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Multiscale characterization of the UV aging resistance and mechanism of light stabilizer-modified asphalt 光稳定剂改性沥青抗紫外线老化性能和机理的多尺度表征
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-02-05 DOI: 10.1515/rams-2023-0152
Wensheng Zhao, Guotao Fang, Xiao Qin, Jie Mao
To clarify the effect and mechanism of hindered amine light stabilizer (HALS) on the UV aging behavior of asphalt binder, T622-HALS was selected as the modifier for UV aging resistance of asphalt. The physicochemical properties and microstructure of T622 light stabilizer were comprehensively analyzed. The light stabilizer-modified asphalt was prepared and placed in the UV radiation chamber for UV aging treatment. Scanning electron microscope and atomic force microscope were used to analyze the microscopic morphology evolution of light stabilizer-modified asphalt induced by UV radiation. The thermal properties and functional group composition changes in light stabilizer-modified asphalt during UV aging were studied by using the thermogravimetric and infrared spectroscopy combined testing system. The decay laws of the physical and rheological performances of light stabilizer-modified asphalt were studied during UV aging process, and the effect of light stabilizer on the UV aging behavior of asphalt binder was clarified. The research results indicated that HALSs could alleviate the microcracks and roughness change on the surface of asphalt and reduce the content of functional groups such as carbonyl and sulfoxide in asphalt. Furthermore, HALS could reduce the value difference of physical and rheological properties of asphalt before and after UV aging, significantly improving the UV aging resistance of asphalt binder.
为阐明受阻胺光稳定剂(HALS)对沥青胶结料紫外光老化行为的影响及机理,选择 T622-HALS 作为沥青抗紫外光老化改性剂。对 T622 光稳定剂的理化性质和微观结构进行了综合分析。制备出光稳定剂改性沥青,并将其置于紫外辐射箱中进行紫外老化处理。使用扫描电子显微镜和原子力显微镜分析了紫外辐射诱导光稳定剂改性沥青的微观形貌演变。利用热重和红外光谱联合测试系统研究了紫外老化过程中光稳定剂改性沥青的热性能和官能团组成变化。研究了光稳定剂改性沥青在紫外老化过程中物理和流变性能的衰减规律,明确了光稳定剂对沥青胶结料紫外老化行为的影响。研究结果表明,HALS 可减轻沥青表面的微裂缝和粗糙度变化,降低沥青中羰基和亚砜等官能团的含量。此外,HALS 还能缩小紫外线老化前后沥青物理和流变特性的数值差异,显著提高沥青胶结料的抗紫外线老化性能。
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引用次数: 0
Characterization of sandwich materials – Nomex-Aramid carbon fiber performances under mechanical loadings: Nonlinear FE and convergence studies 夹层材料的特性分析 - Nomex-Aramid 碳纤维在机械载荷下的性能:非线性 FE 和收敛研究
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-31 DOI: 10.1515/rams-2023-0177
Andreal Muhammad Naufal, Aditya Rio Prabowo, Teguh Muttaqie, Arif Hidayat, Joko Purwono, Ristiyanto Adiputra, Hammar Ilham Akbar, Dharu Feby Smaradhana
Composites are becoming materials of the future. Composite applications have become popular in the air as airframes in the aerospace industry to the deepest seas in the form of underwater pipes. A sandwich structure is a composite with cores with low-density material pinned by a stiff facing. In this article, the sandwich material used is a Nomex-Aramid honeycomb as the core and carbon fiber composite as the facing sandwich structure. The main goal of this study is to obtain the characteristics of the sandwich structure, Nomex-Aramid carbon fiber, and study the effect of core variation on the overall strength of the sandwich structure. Numerical simulation testing was carried out to determine the characteristics of the sandwich structure. The loadings carried out were mainly three-point bending, tensile, compression, and torsional tests. In addition, this study also compared the geometry of cores and several materials to study the effect of core properties on the overall strength of the materials. The authors used the finite element method with ABAQUS. A mesh convergence study was also conducted in this article. The results of the numerical simulation showed that the structure sandwich had a major drawback in the local strength caused by the size of the cells used. In addition, the geometric shape and type of the core material also affected the strength of the sandwich structure.
复合材料正在成为未来的材料。从航空航天工业的空中机身到深海中的水下管道,复合材料的应用已变得十分普遍。三明治夹层结构是一种复合材料,其核心是低密度材料,并由坚硬的面层固定。本文使用的夹层材料是以 Nomex-Aramid 蜂窝为芯,碳纤维复合材料为面的夹层结构。本研究的主要目标是获得夹层结构、Nomex-Aramid 碳纤维的特性,并研究芯材变化对夹层结构整体强度的影响。为确定夹层结构的特性,进行了数值模拟测试。所进行的加载主要是三点弯曲、拉伸、压缩和扭转试验。此外,这项研究还比较了芯材和几种材料的几何形状,以研究芯材特性对材料整体强度的影响。作者使用了 ABAQUS 的有限元方法。本文还进行了网格收敛研究。数值模拟结果表明,结构夹层在局部强度方面存在重大缺陷,这是由所使用的单元尺寸造成的。此外,芯材的几何形状和类型也会影响夹层结构的强度。
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引用次数: 0
Study on the mechanical properties and microstructure of recycled brick aggregate concrete with waste fiber 废纤维再生砖骨料混凝土的力学性能和微观结构研究
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-30 DOI: 10.1515/rams-2023-0175
Ting Wang, Shenao Cui, Xiaoyu Ren, Weishen Zhang, Xuechao Yang, Shangwei Gong, Deqiang Yang, Bangxiang Li, Wengang Zhang, Tian Su, Xuefeng Mei, Xiaoming Dong, Liancheng Duan, Zhiyuan Ma, Xueyun Cao, Xiyao Yu
Recycled concrete technology can promote the sustainable development of the construction industry, but the insufficient mechanical properties of recycled concrete have become a key constraint on its development. By adding waste fibers, the mechanical properties of recycled concrete can be improved, and the problem of disposing of waste polypropylene fibers can be solved. In this article, the effects of recycled brick aggregate content and waste fiber content on the mechanical properties and microstructures of recycled brick aggregate concrete through macroscopic mechanical experiments and microstructure experiments are investigated. The results show that the addition of recycled brick aggregate reduces the mechanical properties of concrete; when the content of recycled brick aggregate is 100%, the compressive strength and splitting tensile strength decrease by 22.04 and 20.00%, respectively. The addition of waste fibers can improve the mechanical properties of recycled brick aggregate concrete, but it is necessary to control the contents of waste fibers in a certain range. When the content of waste fibers is 0.08%, the best improvement effect on the mechanical properties of concrete is achieved; the compressive strength of concrete with a 50% (100%) recycled aggregate replacement rate increases by 6.06% (8.90%), while the splitting tensile strength of concrete with a 50% (100%) recycled aggregate replacement rate increases by 2.30% (6.16%). Through microstructural analysis, the mechanism by which waste fiber improves the mechanical properties of recycled brick aggregate concrete is revealed. The addition of waste fibers has the effect of strengthening the framework inside the recycled brick aggregate concrete, forming a good structural stress system and allowing the recycled brick aggregate concrete to continue to bear loads after cracking. In this study, waste brick aggregate and waste fiber are effectively utilized, which can not only reduce pollution to the environment but also realize the sustainable utilization of resources.
再生混凝土技术可以促进建筑业的可持续发展,但再生混凝土的力学性能不足已成为制约其发展的关键因素。通过添加废纤维,可以改善再生混凝土的力学性能,并解决废聚丙烯纤维的处理问题。本文通过宏观力学实验和微观结构实验,研究了再生砖骨料含量和废纤维含量对再生砖骨料混凝土力学性能和微观结构的影响。结果表明,再生砖骨料的加入会降低混凝土的力学性能;当再生砖骨料含量为 100%时,抗压强度和劈裂抗拉强度分别降低了 22.04% 和 20.00%。添加废纤维可以改善再生砖骨料混凝土的力学性能,但必须将废纤维的含量控制在一定范围内。当废纤维含量为 0.08% 时,对混凝土力学性能的改善效果最好;再生骨料替代率为 50% (100%)的混凝土抗压强度提高了 6.06% (8.90%),再生骨料替代率为 50% (100%)的混凝土劈裂抗拉强度提高了 2.30% (6.16%)。通过微观结构分析,揭示了废纤维改善再生砖骨料混凝土力学性能的机理。废纤维的加入具有强化再生砖骨料混凝土内部骨架的作用,形成良好的结构应力体系,使再生砖骨料混凝土在开裂后仍能继续承受荷载。本研究有效利用了废砖骨料和废纤维,不仅能减少对环境的污染,还能实现资源的可持续利用。
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引用次数: 0
Study on dynamic response of cushion layer-reinforced concrete slab under rockfall impact based on smoothed particle hydrodynamics and finite-element method coupling 基于平滑粒子流体力学和有限元法耦合的落石冲击下缓冲层加固混凝土板的动态响应研究
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-27 DOI: 10.1515/rams-2023-0176
Xuefeng Mei, Jianli Wu, Teng Wang, Ting Wang, Xiaofei Liang, Yanping Wang, Bangxiang Li, Tian Su, Lina Xu
In the rockfall prevention and control project, the reinforced concrete (RC) slab and sand (gravel soil) soil cushion layer are commonly used to form the protection structure, thereby resisting the rockfall impact. Considering that the oversized deformation of the cushion layer under impact load using the finite element simulation cannot converge, this article establishes a numerical calculation model using smoothed particle hydrodynamics–finite-element method coupling (SPH–FEM). First, the standard Lagrange finite-element mesh is established for the whole model using ABAQUS, and then the finite-element mesh of the soil cushion layer is converted to SPH particle at the initial moment of the calculation, and finally the calculation results are solved and outputted. The results indicate that, compared with the results of the outdoor rockfall impact test, the relative errors of the rockfall impact force and the displacement of the RC slab are within 10%, which proves the rationality of the coupling algorithm; moreover, in terms of the numerical simulation, the SPH–FEM coupling algorithm is more practical than the finite element for reproducing the mobility of the rockfall impacting the sand and soil particles. In addition, at an impact speed of less than 12 m·s−1, the cushion layer is able to absorb more than 85% of the impact energy, which effectively ensures that the RC slab is in an elastic working state under small impact energy and does not undergo destructive damage under large impact energy; the peak impact force of the rockfall is approximately linear with the velocity, and the simulated value of the peak impact force is basically the same as that of the theoretical value of Hertz theory; the numerical simulation is good for reproducing the damage process of the RC slab in accordance with the actual situation. The SPH–FEM coupling algorithm is more justified than the FEM in simulating the large deformation problem, and it can provide a new calculation method for the design and calculation of the rockfall protection structure.
在落石防治工程中,通常采用钢筋混凝土(RC)板和砂(砾石土)土垫层组成防护结构,从而抵御落石冲击。考虑到有限元模拟无法收敛缓冲层在冲击荷载作用下的超大变形,本文建立了平滑粒子流体力学-有限元法耦合(SPH-FEM)数值计算模型。首先利用 ABAQUS 为整个模型建立标准拉格朗日有限元网格,然后在计算初始时刻将土垫层的有限元网格转换为 SPH 粒子网格,最后求解并输出计算结果。结果表明,与室外落石冲击试验结果相比,落石冲击力和 RC 板位移的相对误差均在 10%以内,证明了耦合算法的合理性;而且,在数值模拟方面,SPH-FEM 耦合算法比有限元更能真实再现落石冲击砂土颗粒的流动性。此外,在冲击速度小于 12 m-s-1 时,缓冲层能够吸收 85% 以上的冲击能量,有效保证了 RC 板在小冲击能量下处于弹性工作状态,在大冲击能量下不会发生破坏性损伤;落石的冲击力峰值与速度近似成线性关系,冲击力峰值的模拟值与赫兹理论的理论值基本一致;数值模拟能够很好地再现 RC 板的损伤过程,符合实际情况。SPH-FEM耦合算法在模拟大变形问题上比有限元更加合理,可为落石防护结构的设计计算提供一种新的计算方法。
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引用次数: 0
Effect of the axial compression ratio on the seismic behavior of resilient concrete walls with concealed column stirrups 轴压比对暗柱箍筋弹性混凝土墙抗震性能的影响
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-27 DOI: 10.1515/rams-2023-0166
Weiguang Yuan, Yingda Zhang, Qiang Xiao, Zuowei Liu
The axial compression ratio is one of the important factors affecting the seismic performance of reinforced concrete (RC) walls. Thus, the axial compression ratio is critical in the seismic design of RC walls. In addition to the axial compression ratio, the other significant experimental parameter is the stirrup form of the boundary elements. To study the effect of the axial compression ratio and the stirrup form on the seismic behavior of ductile RC walls reinforced by prestressed concrete strands, four full-scale concrete walls were constructed and subjected to reversed cyclic lateral loading while experiencing constant axial compression, with axial load ratios set at 0.17 and 0.26. The considered stirrup forms of the boundary elements are circular and compound, respectively. All specimens exhibit significant drift-hardening capability with a small residual drift and a small crack width. The ultimate capacity, ductility, stiffness and attenuation process, hysteretic characteristics, energy dissipation capacity, residual deformation, and maximum and residual crack width of the shear walls are compared and analyzed. The experimental results and comparisons between the two groups of shear walls with different axial compression ratios and stirrup forms of concealed columns are presented. The characteristics of the envelope curve are also analyzed, and a simplified bilinear envelope curve model is proposed to better fit the test results.
轴压比是影响钢筋混凝土(RC)墙抗震性能的重要因素之一。因此,轴压比在 RC 墙体的抗震设计中至关重要。除了轴压比,另一个重要的实验参数是边界元素的箍筋形式。为了研究轴向压缩比和箍筋形式对预应力混凝土钢绞线加固的延性 RC 墙体抗震行为的影响,我们建造了四堵全尺寸混凝土墙体,并在承受恒定轴向压缩的同时承受反向循环侧向荷载,轴向荷载比分别设置为 0.17 和 0.26。所考虑的边界元素箍筋形式分别为圆形和复合型。所有试样都表现出明显的漂移硬化能力,残余漂移小,裂缝宽度小。对剪力墙的极限承载力、延性、刚度和衰减过程、滞后特性、耗能能力、残余变形以及最大和残余裂缝宽度进行了比较和分析。介绍了两组不同轴向压缩比和暗柱箍筋形式的剪力墙的实验结果和比较。还分析了包络曲线的特征,并提出了简化的双线性包络曲线模型,以更好地拟合试验结果。
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引用次数: 0
Coverage and reliability improvement of copper metallization layer in through hole at BGA area during load board manufacture 负载板制造过程中 BGA 区域通孔金属化铜层的覆盖率和可靠性改进
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-22 DOI: 10.1515/rams-2023-0163
Kai Zhu, Ruimin Xing, Zhongming Jiang, Rongjun Zhong, Liuming Chen, Jianhui Liu, Hua Miao, Guoyun Zhou
The dimple of ball grid array (BGA) area with 70 mm × 70 mm size on load board for high performance integrated circuit final test is investigated by shadow moire at first, the dimple of BGA area decreases from 184.3 to 97.1 μm when six additional prepregs with 60 mm × 60 mm size are added at BGA area before hot lamination process. The micromorphology and stress/strain simulation are conducted to improve the coverage and reliability of copper metallization layer in through hole at that BGA area. The microcracks of electroless copper layer at the position of glass fiber and inner layer copper pad, which leads to serious crack after solder float, are well covered by subsequent electroplating copper layer. When the through holes at BGA area with 0.2 mm diameter and 7.0 mm depth are fabricated based on insulating dielectric material used for high-speed signal transmission, the simulation results point out that IT968 is better than M6G for the thermal shock reliability of through hole metallization layer. A load board vehicle with 126 layers and 8.3 mm thickness based on IT968 shows good interconnection structure reliability after 12 times 288°C solder float.
首先通过阴影摩尔法研究了高性能集成电路最终测试用负载板上 70 mm × 70 mm 大小的球栅阵列(BGA)区域的凹痕,当在热层压工艺前在 BGA 区域增加 6 个 60 mm × 60 mm 大小的预浸料时,BGA 区域的凹痕从 184.3 μm 减小到 97.1 μm。为了提高该 BGA 区域通孔金属化铜层的覆盖率和可靠性,进行了微观形态和应力/应变模拟。玻璃纤维和内层铜垫位置的化学铜层微裂纹导致浮焊后出现严重裂纹,而后续的电镀铜层能很好地覆盖这些裂纹。当基于用于高速信号传输的绝缘介质材料在 BGA 区域制作直径为 0.2 mm、深度为 7.0 mm 的通孔时,仿真结果表明 IT968 在通孔金属化层的热冲击可靠性方面优于 M6G。基于 IT968 的负载板车有 126 层,厚度为 8.3 毫米,在经过 12 次 288°C 焊接浮动后,显示出良好的互连结构可靠性。
{"title":"Coverage and reliability improvement of copper metallization layer in through hole at BGA area during load board manufacture","authors":"Kai Zhu, Ruimin Xing, Zhongming Jiang, Rongjun Zhong, Liuming Chen, Jianhui Liu, Hua Miao, Guoyun Zhou","doi":"10.1515/rams-2023-0163","DOIUrl":"https://doi.org/10.1515/rams-2023-0163","url":null,"abstract":"The dimple of ball grid array (BGA) area with 70 mm × 70 mm size on load board for high performance integrated circuit final test is investigated by shadow moire at first, the dimple of BGA area decreases from 184.3 to 97.1 μm when six additional prepregs with 60 mm × 60 mm size are added at BGA area before hot lamination process. The micromorphology and stress/strain simulation are conducted to improve the coverage and reliability of copper metallization layer in through hole at that BGA area. The microcracks of electroless copper layer at the position of glass fiber and inner layer copper pad, which leads to serious crack after solder float, are well covered by subsequent electroplating copper layer. When the through holes at BGA area with 0.2 mm diameter and 7.0 mm depth are fabricated based on insulating dielectric material used for high-speed signal transmission, the simulation results point out that IT968 is better than M6G for the thermal shock reliability of through hole metallization layer. A load board vehicle with 126 layers and 8.3 mm thickness based on IT968 shows good interconnection structure reliability after 12 times 288°C solder float.","PeriodicalId":54484,"journal":{"name":"Reviews on Advanced Materials Science","volume":"54 1","pages":""},"PeriodicalIF":3.6,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139556351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Latest research progress of SiCp/Al composite for electronic packaging 用于电子封装的 SiCp/Al 复合材料的最新研究进展
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-13 DOI: 10.1515/rams-2023-0158
Hong Yu, Liu Jiaqin, Wu Yucheng
With the rapid development, microelectronic technology has put forward strict requirements for electronic packaging materials (EPMs). SiCp/Al composites with high volume fraction of SiC has become an ideal candidate for EPMs due to their superior properties including high thermal conductivity, tailorable coefficient of thermal expansion as well as low density in many fields. This study reviewed the manufacturing process of SiCp/Al composites in recent years. In addition, the interface between particle and matrix, the application, and the development trend of SiCp/Al composites has also been summarized.
随着微电子技术的快速发展,对电子封装材料(EPM)提出了严格的要求。含有高体积分数 SiC 的 SiCp/Al 复合材料在许多领域都具有高热导率、可调热膨胀系数和低密度等优越性能,因此已成为 EPM 的理想候选材料。本研究回顾了近年来 SiCp/Al 复合材料的制造工艺。此外,还总结了 SiCp/Al 复合材料颗粒与基体之间的界面、应用和发展趋势。
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引用次数: 0
Research on key casting process of high-grade CNC machine tool bed nodular cast iron 高档数控机床床身球墨铸铁关键铸造工艺研究
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-10 DOI: 10.1515/rams-2023-0164
Yang Chen, Shilei Li, Jianhua Huang, Teng Hu, Xiaohu Li, Chentao Li, Guang Xian, Changchun Zhou, Hongyuan Fan
The bed structure of high-grade large-scale CNC machine tools is crucial for maintaining their long-term service accuracy. This study focused on the key casting process of large nodular cast iron beds. AnyCasting software was employed to simulate and analyze the casting scheme, and then the mold filling and solidification processes were proposed based on the simulation results. The proposed casting scheme indicates that the designed gating system exhibited excellent filling capability. The dual sprue ceramic pipe bottom pouring technique, in conjunction with the chills, not only improved casting efficiency but also met the requirements of sequential solidification design. The castings possessed a dense microstructure characterized by uniform and stable phase composition, primarily comprising lamellar pearlite, with ≤0.5% of phosphorus eutectic and cementite. Furthermore, the microstructure of these materials displayed favorable graphite morphology with a spheroidization rate exceeding 85% and spheroidization grade of 2–3. This study has important academic and application value for the casting process of producing low-stress, high-grade CNC machine tool bed cast iron materials.
高档大型数控机床的床身结构对保持其长期使用精度至关重要。本研究的重点是大型球墨铸铁床身的关键铸造工艺。采用 AnyCasting 软件对铸造方案进行了模拟分析,并根据模拟结果提出了充型和凝固工艺。所提出的浇注方案表明,所设计的浇口系统具有出色的充型能力。双浇口陶瓷管底浇注技术与冷却技术相结合,不仅提高了浇注效率,而且满足了顺序凝固设计的要求。铸件具有致密的微观结构,相组成均匀稳定,主要由片状珠光体组成,磷共晶和雪明碳酸盐含量≤0.5%。此外,这些材料的微观结构显示出良好的石墨形态,球化率超过 85%,球化等级为 2-3。这项研究对生产低应力、高等级数控机床床身铸铁材料的铸造工艺具有重要的学术价值和应用价值。
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引用次数: 0
Influence of ultrasonication time on the various properties of alkaline-treated mango seed waste filler reinforced PVA biocomposite 超声时间对碱处理芒果籽废料填料增强 PVA 生物复合材料各种性能的影响
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-08 DOI: 10.1515/rams-2023-0137
Mochamad Asrofi, Rizki Setyobudi, R. A. Ilyas, M. L. Sanyang, A. O. Adegbenjo, I. Idris, Senthil Muthu Kumar Thiagamani, C. D. Midhun Dominic, V. F. Knight, M. N. F. Norrrahim, L. Rajeshkumar, M. R. M. Asyraf
The usage of biodegradable materials is gaining mounting applications owing to the environmental problems created by petroleum-based synthetic materials. Agro-waste materials are finding more scope as reinforcement materials in polymer composites, mainly because of their cost-effectiveness and availability. The main aim of this research work is to utilize agro-waste material in the form of mango seed waste (MSW) as a reinforcing material with polyvinyl alcohol (PVA) to form biocomposite. The biocomposites were fabricated using the solution casting technique. The research work focuses on the influence of varying ultrasonication periods (0–20 min at 5-min intervals, i.e., 0, 5, 10, 15, and 20 min) on the properties of PVA/MSW biocomposites. The fabricated biocomposites were subjected to tensile test, fracture morphology, moisture absorption (MA), Fourier transform infrared spectroscopy, and thermogravimetric analysis. The results revealed that the material with the highest tensile strength was 3.95 MPa obtained with the 20-min ultrasonication sample. This value is 49% higher than that obtained in the sample without ultrasonication. The scanning electron microscopy analysis shows that the 20-min ultrasonication sample indicated a good distribution of MSW fillers in the PVA contrasted with the rest of the samples. The thermal stability of the samples treated with ultrasonication was found to be significantly higher than that of the untreated samples, whereas the MA value decreased with increasing ultrasonication time. It can be observed from the results that biocomposites can be a potential alternative to the synthetic materials used in packaging applications.
由于石油基合成材料造成的环境问题,可生物降解材料的应用越来越广泛。农业废弃物材料作为聚合物复合材料的增强材料,其成本效益和可用性使其具有更大的应用空间。这项研究工作的主要目的是利用芒果种子废料(MSW)作为增强材料,与聚乙烯醇(PVA)形成生物复合材料。生物复合材料采用溶液浇铸技术制成。研究工作的重点是不同超声处理时间(0-20 分钟,间隔 5 分钟,即 0、5、10、15 和 20 分钟)对 PVA/MSW 生物复合材料性能的影响。对制成的生物复合材料进行了拉伸试验、断口形貌、吸湿性(MA)、傅立叶变换红外光谱和热重分析。结果显示,20 分钟超声处理样品的拉伸强度最高,达到 3.95 兆帕。这一数值比未经超声处理的样品高出 49%。扫描电子显微镜分析表明,与其他样品相比,超声处理 20 分钟的样品表明 MSW 填料在 PVA 中分布良好。经超声处理的样品的热稳定性明显高于未处理的样品,而 MA 值则随着超声时间的延长而降低。从结果中可以看出,生物复合材料是包装应用中合成材料的潜在替代品。
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引用次数: 0
High-entropy alloys: A review of their performance as promising materials for hydrogen and molten salt storage 高熵合金:高熵合金:作为有前途的储氢和熔盐材料的性能综述
IF 3.6 4区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-01-03 DOI: 10.1515/rams-2023-0150
Fabiola Pineda, Carola Martínez, Pablo Martin, Claudio Aguilar
Fossil fuels have been the most employed energy source with a consistent and growing consumption; however, they will be replaced by renewable energy sources (RESs). Massively using this type of energy will require new materials, especially metallic-based materials, because the typical materials have shown poor performance. In particular, hydrogen obtained from RESs has technological concerns like absorption/desorption cycling, kinetics, and cost. Similarly, the solar industry demands highly corrosion-resistant materials at high temperatures. As mentioned above, these could be solved using high-entropy alloys (HEAs). HEAs are barely around 15 years old and have been intensively investigated to be used for wide technological and scientific applications due to their unusual mechanical, physical, and chemical properties. Thus, this study summarizes advances in HEAs as promising materials for hydrogen and energy molten salt storage technologies and discusses the corrosion performance of current HEAs, considering both the microstructure and constituent element effect.
化石燃料一直是最常用的能源,其消耗量持续增长;然而,化石燃料将被可再生能源(RES)所取代。大规模使用这种能源需要新材料,尤其是金属材料,因为传统材料的性能较差。特别是,从可再生能源中获取氢气存在吸收/解吸循环、动力学和成本等技术问题。同样,太阳能产业也需要在高温下具有高度耐腐蚀性的材料。如上所述,高熵合金(HEAs)可以解决这些问题。高熵合金问世不到 15 年,由于其不同寻常的机械、物理和化学性质,已被广泛应用于技术和科学领域。因此,本研究总结了 HEAs 作为氢和能源熔盐存储技术的理想材料所取得的进展,并讨论了当前 HEAs 的腐蚀性能,同时考虑了微观结构和组成元素的影响。
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引用次数: 0
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Reviews on Advanced Materials Science
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