首页 > 最新文献

纳米科学与工程(英文)最新文献

英文 中文
Interaction between Kaolin and Urea in Organoclay and Its Impact on Removing Methylene Blue from Aqueous Solution 有机粘土中高岭土与尿素的相互作用及其对去除水溶液中亚甲基蓝的影响
Pub Date : 2015-02-11 DOI: 10.4236/WJNSE.2015.51001
Sabri M. Husssein, O. Shihab, S. S. Ibrahim, N. M. Ahmed
Interaction between kaolin (particle size 53 and 106 μm) and urea was studied by infrared spectroscopy and powder X-ray diffraction. Interaction was found to be dependent on the particle size of kaolin raw material. Nature of interaction achieved through the formation of hydrogen bonds between urea and both AlOH and Si-O surface of kaolinite. Effect of temperature on equilibrium adsorption of methylene blue (MB) from aqueous solution using kaolin also studied, the results were analyzed by Langmuir and frendlich isotherms. Thermodynamic parameters such as ΔG, ΔH and ΔS were calculated. Results suggested that the MB adsorption on kaolin was spontaneous and exothermic process.
采用红外光谱和粉末x射线衍射研究了高岭土(粒径53 ~ 106 μm)与尿素的相互作用。发现相互作用依赖于高岭土原料的粒度。通过尿素与高岭石表面AlOH和Si-O形成氢键实现相互作用的性质。研究了温度对高岭土对亚甲基蓝(MB)平衡吸附的影响,并用Langmuir等温线和frendlich等温线对结果进行了分析。计算了ΔG、ΔH、ΔS等热力学参数。结果表明,MB在高岭土上的吸附是自发的放热过程。
{"title":"Interaction between Kaolin and Urea in Organoclay and Its Impact on Removing Methylene Blue from Aqueous Solution","authors":"Sabri M. Husssein, O. Shihab, S. S. Ibrahim, N. M. Ahmed","doi":"10.4236/WJNSE.2015.51001","DOIUrl":"https://doi.org/10.4236/WJNSE.2015.51001","url":null,"abstract":"Interaction between kaolin (particle size 53 and 106 μm) and urea was studied by infrared spectroscopy and powder X-ray diffraction. Interaction was found to be dependent on the particle size of kaolin raw material. Nature of interaction achieved through the formation of hydrogen bonds between urea and both AlOH and Si-O surface of kaolinite. Effect of temperature on equilibrium adsorption of methylene blue (MB) from aqueous solution using kaolin also studied, the results were analyzed by Langmuir and frendlich isotherms. Thermodynamic parameters such as ΔG, ΔH and ΔS were calculated. Results suggested that the MB adsorption on kaolin was spontaneous and exothermic process.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"176 2 1","pages":"1-9"},"PeriodicalIF":0.0,"publicationDate":"2015-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878966","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Controlling Diameter, Length and Characterization of ZnO Nanorods by Simple Hydrothermal Method for Solar Cells 太阳能电池用简单水热法控制ZnO纳米棒的直径、长度及表征
Pub Date : 2015-02-11 DOI: 10.4236/WJNSE.2015.51005
Ahmed H. Kurda, Y. M. Hassan, N. M. Ahmed
Zinc oxide (ZnO) nanorods have been synthesized by solution processing hydrothermal method in low temperature using the spin coating technique. Zinc acetate dehydrate, Zinc nitrate hexahydrate and hexamethylenetetramine were used as a starting material. The ZnO seed layer was first deposited by spin coated of ethanol zinc acetate dehydrate solution on a glass substrate. ZnO nanorods were grown on the ZnO seed layer from zinc nitrate hexahydrate and hexamethylene-tetramine solution, and their diameters, lengths were controlled by precursor concentration and development time. From UV-Visible spectrometry the optical band gap energy of ZnO nanorods was calculated to be 3.3 eV. The results of X-Ray Diffraction (XRD) showed the highly oriented nature of ZnO nanorods the hardest (002) peak reflects that c-axis elongated nanorods are oriented normal to the glass substrate. The Field Emission Scanning Electron Microscope (FESEM) was employed to measure both of average diameter of ZnO nanorods, Energy Dispersive X-Ray (EDX) is used to identify the elemental present and to determine the element composition in the samples.
采用自旋包覆技术,在低温条件下采用溶液法水热法制备了氧化锌纳米棒。以脱水乙酸锌、六水硝酸锌和六亚甲基四胺为原料。首先在玻璃基板上自旋包覆乙醇醋酸锌脱水溶液制备ZnO种子层。采用六水硝酸锌和六亚甲基四胺溶液在ZnO种子层上生长ZnO纳米棒,其直径和长度受前驱体浓度和发育时间的控制。紫外可见光谱法计算出ZnO纳米棒的光学带隙能为3.3 eV。x射线衍射(XRD)结果表明ZnO纳米棒具有高度取向性,其中最硬的(002)峰反映了c轴细长纳米棒垂直于玻璃基板取向。采用场发射扫描电镜(FESEM)测量了ZnO纳米棒的平均直径,用能量色散x射线(EDX)鉴定了样品中存在的元素并确定了元素组成。
{"title":"Controlling Diameter, Length and Characterization of ZnO Nanorods by Simple Hydrothermal Method for Solar Cells","authors":"Ahmed H. Kurda, Y. M. Hassan, N. M. Ahmed","doi":"10.4236/WJNSE.2015.51005","DOIUrl":"https://doi.org/10.4236/WJNSE.2015.51005","url":null,"abstract":"Zinc oxide (ZnO) nanorods have been synthesized by solution processing hydrothermal method in low temperature using the spin coating technique. Zinc acetate dehydrate, Zinc nitrate hexahydrate and hexamethylenetetramine were used as a starting material. The ZnO seed layer was first deposited by spin coated of ethanol zinc acetate dehydrate solution on a glass substrate. ZnO nanorods were grown on the ZnO seed layer from zinc nitrate hexahydrate and hexamethylene-tetramine solution, and their diameters, lengths were controlled by precursor concentration and development time. From UV-Visible spectrometry the optical band gap energy of ZnO nanorods was calculated to be 3.3 eV. The results of X-Ray Diffraction (XRD) showed the highly oriented nature of ZnO nanorods the hardest (002) peak reflects that c-axis elongated nanorods are oriented normal to the glass substrate. The Field Emission Scanning Electron Microscope (FESEM) was employed to measure both of average diameter of ZnO nanorods, Energy Dispersive X-Ray (EDX) is used to identify the elemental present and to determine the element composition in the samples.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"05 1","pages":"34-40"},"PeriodicalIF":0.0,"publicationDate":"2015-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70879052","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 32
Eco-Friendly Production of Silver Nanoparticles from Peel of Tangerine for Degradation of Dye 以柑桔皮为原料制备纳米银降解染料的研究
Pub Date : 2015-02-11 DOI: 10.4236/WJNSE.2015.51002
Eman Alzahrani
Green chemistry methods for production of nanoparticles have many advantages, such as ease of use, which makes the methods desirable and economically viable. The aim of the present work was to green synthesise silver nanoparticles (SNPs) using aqueous tangerine peel extract in different ratios (2:1, 1:1, 1:2). The formed SNPs were characterised using ultraviolet-visible (UV-Vis) spectrophotometry, and transmission electron microscopy (TEM). The UV-Vis spectra showed that the highest absorbance was observed when the ratio of peel tangerine extract to silver nitrate solution was 1:2. The transmission electron micrographs showed the formation of poly dispersed nanoparticles. It was found that the average diameter of the nanoparticles was 30.29 ± 5.1 nm, 16.68 ± 5.7 nm, and 25.85 ± 8.4 nm, using a tangerine peel solution and silver nitrate solution ratio of 2:1, 1:1, and 1:2, respectively. The formed SNPs were evaluated as catalysts for methyl orange dye degradation, and the results confirmed that SNPs can speed up the degradation of the dye.
绿色化学方法生产纳米颗粒具有许多优点,如易于使用,这使得该方法是理想的和经济上可行的。本研究的目的是利用不同比例(2:1,1:1,1:2)的陈皮水提物绿色合成纳米银(SNPs)。形成的snp用紫外可见分光光度法和透射电子显微镜(TEM)进行了表征。紫外可见光谱表明,当陈皮提取物与硝酸银溶液的比例为1:2时,其吸光度最高。透射电子显微图显示了聚分散纳米颗粒的形成。实验发现,当陈皮溶液与硝酸银溶液的比例分别为2:1、1:1和1:2时,纳米颗粒的平均直径分别为30.29±5.1 nm、16.68±5.7 nm和25.85±8.4 nm。对形成的SNPs作为甲基橙染料降解的催化剂进行了评价,结果证实SNPs可以加速染料的降解。
{"title":"Eco-Friendly Production of Silver Nanoparticles from Peel of Tangerine for Degradation of Dye","authors":"Eman Alzahrani","doi":"10.4236/WJNSE.2015.51002","DOIUrl":"https://doi.org/10.4236/WJNSE.2015.51002","url":null,"abstract":"Green chemistry methods for production of nanoparticles have many advantages, such as ease of use, which makes the methods desirable and economically viable. The aim of the present work was to green synthesise silver nanoparticles (SNPs) using aqueous tangerine peel extract in different ratios (2:1, 1:1, 1:2). The formed SNPs were characterised using ultraviolet-visible (UV-Vis) spectrophotometry, and transmission electron microscopy (TEM). The UV-Vis spectra showed that the highest absorbance was observed when the ratio of peel tangerine extract to silver nitrate solution was 1:2. The transmission electron micrographs showed the formation of poly dispersed nanoparticles. It was found that the average diameter of the nanoparticles was 30.29 ± 5.1 nm, 16.68 ± 5.7 nm, and 25.85 ± 8.4 nm, using a tangerine peel solution and silver nitrate solution ratio of 2:1, 1:1, and 1:2, respectively. The formed SNPs were evaluated as catalysts for methyl orange dye degradation, and the results confirmed that SNPs can speed up the degradation of the dye.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"5 1","pages":"10-16"},"PeriodicalIF":0.0,"publicationDate":"2015-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 21
The Casimir Topological Effect and a Proposal for a Casimir-Dark Energy Nano Reactor * 卡西米尔拓扑效应和卡西米尔-暗能量纳米反应堆的构想*
Pub Date : 2015-02-11 DOI: 10.4236/WJNSE.2015.51004
M. Naschie
A basically topological interpretation of the Casimir effect is given as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so called missing dark energy density of the cosmos. We start with a general outline of the theoretical principle and basic design concepts of a proposed Casimir dark energy nano reactor. In a nutshell the theory and consequently the actual design depends crucially upon the equivalence between the dark energy density of the cosmos and the faint local Casimir effect produced by two sides boundary condition quantum waves. This Casimir effect is then colossally amplified as a one sided quantum wave pushing from the inside on the one sided M?bius-like boundary with nothing balancing it from the non-existent outside. In view of the present theory, this one sided M?bius-like boundary of the holographic boundary of the universe is essentially what leads to the observed accelerated expansion of the cosmos. Thus in principle we will restructure the local topology of space using material nanoscience technology to create an artificial local high dimensionality with a Dvoretzky theorem like volume measure concentration. Needless to say the entire design is based completely on the theory of quantum wave dark energy proposed by the present author. The quintessence of the present theory is easily explained as the intrinsic Casimir topological energy where produced from the zero set of the quantum particle when we extract the empty set quantum wave from it and find by restructuring space via plates similar to that of the classical Casimir experiments but with some modification.
卡西米尔效应的基本拓扑解释是作为量子-康托里亚微观时空的几何拓扑结构的自然固有性质给出的。这一新的解释补充了先前的传统解释,即真空涨落或施温格源,并将卡西米尔能量与所谓的宇宙缺失暗能量密度联系起来。我们首先概述了一个拟议的卡西米尔暗能量纳米反应堆的理论原理和基本设计概念。简而言之,理论和实际设计关键取决于宇宙暗能量密度和两侧边界条件量子波产生的微弱局部卡西米尔效应之间的等效性。这种卡西米尔效应被极大地放大为一个单面量子波从内部推动单面M?像bius一样的边界,没有任何东西与不存在的外部平衡。鉴于目前的理论,这一片面的M?宇宙全息边界的比乌斯边界本质上是导致观测到的宇宙加速膨胀的原因。因此,原则上,我们将利用材料纳米科学技术重构空间的局部拓扑结构,利用类似于体积测度浓度的Dvoretzky定理创建人工局部高维空间。不用说,整个设计完全基于本文作者提出的量子波暗能量理论。本理论的精髓很容易解释为,当我们从量子粒子的零集中提取空集量子波,并通过与经典卡西米尔实验类似但做了一些修改的板重构空间时,从量子粒子的零集产生了卡西米尔拓扑能量。
{"title":"The Casimir Topological Effect and a Proposal for a Casimir-Dark Energy Nano Reactor *","authors":"M. Naschie","doi":"10.4236/WJNSE.2015.51004","DOIUrl":"https://doi.org/10.4236/WJNSE.2015.51004","url":null,"abstract":"A basically topological interpretation of the Casimir effect is given as a natural intrinsic property of the geometrical topological structure of the quantum-Cantorian micro spacetime. This new interpretation compliments the earlier conventional interpretation as vacuum fluctuation or as a Schwinger source and links the Casimir energy to the so called missing dark energy density of the cosmos. We start with a general outline of the theoretical principle and basic design concepts of a proposed Casimir dark energy nano reactor. In a nutshell the theory and consequently the actual design depends crucially upon the equivalence between the dark energy density of the cosmos and the faint local Casimir effect produced by two sides boundary condition quantum waves. This Casimir effect is then colossally amplified as a one sided quantum wave pushing from the inside on the one sided M?bius-like boundary with nothing balancing it from the non-existent outside. In view of the present theory, this one sided M?bius-like boundary of the holographic boundary of the universe is essentially what leads to the observed accelerated expansion of the cosmos. Thus in principle we will restructure the local topology of space using material nanoscience technology to create an artificial local high dimensionality with a Dvoretzky theorem like volume measure concentration. Needless to say the entire design is based completely on the theory of quantum wave dark energy proposed by the present author. The quintessence of the present theory is easily explained as the intrinsic Casimir topological energy where produced from the zero set of the quantum particle when we extract the empty set quantum wave from it and find by restructuring space via plates similar to that of the classical Casimir experiments but with some modification.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"36 1","pages":"26-33"},"PeriodicalIF":0.0,"publicationDate":"2015-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 20
Thermally Agitated Self Assembled Carbon Nanotubes and the Scenario of Extrinsic Defects 热搅拌自组装碳纳米管及其外部缺陷的研究
Pub Date : 2015-02-11 DOI: 10.4236/WJNSE.2015.51003
Chernet Amente, K. Dharamvir
Employing the arc discharge method we prepared carbon nanotubes, CNTs, in open air deionized water. Their morphology was studied varying the annealing temperature and characterizing by Raman Spectroscopy, Transmission Electron Microscopy (TEM), X-Ray Diffractogram (XRD) and Energy Dispersion X-Ray (EDX). According to the study, the CNTs are found self-assembled where the graphene sheets and/or defects are observed sort out themselves with enhancement of temperature.
采用电弧放电法在露天去离子水中制备碳纳米管(CNTs)。采用拉曼光谱、透射电子显微镜(TEM)、x射线衍射仪(XRD)和能量色散x射线(EDX)对不同退火温度下材料的形貌进行了表征。根据这项研究,碳纳米管是自组装的,石墨烯片和/或缺陷随着温度的升高而自我整理。
{"title":"Thermally Agitated Self Assembled Carbon Nanotubes and the Scenario of Extrinsic Defects","authors":"Chernet Amente, K. Dharamvir","doi":"10.4236/WJNSE.2015.51003","DOIUrl":"https://doi.org/10.4236/WJNSE.2015.51003","url":null,"abstract":"Employing the arc discharge method we prepared carbon nanotubes, CNTs, in open air deionized water. Their morphology was studied varying the annealing temperature and characterizing by Raman Spectroscopy, Transmission Electron Microscopy (TEM), X-Ray Diffractogram (XRD) and Energy Dispersion X-Ray (EDX). According to the study, the CNTs are found self-assembled where the graphene sheets and/or defects are observed sort out themselves with enhancement of temperature.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"5 1","pages":"17-25"},"PeriodicalIF":0.0,"publicationDate":"2015-02-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Research Advances in Photocatalysis of Inorganic Hollow Spheres 无机空心球光催化研究进展
Pub Date : 2014-11-19 DOI: 10.4236/WJNSE.2014.44015
Ting Tian, Jing Hu, Zuobing Xiao
Inorganic hollow spheres have shown their superiority in photocatalytic area due to the large specific surface area, controllable structure and their own special optical, electrical, magnetic properties. According to the classification of inorganic hollow spheres as photocatalysts, recent research progress and application status have been summarized in this paper. At last, the future developments of inorganic hollow spheres in photocatalytic field have been discussed.
无机空心球由于其比表面积大、结构可控以及自身特殊的光、电、磁性能,在光催化领域显示出其优势。根据无机空心球光催化剂的分类,综述了近年来无机空心球光催化剂的研究进展和应用现状。最后,对无机空心球在光催化领域的应用前景进行了展望。
{"title":"Research Advances in Photocatalysis of Inorganic Hollow Spheres","authors":"Ting Tian, Jing Hu, Zuobing Xiao","doi":"10.4236/WJNSE.2014.44015","DOIUrl":"https://doi.org/10.4236/WJNSE.2014.44015","url":null,"abstract":"Inorganic hollow spheres have shown their superiority in photocatalytic area due to the large specific surface area, controllable structure and their own special optical, electrical, magnetic properties. According to the classification of inorganic hollow spheres as photocatalysts, recent research progress and application status have been summarized in this paper. At last, the future developments of inorganic hollow spheres in photocatalytic field have been discussed.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"04 1","pages":"111-125"},"PeriodicalIF":0.0,"publicationDate":"2014-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
High Efficiency SiC Terahertz Source in Mixed Tunnelling Avalanche Transit Time Mode 混合隧道雪崩传输时间模式下的高效SiC太赫兹源
Pub Date : 2014-11-19 DOI: 10.4236/WJNSE.2014.44018
P. Panda, S. Padhi, G. Dash
High frequency properties of 4H-SiC double drift region (DDR) Mixed Tunnelling Avalanche Transit Time (MITATT) diodes are studied through computer simulation method. It is interesting to observe that the efficiency of SiC (flat) DDR MITATT diode (16%) is more than 4 times that of Si (flat) DDR MITATT diode (3.59%). In addition, a power output of more than 15 times from the SiC MITATT diode compared to the Si MITATT diode is commendable. A reduced noise measure of 17.71 dB from a low-high-low (lo-hi-lo) structure compared to that of 21.5 dB from a flat structure of SiC is indicative of the favourable effect of tunnelling current on the MITATT diode performance.
采用计算机仿真方法研究了4H-SiC双漂移区(DDR)混合隧道雪崩穿越时间(MITATT)二极管的高频特性。有趣的是,SiC(平板)DDR MITATT二极管的效率(16%)是Si(平板)DDR MITATT二极管(3.59%)的4倍以上。此外,与硅MITATT二极管相比,SiC MITATT二极管的功率输出超过15倍是值得称赞的。低-高-低(low-hi -lo)结构的噪声测量值为17.71 dB,而SiC平坦结构的噪声测量值为21.5 dB,这表明隧道电流对MITATT二极管性能的有利影响。
{"title":"High Efficiency SiC Terahertz Source in Mixed Tunnelling Avalanche Transit Time Mode","authors":"P. Panda, S. Padhi, G. Dash","doi":"10.4236/WJNSE.2014.44018","DOIUrl":"https://doi.org/10.4236/WJNSE.2014.44018","url":null,"abstract":"High frequency properties of 4H-SiC double drift region (DDR) Mixed Tunnelling Avalanche Transit Time (MITATT) diodes are studied through computer simulation method. It is interesting to observe that the efficiency of SiC (flat) DDR MITATT diode (16%) is more than 4 times that of Si (flat) DDR MITATT diode (3.59%). In addition, a power output of more than 15 times from the SiC MITATT diode compared to the Si MITATT diode is commendable. A reduced noise measure of 17.71 dB from a low-high-low (lo-hi-lo) structure compared to that of 21.5 dB from a flat structure of SiC is indicative of the favourable effect of tunnelling current on the MITATT diode performance.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"04 1","pages":"143-150"},"PeriodicalIF":0.0,"publicationDate":"2014-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Unusual Spectral Change Due to a Cyanine Dye Adsorbed on an Inorganic Layered Material upon Photoirradiation 无机层状材料在光照射下吸附菁染料引起的不寻常光谱变化
Pub Date : 2014-11-19 DOI: 10.4236/WJNSE.2014.44016
M. Ishihara, Ryuji Hirase, H. Yoshioka
Photoinduced spectral change can be utilized for various optical devices. The photoinduced spectral change due to an organic dye was demonstrated for the organic-inorganic hybrid film without the aid of photochromism with a simple preparation method for the first time. By the hybridization of a cyanine dye of 2-[5-(1,3-dihydro-3,3-dimethyl-1-octadecyl-2H-indol-2-ylidene)-1,3-pentadienyl]-3,3-dimethyl-1-octadecyl-3H-indolium perchlorate (NK3175) with an inorganic layered material of cation-exchangeable clay, smectite (SWN), a spectral change attributed to NK3175 was generated upon the irradiation of UV light. This result might serve as useful information on the methodology to produce optically controlled function for photoresponsive systems. Furthermore, the hybrid film of SWN and NK3175 was characterized by the use of XRD and FT-IR measurements. NK3175 molecules adsorbed onto external surfaces of SWN were confined by oriented SWN. It was suggested that the enhanced intermolecular interaction between NK3175 molecules caused by the hybridization with SWN resulted in the change of the aggregation state of NK3175 upon the UV light irradiation, which accounts for the spectral change of NK3175.
光致光谱变化可用于各种光学器件。首次用一种简单的制备方法证明了有机-无机杂化膜在没有光致变色的情况下,由于有机染料的光致光谱变化。将2-[5-(1,3-二氢-3,3-二甲基-1-十八烷基- 2h -吲哚-2-乙基)-1,3-戊二烯基]-3,3-二甲基-1-十八烷基- 3h -高氯酸吲哚(NK3175)与无机层状阳离子交换粘土蒙脱石(SWN)杂交,在紫外光照射下产生了光谱变化。这一结果可以为光响应系统产生光控函数的方法提供有用的信息。利用XRD和FT-IR对SWN与NK3175的杂化膜进行了表征。NK3175分子吸附在SWN的外表面,受到定向SWN的约束。推测NK3175与SWN杂交后分子间相互作用增强,导致NK3175在紫外光照射下聚集态发生变化,这是NK3175光谱变化的原因。
{"title":"Unusual Spectral Change Due to a Cyanine Dye Adsorbed on an Inorganic Layered Material upon Photoirradiation","authors":"M. Ishihara, Ryuji Hirase, H. Yoshioka","doi":"10.4236/WJNSE.2014.44016","DOIUrl":"https://doi.org/10.4236/WJNSE.2014.44016","url":null,"abstract":"Photoinduced spectral change can be utilized for various optical devices. The photoinduced spectral change due to an organic dye was demonstrated for the organic-inorganic hybrid film without the aid of photochromism with a simple preparation method for the first time. By the hybridization of a cyanine dye of 2-[5-(1,3-dihydro-3,3-dimethyl-1-octadecyl-2H-indol-2-ylidene)-1,3-pentadienyl]-3,3-dimethyl-1-octadecyl-3H-indolium perchlorate (NK3175) with an inorganic layered material of cation-exchangeable clay, smectite (SWN), a spectral change attributed to NK3175 was generated upon the irradiation of UV light. This result might serve as useful information on the methodology to produce optically controlled function for photoresponsive systems. Furthermore, the hybrid film of SWN and NK3175 was characterized by the use of XRD and FT-IR measurements. NK3175 molecules adsorbed onto external surfaces of SWN were confined by oriented SWN. It was suggested that the enhanced intermolecular interaction between NK3175 molecules caused by the hybridization with SWN resulted in the change of the aggregation state of NK3175 upon the UV light irradiation, which accounts for the spectral change of NK3175.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"04 1","pages":"126-133"},"PeriodicalIF":0.0,"publicationDate":"2014-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.4236/WJNSE.2014.44016","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Neural Network Based on SET Inverter Structures: Neuro-Inspired Memory 基于SET逆变器结构的神经网络:神经启发记忆
Pub Date : 2014-11-19 DOI: 10.4236/WJNSE.2014.44017
B. Hafsi, Rabii Elmissaoui, A. Kalboussi
This paper presents a basic block for building large-scale single-electron neural networks. This macro block is completely composed of SET inverter circuits. We present and discuss the basic parts of this device. The full design and simulation results were done using MATLAB and SIMON, which are a single-electron tunnel device and circuit simulator based on a Monte Carlo method. Special measures had to be taken in order to simulate this circuit correctly in SIMON and compare results with those of SPICE simulation done before. Moreover, we study part of the network as a memory cell with the idea of combining the extremely low-power properties of the SET and the compact design.
本文提出了构建大规模单电子神经网络的基本模块。这个宏模块完全由SET逆变电路组成。我们介绍并讨论了该装置的基本部件。利用MATLAB和SIMON对基于蒙特卡罗方法的单电子隧道器件和电路模拟器进行了完整的设计和仿真。为了在SIMON中正确地模拟该电路,并与之前的SPICE模拟结果进行比较,必须采取特殊措施。此外,我们研究了网络的一部分作为存储单元,并结合了SET的极低功耗特性和紧凑的设计。
{"title":"Neural Network Based on SET Inverter Structures: Neuro-Inspired Memory","authors":"B. Hafsi, Rabii Elmissaoui, A. Kalboussi","doi":"10.4236/WJNSE.2014.44017","DOIUrl":"https://doi.org/10.4236/WJNSE.2014.44017","url":null,"abstract":"This paper presents a basic block for building large-scale single-electron neural networks. This macro block is completely composed of SET inverter circuits. We present and discuss the basic parts of this device. The full design and simulation results were done using MATLAB and SIMON, which are a single-electron tunnel device and circuit simulator based on a Monte Carlo method. Special measures had to be taken in order to simulate this circuit correctly in SIMON and compare results with those of SPICE simulation done before. Moreover, we study part of the network as a memory cell with the idea of combining the extremely low-power properties of the SET and the compact design.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"4 1","pages":"134-142"},"PeriodicalIF":0.0,"publicationDate":"2014-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.4236/WJNSE.2014.44017","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Carbon Rod—Specimens Distance on the Structural and Electrical Properties of Carbon Nanotube 碳棒试样距离对碳纳米管结构和电性能的影响
Pub Date : 2014-09-05 DOI: 10.4236/WJNSE.2014.43014
M. Uonis, B. M. Mustafa, A. Ezzat
The research studies the effect of the distance between the sample and the plasma sputtering source on the properties of the junction (silicon wafer-carbon nanotubes). The silicon wafer is fixed at (near, medium and far distances from the plasma source which is in the form of high purity graphite rod heated electrically). For the three cases, thickness of the sample is constant (20 nm). The samples were studied by scanning electron (SEM) and atomic force microscopes (AFM), X-ray and Raman spectra. For optimum distances the carbon layer is in the form of multi wall carbon nanotube (MWCNT). SEM images shows no formation of CNT on the Si wafer for near distance, which is consistent with the AFM images, X-ray and Raman spectrograms and no existence of characteristics (002) peaks whereas it appears for medium and longer distances, and by experience the optimum distance was found. This means that at closer distance high energy and high intensity plasma particles prevent the formation of CNT. This effect decreases with increasing distance of substrate from the graphite rod.
研究了样品与等离子溅射源之间的距离对硅-碳纳米管结性能的影响。将硅片固定在(近、中、远)距离电加热的高纯度石墨棒形式的等离子体源处。对于这三种情况,样品的厚度是恒定的(20 nm)。采用扫描电子显微镜(SEM)、原子力显微镜(AFM)、x射线和拉曼光谱对样品进行了研究。对于最佳距离,碳层以多壁碳纳米管(MWCNT)的形式存在。SEM图像显示近距离未形成碳纳米管,这与AFM图像,x射线和拉曼光谱图一致,并且不存在特征峰(002),而在中远距离出现,并根据经验找到了最佳距离。这意味着在较近的距离,高能和高强度等离子体粒子阻止碳纳米管的形成。这种效应随着衬底与石墨棒距离的增加而减小。
{"title":"The Effect of Carbon Rod—Specimens Distance on the Structural and Electrical Properties of Carbon Nanotube","authors":"M. Uonis, B. M. Mustafa, A. Ezzat","doi":"10.4236/WJNSE.2014.43014","DOIUrl":"https://doi.org/10.4236/WJNSE.2014.43014","url":null,"abstract":"The research studies the effect of the distance between the sample and the plasma sputtering source on the properties of the junction (silicon wafer-carbon nanotubes). The silicon wafer is fixed at (near, medium and far distances from the plasma source which is in the form of high purity graphite rod heated electrically). For the three cases, thickness of the sample is constant (20 nm). The samples were studied by scanning electron (SEM) and atomic force microscopes (AFM), X-ray and Raman spectra. For optimum distances the carbon layer is in the form of multi wall carbon nanotube (MWCNT). SEM images shows no formation of CNT on the Si wafer for near distance, which is consistent with the AFM images, X-ray and Raman spectrograms and no existence of characteristics (002) peaks whereas it appears for medium and longer distances, and by experience the optimum distance was found. This means that at closer distance high energy and high intensity plasma particles prevent the formation of CNT. This effect decreases with increasing distance of substrate from the graphite rod.","PeriodicalId":66816,"journal":{"name":"纳米科学与工程(英文)","volume":"04 1","pages":"105-110"},"PeriodicalIF":0.0,"publicationDate":"2014-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"70878689","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
期刊
纳米科学与工程(英文)
全部 Acc. Chem. Res. ACS Applied Bio Materials ACS Appl. Electron. Mater. ACS Appl. Energy Mater. ACS Appl. Mater. Interfaces ACS Appl. Nano Mater. ACS Appl. Polym. Mater. ACS BIOMATER-SCI ENG ACS Catal. ACS Cent. Sci. ACS Chem. Biol. ACS Chemical Health & Safety ACS Chem. Neurosci. ACS Comb. Sci. ACS Earth Space Chem. ACS Energy Lett. ACS Infect. Dis. ACS Macro Lett. ACS Mater. Lett. ACS Med. Chem. Lett. ACS Nano ACS Omega ACS Photonics ACS Sens. ACS Sustainable Chem. Eng. ACS Synth. Biol. Anal. Chem. BIOCHEMISTRY-US Bioconjugate Chem. BIOMACROMOLECULES Chem. Res. Toxicol. Chem. Rev. Chem. Mater. CRYST GROWTH DES ENERG FUEL Environ. Sci. Technol. Environ. Sci. Technol. Lett. Eur. J. Inorg. Chem. IND ENG CHEM RES Inorg. Chem. J. Agric. Food. Chem. J. Chem. Eng. Data J. Chem. Educ. J. Chem. Inf. Model. J. Chem. Theory Comput. J. Med. Chem. J. Nat. Prod. J PROTEOME RES J. Am. Chem. Soc. LANGMUIR MACROMOLECULES Mol. Pharmaceutics Nano Lett. Org. Lett. ORG PROCESS RES DEV ORGANOMETALLICS J. Org. Chem. J. Phys. Chem. J. Phys. Chem. A J. Phys. Chem. B J. Phys. Chem. C J. Phys. Chem. Lett. Analyst Anal. Methods Biomater. Sci. Catal. Sci. Technol. Chem. Commun. Chem. Soc. Rev. CHEM EDUC RES PRACT CRYSTENGCOMM Dalton Trans. Energy Environ. Sci. ENVIRON SCI-NANO ENVIRON SCI-PROC IMP ENVIRON SCI-WAT RES Faraday Discuss. Food Funct. Green Chem. Inorg. Chem. Front. Integr. Biol. J. Anal. At. Spectrom. J. Mater. Chem. A J. Mater. Chem. B J. Mater. Chem. C Lab Chip Mater. Chem. Front. Mater. Horiz. MEDCHEMCOMM Metallomics Mol. Biosyst. Mol. Syst. Des. Eng. Nanoscale Nanoscale Horiz. Nat. Prod. Rep. New J. Chem. Org. Biomol. Chem. Org. Chem. Front. PHOTOCH PHOTOBIO SCI PCCP Polym. Chem.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1