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2013 International Conference on Materials for Renewable Energy and Environment最新文献

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The adsorptive ability of Ti-pillared montmorillonite for lead (II) cation 钛柱蒙脱土对铅(II)阳离子的吸附性能
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893739
Yuan Cheng, Xuanhui Zhang, W. Xie, Dan Chen, Guohua Li
In this thesis, Ti-pillared montmorillonite was prepared by a sol-gel method. The sample was characterized by X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). The results show that the crystal phase of the sample is composed of anatase and montmorillonite. The microstructure of the sample is still layered structure, in which anatase particles lie in the interlayer space. Furthermore, the XRD results indicate that the interlayer distance of crystal plane (001) of the montmorillonite left-shift obviously. In other words, its interlayer distance increases obviously. The adsorptive ability of the sample was tested with industry wastewater, which containing Pb2+. The results indicate that the adsorptive rate of the sample for lead (II) cation is 100% almost. The Ti-pillared montmorillonite absorbed Pb2+ saturatedly was impregnated into 3 mol/L nitric acid solution for 2 h to dissolve the lead cation, then it was rinsed by deionized water for three times and dried at 120 °C overnight. The sample impregnated by nitric acid solution was used to treat Pb2+ containing industry wastewater again. The results show that its adsorptive rate can still reach above 95%.
本文采用溶胶-凝胶法制备了钛柱蒙脱土。采用x射线衍射(XRD)和高分辨率透射电镜(HRTEM)对样品进行了表征。结果表明,样品的晶相由锐钛矿和蒙脱石组成。样品的微观结构仍为层状结构,锐钛矿颗粒位于层间空间。此外,XRD结果表明蒙脱土的晶面(001)层间距离左移明显。也就是说,它的层间距离明显增大。用含Pb2+的工业废水对样品进行了吸附性能测试。结果表明,样品对铅(II)阳离子的吸附率几乎为100%。将饱和吸附Pb2+的钛柱蒙脱土浸渍在3 mol/L硝酸溶液中2 h,溶解铅阳离子,然后用去离子水冲洗3次,120℃下烘干过夜。用硝酸溶液浸渍试样对含Pb2+的工业废水进行了再处理。结果表明,其吸附率仍可达95%以上。
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引用次数: 2
Evaluation of coal gangue and ash for calcined kaolin preparation 煅烧高岭土制备用煤矸石和灰分的评价
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893780
P. Zhu, Zhenglun Shi, Leming Cheng, M. Fang
For comprehensive utilization of solid waste, coal gangue, slag of CFB and washed fly ash provided by a coal mine were evaluated on their potential as calcined kaolin. Studies on these samples include the determination of chemical composition by ICP, the analysis of mineralogical construction by XRD, orthogonal experiments of iron leaching by acids and decarburization by calcination. Results show that the chemical compositions of three samples are very close to the kaolinite and their mass ratios of SiO2 to Al2O3 are all about 1.4:1. The major crystalline phase presented in the coal gangue is kaolinite, while an obvious band of amorphous materials are found in others since they are combustion products, but none of them is in exception of layer structure observed though SEM. Orthogonal experiments of iron leaching by acids reveal that the maximal iron leaching rate and product-calcined whiteness of the coal gangue are 63.59% and 68.54% respectively. For that of the slag of CFB, they are 39.74% and 40.55%, while for that of the washed fly ash, they are 31.58% and 45.92%. Thus, it can be inferred that this coal gangue can better fulfill the preparation of high-quality calcined kaolin.
针对固体废弃物的综合利用,对某煤矿提供的煤矸石、循环流化床炉渣和水洗粉煤灰作为煅烧高岭土的潜力进行了评价。对这些样品进行了化学成分测定、XRD矿物结构分析、酸浸铁正交试验和煅烧脱碳试验等研究。结果表明,3种样品的化学成分与高岭石非常接近,SiO2与Al2O3的质量比均在1.4:1左右。煤矸石的主要晶相为高岭石,其余为燃烧产物,存在明显的非晶态物质带,但均以SEM观察到的层状结构为例外。酸浸铁的正交试验结果表明,该煤矸石的最大铁浸出率为63.59%,产品焙烧白度为68.54%。循环流化床炉渣和水洗粉煤灰分别为39.74%和40.55%和31.58%和45.92%。由此可以推断,该煤矸石可以较好地完成高品质煅烧高岭土的制备。
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引用次数: 0
Structure and morphology of SiO2/PVA-PAMPS composite membrane SiO2/PVA-PAMPS复合膜的结构与形态
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893725
Jian Liu, Songbo Li, G. Guo
Polyvinyl alcohol(PVA) modified by SiO2/poly 2-acrylamido 2-methylpropane sulfonic acid (PAMPS) electrolyte membrane SiO2/PVA-PAMPS was prepared by a Sol-gel synthesis in situ technique. Fourier transform infrared spectroscopy is used to characterize changes of the membrane's microstructures after grafting. The morphology of the membrane's microstructures are studied by scanning electrolytic microscope and X-ray diffraction. The results show that the conductivity of the SiO2 (30wt%)/PVA-PAMPS(20wt%) membrane was 4.12×10-2S/cm and AMPS is easily blended into polyvinyl alcohol (PVA) modified by namometer silicon dioxide.
采用溶胶-凝胶原位合成技术制备了SiO2/聚2-丙烯酰胺- 2-甲基丙烷磺酸(PAMPS)改性聚乙烯醇(PVA)电解质膜。利用傅里叶变换红外光谱对接枝后膜的微观结构变化进行了表征。利用扫描电显微镜和x射线衍射对膜的微观结构进行了研究。结果表明:SiO2 (30wt%)/PVA- pamps (20wt%)膜的电导率为4.12×10-2S/cm, AMPS易于与名称型二氧化硅改性的聚乙烯醇(PVA)混合;
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引用次数: 0
Morphology control of LiCoO2 thin film prepared by pulsed laser deposition 脉冲激光沉积LiCoO2薄膜的形貌控制
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893727
Desheng Liu, Yun Chao, Shengnan Wu, Shuying Zhong, M. Lei
LiCoO2 thin film samples have been prepared by pulsed laser deposition under different deposition conditions. A series of tests have been done to investigate the relationship between the film quality and the deposition conditions. The results from XRD show that the LiCoO2 films deposited by PLD thermodynamically tend to form (003) preferred orientation. But the films grown at high repetition rate (35Hz) and low oxygen pressure (1Pa) show a random orientation. SEM and AFM images reveal that the size and uniformity of LiCoO2 crystalline grains is directly depends on the deposition temperature and repetition rate. Therefore, by adjusting the deposition parameters, to achieve the purpose of LiCoO2 thin film morphology control is feasible.
在不同的沉积条件下,采用脉冲激光沉积法制备了LiCoO2薄膜样品。通过一系列试验研究了沉积条件与薄膜质量的关系。XRD结果表明,PLD沉积的LiCoO2薄膜在热力学上倾向于形成(003)择优取向。而在高重复频率(35Hz)和低氧分压(1Pa)条件下生长的薄膜表现出随机取向。SEM和AFM图像显示,LiCoO2晶粒的尺寸和均匀性直接取决于沉积温度和重复速率。因此,通过调节沉积参数,达到控制LiCoO2薄膜形貌的目的是可行的。
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引用次数: 1
Application research of hydrophobic silica in the recovery of oil vapor 疏水二氧化硅在油蒸汽回收中的应用研究
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893733
Hongxing Zhang, Longmei Tan, Jingfeng Wu, Zuzheng Shang
The adsorption characteristics and porous structure of self-made hydrophobic silica (HS) used in the recovery of oil vapor were investigated using the methods of N2 (g) adsorption measurement and SEM photograph, together with the pillared activated carbon (PAC). HS is a typical mesoporous material and has smaller surface area and bigger average pore diameter compared with the PAC. PAC has the well-developed interstitial structure, while HS's surface holes are shallow. The structural difference between the two adsorbents determined the different adsorption/desorption performance in recovery of oil vapor. PAC has the bigger adsorption amount and faster adsorption rate of oil vapor, while the oil vapor adsorbed in HS is much easier to be desorbed. The mixture of PAC and HS represented both the properties of fast adsorption rate and perfect desorption performance which can improve the life and efficiency of the recovery system at the same time. The adsorption amount of adsorbent increased with the increase of inlet concentration and decreased with the increase of inlet velocity of oil vapor.
采用N2 (g)吸附法、扫描电镜(SEM)摄影法,结合柱状活性炭(PAC),研究了自制疏水二氧化硅(HS)在油蒸汽回收中的吸附特性和孔隙结构。HS是一种典型的介孔材料,比PAC具有更小的表面积和更大的平均孔径。PAC具有发育良好的间隙结构,而HS表面孔洞较浅。两种吸附剂的结构差异决定了两种吸附剂在回收油蒸汽时的吸附/解吸性能不同。PAC对油蒸气的吸附量更大,吸附速率更快,而HS中吸附的油蒸气更容易解吸。PAC和HS的混合物具有吸附速度快、解吸性能好等特点,可提高回收系统的使用寿命和效率。吸附剂的吸附量随入口浓度的增大而增大,随入口油蒸气速度的增大而减小。
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引用次数: 0
The research about thermal conductivity for fractal porous material 分形多孔材料的导热性能研究
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893713
Donghui Zhang, C. Tang, Weiliang Kong, Ning Chen
Heat conduction process in fractal structure is analyzed through numerical computation method in this paper. Fractal structure can be simplified as a kind of binary mixture, composed of pore and matrix. If convection and radiation heat transfer are neglected, it is found that the effective thermal conductivity for random Sierpinski Carpet is approximately scaled as the structure length scale or matrix percent. The macro-pore distribution and fractal dimension have much effect to the effective thermal conductivity. That is to say, the structure heterogeneity plays an important role in heat transfer process for fractals. The research would be helpful to understand the micro-scale heat conduction mechanism well.
本文通过数值计算方法对分形结构中的热传导过程进行了分析。分形结构可以简化为一种由孔隙和基质组成的二元混合物。在忽略对流和辐射传热的情况下,发现随机Sierpinski地毯的有效导热系数近似成结构长度尺度或矩阵百分比。宏观孔隙分布和分形维数对有效导热系数有很大影响。也就是说,结构非均质性在分形的传热过程中起着重要的作用。该研究有助于更好地理解微尺度热传导机理。
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引用次数: 0
Wind velocity prediction at wind turbine hub height based on CFD model 基于CFD模型的风力机轮毂高度风速预测
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893695
Li Li, Yimei Wang, Yongqian Liu
To meet the requirements of the wind power prediction of wind farms, the wind velocity at the wind turbines' hub height were predicted in this paper, taking an actual wind farm as the example. First, many steady CFD numerical calculations were conducted to simulate the air flow field above the wind farm. Standard k-εturbulence model was adopted in the calculation. Then, taking the mesoscale NWP parameters as input data, the wind velocities were predicted by the simulated flow fields during the period of the year 2010. Compared with the measured wind velocity, the yearly mean absolute error (MAE) of predicted wind velocity for each wind turbine is less than 2m/s, and as the MAE decreases, the number of wind velocity samples increases. It shows that wind velocity prediction by this CFD method is accurate. The research in this paper may provide support for the work of wind power forecasting.
为满足风电场风电功率预测的要求,本文以实际风电场为例,对风机轮毂高度处的风速进行了预测。首先进行了多次稳态CFD数值计算,模拟了风电场上方的气流场。计算采用标准k-ε湍流模型。然后,以中尺度NWP参数为输入数据,利用模拟流场对2010年的风速进行预测。与实测风速相比,预测风速的年平均绝对误差(MAE)小于2m/s,并且随着MAE的减小,风速样本数量增加。计算结果表明,该方法预测风速是准确的。本文的研究可为风电功率预测工作提供支持。
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引用次数: 6
One study on biogas production potential character of coffee husks 咖啡壳产气潜力特性研究
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893644
W. Qiuxia, X. Rui, Liu Jianchang, Duan Huanyun, Y. Yage, Han Jiahong
Taking the fresh coffee husks as the raw material and the cultured active sludge as the inoculums to operate the measurement of biogas yield potential research, under mesophilic (35 °C) and ambient temperature conditions. In this paper, the biogas yield, cumulative biogas production and biogas production rate were analyzed. The biogas yield potential of coffee husks were 494 ml/g TS and 544 ml/g VS under mesophilic condition and 365 ml/g TS and 402 ml/g VS under ambient temperature condition respectively.
以新鲜咖啡壳为原料,以培养的活性污泥为接种体,在中温(35℃)和环境温度条件下进行了沼气产量潜力的测定研究。本文对产气量、累积产气量和产气率进行了分析。中温条件下咖啡壳的产气潜力分别为494 ml/g TS和544 ml/g VS,常温条件下为365 ml/g TS和402 ml/g VS。
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引用次数: 1
The modified model for predicting the products distribution in pyrolysis of biomass 改进的生物质热解产物分布预测模型
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893677
Shuguang Zhu, Jianfeng Shen, Xinzhi Liu, Houlei Zhang, Bin Li
Pyrolysis is known as one of the promising thermochemical conversion routes in producing solid (charcoal), liquid (tar) and gaseous products. In the present study, deposition coefficient, defined as the fraction of volatile and gases deposited on the char due to the secondary reaction, is introduced to modify the kinetics model in literatures. The effects of heating rates, heating temperatures and deposition coefficients on pyrolysis products distribution under non-isothermal and isothermal conditions are discussed. The investigation based on the modified model shows that the deposition coefficient affects the secondary reaction products distribution significantly. When the deposition coefficient increases, the generation rate and the concentration of char increase and the volatile and gases in secondary reaction decrease. The results indicate that primary reaction plays a dominant role in volatile and gases generation and secondary reaction plays a dominant role in char generation. The work in this paper provides useful information for optimal design of biomass gasifiers and reactors.
热解被认为是生产固体(木炭)、液体(焦油)和气体产品的有前途的热化学转化途径之一。在本研究中,引入沉积系数来修正文献中的动力学模型,沉积系数定义为由于二次反应而沉积在焦炭上的挥发分和气体的比例。讨论了加热速率、加热温度和沉积系数对非等温和等温条件下热解产物分布的影响。基于修正模型的研究表明,沉积系数对二次反应产物分布有显著影响。随着沉积系数的增大,炭的生成速率和浓度增加,二次反应中的挥发分和气体减少。结果表明:一次反应对挥发物和气体的生成起主导作用,二次反应对炭的生成起主导作用。本文的工作为生物质气化炉和反应器的优化设计提供了有益的参考。
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引用次数: 0
High-temperature and low-oxygen combustion technology for carbon rotary kilns 碳回转窑高温低氧燃烧技术
Pub Date : 2013-08-01 DOI: 10.1109/ICMREE.2013.6893803
Chunhua Wang, F. Jia, Hongna Wang, Zhi Zhang, Longbo Gao
Taking a carbon rotary kiln for example, numerical simulations were conducted on gas and solid spaces of the kiln using Fluent and Matlab softwares. Through changing temperature and oxygen mass concentration of primary air, temperature field distributions are obtained in different conditions. The results indicate that, if the low-temperature flue gas instead of the primary air is injected to the kiln at the kiln outlet, the temperature of the gas and solid particles in the cooling zone will be lower, but the length of the calcining zone will not be shortened notably. Therefore, suggestions were put forward, as the low temperature flue gas from the waste heat recovery device after rotary kiln or mixing the high-temperature gas from the kiln inlet, or the primary normal air mixing with the low-temperature gas is injected to the kiln at the kiln outlet, low oxygen atmosphere area can be formed. By the method, solid particles can be cooled, meantime, the solid particles burning loss can be reduced, which lead to the increment of the kiln actual yield.
以某碳料回转窑为例,利用Fluent和Matlab软件对回转窑的气固空间进行了数值模拟。通过改变一次空气的温度和氧质量浓度,得到不同条件下的温度场分布。结果表明,在窑口注入低温烟气代替一次风,冷却区气体和固体颗粒的温度会降低,但煅烧区长度不会明显缩短。因此,提出建议,将回转窑后余热回收装置排出的低温烟气或与窑口的高温气体混合,或将与低温气体混合的一次正常空气在窑口注入窑内,可形成低氧大气区。该方法在对固体颗粒进行冷却的同时,降低了固体颗粒的燃烧损失,从而提高了窑炉的实际产量。
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引用次数: 0
期刊
2013 International Conference on Materials for Renewable Energy and Environment
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