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2020 47th IEEE Photovoltaic Specialists Conference (PVSC)最新文献

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Mapping Current Collection in Cross Section: The case of Copper- doped CdTe Solar Cells 在截面上绘制电流集:以铜掺杂CdTe太阳能电池为例
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300979
Niranjan Kumar, A. R. Shaik, T. Walker, T. Nietzold, B. Lai, E. Colegrove, M. Stuckelberger, M. Bertoni
For decades, copper has been used to improve the performance of cadmium telluride thin film solar cells. However, it has also been shown to be the main cause of metastability in CdTe. Recently a low activation energy has been reported for the thermal diffusion of Cu in CdTe explaining the ease of motion that it has under moderate temperatures. The community consensus is that copper segregates to the absorber grain boundaries, where it's either beneficial or detrimental to device performance depending on its concentration. Using nanoscale X-ray micrsocopy and a two-dimensional drift-diffusion model we present a preliminary correlation between local copper distribution and electrical performance of a single-junction CdTe/CdS solar cell.
几十年来,铜一直被用来提高碲化镉薄膜太阳能电池的性能。然而,它也被证明是CdTe亚稳态的主要原因。最近报道了Cu在CdTe中的热扩散的低活化能,解释了它在中等温度下的易动性。社区的共识是,铜偏析到吸收器晶界,在那里它是有利的或有害的器件性能取决于其浓度。利用纳米x射线显微镜和二维漂移扩散模型,我们提出了局部铜分布与单结CdTe/CdS太阳能电池电性能之间的初步相关性。
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引用次数: 1
Carrier-Resolved Photo-Hall Effect: Unlocking a 140-year-old secret in Hall effect 载波分辨率照片霍尔效应:在霍尔效应中解开140年的秘密
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300483
O. Gunawan, S. Pae, Douglas M. Bishop, B. Shin, Yudistira Virgus, D. Mitzi
Majority and minority carrier properties such as type, density and mobility represent fundamental yet difficult to access parameters governing semiconductor device performance, most notably solar cells. Obtaining this information simultaneously under light illumination would unlock many critical parameters such as recombination lifetime, recombination coefficient, and diffusion length; while deeply interesting for optoelectronic devices, this goal has remained elusive. We demonstrate here a new carrier-resolved photo-Hall technique that rests on a new equation relating hole-electron mobility difference ($Deltamu$), Hall coefficient ($H$), and conductivity ($sigma$), and a rotating parallel dipole line ac-field Hall system with Fourier/lock-in detection for clean Hall signal measurement [1]. We successfully apply this technique to recent world-record-quality perovskite film and map the results against varying light intensities, demonstrating unprecedented simultaneous access to the above-mentioned parameters.
多数载流子和少数载流子的性质,如类型、密度和迁移率,代表了控制半导体器件性能的基本但难以获得的参数,尤其是太阳能电池。在光照条件下同时获得这些信息将解锁许多关键参数,如复合寿命、复合系数和扩散长度;虽然光电器件非常有趣,但这一目标仍然难以实现。我们在这里展示了一种新的载流子分辨光霍尔技术,该技术基于一个新的空穴电子迁移率差($Deltamu$)、霍尔系数($H$)和电导率($sigma$)的方程,以及一个旋转平行偶极子线交流场霍尔系统,该系统具有用于清洁霍尔信号测量的傅里叶/锁定检测[1]。我们成功地将这项技术应用于最近的世界纪录质量的钙钛矿薄膜,并在不同的光强度下绘制结果,展示了前所未有的同时访问上述参数。
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引用次数: 1
Highly Flexible Solar Sheets With High Specific Power for Stratospheric Flight Applications 具有高比功率的高柔性太阳能片,用于平流层飞行应用
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300996
M. Drees, C. Stender, R. Chan, M. Osowski, N. Pan
MicroLink has developed highly flexible solar sheets that exhibit high specific power and are suitable for stratospheric flight applications. Here we present reliability test data as well as actual stratospheric flight data of these solar sheets. Data from the 24-hour high-altitude balloon flight that was performed in September 2019 out of Baltic, SD at an altitude of 19km showed peak power output of 421W/m2 of MicroLink's panel at an operating temperature of 24°C. This translates into a specific power of the solar sheets of 1,668 W/kg including top sheet and adhesive layers.
MicroLink开发了高度灵活的太阳能片,具有高比功率,适合平流层飞行应用。本文给出了这些太阳能板的可靠性测试数据以及实际的平流层飞行数据。2019年9月在波罗的海,SD进行的24小时高空气球飞行数据显示,在24°C的工作温度下,MicroLink面板的峰值输出功率为421W/m2。这转化为太阳能板的特定功率为1,668 W/kg,包括顶部板和粘合剂层。
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引用次数: 1
Minority carrier traps in Czochralski-grown p-type silicon crystals doped with B, Al, Ga, or In impurity atoms 掺杂B、Al、Ga或in杂质原子的czochralski生长的p型硅晶体中的少数载流子陷阱
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300860
J. T. D. de Guzman, V. Markevich, S. Hammersley, I. Hawkins, I. Crowe, N. Abrosimov, R. Falster, J. Binns, P. Altermatt, M. Halsall, A. Peaker
Minority carrier traps in Czochralski-grown (Cz) silicon crystals doped with either boron, aluminum, gallium, or indium impurity atoms have been investigated by means of deep-level transient spectroscopy and other junction-related techniques. The experimental data have suggested that minority carrier trapping effects in Cz-Si samples doped with different acceptor impurities are associated with complexes incorporating a substitutional group-III impurity atom and two oxygen atoms, which are found to be negative-U defects with close locations of E(-/+) occupancy level at about Eu + 0.32 eV. We have determined the energy barriers and frequency factors for the reversible transformations of the complexes between deep donor and shallow acceptor states. These parameters are discussed in relation to light-induced degradation behavior of solar cells on p-type Cz-Si crystals.
利用深能级瞬态光谱和其他结相关技术研究了掺杂硼、铝、镓或铟杂质原子的Cz生长硅晶体中的少数载流子陷阱。实验数据表明,掺杂不同受体杂质的Cz-Si样品中的少数载流子捕获效应与含有取代族iii杂质原子和两个氧原子的配合物有关,这些配合物被发现是负u缺陷,其E(-/+)占据水平在Eu + 0.32 eV左右。我们确定了深层给体态和浅层受体态之间的可逆转化的能量势垒和频率因子。讨论了这些参数与太阳能电池在p型Cz-Si晶体上的光致降解行为的关系。
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引用次数: 0
Environmental Influence on Fracture and Delamination of Electrically Conductive Adhesives 环境对导电胶粘剂断裂和分层的影响
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300480
M. Springer, N. Bosco
This paper presents our continued work on developing a degradation model for electrically conductive adhesive (ECA) interconnects in photovoltaic modules. Here, we characterize the fracture mechanics properties of an epoxy based ECA, for both critical and subcritical loading conditions. Emphasis is put on the influence of different environmental conditions such as temperature and humidity. We found that high levels of humidity not only weaken the adhesive joint but also promote subcritical debonding at significantly lower driving forces than in dry environments.
本文介绍了我们在开发光伏组件中导电胶粘剂(ECA)互连的降解模型方面的持续工作。在这里,我们描述了环氧基ECA在临界和亚临界载荷条件下的断裂力学性能。重点讨论了温度、湿度等不同环境条件的影响。我们发现,与干燥环境相比,高湿度水平不仅削弱了粘合接缝,而且在显著降低驱动力的情况下促进了亚临界脱粘。
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引用次数: 3
Stringing monolithic three terminal III-V tandems 串联三个III-V端子串联
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300914
J. Buencuerpo, J. Geisz, M. Young, Talysa R Klein, W. McMahon, E. Warren, A. Tamboli
Tandem devices are well known to surpass single junctions. However, the limitations of current-matching is a concern for changing spectra in terrestrial applications. Three terminal tandem (3T) devices can be more robust to these variations resulting in higher energy yield than single junction devices and two terminal series-connected tandems. We fabricate one-sun 3T tandem devices made of inverted grown III-V tandem (GaInP/GaAs) as a prototype of 3T tandems for stringing and measurement demonstrations. We demonstrate 3T tandem measurements that can be used to understand the use of 3T tandems in various constrained configurations.
串联装置是众所周知的超越单结。然而,电流匹配的局限性是变化光谱在地面应用中的一个问题。三端串联(3T)器件比单端串联器件和两端串联器件具有更高的能量产量。我们制造了由倒置生长III-V串联(GaInP/GaAs)制成的单太阳3T串联器件,作为3T串联的原型,用于串接和测量演示。我们演示了3T串联测量,可用于了解3T串联在各种约束配置中的使用。
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引用次数: 0
Passivation of the Recombination Activities with Rubidium incorporation for Efficient and Stable Sn- HaP Solar Cells 铷掺杂对高效稳定的Sn- HaP太阳能电池复合活性的钝化
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300783
Dhruba B. Khadka, Yashihiro Shirai, M. Yanagida, K. Miyano
A number of non- toxic candidates such as Sn, Ge, Bi, and Sb based halide perovskites, etc. have been explored as Pb free HaPSCs Among these alternatives, Sn-based halide perovskites (Sn-HaP) are promising alternatives. The oxidative instability of tin-based halide perovskite (Sn-HaP) deteriorates the device performance. In this report, we have explored the role of Rb insertion in FASnI3lattice for device performance. The Rb incorporation in crystal lattice facilitates uniform morphology with better crystal quality and suppression of oxidation of Sn2+. The device analysis showed higher diffusion potential and mitigation of defect activities with RbCl additive in Sn-HaPSCs. This leads to the improvement in device performance and stability with the power conversion efficiency of ~3 % for pure FASnI3to 6 % for Rb incorporated FASnI3.
许多无毒的候选物,如锡、锗、铋和Sb基卤化物钙钛矿等,已经被探索作为无铅HaPSCs。在这些替代品中,锡基卤化物钙钛矿(Sn- hap)是很有前途的替代品。锡基卤化物钙钛矿(Sn-HaP)的氧化不稳定性降低了器件的性能。在本报告中,我们探讨了在fasni3晶格中插入Rb对器件性能的作用。在晶格中掺入Rb有利于形貌均匀,具有较好的晶体质量和抑制Sn2+氧化的作用。器件分析显示,RbCl添加剂在Sn-HaPSCs中具有更高的扩散电位和降低缺陷活性。这导致器件性能和稳定性的提高,纯FASnI3的功率转换效率为~ 3%,而Rb加入FASnI3的功率转换效率为6%。
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引用次数: 0
In Situ Phosphorus-Doped Poly-Si by Low Pressure Chemical Vapor Deposition for Passivating Contacts 低压化学气相沉积原位掺磷多晶硅钝化触点
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300543
Meriç Fırat, H. S. Radhakrishnan, M. R. Payo, F. Duerinckx, Rajiv Sharma, J. Poortmans
The potential of in situ phosphorus (P)-doped polycrystalline silicon (poly-Si) films by low pressure chemical vapor deposition (LPCVD) was studied for the realization of poly-Si/SiOx passivating contacts. In situ doping of poly-Si, as an alternative to ex situ methods, could enable simpler fabrication of industrial solar cells featuring these passivating contacts. With this approach, recombination current densities down to 1.7 fA/cm2 and 3.5 fA/cm2 were achieved on saw-damage removed and textured Cz-Si surfaces, respectively. It was found that the use of thermal SiOx, high active doping in the poly-Si, and hydrogenation improve the passivation quality. In addition, while post-LPCVD annealing was also beneficial, dopant loss from poly-Si at high annealing thermal budgets was observed to be detrimental to the specific contact resistivity and passivation quality, thus making it crucial to mitigate such dopant losses.
研究了低压化学气相沉积法(LPCVD)原位磷掺杂多晶硅(poly-Si)薄膜的电位,以实现多晶硅/SiOx钝化触点。原位掺杂多晶硅,作为非原位方法的一种替代方法,可以使具有这些钝化接触的工业太阳能电池的制造更简单。通过这种方法,复合电流密度分别降低到1.7 fA/cm2和3.5 fA/cm2,分别用于去除锯损伤和纹理化的Cz-Si表面。结果表明,采用热SiOx、高活性掺杂多晶硅、加氢等方法可以提高多晶硅的钝化质量。此外,虽然lpcvd后退火也是有益的,但观察到高退火热收支下多晶硅的掺杂损失对比接触电阻率和钝化质量有害,因此减少这种掺杂损失至关重要。
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引用次数: 3
Large Area (>1cm2) Efficient Perovskite/N type C-Si Tandem Solar Cell 大面积(>1cm2)高效钙钛矿/N型C-Si串联太阳能电池
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300472
P. Hsieh, Ming-Hsien Li, Wei-Chiao Hung, C. Yang, Peter Chen, I. Chen
In this article, we demonstrate mechanically stacked four-terminal perovskite-silicon tandem solar cells. N-type C-Si solar cell with PERT structure were used as the bottom cell and the perovskite solar cell on FTO glass substrate was used for top cell under 1.02 cm2 active area. In order to increase the FF for PSC, we introduce a metal mesh design for connecting TCO layers. With the metal mesh inside, the best power conversion efficiency (PCE) of 20.46% with 1.02cm2 was performed.
在这篇文章中,我们展示了机械堆叠的四端钙钛矿硅串联太阳能电池。底部采用PERT结构的n型C-Si太阳能电池,顶部采用FTO玻璃衬底上的钙钛矿太阳能电池,有效面积为1.02 cm2。为了增加PSC的FF,我们引入了连接TCO层的金属网设计。在1.02 m2的面积上,金属网的最佳功率转换效率(PCE)为20.46%。
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引用次数: 0
Going beyond Alchemy: In-situ Analysis of Perovskite Growth by Optical Reflectance 超越炼金术:钙钛矿生长的光学反射原位分析
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300415
C. Camus, C. Kaspari, J. Rappich, V. Blank, N. Nickel
In this paper a novel method for in-situ monitoring of a complete perovskite fabrication process by means of highspeed spectral reflectance measurements is introduced. Firstly, the spin-coating deposition and secondly, the annealing process is monitored. The results clearly show that this method is capable to fully characterize the perovskite growth kinetics and the phase transitions during thin film annealing. Thereby in-situ reflectance constitutes an ideal method for monitoring perovskite formation, which as of today often suffers from poor reproducibility. This paper focuses on the experimental implementation of the in-situ- reflectance measurements during spin-coating.
本文介绍了一种利用高速光谱反射率测量对钙钛矿制备过程进行现场监测的新方法。首先对旋转涂层沉积过程进行了监测,其次对退火过程进行了监测。结果清楚地表明,该方法能够完整地表征钙钛矿在薄膜退火过程中的生长动力学和相变。因此,原位反射构成了监测钙钛矿形成的理想方法,目前这种方法的重现性很差。本文研究了旋转镀膜过程中原位反射率测量的实验实现。
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引用次数: 1
期刊
2020 47th IEEE Photovoltaic Specialists Conference (PVSC)
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