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2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)最新文献

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Manufacturing Processes for the Creation of 15% Power Conversion Efficiency Inorganic Inorganic-Organic Perovskite Solar Cells 创造15%功率转换效率的无机无机-有机钙钛矿太阳能电池的制造工艺
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198958
A. Rodriguez, Author Ramirez, Author De La Rosa, A. Enriquez, Author Arquero, Author Rivera, Author Bustamante, Author Telles, Author Valerio, A. Hodges
Solar cell research aims at a gradual increment on the overall power conversion efficiency, looking into the possibility of an increment on the output current of the device. This research discusses the different methods applied during experimentation allowing for the reach of higher efficiency, explaining the effects each method had on the different samples used. Some of the methods to be discussed are some conventional methods in the creation of perovskite solar cells such as sonication, spin spin-on doping, annealing, and contact creation. In accordance to the methods used, a power conversion efficiency of 15.2% was obtained, as well as an open circuit voltage (Voc) of 1.065 V, a short circuit current (Isc) of 1.99 mA, a fill factor (FF) of 50.4%, a short circuit current density (Jsc) of 28.2 mA/cm2, and a shunt resistance of 3.3 kΩ. Each sample is discussed in order to provide a wider view on the positive and negative aspects of each method applied.
太阳能电池的研究目标是逐步提高整体的功率转换效率,探索器件输出电流增加的可能性。本研究讨论了在实验过程中应用的不同方法,以达到更高的效率,并解释了每种方法对使用的不同样品的影响。本文将讨论制备钙钛矿太阳能电池的一些常规方法,如超声、自旋自旋掺杂、退火和触点制备。根据所采用的方法,功率转换效率为15.2%,开路电压(Voc)为1.065 V,短路电流(Isc)为1.99 mA,填充因子(FF)为50.4%,短路电流密度(Jsc)为28.2 mA/cm2,分流电阻为3.3 kΩ。对每个样本进行讨论,以便对所应用的每种方法的积极和消极方面提供更广泛的看法。
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引用次数: 0
Exceeding 1 ms effective lifetime in High High-Resistivity P-Type Kerfless Multi-crystalline Wafers 高电阻率p型无角多晶片的有效寿命超过1ms
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198964
J. Hofstetter, R. Fraser, R. Jonczyk, A. Erşen, John Linton, A. Lorenz
Kerfless p-type wafers of varying resistivity are grown with Direct Wafer technology with precise control of dosing the Boron concentration in the melt. At very low Boron concentration, bulk resistivity values ≫100 Ω-cm are achieved and an effective lifetime above 1 ms is measured, corresponding to an estimated bulk lifetime around 2 ms. In contrast to ingot-based wafers, continuous growth using Direct Wafer technology produces a very tight resistivity distribution at any desired target resistivity, without variations caused by zone refining. In addition, the technology enables growth of 3D wafers, e.g. thin wafers with a thick frame that allows to maintain mechanical wafer strength. Thus, Direct Wafer product can be customized for a given solar cell architecture by growing each individual wafer at the optimum bulk resistivity and optimum thickness.
采用直接晶圆技术,通过对熔体中硼浓度的精确控制,生长出了不同电阻率的无角p型晶圆。在极低硼浓度下,体电阻率值达到了> 100 Ω-cm,有效寿命大于1 ms,对应于估计的体寿命约为2 ms。与锭基晶圆片相比,使用直接晶圆技术的连续生长在任何期望的目标电阻率下都能产生非常紧密的电阻率分布,而不会因区域精炼而产生变化。此外,该技术还可以实现3D晶圆的生长,例如,具有厚框架的薄晶圆可以保持晶圆的机械强度。因此,Direct晶圆产品可以根据给定的太阳能电池结构定制,通过在最佳体积电阻率和最佳厚度下生长每个单独的晶圆。
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引用次数: 0
Measurements of Six-Junction Concentrator Solar Cells 六结聚光太阳能电池的测量
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198953
J. Geisz, R. France, M. Steiner, T. Moriarty, Tao Song
Accurate measurements of six-junction inverted metamorphic concentrator solar cells under AM1.5 direct spectrum are obtained by adjusting the spectrum of a tunable high-intensity solar simulator with custom mirrors. Isotype reference cells and broadband InGaAs QE calibration cells were developed for accurate measurements. Modeling and varying the illumination show that an unavoidable 15% - 17% overillumination on the sixth junction does not result in significant error of these 6J IMM devices. Spectrally adjusted flash measurements are independently confirmed by NREL's Cell and Module Performance team. Concentration measurements of a 6J IMM solar cell resulted in 47.1 ± 3.2% (absolute) efficiency at 143 suns.
通过对可调高强度太阳模拟器的光谱进行调整,实现了六结反向变质聚光太阳能电池在AM1.5直接光谱下的精确测量。开发了同型参考单元和宽带InGaAs QE校准单元,用于精确测量。建模和改变照度表明,在第6结不可避免的15% - 17%的过照度不会导致这些6J IMM器件的显着误差。光谱调整闪光测量由NREL的电池和模块性能团队独立确认。6J IMM太阳能电池在143个太阳下的浓度测量结果为47.1±3.2%(绝对)效率。
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引用次数: 1
Effects of increasing PV deployment on US Regional Transmission Organizations 增加光伏部署对美国区域输电组织的影响
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198971
Chinmay Vad, A. Aguilar, A. Srinivasa, S. Kurtz, C. Honsberg, R. King
Installed photovoltaic capacity has been rapidly increasing as the price of solar modules has continued to fall. When photovoltaic (PV) generation approaches the mid-day electric load demand, actions must be taken to balance the supply and demand. The challenge of matching the generation and demand is expected to vary with location. The goal of this project is to estimate the amount of PV that Regional Transmission Organizations (RTO) in the United States can afford to have on its grid before solar curtailment, storage, or load shifting will become important at mid-day to maintain balance of supply and demand. This paper uses historical renewable generation and load data for each RTO to assess imbalance between electricity supply and demand as solar generation increases. Imbalance was estimated as a function of solar penetration. Two scenarios were used to model the imbalance: 1) when the net load is calculated to be negative (PV generation exceeds the demand); and 2) when net load is less than a minimum generation limit value, e.g., determined by policy for baseload generation from conventional sources. The impact of increasing solar generation on real-time pricing is studied for the case of California, which presently has the highest solar penetration of the U.S. RTOs. This paper thus provides data-based projections for U.S. RTOs on the degree to which storage, load shifting, or trading on energy imbalance markets will need to be adopted to avoid severe curtailment of solar PV electricity generation.
随着太阳能组件价格的持续下降,光伏发电装机容量一直在迅速增加。当光伏发电接近中午电力负荷需求时,必须采取措施平衡供需。发电和需求相匹配的挑战预计会因地区而异。该项目的目标是估计美国区域输电组织(RTO)在太阳能弃电、储能或负荷转移对维持中午供需平衡变得重要之前,能够负担得起的光伏发电数量。本文使用历史可再生能源发电量和各RTO的负荷数据来评估随着太阳能发电量的增加,电力供需之间的不平衡。不平衡被估计为太阳穿透的函数。采用两种情况来模拟不平衡:1)净负荷为负(光伏发电超过需求);2)当净负荷小于最小发电限制值时,例如,由常规源的基本负荷发电政策确定。增加太阳能发电对实时定价的影响以加州为例进行了研究,加州目前拥有美国最高的太阳能渗透率。因此,本文为美国的rto提供了基于数据的预测,即为了避免太阳能光伏发电的严重削减,需要采用何种程度的存储、负荷转移或能源不平衡市场交易。
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引用次数: 0
Attempt to Design a Facile Lead-free Halide Double Perovskite Cs2AgBiBr6 p-i-n Solar Cell 设计一种简易无铅卤化物双钙钛矿Cs2AgBiBr6 p-i-n太阳能电池的尝试
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198967
J. Jang, Jinyoung Kim
Recently the power conversion efficiency of lead (Pb)-based organometallic halide perovskite materials was reached to 23 %. Despite of its excellent performance, the issue of environment and health still remained due to the lead toxicity. Therefore, the double perovskite (A2B'B"X6) which was composed of binary B site cations was particularly investigated as suitable non-toxic and lead-free perovskite composition. In this work, we synthesized all inorganic halide double perovskite composition, Cs2AgBiBr6 with dropping method. Furthermore, the p-i-n double perovskite solar cell was designed and improved by applying various hole and electron transporting layers based on the optimization of band alignment.
近年来,铅基有机金属卤化物钙钛矿材料的功率转换效率达到23%。尽管其性能优异,但由于铅的毒性,环境和健康问题仍然存在。因此,特别研究了由二元B位阳离子组成的双钙钛矿(A2B’B’X6)作为合适的无毒无铅钙钛矿组合物。本文采用滴法合成了全无机卤化物双钙钛矿组合物Cs2AgBiBr6。在优化带向的基础上,设计并改进了p-i-n双钙钛矿太阳能电池。
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引用次数: 0
Analysis of Cu(In,Ga) Se grading evolution during low deposition temperature co-evaporation process by GD-OES and XPS measurements. Impact on solar cell performances and modelling 低温共蒸发过程中Cu(In,Ga) Se级配演化的GD-OES和XPS分析对太阳能电池性能和建模的影响
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198992
V. Achard, S. Béchu, M. Balestrieri, M. Bouttemy, M. Jubault, A. Etcheberry, D. Lincot, F. Donsanti
One of the key parameters to achieve high efficienc y Cu(In,Ga)Se Se2 (CIGS) solar cells is the proper control of Ga grading. From previous results, by using bulk material characterization, a first assessment of the CIGS growth on polyimide foils at low temperature was performed. Moreover, a maximum efficiency of 17.8% ha has been achieved with steep Ga grading. Here, a first step to the establishment of a growth model of CIGS grown at low temperature is proposed by coupling surface and volume characterization. Then, simulation of the photovoltaic performances of the cell is used to complete experimental observations and to explain the benefic ial effect of steep Ga grading.
实现高效Cu(In,Ga)Se Se2 (CIGS)太阳能电池的关键参数之一是正确控制Ga的分级。根据先前的结果,通过使用大块材料表征,首次评估了低温下聚酰亚胺箔上CIGS的生长。此外,陡坡Ga级配的效率最高可达17.8%。本文提出了通过表面和体积耦合表征来建立低温生长CIGS模型的第一步。然后,通过对电池光伏性能的模拟来完成实验观察,并解释陡峭Ga级配的有利影响。
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引用次数: 0
Spatially and spectrally resolved defects in polycrystalline CdTe thin films revealed by quantitative cathodoluminescence 用定量阴极发光技术揭示多晶碲化镉薄膜的空间和光谱分辨缺陷
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198976
Thomas Bidaud, J. Moseley, M. Al-Jassim, M. Amarasinghe, W. Metzger, S. Collin
Increasing the grain size is a potential strategy to reduce grain-boundary recombination and improve performance of thin-film solar cells. Here, CdTe thin films with a range of grain sized were produced by varying the CdC12 post-deposition treatment temperature. We use high-resolution cathodoluminescence (CL) microscopy to study recombination and shallow defect levels in detail. Intensities from room temperature CL maps were compared across samples. We find that the CL intensity initially increases with grain size, as expected, but then plateaus as the grain size is increased further. The plateau is correlated with a decrease in the characteristic length-related to the carrier diffusion length-determined from CL intensity profiles near grain boundaries. In addition, low-temperature CL measurements demonstrate the evolution of the defect levels with CdC12 temperature.
增加晶粒尺寸是减少晶界复合和提高薄膜太阳能电池性能的潜在策略。在这里,通过改变CdC12沉积后的处理温度,制备了具有一定晶粒尺寸的CdTe薄膜。我们使用高分辨率阴极发光(CL)显微镜来详细研究重组和浅缺陷水平。在不同样品间比较室温CL图的强度。我们发现,与预期的一样,CL强度最初随着晶粒尺寸的增加而增加,但随后随着晶粒尺寸的进一步增加而趋于平稳。高原与载流子扩散长度相关的特征长度的减少相关,这是由晶界附近的CL强度曲线确定的。此外,低温CL测量显示了CdC12温度下缺陷水平的演变。
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引用次数: 2
High-level financial assessment of colored BIPV façades: Case study in Singapore 有色BIPV项目高层财务评估:新加坡案例研究
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198989
V. Shabunko, T. Reindl
Building integrated photovoltaics (BIPV) on façade areas is an innovative trend for on-site clean energy generation on a large façade areas and hence also for the reduction of greenhouse gas emissions. For densely built-up environments like the city state of Singapore, optimally integrated BIPV systems into the building envelope are critical to achieve Super Low Energy (SLE), or even Zero Energy (ZE) or Plus Energy (PE) buildings. In the framework of a Sino-Singapore research project, a first real-world test-bedding of colored BIPV façades have been conducted at National University of Singapore (NUS) campus. This paper discusses the financial viability of an innovative colored BIPV technology for applications in tropical urban areas and beyond.
在农村地区建设综合光伏(BIPV)是一种创新趋势,可以在大型农村地区进行现场清洁能源发电,从而减少温室气体排放。对于像新加坡这样的密集建筑环境,将BIPV系统优化集成到建筑围护结构中对于实现超低能耗(SLE),甚至零能耗(ZE)或正能耗(PE)建筑至关重要。在中新研究项目的框架下,在新加坡国立大学(NUS)校园进行了第一个彩色BIPV面板的实际测试平台。本文讨论了一种创新的彩色BIPV技术在热带城市地区及其他地区应用的财务可行性。
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引用次数: 1
Multi-dimensional luminescence imaging: accessing transport properties 多维发光成像:获取输运特性
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198955
D. Ory, A. Bercegol, D. Suchet, Jean-Baptiste Puel, Amadéo Michaud, A. B. Slimane, S. Collin, Stefania Cacovich, Olivier Fournier, Amelle Rebai, J. Rousset, J. Guillemoles, L. Lombez
Among all the characterization methods in the photovoltaic research area the luminescence luminescence-based ones offer multiple advantages. Indeed, it is possible to analyze both photovoltaic materials and devices in a quantitative way since the luminescence signals are linked to several photovoltaic conversion mechanisms such as the voltage generation, charge extraction or diffusion length. Here we use imaging methods to probe the transport properties and/or image material inhomogeneities. By using multi multi-dimensional imaging systems, we show how we can broaden the range of determined optoelectronic properties. A focus is made on transport properties applied to multiple PV absorbers.
在光伏研究领域的表征方法中,基于发光的表征方法具有多种优势。事实上,由于发光信号与电压产生、电荷提取或扩散长度等几种光伏转换机制有关,因此可以定量地分析光伏材料和器件。在这里,我们使用成像方法来探测传输性质和/或成像材料的不均匀性。通过使用多多维成像系统,我们展示了如何扩大确定的光电特性的范围。重点研究了应用于多个PV吸收器的输运特性。
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引用次数: 0
Synthesis of CdSeCdSexTe1-x/CdTe for graded solar cells 梯度太阳能电池用CdSeCdSexTe1-x/CdTe的合成
Pub Date : 2019-06-16 DOI: 10.1109/PVSC40753.2019.9198949
Xin Zheng, D. Kuciauskas, J. Moseley, E. Colegrove, D. Albin, H. Moutinho, J. Duenow, S. Harvey, T. Ablekim, A. Ferguson, S. Sivananthan, W. Metzger
Here, we have developed CdSexTe1-x/CdTe bilayer deposition for graded solar cell technolgoly technolgoly. Smoothly graded Se profiles with > 16% efficiency with Jsc=28 mA/cm2 and 20-ns bulk lifetime has been observed observed. The CdSeTe reveals longer carrier lifetimes than CdTe within the same device.
在这里,我们开发了CdSexTe1-x/CdTe双层沉积技术用于梯度太阳能电池技术。在Jsc=28 mA/cm2、体积寿命为20 ns的情况下,可以观察到效率> 16%的光滑梯度Se剖面。在相同的设备中,CdTe显示出比CdTe更长的载波寿命。
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引用次数: 1
期刊
2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)
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