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2021 IEEE 21st International Conference on Nanotechnology (NANO)最新文献

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Electron Transport in Trans-polyacetylene with Heterogeneous Electrodes: A DFT Study 非均相电极反式聚乙炔中的电子输运:DFT研究
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514309
K. Gaurav, A. Srivastava
The conducting polymers are the highly studied class of functional materials for their applications in the various technological field. Trans-polyacetylene is a conducting polymer having n repetitive units of $(-mathrm{C}=mathrm{C}-)_{n}$, indicating inherent conjugation in nature. In the present work, a two-probe model of pristine and defects (hybridization and torsion) induced trans-polyacetylene with the semi-infinite zigzag graphene nanoribbon (ZGNR) electrodes have been modeled and employed to analyze the transport properties, within the framework of Density Functional Theory (DFT) and Non-Equilibrium Green's Function (NEGF) formalisms. We report that the incorporation of hybridization and torsion defects decreases the drive current. Moreover, the hybridization defect has caused about 75 times reduction in the drive current at 2V, whereas both hybridization and torsion defects shows a reduction by about 21 times with respect to the pristine model. The computed transmission spectrum, transmission pathways, and molecular projected self-consistent Hamiltonian (MPSH) eigenstates, very well comprehend the degradation of drive current in the altered models.
导电聚合物是一类被广泛研究的功能材料,在各个技术领域都有广泛的应用。反式聚乙炔是一种具有n个重复单位$(- mathm {C}= mathm {C}-)_{n}$的导电聚合物,表明其性质固有共轭性。本文在密度泛函理论(DFT)和非平衡格林函数(NEGF)形式的框架下,建立了半无限之字形石墨烯纳米带(ZGNR)电极诱导的原始和缺陷(杂化和扭转)双探针模型,并利用该模型分析了其输运性质。我们报道了杂化和扭转缺陷的结合降低了驱动电流。此外,在2V时,杂化缺陷导致驱动电流降低约75倍,而杂化缺陷和扭转缺陷都显示出相对于原始模型降低约21倍。计算得到的透射谱、传输路径和分子投影自一致哈密顿(MPSH)特征态,很好地理解了改变模型中驱动电流的退化。
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引用次数: 0
2D transition metal dichalcogenides nanosheets as gate modulated cold electron emitters 作为栅极调制冷电子发射体的二维过渡金属二硫化物纳米片
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514271
F. Giubileo, E. Faella, A. Pelella, A. Grillo, M. Passacantando, A. Di Bartolomeo
We report a detailed investigation of the field emission properties of transition metal dichalcogenides, namely MoS2 and WSe2, taking advantage of an experimental setup realized inside a scanning electron microscope equipped with nano-manipulated probe-tips, used for positioning a tip-shaped anode at a nanometric distance from the emitting surface. For n-type WSe2 monolayer on Si/SiO2 substrate, we show that electrons can be extracted also from the flat part of the flake with a current intensity up to few nanoamperes. More interestingly, we demonstrate that the field emission current can be modulated by the back-gate voltage that controls the n-type doping of the WSe2 monolayer. Similarly, we demonstrate that monolayer MoS2 flakes are suitable for gate-controlled field emission devices, opening the way to the development of new field emission transistors based on ultrathin materials.
我们报告了过渡金属二硫化物,即MoS2和WSe2的场发射特性的详细研究,利用在扫描电子显微镜内实现的实验装置,配备了纳米操纵探针尖端,用于定位一个尖端形阳极在纳米距离发射表面。对于Si/SiO2衬底上的n型WSe2单层,我们发现电子也可以从薄片的平坦部分提取,电流强度高达几纳安培。更有趣的是,我们证明了场发射电流可以通过控制n型掺杂WSe2单层的后门电压来调制。同样,我们证明了单层MoS2薄片适用于栅极控制的场发射器件,为开发基于超薄材料的新型场发射晶体管开辟了道路。
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引用次数: 1
Synthesis and experimental investigation of zinc oxide and praseodymium oxide fused metal oxide nanostructures 氧化锌和氧化镨熔融金属氧化物纳米结构的合成及实验研究
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514345
Parvathy Bhaskar, M. Veena, B. S. Madhukar
This paper encapsulates the synthesis of zinc oxide (ZnO) nanoparticles with different weight percentages of praseodymium oxide (PrO2), by low-cost environmentally friendly solution combustion synthesis (SCS) method. In this procedure metal nitrates are used as oxidizer with glycine as fuel for the synthesis of nanoparticles. This procedure involves propagation of self-sustained exothermic reactions in aqueous or sol-gel media. The structural, morphological and optical properties of the prepared nanoparticles are examined by powder X-ray Diffraction (XRD), High-Resolution Transmission Electron Microscopy (HRTEM) and ultra violet visible near infra-red (UV - Vis NIR) spectroscopy. The XRD patterns of the samples confirm that the average crystalline size of the praseodymium added ZnO samples decreases from 37.32 nm to 18.776 nm, when the praseodymium content increases from 5 to 20% by weight. The HRTEM and Selected Area Electron Diffraction (SAED) data clearly show the morphology and structure of the samples. Furthermore, the UV - vis spectra validate the presence of praseodymium content in the ZnO samples.
本文采用低成本、环境友好的溶液燃烧合成(SCS)方法合成了含有不同重量百分比氧化镨(PrO2)的氧化锌(ZnO)纳米颗粒。在这个过程中,金属硝酸盐作为氧化剂与甘氨酸作为燃料合成纳米颗粒。这个过程包括在水或溶胶-凝胶介质中进行自我持续放热反应的传播。采用粉末x射线衍射(XRD)、高分辨率透射电子显微镜(HRTEM)和紫外可见近红外光谱(UV - Vis NIR)对制备的纳米颗粒的结构、形貌和光学性能进行了表征。样品的XRD谱图证实,当镨含量从重量比的5%增加到重量比的20%时,添加ZnO的镨样品的平均晶粒尺寸从37.32 nm减小到18.776 nm。HRTEM和选择区域电子衍射(SAED)数据清楚地显示了样品的形貌和结构。紫外可见光谱进一步证实了氧化锌样品中镨含量的存在。
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引用次数: 0
Exploring the Holliday Junction in a DNA nanostructure for creating excitonic dimers 探索DNA纳米结构中的假日结以创造激子二聚体
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514330
Divita Mathur, Young C. Kim, S. A. Díaz, Gregory A Ellis, P. Cunningham, S. B. Rolczynski, M. Ancona, Igor L. Medintz, J. Melinger
DNA nanostructures can perform as scaffolds to organize dye molecules into networks for a variety of applications. Such networks rely on having efficient energy-and/or electron-transport processes, and these in turn depend sensitively on the relative distance and orientation of the dye molecules. In using DNA as a scaffold, a crucial question is - to what extent can it control the dye position and orientation? The ability of DNA nanostructures to dictate the position is reasonably well addressed in the literature, but much less is known about the potential for controlling the orientation and its dependences on the local microenvironment of the DNA and on the dye attachment chemistry. Furthermore, can sites within a DNA nanostructure be used to place dyes in close proximity to create strong excitonic coupling, which, ultimately, could be useful in creating networks that use coherent energy transfer? To investigate these issues, we employ a Cy3 probe dye dimer and use both fluorescence measurements and numerical simulations to determine the degree to which a 30-helix DNA origami bundle can provide the desired excitonic coupling. Overall, the results of this work should be useful for creating DNA-scaffolded dye networks that use strong dye coupling.
DNA纳米结构可以作为支架,将染料分子组织成各种各样的网络。这种网络依赖于有效的能量和/或电子传递过程,而这些过程又敏感地取决于染料分子的相对距离和方向。在使用DNA作为支架时,一个关键的问题是——它能在多大程度上控制染料的位置和方向?DNA纳米结构决定位置的能力在文献中得到了很好的解决,但对控制取向的潜力及其对DNA局部微环境和染料附着化学的依赖性知之甚少。此外,DNA纳米结构中的位点是否可以用于将染料放置在近距离以产生强激子耦合,从而最终可以用于创建使用相干能量转移的网络?为了研究这些问题,我们采用Cy3探针染料二聚体,并使用荧光测量和数值模拟来确定30螺旋DNA折纸束可以提供所需激子耦合的程度。总的来说,这项工作的结果应该有助于创建使用强染料偶联的dna支架染料网络。
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引用次数: 1
Undoped and Fe-doped core/shell ZnS@ZnO heterostructure for photocatalytic water splitting hydrogen evolution 未掺杂和掺铁核壳ZnS@ZnO光催化水裂解析氢异质结构
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514347
S. Didarataee, A. Khodadadi, M. Mortazavi, F. Mousavi
This paper reports undoped and Fe-doped ZnS/ZnO heterostructure for photocatalytic water splitting to evolve hydrogen. Zn(1-x)FexS nanorods were first prepared by a hydrothermal method and then partially oxidized in air to incorporate ZnO in the structure. The heterostructures were characterized by XRD, BET surface area measurement, FESEM-EDS, UV-DRS, and temperature programmed oxidation (TPO). When 34wt% ZnO is incorporated into the heterostructure its bandgap decreases by 0.34 eV. It is demonstrated that by doping 3mol% Fe into the heterostructure, the hydrogen evolution increases by 41%.
本文报道了未掺杂和掺铁的ZnS/ZnO异质结构用于光催化水裂解析氢。首先采用水热法制备Zn(1-x)FexS纳米棒,然后在空气中进行部分氧化,使ZnO加入到结构中。采用XRD、BET比表面积测量、FESEM-EDS、UV-DRS和程序升温氧化(TPO)等方法对异质结构进行了表征。当在异质结构中加入34wt% ZnO时,其带隙减小了0.34 eV。结果表明,在异质结构中掺入3mol% Fe后,析氢量提高了41%。
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引用次数: 0
Ginsenoside Rg1 Nanophytosome synthesis and their characterization: An initiative towards the treatment of Amyotrophic Lateral Sclerosis 人参皂苷Rg1纳米植物体合成及其表征:肌萎缩性侧索硬化症治疗的一项倡议
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514358
N. Merchant, T. Kavya, Rachana Srinivasa, P. Rao, P. Narayanan, Savithri Bhat
Amyotrophic lateral sclerosis is a devastating neurodegenerative disease that affects the brain and spinal cord of healthy adults. The disease progresses rapidly and is fatal, leaving patients paralyzed and unable to breathe. The cause of the disease and its progression remains poorly understood. Currently, there are no known cure or effective treatment available for ALS. But with the advances in medicine and technology, there has been a huge rise in data produced. The present study is focused on synthesis and characterization of Nanophytosomes (NP) to improve the bioavailability and efficacy of Ginsenoside Rg1 compound. The nanoparticles were visualized by SEM and analyzed by Fourier Transform Infrared Spectroscopy for the type of interactions holding the components together in the NP. The size of the NP was in the range of 180 to 195nm. A comparative antimicrobial assay against strains of E.coli for NP and Ginsenoside Rg1 showed positive results for NP with increasing CFUs of E.coli while Ginsenoside Rg1 showed results only at lower CFUs of the Bacteria. Dispersion studies suggested that the NP had a maximum release rate of the drug at about 4 hours. This suggests the stability and sustained release property of the NP as compared to Ginsenoside Rgl which acts immediately on the target. Antioxidant's property of the NP was compared with Ginsenoside Rg1 by testing scavenging potential through assays such as SOD, NO and DPPH. The antioxidant activity was concentration dependent and the anti-oxidative properties of NP was found in the close range with that of Ginsenoside Rg1 compound. NP could possess antioxidative properties which could last longer than the compound alone when compared. The current technology thus could be a boon to the treatment of chronic diseases like ALS, Parkinson's Disease, AD as it improves the bioavailability and efficacy of the drug it encapsulates.
肌萎缩性侧索硬化症是一种破坏性的神经退行性疾病,影响健康成年人的大脑和脊髓。该病进展迅速,致命,使患者瘫痪,无法呼吸。这种疾病的病因及其进展仍然知之甚少。目前,ALS还没有已知的治愈方法或有效的治疗方法。但随着医学和技术的进步,产生的数据量大幅增加。为了提高人参皂苷Rg1化合物的生物利用度和药效,本文主要研究纳米植物体(nanophytosome, NP)的合成和表征。利用扫描电子显微镜对纳米颗粒进行了可视化观察,并用傅里叶变换红外光谱分析了纳米颗粒在NP中相互作用的类型。NP的大小在180 ~ 195nm之间。对大肠杆菌NP和人参皂苷Rg1的比较抑菌试验表明,NP随着大肠杆菌cfu的增加呈阳性,而人参皂苷Rg1仅在大肠杆菌cfu较低时呈阳性。分散研究表明,NP在约4小时时具有药物的最大释放率。这表明与人参皂苷Rgl相比,NP的稳定性和缓释特性立即作用于靶标。通过SOD、NO、DPPH等检测,比较了NP与人参皂苷Rg1的抗氧化能力。其抗氧化活性呈浓度依赖性,与人参皂苷Rg1化合物的抗氧化性能相近。NP具有比单独化合物更持久的抗氧化性能。因此,目前的技术对于治疗ALS、帕金森氏症、阿尔茨海默氏症等慢性疾病可能是一个福音,因为它提高了所封装药物的生物利用度和功效。
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引用次数: 1
Fabrication and simulations of high-aspect-ratio nanopores for polymer-based resistive pulse sensors 聚合物基电阻式脉冲传感器高纵横比纳米孔的制备与仿真
Pub Date : 2021-07-28 DOI: 10.1109/nano51122.2021.9514281
J. Berkenbrock, G. Wells, M. Mail, T. Scherer, S. Achenbach
Microfluidic devices are a class of Micro Electromechanical Systems (MEMS) intended for fluids manipulation, mostly liquids, in the order of microliters and below. The global market of micro and nanofluidic devices has experienced continuous growth over the past few years [1]. In 2020, this market was valued at over USD 4.6 billion in conservative terms, and it is predicted to keep a growth rate of somewhat between 13 and 23% in the next half-decade [2]–[3]. Microdevices are characterized by having at least one dimension in the micrometre range, as well as nanodevices, have it in the nanometer scale. The main applications to micro and nanofluidic devices are drug delivery, pharmaceutical and biotechnology research, clinical and point-of-care (POC) diagnostics [2]. Companies working in this field experienced a surge in demand with the rise of the COVID-19 pandemic. For the rapid testing against SARS-CoV-2, testing devices became necessary for screening populations afar from testing centers and health care facilities [4]–[5]. The development of micro-and nano detectors for new viruses is challenging even with all the background acquired from working with other viruses [6]–[7]. One long-standing detection approach was established in 1953 by W. Coulter for counting cells, a method which is known as Resistive Pulse Sensor (RPS) or Coulter counter [8]. In short, an RPS refers to two chambers filled with electrolyte solution and connected by a single orifice. The target delivered in one chamber shall flow through the orifice to the other chamber led by electrochemical forces. The translocation of the targets causes partial and non-permanent obstruction of the orifice. By monitoring the electric current during this assay, it induces the formation of a pulse-like shape representing a pulse of resistance. In the following decades, this method was adapted to the submicrometric scale with advances in micro-and nanofabrication techniques [9]–[10]. The fabrication of such micro detectors is often based on photolithography, but some emergent and alternative techniques are becoming more common [6, 11–12]. Focused ion beam (FIB) is one of these unconventional approaches that allow for patterning high aspect ratio structures into a mixture of materials [13]–[14]. A challenge to pattern composite materials (e.g., sandwich-like membranes), which might be based on polymers and metals, raises from the different physical properties of materials [15]. The sensitivity and applicability of RPS are directly dependant on the shape and quality of the final structure. For instance, wall smoothness is one of the parameters that should be considered when choosing a fabrication approach. In this work, we will present an advanced nanofabrication design based on focused ion beam technology to drill a nanopore into a polymer-metal-polymer membrane. The intricate structure to be presented in this work was chosen to avoid fabrication artifacts described previously [16]. Numerical sim
微流控装置是一类用于流体操纵的微机电系统(MEMS),主要是液体,以微升及以下的顺序。在过去几年中,全球微纳米流体器件市场经历了持续增长[1]。保守估计,2020年这一市场价值超过46亿美元,预计未来五年将保持13%至23%的增长率[2]-[3]。微器件的特点是至少有一个维度在微米范围内,而纳米器件的特征是至少有一个维度在纳米尺度上。微纳米流体器件的主要应用是药物输送、制药和生物技术研究、临床和护理点(POC)诊断[2]。随着COVID-19大流行的兴起,这一领域的公司需求激增。为了快速检测SARS-CoV-2,需要检测设备来筛查远离检测中心和医疗机构的人群[4]-[5]。开发用于新病毒的微纳米探测器是具有挑战性的,即使我们已经从研究其他病毒中获得了所有的背景[6]-[7]。1953年,W. Coulter建立了一种长期存在的检测方法,用于计数细胞,这种方法被称为电阻脉冲传感器(RPS)或Coulter计数器[8]。简而言之,RPS是指两个充满电解质溶液的腔室,并通过单个孔连接。在电化学力的引导下,在一个腔室中传递的目标将通过孔流到另一个腔室。靶的移位引起孔的局部和非永久性阻塞。在检测过程中,通过监测电流,它诱导形成一个脉冲状的形状,代表一个脉冲的电阻。在接下来的几十年里,随着微纳米加工技术的进步,这种方法被应用于亚微米尺度[9]-[10]。这种微型探测器的制造通常基于光刻技术,但一些新兴和替代技术正变得越来越普遍[6,11 - 12]。聚焦离子束(FIB)是这些非常规方法之一,它允许在材料混合物中绘制高纵横比结构的图案化[13]-[14]。可能基于聚合物和金属的复合材料(例如三明治状膜)的图案设计面临挑战,这源于材料的不同物理性质[15]。RPS的灵敏度和适用性直接取决于最终结构的形状和质量。例如,壁面平滑度是选择制造方法时应考虑的参数之一。在这项工作中,我们将提出一种基于聚焦离子束技术的先进纳米制造设计,在聚合物-金属-聚合物膜上钻一个纳米孔。选择在本作品中呈现的复杂结构是为了避免先前描述的制造人工制品[16]。数值模拟也将提供比较与一个平凡的圆柱形设计。
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引用次数: 0
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2021 IEEE 21st International Conference on Nanotechnology (NANO)
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