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2020 47th IEEE Photovoltaic Specialists Conference (PVSC)最新文献

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Low-temperature, solution processed device quality CZTS film for efficient heterojunction solar cells 用于高效异质结太阳能电池的低温,溶液处理器件质量的CZTS薄膜
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300987
M. Dhanasekar, S. V. Bhat
We report the preparation of device quality CZTS films by dip coating of a highly stable precursor solution followed by annealing at very low temperature of only 100°C.We also demonstrate that, the films can be used to make simple CZTS-CdS heterojunction based efficient solar cells. Initial devices with aluminium top contacts showed the best photovoltaic performance reported for this type of devices with power conversion efficiency (PCE) of 2.73%. In addition to fully avoiding the sulphurization/selenization step and the toxic solvents, our method to deposit the kesterite functional layer has added advantages of exceptional stability of the molecular precursor and the ultra-low temperature of processing suitable for various flexible optoelectronics applications at large scale.
我们报告了通过浸涂高度稳定的前驱体溶液,然后在仅100°C的极低温度下退火,制备器件质量的CZTS薄膜。我们还证明,该薄膜可用于制作简单的CZTS-CdS异质结型高效太阳能电池。采用铝顶触点的初始器件表现出最佳的光电性能,功率转换效率(PCE)为2.73%。除了完全避免了硫化/硒化步骤和有毒溶剂外,我们的沉积kesterite功能层的方法还增加了分子前驱体的优异稳定性和超低温加工的优点,适用于各种大规模柔性光电子应用。
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引用次数: 1
Temperature-dependent Photoluminescence Imaging using Non-uniform Excitation 使用非均匀激发的温度依赖性光致发光成像
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9301027
S. Nie, Yan Zhu, O. Kunz, H. Kampwerth, T. Trupke, Z. Hameiri
Photoluminescence (PL) imaging is a powerful inspection technique for research laboratories and production lines. It is used for a wide range of applications across the entire manufacturing chain from bricks and ingots to modules. However, common PL imaging systems have three main limitations: (a) Due to the uniform illumination, the acquired images are affected by lateral carrier flow, resulting in image blurring; (b) sample's nonuniformity is measured at different injection levels; and (c) images are taken at room temperatures, although there is valuable information in temperature-dependent measurements. In this paper we present a novel temperature-dependent PL imaging system that is not affected by lateral balancing currents. By adaptively adjusting the light intensity at each pixel, we set a uniform excess carrier density across the sample. Hence, the lateral currents are eliminated. The non-uniformity of the material's electrical properties and temperature characteristics can then be extracted from the excitation image. The advantages of the proposed system are demonstrated using mono and multicrystalline silicon wafers. This novel approach presents a significant improvement in accuracy and resolution compared to conventional PL imaging techniques and is therefore, expected to be beneficial for any PL-based quantitative analysis.
光致发光(PL)成像是一种强大的检测技术的研究实验室和生产线。它被广泛用于从砖和锭到模块的整个制造链的应用。然而,常见的PL成像系统存在三个主要的局限性:(a)由于光照均匀,采集的图像受到横向载流子流的影响,导致图像模糊;(b)在不同注射水平下测量样品的不均匀性;(c)图像是在室温下拍摄的,尽管在温度相关的测量中有有价值的信息。在本文中,我们提出了一种不受横向平衡电流影响的新型温度相关PL成像系统。通过自适应调整每个像素处的光强度,我们在整个样品中设置了均匀的多余载流子密度。因此,横向电流被消除。然后可以从激发图像中提取材料电性能和温度特性的不均匀性。用单晶硅片和多晶硅片证明了该系统的优点。与传统的PL成像技术相比,这种新方法在精度和分辨率上有了显著的提高,因此,有望对任何基于PL的定量分析有益。
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引用次数: 1
Modeling Spectrally-Selective Reflection for Thermal Management in Monofacial and Bifacial Modules 单面和双面模块热管理的光谱选择反射建模
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300678
I. Slauch, M. Deceglie, T. Silverman, V. Ferry
Parasitic absorption in photovoltaic modules is a major source of waste heat, which drives operating temperatures 20-30K above ambient. Spectrally-selective sub-bandgap reflection can reduce parasitic absorption, thereby improving module efficiency and power output. Here, we investigate the performance of 1-D spectrally-selective mirrors in monofacial Al BSF and PERC modules, and bifacial PERC modules. In monofacial modules, these mirrors offer >1.2% increase in energy yield compared to single-layer anti-reflection coatings, while cooling by over 1K on average. Mirrors reduced bifacial module parasitic absorption by up to 34 W/m2 out of 1240 W/m2 incident.
光伏组件中的寄生吸收是废热的主要来源,它驱动工作温度高于环境温度20-30K。光谱选择性亚带隙反射可以减少寄生吸收,从而提高模块效率和功率输出。在这里,我们研究了一维光谱选择镜在单面Al BSF和PERC模块以及双面PERC模块中的性能。在单面模块中,与单层增透涂层相比,这些反射镜的能量产量增加了>1.2%,同时平均冷却超过1K。镜子减少了双面模块的寄生吸收,在1240 W/m2的事件中减少了34 W/m2。
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引用次数: 0
UV-Fluorescence Imaging of Silicon PV Modules After Outdoor Aging and Accelerated Stress Testing 硅光伏组件户外老化和加速应力测试后的紫外荧光成像
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300901
D. Sulas‐Kern, S. Johnston, Michael Owen‐Bellini, K. Terwilliger, J. Meydbray, Laura Spinella, Archana Sinha, L. Schelhas, D. Jordan
Fast, non-destructive, outdoor-compatible methods for photovoltaic module characterization are essential for monitoring module quality without disrupting energy production. UV-fluorescence (UVF) imaging of the encapsulant layer can be used for solar cell crack detection in the field. We show that UVF patterns vary widely between modules and types of applied stress. We propose that combining accelerated stress testing (e.g. thermal cycling and damp heat) with field investigations can help build understanding of different types of UVF and the rates of UVF formation and quenching. Ultimately, further understanding could enable estimating the age and propagation rates of cracks.
快速、非破坏性、室外兼容的光伏组件表征方法对于在不中断能源生产的情况下监测组件质量至关重要。封装层的紫外荧光(UVF)成像可用于太阳能电池的现场裂纹检测。我们表明,UVF模式在模块和应用应力类型之间差异很大。我们建议将加速应力测试(例如热循环和湿热)与现场调查相结合,可以帮助建立对不同类型UVF以及UVF形成和猝灭速率的理解。最终,进一步的了解可以估计裂纹的年龄和扩展速率。
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引用次数: 5
First Principles assisted modeling to understand Chlorine passivation of CdTe grain boundary 第一性原理帮助建模来理解镉镉晶界的氯钝化
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300548
Akash Shah, A. Nicholson, A. Thiyagarajan, W. Sampath
A computational study on cadmium telluride (CdTe) (111)/(220) grain boundary was performed using a first-principles approach. Cadmium chloride (CdCl2) treatment of CdTe based solar cells has proven to be highly beneficial for device performance. Published literature suggests incorporation of chlorine at Te site (ClTe) in CdTe grain boundaries. Density Functional Theory was therefore used to identify the mechanisms responsible for enhancing CdTe device performance after CdCl2 treatment. The computational model explains the formation of local p-n-p junctions through field effect passivation after inclusion of ClTe, which significantly improves CdTe device performance by mitigating recombination at the interface.
采用第一性原理方法对碲化镉(CdTe)(111)/(220)晶界进行了计算研究。CdTe基太阳能电池的氯化镉(CdCl2)处理已被证明对器件性能非常有益。已发表的文献表明在CdTe晶界的Te位点(ClTe)有氯的掺入。因此,密度泛函理论被用于确定CdCl2处理后CdTe器件性能增强的机制。计算模型解释了加入ClTe后通过场效应钝化形成局部p-n-p结,通过减轻界面处的复合,显著提高了CdTe器件的性能。
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引用次数: 0
Towards Validation of Advanced Accelerated Stress Testing Protocols through Failure Analysis and Materials Characterization 通过失效分析和材料表征来验证先进的加速应力测试方案
Pub Date : 2020-06-14 DOI: 10.1109/pvsc45281.2020.9301012
L. Schelhas, Michael Owen‐Bellini, S. Moffitt, Ashley M. Maes, James Y. Hartley, Todd Karin, Donald R. Jenket, Archana Sinha, J. Tracy, David C. Miller, P. Hacke
As the lifetime of photovoltaic modules increases toward the goal of 50 years, accelerated stress testing is critical to assessing the viability of newer, improved, and often cheaper materials in the field. However, the validation of accelerated testing to reproduce field failure has remained elusive. The recent developments of more advanced stress testing protocols utilizing sequential and combined stressors have provided another opportunity for validation. Using a suite of mechanical, chemical, and structural characterization methods we report the development of our approach using a known bad backsheet “AAA.” We then apply this approach to PVDF-based backsheets to further confirm the generalizability of this approach. The outcome of this work is two-fold: (1) validation of advanced accelerated testing protocols which will enable the prediction of field failures in new materials, and (2) deeper insights into the degradation mechanisms observed through the extensive characterization allowing for improved materials engineering and development.
随着光伏组件的寿命向50年的目标增长,加速压力测试对于评估该领域更新,改进和通常更便宜的材料的可行性至关重要。然而,加速测试重现现场故障的有效性仍然难以捉摸。最近更先进的压力测试协议的发展利用顺序和组合压力源提供了另一个验证的机会。使用一套机械、化学和结构表征方法,我们报告了使用已知坏背板“AAA”的方法的发展。然后,我们将该方法应用于基于pvdf的背板,以进一步确认该方法的通用性。这项工作的结果是双重的:(1)验证先进的加速测试协议,这将使新材料的现场故障预测成为可能;(2)通过广泛的表征来深入了解降解机制,从而改进材料工程和开发。
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引用次数: 1
Correlation of grid-frequency, electricity prices, share of renewable, and CO2—contents in the German electricity grid to enable inexpensive triggering of Demand—Side—Management 德国电网中电网频率、电价、可再生能源份额和二氧化碳含量的相关性,以实现低成本触发需求侧管理
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300487
S. Krauter, Lin Zhang
Due to the present inflexibility and the lack of sufficient throttling capabilities of lignite and nuclear power plants, a surplus of electricity generation occurs during periods of high wind and solar power generation in the German electricity grid. While the specific CO2-emission is decreasing then – due to the increased share of Renewables, the grid frequency should be increasing (to a certain limit). Using the grid frequency as an indicator to switch–on and –off certain loads (loads that do not require power permanently (e.g. dishwashers, washing machines, dryers, fridges and freezers, heaters) could provide a simple, inexpensive demand-side-management indicator to lower specific CO2-emssions and costs (if a dynamic consumption tariff is applied). To check the truthfulness of that hypothesis, the grid and frequency data of the German grid of the year 2018 have been collected and the correlations between grid frequency, share of renewables, CO2-contents, and actual price at the European energy exchange (EEX) have been calculated. The results show: Correlation between grid frequency and the share of renewables is quite low ($r=0.155$) due to the fact that primary grid control quickly compensates deviations from the 50 Hz nominal frequency. As expected, there is a good anti–correlation $(r=-0.687)$ between the EEX–prices and the share of renewables in the grid. Over the years, correlation between electricity trading prices (EEX) and CO2 emissions is quite good ($r=0.665$), within the one year (2018) that correlation almost doesn't exist, possibly due to the inflexibility of the bulky lignite baseload power plants that even operate at negative prices.
由于目前褐煤电厂和核电厂的不灵活性和缺乏足够的节流能力,德国电网在风能和太阳能发电高的时期会出现发电过剩。由于可再生能源份额的增加,具体的二氧化碳排放量正在减少,而电网频率应该增加(到一定限度)。使用电网频率作为打开和关闭某些负载(不需要永久电力的负载(例如洗碗机、洗衣机、烘干机、冰箱和冰柜、加热器)的指标,可以提供一个简单、廉价的需求侧管理指标,以降低特定的二氧化碳排放和成本(如果采用动态消费关税)。为了验证这一假设的真实性,我们收集了2018年德国电网的电网和频率数据,并计算了电网频率、可再生能源份额、二氧化碳含量和欧洲能源交易所(EEX)实际价格之间的相关性。结果表明:电网频率与可再生能源份额之间的相关性相当低(r=0.155),因为主电网控制迅速补偿了50 Hz标称频率的偏差。正如预期的那样,eex价格与可再生能源在电网中的份额之间存在良好的反相关性(r=-0.687)。多年来,电力交易价格(EEX)与二氧化碳排放之间的相关性相当好($r=0.665$),在一年内(2018年),这种相关性几乎不存在,可能是由于大型褐煤基载发电厂缺乏灵活性,甚至以负价格运行。
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引用次数: 0
Interfacial Characterization of Positive Bias Voltage Degradation in PV Modules 光伏组件中正偏置电压退化的界面表征
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300934
Archana Sinha, S. Moffitt, K. Hurst, Jiadong Qian, David C. Miller, P. Hacke, L. Schelhas
Degradation from high system voltage is a prevailing failure mode in fielded photovoltaic modules, and the degradation mechanism is inherently dependent on the bias polarity. Here we report the effects of positive bias. Modules under positive bias demonstrated a significant photocurrent loss caused by two routes. First, delamination and discoloration of the silicon nitride layer, leading to optical loss determined by reflectance measurements. Second, chemical discoloration of the cell gridlines and encapsulant (EVA), which is linked to an electrochemical reaction at the silver electrodes. Chemical compositional analysis using X-ray photoemission spectroscopy demonstrated that the discoloration is attributed to Ag2S and/or Ag2O. Evidence of Ag ion migration from the cell grid into the encapsulant is observed after shallow depth profiling on the EVA surface. However, Ag was not detected at the EVA/glass interface, inferring limited Ag ion transport through the EVA. The source of sulfur is believed to be ambient air, which diffused into the module through the breathable backsheet.
高系统电压导致的退化是光伏组件的主要失效模式,其退化机制本质上依赖于偏置极性。在这里,我们报告了正偏倚的影响。在正偏置下的模块显示出由两条路径引起的显著光电流损耗。首先,氮化硅层的分层和变色,导致通过反射率测量确定的光学损耗。其次,电池网格线和封装剂(EVA)的化学变色,这与银电极上的电化学反应有关。x射线光发射光谱分析表明,变色是由Ag2S和/或Ag2O引起的。在EVA表面的浅深度剖面上观察到Ag离子从细胞网格迁移到封装剂的证据。然而,在EVA/玻璃界面未检测到Ag,推断通过EVA的Ag离子传输有限。硫的来源被认为是周围的空气,它通过可呼吸的背板扩散到模块中。
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引用次数: 1
An Asian case study on the effectiveness of a storytelling approach on solar PV career aspirations of preadolescent students 亚洲案例研究:讲故事方法对青春期前学生太阳能光伏事业抱负的有效性
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300925
S. Tay
With increased global activity in solar photovoltaic research, manufacturing and deployment, a corresponding increase in professionals is needed, especially in Asia where most of the growth is. Hence, it is crucial to engage students to instill interest and future participation in the industry. This study explores the efficacy of a story-telling approach as an educational method to instill interest. An entire preadolescent Primary 6 cohort of 218 students in a local primary school was engaged. It was found that there was a statistical significance (p-value < 0.05) in the efficacy of the story-telling approach.
随着全球太阳能光伏研究、制造和部署活动的增加,需要相应增加专业人员,特别是在增长最快的亚洲。因此,培养学生对行业的兴趣和未来参与至关重要。本研究探讨了讲故事作为一种灌输兴趣的教育方法的功效。本研究以当地一所小学的218名学龄前小学生为研究对象。结果发现,讲故事方法的疗效差异有统计学意义(p值< 0.05)。
{"title":"An Asian case study on the effectiveness of a storytelling approach on solar PV career aspirations of preadolescent students","authors":"S. Tay","doi":"10.1109/PVSC45281.2020.9300925","DOIUrl":"https://doi.org/10.1109/PVSC45281.2020.9300925","url":null,"abstract":"With increased global activity in solar photovoltaic research, manufacturing and deployment, a corresponding increase in professionals is needed, especially in Asia where most of the growth is. Hence, it is crucial to engage students to instill interest and future participation in the industry. This study explores the efficacy of a story-telling approach as an educational method to instill interest. An entire preadolescent Primary 6 cohort of 218 students in a local primary school was engaged. It was found that there was a statistical significance (p-value < 0.05) in the efficacy of the story-telling approach.","PeriodicalId":6773,"journal":{"name":"2020 47th IEEE Photovoltaic Specialists Conference (PVSC)","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86692664","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Energy Production by Solar Tracking/ Anti-tracking Combined with Wind Turbine 太阳能跟踪/反跟踪与风力发电相结合的能源生产
Pub Date : 2020-06-14 DOI: 10.1109/PVSC45281.2020.9300691
S. Mil'shtein, D. Asthana, J. Scheminger, S. Hummer
The efficient operation of companies distributing electricity is characterized by stable control of power in a grid. Integration of clean energy producers such as solar cells and wind turbine farms significantly complicate the mitigation of intermittent generation. Lengths of a sunny day, appearance/ disappearance of sun in clouds, changing speed and direction of wind complicate significantly the control of load stability in the grid. In current study, we describe a mini scale, I kW system comprising of solar panels and wind turbine. The uniqueness of our design consists of solar panels equipped with capability of tracking/ anti-tracking the position and the amount of energy coming from the sun, our system will increase the duration of the sunny day by 30% regardless of geographical location. On MWatt commercial wind turbines, tracking/anti-tracking could be done by changing angle of attack of blades. The most important factor in our design is programmable control algorithm synchronizing simultaneous production of energy by both components of the system especially during extremely windy conditions. The major commands for control of the combined clean energy system would be provided by the operator of the grid system. We will discuss design of unified solar/wind system integrated with grid, where programmable tracking/anti-tracking control is used.
电网中电力的稳定控制是配电网公司高效运行的特征。太阳能电池和风力涡轮机农场等清洁能源生产商的整合,使缓解间歇性发电的问题大大复杂化。晴天的长度、云层中太阳的出现/消失、风速和风向的变化使电网负荷稳定性的控制显著复杂化。在目前的研究中,我们描述了一个由太阳能电池板和风力涡轮机组成的小型,1千瓦的系统。我们设计的独特之处在于太阳能电池板配备了跟踪/反跟踪位置和来自太阳的能量的能力,我们的系统将增加30%的晴天持续时间,无论地理位置如何。在兆瓦商用风力涡轮机上,跟踪/反跟踪可以通过改变叶片的迎角来实现。我们设计中最重要的因素是可编程控制算法,使系统的两个组件同步产生能量,特别是在极端多风的条件下。联合清洁能源系统的主要控制指令将由电网系统的运营商提供。我们将讨论与电网集成的统一太阳能/风能系统的设计,其中使用可编程跟踪/反跟踪控制。
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引用次数: 1
期刊
2020 47th IEEE Photovoltaic Specialists Conference (PVSC)
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