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2021 IEEE 21st International Conference on Nanotechnology (NANO)最新文献

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Solar Induced CO2 Reduction Achieved by Halide Tuning in Cesium Titanium (IV) Mixed Perovskite 铯钛(IV)混合钙钛矿卤化物调谐实现太阳诱导CO2还原
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514279
Shravanti Joshi
Atmospheric carbon dioxide (CO2) levels are rising dramatically owing to the unmonitored usage of fossil fuels, raising not only environmental hazards but also energy crises. Green energy that is, derived from renewable sources is the better exploitation of solar energy and hence, a promising idea for an efficient conversion of CO2 to hydrocarbon fuels (CxHyOz). Currently, the research activities in carbon-neutral technologies are focused on developing novel catalysts and designing highly effective conversion kinetics. In this context, for since past few years, zero lead all-inorganic halide perovskites have been trending as capable candidates due to their exceptional optoelectronic properties. Herein, we report on the facile synthesis of cesium titanium (IV) mixed halide perovskite ((CsTi(Brx.I1-x)3) with x value varying from 0 to 1) by tuning the bromide (Br) to iodide (I) ratio and its use for solar-induced CO2 reduction. Scanning electron micrographs revealed hierarchical morphology composed of several nanowires assembled into microspheres resembling the dandelions. In the presence of natural sunlight, pristine cesium titanium (IV) mixed halide perovskite (CsTi(Brx.I1-x)3) with x=0.5, yielded ~159 µmol/g of CO gas, ~94 µmol/g of CH4 and ~14 µmol/g of H2 under 6 h of experimental conditions. A lower conversion rate was observed in presence of artificial solar and UV light, which could be due to experimental conditions. The findings reported here are anticipated to contribute to the vast field of novel materials for solar fuel generation.
由于对化石燃料的不加监控的使用,大气中的二氧化碳(CO2)水平正在急剧上升,这不仅加剧了环境危害,也加剧了能源危机。绿色能源,即来自可再生能源,是对太阳能的更好利用,因此,将二氧化碳有效地转化为碳氢化合物燃料是一个很有前途的想法(CxHyOz)。目前,碳中和技术的研究主要集中在开发新型催化剂和设计高效的转化动力学上。在这种背景下,在过去的几年里,零铅全无机卤化物钙钛矿由于其特殊的光电性能而成为有能力的候选者。本文报道了通过调节溴化(Br)与碘化(I)的比例,快速合成铯钛(IV)混合卤化物钙钛矿((CsTi(Brx.I1-x)3),其x值从0到1变化),并将其用于太阳能诱导CO2还原。扫描电子显微照片显示,由几根纳米线组装成类似蒲公英的微球组成的分层形态。在自然光照条件下,原始铯钛(IV)混合卤化物钙钛矿(CsTi(Brx.I1-x)3)在x=0.5的条件下,在实验条件下6 h产生~159µmol/g CO气体,~94µmol/g CH4和~14µmol/g H2。在人工太阳光和紫外光照射下观察到较低的转化率,这可能是由于实验条件所致。在此报告的研究结果有望为太阳能燃料发电新材料的广泛领域做出贡献。
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引用次数: 2
Modeling and Simulation of DG SOI N FinFET 10 nm using Hafnium Oxide 氧化铪对10nm DG soin FinFET的建模与仿真
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514308
A. Lazzaz, K. Bousbahi, M. Ghamnia
This paper explores the modeling and simulation of DG SOI (Semiconductor On Insulator) N FinFET 10 nm with Hafnium Oxide by using SILVACO TCAD Atlas Software. The major critical parameters like ION, IOFF are evaluated in order to estimate the performance of the device. The Berkeley PTM (Predictive Technology Model) parameters for 10 nm nodes are used.
本文利用SILVACO TCAD Atlas软件,对10 nm氧化铪的dgsoi (Semiconductor On Insulator) N FinFET进行了建模和仿真。主要的关键参数,如离子,IOFF进行评估,以估计设备的性能。10 nm节点采用Berkeley PTM (Predictive Technology Model)参数。
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引用次数: 3
First Principle Study of Electronic Property of Doped/Undoped Graphene Structure for Interconnect Application 掺杂/未掺杂石墨烯互连结构电子特性第一性原理研究
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514343
Vijay Rao Kumbhare, P. Paltani, M. Majumder
Emerging trends in the VLSI industry open a new way to explore the electronic behavior of the novel graphene due to fundamental limitations (physical and geometrical) of silicon CMOS technology. In order to accomplish it, the structural behavior of graphene under the influence of different intercalation doping materials is investigated using spin-polarized density functional theory (DFT) and nonequilibrium Green's function (NEGF). This work considers three different graphene structures such as an armchair, zigzag, and (3, 2) chiral configurations to demonstrate the transmission spectrum for doped and pristine multi-layered graphene nanoribbon (MLGNR). Further, pristine graphene is compared with the different intercalation doped materials such as Lithium (Li), Ferric chloride (FeCl3), Arsenic pentafluoride (AsF5), and Molybdenum pentachloride (MoCl5) to observe the transmission in the central channel region. It is evident that the intercalated Li doping on zigzag MLGNR provides 71.60%, 95.12%, and 88.23% higher transmission in the central channel region compared to pristine zigzag, armchair, and (3, 2) chiral structures, respectively. Therefore, it is observed that intercalation doping is a suitable choice to improve the metallic nature of MLGNR structure that can be a better choice for nanoscale interconnect application.
由于硅CMOS技术的基本限制(物理和几何),VLSI行业的新兴趋势为探索新型石墨烯的电子行为开辟了新的途径。为此,利用自旋极化密度泛函理论(DFT)和非平衡格林函数(NEGF)研究了石墨烯在不同插层掺杂材料影响下的结构行为。本研究考虑了三种不同的石墨烯结构,如扶手椅结构、之字形结构和(3,2)手性结构,以展示掺杂和原始多层石墨烯纳米带(MLGNR)的透射光谱。此外,将原始石墨烯与不同的插层掺杂材料如锂(Li)、氯化铁(FeCl3)、五氟化砷(AsF5)和五氯化钼(MoCl5)进行比较,观察其在中央通道区域的透射情况。结果表明,与原始之字形、扶手型和(3,2)手性结构相比,在之字形MLGNR上掺杂Li,在中心通道区域的透射率分别提高了71.60%、95.12%和88.23%。因此,可以看出,嵌入掺杂是改善MLGNR结构金属性质的合适选择,可以成为纳米级互连应用的更好选择。
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引用次数: 0
Implementation of sub-filamentary network-based variability model for Ta2O5/TaOx RRAM 基于子纤维网络的Ta2O5/TaOx RRAM变异性模型的实现
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514298
J. A. Lekshmi, T. N. Kumar, A. Haider, K. Jinesh
This paper presents an analytical model of the cycle to cycle (c2c) variability in Pt/Ta2O5/TaOx/Pt RRAM device. The model is developed by considering the dynamic randomness in physical parameters related to the conduction filament of the device by demonstrating the formation of a sub filamentary network. The reasons behind the variability of the device characteristics are categorized into three possible aspects such as the formation of unstable sub filaments with varying lengths, formation of conduction filament with different radius in multiple cycles, and the barrier height modulations due to change in the number of oxygen vacancies(Vos) present at the interface and bulk. The major observations from the model are; the multiple resistive levels seen in the RRAM device is due to the formation of multiple stable/unstable filaments, the radius of the conduction filament has an impact on the RESET voltage, and finally, the modulations in tunneling barrier height cause randomness in high resistance state (HRS) of the device.
本文提出了Pt/Ta2O5/TaOx/Pt RRAM器件周期间(c2c)变异性的解析模型。该模型考虑了与器件导丝相关的物理参数的动态随机性,通过演示亚丝网络的形成来建立模型。器件特性变化背后的原因可分为三个可能的方面,即不同长度的不稳定亚丝的形成,在多个循环中形成不同半径的传导丝,以及由于界面和体上存在的氧空位(Vos)数量的变化而引起的势垒高度调制。该模型的主要观测值是;在RRAM器件中看到的多个电阻电平是由于形成了多个稳定/不稳定丝,传导丝的半径对RESET电压有影响,最后,隧道势垒高度的调制导致器件的高电阻状态(HRS)的随机性。
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引用次数: 0
The nanofluids application in a twin-screw electromechanical hydrolyser 纳米流体在双螺杆机电水解装置中的应用
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514326
N. Zablodskiy, S. Kovalchuk, R. Chuenko, Oleksii Romanenko, V. Gritsyuk
The analysis of the electromechanical device with nanofluid filling is performed in the work. The principle of operation of this machine is developed theoretically. Mechanical characteristics, spatial representation of heating and distribution density of magnetic induction were obtained by numerical analysis by the finite element method. According to the simulation results, by applying the nanofluid in the device, an increase in the electromagnetic moment is achieved, heat exchange conditions are improved.
在工作中对纳米流体填充的机电装置进行了分析。从理论上阐述了这台机器的工作原理。通过有限元数值分析,得到了其力学特性、加热空间表示和磁感应分布密度。仿真结果表明,在器件中加入纳米流体,可以提高电磁力矩,改善换热条件。
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引用次数: 1
Detection of heart-fatty acid binding protein in human serum using gold nano/micro-islands and molecularly imprinted polymers 利用金纳米/微岛和分子印迹聚合物检测人血清中心脏脂肪酸结合蛋白
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514337
A. Sanati, R. Moakhar, K. Raeissi, F. Karimzadeh, H. Vali, S. Mahshid
Here, we have developed a biomimetic sensor using gold nano/micro-islands (NMIs) and molecularly imprinted polymers (MIPs) for electrochemical detection of H-FABP. The fabricated nanostructured electrode was characterized and its analytical performance was evaluated in human serum spiked with H-FABP in the clinical range (10 pg mL−1 to 100 ng mL−1). In this regard, an excellent linear performance (R2=0.99) and a low limit of detection (LOD) of 4.86 pg mL−1 were observed. Moreover, the selectivity performance of the proposed biosensor was investigated in the presence of troponin T (TnT), and myoglobin (Myo). The differential pulse voltammetry (DPV) results showed that the MIP current has altered approximately 16, 20, and 62% for TnT, Myo, and H-FABP, respectively, confirming the low interference of other cardiac biomarkers on the sensing performance. Ultimately, the developed biomimetic sensor fabricated by the integration of hierarchical structures of gold and MIP opens up future perspectives for sensitive, low-cost, and early detection of myocardial infarction in human serum.
本文利用金纳米/微岛(NMIs)和分子印迹聚合物(MIPs)开发了一种用于H-FABP电化学检测的仿生传感器。对制备的纳米结构电极进行了表征,并在临床范围(10 pg mL−1 ~ 100 ng mL−1)内对加入H-FABP的人血清的分析性能进行了评价。在这方面,观察到良好的线性性能(R2=0.99)和低检出限(LOD)为4.86 pg mL−1。此外,研究了该生物传感器在肌钙蛋白T (TnT)和肌红蛋白(Myo)存在下的选择性性能。差分脉冲伏安法(DPV)结果显示,TnT、Myo和H-FABP的MIP电流分别改变了约16%、20%和62%,证实了其他心脏生物标志物对传感性能的低干扰。最终,开发出的由金和MIP分层结构集成而成的仿生传感器为灵敏、低成本和早期检测人类血清中的心肌梗死开辟了未来的前景。
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引用次数: 1
Surface wettability of nanopillar array structures fabricated by bio-template ultimate top-down processes 生物模板自顶向下工艺制备纳米柱阵列结构的表面润湿性
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514287
Sou Takeuchi, D. Ohori, Teruhisa Ishida, Mami Tanaka, Masahiro Sota, Yiming Li, J. Tarng, K. Endo, Seiji Sarnukawa
We made nanopillars with intervals of several tens of nanometers and diameter, and examined wettability. When the interval is narrow, the capillary phenomenon can be suppressed and hydrophobicity is realized. On the other hand, when the interval was widened, the wettability decreased due to the capillary phenomenon. As a result, it was found that the Cassie-Baxter model with filling factor gives a hydrophobic effect as the wetting property becomes narrower.
我们制作了间距为几十纳米和直径的纳米柱,并检测了润湿性。当间隔较窄时,可以抑制毛细现象,实现疏水性。另一方面,当间隙变宽时,由于毛细现象,润湿性降低。结果发现,当润湿特性变窄时,具有填充因子的Cassie-Baxter模型具有疏水效应。
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引用次数: 0
Collective Resonances of Lossy Material Nanoantennas 有损材料纳米天线的集体共振
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514325
V. Karimi, Viktoriia E. Babicheva
We analyze the multipole lattice effects on the resonant properties of periodic nanostructures and nanophotonic components made of lossy materials. The periodic arrangement of nanoscatterers facilitates the excitation of additional multipoles and allows light localization in planar photonic components. We show that our design can improve localized resonances and enhance the efficiency of the nanophotonic devices and sensors by adjusting nanoantenna periodicity in in-plane directions.
本文分析了多极晶格效应对含损耗材料的周期纳米结构和纳米光子元件共振特性的影响。纳米散射体的周期性排列有利于激发额外的多极子,并允许光在平面光子分量中定位。我们的研究表明,我们的设计可以通过调整纳米天线在平面方向上的周期性来改善局域共振,提高纳米光子器件和传感器的效率。
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引用次数: 0
Understanding Electron Transport in oxygen decorated Zigzag Graphene nanoribbons for nanoscale interconnects 了解氧修饰之字形石墨烯纳米带中用于纳米级互连的电子传输
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514303
S. Agrawal, A. Srivastava, G. Kaushal
Density functional theory with non-equilibrium Green's function has been used to extract the current voltage behaviour, fermi velocities and dynamical parameters of Oxygen (O) doped Zigzag Graphene Nano ribbons (GNRs). The Zigzag GNR has been subjected to monovacancy, and decorated with oxygen impurities at three possible sites around the Monovacancy (MV). The transport properties of these structures have been analysed in terms of transmission spectrum, I- V characteristics, transmission pathways and the dynamical parameters (kinetic inductance and quantum capacitance) of oxygen decorated ZGNRs. It has been observed that both linear I- V characteristics and improved dynamical parameters of 20- MVZGNR are relatively suitable for interconnect application in comparison to its other counterparts.
利用非平衡格林函数的密度泛函理论,提取了掺杂氧(O)之字形石墨烯纳米带的电流电压行为、费米速度和动力学参数。锯齿形GNR受到单空位的影响,并在单空位(MV)周围的三个可能的位置上装饰了氧杂质。从传输谱、I- V特性、传输路径和氧修饰zgnr的动力学参数(动电感和量子电容)等方面分析了这些结构的输运性质。与其他同类材料相比,20- MVZGNR的线性I- V特性和改进的动态参数都相对适合于互连应用。
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引用次数: 0
Low-Impedance Graphene – PEDOT-PSS Electrodes for Neural Recording and Stimulation in Implantable Medical Devices 用于植入式医疗设备中神经记录和刺激的低阻抗石墨烯- PEDOT-PSS电极
Pub Date : 2021-07-28 DOI: 10.1109/NANO51122.2021.9514286
Huy Nguyen, Jose Montes, Sepehr Soroushiani, Sk Yeahia Been Sayeed, Carolina Moncion, J. R. Diaz, P. Raj
Flexible electrode arrays with low impedance are becoming critical to enhance single-neuron sensing with high sensitivity. Such electrodes should be scalable to micron dimensions and yet retain low impedance. The key to accomplish this is to achieve: a) higher effective surface area to obtain high capacitance, b) chemically stable and biocompatible materials with no adverse reactions and toxicity, and c) mechanically compliant structures for minimal scar tissue formation. Nanostructured electrode arrays with emerging materials such as graphene and PEDOT -PSS are projected to meet all these requirements. Graphene - PEDOT-PSS films were transferred onto flexible LCP (liquid crystal polymer) substrates to form neural electrode recording arrays. These electrodes were subsequently integrated with flexible passive wireless neural recording sensors to form low-impedance (<1 Ohms-cm2) neural recording units. Impedance enhancements were simulated and validated with an electrochemical analyzer in a phosphate buffered saline PBS solution. In addition, evoked potentials during pulse stimulation were recorded to show improved signal - noise ratio with low-impedance electrodes.
具有低阻抗的柔性电极阵列已成为提高单神经元高灵敏度传感的关键。这种电极应该可扩展到微米尺寸,同时保持低阻抗。实现这一目标的关键是实现:a)更高的有效表面积,以获得高电容;b)化学稳定,无不良反应和毒性的生物相容性材料;c)机械柔韧的结构,以最小的疤痕组织形成。采用石墨烯和PEDOT -PSS等新兴材料的纳米结构电极阵列有望满足所有这些要求。将石墨烯- PEDOT-PSS薄膜转移到柔性LCP(液晶聚合物)衬底上,形成神经电极记录阵列。这些电极随后与柔性无源无线神经记录传感器集成,形成低阻抗(<1欧姆-平方厘米)神经记录单元。阻抗增强模拟和验证与电化学分析仪在磷酸盐缓冲盐水PBS溶液。此外,记录脉冲刺激时的诱发电位,显示低阻抗电极改善了信噪比。
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引用次数: 0
期刊
2021 IEEE 21st International Conference on Nanotechnology (NANO)
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