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Research status and challenges in the manufacturing of IR conformal optics 红外保偏光学器件制造的研究现状与挑战
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.04.015
The infrared conformal window is one of the most critical components in aircraft. Conformal windows with high performance bring low aberrations, high aerodynamic performance, reliability in extreme working environments, and added value for aircraft. Through the past decades, remarkable advances have been achieved in manufacturing technologies for conformal windows, where the machining accuracy approaches the nanometer level, and the surface form becomes more complex. These advances are critical to aircraft development, and these manufacturing technologies also have significant reference values for other directions of the ultra-precision machining field. In this review, the infrared materials suitable for manufacturing conformal windows are introduced and compared with insights into their performances. The remarkable advances and concrete work accomplished by researchers are reviewed. The challenges in manufacturing conformal windows that should be faced in the future are discussed.
红外保形窗是飞机上最关键的部件之一。高性能的保形窗具有低像差、高气动性能、在极端工作环境下的可靠性,并能为飞机带来附加值。过去几十年来,保形窗制造技术取得了显著进步,加工精度接近纳米级,表面形状也变得更加复杂。这些进步对飞机的发展至关重要,同时这些制造技术也对超精密加工领域的其他方向具有重要的参考价值。本综述介绍了适用于制造保形窗的红外材料,并比较了这些材料的性能。此外,还回顾了研究人员取得的重大进展和完成的具体工作。还讨论了未来在制造保形窗方面应面临的挑战。
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引用次数: 0
Comparative impact behaviours of ultra high performance concrete columns reinforced with polypropylene vs steel fibres 用聚丙烯纤维和钢纤维加固的超高性能混凝土柱的冲击行为比较
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.04.016
Polypropylene (PP) fibres have primarily used to control shrinkage cracks or mitigate explosive spalling in concrete structures exposed to fire or subjected to impact/blast loads, with limited investigations on capacity improvement. This study unveils the possibility of using PP micro-fibres to improve the impact behaviour of fibre-reinforced ultra-high-performance concrete (FRUHPC) columns. Results show that the addition of fibres significantly improves the impact behaviour of FRUHPC columns by shifting the failure mechanism from brittle shear to favourable flexural failure. The addition of steel or PP fibres affected the impact responses differently. Steel fibres considerably increased the peak impact force (up to 18%) while PP micro-fibres slightly increased the peak (3%–4%). FRUHPC significantly reduced the maximum mid-height displacement by up to 30% (under 20° impact) and substantially improved the displacement recovery by up to 100% (under 20° impact). FRUHPC with steel fibres significantly improved the energy absorption while those with PP micro-fibres reduced the energy absorption, which is different from the effect of PP-macro fibre reported in the literature. The optimal fibre content for micro-PP fibres is 1% due to its minimal fibre usage and low peak and residual displacement. This study highlights the potential of FRUHPC as a promising material for impact-resistant structures by creating a more favourable flexural failure mechanism, enhancing ductility and toughness under impact loading, and advancing the understanding of the role of fibres in structural performance.
聚丙烯(PP)纤维主要用于控制受火或受冲击/爆破载荷的混凝土结构中的收缩裂缝或减轻爆炸剥落,但对提高承载能力的研究有限。本研究揭示了使用聚丙烯微纤维改善纤维增强超高性能混凝土(FRUHPC)柱冲击性能的可能性。研究结果表明,添加纤维可将破坏机制从脆性剪切破坏转变为有利的弯曲破坏,从而显著改善 FRUHPC 柱的抗冲击性能。添加钢纤维或聚丙烯纤维对冲击响应的影响各不相同。钢纤维显著提高了冲击力峰值(高达 18%),而聚丙烯微纤维则略微提高了峰值(3%-4%)。FRUHPC 可将最大中高位移大幅降低 30%(在 20° 冲击下),并将位移恢复大幅提高 100%(在 20° 冲击下)。含有钢纤维的 FRUHPC 显著提高了能量吸收能力,而含有聚丙烯微纤维的 FRUHPC 则降低了能量吸收能力,这与文献中报道的聚丙烯超细纤维的效果不同。由于纤维用量极少,峰值和残余位移较低,因此 PP 微纤维的最佳纤维含量为 1%。这项研究强调了 FRUHPC 作为抗冲击结构材料的潜力,它能创造更有利的弯曲破坏机制,提高冲击荷载下的延展性和韧性,并加深人们对纤维在结构性能中作用的理解。
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引用次数: 0
Spontaneous ignition of corrugated cardboard under dynamic high radiant flux 动态高辐射通量下瓦楞纸板的自燃
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.05.010
Understanding the response of solid combustibles under high radiant fluxes is critical in predicting the thermal damage from extreme scenarios. Unlike the more moderate radiant fluxes in conventional hydrocarbon fires, extreme events such as strong explosion, concentrated sunlight and directed energy can generate dynamic radiant fluxes at the MW/m2 level, creating a unique threat to materials. This study investigates the pyrolysis and spontaneous ignition behaviors of corrugated cardboard by using both experimental and numerical methods, under 10-cm dynamic high radiant fluxes ranging from 0.2 to 1.25 MW/m2 for 10 s. The spontaneous ignition process at dynamic high radiant fluxes was recorded and quantified. Two ignition modes were found at the critical radiant flux of 0.4 MW/m2, namely hot-gas spontaneous ignition and hot-residue piloted ignition. The latter is not the focus of this paper due to its extremely small probability of occurrence. The research reveals that the increase in flux intensity induces shorter delay times for both pyrolysis and ignition, lower ignition energy density, along with a corresponding rise in the critical mass flux and surface temperature at ignition moment. The simulation results are generally aligned with the experimental findings, despite some divergences may be attributed to model simplifications and parameter assumptions. The work contributes to a deeper insight into material behavior under extreme radiation, with valuable implications for fire safety and hazard assessment.
了解固体可燃物在高辐射通量下的反应对于预测极端情况下的热损害至关重要。与传统碳氢化合物火灾中较为温和的辐射通量不同,强烈爆炸、集中阳光和定向能等极端事件可产生兆瓦/平方米级别的动态辐射通量,从而对材料造成独特的威胁。本研究采用实验和数值方法研究了瓦楞纸板在 10 厘米动态高辐射通量(0.2 至 1.25 兆瓦/平方米)条件下 10 秒钟的热解和自燃行为。在 0.4 兆瓦/平方米的临界辐射通量下发现了两种点火模式,即热气体自发点火和热残留物先导点火。由于后者发生的概率极小,因此不是本文的重点。研究表明,通量强度的增加会缩短热解和点火的延迟时间,降低点火能量密度,同时相应提高临界质量通量和点火时刻的表面温度。模拟结果与实验结果基本一致,尽管有些差异可能是由于模型简化和参数假设造成的。这项工作有助于深入了解极端辐射下的材料行为,对消防安全和危险评估具有重要意义。
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引用次数: 0
Blast injury risks to humans within a military trench 军事战壕内的爆炸对人体造成伤害的风险
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.03.006
In land warfare, trenches serve as vital defensive fortifications, offering protection to soldiers while engaging in combat. However, despite their protective function, soldiers often sustain injuries within these trenches. The lack of corresponding blast data alongside empirical injury reports presents a significant knowledge gap, particularly concerning the blast pressures propagating within trench spaces following nearby explosions. This absence hinders the correlation between blast parameters, trench geometry, and reported injury cases, limiting our understanding of blast-related risks within trenches.
This paper addresses the critical aspect of blast propagation within trench systems, essential for evaluating potential blast injury risks to individuals within these structures. Through advanced computational fluid dynamics (CFD) simulations, the study comprehensively investigates blast injury risks resulting from explosions near military trenches. Employing a sophisticated computational model, the research analyzes the dynamic blast effects within trenches, considering both geometrical parameters and blast characteristics influenced by explosive weight and scaled distance.
The numerical simulations yield valuable insights into the impact of these parameters on blast injury risks, particularly focusing on eardrum rupture, lung injury, and traumatic brain injury levels within the trench. The findings elucidate distinct patterns of high-risk zones, highlighting unique characteristics of internal explosions due to confinement and venting dynamics along the trench. This study underscores the significance of detailed numerical modeling in assessing blast injury risks and provides a novel knowledge base for understanding risks associated with explosives detonating near military trenches. The insights gained contribute to enhancing safety measures in both military and civilian contexts exposed to blast events near trench structures.
在陆战中,战壕是重要的防御工事,为士兵作战提供保护。然而,尽管战壕具有保护功能,士兵们还是经常在战壕内受伤。缺乏相应的爆炸数据以及经验性伤害报告是一个重大的知识空白,特别是关于附近爆炸后战壕空间内传播的爆炸压力。这种缺失阻碍了爆炸参数、战壕几何形状和所报告的受伤案例之间的相关性,限制了我们对战壕内爆炸相关风险的了解。本文探讨了战壕系统内爆炸传播的关键问题,这对于评估这些结构内人员的潜在爆炸伤害风险至关重要。通过先进的计算流体动力学(CFD)模拟,该研究全面调查了军事战壕附近爆炸造成的爆炸伤害风险。研究采用了一个复杂的计算模型,分析了战壕内的动态爆炸效应,同时考虑了几何参数以及受爆炸物重量和缩放距离影响的爆炸特征。数值模拟就这些参数对爆炸伤害风险的影响提出了宝贵的见解,尤其侧重于战壕内的耳膜破裂、肺部伤害和脑外伤水平。研究结果阐明了高风险区域的独特模式,突出了由于海沟沿线的封闭和排气动力学而产生的内部爆炸的独特特征。这项研究强调了详细数值建模在评估爆炸伤害风险方面的重要意义,并为了解与军事战壕附近爆炸物爆炸相关的风险提供了新的知识基础。所获得的见解有助于加强在战壕结构附近暴露于爆炸事件的军事和民用环境中的安全措施。
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引用次数: 0
Exploring the hygroscopic behavior of highly energetic oxidizer ammonium dinitramide (ADN) at different temperatures and humidities using an innovative hygroscopic modeling 利用创新吸湿模型探索高能氧化剂二硝胺铵(ADN)在不同温度和湿度下的吸湿行为
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.06.003
Ammonium dinitramide (ADN) is a new type of green energetic oxidizer with excellent energy density and low pollution combustion characteristics. However, the strong hygroscopicity has a significant impact on its practical application. To assist in the research on moisture-proof modification of ADN materials, an innovative hygroscopic modeling approach was proposed to evaluate the hygroscopicity of ADN at various temperatures and humidities. By investigating the diffusion coefficient of water molecules in molecular dynamics processes, a visual insight into the hygroscopic process of ADN was gained. Furthermore, analyzing the non-covalent interactions between ADN and water molecules, the hygroscopicity of ADN could be evaluated qualitatively and quantitatively. The energy analysis revealed that electrostatic forces play a dominant role in the process of water adsorption by ADN, whereas van der Waals forces impede it. As a whole, the simulation results show that ADN presents the following hygroscopic law: At temperatures ranging from 273 K to 373 K and relative humidity (RH) from 10% to 100%, the hygroscopicity of ADN generally shows an increasing trend with the rise in temperature and humidity based on the results of three simulations. According to the non-hygroscopic point (298 K, 52% RH) of ADN obtained by experiment in the literature, a non-hygroscopic range of temperature and humidity for ADN can be depicted when the simulation results in relative hygroscopicity is less than or equal to 17%. This study can provide effective strategies for screening anti-hygroscopic modified materials of ADN.
二硝胺铵(ADN)是一种新型绿色高能氧化剂,具有优异的能量密度和低污染燃烧特性。然而,强烈的吸湿性对其实际应用有很大影响。为了帮助研究 ADN 材料的防潮改性,研究人员提出了一种创新的吸湿性建模方法,用于评估 ADN 在不同温度和湿度下的吸湿性。通过研究分子动力学过程中水分子的扩散系数,可以直观地了解 ADN 的吸湿过程。此外,通过分析 ADN 与水分子之间的非共价相互作用,可以定性和定量地评估 ADN 的吸湿性。能量分析表明,静电力在 ADN 吸附水的过程中起主导作用,而范德华力则阻碍吸附。总的来说,模拟结果表明 ADN 呈现出以下吸湿规律:在温度为 273 K 至 373 K 和相对湿度(RH)为 10% 至 100% 的条件下,根据三次模拟结果,ADN 的吸湿性一般会随着温度和湿度的升高而呈上升趋势。根据文献中通过实验得到的 ADN 的非吸湿点(298 K,52% RH),当模拟结果中的相对吸湿性小于或等于 17% 时,可以描绘出 ADN 的非吸湿温度和湿度范围。这项研究可为筛选 ADN 的抗吸湿改性材料提供有效策略。
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引用次数: 0
Data-driven prediction of dimensionless quantities for semi-infinite target penetration by integrating machine-learning and feature selection methods 通过整合机器学习和特征选择方法,以数据驱动预测半无限目标穿透的无量纲数量
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.04.012
This study employs a data-driven methodology that embeds the principle of dimensional invariance into an artificial neural network to automatically identify dominant dimensionless quantities in the penetration of rod projectiles into semi-infinite metal targets from experimental measurements. The derived mathematical expressions of dimensionless quantities are simplified by the examination of the exponent matrix and coupling relationships between feature variables. As a physics-based dimension reduction methodology, this way reduces high-dimensional parameter spaces to descriptions involving only a few physically interpretable dimensionless quantities in penetrating cases. Then the relative importance of various dimensionless feature variables on the penetration efficiencies for four impacting conditions is evaluated through feature selection engineering. The results indicate that the selected critical dimensionless feature variables by this synergistic method, without referring to the complex theoretical equations and aiding in the detailed knowledge of penetration mechanics, are in accordance with those reported in the reference. Lastly, the determined dimensionless quantities can be efficiently applied to conduct semi-empirical analysis for the specific penetrating case, and the reliability of regression functions is validated.
本研究采用数据驱动方法,将尺寸不变性原理嵌入人工神经网络,从实验测量结果中自动识别棒状射弹穿透半无限金属目标时的主要无量纲量。通过检查指数矩阵和特征变量之间的耦合关系,简化了无量纲量的数学表达式。作为一种基于物理学的维度缩减方法,这种方法将高维参数空间缩减为在穿透情况下只涉及几个物理上可解释的无量纲量的描述。然后,通过特征选择工程评估了四种撞击条件下各种无量纲特征变量对穿透效率的相对重要性。结果表明,通过这种协同方法,无需参考复杂的理论方程,也无需借助详细的穿透力学知识,所选择的关键无量纲特征变量与参考文献中的变量一致。最后,确定的无量纲量可以有效地应用于对特定穿透情况进行半经验分析,并验证了回归函数的可靠性。
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引用次数: 0
A data and physical model dual-driven based trajectory estimator for long-term navigation 基于数据和物理模型双驱动的长期导航轨迹估计器
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.05.006
Long-term navigation ability based on consumer-level wearable inertial sensors plays an essential role towards various emerging fields, for instance, smart healthcare, emergency rescue, soldier positioning et al. The performance of existing long-term navigation algorithm is limited by the cumulative error of inertial sensors, disturbed local magnetic field, and complex motion modes of the pedestrian. This paper develops a robust data and physical model dual-driven based trajectory estimation (DPDD-TE) framework, which can be applied for long-term navigation tasks. A Bi-directional Long Short-Term Memory (Bi-LSTM) based quasi-static magnetic field (QSMF) detection algorithm is developed for extracting useful magnetic observation for heading calibration, and another Bi-LSTM is adopted for walking speed estimation by considering hybrid human motion information under a specific time period. In addition, a data and physical model dual-driven based multi-source fusion model is proposed to integrate basic INS mechanization and multi-level constraint and observations for maintaining accuracy under long-term navigation tasks, and enhanced by the magnetic and trajectory features assisted loop detection algorithm. Real-world experiments indicate that the proposed DPDD-TE outperforms than existing algorithms, and final estimated heading and positioning accuracy indexes reaches 5° and less than 2 m under the time period of 30 min, respectively.
基于消费级可穿戴惯性传感器的长期导航能力在智能医疗、紧急救援、士兵定位等多个新兴领域发挥着至关重要的作用。现有长期导航算法的性能受到惯性传感器累积误差、本地磁场干扰和行人复杂运动模式的限制。本文开发了一种基于数据和物理模型双驱动的稳健轨迹估计(DPDD-TE)框架,可用于长期导航任务。本文开发了一种基于双向长短期记忆(Bi-LSTM)的准静态磁场(QSMF)检测算法,用于提取有用的磁场观测信息以进行航向校准;还采用了另一种 Bi-LSTM 算法,通过考虑特定时间段内的混合人体运动信息来估计步行速度。此外,还提出了基于数据和物理模型双驱动的多源融合模型,以整合基本的 INS 机械化和多层次约束与观测,从而在长期导航任务中保持精度,并通过磁场和轨迹特征辅助环路检测算法进行增强。实际实验表明,所提出的 DPDD-TE 优于现有算法,在 30 分钟的时间内,最终估计的航向和定位精度指标分别达到 5°和小于 2 米。
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引用次数: 0
A cloud model target damage effectiveness assessment algorithm based on spatio-temporal sequence finite multilayer fragments dispersion 基于时空序列有限多层片段分散的云模型目标损伤效果评估算法
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.05.008
To solve the problem of target damage assessment when fragments attack target under uncertain projectile and target intersection in an air defense intercept, this paper proposes a method for calculating target damage probability leveraging spatio-temporal finite multilayer fragments distribution and the target damage assessment algorithm based on cloud model theory. Drawing on the spatial dispersion characteristics of fragments of projectile proximity explosion, we divide into a finite number of fragments distribution planes based on the time series in space, set up a fragment layer dispersion model grounded in the time series and intersection criterion for determining the effective penetration of each layer of fragments into the target. Building on the precondition that the multilayer fragments of the time series effectively assail the target, we also establish the damage criterion of the perforation and penetration damage and deduce the damage probability calculation model. Taking the damage probability of the fragment layer in the spatio-temporal sequence to the target as the input state variable, we introduce cloud model theory to research the target damage assessment method. Combining the equivalent simulation experiment, the scientific and rational nature of the proposed method were validated through quantitative calculations and comparative analysis.
为解决防空拦截中不确定弹丸与目标交点下碎片攻击目标时的目标毁伤评估问题,本文提出了一种利用时空有限多层碎片分布计算目标毁伤概率的方法和基于云模型理论的目标毁伤评估算法。借鉴弹丸近炸破片的空间弥散特性,基于空间时间序列划分有限个破片分布平面,建立基于时间序列的破片层弥散模型和交集判据,确定各层破片对目标的有效穿透力。在时间序列的多层碎片有效攻击目标的前提下,我们还建立了穿孔和穿透损伤的损伤判据,并推导出损伤概率计算模型。以时空序列中碎片层对目标的损伤概率为输入状态变量,引入云模型理论研究目标损伤评估方法。结合等效模拟实验,通过定量计算和对比分析,验证了所提方法的科学性和合理性。
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引用次数: 0
Influences of oscillation on the physical stability and explosion characteristics of solid‒liquid mixed fuel 振荡对固液混合燃料物理稳定性和爆炸特性的影响
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.05.014
Chi Zhang , Ge Song , Hui Guo , Jiafan Ren , Chunhua Bai
The stratification phenomenon resulting from differences in the physical properties of solid‒liquid components seriously affect the final combustion and explosion characteristics of mixed fuel under the action of oscillation. The effects of oscillation on the physical stability of mixed fuel with two solid‒liquid ratios and three liquid component distribution ratios have been investigated using a self-designed experimental system at oscillation frequencies of 60–300 r/min. The explosion characteristics of mixed fuel before and after oscillation are gained from a 20 L spherical explosion container system. When the mass ratio of liquid components is controlled at 66.9%, 64.7%, 62.6% the final explosion characteristics are stable, with a maximum difference of only 0.71%. The volume of liquid fuel precipitation increases with increasing oscillation frequency when the mass ratio of liquid components reaches 71.7%, 69.6%, 67.7%. The fuel explosion overpressure after oscillation decreases with increasing liquid precipitation volume, and the repeatability is poor, with a maximum standard deviation of 82.736, which is much higher than the ratio without stratification. Properly controlling the mass ratio of liquid components of the mixed fuel can effectively combat the impact of oscillation on the physical state and maintain the stability of the final explosion characteristics.
在振荡作用下,固液组分物理性质差异导致的分层现象严重影响了混合燃料的最终燃烧和爆炸特性。利用自行设计的实验系统,在振荡频率为 60-300 r/min 的条件下,研究了振荡对两种固液比和三种液体组分分布比的混合燃料的物理稳定性的影响。从一个 20 L 的球形爆炸容器系统中获得了混合燃料在振荡前后的爆炸特性。当液体成分的质量比控制在 66.9%、64.7% 和 62.6% 时,最终爆炸特性稳定,最大差异仅为 0.71%。当液体组分质量比达到 71.7%、69.6%、67.7% 时,液体燃料析出量随振荡频率的增加而增加。振荡后的燃料爆炸超压随液体析出量的增加而减小,重复性较差,最大标准偏差为 82.736,远高于不分层的比例。适当控制混合燃料液体组分的质量比,可有效对抗振荡对物理状态的影响,保持最终爆炸特性的稳定性。
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引用次数: 0
Kinetics and mechanism of the low-energy β-α phase transition of the second kind in 2,4-dinitroanisole 2,4-二硝基苯甲醚中低能β-α第二类相变的动力学和机理
IF 5 Q1 ENGINEERING, MULTIDISCIPLINARY Pub Date : 2024-10-01 DOI: 10.1016/j.dt.2024.04.004
In this work, comprehensive studies of 2,4-dinitroanisole (2,4DNAN) were carried out using powder thermorentgenography of the internal standard. The time of the complete polymorphic transition in the solid phase β→α in 2,4DNAN under various combinations of conditions has been determined. It has been established that, regardless of the season of manufacture of the substance, when it is stored for 8–9 months, with a change in ambient temperature from minus 30 °C to plus 30 °C, a complete polymorphic transition β→α occurs. When stored in conditions below minus 5 °C, polymorphic transition does not occur. When stored in conditions above plus 30 °C in a closed container, polymorphic transition occurs within 3 weeks. The polymorphic transition is accompanied by a decrease in density by 1.3%–1.5% and an increase in melting temperature by 10–12 °C, depending on the degree of purity of the starting substance. The activation energy of the molecular rearrangement was 68–70 kJ/mol (16.5 ± 3 kcal/mol). The mechanism of polymorphic transition has been evaluated, which is presumably based on internal homodiffusion and energy transfer to the surface of the mass of powder particles and the product. The average activation energy of the polymorphic transition process was 110 ± 6.2 kJ/mol (26.2 kcal/mol). In an open container, reactions proceed by a homogeneous mechanism, and in a closed container by a heterogeneous mechanism involving the gas phase.
本研究利用内标粉末热成像仪对 2,4-二硝基苯甲醚(2,4DNAN)进行了全面研究。测定了在不同条件组合下,2,4-二硝基苯甲醚固相β→α完全多态转变的时间。结果表明,无论该物质的生产季节如何,在环境温度从零下 30 °C升至零上 30 °C、贮存 8-9 个月后,都会发生完全的多态转变 β→α。在低于零下 5 °C 的条件下储存时,不会发生多态转变。如果在高于正 30 °C 的条件下储存在密闭容器中,多态转变会在 3 周内发生。多态转变伴随着密度下降 1.3%-1.5%,熔化温度升高 10-12 °C,具体取决于起始物质的纯度。分子重排的活化能为 68-70 kJ/mol(16.5 ± 3 kcal/mol)。对多晶型转变的机理进行了评估,推测其机理是基于粉末颗粒和产物表面的内部同扩散和能量转移。多态转变过程的平均活化能为 110 ± 6.2 kJ/mol(26.2 kcal/mol)。在开放容器中,反应以均相机制进行,而在封闭容器中,反应以涉及气相的异相机制进行。
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引用次数: 0
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Defence Technology(防务技术)
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