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Robust Trajectory Tracking Control in Two Stages of a Robot Manipulator in Quasi Linearization Form 拟线性化形式的机器人两阶段鲁棒轨迹跟踪控制
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-08-07 DOI: 10.1007/s13369-025-10508-z
Irfan Ali, Zarqa Bano, Lyu Guanghua, Ghulam E Mustafa Abro, Syed Hadi Hussain Shah

Rapid adoption of industrial robots in manufacturing highlights their critical role in achieving high productivity and precision while minimizing errors and physical strain on workers. Among these, industrial serial robots, such as SCARA manipulators, are widely implied for tasks requiring speed and accuracy, including assembly and material handling. This study presents a robust two stage trajectory tracking control scheme designed for a SCARA type robot manipulator. The approach addresses uncertainties in payload mass, external disturbances, and system dynamics. In first stage, optimal control is applied to quasilinear nominal model drive through Taylor series approximation, following Lin’s robust control frame work. The second stage incorporated an integral sliding mode controller ISMC to enhance the robustness against bounded disturbances and the system nonlinearities. The stability of the proposed method is rigorously validated using the Lyapunov function, while a boundary layer approach mitigates chattering effects and control inputs. Numerical simulation conducted on a 2-DoF SCARA manipulator demonstrate effective trajectory tracking under varying payload masses and external disturbances. The results affirm the proposed method capability to deliver robust and efficient trajectory tracking control for industrial robotic applications.

工业机器人在制造业中的快速采用凸显了它们在实现高生产率和精度,同时最大限度地减少工人的错误和身体压力方面的关键作用。其中,工业系列机器人,如SCARA机械手,广泛适用于需要速度和精度的任务,包括装配和材料处理。针对SCARA型机械臂,提出了一种鲁棒的两级轨迹跟踪控制方案。该方法解决了有效载荷质量、外部干扰和系统动力学中的不确定性。在第一阶段,根据Lin的鲁棒控制框架,通过泰勒级数逼近将最优控制应用于拟线性标称模型驱动。第二阶段引入积分滑模控制器ISMC以增强系统对有界扰动和非线性的鲁棒性。利用李雅普诺夫函数严格验证了所提方法的稳定性,而边界层方法减轻了抖振效应和控制输入。对2自由度SCARA机械臂进行了数值仿真,验证了在不同载荷质量和外部干扰下的有效轨迹跟踪。结果证实了该方法能够为工业机器人应用提供鲁棒和高效的轨迹跟踪控制。
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引用次数: 0
A Hybrid LSTM RNN and Ontology-Based Approach to Sentiment Analysis Across Multiple Arabic Dialects 基于LSTM RNN和本体的混合阿拉伯语方言情感分析方法
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-30 DOI: 10.1007/s13369-025-10406-4
Rahima Bentrcia, Kaddour Djakam, Okba Madani, Ashraf Elnagar

Sentiment Analysis (SA) is pivotal for extracting people’s opinions and feedback from texts on specific topics or products. Arabic texts often present unique challenges for SA due to their intricate combination of multiple dialects alongside Modern Standard Arabic (MSA), leading to complex regional variations. This paper addresses these complexities by introducing a sentiment analysis system tailored for the travel domain. Our system is equipped to analyze sentences encompassing a blend of Arabic dialects from regions such as the Maghreb, Nile Basin, Levant, Gulf, and Yemen, spanning 25 cities. Initially, sentences undergo preprocessing and tokenization. To account for potential misspellings, we developed a probability-driven approach to generate word variations. These variations are then processed by a trained Long Short-Term Memory Recurrent Neural Network (LSTM RNN) to predict their MSA synonyms. Concurrently, a comprehensive ontology is employed, which not only extracts the relevant dialectal variation mapped to the predicted MSA using similarity measurements but also assigns the appropriate sentiment class. The ontology further enhances accuracy by addressing excessive words and negations, given their significant role in sentiment determination. Our approach showcases its robustness with promising experimental results, achieving an overall accuracy of 85%. This work signifies a notable advancement in sentiment analysis for multi-dialectal Arabic texts, bridging the gap between diverse regional nuances and effective opinion mining.

情感分析(SA)对于从特定主题或产品的文本中提取人们的意见和反馈至关重要。由于阿拉伯语文本与现代标准阿拉伯语(MSA)复杂地结合了多种方言,导致了复杂的地区差异,因此经常对SA提出独特的挑战。本文通过引入为旅游领域量身定制的情感分析系统来解决这些复杂性。我们的系统可以分析包括马格里布、尼罗河盆地、黎凡特、海湾和也门等地区的阿拉伯方言的混合句子,涵盖25个城市。最初,句子要经过预处理和标记化。为了解决潜在的拼写错误,我们开发了一种概率驱动的方法来生成单词变体。然后通过训练好的长短期记忆递归神经网络(LSTM RNN)对这些变化进行处理,以预测它们的MSA同义词。同时,采用综合本体,通过相似性度量提取映射到预测MSA的相关方言变异,并分配相应的情感类。考虑到过多的单词和否定在情绪确定中的重要作用,本体进一步提高了准确性。我们的方法展示了它的鲁棒性和有希望的实验结果,实现了85%的总体精度。这项工作标志着多方言阿拉伯语文本情感分析的显著进步,弥合了不同地区细微差别和有效意见挖掘之间的差距。
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引用次数: 0
Applications of Remote Sensing Technologies to Assess Ground Displacements and Seismic Hazards: Precision, Scale, and Insight 遥感技术在评估地面位移和地震灾害中的应用:精度、规模和洞察力
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-30 DOI: 10.1007/s13369-025-10424-2
Aaqib Ali, Mubashir Aziz, Ali Murtaza Rasool, Umair Ali, Muhammad Umar, K. M. N. Saquib Wani

Remote sensing (RS) has emerged as a transformative tool in geotechnical earthquake engineering, enabling large-scale, high-resolution assessment of ground displacements and failure mechanisms. This review critically examines recent advancements in RS technologies including Interferometric Synthetic Aperture Radar (InSAR), Light Detection and Ranging (LiDAR), Unmanned Aerial Vehicles (UAVs), and Structure-from-Motion (SfM) photogrammetry. Each method is reviewed in terms of its application to seismic hazard assessment and ground displacement monitoring. The paper highlights the integration of RS techniques in generating 3D digital elevation models, measuring multi-axis displacements, and supporting post-disaster reconnaissance. A case study on the 2023 Kahramanmaraş earthquake in Türkiye showcases the power of multi-platform remote sensing in mapping over 3600 coseismic landslides and analyzing their spatial relationship with geological and seismic parameters. Despite substantial progress, critical gaps remain in sensor integration, real-time processing, and predictive modeling. This review emphasizes the need for AI-driven, multi-sensor frameworks and standardized workflows to move from observational insights to operational impact. By bridging geotechnical science with RS innovation, this interdisciplinary approach offers a robust pathway toward resilient infrastructure and disaster-ready communities in seismic regions.

遥感(RS)已经成为岩土地震工程的一种变革性工具,使大规模、高分辨率的地面位移和破坏机制评估成为可能。本文综述了干涉合成孔径雷达(InSAR)、光探测和测距(LiDAR)、无人机(uav)和运动结构(SfM)摄影测量等遥感技术的最新进展。对每种方法在地震危险性评估和地面位移监测中的应用进行了综述。本文重点介绍了遥感技术在生成三维数字高程模型、测量多轴位移和支持灾后侦察方面的集成。以2023年塔吉克斯坦kahramanmaraki地震为例,展示了多平台遥感在绘制3600多个同震滑坡并分析其与地质和地震参数的空间关系方面的强大功能。尽管取得了实质性进展,但在传感器集成、实时处理和预测建模方面仍存在重大差距。这篇综述强调了人工智能驱动的多传感器框架和标准化工作流程的必要性,以便从观察见解转变为运营影响。通过将岩土工程科学与RS创新相结合,这种跨学科的方法为地震地区的弹性基础设施和灾害准备社区提供了一条强有力的途径。
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引用次数: 0
Realization of a PVT-Independent Current-Mode CMOS Logarithmic Circuit 一种不依赖pvt电流模CMOS对数电路的实现
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-30 DOI: 10.1007/s13369-025-10493-3
Mazen Abouelezz, Muneer A. Al-Absi

This paper presents the realization of a current-mode and wide-range logarithmic circuit. The circuit is based on the Taylor series expansion approximation of the logarithmic function and employs MOSFET operating in saturation. The proposed circuit is insensitive to process, voltage and temperature (PVT) variations. The post-layout simulation using CADENCE Virtuoso tools validates the proposed design functionality in 0.18 ({upmu })m TSMC CMOS technology. The circuit is powered by a ±1.25 volt DC source with a normalized input range that can go from (-1) to 2 and can be used in up to 2.8 MHz application.

本文介绍了一种电流型宽量程对数电路的实现。该电路基于对数函数的泰勒级数展开近似,采用MOSFET在饱和状态下工作。该电路对工艺、电压和温度(PVT)变化不敏感。使用CADENCE Virtuoso工具进行布局后仿真,验证了在0.18 ({upmu }) m TSMC CMOS技术中提出的设计功能。该电路由±1.25伏直流电源供电,其归一化输入范围可从(-1)到2,可用于高达2.8 MHz的应用。
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引用次数: 0
A Holistic Approach Weighing Up the Pros and Cons of Winter Road Maintenance Operations: A State-of-Art Review 全面评估冬季道路养护作业的利弊:一项最新研究综述
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-29 DOI: 10.1007/s13369-025-10419-z
Abdulgazi Gedik

Heavy snow and freezing rain hit essential parts of highway networks in winter time, bringing mobility to a halt, and causing chaos and major disruptions to the road transport. Understanding the role that deicing practices and deicers play in winter road maintenance operations underscores the concordant importance of protecting transportation infrastructures and the environment. To this end, this paper aims to provide a thorough review of the existing literature and to gather prominent findings elucidating the impact of each technique and agent commonly employed in snow-fighting. Findings from previous studies revealed that, in most cases, the chloride salts-driven deteriorations provided a particularly stark example of the difficult-to reverse and unpredictable hazards to highway structures, the ecosystem and, in turn, human life. It is therefore vital to select and apply the right type and amount of deicing materials in the right place at the right time. More specifically, past scholarly work suggested that the use of chlorides should be strictly regulated, optimized and diminished by at least 50% to recover the current conjuncture. On the other hand, the adverse effects of other approaches, particularly the contribution of winter service vehicles employed in mechanical snow and ice removal to greenhouse gas emission, air pollution and climate change should not be underestimated. As this critical environmental issue has not been systematically investigated in any other reviews to date, future endeavors should address this research gap regarding the cold-climate regions overburdened by fossil-fuel reliant vehicles in snow and ice clearing. Solving this problem could promote mechanical snow clearing and lead to more extensive applications. Building upon previous literature, the purpose of this paper is to identify further research gaps in snow-fighting and to lay the groundwork for future works. Hence, this study is an attempt to incentivize policymakers and key stakeholders in transportation engineering to discover chloride salt-free deicing sources, eco-friendlier techniques, and sustainable maintenance strategies for winter roads.

在冬季,大雪和冻雨袭击了高速公路网的重要部分,导致交通中断,造成道路运输混乱和严重中断。了解除冰做法和除冰机在冬季道路养护作业中的作用,强调了保护交通基础设施和环境的协调重要性。为此,本文旨在对现有文献进行全面的回顾,并收集突出的研究结果,阐明在抗雪中常用的每种技术和药剂的影响。先前的研究结果显示,在大多数情况下,氯化物盐导致的劣化提供了一个特别鲜明的例子,说明对公路结构、生态系统以及人类生命的危害是难以逆转和不可预测的。因此,在正确的时间和地点选择和使用正确类型和数量的除冰材料是至关重要的。更具体地说,过去的学术研究表明,氯化物的使用应该严格管制,优化和减少至少50%,以恢复目前的状况。另一方面,其他方法的不利影响,特别是用于机械除雪和除冰的冬季服务车辆对温室气体排放、空气污染和气候变化的贡献不应低估。由于这一关键的环境问题尚未在任何其他评论中进行系统的调查,未来的努力应该解决这一研究差距,特别是在寒冷气候地区,依赖化石燃料的车辆在雪和冰清除中负担过重。解决这个问题可以促进机械除雪,并导致更广泛的应用。在以往文献的基础上,本文的目的是确定进一步的研究差距,并为未来的工作奠定基础。因此,本研究旨在激励交通工程领域的决策者和关键利益相关者发现无氯盐除冰来源、更环保的技术和可持续的冬季道路维护策略。
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引用次数: 0
Optimal Clustering and Mobile BS Deployment Through Improved PSO 基于改进粒子群算法的最优聚类与移动BS部署
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-29 DOI: 10.1007/s13369-025-10379-4
Gamil Ahmed, Farid Binbeshr, Maged S. Al-Quraishi, Ahmed Eltayeb, Nezar M. Alyazidi, Mahmoud S. AbouOmar, Tarek Sheltami

With the rapid advancement of technology, wireless sensor networks (WSNs) have become a prominent focus of research and development, playing a vital role in a wide range of modern sensing applications. However, their performance is often constrained by the limited energy resources of sensor nodes (SNs), significantly affecting network lifetime, particularly when the base station (BS) is located far from the sensing area. This excessive energy demand significantly reduces the overall network lifetime. Unmanned aerial vehicles (UAVs) have emerged as a promising solution to address the limitations of fixed base stations in WSNs by serving as aerial base stations. To tackle the aforementioned challenges, this paper formulates the problem as two sub-problems: clustering optimization and the strategic deployment of UAVs as aerial base stations. These problems are known to be NP-hard and cannot be solved utilizing a deterministic approach. Thus, we propose applying improved particle swarm optimization (IPSO) to tackle clustering and deployment issues, minimizing energy consumption and prolonging the sensor network’s lifespan. The simulation results of optimal clustering show significant improvement in network life time and energy consumption. Results of comparison demonstrate that the proposed algorithm outperforms the PSO, LEACH_GA algorithms in terms of the lifespan of the network and the remaining energy consumption, reaching 33.5% and 17.4% for the first node to die. Moreover, the results of UAV-assisted demonstrate a significant improvement in remaining energy consumption and network lifetime reaching 54.3% and 87.3453%, respectively. A one-way ANOVA test and 95% confidence intervals validate the statistical significance of the proposed approach performance.

随着技术的飞速发展,无线传感器网络(WSNs)已成为研究和发展的突出焦点,在广泛的现代传感应用中发挥着至关重要的作用。然而,它们的性能往往受到传感器节点(SNs)有限能量资源的限制,严重影响网络寿命,特别是当基站(BS)位于远离传感区域时。这种过度的能源需求显著降低了整个网络的生命周期。无人机(uav)作为空中基站,解决了无线传感器网络中固定基站的局限性,成为一种很有前途的解决方案。为了解决上述问题,本文将该问题分为两个子问题:集群优化问题和无人机作为空中基站的战略部署问题。这些问题被认为是np困难的,不能用确定性方法来解决。因此,我们建议应用改进的粒子群优化(IPSO)来解决聚类和部署问题,从而最大限度地减少能耗并延长传感器网络的使用寿命。仿真结果表明,最优聚类在网络寿命和能耗方面有显著改善。对比结果表明,该算法在网络寿命和剩余能量消耗方面优于PSO、LEACH_GA算法,第一个节点死亡的剩余能量消耗分别达到33.5%和17.4%。此外,无人机辅助的结果表明,剩余能量消耗和网络寿命分别达到54.3%和87.3453%。单因素方差分析检验和95%置信区间验证了所提出方法性能的统计显著性。
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引用次数: 0
Experimental Study on Wet Storage of Methane on Porous Materials 甲烷在多孔材料上湿法储存的实验研究
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-27 DOI: 10.1007/s13369-025-10456-8
Weidong Li, Shuang Li, Lin Li, Pengbo Yin, Huiyuan Li, Yufan Zhang, Yutao Cheng, Jinxin Tang, Dagang Wu

Wet storage of natural gas on porous materials in form of hydrate is an emerging and promising technology for natural gas storage and transportation. This work aims to systematically investigate methane storage on porous media in form of hydrate. A custom-designed high-pressure autoclave was constructed to evaluate methane adsorption under controlled conditions. Five commercially available porous media were used. In adsorption experiments, powdered activated carbon (PAC) shows the best methane uptake capability of 114.0 V/V among the five porous media. For most porous materials, wet storage dramatically improves methane uptake compared with dry adsorption. Notably, sodium dodecyl sulphate (SDS) aqueous solution proves to be more effective than pure water in accelerating hydrate formation. Methane uptake of SDS-added PAC reaches up to 139.5 V/V at 8 MPa, achieving a 22.4% improvement when compared with pure PAC. It is found that 200 mL of SDS solution and 2 °C of ambient temperature in the given experimental condition present the best methane uptake. Moreover, morphology of methane hydrate was directly observed and mechanism of wet storage of methane on porous media was analysed from the perspective of pore structure. Sensitivity analysis revealed that optimal methane storage on porous material requires specific water content and temperature conditions. Grain diameter of porous media presents a complex impact on the methane storage capacity and methane hydrate formation process. These findings confirm the potential of wet storage of methane in form of hydrate on porous materials and are conducive for this technology towards industrial application.

以水合物形式在多孔材料上湿法储存天然气是一种新兴的天然气储运技术。本工作旨在系统地研究甲烷在多孔介质中以水合物形式的储存。建立了一个定制的高压高压灭菌器,在控制条件下评估甲烷吸附。使用了五种市售多孔介质。在吸附实验中,粉末活性炭(PAC)吸附甲烷的能力最好,为114.0 V/V。对于大多数多孔材料,与干燥吸附相比,湿储存显著提高了甲烷的吸收率。值得注意的是,十二烷基硫酸钠(SDS)水溶液在加速水合物形成方面比纯水更有效。在8 MPa下,加入SDS的PAC的甲烷吸收率高达139.5 V/V,比纯PAC提高了22.4%。实验发现,在给定的实验条件下,200 mL SDS溶液和2℃的环境温度下,PAC的甲烷吸收率最高。直接观察了甲烷水合物的形态,并从孔隙结构角度分析了甲烷在多孔介质上湿储存的机理。敏感性分析表明,多孔材料的最佳甲烷储存需要特定的含水量和温度条件。多孔介质粒径对甲烷储集能力和甲烷水合物形成过程具有复杂的影响。这些发现证实了甲烷以水合物形式湿储存在多孔材料上的潜力,并有利于该技术的工业应用。
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引用次数: 0
Real-time Detection of Paraffin Deposits in Smart GFRP Composite Pipe using Optical Fiber and Conventional Sensors 基于光纤和传统传感器的智能玻璃钢复合管道石蜡沉积物实时检测
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-25 DOI: 10.1007/s13369-025-10486-2
Santoshi Mohanta, Jeetendra Gupta, Swati Neogi

Glass-fiber reinforced polymer (GFRP) composites pipes are increasingly opted as an alternative to metallic pipes for transportation of crude oil due to their high specific strength, superior corrosion resistance and tailor-made properties. However, during transportation of crude oil, paraffin deposits over the inside pipe surface, reducing the cross-sectional area and affecting the performance. Therefore, an effective methodology for real-time measurement of thickness of wax deposition on the inside of a smart GFRP circular pipe is explored. The proposed approach employs sensors i.e. Fiber Bragg grating (FBG) sensors, strain gauges and thermocouples which are embedded during manufacturing to monitor the real-time temperature and strain under operating condition. Water at varying temperatures and flow rate is circulated through the pipe and the resulting temperature gradient along the thickness are measured. As wax builds up, it acts as an insulating layer, reduces heat transfer and results in a measurable temperature drop. This temperature drop is correlated with the thickness of wax deposition in the pipe using heat transfer equations, provided the film heat- transfer co-efficient is calculated accurately. Additionally, the strain is recorded on real-time basis which increases linearly with the thickness of deposit. While the temperature-based estimation may under-predict thin wax layer due to little change in outlet temperature, strain measurements offer great sensitivity even to a minor deposition. Strain data also helps to locate the place of deposition along the pipe axial length. This dual parameter monitoring strategy enhances the reliability and accuracy in estimating wax thickness without disruption.

玻璃纤维增强聚合物(GFRP)复合材料管道由于其高比强度、优异的耐腐蚀性和定制性能,越来越多地被用作原油运输金属管道的替代品。然而,在原油输送过程中,石蜡沉积在管内表面,减少了截面积,影响了性能。为此,研究了一种实时测量智能玻璃钢圆管内部蜡沉积厚度的有效方法。所提出的方法采用传感器,即光纤布拉格光栅(FBG)传感器,应变片和热电偶,这些传感器在制造过程中嵌入,以监测工作条件下的实时温度和应变。不同温度和流速的水在管道中循环,并测量沿厚度产生的温度梯度。随着蜡的积累,它起到了绝缘层的作用,减少了热量的传递,并导致了可测量的温度下降。在精确计算膜层换热系数的前提下,利用换热方程计算了该温度降与管内蜡层厚度的关系。实时记录应变,应变随沉积层厚度线性增加。由于出口温度变化不大,基于温度的估计可能会低估薄蜡层,应变测量即使对少量沉积也具有很高的灵敏度。应变数据也有助于沿管道轴向长度定位沉积位置。这种双参数监测策略提高了蜡层厚度估计的可靠性和准确性。
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引用次数: 0
Acid–Alkali Activation and Synergistic Ball-Milling Co-processing of Palm Silk for Photothermal Conversion 棕榈丝光热转化的酸碱活化及协同球磨协同加工
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-25 DOI: 10.1007/s13369-025-10436-y
Yingao Jiao, Bangyi Wu, Guanzhi Wang, Cheng Pan, Xiaofei Li, Guozhi Fan, Yifei Long, Qunpeng Cheng, Haitao Yang

With issues such as the modern fossil energy crisis and energy shortage, phase change energy storage plays an important role in the conversion of renewable energy sources such as solar energy. However, its application in thermal energy storage has been limited by problems such as easy leakage, low thermal conductivity, and low energy conversion efficiency. In this work, carbon-based carriers were obtained by acid–base activation pretreatment and hybrid ball-milling post-treatment with nanocellulose. Composite phase change materials (CPCMs) with high thermal conductivity, stable morphology, and good energy storage properties were prepared by loading paraffin wax (PW). Scanning electron microscopy and Fourier transform infrared spectroscopy showed that PW was encapsulated in the supporting skeleton. BET nitrogen adsorption–desorption demonstrated that the carbon material produced by activation pyrolysis had rich pore size structures. X-ray diffractometer, laser Raman spectrometer, and visible/near-infrared spectroscopy indicated that the carbon-based carrier had good crystallinity, highly graphitized, and good light absorption properties in the full band. Differential scanning calorimetry measured the latent heat of CPCMs reached around 100 J/g, which maintained cycle stability after 50 heating/cooling cycles. With a photothermal conversion efficiency of 85.71%, this biomass-based CPCM has promising applications in solar thermal storage applications and contributes to the sustainable utilization of biomass waste.

面对现代化石能源危机和能源短缺等问题,相变储能在太阳能等可再生能源的转化中发挥着重要作用。然而,由于其易泄漏、导热系数低、能量转换效率低等问题,限制了其在储热领域的应用。采用酸碱活化预处理和纳米纤维素混合球磨后处理法制备了碳基载体。以石蜡(PW)为载体,制备了导热系数高、形貌稳定、储能性能好的复合相变材料(CPCMs)。扫描电镜和傅里叶变换红外光谱分析表明,PW被包裹在支撑骨架中。BET对氮气的吸附-解吸表明,活化热解制备的炭材料具有丰富的孔隙结构。x射线衍射仪、激光拉曼光谱仪和可见/近红外光谱分析表明,碳基载体结晶度好,石墨化程度高,在全波段具有良好的光吸收性能。差示扫描量热法测得cpcm的潜热达到100 J/g左右,在50次加热/冷却循环后仍保持循环稳定性。该生物质基CPCM光热转换效率高达85.71%,在太阳能储热应用中具有广阔的应用前景,有助于生物质废弃物的可持续利用。
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引用次数: 0
Antibacterial Activity of Hydrogel Microparticles Based on Alginate/Silver Enriched Natural Zeolite Composites 海藻酸盐/富银天然沸石复合材料水凝胶微粒的抗菌活性研究
IF 2.9 4区 综合性期刊 Q2 MULTIDISCIPLINARY SCIENCES Pub Date : 2025-07-25 DOI: 10.1007/s13369-025-10441-1
Milica Janković, Jelena Dikić, Nemanja Vučković, Nedeljko Milosavljević, Melina Kalagasidis Krušić, Nikola Milašinović

In this study, hydrogel microparticles of sodium alginate and natural zeolite – clinoptilolite enriched with silver ions were synthesized, and a zeolitic tuff from the Zlatokop mine (Vranjska Banja) containing clinoptilolite (73 wt%), quartz (10 wt%) and feldspar (7 wt%) was used. Zeolite phase from the tuff was enriched with silver ions using ion exchange method. For the synthesis, optimal parameters were determined as follows: suspension of zeolite enriched with silver ions (Ag-Z; 2.0 wt%) in water solution of sodium alginate (1.5 wt%) and 0.25 mol dm−3 solution of zinc chloride as a crosslinker. The prepared composite microparticles were characterized using Fourier-transform infrared spectroscopy (FT-IR analysis), thermal analysis (TG/DTG), swelling studies at pH = 7.4 and room temperature, and optical microscopy. Additionally, the desorption behavior of silver ions from the composites was investigated. Antibacterial activity was tested against Gram-negative bacterium Escherichia coli DSM 498 and Gram-positive bacterium Staphylococcus aureus ATCC 25923 by a disc diffusion method. The hydrogel microparticles with 2.0 wt% Ag-Z showed superior antibacterial properties compared to other synthesized samples.

本研究合成了海藻酸钠水凝胶微粒和富含银离子的天然沸石-斜发沸石,并使用了Zlatokop矿(Vranjska Banja)含斜发沸石(73%)、石英(10%)和长石(7%)的沸石凝灰岩。采用离子交换法富集凝灰岩沸石相中的银离子。合成的最佳参数为:富银离子(Ag-Z, 2.0 wt%)沸石悬浮于海藻酸钠水溶液(1.5 wt%)和0.25 mol dm−3氯化锌溶液(交联剂)中。采用傅里叶红外光谱(FT-IR)、热分析(TG/DTG)、pH = 7.4和室温下的溶胀研究以及光学显微镜对制备的复合微粒进行了表征。此外,还研究了复合材料中银离子的解吸行为。采用圆盘扩散法检测对革兰氏阴性菌大肠杆菌DSM 498和革兰氏阳性菌金黄色葡萄球菌ATCC 25923的抑菌活性。与其他合成样品相比,含2.0 wt% Ag-Z的水凝胶微颗粒具有更好的抗菌性能。
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Arabian Journal for Science and Engineering
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