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A High Channel Mobility and a Normally‐off Operation of a Vertical GaN MOSFET Using an AlSiO/AlN Gate Stack Structure on m‐plane Trench Sidewall m 平面沟槽侧壁上使用氧化铝/氮化铝栅极叠层结构的垂直 GaN MOSFET 的高沟道迁移率和常关断操作
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-23 DOI: 10.1002/pssr.202400010
Masakazu Kanechika, Kenji Ito, Tetsuo Narita, Kazuyoshi Tomita, Shiro Iwasaki, Daigo Kikuta, Tetsu Kachi
We previously developed an AlSiO/AlN‐interlayer gate stack formed on c‐plane GaN metal‐oxide‐semiconductor (MOS) devices to enhance the interface of the gate insulator. By utilizing this gate stack structure, we obtained a channel mobility of over 200 cm2/Vs on c‐plane. However, the threshold voltage was negative because of the polarization charge at the AlN/GaN interface. This study extends the application of this gate stack structure to the nonpolar m‐plane, which is obtained from a trench sidewall. We successfully achieve both a high channel mobility of 150 cm2/Vs and a threshold voltage of 1.3 V, normally‐off operation. This achievement holds significant promise for the gate structure of a GaN trench‐gate MOS field‐effect transistor. The limiting factor of the channel mobility is Coulomb scattering in a low electric field, whereas surface roughness scattering is dominant in a higher field.This article is protected by copyright. All rights reserved.
我们之前开发了一种在 c 平面氮化镓金属氧化物半导体(MOS)器件上形成的 AlSiO/AlN 夹层栅极堆栈,以增强栅极绝缘体的界面。利用这种栅极堆栈结构,我们在 c 平面上获得了超过 200 cm2/Vs 的沟道迁移率。然而,由于 AlN/GaN 界面的极化电荷,阈值电压为负。本研究将这种栅极叠层结构的应用扩展到了非极性 m 面,即通过沟槽侧壁获得的 m 面。我们成功地实现了 150 cm2/Vs 的高沟道迁移率和 1.3 V 的正常关断工作阈值电压。这一成果为氮化镓沟槽栅 MOS 场效应晶体管的栅极结构带来了重大希望。沟道迁移率的限制因素是低电场下的库仑散射,而表面粗糙度散射在高电场下占主导地位。本文受版权保护。
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引用次数: 0
Metastability in Dark Current Diode Characteristics of Chalcogenide Photovoltaic Modules 卤化铝光伏组件暗电流二极管特性的易变性
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-23 DOI: 10.1002/pssr.202300239
Bettina Friedel
While present trends in commercial PV are set on a‐Si/c‐Si heterojunctions and promising perovskites, the chalcogenides still attract interest as an excellent candidate for coming multi‐ and heterojunction devices with perovskites. Continuously enhanced over the years, typical metastabilities in thin film devices still remain, causing issues under outdoor operation. Unfortunately, qualitative assessment in commercial PV is solely focused on data at the maximum power point of its operation, whether in simple on‐site PV plant monitoring or following latest standards for certified laboratory testing, thus metastabilities merely register as undefined power fluctuations. We show in this study that dark current characteristics are a simple and yet field‐fit method, to identify metastable changes and take suitable counter measures. With this study, using commercial CdTe and CIGS showcase modules of various manufacturers and production generations, we demonstrate how dark current characteristics allow to pin‐point physical changes of the individual module, between its pristine state, outdoor operation, dark degradation and stabilization, like a fingerprint. Using the two‐diode model, we show that alterations to respective regimes of the characteristic can be assigned to typical defects, defining the module’s current state, and be used to it as a guide to evaluate its recuperation via preconditioning treatments.This article is protected by copyright. All rights reserved.
虽然目前商用光伏技术的发展趋势是非晶硅/微晶硅异质结和前景广阔的包晶体,但钙化物作为未来与包晶体的多结和异质结设备的最佳候选材料,仍然备受关注。多年来,薄膜设备的性能不断提高,但其典型的迁移性仍然存在,在户外运行时会产生问题。遗憾的是,无论是在简单的现场光伏电站监测中,还是按照最新的认证实验室测试标准,商用光伏设备的定性评估都只关注其运行的最大功率点数据,因此陨石效应只是作为未定义的功率波动记录在案。我们在本研究中表明,暗电流特性是一种简单且适合现场的方法,可用于识别瞬变并采取适当的应对措施。通过这项研究,我们利用不同制造商和不同生产世代的商用碲化镉和铜铟镓硒展示模块,展示了暗电流特性如何像指纹一样,精确定位单个模块在原始状态、户外运行、暗衰减和稳定之间的物理变化。通过使用双二极管模型,我们展示了该特性在不同状态下的变化可以归因于典型的缺陷,从而确定模块的当前状态,并以此为指导,评估模块通过预处理后的恢复情况。本文受版权保护,保留所有权利。
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引用次数: 0
High‐Performance of Self‐Powered UV‐Visible CdS (PVP)/PbI2 Heterojunction Photodetector 高性能自供电紫外可见 CdS(PVP)/PbI2 异质结光电探测器
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-23 DOI: 10.1002/pssr.202400009
Lei Yang, Mingkun Huang, Yue Wang, Yuanhao Kang, Le Wang, Niumiao Zhang
In this work, the PVP‐assisted CdS/PbI2 heterojunction UV‐Visible Photodetector was constructed by the sol‐gel spin coating method. The X‐ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) demonstrated the synthesis and successful complexation of PVP, CdS, and PbI2. The UV‐Visible absorption spectroscopy and UV photoelectron spectroscopy (UPS) measurements of CdS and PbI2 were carried out to prove that the CdS and PbI2 form a type II heterojunction. Compared with pure CdS film photodetector, the CdS (PVP)/PbI2 heterojunction photodetector has self‐powered characteristics, and exhibits excellent photoconductivity in the UV‐Visible with higher switching ratios, detection rates, and faster response times of 1.1 × 105, 9.77 × 1011 Jones and 20 ms, respectively, which has great potential in the field of UV‐Visible self‐powered photodetector.This article is protected by copyright. All rights reserved.
本研究采用溶胶-凝胶旋涂法构建了 PVP 辅助 CdS/PbI2 异质结紫外-可见光光电探测器。X 射线衍射(XRD)、扫描电子显微镜(SEM)和能量色散光谱仪(EDS)证明了 PVP、CdS 和 PbI2 的合成和成功络合。对 CdS 和 PbI2 的紫外可见吸收光谱和紫外光电子能谱(UPS)进行了测量,证明 CdS 和 PbI2 形成了 II 型异质结。与纯 CdS 薄膜光电探测器相比,CdS(PVP)/PbI2 异质结光电探测器具有自供电特性,在紫外-可见光下表现出优异的光电导性,具有更高的开关比、检测率和更快的响应时间,分别为 1.1 × 105、9.77 × 1011 Jones 和 20 ms,在紫外-可见光自供电光电探测器领域具有巨大潜力。本文受版权保护。
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引用次数: 0
High performance amorphous IGO TFTs grown at low temperature 低温生长的高性能非晶 IGO TFT
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-19 DOI: 10.1002/pssr.202300457
Chuan Peng, Han He, Hao Huang, Yongyuan Shang, Zipeng Feng, Zhipeng Zhang, Chunlan Wang, Bingsuo Zou, Liu Xingqiang
Polycrystalline indium gallium oxide has been widely studied in the domain of oxide thin film transistors (TFTs) due to its high mobility. However, there are few researches focus on amorphous IGO (a‐IGO), which has the advantage of large area display. Herein, high‐performance a‐IGO TFTs are demonstrated by magnetron sputtering method with simple process. The efficiency of a‐IGO TFTs fabricated under various conditions are evaluated, and a‐IGO TFTs prepared by 27 nm thin films grown at 220 °C have the best electrical properties. It exhibits the mobility of 35 cm2 V‐1 s‐1, threshold voltage of 0.5 V, subthreshold swing of 0.8 V/dec, and the on/off current ratio over 106. This is due to the precise control of the deposition energy state by temperature during sputtering and the influence of the semiconductor layer thickness on the distribution of the accumulation layer. The results present here demonstrate a simple fabrication method for high‐performance amorphous oxide thin film transistors, providing a new option for display driver circuits.This article is protected by copyright. All rights reserved.
多晶氧化铟镓因其高迁移率而在氧化物薄膜晶体管(TFT)领域被广泛研究。然而,很少有研究关注非晶氧化铟镓(a-IGO),因为它具有大面积显示的优势。本文通过磁控溅射法展示了工艺简单的高性能 a-IGO TFT。评估了在不同条件下制备的 a-IGO TFT 的效率,发现在 220 ℃ 下生长的 27 nm 薄膜制备的 a-IGO TFT 具有最佳的电性能。它的迁移率为 35 cm2 V-1 s-1,阈值电压为 0.5 V,阈下摆幅为 0.8 V/dec,开/关电流比超过 106。这归功于溅射过程中温度对沉积能态的精确控制,以及半导体层厚度对堆积层分布的影响。本文的研究结果展示了一种高性能非晶氧化物薄膜晶体管的简单制造方法,为显示驱动电路提供了一种新的选择。本文受版权保护。
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引用次数: 0
Electroluminescence from Silicon‐Based Light‐Emitting Devices with Erbium‐Doped Ta2O5 Films 掺铒 Ta2O5 薄膜硅基发光器件的电致发光性能
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-18 DOI: 10.1002/pssr.202400045
Chengtao Xia, Ziwei Wang, Shuming Jiang, Ran Ji, Linlin Lu, Deren Yang, Xiangyang Ma
The visible and near‐infrared electroluminescence (EL) from the light‐emitting device (LED) based on the erbium (Er)‐doped Ta2O5 (Ta2O5:Er)/SiO2/Si structure is reported in this study. Wherein, an ∽10 nm thick SiO2 intermediate layer serves as an energy plateau for forming hot electrons, which initially transport from Si via trap‐assisted tunneling mechanism under sufficiently forward bias with the negative voltage connecting with Si. The hot electrons impact‐excite the Er3+ ions incorporated into the Ta2O5 host, leading to the Er‐related EL from the aforementioned LED. It is found that the 750 °C ‐ annealed Ta2O5:Er films are desirable to act as the light‐emitting component. Despite that the Er‐related photoluminescence from the Ta2O5:Er film becomes stronger in turn with the Er‐doping content increasing from nominal 0.75, 1.5 to 3 mol %, it is the Ta2O5:Er film with Er‐doping content of nominal 1.5 mol % rather than 3 mol % that enables the LED to exhibit the strongest EL. Based on the EL lifetime measurement and the structural characterizations, it is believed that the enhanced non‐radiative interactions among the Er3+ ions and the substantial amorphousness of Ta2O5 host caused by the nominal 3 mol % Er‐doping are responsible for the weakened EL as mentioned above.This article is protected by copyright. All rights reserved.
本研究报告了基于掺铒 Ta2O5(Ta2O5:Er)/SiO2/Si 结构的发光器件(LED)发出的可见光和近红外电致发光(EL)。其中,∽10 nm 厚的 SiO2 中间层是形成热电子的能量高原,在与 Si 相连的负电压下,热电子最初通过阱辅助隧道机制从 Si 传输。热电子撞击并激发掺杂在 Ta2O5 主成分中的 Er3+ 离子,从而导致上述 LED 发出与 Er 有关的 EL。研究发现,750 °C退火的Ta2O5:Er薄膜可用作发光元件。尽管随着掺铒含量从标称的 0.75、1.5 到 3 摩尔%的增加,Ta2O5:Er 薄膜发出的与铒有关的光致发光依次变强,但标称掺铒含量为 1.5 摩尔%而不是 3 摩尔%的 Ta2O5:Er 薄膜使 LED 显示出最强的 EL。根据电致发光寿命的测量结果和结构特征,我们认为,Er3+离子之间非辐射性相互作用的增强,以及标称的 3 摩尔% Er 掺杂造成的 Ta2O5 主基的大量非晶性,是上述电致发光减弱的原因。本文受版权保护。
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引用次数: 0
Topologically protected synthesizing of Fock states in a circuit QED architecture 电路 QED 架构中受拓扑保护的福克态合成
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-16 DOI: 10.1002/pssr.202300478
Wei Xin, Xiang-min Yu, Kun Zhou, Shaoxiong Li, Yang Yu
The preparation of Fock states is important for quantum information storage and processing. Here we present a two‐step protocol with topological protection for multi‐photon Fock states synthesizing in a circuit QED architecture. Due to photon number‐dependent vacuum Rabi splitting, the dynamics of the Jaynes‐Cummings ladder in the resonant regime can be equivalent to a spin‐1/2 chain while a multi‐frequency microwave pulse is applied. Based on the topologically assisted quantum state transfer technique, multi‐photon Fock states can be conditionally generated. Our method significantly reduces the complexity of experimental manipulation compared with previous multi‐step methods and is more robust as a result of topological protection. Furthermore, the protocol indicates that the circuit QED architecture could potentially provide a platform to explore the exotic phase in condensed matter.This article is protected by copyright. All rights reserved.
Fock 态的制备对于量子信息的存储和处理非常重要。在这里,我们提出了一种在电路 QED 架构中合成多光子 Fock 态的具有拓扑保护功能的两步协议。由于光子数依赖于真空拉比分裂,当应用多频微波脉冲时,杰恩-康明斯阶梯在共振机制下的动力学可以等同于自旋-1/2 链。基于拓扑辅助量子态转移技术,可以有条件地产生多光子福克态。与以往的多步骤方法相比,我们的方法大大降低了实验操作的复杂性,并且由于拓扑保护而更加稳健。此外,该协议还表明,电路 QED 架构有可能为探索凝聚态物质中的奇异相提供一个平台。本文受版权保护。
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引用次数: 0
True‐Red InGaN Light‐Emitting Diodes for Display Applications 用于显示应用的真彩色 InGaN 发光二极管
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-16 DOI: 10.1002/pssr.202400012
Robert Armitage, Zhongmin Ren, Mark Holmes, Joseph Flemish
Red InGaN has attracted much attention recently for microLED display applications. However, the consequences of spectral broadening are often overlooked and many of the published spectra do not meet display gamut requirements. We focus on maximizing the red InGaN radiance with a spectrum capable of meeting the DCI‐P3 standard (dominant wavelength of ∽615 nm). The maximum radiance for LEDs meeting said requirement is obtained at 20 A/cm2 and corresponds to 4% WPE in large‐area encapsulated devices. The WPE can be increased to 12.5% using epitaxy of lower In concentration driven at 2 A/cm2. We also report data for microLEDs fabricated from similar red InGaN epitaxy. No size dependence of the IQE or spectra are observed down to the smallest sizes studied (∽2 microns). We have further leveraged our expertise with red InGaN and nitride tunnel junctions to demonstrate polychromatic microLEDs with independent control of red, green, and blue emission within single pixels of 9x12 micron dimensions. These devices are grown in a single growth run on the same sapphire substrate wafer using methods proven in high‐volume epitaxy manufacturing.This article is protected by copyright. All rights reserved.
最近,红色 InGaN 在微型 LED 显示器应用中备受关注。然而,光谱展宽的后果往往被忽视,许多已发布的光谱都不符合显示色域要求。我们的重点是最大限度地提高红色 InGaN 的辐射率,使其光谱符合 DCI-P3 标准(主波长为 ∽615 nm)。符合上述要求的 LED 在 20 A/cm2 时可获得最大辐射率,相当于大面积封装器件中 4% 的 WPE。在 2 A/cm2 的驱动下,使用较低铟浓度的外延,WPE 可提高到 12.5%。我们还报告了利用类似的红色 InGaN 外延技术制造的微型 LED 的数据。在所研究的最小尺寸(∽2 微米)下,IQE 或光谱均未观察到尺寸依赖性。我们进一步利用在红色 InGaN 和氮化物隧道结方面的专业知识,展示了在 9x12 微米尺寸的单个像素内独立控制红色、绿色和蓝色发射的多色微型 LED。这些器件是采用在大批量外延制造中得到验证的方法,在同一蓝宝石衬底晶片上一次性生长出来的。本文受版权保护。
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引用次数: 0
Optical properties of low‐defect large‐area h–BN for quantum applications 用于量子应用的低缺陷大面积 h-BN 的光学特性
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-14 DOI: 10.1002/pssr.202400034
Shrivatch Sankar, Shantanu Saha, Jia-Shiang Chen, Shih-Po Chien, Yann­Wen Lan, Xuedan Ma, Michael Snure, Shamsul Arafin
Intrinsic defects and their concentrations in hexagonal boron nitride play a key role in single photon emission. This study explores the optical properties of large‐area multilayer h–BN‐on‐sapphire grown by metalorganic chemical vapor deposition. Based on our detailed spectroscopic characterization using both cathodoluminescence and photoluminescence measurements, the material is devoid of random single‐point defects instead of a few clustered complex defects. The emission spectra of the measurements confirm a record‐low defect concentration of ∽104 cm‐2. Post‐annealing, no significant changes are observed in the measured spectra and the defect concentrations remain unaltered. Through cathodoluminescence and photoluminescence spectroscopy, we identify an optically active boron vacancy spin defect and reveal a novel complex defect combination arising from carbon impurities. This complex defect, previously unreported, signifies a unique aspect of our material. Our findings contribute to the understanding of defect‐induced optical properties in h–BN films, providing insights for potential applications in quantum information science.This article is protected by copyright. All rights reserved.
六方氮化硼中的内在缺陷及其浓度在单光子发射中起着关键作用。本研究探讨了通过金属有机化学气相沉积法在蓝宝石上生长的大面积多层 h-BN 的光学特性。根据我们使用阴极发光和光致发光测量方法进行的详细光谱表征,该材料不存在随机单点缺陷,而是存在一些成簇的复杂缺陷。测量结果的发射光谱证实了∽104 cm-2 的创纪录低缺陷浓度。退火后,测量到的光谱没有明显变化,缺陷浓度也保持不变。通过阴极发光和光致发光光谱,我们确定了一种光学活性硼空位自旋缺陷,并揭示了一种由碳杂质引起的新型复合缺陷组合。这种复杂缺陷以前从未报道过,它标志着我们材料的一个独特方面。我们的发现有助于理解 h-BN 薄膜中缺陷诱导的光学特性,为量子信息科学的潜在应用提供了启示。本文受版权保护。
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引用次数: 0
The Interplay between Strain, Sn Content, and Temperature on Spatially Dependent Bandgap in Ge1−xSnx Microdisks 应变、锡含量和温度对 Ge1-xSnx 微晶盘空间依赖性带隙的相互作用
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-13 DOI: 10.1002/pssr.202470005
Ignatii Zaitsev, Agnieszka Anna Corley-Wiciak, Cedric Corley-Wiciak, Marvin Hartwig Zoellner, Carsten Richter, Edoardo Zatterin, Michele Virgilio, Beatriz Martín-García, Davide Spirito, Costanza Lucia Manganelli
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引用次数: 0
GaN Drift Layers on Sapphire and GaN Substrates for 1.2 kV Class Vertical Power Devices 蓝宝石和氮化镓衬底上的氮化镓漂移层,用于 1.2 kV 级垂直功率器件
IF 2.8 4区 物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY Pub Date : 2024-03-10 DOI: 10.1002/pssr.202400013
Frank Brunner, Enrico Brusaterra, Eldad Bahat‐Treidel, Oliver Hilt, Markus Weyers
The development of processes for epitaxial growth of vertical gallium nitride (GaN) drift layers enabling 1.2 kV breakdown voltage on low‐cost sapphire substrates is presented in comparison to GaN bulk substrates. The targeted blocking capability demands drift layers with a thickness of 10 μm and low but controllable n‐type doping. Using a growth rate of 2.5 μm h−1 the concentration of unintentionally incorporated carbon is sufficiently low to adjust the n‐type carrier concentration to ≈1 × 1016 cm−3 for all types of substrates. To assess GaN drift region properties in terms of forward bias conductivity and reverse bias blocking strength, a quasi‐vertical p‐n‐diode structure is utilized. Bow reduction of GaN‐on‐sapphire structures is achieved using a stealth laser scribing process. Breakdown voltages higher than 1600 V and a specific on‐state resistance as low as 0.7 mΩ cm2 are obtained with diodes fabricated on GaN substrates. Similar structures grown on sapphire show breakdown voltages of about 1300 V due to higher levels of current leakage. Comparing different types of substrates, a direct correlation between dislocation density in the drift layer with the leakage current in p‐n diodes is deduced.
介绍了在低成本蓝宝石衬底上外延生长垂直氮化镓(GaN)漂移层的工艺开发情况,与氮化镓块状衬底相比,该漂移层的击穿电压可达 1.2 kV。目标击穿能力要求漂移层的厚度为 10 μm,并具有低但可控的 n 型掺杂。采用 2.5 μm h-1 的生长速率,无意掺入的碳浓度足够低,可以将所有类型衬底的 n 型载流子浓度调整到 ≈1 × 1016 cm-3。为了评估氮化镓漂移区在正向偏压电导率和反向偏压阻断强度方面的特性,采用了准垂直 p-n 二极管结构。通过隐形激光划线工艺实现了蓝宝石上氮化镓结构的弓形减小。在氮化镓衬底上制造的二极管可获得高于 1600 V 的击穿电压和低至 0.7 mΩ cm2 的特定导通电阻。在蓝宝石上生长的类似结构由于漏电流水平较高,击穿电压约为 1300 V。通过比较不同类型的衬底,可以推断出漂移层中的位错密度与 p-n 二极管的漏电流之间存在直接的相关性。
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引用次数: 0
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