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NUMERICAL SIMULATION FOR CYCLIC STEAM INJECTION AT SANTA CLARA FIELD 圣克拉拉油田循环注汽数值模拟
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.466
E. Rodriguez, Wilson Barrios, R. Sandoval, N. Santos, I. Cortes
This article presents the methodology used and the results obtained in the construction, match and prediction of the first thermal composition simulation model done in Colombia by employing advanced thermal process commercial software, globally recognized because of its effectiveness in modeling these types of processes (CMG-STARS, 2005). The Santa Clara and Palermo fields were modeled and an excellent history match was achieved. All in all 28 wells and 17 years of production were matched.  Two production scenes were proposed. The first involved primary production from existing wells, in other words: primary production; and a second escen where all the wells in the field are converted into injectors and producers, to simulate cyclic steam injection. This injection process included a series of sensitivity studies for several of the parameters involved in this technology, such as: pressure and temperature injection, time and rate of injection, heat injected, soaking period, steam quality, and injection cycles. This sensitivity study was focused on optimizing the processes to obtain the maximum end recovery possible.  The information entered into the simulator was validated by laboratory tests developed at the Instituto Colombiano del Petróleo (ICP). Among the tests performed the following were assessed: rock compressibility, relative permeability curve behavior at different temperatures, formation sensitivity to injection fluids, DRX analysis and residual saturation of crude oil for steam injection. The aforementioned results are documented in this paper.
本文介绍了在哥伦比亚使用先进的热过程商业软件构建、匹配和预测第一个热成分模拟模型时所使用的方法和获得的结果,该软件因其在模拟这些类型的过程方面的有效性而得到全球认可(CMG-STARS, 2005)。以圣克拉拉和巴勒莫油田为模型,实现了出色的历史匹配。所有28口井和17年的生产都进行了匹配。提出了两个生产场景。第一个涉及现有井的初级生产,换句话说:初级生产;第二个场景是将现场所有井转换为注水井和采水井,模拟循环注汽。该注入过程包括对该技术中涉及的几个参数的一系列敏感性研究,例如:注入压力和温度、注入时间和速度、注入热量、浸泡时间、蒸汽质量和注入周期。该敏感性研究的重点是优化工艺以获得最大的最终回收率。输入模拟器的信息由哥伦比亚研究所Petróleo (ICP)开发的实验室测试验证。在进行的测试中,评估了以下内容:岩石压缩性、不同温度下的相对渗透率曲线行为、地层对注入流体的敏感性、DRX分析和注汽原油的剩余饱和度。本文记录了上述结果。
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引用次数: 2
THE STRUCTURAL STYLE OF FOOTWALL SHORTCUTS ALONG THE EASTERN FOOTHILLS OF THE COLOMBIAN EASTERN CORDILLERA. DIFFERENCES WITH OTHER INVERSION RELATED STRUCTURES 沿着哥伦比亚东部科迪勒拉东部山麓的下盘捷径的结构风格。与其他反转相关结构的区别
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.460
A. Mora, M. Parra
For the first time we show geological evidence of unambiguosly documented footwall shortcuts adjacent to the trace of inverted master nomal faults, in the Eastern Cordillera of Colombia. The Eastern Cordillera is an orogen whose width and location are traced by a Mesozoic graben. However, few structures related with the graben have been documented up to the date. In this study we propose the Ariari-Guatiquía region as a type location for a unique observation of footwall shortcuts. The master normal faults in the Ariari-Guatiquia region, and documented in this manuscript, were active during the Lower Cretaceous, partially inverted during the Andean orogenesis (since the Oligocene at least) and active still nowadays. In the hangingwall basins of those master normal faults, like the Servitá fault, all the Cretaceous syn-rift sequence has been deposited and maximum paleo temperatures in the lowermost Cretaceous rocks are higher than those for the Zircon FT partial annealing zone (~250°C; 23,15 K). In contraction, the inverted master normal faults are high angle basement involved features that generated the main topographic contrast and exposing Lower Cretaceous units or older. In contrast, in the adjacent footwall shortcuts only part of the syn-rift Lower Cretaceous sequence was deposited or more commonly was not deposited at all. Maximum paletemperatures reached by the basal Cretaceous units exposed in the hanging wall blocks of the footwall shortcuts are always less than those of the Zircon FT partial annealing zone (~250°C; 23,15 K). Finally we use AFT data to document that the footwall shortcuts originated during the Late Miocene and later as shallowly dipping faults generating low elevation hanging wall areas. All the described features are present in the Ariari-Guatiquia region. However, northwards and along strike in the Eastern foothills there is a lot of partially analogue scenarios with respect to those described in the Ariari-Guatiquia region. Therefore we deduce that a similar structural segmentation should be present along the entire Eastern foothills of the Colombian Eastern Cordillera. Based on that we propose plausible candidates for master inverted normal faults and footwall shorcuts in other areas of the Eastern foothills.
在哥伦比亚东部科迪勒拉,我们首次展示了明确记录的下盘捷径与倒转主正断层痕迹相邻的地质证据。东科迪勒拉是一个造山带,其宽度和位置可追溯到中生代地堑。然而,迄今为止,与地堑有关的构造文献很少。在这项研究中,我们提出Ariari-Guatiquía区域作为一个独特的观察下盘捷径的类型位置。本文记录的ariarii - guatiquia地区的主正断层在下白垩世活跃,在安第斯造山运动期间部分反转(至少从渐新世开始),至今仍在活动。在servit断裂等主控正断层的上盘盆地中,白垩系同裂谷序列全部沉积,白垩系最下端岩石的最高古温度高于锆石FT部分退火带(~250℃;在收缩作用下,逆主控正断层为高角度基底卷入特征,形成了主要的地形对比,暴露出下白垩统或更老的单元。相比之下,在邻近的下盘捷径中,只有部分同裂谷下白垩统层序沉积,更常见的是根本没有沉积。下盘捷径上盘块体暴露的基底白垩纪单元所达到的最高古温度始终低于锆石FT部分退火带(~250℃;最后,我们利用AFT数据证明了下盘捷径起源于晚中新世,后来成为浅倾斜断层,形成了低海拔上盘区域。所有描述的特征都存在于ariarii - guatiquia地区。然而,在东部山麓向北和沿走向的地区,有许多与ariarii - guatiquia地区描述的部分类似的情况。因此,我们推断,在哥伦比亚东部科迪勒拉的整个东部山麓应该存在类似的结构分割。在此基础上,提出了东麓其他地区主逆正断层和下盘捷径的合理候选带。
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引用次数: 17
ESTIMATION OF CRITICAL PROPERTIES OF TYPICALLY COLOMBIAN VACUUM RESIDUE SARA FRACTIONS 典型哥伦比亚真空渣油Sara馏分临界性质的估计
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.467
A. León, M. Parra, J. Grosso
Knowledge of critical properties and the acentric factor is required in phase-equilibrium studies in different extraction processes conducted in the petroleum industry, particularly in the solvent deasphalting process. Correlations to estimate critical temperature, critical pressure and acentric factor values of SARA (Saturated, Aromatic, Resin, and Asphaltene) fractions of vacuum residue from the Barrancabermeja Refinery were determined from their physical properties such as density (molar volume) and molecular weight. New correlations for critical property prediction were evaluated using model molecules and the Avaullee and Satou's group contribution methods, respectively.
在石油工业中进行的不同萃取过程的相平衡研究中,特别是在溶剂脱沥青过程中,需要了解关键性质和离心因素。根据Barrancabermeja炼油厂真空渣油SARA(饱和、芳香族、树脂和沥青质)馏分的物理性质,如密度(摩尔体积)和分子量,确定了临界温度、临界压力和离心因子值的相关性。分别使用模型分子和Avaullee和Satou的基团贡献方法对临界性质预测的新相关性进行了评估。
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引用次数: 7
DESIGN AND DEVELOPMENT OF A HIGH EFFICIENCY TANK FOR CRUDE OIL DEHYDRATION (I) 高效原油脱水罐的设计与研制(一)
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.472
J. E. Forero, Olga-Patricia Ortiz, Fredy-Abelardo Nariño, J. Díaz, H. Peña
This paper introduces a new tank design for dehydrating and desalting large volumes of crude oils previously degasified, crude oil dehydration efficiency is reduced by gas presence in the emulsion interphase. The design presented in this paper is versatile (it is adaptable to any classical dehydration process), highly efficient in terms of separation (values usually greater than 90% and/or treated crude oil BSW less than 0,5% are ensured), low installation and operation costs, less consumption of additives. These are some of the advantages found in pilot tests plants and proven in industrial systems at the Ecopetrol S.A. production fields with treatment capacities from 14 to 50 KBD. Although this process also can be applied to other ranks of flow, maintaining the design critical conditions of each case in particular.  This system does not exhibit the typical limitations shown by treatment tradicional systems (FWKO, Gun Barrel, thermal and electrostatic separators, etc.) (Al-Ghamdi, 2007) since it can be easily adapted to system treatments for light, intermediate, and heavy crude oils and to treatments with BSW content ranging from a very low levels of < 1% to very high levels > 95%, values that are not unusual in production fields nowadays, especially where accelerated production methods are used.
本文介绍了一种新的储罐设计,用于对大量已脱气的原油进行脱水脱盐,由于乳化相中存在气体而降低了原油脱水效率。本文提出的设计具有通用性(适用于任何经典的脱水工艺)、分离效率高(通常大于90%和/或处理后的原油BSW小于0.5%)、安装和运行成本低、添加剂消耗少。这些都是在中试工厂中发现的一些优势,并在Ecopetrol S.A.生产领域的工业系统中得到了验证,处理能力从14到50 KBD。虽然这个过程也可以应用到其他等级的流量,保持设计的临界条件的每一种情况下,特别是。该系统没有传统系统(FWKO、Gun Barrel、热和静电分离器等)所表现出的典型局限性(Al-Ghamdi, 2007),因为它可以很容易地适应轻、中、重质原油的系统处理,以及BSW含量从非常低的< 1%到非常高的> 95%的处理,这些值在当今的生产领域并不罕见,特别是在使用加速生产方法的领域。
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引用次数: 5
PREDICTION OF PHYSICOCHEMICAL PROPERTIES OF FCC FEEDSTOCK BY CHEMOMETRIC ANALYSIS OF THEIR ULTRAVIOLET SPECTRUM 用化学计量学分析催化裂化原料的紫外光谱预测其理化性质
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.468
Carlos A. Baldrich Ferrer
Chemometric analysis by Partial Least Squares (PLS) has been applied in this work to correlate the ultraviolet spectrum of combined Fluid Catalytic Cracking (FCC) feedstocks with their physicochemical properties. The prediction errors obtained in the validation process using refinery samples demonstrate the accuracy of the predicted properties. This new analytical methodology allows obtaining in one analysis detailed information about the most important physicochemical properties of FCC feedstocks and could be used as a valuable tool for operational analysis.
应用偏最小二乘(PLS)的化学计量分析方法,研究了复合催化裂化(FCC)原料的紫外光谱与其理化性质之间的关系。在炼油厂样品验证过程中得到的预测误差证明了预测性质的准确性。这种新的分析方法可以在一次分析中获得关于FCC原料最重要的物理化学性质的详细信息,并且可以用作操作分析的有价值的工具。
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引用次数: 3
APPLICATION OF TDS TECHNIQUE TO MULTIPHASE FLOW TDS技术在多相流中的应用
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.465
F. Escobar, Matilde Montealegre-M.
Although, the radial difussivitity equation has been solved for a single-fluid phase flow, in some cases more than one phase flows from the reservoir to the well; therefore, the single-phase solution has been previously extended to multiphase flow without losing a significant degree of accuracy. Practically, there exist two ways of dealing with multiphase flow: The Perrine method, Perrine (1956) which basically replaces the single-phase compressibility by the multiphase compressibility so that each fluid is analyzed separately using the concept of mobility. The other one is the use of pseudofunctions which have been found to be the best option. The TDS technique has been widely applied to a variety of scenarios. It has been even tested to successfully work on condensate systems with the use of pseudofunctions, Jokhio, Tiab and Escobar (2002). However, equations for estimation of phase permeability, skin factor and drainage area has not neither presented nor tested. In this article, we present new versions of a set of equations of the TDS technique to be applied to multiphase flow following the Perrine method along with a previously presented way of estimation of the absolute relative permeability. We successfully applied the proposed equations to synthetic and field examples.
虽然径向扩散方程已经解决了单相流体的流动,但在某些情况下,从储层到井中有不止一个相的流动;因此,单相解决方案之前已经扩展到多相流,而不会损失很大程度的准确性。实际上,有两种处理多相流的方法:Perrine方法,Perrine(1956)基本上用多相压缩率代替单相压缩率,用流动性的概念对每种流体进行单独分析。另一种是使用伪函数,这是最好的选择。TDS技术已广泛应用于各种场景。Jokhio, Tiab和Escobar(2002)甚至通过使用伪函数成功地测试了它在冷凝系统上的工作。然而,相渗透率、集肤系数和排水面积的估算方程既没有提出也没有测试。在本文中,我们根据Perrine方法和先前提出的估计绝对相对渗透率的方法,提出了一套适用于多相流的TDS技术方程的新版本。我们成功地将所提出的方程应用于综合和现场实例。
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引用次数: 2
RATE TRANSIENT ANALYSIS FOR HOMOGENEOUS AND HETEROGENEOUS GAS RESERVOIRS USING THE TDS TECHNIQUE 利用TDS技术对均质和非均质气藏进行速率瞬态分析
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.462
F. Escobar, J. A. Sánchez, José-Humberto Cantillo
In this study pressure test analysis in wells flowing under constant wellbore flowing pressure for homogeneous and naturally fractured gas reservoir using the TDS technique is introduced. Although, constant rate production is assumed in the development of the conventional well test analysis methods, constant pressure production conditions are sometimes used in the oil and gas industry. The constant pressure technique or rate transient analysis is more popular reckoned as "decline curve analysis" under which rate is allows to decline instead of wellbore pressure.  The TDS technique, everyday more used even in the most recognized software packages although without using its trade brand name, uses the log-log plot to analyze pressure and pressure derivative test data to identify unique features from which exact analytical expression are derived to easily estimate reservoir and well parameters. For this case, the "fingerprint" characteristics from the log-log plot of the reciprocal rate and reciprocal rate derivative were employed to obtain the analytical expressions used for the interpretation analysis. Many simulation experiments demonstrate the accuracy of the new method. Synthetic examples are shown to verify the effectiveness of the proposed methodology.
本文介绍了采用TDS技术对均质天然裂缝气藏在恒井压下的压力测试分析。虽然在常规试井分析方法的开发中,假设恒定速率生产,但在石油和天然气行业中,有时会使用恒定压力生产条件。恒压技术或速率瞬态分析更常被认为是“递减曲线分析”,在这种分析下,允许速率而不是井筒压力下降。TDS技术每天都在最知名的软件包中使用,尽管没有使用其商标名称,但它使用对数-对数图来分析压力和压力导数测试数据,以识别独特的特征,从中推导出精确的分析表达式,从而轻松估计储层和井参数。在这种情况下,利用互反速率的对数-对数图和互反速率导数的“指纹”特征来获得用于解释分析的解析表达式。大量的仿真实验证明了该方法的准确性。综合算例验证了所提方法的有效性。
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引用次数: 9
DEVELOPMENT OF EXPERIMENTAL CORRELATIONS BETWEEN INDENTATION PARAMETERS AND UNCONFINED COMPRESSIVE STRENGTH (UCS) VALUES IN SHALE SAMPLES 页岩样品压痕参数与无侧限抗压强度(ucs)值之间的实验相关性研究
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.463
R. García, N. Saavedra, Zuly Calderón-Carrillo, D. Mateus
Unconfined Compressive Strength (UCS) is one of the rock mechanical properties that is important take into account during drilling operations in order to avoid wellbore instability. During drilling operations, UCS variability influences wellbore stability more than other factors such as azimuth, slope, exposure time, and mud weight (Jaramillo, 2004). In last years, the indentation technique has been demonstrated to be an appropriate method for determining rock strength in real time during oil well drilling. This technique implements correlation that allow UCS evaluation from indentation parameters such as Indentation Module (IM) and Critical Transition Force (CTF), that can be measured on small rock fragments obtained during drilling. Shale formations in well drilling have demonstrated to be a hindrance since they represent the most important problem in reservoir stability (Abass, H., A. et al. 2006). Therefore, the main objective of this article is to find experimental correlations that allow the modeling of rock strength by applying the indentation technique to reservoir plug. The importance of this technique is the possibility to get rock strength properties in real time during drilling operations, although, those reservoir sections which do not have neither direct UCS records nor indirect measurements.  Eight Unconfined Compression Tests (UCS) on rock cylinders (plugs) extracted from the Paja formation upwelling were conducted in order to develop the corresponding experimental correlations. Two hundred indentation tests were also simultaneously conducted on shale fragments extracted from each plug surroundings in order to simulate the cavings obtained from reservoir drilled. Results of both tests were correlated using the Minimum Square technique, seeking the best correlation that shall represent result behavior, thus obtaining two 2nd-degree polynomial correlations. Correlation coefficients of 0,6513 were determined for the (IM) - (UCS) correlation and 0,8111 for the (CTF) - (UCS) correlation. This demonstrates that the highest correlation between indentation parameters and (UCS) is obtained with the Critical Transition Force (CTF).
无侧限抗压强度(UCS)是岩石的力学特性之一,在钻井作业中,为了避免井筒失稳,必须加以考虑。在钻井作业中,与方位角、坡度、暴露时间和泥浆比重等因素相比,UCS变化对井筒稳定性的影响更大(Jaramillo, 2004)。近年来,压痕技术已被证明是一种适合于油井钻井过程中实时测定岩石强度的方法。该技术实现了相关性,允许通过压痕参数(如压痕模块(IM)和临界过渡力(CTF))对UCS进行评估,这些参数可以在钻井过程中获得的小岩石碎片上测量。页岩地层在钻井中被证明是一个障碍,因为它们代表了储层稳定性的最重要问题(Abass, H., a . et al. 2006)。因此,本文的主要目标是通过将压痕技术应用于储层堵头,找到能够模拟岩石强度的实验相关性。该技术的重要性在于可以在钻井作业中实时获得岩石强度特性,尽管对于那些既没有直接UCS记录也没有间接测量的油藏段。为了建立相应的实验相关性,对Paja地层上升流中提取的岩石柱(塞)进行了8次无侧限压缩试验(UCS)。同时对从每个堵头周围提取的页岩碎片进行了200次压痕试验,以模拟从钻探的储层中获得的崩落。利用最小二乘技术对两个试验的结果进行相关性分析,寻求代表结果行为的最佳相关性,从而得到两个二阶多项式相关性。(IM) - (UCS)的相关系数为0,6513,(CTF) - (UCS)的相关系数为0,8111。这表明,压痕参数和(UCS)之间的最高相关性与临界过渡力(CTF)有关。
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引用次数: 23
SYNTHESIS AND CHARACTERIZATION OF THE POLYSTYRENE - ASPHALTENE GRAFT COPOLYMER BY FT-IR SPECTROSCOPY 聚苯乙烯-沥青烯接枝共聚物的合成及红外光谱表征
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.469
Adan-Yovani León-Bermúdez, R. Salazar
The creation of new polymer compounds to be added to asphalt has drawn considerable attention because these substances have succeeded in modifying the asphalt rheologic characteristics and physical properties for the enhancement of its behavior during the time of use. This work explains the synthesis of a new graft copolymer based on an asphalt fraction called asphaltene, modified with maleic anhydride. Polystyrene functionalization is conducted in a parallel fashion in order to obtain polybenzylamine resin with an amine - NH2 free group, that reacts with the anhydride graft groups in the asphaltene, thus obtaining the new Polystyrene/Asphaltene graft copolymer.
添加到沥青中的新型聚合物化合物的创造引起了相当大的关注,因为这些物质已经成功地改变了沥青的流变特性和物理性质,以增强其在使用期间的行为。这项工作解释了一种新的接枝共聚物的合成,这种接枝共聚物是基于一种叫做沥青烯的沥青馏分,用马来酸酐改性。对聚苯乙烯进行平行官能化反应,得到无胺NH2基团的聚苄胺树脂,该树脂与沥青烯中的酸酐接枝基团反应,得到新型聚苯乙烯/沥青烯接枝共聚物。
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引用次数: 47
PRESSURE AND PRESSURE DERIVATIVE ANALYSIS FOR INJECTION TESTS WITH VARIABLE TEMPERATURE WITHOUT TYPE-CURVE MATCHING 无类型曲线匹配的变温喷射试验压力及压力导数分析
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2008-12-01 DOI: 10.29047/01225383.464
F. Escobar, J. Martínez, Matilde Montealegre-M.
The analysis of injection tests under nonisothermic conditions is important for the accurate estimation of the reservoir permeability and the well's skin factor; since previously an isothermical system was assumed without taking into account a moving temperature front which expands with time plus the consequent changes in both viscosity and mobility between the cold and the hot zone of the reservoir which leads to unreliable estimation of the reservoir and well parameters. To construct the solution an analytical approach presented by Boughrara and Peres (2007) was used. That solution was initially introduced for the calculation of the injection pressure in an isothermic system. It was later modified by Boughrara and Reynolds (2007) to consider a system with variable temperature in vertical wells. In this work, the pressure response was obtained by numerical solution of the anisothermical model using the Gauss Quadrature method to solve the integrals, and assuming that both injection and reservoir temperatures were kept constant during the injection process and the water saturation is uniform throughout the reservoir. For interpretation purposes, a technique based upon the unique features of the pressure and pressure derivative curves were used without employing type-curve matching (TDS technique). The formulation was verified by its application to field and synthetic examples. As expected, increasing reservoir temperature causes a decrement in the mobility ratio, then estimation of reservoir permeability is some less accurate from the second radial flow, especially, as the mobility ratio increases.
非等温条件下的注入试验分析对于准确估计储层渗透率和井表皮系数具有重要意义;由于以前假设的等温系统没有考虑移动的温度锋,温度锋随着时间的推移而膨胀,加上油藏冷热区之间粘度和流动性的变化,导致对油藏和井参数的估计不可靠。为了构建解决方案,使用了Boughrara和Peres(2007)提出的分析方法。该解决方案最初是用于等温系统中注入压力的计算。后来,Boughrara和Reynolds(2007)对其进行了改进,以考虑直井中温度变化的系统。本文采用高斯正交法对等温模型进行数值求解,并假设注入过程中注入温度和储层温度保持恒定,整个储层含水饱和度均匀,得到压力响应。为了解释目的,采用了一种基于压力和压力导数曲线独特特征的技术,而不采用类型曲线匹配(TDS技术)。通过现场应用和综合算例验证了该公式的正确性。正如预期的那样,随着储层温度的升高,流度比减小,从第二次径向流动中估计储层渗透率的准确性有所降低,特别是当流度比增加时。
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引用次数: 3
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