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Method to determine the weakness planes effect on the calculation of the collapse pressure of oil wells 软弱面对油井坍塌压力计算影响的确定方法
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.244
Juan-David Velilla-Uribe, Jorge-Luis Cáceres-Montero, Publio-Alejandro Sandoval, Reinel Corzo-Rueda, Zuly Calderón-Carrillo
Given the complexity involved when modeling heterogeneous and anisotropic formations, this condition is usually ignored, supposing that the well is surrounded by a homogenous and isotropic medium. The main objective of this paper is to present a method that shows the error that might occur when the condition of homogeneity and isotropy is not satisfied, when determining collapse pressure in a formation containing planes of weakness. Although the literature presents some studies, there is not a clear method for determining the collapse pressure of a well that takes into account the mechanical properties of the planes of weakness contained in the formation. The proposed method is based on the Mohr Coulomb criterion for homogeneous and isotropic formations and the criterion of Jaeger and Cook (1979) for laminated anisotropic media. It constitutes a robust tool that calculates the collapse pressure in highly complex configurations, contributing thus to prevent waste of time and money by more accurately considering the actual behavior of laminated formations. The method includes: the deduction of the direction cosine equation, the proposal of an objective function, the construction of a collapse pressure profile, and the sensitivity analysis of the collapse pressure with colored rosettes. A real case was selected to implement the proposed method.
考虑到非均质和各向异性地层建模的复杂性,假设井被均质和各向同性介质包围,通常忽略这一条件。本文的主要目的是提出一种方法,以显示在确定含有软弱面的地层的崩溃压力时,当均质性和各向同性条件不满足时可能出现的误差。虽然文献中提出了一些研究,但没有一个明确的方法来确定井的崩溃压力,该方法考虑了地层中软弱面的力学特性。所提出的方法是基于均匀和各向同性地层的Mohr Coulomb判据和层状各向异性介质的Jaeger和Cook(1979)判据。它是一种强大的工具,可以在高度复杂的配置中计算崩溃压力,从而通过更准确地考虑层压地层的实际行为,避免浪费时间和金钱。该方法包括:方向余弦方程的推导、目标函数的提出、坍塌压力剖面的构造以及彩色玫瑰花对坍塌压力的敏感性分析。选取一个实际案例对所提出的方法进行了验证。
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引用次数: 0
Evaluating the functionalities of NiMo/y-Al2O3-B2O3 catalysts in naphthalene hydrodearomatization and dibenzothiophene hydrodesulfurization 评价NiMo/y-Al2O3-B2O3催化剂在萘加氢脱芳和二苯并噻吩加氢脱硫中的功能
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.290
V. Baldovino-Medrano, A. Centeno, S. Giraldo
The aim of this work is to contribute to the current understanding on the role of the support’s acidic properties in the hydrogenating function of NiMo/-Al2O3 type catalysts during hydrodearomatization (HDA) and dibenzothiophene (DBT) type molecules desulfurization. NiMo/-Al2O3-B2O3 catalysts of different B2O3 (0, 2, 3, 6 and 8 wt.%) contents were prepared and tested in independent and simultaneous naphthalene (NP) HDA and DBT hydrodesulfurization (HDS) reactions. For HDA the catalytic activity as a function of the B2O3 content followed a volcano-shape trend, with a maximum around 3 wt.% of B2O3. In DBT desulfurization boron was found to have a positive effect in the development of the HYD route of desulfurization possibly due to an increase in total acidity. Conversely, the direct desulfurization route (DDS) was negatively affected by boron addition. The presence of NP during the HDS of DBT was found to have a significant effect in neither total HDS activity nor the HYD/DDS selectivity. The findings in this paper are significant for ultra-deep HDS of heavy oil cuts where increasing in the selectivity to HYD is a must because highly refractory alkyl-DBTs mostly react by this reaction route.
本研究的目的是为了进一步了解载体的酸性性质在NiMo/-Al2O3型催化剂在加氢脱芳(HDA)和二苯并噻吩(DBT)型分子脱硫过程中的加氢作用。制备了不同B2O3(0、2、3、6、8 wt.%)含量的NiMo/-Al2O3-B2O3催化剂,并在萘(NP) HDA和DBT加氢脱硫(HDS)反应中分别进行了独立和同步试验。HDA的催化活性随B2O3含量的变化呈火山状,B2O3含量在3 wt.%左右达到最大值。在DBT脱硫中,发现硼对HYD脱硫路线的发展有积极的影响,可能是由于总酸度的增加。相反,硼的加入对直接脱硫路线(DDS)有负面影响。在DBT的HDS过程中,NP的存在对HDS的总活性和HYD/DDS的选择性都没有显著影响。本文的研究结果对于稠油岩屑的超深层HDS具有重要意义,因为高难熔性烷基- dbt主要通过该反应途径反应,因此必须提高对HYD的选择性。
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引用次数: 1
Methodology to design of synthetic sonic log (SSL), using artificial neural networks. Colorado field application 利用人工神经网络设计合成声波测井(SSL)的方法。科罗拉多油田应用
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.242
Carlos-Andrés Ayala Marín, Christiann-Camilo García-Yela
A method that allows the creation of the Synthetic Sonic Log (SSL) was developed from the Spontaneous Potential (SP) logs, the resistivity logs of the flushed zone (SN), and the resistivity zone of the uninvaded zone (ILD), using Artificial Neural Networks (ANN). The SSL was obtained with the created tool calledGeneration of Synthetic Sonic Logs (GSSL). The results obtained are presented hereinafter: in the Colorado 70 well, 90% of the generated SSL data present errors of less than 10%; in the Colorado 72 well; 53% of the SSL data obtained with the tool are below 5% error, in the Colorado 75 well, 80% of the SSL data present errors of less than 10%, and finally, the SSL generated for the Colorado 38 well follows the behavior of the original Sonic Logs of the well in an accurate manner. From the foregoing we conclude that the quality of the created tool is good and that the deviations are minimal in the times of transit of synthetic sonic profile.
利用人工神经网络(ANN),利用自然电位(SP)测井、冲刷层(SN)的电阻率测井和未侵层(ILD)的电阻率测井,开发了一种合成声波测井(SSL)的方法。SSL是通过创建的合成声波测井生成工具(GSSL)获得的。结果如下:在Colorado 70井中,90%生成的SSL数据误差小于10%;科罗拉多72号井;使用该工具获得的SSL数据中,53%的数据误差小于5%,在Colorado 75井中,80%的SSL数据误差小于10%,最后,Colorado 38井生成的SSL数据准确地遵循了该井原始声波测井的行为。从上述我们得出的结论是,所创建的工具的质量是好的,并且偏差是最小的时间在合成声波剖面的过境。
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引用次数: 3
Modified design for vacuum residue processing 改进的真空残渣处理设计
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.245
Sandro Faruc González, J. A. Carrillo, M. Núñez, L. Hoyos, S. Giraldo
The world petroleum industry shows a decreasing in the oil reserves, specially the light kind. For this reason is very important to implement process schemes that give the possibility to improve the recuperation of valuable products of heavy oil. In this case the bottom processing in each one of the petroleum refining stages earns great importance with the purpose of maximizing the quantity of fuel by barrel of raw processed. Therefore, it has been proposed the modification of the currently vacuum residues process scheme in the Ecopetrol`s Barrancabermeja refinery (DEMEX-Visbreaking-Hydroprocessing). That modification consists in the incorporation of an additional Visbreaking stage, previous at DEMEX extraction stage. This investigation was developed with plant pilot tests combined with statistical models that predict the yield and the quality of the products obtained in the industrial plants. These models were developed by the Instituto Colombiano de Petróleo (ICP). The modified scheme Visbreaking I-DEMEX- Visbreaking II- Hydroprocessing, gives the possibility to increase the yield of middle distillates. Besides decrease the quantity of demetalized oil produced in DEMEX stage. This reduction is very favorable since environmental point of view, because it allows have a percentage of free capacity in the Hydroprocessing unit in order to removed sulfur of valuable products like Diesel and in this way to respect the environment law to this kind of fuel.
世界石油工业的石油储量呈下降趋势,特别是轻质石油。因此,实施能够提高重油有价产物回收率的工艺方案是非常重要的。在这种情况下,为了最大限度地提高每桶原料的燃料产量,每一个石油炼制阶段的底部加工都是非常重要的。因此,提出了对Ecopetrol的Barrancabermeja炼油厂目前的真空渣油处理方案(demex - visbreak - hydroprocessing)的改进。该改进包括在DEMEX萃取阶段之前加入额外的破粘阶段。这项调查是通过工厂中试试验结合统计模型开发的,该模型预测了工业工厂获得的产品的产量和质量。这些模型是由哥伦比亚研究所Petróleo (ICP)开发的。改进的脱粘I-DEMEX-脱粘II-加氢工艺方案,使中间馏分的收率有了提高的可能。同时减少DEMEX阶段脱金属油的产量。从环境的角度来看,这种减少是非常有利的,因为它允许在加氢处理装置中有一定比例的自由容量,以去除柴油等有价值产品的硫,并以这种方式尊重环境法对这种燃料。
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引用次数: 3
Pressure and pressure derivative analysis for a well in a radial composite reservoir with a non-newtonian/newtonian interface 具有非牛顿/牛顿界面的径向复合油藏井的压力和压力导数分析
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.243
F. Escobar, J. Martínez, Matilde Montealegre-Madero
In many activities of the oil industry, engineers have to deal with completion and stimulation treatment fluids such as polymer solutions and some heavy crude oils which obey a non-Newtonian power-law behavior. When it is required to conduct a treatment with a non-Newtonian fluid in an oil-bearing formation, thiscomes in contact with conventional oil which possesses a Newtonian nature. This implies the definition of two media with entirely different mobilities. If a pressure test is run in such a system, the interpretation of data from such a test through the use of conventional straight-line method may be erroneous and may not provide a way for verification of the results obtained. In this work, the signature of the pressure derivative curve is investigated to understand and ease the interpretation of the well test data in reservoirs with non-Newtonian power-law fluids. Specifically, the Tiab’s Direct Synthesis (TDS) technique is implemented using some characteristics features found on the pressure and pressure derivative curves. Hence, new equations are introduced to estimate permeability, non-Newtonian bank radius and skin factor. Permeability can be verified. The proposed methodology was successfully verified by its application to an example reported in the literature and a synthetic case.
在石油工业的许多活动中,工程师必须处理完井和增产处理流体,如聚合物溶液和一些重质原油,它们遵循非牛顿幂律行为。当需要在含油地层中使用非牛顿流体进行处理时,它会与具有牛顿性质的常规油接触。这意味着两种具有完全不同移动性的媒体的定义。如果在这样的系统中进行压力测试,通过使用传统的直线方法对测试数据的解释可能是错误的,并且可能无法提供验证所获得结果的方法。在这项工作中,研究了压力导数曲线的特征,以理解和简化非牛顿幂律流体油藏试井数据的解释。具体来说,Tiab的直接合成(TDS)技术是利用压力和压力导数曲线上的一些特征来实现的。因此,引入了新的方程来估计渗透率、非牛顿堤岸半径和表皮因子。可以验证渗透率。通过对文献报道的一个实例和一个综合案例的应用,成功地验证了所提出的方法。
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引用次数: 20
COMPARISON BETWEEN NIR AND UVVIS SPECTRA CHEMOMETRICS FOR PREDICTING FCC FEEDSTOCKS PROPERTIES 近红外光谱与紫外光谱化学计量学预测催化裂化原料性能的比较
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-06-30 DOI: 10.29047/01225383.444
C. Baldrich, L. Novoa, A. Bueno
In this paper a comparison is made between the performance of models developed by applying chemometric analysis to NIR and UVVIS spectral data obtained from feedsctock samples corresponding to the different Ecopetrol S.A., Barrancabermeja Refinery FCC units for predicting some important physicochemical properties. The results show the utility of both methodologies here evaluated to follow up the quality of these types of refinery streams and present the advantages and disadvantages of each methodology for predicting the feedstock properties here evaluated.
本文比较了采用化学计量学分析方法建立的模型的性能,这些模型采用近红外和紫外可见光谱数据,从不同的Ecopetrol sa, Barrancabermeja炼油厂催化裂化装置对应的原料样品中获得,用于预测一些重要的物理化学性质。结果显示了本文所评估的两种方法在跟踪这些类型的炼油厂流的质量方面的效用,并展示了每种方法在预测所评估的原料特性方面的优缺点。
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引用次数: 1
PCA REDUCTION IN NAPHTHENIC BASE OILS BY OPTIMIZING HDT CONDITIONS 优化HDT条件降低环烷基基础油中Pca含量
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-06-30 DOI: 10.29047/01225383.443
Maria Elizabeth Gómez, Liliana Santos, Néstor Tapias, Clemencia Vargas, J. Lizcano
Polycyclic Aromatics (PCA) are aromatic hydrocarbons and related sulphur and nitrogen compounds, containing three or more fused aromatic rings, which are considered as toxic compounds. PCA control is a complex task because the Base Oil production involves different processes with many variables such as pressure, temperature, feedstock quality, catalyst, etc. This study focuses on controlling the hydrotreating temperature as main variable in the reduction of PCA in Naphthenic Bases. Two Naphthenic distillate fractions taken from an industrial plant were hydrotreated in pilot plant at different temperatures. The results show that PCA are reduced as hydrotreating temperature increases; however there is an optimum temperature above it, the thermodynamic equilibrium of aromatic hydrogenation reverses, increasing as a result, the PCA content. These results were implemented in the industrial Unit by installing a hydrogen quench between the two industrial reactors to guarantee that the profile of temperature, due to exothermic character of some reactions, be always in the optimun operating range. 
多环芳烃(Polycyclic Aromatics, PCA)是一种含有三个或三个以上芳香环的芳烃及其相关的硫、氮化合物,被认为是有毒化合物。PCA控制是一项复杂的任务,因为基础油的生产涉及不同的过程,有许多变量,如压力、温度、原料质量、催化剂等。研究了以加氢处理温度为主要变量对环烷基中PCA还原的影响。采用中试装置在不同温度下对某工业装置的两种环烷馏分进行了加氢处理。结果表明:随着加氢处理温度的升高,PCA减小;但在此温度以上存在一个最佳温度,芳香族氢化热力学平衡发生逆转,导致PCA含量增加。这些结果通过在两个工业反应器之间安装氢淬火装置来实现,以保证由于某些反应的放热特性,温度分布始终在最佳操作范围内。
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引用次数: 5
PRESSURE AND PRESSURE DERIVATIVE TRANSIENT ANALYSIS WITHOUT TYPE-CURVE MATCHING FOR ELONGATED RESERVOIRS WITH CHANGES IN FACIES OR WIDTH 带相或宽度变化的细长型储层非类型曲线拟合的压力和压力导数瞬态分析
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-06-30 DOI: 10.29047/01225383.441
F. Escobar, M. Montealegre, Daniel Carrillo-Moreno
Due to geologic and tectonic events many reservoirs have an elongated geometry in which dual-linear and single-linear flow regimes may be developed. The single-linear flow may be altered by changes in facies (mobility) or reservoir width (composite reservoir). Therefore, it is desirable to identify and characterize these types of systems which lead to competent decisions and adequate reservoir management. The identification and determination of parameters for such reservoirs are conducted by conventional techniques (straight-line method), type-curve matching of pressure versus time and the Tiab’s Direct Synthesis (TDS) technique. This last one has been lately presented for homogeneous and constant width reservoirs. In this paper, an extension of the TDS technique to incorporate variations in either mobility or reservoir width is presented. Several simulation experiments were run to understand the behavior of the reservoir under these new conditions. If the change of the mentioned parameters takes place after the dual- linear flow has ended a new half-slope line is observed on the pressure derivative curve. This new line is shifted upwards the original dual-linear line without regarding the variation of one of the studied parameter. When, the anomaly occurs during dual- linear flow the new half-slope line of the pressure derivative curve may be shifted upwards or downwards depending upon the magnitude of either mobility or reservoir width. This new line may not be referred as linear flow regime because it is really not. We have named it as pseudo-linear flow regime, instead. Therefore, a modification of the intercept of the ½-slope line from 0,5 for dual-linear flow regime to a greater or smaller value, which may be different from (single-linear flow case) has to be considered in order to provide new equations for the estimation of new values of either permeability or reservoir width. The proposed methodology was successfully verified by interpreting both synthetic and field pressure tests for elongated oil reservoirs which involve changes in either mobility or reservoir width during the path of the transient wave. 
由于地质和构造事件,许多储层具有细长的几何形状,其中可能发育双线和单线流动。单线流可能因相(流动性)或储层宽度(复合储层)的变化而改变。因此,有必要确定并确定这些类型的系统的特征,以便作出适当的决定和适当的水库管理。这些储层的参数识别和确定采用常规技术(直线法)、压力-时间类型曲线匹配和Tiab的直接合成(TDS)技术。最后一种是最近在均质和等宽储层中提出的。在本文中,提出了一种扩展TDS技术,以纳入流动性或储层宽度的变化。为了了解储层在这些新条件下的行为,进行了几次模拟实验。如果上述参数的变化发生在双线流动结束后,则在压力导数曲线上观察到一条新的半斜率线。这条新线在不考虑所研究参数之一的变化的情况下,向上平移了原来的双线。当异常发生在双线流动时,压力导数曲线的新半斜率线可能会根据流度或储层宽度的大小向上或向下移动。这条新线可能不被称为线性流态,因为它确实不是。我们把它命名为伪线性流态。因此,为了提供新的方程来估计渗透率或储层宽度的新值,必须考虑将1 / 2斜率线的截距从双线流动情况下的0,5修改为可能不同于(单线流动情况下)的更大或更小的值。通过解释涉及瞬态波路径中流动性或储层宽度变化的细长油藏的合成和现场压力测试,成功验证了所提出的方法。
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引用次数: 3
Determination of reservoir drainage area for constant pressure systems using well test data 用试井数据确定定压系统的储层排水面积
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-06-30 DOI: 10.29047/01225383.440
F. Escobar, Y. Hernández, D. Tiab
In this work, the conventional cartesian straight-line pseudosteady-state solution and the Total Dissolved Solids (TDS) solution to estimate reservoir drainage area is applied to constant-pressure reservoirs to observe its accuracy. It was found that it performs very poorly in such systems, especially in those having rectangular shape. On the other hand, the pseudosteady-state solution of the TDS technique performs better in constant-pressure systems and may be applied only to regular square- or circular-shaped reservoirs with a resulting small deviation error. Therefore, new solutions for steady-state systems in circular, square and rectangular reservoir geometries having one or two constant-pressure boundaries are developed, compared and successfully verified with synthetic and real field cases. Automatic matching performed by commercial software sometimes are so time consuming and tedious which leads to another reason to use the proposed equations.
将传统的笛卡儿直线拟稳态解和总溶解固形物(TDS)解用于储层排水面积估算,并应用于恒压储层,观察其精度。研究发现,在这种系统中,特别是在矩形系统中,它的性能非常差。另一方面,TDS技术的伪稳态解决方案在恒压系统中表现更好,并且只能应用于规则的方形或圆形油藏,因此偏差很小。因此,对于具有一个或两个定压边界的圆形、方形和矩形油藏,开发了新的稳态系统解决方案,并与综合和实际现场案例进行了比较和成功验证。商业软件执行的自动匹配有时非常耗时和繁琐,这是使用所提出方程的另一个原因。
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引用次数: 10
Selection of OBM salinity through effective osmotic pressure evaluation in carbonera shale for colombian foothills 通过有效渗透压评价选择哥伦比亚山麓石炭系页岩OBM盐度
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-06-30 DOI: 10.29047/01225383.436
William-Armando Fernández-Vera, R. Corzo, N. Saavedra
Wellbore instability in shales is attributed to many factors. Two of them are mechanical effects and physico-chemical effects. Drilling and drilling fluid cause physico-chemical interaction and the flux of water and ions that may alter the shale stress state through pore pressure and shale strength. This paper presents the analysis of the chemical osmosis phenomenon between drilling fluids and shale formations to evaluate the chemical parameters necessary for modeling the aqueous flux. These parameters are the drilling fluid activity (Adf), shale activity (Ash) and membrane efficiency (ME). This work also characterizes the shales for drilling purposes and describes an integrated methodology to obtain the magnitude of the chemical parameters. Furthermore, it is stated how the generation of effective osmotic pressure between the formation and drilling fluid define the water flux direction. Finally, the application of the results of the chemical analysis to Carbonera shale is presented. The design of laboratory tests for two mud formulations, Mud A and Mud B, and the field application is also showed. The Mud A is a balanced activity mud and the Mud B is a high salt concentration mud which may produce water flux out of the shale formation (dehydration) during drilling, in some sections of the wellbore, increasing the formation strength. The results presented in this paper will help to reduce the risks associated with wellbore instability during the drilling of shale formations and thereby lowering the overall non-productive time and reducing drilling costs.
页岩井筒失稳的原因有很多。其中两种是机械效应和物理化学效应。钻井与钻井液之间的物理化学相互作用以及水和离子的通量可能通过孔隙压力和页岩强度改变页岩应力状态。本文分析了钻井液与页岩地层之间的化学渗透现象,以评估模拟含水通量所需的化学参数。这些参数分别是钻井液活度(Adf)、页岩活度(Ash)和膜效率(ME)。这项工作还描述了用于钻井目的的页岩特征,并描述了一种获得化学参数大小的综合方法。此外,还阐述了地层与钻井液之间有效渗透压的产生是如何决定水通量方向的。最后,介绍了化学分析结果在石炭纪页岩中的应用。介绍了泥浆A和泥浆B两种泥浆配方的室内试验设计和现场应用情况。泥浆A是一种平衡活性泥浆,泥浆B是一种高盐浓度泥浆,在钻井过程中,在井筒的某些部分可能会产生从页岩地层中流出的水通量(脱水),从而增加地层强度。本文的研究结果将有助于降低页岩地层钻井过程中与井筒不稳定相关的风险,从而减少总体非生产时间,降低钻井成本。
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引用次数: 0
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