来,有关金属氧化物纳米颗粒(MONs)的研究取得了惊人的发展,因为它们是具有多种应用前景的电极材料。本研究采用逐层组装法,以锌、钴和铈金属为基础,通过水热法合成了形态各异的金属氧化物纳米颗粒,并用苯三羧酸(BTC)对其进行了修饰。通过傅立叶变换红外光谱、X 射线衍射、扫描电镜-电子显微镜和热重分析,对简单的纳米颗粒和改性纳米颗粒进行了结构表征。使用 3 cc 便携式塑料注射器,在石蜡油中分别加入 ZnO、ZnO-Cu-BTC、Co3O4、Co3O4-Cu-BTC、CeO2 和 CeO2-Cu-BTC 材料和石墨粉,制成了改性碳浆电极(1% w/w)。XRD 结果显示,ZnO、ZnO-Cu-BTC、Co3O4、Co3O4-Cu-BTC、CeO2 和 CeO2-Cu-BTC 的平均晶体尺寸分别为 35.5、10.8、14.1、11.6、10.2 和 8.6 nm。通过 EIS 和 CV 对每个电极进行了电化学表征。经计算,由 ZnO、ZnO-Cu-BTC、Co3O4、Co3O4-Cu-BTC、CeO2 和 CeO2-Cu-BTC 材料制成的电极的电化学表面积分别为 153.4、610.4、746.1、951.5、161.7 和 951.8 平方厘米。EIS 图的结果表明,与基于简单金属氧化物的电极相比,基于改性金属氧化物纳米颗粒的电极具有较小的电荷转移电阻。所有结果都表明,与简单的基于 MON 的电极相比,基于改性 MON 的电极具有更好的表面积、表面覆盖率、电荷转移系数和速率常数。结论是,用 BTC 对简单 MONs 进行改性,可使其颗粒尺寸更小、结构形态更好并有助于氧化还原反应,从而使其适用于更好的电化学应用。
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Arabian Journal for Science and Engineering
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