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2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)最新文献

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Evaluation of ITO/a-Si Interface Fabricated by RPD Technique RPD技术制备ITO/a-Si界面的评价
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980657
Tappei Nishihara, T. Kamioka, Hiroki Kanai, Y. Ohshita, H. Matsumura, S. Yasuno, I. Hirosawa, A. Ogura
We evaluated the ITO/p-type a-Si interface for Si heterojunction solar cells using XPS and TEM. It was found that ITO/a-Si interface which is 20 nm from the surface is oxidized by using non-destructive and non-contact HAXPES. The ITO/a-Si interface was oxidized during ITO film deposition by RPD technique, which leads to an increase in contact resistance. The chemical bonding states at the ITO/a-Si interface was modified by post deposition annealing (PDA). The TEM and the EDX mapping images revealed the interdiffusion of Si and Sn resulting in the interface roughness enhancement and the possible In precipitation in the a-Si layer.
我们利用XPS和TEM对硅异质结太阳能电池的ITO/p型a-Si界面进行了评价。用非接触式HAXPES对ITO/a-Si界面进行了氧化处理。在RPD沉积过程中,ITO/a-Si界面被氧化,导致接触电阻增加。采用沉积后退火(PDA)技术修饰了ITO/a-Si界面的化学键态。TEM和EDX成像显示Si和Sn的相互扩散导致界面粗糙度增强,并可能在a-Si层中析出in。
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引用次数: 0
Influence of Front-Side Ag Metallization on High Temperature and High Humidity Test of Crystalline Silicon PV Module 前端镀银对晶体硅光伏组件高温高湿测试的影响
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8981218
T. Semba, Takeo Shimada, T. Fujita
Regarding the crystalline Silicon Photovoltaic module in which the corrosion of the front-side metallization occurred form near the bus bars in the high temperature high humidity test, the state of the finger metallization after the test was observed. Corrosion of the glass of the metallization was confirmed as in the previous report. In addition, there was a gap between the bulk Ag and the glass layer. This gap can cause an increase in series resistance between the emitter and the finger bars. Sn was also detected from a part of the corroded metallization surface.
对于高温高湿试验中前端金属化腐蚀发生在母线附近的晶体硅光伏组件,观察试验后手指金属化的状态。金属化玻璃的腐蚀在之前的报告中得到了证实。此外,大块银与玻璃层之间存在间隙。这个间隙会导致发射极和指棒之间的串联电阻增加。在腐蚀的部分金属化表面也检测到锡。
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引用次数: 3
PolySi Based Passivating Contacts Enabling Industrial Silicon Solar Cell Efficiencies up to 24% 基于多晶硅的钝化触点使工业硅太阳能电池效率高达24%
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980806
M. Stodolny, K. Tool, B. Geerligs, J. Löffler, A. Weeber, Yu Wu, J. Anker, Xiaoqian Lu, Ji Liu, P. Bronsveld, A. Mewe, G. Janssen, G. Coletti
In this paper we present our recent results on n+, p+ and intrinsic polysilicon contacts, including their contacting with industrial metallization process by screen printed fire-through pastes. The review is complemented by comparison with polysilicon passivation results by other relevant players in this field. We present record surface passivation levels on textured surfaces (J0~1 fA/cm2 for n+ polySi and J0<10 fA/cm2 for p+ and i-polySi), and record low contact recombination for screen printed fire-through metal contacts reaching down to 65 and 200 fA/cm2 for n+ and p+polySi, respectively. In addition, an improvement in the silicon bulk passivation can be attributed to the introduction of n+ polysilicon in the cell process. These results are the fundamental components to demonstrate a roadmap towards 24% industrial PERPoly (industrial TOPCon) cells.
本文介绍了n+, p+和本征多晶硅触点的最新研究成果,包括它们与丝网印刷过火糊工业金属化工艺的接触。该综述还与该领域其他相关参与者的多晶硅钝化结果进行了比较。我们在织构表面上记录了表面钝化水平(n+多晶硅为J0~1 fA/cm2, p+和i-多晶硅为J02),并且在丝网印刷的fire-through金属触点上记录了低接触复合,n+和p+多晶硅分别达到65和200 fA/cm2。此外,硅体钝化的改进可归因于在电池工艺中引入n+多晶硅。这些结果是展示24%工业PERPoly(工业TOPCon)电池路线图的基本组成部分。
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引用次数: 6
Reducing CPV Materials Cost Through Multistage Concentration 多级浓缩降低CPV材料成本
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980520
R. Norman, B. Siskavich, É. Léveillé, W. Cloutier, L. Fréchette, V. Aimez
In PV manufacturing, process costs fall rapidly with scale, but a slower decrease in material costs limits cost reduction. Analysis of a proposed multi-stage-concentration module shows that even with additional concentration stages for low tandem-cell cost, initial concentration by a trough mirror can greatly reduce overall materials usage compared to Fresnel/box CPV. A compact sealed module at the trough’s focus allows high-performance materials for efficiency and durability, and estimated costs (¢/W, LCOE, capital-to-scale) compare favorably to even silicon PV.
在光伏制造业中,工艺成本随着规模的扩大而迅速下降,但材料成本的缓慢下降限制了成本的降低。对多级浓缩模块的分析表明,即使增加了低串联电池成本的浓缩级,与菲涅耳/盒CPV相比,槽镜的初始浓缩可以大大减少材料的总体使用。一个紧凑的密封模块在槽的焦点允许高性能材料的效率和耐用性,和估计的成本(美分/W, LCOE,资本规模)甚至比硅PV更有利。
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引用次数: 1
Hybrid Intra-hour Solar PV Power Forecasting using Statistical and Skycam-based Methods 基于统计和skycam的混合小时内太阳能光伏发电预测方法
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980732
Jing Huang, M. Khan, Yi Qin, Sam West
We propose and test a hybrid solar PV power forecasting model which optimally combines statistical and skycam-based forecasts. We show our model’s capability to produce accurate forecasts seamlessly from 10-s to 10-min ahead using high-frequency measurements in Canberra, Australia. The hybrid model relies on an empirical clear-sky model for solar power and the identification of three condition variables, which are able to separate and model characteristic events associated with them. It significantly overperforms both its statistical component and its skycam component alone, achieving a relative RMSE reduction (forecast skill) of 19% against persistence of clear-sky index at 5-min ahead.
我们提出并测试了一种混合太阳能光伏发电预测模型,该模型将统计和基于天空摄像机的预测最佳地结合在一起。我们展示了我们的模型在澳大利亚堪培拉使用高频测量提前10- 10分钟无缝生成准确预测的能力。该混合模型依赖于太阳能的经验晴空模型和三个条件变量的识别,这些条件变量能够分离和模拟与之相关的特征事件。它明显优于其统计组件和单独的天空摄像头组件,在持续5分钟的晴空指数下实现相对RMSE降低19%(预测技能)。
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引用次数: 2
NIEL Dose Analysis on triple and single junction InGaP/GaAs/Ge solar cells irradiated with electrons, protons and neutrons 电子、质子和中子辐照三结和单结InGaP/GaAs/Ge太阳能电池的NIEL剂量分析
Pub Date : 2019-06-01 DOI: 10.1109/pvsc40753.2019.8980581
R. Campesato, C. Baur, M. Carta, M. Casale, D. Chiesa, M. Gervasi, E. Gombia, E. Greco, Aldo Kingma, M. Nastasi, E. Previtali, P. Rancoita, D. Rozza, E. Santoro, M. Tacconi
Triple junction (InGaP/GaAs/Ge) and single junction (SJ) solar cells were irradiated with electrons, protons and neutrons. The degradation of remaining factors was analyzed as function of the induced Displacement Damage Dose (DDD) calculated by means of the SR-NIEL (Screened Relativistic Non Ionizing Energy Loss) approach. In particular, the aim of this work is to analyze the variation of the solar cells remaining factors due to neutron irradiation with respect to those previously obtained with electrons and protons. The current analysis confirms that the degradation of the Pmax electrical parameter is related by means of the usual semi-empirical expression to the displacement dose, independently of type of the incoming particle. Isc and Voc parameters were also measured as a function of the displacement damage dose. Furthermore, a DLTS analysis was carried out on diodes –with the same epitaxial structure as the middle sub-cell - irradiated with neutrons.
用电子、质子和中子辐照三结(InGaP/GaAs/Ge)和单结(SJ)太阳能电池。利用SR-NIEL(筛选相对论非电离能量损失)方法计算了诱发位移损伤剂量(DDD),分析了剩余因素的退化情况。特别地,这项工作的目的是分析由于中子辐照而引起的太阳能电池剩余因素的变化,相对于以前用电子和质子获得的因素。目前的分析证实,Pmax电参数的退化是通过通常的半经验表达式与位移剂量有关,而与入射粒子的类型无关。测定了Isc和Voc参数随位移损伤剂量的变化规律。此外,对中子辐照后具有与中间亚电池相同外延结构的二极管进行了DLTS分析。
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引用次数: 4
Modelling and Validation on Field of EESS Management Strategies in Grid-Connected PV Systems for End Users 最终用户并网光伏系统EESS管理策略领域建模与验证
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980659
F. D. Lia, Francesca Lorè, R. Schioppo, R. L. Presti, M. Tucci
In this work different management strategies for Electrical Energy Storage Systems (EESS) have been modeled in the ENEA’s Simulator Plant and subsequently tested on field in the PV Plant. The Plant (12 kWp, 12 kWh) is equipped with ABB REACT1 systems. A relevant aspect of the Plant is the Energy Management System (EMS), developed by ENEA that allows the EESS control and supervision in real time according to the selected management strategy. Self-consumption and Peak-Shaving strategies have been modeled and successfully tested.
在这项工作中,电能存储系统(EESS)的不同管理策略在ENEA的模拟器工厂中进行了建模,并随后在光伏工厂进行了现场测试。该电厂(12 kWp, 12 kWh)配备了ABB REACT1系统。该工厂的一个相关方面是能源管理系统(EMS),该系统由ENEA开发,允许根据选定的管理策略实时控制和监督EESS。自我消费和调峰策略已经建模并成功测试。
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引用次数: 0
Structural and Optical Properties of Two-Stage CuInSe2 Thin Films Studied by Real Time Spectroscopic Ellipsometry 实时椭圆偏振光谱法研究两级CuInSe2薄膜的结构和光学性质
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980671
Dhurba R. Sapkota, R. Collins, P. Pradhan, P. Koirala, R. Irving, A. Phillips, R. Ellingson, M. Heben, S. Marsillac, N. Podraza
CuInSe2 (CIS) thin films ~ 500-650 Å in thickness have been deposited on c-Si substrates by two-stage thermal co-evaporation starting either from In2Se3 [according to In2Se3 + (2Cu+Se) → 2(CuInSe2)] or from Cu2-xSe [according to Cu2Se + (2In+3Se) → 2(CuInSe2)]. The design of such processes is facilitated by accurate calibrations of Cu and In2Se3 growth rates on substrate/film surfaces obtained by real time spectroscopic ellipsometry (RTSE). The two-stage deposited CIS films were also studied by RTSE to deduce (i) the evolution of film structure upon conversion of the starting In2Se3 or Cu2-xSe films to CIS via Cu+Se or In+Se co-evaporation, respectively, and (ii) the complex dielectric functions of the starting films as well as the resulting CIS. The goal is to fabricate CIS that develops large grains as early as possible during growth for high quality materials in tandem solar cell applications. Results indicate that by depositing Cu2-xSe in the first stage and exposing the film to In+Se flux in the second stage [as in the third stage of a three-stage CIS process] well-defined bandgap critical points with no detectable subgap absorption are noted in films as thin as 650 Å.
在c-Si衬底上通过两段热共蒸发沉积了厚度为500 ~ 650 Å的CuInSe2 (CIS)薄膜,分别由In2Se3[根据In2Se3 + (2Cu+Se)→2(CuInSe2)]和Cu2-xSe[根据Cu2Se + (2In+3Se)→2(CuInSe2)]开始。通过实时光谱椭偏仪(RTSE)精确校准Cu和In2Se3在衬底/薄膜表面的生长速率,方便了这种工艺的设计。RTSE还研究了两阶段沉积的CIS膜,以推断(i)分别通过Cu+Se或In+Se共蒸发将起始In2Se3或Cu2-xSe膜转化为CIS时膜结构的演变,以及(ii)起始膜的复杂介电函数以及由此产生的CIS。目标是在串联太阳能电池应用的高质量材料的生长过程中,尽早制造出能够形成大颗粒的CIS。结果表明,通过在第一阶段沉积Cu2-xSe,并在第二阶段将薄膜暴露于in +Se通量中[如同在三阶段CIS过程的第三阶段],在薄至650 Å的薄膜中发现了明确的带隙临界点,没有可检测到的子隙吸收。
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引用次数: 2
Effects of Fabrication Atmosphere on Bulk and Back Interface Defects of CdTe Solar Cells with CdS and MgZnO Buffers 制备气氛对CdS和MgZnO缓冲CdTe太阳能电池体积和后界面缺陷的影响
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8981376
R. Awni, A. Phillips, M. Heben, R. Ellingson, Jian V. Li, Yanfa Yan, Dengbing Li, Zhaoning Song, S. Bista, Mohammed A. Razooqi, C. Grice, Lei Chen, Geethika K. Liyanage, Chongwen Li
The performance of Cadmium telluride (CdTe) solar cell devices is limited by the properties of front and back interfaces as well as the absorber layer, which can be influenced by the fabrication atmosphere. In this work, we report a detailed study of electrical properties of ZnMgO (ZMO)/CdTe and cadmium sulfide (CdS)/CdTe solar cells with the cadmium chloride (CdCl2) treatment performed in different atmospheres using temperature-dependent impedance spectroscopy and capacitance – voltage measurements. An equivalent circuit model consisting of two serial combinations of the front and back junctions is employed to fit the complex impedance spectra of devices measured in dark. Fitted data from equivalent circuit provides the value of each element, from which the bulk conductivity, back contact barrier height, as well as spatial inhomogeneities within the cell are extracted. Impedance spectroscopy analysis shows that there are negative and positive effects of back surface treatment in oxygen free ambient on device performance. For oxygen-free treatment, an obvious increase in the bulk conductivity is observed, suggesting an increased copper doping in the device. Additionally, ZMO devices show less junction inhomogeneity. All these improvements lead to better device performance of ZMO/CdTe solar cells.
碲化镉(CdTe)太阳能电池器件的性能受到前后界面和吸收层性能的限制,这些性能受制造气氛的影响。在这项工作中,我们报告了详细的研究ZnMgO (ZMO)/CdTe和硫化镉(CdS)/CdTe太阳能电池与氯化镉(CdCl2)处理在不同的气氛下进行的电学性质,使用温度相关的阻抗谱和电容电压测量。采用由前后结两个串联组合组成的等效电路模型拟合了在黑暗中测量的器件的复杂阻抗谱。来自等效电路的拟合数据提供了每个元素的值,从中提取了电池内的总体电导率、后接触垒高度以及空间不均匀性。阻抗谱分析表明,无氧环境下背表面处理对器件性能有积极和消极的影响。对于无氧处理,观察到体积电导率明显增加,表明器件中铜掺杂增加。此外,ZMO器件表现出较少的结不均匀性。这些改进提高了ZMO/CdTe太阳能电池的器件性能。
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引用次数: 0
Performance assessment of field deployed multi-crystalline PV modules in Nordic conditions 北欧条件下现场部署多晶光伏组件的性能评估
Pub Date : 2019-06-01 DOI: 10.1109/PVSC40753.2019.8980629
B. Paudyal, Anne Gerd Imenes
This paper presents an investigation of data monitoring quality and evaluation of performance degradation of four different multi-crystalline silicon (mc-Si) photovoltaic (PV) modules installed in the higher latitude conditions in southern Norway. Degradation of each module has been investigated in terms of degradation of short-circuit current (ISC), open-circuit voltage (VOC), fill factor (FF) and maximum power (PMPP). The analysis for the period of monitoring data from 2014 to 2018 show no considerable module degradation compared to the standard degradation rate of all parameters. The statistical analysis of ISC shows an average degradation of 0.17% for all modules. Spectral corrections were applied to ISC and PMPP, in addition to temperature and irradiance corrections. Among the parameters, FF and ISC show slight degradation based on the yearly average method. Infrared images were used for validation of findings, but due to the unavailability of images from the initial installation period, the image results are inconclusive. Performance ratio plots based on corrected ISC values show very stable performances over the five-year period. The results suggest that PV modules in cold conditions may undergo lower degradation compared to typical degradation rates experienced in other regions.
本文介绍了在挪威南部高纬度条件下安装的四种不同多晶硅(mc-Si)光伏(PV)模块的数据监测质量和性能退化评估的调查。从短路电流(ISC)、开路电压(VOC)、填充因子(FF)和最大功率(PMPP)的退化方面对每个模块的退化进行了研究。对2014年至2018年监测数据的分析显示,与所有参数的标准退化率相比,模块没有明显的退化。ISC的统计分析表明,所有模块的平均退化率为0.17%。除了温度和辐照度校正外,还对ISC和PMPP进行了光谱校正。其中,FF和ISC按年平均值法略有下降。红外图像用于验证发现,但由于无法获得最初安装期间的图像,图像结果是不确定的。基于修正的ISC值的性能比率图显示,在五年期间的性能非常稳定。结果表明,与其他地区的典型降解率相比,在寒冷条件下的光伏组件可能会经历更低的降解。
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引用次数: 2
期刊
2019 IEEE 46th Photovoltaic Specialists Conference (PVSC)
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