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Low - medium enthalpy geothermal resource assessment in deep reservoirs of the Llanos Basin - Colombia 哥伦比亚Llanos盆地深层中低焓地热资源评价
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2022-06-29 DOI: 10.29047/01225383.380
Eduardo López- Ramos, Felipe Gonzalez-Penagos, Cesar A. Patiño, A. López
The exploration and exploitation of hydrocarbons in sedimentary basins such as the Llanos Basin of Colombia, have enabled the acquisition of large volumes of surface and subsurface data, for assessing the geothermal potential of deep aquifers. The integrated analysis of geothermal play elements such as temperature, reservoir - fluid  properties, and their depth in the basin, with the available hydrogeological-chemical data, allow us to define three regional plays as follows: Play A, characterized by naturally fractured reservoirs, in crystalline basement rocks - Paleozoic, with temperatures above 150 ºC, semi-confined aquifers; b) Play B, composed by Mesozoic quartz sandstone reservoirs, with primary porosity greater than 10%, temperatures between 75 ºC to 150 ºC, semi-confined aquifers, near to high hydraulic head zones with 500 m difference ranges in the regional piezometric surface; c) Play C, composed by Mesozoic quartz sandstones, high primary porosity, temperatures below 100 ºC, confined aquifers. Available well and Oil and Gas production data suggests that Play A is speculative, Play B is hypothetical, and Play C is known.
在沉积盆地(如哥伦比亚的Llanos盆地)对碳氢化合物的勘探和开发,使人们能够获得大量的地表和地下数据,以评估深层含水层的地热潜力。结合现有水文地质化学资料,综合分析了盆地内地热储层温度、储层流体性质及储层深度等要素,确定了3个区域的地热储层:A区为结晶基岩-古生代天然裂缝型储层,温度在150℃以上,为半密闭含水层;b) b区为中生代石英砂岩储层,原生孔隙度大于10%,温度在75 ~ 150℃之间,为半承压含水层,靠近高水头区,区域测压面差值范围为500 m;c) c区,由中生代石英砂岩组成,原生孔隙度高,温度低于100℃,承压含水层。现有的油井和油气生产数据表明,A层是推测性的,B层是假设的,C层是已知的。
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引用次数: 0
Techno-economic assessment of small wind turbines under la Guajira-Colombia resource conditions 瓜地拉-哥伦比亚资源条件下小型风力发电机技术经济评价
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2022-06-29 DOI: 10.29047/01225383.400
Juan Pablo Jaramillo-Cardona, Juan Carlos Perafan-Lopez, José Luis Torres-Madroñero, C. Nieto-Londoño, J. Sierra-Pérez
Hydroelectric plants broadly sustain Colombian electricity demand. However, wind power emerges to improve the Colombian energy matrix and capacity, satisfying the energy demand. Thus, this study evaluates the technical and economic feasibility of projects based on Small Wind Turbines (SWTs), based on the Colombian wind resource availability. Furthermore, due to the Colombian diversity of energy sources, sensitivity to climate changes and a high percentage of non-interconnected territory, the SWTs excels as an off-grid energy system alternative. For this purpose, the annual energy production and the capacity factor of 24 SWT and the wind resource in Puerto Bolívar, La Guajira, are considered. A techno-economic study that includes cash flow analysis and net present value is used to determine economic viability, considering a financing percentage sensitivity analysis. From the results, it can be concluded that an SWT based project increases its profitability by increasing the IRR value and lowering the financing percentage. Further, the best SWT models can be related to a higher capacity factor value based on the economic phase.
水力发电厂基本上满足了哥伦比亚的电力需求。然而,风力发电的出现改善了哥伦比亚的能源矩阵和容量,满足了能源需求。因此,本研究基于哥伦比亚风能资源的可用性,评估了基于小型风力涡轮机(SWTs)的项目的技术和经济可行性。此外,由于哥伦比亚能源的多样性、对气候变化的敏感性以及非互联领土的高比例,SWTs作为离网能源系统的替代方案非常出色。为此,考虑了La Guajira Puerto Bolívar的年发电量和24 SWT的容量因子以及风力资源。考虑到融资百分比敏感性分析,采用包括现金流量分析和净现值在内的技术经济研究来确定经济可行性。从结果可以看出,基于SWT的项目通过提高IRR值和降低融资比例来提高其盈利能力。此外,最好的SWT模型可能与基于经济阶段的较高容量因子值相关。
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引用次数: 3
Simulation of thermochemical processes in Aspen Plus as a tool for biorefinery analysis 在Aspen Plus中模拟热化学过程作为生物炼制分析的工具
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-12-27 DOI: 10.29047/01225383.372
Valentina Sierra Jimenez, Carlos M. Ceballos Marín, Farid Chejne Janna
The development of tools for the synthesis, design, and optimization of biorefineries requires deep knowledge of the thermochemical processes involved in these schemes. For this project, three models from scientific literature were implemented to simulate the processes: fast pyrolysis in a fluidized bed, fixed-bed, and fluidized-bed gasification using the Aspen PlusTM software. These models allow the user to obtain performance, consumption, and cost parameters necessary for the design and optimization of biorefineries schemes. The fast pyrolysis model encompasses a detailed description of biomass decomposition and kinetics of the process (149 reactions). In the fixed-bed gasification process, seven reactions that model the process have been integrated into two equilibrium reactors that minimize the Gibbs free energy. The model used for fluidized bed gasification considers both hydrodynamic and kinetic parameters, as well as a kinetic model that considers the change in the combustion reaction rate of biomass with oxygen leading to a change in temperature. Due to the complexity and detail of all these models, it was necessary to use FORTRAN subroutines and iterative Excel macros linked to Aspen PlusTM. Finally, the results of each simulation were validated with data from the model sources, as well as experimental results from the literature.
开发用于合成、设计和优化生物精炼厂的工具需要对这些方案中涉及的热化学过程有深入的了解。在本项目中,使用Aspen PlusTM软件,采用科学文献中的三个模型来模拟过程:流化床快速热解、固定床和流化床气化。这些模型允许用户获得设计和优化生物炼制方案所需的性能、消耗和成本参数。快速热解模型包含了对生物质分解和过程动力学(149个反应)的详细描述。在固定床气化过程中,七个模拟该过程的反应被整合到两个使吉布斯自由能最小的平衡反应器中。流化床气化模型考虑了流体动力学参数和动力学参数,同时考虑了生物质与氧的燃烧反应速率变化导致温度变化的动力学模型。由于所有这些模型的复杂性和细节,有必要使用FORTRAN子程序和链接到Aspen PlusTM的迭代Excel宏。最后,利用模型来源的数据和文献中的实验结果对每个模拟结果进行验证。
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引用次数: 0
Low field NMR as an alternative technique to estimate of density and viscosity in toluene-heavy oil mixtures 低场核磁共振作为估计甲苯重油混合物密度和粘度的替代技术
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-12-27 DOI: 10.29047/01225383.366
Maria Sandoval, Herin Valderrama P, Miranda Sánchez M, Daniel R. Molina Velasco, S. Muñoz N
 The success of low field Nuclear Magnetic Resonance (LF-NMR) to estimate heavy oil properties depends on a good selection of mathematical models and fitting parameters. Since the correlations proposed are not universally applicable, in this study, a NMR published model was chosen and tuned to determine the density and viscosity of several mixtures of a Colombian heavy oil with toluene. The process began by mixing toluene with heavy oil to obtain several measuring points with properties similar to those of heavy oils. Each mixture was taken to a 7.5 MHz spectrometer at 40°C, where NMR parameters were acquired and used in the five pre-selected mathematical models. The reliability of viscosity measurements was analysed with the root mean square error (RMSE) and maximum absolute error (MAE). After the NLS regression process, the most accurate prediction was reached through the Burcaw model, with RMSE values of 40.55 cP. On the other hand, the density was estimated with the Wen correlation with results showing a relative error percentage of less than 1%. According to such error values, the tuned models are considered a starting point to extend the NRM technique use to other Colombian heavy oils with low uncertainty levels.
低场核磁共振(LF-NMR)估计稠油性质的成功与否取决于数学模型和拟合参数的选择。由于所提出的相关性并不普遍适用,因此在本研究中,选择并调整了一个已发表的核磁共振模型,以确定哥伦比亚稠油与甲苯的几种混合物的密度和粘度。该过程首先将甲苯与重油混合,以获得与重油性质相似的几个测量点。每种混合物在40°C下被带到7.5 MHz光谱仪,在那里获得核磁共振参数并用于五个预先选择的数学模型。用均方根误差(RMSE)和最大绝对误差(MAE)分析了粘度测量的可靠性。经过NLS回归处理后,Burcaw模型预测最准确,RMSE值为40.55 cP。另一方面,使用Wen相关估计密度,结果显示相对误差百分比小于1%。根据这些误差值,调整后的模型被认为是将NRM技术应用于哥伦比亚其他低不确定性稠油的起点。
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引用次数: 0
Modeling and analysis of a two-stage ORC for recovering waste heat of single flash geothermal cycle 单闪热循环余热回收两级ORC的建模与分析
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2021-12-27 DOI: 10.29047/01225383.383
Yashar Aryanfar, Arash Akhsheej, Kasra Ataei Sheykh, Shaban Mousavi Ghasemlou, J. L. García Alcaraz
Reusing heat dissipation in thermodynamic cycles is an exciting proposal to increase efficiency. In this paper, a two-stage ORC (Organic Rankine Cycle) is proposed to recover and reuse wasted energy from an SFGC (Single Flash Geothermal Cycle). The working fluids studied for the recovery system include R227ea and R116 and R124 and R125. The effect of the main elements of system performance is investigated using sensitivity analyses. Exergy degradation of various components is also calculated. For working fluids R227ea and R116, the thermal efficiency improved by 7.66%, from 0.2023 to 0.2178. The system's thermal efficiency is improved from 0.2023 to 0.2177 by 7.61% using R124 and R125. The exergy efficiency of the initial working fluid improves by 15.04%, from 0.5044 to 0.5803. Further, the second pair of working fluids from 0.5044 to 0.5852, which indicates a 16.01% system efficiency improvement. 85% of the system exergy is eliminated through the expansion valve, turbine 3, heat exchanger 2, and mixer. Including the recovery phase in the base, SFGC will positively affect the power plant's performance.
在热力学循环中重复利用散热是提高效率的一个令人兴奋的建议。本文提出了一种两阶段的有机朗肯循环(ORC)来回收和再利用SFGC(单闪地热循环)中浪费的能量。研究的采油系统工作液包括R227ea和R116, R124和R125。利用灵敏度分析研究了系统性能主要因素的影响。还计算了各组分的火用退化。对于R227ea和R116工质,热效率提高了7.66%,从0.2023提高到0.2178。采用R124和R125,系统热效率从0.2023提高到0.2177,提高了7.61%。初始工质的火用效率从0.5044提高到0.5803,提高了15.04%。此外,第二对工作流体从0.5044提高到0.5852,表明系统效率提高了16.01%。85%的系统用能通过膨胀阀、涡轮3、热交换器2和混合器消除。包括在基地的回收阶段,SFGC将对电厂的性能产生积极影响。
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引用次数: 1
Improvement of lipid productivity on chlorella vulgaris using waste glycerol and sodium acetate 利用废甘油和乙酸钠提高普通小球藻的脂质产率
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2013-06-05 DOI: 10.29047/01225383.203
Laura-Lucía Estévez-Landazábal, A. Barajas-Solano, C. Barajas-Ferreira, V. Kafarov
Although microalgae have great potential as a raw material for biodiesel production it is necessary to increase both biomass and lipids productivity. One way to achieve this goal is the implementation of mixotrophic cultures and the regulation of carbon/nitrogen ratio. The present work aims to improve the productivity of biomass and lipids in Chlorella vulgaris UTEX 1803 using waste glycerol from biodiesel production (1, 5 and 10% v/v) and sodium acetate (5, 10 and 20 mM) as carbon sources together with modification of the initial concentration of nitrogen (1.02; 1.47 and 2.94mM de NaNO3). All experiments were performed at 23±1ºC, with light: dark cycles of 12:12 h during 5 days. In biomass production was achieved a significant increase (80% higher that autothrophic cultures without modification). The best percentages of lipids exceeded control culture up to 2.18. Lipid productivities were also found 2.83 and 3.5 times greater than control. Results show the possibility of increasing the production of biomass and lipids by applying the carbon/nitrogen ratio using as a carbon source waste glycerol of the biodiesel industry that opens up great possibilities for the re-use of this residue thus increasing the sustainability of the process in general, Also has been proved that carbon/nitrogen ratio using sodium acetate is an interesting alternative due to his low cost carbon/nitrogen ratio using sodium acetate is an interesting alternative.
虽然微藻作为生物柴油的原料具有很大的潜力,但必须提高生物质的生产效率和脂质生产效率。实现这一目标的一种方法是实施混合营养培养和调节碳/氮比。本研究旨在提高小球藻UTEX 1803中生物质和脂质的生产效率,以生物柴油生产的废甘油(1、5和10% v/v)和乙酸钠(5、10和20 mM)为碳源,并改变初始氮浓度(1.02;1.47和2.94mM de NaNO3)。所有实验均在23±1℃下进行,5 d内明暗周期为12:12 h。生物量产量显著增加(比未经改造的自养培养高80%)。脂质比对照最高可达2.18%。脂质产量分别是对照组的2.83倍和3.5倍。结果表明,利用生物柴油工业的废甘油作为碳源,应用碳/氮比可以增加生物质和脂类的产量,这为这种残留物的再利用开辟了巨大的可能性,从而提高了整个过程的可持续性。也证明了使用乙酸钠的碳氮比是一个有趣的替代方案,因为使用乙酸钠的低成本碳氮比是一个有趣的替代方案。
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引用次数: 27
Determination of molecular weight of vacuum residue and their SARA fractions 真空渣油及其SARA馏分分子量的测定
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.291
A. León, M. Parra
The molecular weight of a number of vacuum residue and their SARA fractions (Saturated, Aromatics, Resins, and Asphaltenes) typical of the Barrancabermeja refinery in Colombia were determined using the following methods: Gel Permeation Chromatography (GPC), Vapor Pressure Osmometry, (VPO), and Simulated Distillation at High Temperature adjusted to the Gamma distribution function. Molecular weight results in vacuum residue and saturated and aromatics fraction obtained from the three techniques used show consistency within an acceptable range. However, the molecular weight results in resins and asphaltenes fraction obtained by the VPO technique significant differences compared with the results found using the techniques of GPC and DS-Gamma.
采用凝胶渗透色谱法(GPC)、蒸汽压渗透法(VPO)和高温模拟蒸馏法(调整为Gamma分布函数)测定了哥伦比亚Barrancabermeja炼油厂典型真空渣油及其SARA馏分(饱和馏分、芳烃馏分、树脂馏分和沥青馏分)的分子量。三种技术所得的真空渣油、饱和馏分和芳烃馏分的分子量结果均在可接受范围内。然而,VPO技术获得的树脂和沥青质组分的分子量与使用GPC和DS-Gamma技术获得的结果存在显著差异。
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引用次数: 6
Development of a correlation to estimate the fatigue strength for steels based on low-cost tests 基于低成本试验估算钢疲劳强度的相关性的发展
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.246
Alexander Martínez, A. Jaimes, A. Serna, Iván Uribe
Fatigue cracking in metallic materials occurs mainly due to the effect of cyclic stresses and their variation of magnitude over time.  To evaluate the fatigue strength based on S-N curves, many tests are needed, which require a lot of time and incur high costs. For this research, several tests were conducted on examples of high-strength steel to determine their mechanical properties, chemical composition and fatigue. It was found that (Charpy V Notch) CVN impact toughness, the percentage of alloying elements and the mechanical properties of the tension test show a positive lineal effect in relation to the fatigue strength of the materials evaluated. Finally, a correlation was found that showed a very good fit between the experimental fatigue data and the predicted values. The correlation, based on Charpy impact energy tests, the relation to the yield stress, the ultimate stress, and the hardness of the material, allows one to predict resistance to fatigue at a low cost.
金属材料的疲劳开裂主要是由于循环应力的作用及其随时间的变化幅度。基于S-N曲线的疲劳强度评估需要进行多次试验,耗时长,成本高。在本研究中,对高强度钢进行了多次试验,以确定其机械性能、化学成分和疲劳性能。结果表明,(Charpy V缺口)CVN的冲击韧性、合金元素含量和拉伸试验的力学性能与材料的疲劳强度呈正线性关系。最后,发现疲劳试验数据与预测值具有很好的拟合关系。基于Charpy冲击能测试的相关性,与屈服应力、极限应力和材料硬度的关系,使人们能够以低成本预测疲劳抗力。
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引用次数: 5
Detecting and characterizing fractures in sedimentary deposits with stoneley waves 石波沉积层裂缝探测与表征
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.241
C. Escandon, Luis Montes
The naturally fractured reservoirs are attractive potential zones for a successful hydrocarbon prospecting, and the variable density logs (VDL) with Chevron patterns generated by Stoneley waves is a suited tool to characterize fractures. In this project, a simplified algorithm to evaluate fracture location using reflection coefficients and analysis of attenuation was implemented. It also uses a permeability indicator (Stoneley Slowness added by Permeability) to discriminate permeability in fractures.The algorithm was tested in a foot hill well of the Colombian west range, detecting a previously known fractured sandstone zone and indicating its permeability. Besides, the algorithm detected other existent fractures zones with low permeability for production. Previous well flow evaluation of the localized fractures characterized them as low or no permeability fractures.
天然裂缝性储层是成功勘探油气的有吸引力的潜在区,由斯通利波产生的雪佛龙型变密度测井(VDL)是表征裂缝的合适工具。在这个项目中,实现了一种利用反射系数和衰减分析来评估裂缝位置的简化算法。它还使用渗透率指标(斯通利慢度加上渗透率)来区分裂缝的渗透率。该算法在哥伦比亚西部的一口山脚井中进行了测试,发现了一个已知的裂缝砂岩带,并指出了其渗透率。此外,该算法还发现了其他存在的低渗透裂缝带进行生产。以往对局部裂缝的井流评价将其定性为低渗透率或无渗透率裂缝。
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引用次数: 1
Separation of fractions from vacuum residue by supercritical extraction 超临界萃取分离真空渣油馏分
4区 工程技术 Q4 ENERGY & FUELS Pub Date : 2010-07-01 DOI: 10.29047/01225383.286
M. Parra, A. León, L. Hoyos
The Instituto Colombiano del Petróleo (ICP), has implemented a methodology for separating vacuum residue fractions using the technique of supercritical fluid extraction at the pilot scale. The present study evaluates the efficiency of extraction of fractions of a typical vacuum residue in the Barrancabermeja refinery. The extraction test was carried out with n-hexane under supercritical conditions of temperature and pressure of the 265ºC in the range from 450 to 1250 psi, respectively. Finally, each of the fractions were analyzed for their density, viscosity, sulfur content, Conradson Carbon Residue (CCR) content, SARA com-positional analysis, and metals.
哥伦比亚研究所Petróleo (ICP)在中试规模上采用超临界流体萃取技术分离真空残渣馏分。本研究评估了在Barrancabermeja炼油厂提取典型真空渣油馏分的效率。在温度265℃、压力450 ~ 1250 psi的超临界条件下,用正己烷进行萃取试验。最后,对每个馏分进行密度、粘度、硫含量、康拉德森碳渣(CCR)含量、SARA成分分析和金属成分分析。
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引用次数: 5
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