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CdTe QDs@SiO2 composite material for efficient photocatalytic degradation of tetracycline composites 用于高效光催化降解四环素复合材料的 CdTe QDs@SiO2 复合材料
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-02-02 DOI: 10.1016/j.gce.2024.01.004

In the contemporary context, tetracycline is widely utilized as a prevalent antibiotic in various facets of life. However, the excessive use of antibiotics has caused visible environmental consequences. Henceforth, the scientific community has increasingly focused on developing catalysts that exhibit exceptional efficacy in the proficient degradation of tetracycline. In this study, a novel nanomaterial was developed to encapsulate CdTe quantum dots (QDs) with a SiO2 shell. The distinct synthesis approach generated a composite material that showed heterogeneity and considerably increased the contact area with contaminants. Consequently, the transfer of photoelectron to the SiO2 spheres was significantly improved, leading to a more efficient separation during the catalytic process. The study investigated how different factors, such as the loading of the catalyst, the initial concentration of tetracycline, pH levels, and the wight ratio of CdTe QDs (SiO2 + CdTe QDs) affected the effectiveness of photocatalytic tetracycline degradation. The findings indicated that the optimal degradation efficiency was observed at a catalyst concentration of 0.25 g/L and a solution pH of 9, leading to an impressive degradation rate of 96% within a mere 2 h timeframe.

在当代,四环素作为一种普遍的抗生素被广泛应用于生活的各个方面。然而,抗生素的过度使用对环境造成了明显的影响。因此,科学界越来越重视开发能有效降解四环素的催化剂。本研究开发了一种新型纳米材料,用二氧化硅外壳封装碲化镉量子点(QDs)。独特的合成方法产生的复合材料具有异质性,大大增加了与污染物的接触面积。因此,光电子向二氧化硅球体的转移得到了显著改善,从而在催化过程中实现了更高效的分离。研究调查了催化剂的负载量、四环素的初始浓度、pH 值以及碲化镉 QDs(SiO2 + 碲化镉 QDs)的重量比等不同因素如何影响光催化降解四环素的效果。研究结果表明,催化剂浓度为 0.25 克/升、溶液 pH 值为 9 时,降解效率最佳,在短短 2 小时内降解率达到 96%。
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引用次数: 0
Machine learning aided investigation on the structure-performance correlation of MOF for membrane-based He/H2 separation 机器学习辅助研究用于膜式氢/氢分离的 MOF 的结构-性能相关性
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-02-01 DOI: 10.1016/j.gce.2024.01.005

The separation of He/H2 using membrane technology has gained significant interest in the field of He extraction from natural gas. One of the greatest challenges associated with this process is the extremely close kinetic diameters of the two gas molecules, resulting in low membrane selectivity. In this study, we investigated the structure-performance relationship of metal-organic framework (MOF) membranes for He/H2 separation through molecular simulations and machine learning approaches. By conducting molecular simulations, we identified the potential MOF membranes with high separation performance from the Computation-Ready Experimental (CoRE) MOF database, and the diffusion-dominated mechanism was further elucidated. Moreover, random forest (RF)-based machine learning models were established to identify the crucial factors influencing the He/H2 separation performance of MOF membranes. The pore limiting diameter (PLD) and void fraction (φ), are revealed as the most important physical features for determining the membrane selectivity and He permeability, respectively. Additionally, density functional theory (DFT) calculations were carried out to validate the molecular simulation results and suggested that the electronegative atoms on the pore surfaces can enhance the diffusion-based separation of He/H2, which is critical for improving the membrane selectivities of He/H2. This study offers useful insights for designing and developing novel MOF membranes for the separation of He/H2 at the molecular level.

利用膜技术分离 He/H2 在从天然气中提取 He 领域获得了极大的关注。该工艺面临的最大挑战之一是两种气体分子的动力学直径非常接近,导致膜的选择性较低。在本研究中,我们通过分子模拟和机器学习方法研究了用于 He/H2 分离的金属有机框架(MOF)膜的结构性能关系。通过分子模拟,我们从计算准备实验(CoRE)MOF 数据库中识别出了具有高分离性能的潜在 MOF 膜,并进一步阐明了以扩散为主导的机理。此外,还建立了基于随机森林(RF)的机器学习模型,以确定影响MOF膜He/H2分离性能的关键因素。结果表明,孔极限直径(PLD)和空隙率(φ)分别是决定膜选择性和氦渗透性的最重要物理特征。此外,为验证分子模拟结果,还进行了密度泛函理论(DFT)计算,结果表明孔表面的电负性原子可增强 He/H2 的扩散分离,这对提高膜的 He/H2 选择性至关重要。这项研究为在分子水平上设计和开发用于分离 He/H2 的新型 MOF 膜提供了有益的启示。
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引用次数: 0
Outside Back Cover 封底外侧
Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-22 DOI: 10.1016/S2666-9528(23)00068-7
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引用次数: 0
OFC: Outside Front Cover OFC:封面外侧
Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-22 DOI: 10.1016/S2666-9528(23)00061-4
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引用次数: 0
Propylene epoxidation coupled with furfural oxidation over Pt (II)TPP porphyrin with molecular oxygen 卟啉铂(II)与分子氧的丙烯环氧化反应及糠醛氧化反应
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-18 DOI: 10.1016/j.gce.2024.01.003

The development of green route for preparing propylene oxide (PO) with molecular oxygen is of significance both in academic and industrial. In this work, propylene epoxidation coupled with furfural oxidation catalyzed by platinum meso-tetraphenylporphyrin (Pt (II)TPP) has been developed. Propylene conversion and PO selectivity reached up to 56% and 83%, respectively. Meanwhile, furfural was almost completely converted to furoic acid. Based on operando characterizations and electron paramagnetic resonance (EPR) tests, a mechanism involved high-valent Pt species was proposed. This work is expected to provide a potential application prospects for producing PO and furoic acid simultaneously in chemical industry.

开发用分子氧制备环氧丙烷(PO)的绿色方法在学术界和工业界都具有重要意义。本研究开发了铂介四苯基卟啉(Pt (II)TPP)催化的丙烯环氧化与糠醛氧化反应。丙烯转化率和 PO 选择性分别高达 56% 和 83%。同时,糠醛几乎完全转化为糠酸。根据操作表征和电子顺磁共振(EPR)测试,提出了一种涉及高价铂物种的机理。这项工作有望为化工行业同时生产 PO 和呋喃酸提供潜在的应用前景。
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引用次数: 0
Pool bio-oxidation and fitting analysis of low-grade arsenic-containing refractory gold ore 低品位含砷难熔金矿的矿池生物氧化和拟合分析
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-11 DOI: 10.1016/j.gce.2024.01.001

To overcome the limitations of geography, climate, and ore characteristics on the ore beneficiation process, bio-oxidation studies on low-grade arsenic-bearing refractory gold ore by pool leaching were carried out, as well as process fitting analysis. The gold particles are encapsulated by pyrite and arsenopyrite. After 60 days of bio-oxidation, the oxidation rates of arsenic, sulfur, and gold were 39%∼69%, 24%∼41%, and 49%∼83%, respectively. The inoculated Acidithiobacillus ferrooxidans, Ferroplasma acidiphilum, and Leptospirillum ferrodiazotrophum could all mediate the initial pyrite/arsenopyrite oxidation and the Fe2+ oxidation reaction, but only the former could mediate the subsequent sulfur compound oxidation. When compared to daily bacterial circulation and bacterial replacement every ten days, aeration improved the gold leaching rate by 14%∼22%. The Boltzmann model could fit both the arsenic and sulfur bio-oxidation, with model fit variances greater than 0.98. Based on the experimental and fitting results, the bio-oxidation cycle was determined to be 60 days, and the bio-oxidation mechanisms are summarized. This study has significant practical implications for the rational utilization of gold resources and provides theoretical and practical guidance for similar gold ores.

为了克服地理、气候和矿石特性对选矿工艺的限制,对低品位含砷难选金矿进行了池浸生物氧化研究,并进行了工艺拟合分析。金颗粒被黄铁矿和砷黄铁矿包裹。经过 60 天的生物氧化,砷、硫和金的氧化率分别为 39%∼69%、24%∼41% 和 49%∼83%。接种的铁氧化酸硫杆菌、酸性铁浆菌和铁锈肽杆菌都能介导最初的黄铁矿/砷黄铁矿氧化反应和 Fe2+ 氧化反应,但只有前者能介导随后的硫化合物氧化反应。与每天进行细菌循环和每十天更换一次细菌相比,曝气可使金浸出率提高 14%∼22%。玻尔兹曼模型可以同时拟合砷和硫的生物氧化作用,模型拟合方差大于 0.98。根据实验和拟合结果,确定生物氧化周期为 60 天,并总结了生物氧化机理。该研究对合理利用金资源具有重要的现实意义,并为类似金矿石提供了理论和实践指导。
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引用次数: 0
Eco-friendly synthesis and environmental impact assessment of hierarchical Beta zeolite from kaolinite and recycled mother liquor 利用高岭石和回收母液合成生态友好型分层β沸石及其环境影响评估
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2024-01-10 DOI: 10.1016/j.gce.2024.01.002

The development of sustainable techniques to produce high-performance zeolite is essential to achieve green production in industry. Herein, we report an eco-friendly route to synthesizing hierarchical Beta zeolite from kaolinite and recycled mother liquor. The results reveal that the unutilized species (such as silicon species and Na+) in mother liquor stayed in a stable concentration during eleven recycled experiments. Moreover, the synthesized Beta zeolites still have comparable physicochemical properties and catalytic performance in the esterification of levulinic acid with ethanol over the initial zeolite although eleven recycled experiments. Life cycle assessment exhibits that the synthesis of Beta zeolite with recycled mother liquor can reduce global warming potential by 23% and resource depletion-water use by 36% compared to that without recycled mother liquor. This quantitatively demonstrates that the approach proposed in this work is really a sustainable one, extremely increasing the utilization efficiency of raw materials and decreasing the environmental burden.

开发生产高性能沸石的可持续技术对于实现工业领域的绿色生产至关重要。在此,我们报告了一种利用高岭石和回收母液合成分层 Beta 沸石的生态友好型路线。结果表明,在 11 次循环实验中,母液中未被利用的物质(如硅和 Na+)保持了稳定的浓度。此外,在乙醇酯化乙酰丙酸的过程中,合成的 Beta 沸石与初始沸石相比,在 11 次循环实验中仍具有相当的理化性质和催化性能。生命周期评估表明,与不使用回收母液相比,使用回收母液合成 Beta 沸石可减少 23% 的全球升温潜能值和 36% 的资源损耗-用水量。这从数量上表明,这项工作提出的方法确实是一种可持续的方法,它极大地提高了原材料的利用效率,减轻了环境负担。
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引用次数: 0
Advancements in adsorption and photodegradation technologies for Rhodamine B dye wastewater treatment: fundamentals, applications, and future directions 用于罗丹明 B 染料废水处理的吸附和光降解技术的进展:基本原理、应用和未来方向
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-12-30 DOI: 10.1016/j.gce.2023.12.004

Organic dye pollutants present in wastewater pose a significant global challenge. Among pollutants, the synthetic dye Rhodamine B (RB) stands out due to its non-biodegradable nature and associated neurotoxic, carcinogenic, and respiratory irritant properties. Extensive research has been conducted on the efficacy of adsorption and photodegradation techniques for the removal of RB from wastewater. While adsorption and advanced oxidation processes (AOPs) have gained considerable attention for their effectiveness in recent years, the underlying behaviors and mechanisms of these technologies remain incompletely understood. Therefore, a comprehensive summary of recent research progress in this domain is imperative to clarify the basics and present the up-to-date achievements.

This review provides an in-depth exploration of the fundamentals, advancements, and future trajectories of RB wastewater treatment technologies, mainly encompassing adsorption and photodegradation. This work starts with a general introduction of outlining the sources, toxicity, and diverse applicable removal strategies. Subsequently, it thoroughly examines crucial techniques within non-photochemical, photochemical, and adsorption technologies, such as UV light assisted AOP, catalyst assisted AOP, ozonation, Fenton system, electrochemical AOP, and adsorption technology. The primary objective is to furnish a broad overview of these techniques, elucidating their effectiveness, limitations, and applicability. Following this, the review encapsulates state-of-the-art computational simulations pertaining to RB adsorption and interactions with clays and other adsorbents. Lastly, it delves into column adsorption of RB dye, and elucidates various influencing factors, including bed height, feed concentration, pollutant (RB) feeding or flow rate, and column regeneration. This panoramic review aims to provide valuable insights into suitable techniques, research gaps, and the applicability of non-photochemical, photochemical, and adsorption technologies in the treatment of wastewater containing RB dye.

废水中的有机染料污染物是一项重大的全球性挑战。在各种污染物中,合成染料罗丹明 B(RB)因其不可生物降解性以及相关的神经毒性、致癌性和呼吸道刺激性而脱颖而出。人们对吸附和光降解技术去除废水中罗丹明 B 的功效进行了广泛的研究。虽然近年来吸附和高级氧化工艺(AOPs)因其有效性而备受关注,但人们对这些技术的基本行为和机理仍不甚了解。本综述深入探讨了主要包括吸附和光降解技术在内的 RB 废水处理技术的基本原理、进展和未来轨迹。本研究首先概述了废水的来源、毒性和各种适用的去除策略。随后,它深入研究了非光化学、光化学和吸附技术中的关键技术,如紫外光辅助 AOP、催化剂辅助 AOP、臭氧处理、芬顿系统、电化学 AOP 和吸附技术。主要目的是概述这些技术,阐明其有效性、局限性和适用性。随后,本综述囊括了有关 RB 吸附以及与粘土和其他吸附剂相互作用的最新计算模拟。最后,它深入探讨了 RB 染料的柱吸附,并阐明了各种影响因素,包括床层高度、进料浓度、污染物(RB)进料或流速以及柱再生。本综述旨在就处理含 RB 染料废水的适用技术、研究空白以及非光化学、光化学和吸附技术的适用性提供有价值的见解。
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引用次数: 0
The role of hydrogen bonding in solubilizing camptothecin in hydrophilic and hydrophobic ionic liquids 氢键在亲水和疏水离子液体中增溶喜树碱的作用
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-12-27 DOI: 10.1016/j.gce.2023.12.002
Xiaotong Zhu , Liwen Mu , Jiahua Zhu , Xiaohua Lu , Yuanhui Ji

Utilizing ionic liquid (IL)-water mixtures as selective extraction solvents for raw materials from natural sources represents an efficacious approach; however, elucidating the underlying mechanisms inherent in various types of IL-aqueous solutions continues to pose a significant challenge. In this study, molecular dynamics simulations and density functional theory calculations are employed to illuminate the influence of the functional anion within ILs and the water content on the solvation mechanism and phase separation phenomena observed during the extraction of camptothecin (CPT) using aqueous IL solutions. The simulation results show that the anions in ILs preferentially dissolve CPT through hydrogen bonding at low water concentrations. As the water concentration increases, the hydrophobic IL binds more tightly to CPT, enabling the water to self-aggregate. The anions in hydrophilic IL form hydrogen bonds with water instead, further enhancing the dissolution of CPT. This work reveals the mechanism of phase separation and solvation of different types of IL aqueous solutions, which is helpful in developing new drug extraction and purification technologies.

利用离子液体(IL)-水混合物作为从天然资源中选择性萃取原材料的溶剂是一种有效的方法;然而,阐明各种类型的离子液体-水溶液的内在机理仍然是一项重大挑战。本研究通过分子动力学模拟和密度泛函理论计算,阐明了在使用 IL 水溶液萃取喜树碱(CPT)的过程中,IL 中的功能阴离子和水含量对溶解机制和相分离现象的影响。模拟结果表明,在水浓度较低时,IL 中的阴离子通过氢键优先溶解 CPT。随着水浓度的增加,疏水的 IL 与 CPT 结合得更紧密,使水能够自我聚集。亲水性 IL 中的阴离子反而与水形成氢键,进一步提高了 CPT 的溶解度。这项研究揭示了不同类型 IL 水溶液的相分离和溶解机理,有助于开发新的药物提取和纯化技术。
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引用次数: 0
Elucidating solvent effects on the stability of phenoxyl radicals in monohydric alcohols via electron paramagnetic resonance 通过电子顺磁共振阐明溶剂对一元醇中苯氧自由基稳定性的影响
IF 9.1 Q1 ENGINEERING, CHEMICAL Pub Date : 2023-12-26 DOI: 10.1016/j.gce.2023.12.003

Research on solvent effects is an important and long-standing topic, but there still is some room, especially for the special solvent effect of fluoroalcohols. In this work, we investigated the stability of phenoxyl radical in monohydric alcohol solvents through in-situ electron paramagnetic resonance detections. The decay behavior of phenoxyl radical showed a reasonable relationship with the mesoscopic structure of alcohols, characterized by small- and wide-angle X-ray scattering. Moreover, the distinct solvent effects of fluoroalcohols were emphasized, and the significant influence of van der Waals distance in the solvents was suggested. Overall, the stability of phenoxyl radical in alcohols was quantified and correlated with the solvent structures. We believe that the established method for stability study on radicals will encourage solvent effect studies on various organic reactions, and the proposed solvent effects in fluoroalcohols may inspire the development of green solvents in both industrial conversions and organic synthesis.

溶剂效应研究是一个重要而长期的课题,但仍有一定的研究空间,尤其是对氟醇的特殊溶剂效应的研究。在这项工作中,我们通过原位电子顺磁共振检测研究了苯氧自由基在一元醇溶剂中的稳定性。根据小角和广角 X 射线散射的特征,苯氧自由基的衰减行为与醇的中观结构有合理的关系。此外,研究还强调了氟醇的独特溶剂效应,并认为溶剂中的范德华距离具有重要影响。总之,苯氧自由基在醇中的稳定性得到了量化,并与溶剂结构相关联。我们相信,所建立的自由基稳定性研究方法将鼓励对各种有机反应进行溶剂效应研究,而所提出的氟醇中的溶剂效应可能会对工业转化和有机合成中绿色溶剂的开发有所启发。
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引用次数: 0
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Green Chemical Engineering
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