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Assessment of thermal characteristics of Al2O3-based nanofluids in micro-fin helical coil heat exchangers 微翅片螺旋盘管换热器中al2o3基纳米流体的热特性评价
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-12 DOI: 10.1007/s10973-025-15030-w
Anand Kumar Solanki, Rabba Sivanagaraju, Yamala Muralikrishna, Nitesh Dutt, Ashwani Kumar, Anil Kumar, Ankur Jaiswal, Royal Madan

Enhancement in heat transfer can be realized by adding nanoparticles to boost the thermal properties of the base fluid, increase the tube surface area, and modify the flow trajectory of the fluid. In the present investigation, the convective heat transfer and pressure loss characteristics of Al2O3-Ethylene glycol and Al2O3-Water-based nanofluid in the vertically positioned helically coiled tube with micro-fin are studied by ANSYS FLUENT 19.2 through numerical methods. The effects of nanofluid mass fraction (1–4%), Reynolds number changing (10,000–30,000), micro-fin number (4–12), and the coil diameter (100–200 mm) on the heat transfer coefficient and pressure drop characteristics are carried out. The heat transfer and pressure drop characteristics are found to be highly sensitive to changes in Reynolds number and nanoparticle volume concentration. Furthermore, an increase in micro-fin density contributes to elevated heat transfer coefficients and higher pressure losses in nanofluid. The study confirms that the thermal performance index of Al2O3-Ethylene glycol nanofluid is universally lower than that of Al2O3-Water nanofluid across all nanofluid mass fraction.

通过添加纳米颗粒来提高基液的热性能,增加管的表面积,改变流体的流动轨迹,可以实现强化传热。本文利用ANSYS FLUENT 19.2软件,通过数值方法研究了al2o3 -乙二醇和al2o3 -水基纳米流体在垂直定位螺旋盘绕管内的对流换热和压力损失特性。研究了纳米流体质量分数(1 ~ 4%)、雷诺数变化(10000 ~ 30000)、微翅片数(4 ~ 12)、盘管直径(100 ~ 200mm)对换热系数和压降特性的影响。传热和压降特性对雷诺数和纳米颗粒体积浓度的变化高度敏感。此外,微鳍密度的增加有助于提高纳米流体的传热系数和压力损失。研究证实,在所有纳米流体质量分数中,al2o3 -乙二醇纳米流体的热性能指标普遍低于al2o3 -水纳米流体。
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引用次数: 0
Hybrid numerical evaluation of thermo-hydraulic and exergetic behaviour in solar air heaters with advanced arc rib architectures 先进弧形肋结构太阳能空气加热器热液和火用性能的混合数值评价
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-12 DOI: 10.1007/s10973-025-15035-5
Jagadeshwar Kandula, S. K. Gugulothu, Raju Muthyala, G. Sailaja

Enhancing the heat transfer efficiency of solar air heaters (SAHs) remains a critical challenge in renewable energy applications due to the inherently poor convective characteristics of air. Improving the absorber plate design through optimized roughness geometry is therefore essential for achieving higher energy conversion efficiency. Despite numerous studies on conventional rib geometries, limited attention has been paid to the comparative thermo-hydraulic behaviour of fixed and variable arc rib configurations under identical boundary conditions. This study numerically investigates the thermal and fluid flow performance of SAHs equipped with three arc rib geometries: Fixed Arc Rib (FAR), Fixed Arc Rib with Diameter variation (FARD), and Variable Arc Rib (VAR) over two duct lengths (1 m and 2 m). Simulations were performed using the RNG kε turbulence model under a uniform heat flux of 1000 W m−2 and Reynolds numbers ranging from 3000 to 21000. The results reveal that the VAR(1 m) configuration achieves the highest thermal efficiency (93.2%) and exergy efficiency (2.65), while FARD(1 m) exhibits the best thermo-hydraulic performance parameter (THPP ≈ 6.1). Velocity contour analysis further confirms enhanced mixing and turbulence intensity for variable rib geometries. The findings offer practical design guidance for developing compact and energy-efficient solar air heaters suitable for sustainable heat recovery systems.

由于空气固有的对流特性较差,提高太阳能空气加热器(SAHs)的传热效率仍然是可再生能源应用中的一个关键挑战。因此,通过优化粗糙度几何来改进吸收板设计对于实现更高的能量转换效率至关重要。尽管对传统的肋形几何进行了大量的研究,但在相同的边界条件下,固定和可变弧肋结构的热水力特性的比较研究却很少。本研究数值研究了三种弧形肋的SAHs的热和流体流动性能:固定弧形肋(FAR),直径变化的固定弧形肋(FARD)和可变弧形肋(VAR),两种管道长度(1米和2米)。采用RNG k -ε湍流模型,在均匀热流密度为1000 W m−2,雷诺数为3000 ~ 21000的条件下进行了模拟。结果表明,VAR(1 m)配置的热效率最高(93.2%),火用效率最高(2.65),而FARD(1 m)配置的热工性能参数最佳(THPP≈6.1)。速度轮廓分析进一步证实了可变肋条几何形状增强了混合和湍流强度。研究结果为开发适用于可持续热回收系统的紧凑型节能太阳能空气加热器提供了实用的设计指导。
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引用次数: 0
Modeling, evaluation and optimization of post-harvest processing of ivy gourd using eco-friendly solar technique 绿色太阳能冬瓜采后加工的建模、评价与优化
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-12 DOI: 10.1007/s10973-025-14969-0
Karthikeyan Subramanian, Raghavan Ashwin, S. Murugapoopathi, N. Poyyamozhi

The study is concerned with the optimization of performance of solar drying to be carried out on ivy gourd (Coccinia grandis) making use of indirect convection-based technologies. The results of three systems of dryer such as indirect solar dryer (ISD), mixed-type solar dryer (MSD) and greenhouse solar dryer (GSD) were compared based on drying kinetics, product quality, nutrient retention and energy consumption. The effect of four important parameters such as drying temperature, drying time, air velocity and type of dryer used was studied using response surface methodology (RSM). The experimental analysis indicated that the rate of drying was very much enhanced with variation of temperature and the air velocity, the value being high (19.7 g h–1) in the mixed-type dryer. A maximum of nutrient retention (86.2) was achieved at the moderate temperatures and low drying times, more so when the application of energy efficiency with consideration of designs in dryers was adopted. Nonetheless, the increased temperature of drying and an increased time had significant knock-off effects on the heat-sensitive nutrients. The difference in energy consumption across conditions was quite large with a high of 15.7 kWh attained at the maximum parameter level. The paper presents essential trade-offs between the consumption of energy and the quality of products. The indirect dryer exhibited a high degree of energy efficiency, and the mixed-type dryer provided relatively high rates of drying with tolerable loss of quality. The greenhouse dryer demonstrated a well-balanced ratio in the quality and sustainability indicators. RSM integrations enabled determination of the best drying conditions, which at the same time consumed minimal energy and preserved maximum nutrients. The study has added a strong framework in the designing and operation of solar drying systems that address various agro-processing requirements, a sustainable, energy-efficient and quality food preservation at post-harvesting.

研究了利用间接对流技术对常青藤葫芦(Coccinia grandis)进行太阳能干燥的性能优化。对间接太阳能干燥机(ISD)、混合型太阳能干燥机(MSD)和温室太阳能干燥机(GSD) 3种干燥系统的干燥动力学、产品质量、营养保留和能耗进行了比较。利用响应面法(RSM)研究了干燥温度、干燥时间、风速和干燥机类型等4个重要参数对干燥效果的影响。实验分析表明,随着温度和风速的变化,干燥速率大大提高,其中混合式干燥机的干燥速率最高(19.7 g h-1)。在适宜的温度和较短的干燥时间下,获得了最大的营养保留(86.2),当采用考虑干燥器设计的节能应用时更是如此。尽管如此,干燥温度的升高和时间的延长对热敏性营养物质有显著的连锁效应。不同条件下的能耗差异相当大,在最大参数水平下达到15.7千瓦时。本文提出了能源消耗和产品质量之间的基本权衡。间接干燥机表现出高度的能源效率,而混合型干燥机提供了相对较高的干燥率和可容忍的质量损失。温室干燥机在质量和可持续性指标上表现出良好的平衡比例。RSM综合可以确定最佳干燥条件,同时消耗最小的能量和保留最大的营养成分。这项研究为太阳能干燥系统的设计和操作增加了一个强有力的框架,解决了各种农业加工要求,以及收获后可持续、节能和高质量的食品保存。
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引用次数: 0
Experimental study on the suppression of surface fire spread of leaf litter in forested areas of southwestern China by different extinguishing agent barrier strips in indoor environment 不同灭火剂屏障条室内环境对西南林区凋落叶地表火蔓延的抑制实验研究
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-12 DOI: 10.1007/s10973-025-15068-w
Zhangyin Dai, Congbao Huang, Youcheng Chen, Manyin Zhong

Forest fires mainly come from the surface fuel layer, and the key to reducing the risk of forest fires is to block the spread of surface fires. Due to the complexity of the terrain environment, it is difficult to achieve efficient and rapid fire prevention by conventional physical means, which increases the difficulty and cost of forest fire prevention and control. Therefore, it is imperative to find a suitable, effective and clean extinguishing agent. In this paper, the inhibition test of fire extinguishing agent isolation zone in indoor environment was carried out on the spread of surface litter fire in the area with frequent forest fires in Southwest China. Three different fire extinguishing media, water, foam fire extinguishing agent and hydrogel fire extinguishing agent, are used. The results show that the different extinguishing media are able to suppress flame spread of mixed leaf litter combustion and the phenomenon of flying fire. However, as the slope increases, water and foam extinguishing agents cannot completely inhibit the spread of foliage litter flames, and during the period of inhibition by these two extinguishing media, when fuel flames are prone to spreading and burning across the containment zone, hydrogel is effective in inhibiting the spread of foliage litter flames. Comparing the peak temperature of TC1 before isolation zone and the peak temperature of TC5 after isolation zone, the reduction is about 70 °C, 176 °C and 208 °C in the three extinguishing media conditions, respectively. And the cooling effect of hydrogel is the best compared with water and foam extinguishing agent. Based on the results of different widths of hydrogel barrier inhibiting the spread of leaf litter at different slopes, the relationship model between the intensity of surface fire spread at different slopes and the width of hydrogel barrier is constructed, and the boundary conditions of the hydrogel barrier inhibiting the spread of surface fire in leaf litter are determined, which is of great significance for the design of forest fire fighting systems.

森林火灾主要来源于地表燃料层,降低森林火灾风险的关键是阻断地表火灾的蔓延。由于地形环境的复杂性,常规的物理手段难以实现高效、快速的防火,增加了森林防火的难度和成本。因此,寻找一种合适、有效、清洁的灭火剂势在必行。本文在西南森林火灾多发地区进行了室内环境中灭火剂隔离区对地表凋落物火灾蔓延的抑制试验。使用三种不同的灭火剂:水、泡沫灭火剂和水凝胶灭火剂。结果表明,不同灭火剂均能抑制混合凋落叶燃烧的火焰蔓延和飞火现象。但随着坡度的增大,水灭火剂和泡沫灭火剂不能完全抑制凋落叶火焰的蔓延,在这两种灭火剂的抑制期内,当燃料火焰容易在隔离区蔓延燃烧时,水凝胶对凋落叶火焰的蔓延是有效的。对比隔离前TC1的峰值温度和隔离后TC5的峰值温度,三种灭火剂条件下分别降低了约70℃、176℃和208℃。与水和泡沫灭火剂相比,水凝胶的冷却效果最好。基于不同宽度的水凝胶屏障抑制不同坡度凋落叶蔓延的结果,构建了不同坡度地表火灾蔓延强度与水凝胶屏障宽度的关系模型,确定了水凝胶屏障抑制凋落叶中地表火灾蔓延的边界条件,这对森林灭火系统的设计具有重要意义。
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引用次数: 0
Computational study of MHD tri-hybrid (left( {Al_{2} O_{3} + CuO + TiO_{2} } right)/H_{2} O) nanofluid flow between disk and cone with the effect of thermal radiation 考虑热辐射影响的MHD三混合(left( {Al_{2} O_{3} + CuO + TiO_{2} } right)/H_{2} O)纳米流体盘锥间流动的计算研究
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-14864-8
Amjid Rashid, Zehba Raizah, Fuad S. Alduais, Afrah Al-Bossly, Tenglong Cong

Scholars are interested in the significance of this study, which looks at a transportation phenomenon where the host fluid is fully mixed with three different types of nanoparticles (ternary hybrid nanofluid). Tri-hybrid nanofluid's (THNF) special capacity to enhance thermal performance is the main driver of its growing popularity, as it is highly beneficial in a variety of heat exchangers. In order to observe the fluid heat presentation, the primary goal of this research is to analyze the Incompressible, unsteady, laminar 3D magnetohydrodynamics (MHD) ternary hybrid flow with the model of heat flux and viscous dissipation of nanofluid between two surfaces. This method for succeeding a well heat conductor than hybrid nanofluid (HNF), and mono nanofluid is described by this model. Three different kinds of nanoparticles with unique chemical and physical bonds are added to water as a base liquid to create the ternary nanofluid. This mixture aids in environmental cleaning, the breakdown of harmful materials, and the cooling of other devices. At z = 0, the lower disk remains fixed the top disk moves axially, while causing the liquid to squeeze. A homogenous suction or injection is applied at the lower surface. At the fixed bottom disk, the effects of energy and velocity slip are also taken into account. The governing equations are transformed into nonlinear ordinary differential equations (ODEs) by applying the proper similarity functions, and the bvp4c approach is then used to solve them numerically in the MATLAB environment. The results are then graphically shown to examine the velocity, temperature and concentration profiles. Finally, we determine that the thermal conductivity of tri-hybrid nanoparticles is well as compare to hybrid and nanofluids particles since the temperature profile reduced against the tri-hybrid case in the bottom disk case and subsequently increased near the top disk in the tri-hybrid case. For a small number of examples, the current findings are shown to be in good agreement with existing literature.

学者们对这项研究的意义感兴趣,该研究着眼于宿主流体与三种不同类型的纳米颗粒(三元混合纳米流体)充分混合的运输现象。三混合纳米流体(THNF)提高热性能的特殊能力是其日益普及的主要驱动力,因为它在各种热交换器中都非常有益。为了观察流体的热表现,本研究的主要目标是分析不可压缩、非定常、层流三维磁流体力学(MHD)三元混合流动,并采用纳米流体在两表面之间的热流通量和粘性耗散模型。该模型描述了该方法比混合纳米流体(HNF)和单纳米流体获得更好的导热体。三种不同的纳米粒子具有独特的化学和物理键,被添加到水中作为基础液体,形成三元纳米流体。这种混合物有助于环境清洁,有害物质的分解和其他设备的冷却。在z = 0时,下盘保持固定,上盘轴向移动,同时导致液体挤压。在较低的表面进行均匀的吸力或注射。在固定底盘处,还考虑了能量滑移和速度滑移的影响。采用适当的相似函数将控制方程转化为非线性常微分方程,并利用bvp4c方法在MATLAB环境下进行数值求解。然后用图形显示结果,以检查速度、温度和浓度分布。最后,我们确定三杂化纳米颗粒的导热性与杂化和纳米流体颗粒相比良好,因为在底部圆盘情况下,三杂化纳米颗粒的温度分布降低,随后在三杂化情况下,在顶部圆盘附近增加。对于少数例子,目前的研究结果显示与现有文献很好地一致。
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引用次数: 0
Properties and crystallization behaviors of polyethylene terephthalate nucleated with compound nucleating agents based on talc and carboxylates 基于滑石和羧酸盐的复合成核剂成核聚对苯二甲酸乙二醇酯的性能和结晶行为
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-15067-x
Zhengyu Hu, Yaqiong Zhao, Meijiao Yuan, Ting Huang, Yue-Fei Zhang

To improve the slow crystallization and difficult processing issues of polyethylene terephthalate (PET) and enhance its mechanical properties, we prepared a nucleating agent composed of sodium linoleate and talc, studied the synergistic effects of both individual and composite components on properties of PET, and established that the optimal talc to sodium linoleate ratio is 1:1. The sodium carboxylate component serves as the primary active agent governing PET crystallization. The synergistic action of both can lower the crystal grain size during PET crystallization, resulting in a 13–23% enhancement in flexural modulus. Based on the findings, we prepared five alternative compound nucleating agents (CNAs) made from sodium carboxylate and talc. Among them, the crystallization performance and mechanical properties of PET nucleated with the CNA in which the mass ratio of sodium linoleate to talc is 1:1 exhibited the most significant enhancement compared with pure PET, surpassing the performance improvement observed in PET nucleated with the commercial nucleating agent P250. The findings indicate that the nucleating agents developed in this work demonstrate significant potential to substitute commercial nucleating agents, reducing production costs, enhancing PET characteristics, and facilitating industrial manufacturing.

为改善聚对苯二甲酸乙二醇酯(PET)结晶慢、加工难的问题,提高PET的力学性能,制备了由亚油酸钠和滑石组成的成核剂,研究了单组分和复合组分对PET性能的协同作用,确定了滑石与亚油酸钠的最佳配比为1:1。羧酸钠组分是控制PET结晶的主要活性剂。两者的协同作用可以降低PET结晶过程中的晶粒尺寸,使其弯曲模量提高13-23%。在此基础上,以羧酸钠和滑石为原料制备了5种可替代的复合成核剂(CNAs)。其中,亚油酸钠与滑石粉质量比为1:1的CNA成核PET的结晶性能和力学性能较纯PET有最显著的提高,超过了用市售成核剂P250成核PET的性能提高。研究结果表明,本研究开发的成核剂在替代商业成核剂、降低生产成本、提高PET性能和促进工业制造方面具有很大的潜力。
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引用次数: 0
Artificial neural network modeling for multi-parameter performance prediction of electronically commutated fan coils based on experimental data 基于实验数据的电子换向风机盘管多参数性能预测的人工神经网络建模
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-15007-9
Burak Uguz, Andaç Batur Çolak, Yakup Karakoyun, Zafer Gemici, Ahmet Selim Dalkilic

The main problems with the selection and operation of fan coils in air conditioning systems impact thermal comfort and energy efficiency, and research on fan coil performance at various operating points is inadequate. No research on artificial neural networks has been undertaken about a concealed ceiling-type electronically commutated motor fan coil that has been subjected to extensive experimental assessments. Four artificial neural networks were trained using 1700 test points to predict the thermal performance and capacity as a main aim. The experiments were conducted in a test apparatus designed according to related standards and an indoor air and heat exchanger fluid regime based on international test norms. The first model estimated air flowrate using six input parameters. The second one estimated air outlet temperature and total cooling capacity using five input parameters. Then, the third one estimated heat exchanger fluid side pressure loss using five input parameters. Lastly, the fourth one estimated air outlet temperature, fan power, and total cooling capacity using eight-input parameters. The Levenberg–Marquardt training algorithm was employed in the feedforward backpropagation multilayer perceptron network model comprising 10 neurons in the hidden layer. The deviation obtained for the air flowrate was  − 0.255% in the first one, while the deviations obtained for the air outlet temperature and cooling capacity were  − 0.195,  − 0.012%, respectively, in the second one. In the third one, the fluid pressure loss exhibited a deviation of − 0.014%. In contrast, the air outlet temperature, cooling capacity, and fan power exhibited deviations of + 0.045, − 0.014, and + 0.283%, respectively, in the fourth one. This study promotes energy-efficient industries using artificial intelligence-driven performance modeling as a collaboration sample between university and industry.

风机盘管在空调系统中的选型和运行主要存在影响热舒适和能效的问题,对风机盘管在各工况下的性能研究不足。隐顶式电子换向电机风机盘管的人工神经网络研究尚未开展,但已进行了大量的实验评估。利用1700个测试点训练4个人工神经网络,以预测热工性能和热容为主要目标。实验采用按照相关标准设计的试验设备和基于国际试验规范的室内空气和热交换器流体制度进行。第一个模型使用六个输入参数估计空气流量。第二种方法使用五个输入参数估计出风口温度和总制冷量。然后,利用5个输入参数估计换热器流体侧压力损失。最后,第四种方法使用8个输入参数来估计出风口温度、风扇功率和总制冷量。将Levenberg-Marquardt训练算法应用于隐层包含10个神经元的前馈反向传播多层感知器网络模型。第一个模型的空气流量偏差为- 0.255%,第二个模型的出口温度偏差为- 0.195,制冷量偏差为- 0.012%。在第三个模型中,流体压力损失的偏差为- 0.014%。而在第4个模型中,出风口温度、制冷量和风机功率的偏差分别为+ 0.045、−0.014和+ 0.283%。本研究使用人工智能驱动的绩效建模作为大学和工业之间的合作样本来促进节能产业。
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引用次数: 0
Analysis of PV-NEPCM systems by using different nanoparticles: effects of inclination angles 不同纳米颗粒对PV-NEPCM体系的影响
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-15024-8
K. S. Unnikrishnan, Rohinikumar Bandaru

This paper deals with the two-dimensional numerical modelling and dynamic simulation of photovoltaic (PV) module attached with phase change material (PCM) loaded with different nanoparticles (to form PV-NEPCMs) operating at various inclinations ((theta)) for thermal regulation. The study investigates PV-NEPCM systems using n-octadecane PCM loaded with titanium dioxide (TiO2), copper (Cu), and cupric oxide (CuO) nanoparticles at a mass concentration of 3%. The inclination angles considered are 0°, 15°, 30°, and 45°. Additionally, the effect of varying Cu nanoparticle mass concentrations (0%, 3%, and 5%) is analysed. The findings show that loading of nanoparticles in PCM improves rate of heat transfer and effective thermal conductivity. Out of three NEPCMs studied, Cu nanoparticles are able to give the lowest average PV temperature. The maximum PV temperature reduction of 1.67 °C compared to the conventional PV-PCM system is obtained for PV-NEPCM loaded with Cu nanoparticles at 0° inclination, and the relative impact of NEPCM diminishes with the increase in inclination. It is also found that the mean velocity magnitudes of melted NEPCMs are lower than pure PCM at all inclinations, indicating a decrease in strength of the convection current in NEPCMs. The PV power output rose from 18.6 W in the PCM system to 18.82 W in the Cu-loaded NEPCM system at an inclination of 0°. The study also investigates the effect of varying Cu nanoparticle mass concentration in NEPCM on PV temperature. The greatest PV temperature reductions of 2.37 °C at 0° and 1.03 °C at 45° are observed compared to the conventional PV-PCM system.

本文研究了光伏(PV)组件的二维数值模拟和动态模拟,光伏(PV)组件与装载不同纳米颗粒(形成PV- nepcm)的相变材料(PCM)在不同倾角下运行以进行热调节((theta))。该研究使用负载二氧化钛(TiO2)、铜(Cu)和氧化铜(CuO)纳米颗粒的正十八烷PCM,在质量浓度为3的情况下对PV-NEPCM系统进行了研究%. The inclination angles considered are 0°, 15°, 30°, and 45°. Additionally, the effect of varying Cu nanoparticle mass concentrations (0%, 3%, and 5%) is analysed. The findings show that loading of nanoparticles in PCM improves rate of heat transfer and effective thermal conductivity. Out of three NEPCMs studied, Cu nanoparticles are able to give the lowest average PV temperature. The maximum PV temperature reduction of 1.67 °C compared to the conventional PV-PCM system is obtained for PV-NEPCM loaded with Cu nanoparticles at 0° inclination, and the relative impact of NEPCM diminishes with the increase in inclination. It is also found that the mean velocity magnitudes of melted NEPCMs are lower than pure PCM at all inclinations, indicating a decrease in strength of the convection current in NEPCMs. The PV power output rose from 18.6 W in the PCM system to 18.82 W in the Cu-loaded NEPCM system at an inclination of 0°. The study also investigates the effect of varying Cu nanoparticle mass concentration in NEPCM on PV temperature. The greatest PV temperature reductions of 2.37 °C at 0° and 1.03 °C at 45° are observed compared to the conventional PV-PCM system.
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引用次数: 0
Stabilizers for Nitrocellulose-Based Propellants: Insights from Compatibility and Thermal Stability 硝化纤维基推进剂的稳定剂:从相容性和热稳定性的见解
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-15044-4
Siti Nor Ain Rusly, Siti Hasnawati Jamal, Alinda Samsuri, Siti Aminah Mohd Noor, Nur Shazwani Abdul Latif, Khoirul Solehah Abdul Rahim

Nitrocellulose (NC)-based propellants are reactive solid materials and inherent instability. These propellants undergo chemical and physical changes upon aging, which can reduce their stability and potentially leading to safety issues. Ensuring the stability of NC-based propellants is crucial for safe and efficient operation within propulsion system. To mitigate this issue, stabilizers are incorporated into propellant formulations to improve the stability performance by slowing down autocatalytic reactions so that the safe storage life of propellant can be extended. Recently, the progress in the application of stabilizers in NC-based propellants has garnered extensive attention due to the necessity to enhance stability performances and prolong shelf life of propellants. This review examines various stabilizers utilized in NC-based propellant formulations, elucidating their mechanisms of action, thermal behavior, and compatibility with NC. Through comparative analysis, the advantages and limitations of both conventional and emerging stabilizers are evaluated, with a particular focus on novel compounds demonstrating improved the thermal stability and compatibility with NC. Additionally, the methods used for evaluating the stability performances of NC-based propellants are discussed, focusing on the compatibility and thermal behavior of stabilized NC. The challenges and future directions are identified, paving the way for further advancements in propellant stability. Overall, this review aims to provide a comprehensive understanding of the effect of stabilizer in improving the stability of NC-based propellant, thereby contributing to the development of safer and highly efficient propellants.

硝基推进剂是一种反应性固体材料,具有固有的不稳定性。这些推进剂在老化过程中会发生化学和物理变化,这会降低它们的稳定性,并可能导致安全问题。确保核基推进剂的稳定性对推进系统的安全高效运行至关重要。为了缓解这一问题,在推进剂配方中加入稳定剂,通过减缓自催化反应来提高稳定性,从而延长推进剂的安全储存寿命。近年来,为了提高推进剂的稳定性能和延长推进剂的保质期,稳定剂在纳米基推进剂中的应用得到了广泛的关注。本文综述了各种稳定剂在基于NC的推进剂配方中使用,阐明了它们的作用机制、热行为以及与NC的相容性。通过对比分析,评估了传统稳定剂和新兴稳定剂的优点和局限性,特别关注了新型化合物,它们表现出改善的热稳定性和与NC的相容性。此外,本文还讨论了评价NC基推进剂稳定性的方法,重点讨论了稳定NC基推进剂的相容性和热性能。确定了面临的挑战和未来的方向,为进一步提高推进剂的稳定性铺平了道路。综上所述,本文旨在全面了解稳定剂在提高纳米基推进剂稳定性方面的作用,从而为开发更安全、高效的推进剂做出贡献。
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引用次数: 0
Artificial intelligence analysis of nonlinear radiative and chemically reactive Williamson nanofluid flow with motile microorganisms 动态微生物的非线性辐射和化学反应威廉森纳米流体流动的人工智能分析
IF 3.1 3区 工程技术 Q2 CHEMISTRY, ANALYTICAL Pub Date : 2025-11-11 DOI: 10.1007/s10973-025-14974-3
Imran Abbasi, Zohaib Arshad, S. AlFaify, Zahoor Shah, Waqar Azeem Khan, Taseer Muhammad

By virtue of significant thermal properties, nanofluids have much importance in medical field, pharmaceutical arrangements, electric batteries, chemical engineering areas and industrial heating and cooling processes. This study explores the changing effects of three-dimensional (3D) flow of (WNFM). Due to shear thinning feature of WNFM, this plays a vital role in chemical industries, plastic industries, oil industries, biotechnology and graphic designing. Modeled arrangement of PDEs is transfigured to arrangement of ordinary differential equations (ODEs) via similarity transformation. System of ODEs is then coded into Mathematica software. Numerical dataset is obtained by applying ND-Solve technique. Numerical dataset is then transferred into MATLAB for graphical study. Obtained system of ODEs is numerically solved by classy Levenberg–Marquardt backpropagation scheme (LMBS) joined with neural networks (NNs) of artificial intelligence (AI). Results are gauged through performance graphs under NNs of AI in LMBS. Engagement of regression illustrations (RIs), mean-squared errors (MEs) training state analysis (TSA), and histogram analysis of errors (AHEs) is considered for accuracy and convergence of results. Along temperature, concentration, bioconvection, and velocity profiles, various parameters are analyzed including Lewis number, thermophoresis parameter, Prandtl number, magnetic parameter, parameter of temperature ratio, thermal Biot number, parameter of chemical reaction, and parameter of Brownian motion. The absolute error factor ranges in the bracket of (left[{10}^{-6}-{10}^{-3}right]). This study of WNFM shows momentous associations for real-time applications.

纳米流体具有显著的热性能,在医学、制药、电池、化学工程以及工业加热和冷却过程中具有重要的应用价值。本研究探讨了(WNFM)三维流动的变化效应。由于WNFM的剪切变薄特性,它在化学工业、塑料工业、石油工业、生物技术和平面设计中发挥着至关重要的作用。通过相似变换将模型微分方程的排列转化为常微分方程的排列。然后将ode系统编码到Mathematica软件中。应用ND-Solve技术获得数值数据集。然后将数值数据集转换到MATLAB中进行图形化研究。利用经典的Levenberg-Marquardt反向传播格式(LMBS)与人工智能(AI)的神经网络(nn)相结合,对得到的ODEs系统进行了数值求解。结果通过LMBS中人工智能神经网络下的性能图来衡量。考虑了回归图(RIs)、均方误差(MEs)、训练状态分析(TSA)和误差直方图分析(ahs)的结合,以提高结果的准确性和收敛性。沿着温度、浓度、生物对流和速度等剖面,分析了路易斯数、热泳参数、普朗特数、磁性参数、温比参数、热Biot数、化学反应参数和布朗运动参数等参数。绝对误差因子的范围在(left[{10}^{-6}-{10}^{-3}right])括号内。这项关于WNFM的研究显示了与实时应用程序的重大关联。
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引用次数: 0
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Journal of Thermal Analysis and Calorimetry
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