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Socio-technical feasibility of coal transitions in India: Results from stakeholder interviews 印度煤炭转型的社会技术可行性:利益相关者访谈的结果
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-04-14 DOI: 10.1016/j.egycc.2025.100188
Udayan Singh , Saritha Sudharmma Vishwanathan , Amit Garg , Ajay K. Singh , Srinath Haran Iyer
Strategizing development-led energy transitions for India would need considerable stakeholder inputs for improved decision-making. While modeling exercises have largely been used for research and policymaking, an increasing need is felt to validate underlying assumptions and model findings based on views of important stakeholders. Particularly, for the coal sector, these stakeholders are present throughout the value chain: mining, end-use (power and industry), regulatory agencies, transport and advocacy. This paper summarizes the key findings of our interviews with n = 21 stakeholders across these sectors focusing on evolving coal use, underlying technologies and socio-technical features of this transition. Based on this exercise, interviewed experts largely believe that coal use would continue for the next two decades in the interest of energy security and energy affordability to the consumer. At the same time, they also acknowledged the reduced costs of solar, which makes it a key player in the analysis. We also notice an improved perception of carbon management technologies. Particularly, CO2 utilization to produce methanol and urea are seen as potential winners as these approaches could facilitate lower imports of petroleum and natural gas products. Geologic CO2 storage is still somewhat impeded by technical limitations and lack of global exemplars. Other approaches such as recovery of methane from gassy coal mines and biomass co-firing are seen as important but limited in potential. Most stakeholders also pointed to the need for averting job losses in the coal value-chain, which may not necessarily be made up by renewables.
为印度制定以发展为主导的能源转型战略需要大量利益相关者的投入,以改善决策。虽然建模练习主要用于研究和决策,但越来越需要根据重要利益相关者的观点来验证基本假设和模型结果。特别是对于煤炭行业,这些利益相关者存在于整个价值链中:采矿、最终用途(电力和工业)、监管机构、运输和宣传。本文总结了我们对这些行业的n = 21名利益相关者的访谈的主要发现,重点关注煤炭使用的演变、基础技术和转型的社会技术特征。基于这一调查,受访专家大多认为,为了能源安全和消费者的能源负担能力,煤炭的使用将在未来20年继续下去。与此同时,他们也承认太阳能的成本降低,这使其成为分析中的关键因素。我们还注意到对碳管理技术的认识有所提高。特别是,利用二氧化碳生产甲醇和尿素被视为潜在的赢家,因为这些方法可以促进减少石油和天然气产品的进口。由于技术限制和缺乏全球范例,地质二氧化碳储存仍然受到一定程度的阻碍。其他方法,如从瓦斯煤矿中回收甲烷和生物质共烧,被认为是重要的,但潜力有限。大多数利益相关者还指出,有必要避免煤炭价值链上的失业,而可再生能源不一定能弥补这一损失。
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引用次数: 0
Distributional implications of carbon taxation policy in Indonesia 印尼碳税政策的分配影响
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-04-11 DOI: 10.1016/j.egycc.2025.100186
Aldy Darwili, Servaas Storm , Enno Schröder
We combine the Environmentally-Extended Multi-Regional Input-Output (EE MRIO) analysis with a microsimulation analysis to estimate the distributional implications of carbon policy reform, a combination of carbon tax and revenue recycling initiatives, on households in Indonesia. We consider two relevant scenarios: an “economy-wide” carbon tax versus an “electricity-only” carbon tax. The impact of carbon policy reform is measured by the net impact of carbon tax and cash transfer relative to initial expenditure. Carbon policy reform in Indonesia tends to be progressive, meaning the relative net impact on households decreases as income increases. Carbon tax in Indonesia primarily affects households through the price increase in electricity and fuel products. The distributional impacts of a carbon policy reform are determined more by the percentage of tax revenue recycled and taxation scenario and less by the tax rate. In order to protect the poorest 40 % of Indonesian households from inflationary pressure, the Indonesian government needs to recycle 25 % of tax revenue.
我们将环境扩展型多区域投入产出(EE MRIO)分析与微观模拟分析相结合,估算了碳税和收入循环举措相结合的碳政策改革对印度尼西亚家庭的分配影响。我们考虑了两种相关方案:"全经济 "碳税和 "纯电力 "碳税。碳政策改革的影响以碳税和现金转移相对于初始支出的净影响来衡量。印尼的碳政策改革趋于累进,这意味着对家庭的相对净影响随着收入的增加而减少。印尼的碳税主要通过提高电力和燃料产品的价格来影响家庭。碳政策改革对分配的影响更多地取决于税收回收的比例和征税方案,而较少取决于税率。为了保护印尼 40% 的最贫困家庭免受通胀压力,印尼政府需要回收 25% 的税收。
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引用次数: 0
Climate change exposure, oil price uncertainty, and managerial ownership: Insights from textual analysis 气候变化风险,石油价格的不确定性,和管理所有权:从文本分析的见解
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-03-30 DOI: 10.1016/j.egycc.2025.100187
Viput Ongsakul , Pornsit Jiraporn , Pandej Chintrakarn , Pattanaporn Chatjuthamard
We examine the impact of oil price uncertainty on firm-specific climate change exposure, with a focus on the moderating role of managerial ownership. Using a comprehensive dataset generated from sophisticated textual analysis of conference earnings calls, we find that oil price uncertainty significantly increases overall climate change exposure, with managerial ownership playing a crucial moderating role. Firms with higher managerial ownership demonstrate reduced regulatory risks and enhanced new business opportunities in response to oil price volatility. Moreover, we explore how the effect of oil price uncertainty on climate change exposure evolves over time and find that the strength of this effect remains stable. These results highlight the importance of aligning managerial incentives with long-term sustainability goals to mitigate climate risks and capitalize on emerging opportunities.
我们研究了油价不确定性对企业特定气候变化风险的影响,重点关注管理层所有权的调节作用。通过对财报电话会议的复杂文本分析生成的综合数据集,我们发现油价的不确定性显著增加了整体气候变化风险,而管理层所有权起着至关重要的调节作用。管理层持股比例较高的公司在应对油价波动时,监管风险降低,新业务机会增加。此外,我们探讨了油价不确定性对气候变化暴露的影响如何随着时间的推移而演变,并发现这种影响的强度保持稳定。这些结果强调了将管理激励与长期可持续性目标相结合的重要性,以减轻气候风险并利用新出现的机会。
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引用次数: 0
Assessing the Impact of Energy Transition Initiatives on the Policy Cost of Saudi Arabia's Net-Zero Ambition 评估能源转型举措对沙特阿拉伯净零目标政策成本的影响
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-03-18 DOI: 10.1016/j.egycc.2025.100184
Raphael Apeaning , Puneet Kamboj , Mohamad Hejazi , Yang Qiu , Page Kyle , Gokul Iyer
Saudi Arabia's ambitious goal to achieve a net-zero economy by 2060 offers a unique opportunity to diversify away from fossil fuels while fostering long-term economic resilience and sustainability. Crucial to this transition are energy policies that guide the Kingdom from a fossil fuel-based economy toward carbon neutrality. This study uses GCAM-KSA, a multi-sectoral integrated assessment model tailored to Saudi Arabia's economic and energy systems, to evaluate the impact of early energy transition initiatives on the policy costs of achieving the Kingdom's net-zero target. These initiatives include ongoing and proposed energy efficiency measures, renewable energy deployment, and fuel displacement targets. The study highlights that early implementation of these initiatives can significantly reduce barriers to adopting low-carbon technologies, ultimately lowering the economic burden of achieving the net-zero goal. Compared to a delayed implementation scenario, early action reduces long-term policy costs by 38–72% over the period from 2025 to 2060, driven by accelerated energy system transformation. These findings provide valuable insights into how Saudi Arabia's energy policies can mitigate economic challenges, promote economic diversification, and contribute to global emission reductions, reinforcing the Kingdom's transition to a sustainable net-zero economy.
沙特阿拉伯雄心勃勃的目标是到2060年实现净零经济,这为摆脱化石燃料的依赖,同时促进长期经济弹性和可持续性提供了一个独特的机会。实现这一转变的关键是能源政策,这些政策将引导沙特王国从以化石燃料为基础的经济走向碳中和。本研究使用针对沙特阿拉伯经济和能源系统量身定制的多部门综合评估模型GCAM-KSA来评估早期能源转型举措对实现沙特净零排放目标的政策成本的影响。这些倡议包括正在进行的和拟议的能源效率措施、可再生能源部署和燃料替代目标。该研究强调,尽早实施这些举措可以大大减少采用低碳技术的障碍,最终降低实现净零排放目标的经济负担。与推迟实施情景相比,在加速能源系统转型的推动下,早期行动在2025年至2060年期间可将长期政策成本降低38-72%。这些发现为沙特阿拉伯的能源政策如何缓解经济挑战、促进经济多样化、为全球减排做出贡献、加强王国向可持续净零经济的过渡提供了有价值的见解。
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引用次数: 0
The effects of public deliberation on attitude change toward net-zero pathway: Generational differences in Taiwan 公众审议对零净路径态度转变的影响:台湾代际差异
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-03-06 DOI: 10.1016/j.egycc.2025.100183
Mei-Fang Fan , Alice Siu
Deliberative democracy researchers argue that democratic deliberation is the key to addressing problems posed by polarisation and post-truth politics. Decarbonisation toward net zero has become a key topic of public deliberation worldwide in the face of our climate emergency. This article explores generational differences in the effects of deliberation on changes in attitudes toward policies. The empirical analysis conducted in the present study was based on a nationwide online deliberation polling experiment in which a random sample of 91 citizens was gathered in July 2022 to deliberate on Taiwan's pathway to net-zero emissions with consideration of social divisions and barriers to the implementation of long-term energy policies. The findings revealed that deliberation resulted in significant increases in the feasibility of the 2050 Net-Zero Pathway and the support of citizens for several policy proposals, such as the target of 60–70 % renewable energy in the energy mix. The effects of deliberation on changes in attitudes toward certain policy proposals between two generations (aged <40 years and >41 years) varied significantly. The results showed five ways of generational policy attitude change. These findings suggest that public deliberation promotes knowledge expansion, collective learning, and reflection on Taiwan's Net-Zero Pathway plan.
协商民主研究人员认为,民主协商是解决两极分化和后真相政治带来的问题的关键。面对我们的气候紧急情况,向净零排放脱碳已成为全球公众审议的一个关键话题。本文探讨了审议对政策态度变化影响的代际差异。本研究的实证分析基于2022年7月在全国范围内随机抽取91名公民的在线审议投票实验,在考虑社会分化和长期能源政策实施障碍的情况下,就台湾实现净零排放的途径进行讨论。调查结果显示,审议导致2050年净零路径的可行性显著增加,公民对若干政策建议的支持,例如可再生能源在能源结构中占60 - 70%的目标。审议对两代人(40岁和41岁)对某些政策建议的态度变化的影响差异很大。结果显示了代际政策态度变化的五种方式。研究结果显示,公众讨论促进了台湾零净路径计划的知识扩展、集体学习和反思。
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引用次数: 0
US economy-wide decarbonization: Sectoral and distributional impacts 美国经济整体脱碳:部门和分配影响
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-03-05 DOI: 10.1016/j.egycc.2025.100181
Jonathon Becker , Maxwell Brown , Morgan Browning , Yongxia Cai , Daden Goldfinger , James McFarland , Sergey Paltsev , Shane Weisberg , Mei Yuan
This paper investigates the sectoral and distributional welfare impacts of reaching net-zero CO2 emissions in the US by 2050. We simulate several net-zero projections using a CGE model linked with an electricity capacity expansion model to try to understand what a transition to net-zero might look like and the role played by different policies and technologies. Reaching net-zero leads to high carbon prices in 2045 and 2050, which drives deployment of direct air capture (DAC) technology. The electricity sector reaches negative emissions by 2050. Electrification is the predominant means for decarbonizing the buildings and transportation sectors, whereas industrial sectors are assumed to have limited electrification potential and prefer carbon management. The negative emissions in the power sector are primarily achieved through biomass-fired electricity generation with carbon capture and storage. In our scenarios, decarbonization is progressive (i.e., burden increases with income) due to our modeling assumption of lump-sum recycling of carbon permit revenues. In 2050, we find a break in the progressive trend when capital-intensive DAC technology enters, as permit revenue distributions that benefit the lowest income groups are directly substituted for returns to capital from DAC deployment that benefit the highest income groups. Our other non-CCS and non-DAC technology improvement cases in the buildings, transportation, and industrial sectors led to a more evenly distributed benefit across households as these mitigation channels are less capital intensive. When the Inflation Reduction Act (IRA) is included, the net-zero emissions limit does not bind as early, the need for DAC is reduced, and industrial CCS investment occurs earlier and in greater amounts. These effects highlight the importance of considering interactions between technologies, policies, and fiscal decisions when prescribing net-zero pathways around a distributional goal.
本文研究了到2050年美国实现二氧化碳净零排放对部门和分配福利的影响。我们使用与电力容量扩张模型相关联的CGE模型模拟了几个净零预测,试图了解向净零的过渡可能是什么样子,以及不同政策和技术所起的作用。达到净零排放将导致2045年和2050年的高碳价格,这将推动直接空气捕获(DAC)技术的部署。到2050年,电力部门达到负排放。电气化是建筑和运输部门脱碳的主要手段,而工业部门被认为电气化潜力有限,更喜欢碳管理。电力部门的负排放主要是通过生物质发电和碳捕获和储存来实现的。在我们的情景中,由于我们的建模假设碳许可收入的一次性回收,脱碳是渐进的(即负担随着收入的增加而增加)。在2050年,当资本密集型DAC技术进入时,我们发现进步趋势出现了突破,因为允许使最低收入群体受益的收入分配直接取代了使最高收入群体受益的DAC部署的资本回报。我们在建筑、交通和工业领域的其他非ccs和非dac技术改进案例,由于这些缓解渠道的资本密集程度较低,因此在家庭之间的利益分配更为均匀。当通货膨胀减少法案(IRA)包括在内时,净零排放限制不那么早具有约束力,对DAC的需求减少,工业CCS投资发生得更早,数量也更大。这些影响突出了在围绕分配目标制定净零排放途径时,考虑技术、政策和财政决策之间相互作用的重要性。
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引用次数: 0
Trust in scientists, researchers, and environmental organizations associated with policy support for energy transition 信任与能源转型政策支持相关的科学家、研究人员和环保组织
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-02-20 DOI: 10.1016/j.egycc.2025.100179
Runa R. Das , Reuven Sussman , Richard Carlson
Energy transition, shifting away from fossil fuel use, is fundamental to addressing climate change. To explore public support for energy transition policies, we surveyed a representative sample of residents in Canada's largest province, Ontario, (N = 1620), and conducted regression analyses to examine how support varies with trust in the actors communicating these policies. Ontarians prefer ‘carrot’ policies—those offering direct benefits to households—over ‘stick’ policies. The most supported policies include the development of renewable natural gas, interest-free energy efficiency loan programs, and funding for low-income energy efficiency programs, while the least supported policies are a carbon tax, continued oil sands development, and the electrification of heating.
Ontarians have low to moderate levels of trust in governments at all levels, utilities, media, oil and gas companies, and to some extent in renewable energy companies. However they demonstrate consistently high trust in scientists, researchers, and non-profit organizations. Public support for policies in Ontario is influenced by trust in stakeholders and policymakers, with the relationship varying across different policies. We find Ontarians’ trust in scientists, researchers, and non-profit organizations is positively associated with supporting ‘emerging’ energy transition policies, such as the development of renewable natural gas and hydrogen.
Our findings suggest that policymakers seeking to advance energy transition policies can strengthen both effectiveness and public acceptance by engaging with trusted actors, such as scientists and non-profits, and leveraging their credibility. Furthermore, adopting inclusive and participatory planning processes that reflect public values and address equity concerns is crucial to fostering long-term trust and policy stability amidst the challenges of the energy transition.
从使用化石燃料转向能源转型,是应对气候变化的根本。为了探索公众对能源转型政策的支持,我们调查了加拿大最大省份安大略省的一个有代表性的居民样本(N = 1620),并进行了回归分析,以检验对传达这些政策的行为者的信任如何影响支持。安大略人更喜欢“胡萝卜”政策——那些为家庭提供直接利益的政策——而不是“大棒”政策。最受支持的政策包括开发可再生天然气、无息能源效率贷款计划和为低收入能源效率计划提供资金,而最不受支持的政策是征收碳税、继续开发油砂和供暖电气化。安大略人对各级政府、公用事业、媒体、石油和天然气公司,以及在一定程度上对可再生能源公司的信任程度为低至中等。然而,他们始终表现出对科学家、研究人员和非营利组织的高度信任。安大略省公众对政策的支持受到对利益相关者和政策制定者的信任的影响,不同政策之间的关系各不相同。我们发现,安大略省人对科学家、研究人员和非营利组织的信任与支持“新兴”能源转型政策(如开发可再生天然气和氢)呈正相关。我们的研究结果表明,寻求推进能源转型政策的政策制定者可以通过与值得信赖的行为体(如科学家和非营利组织)合作,并利用他们的可信度,从而提高效率和公众接受度。此外,在能源转型的挑战中,采用反映公众价值观和解决公平问题的包容性和参与性规划过程对于促进长期信任和政策稳定至关重要。
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引用次数: 0
China's provincial renewable energy electricity consumption allocations for 2030: A study using the zero-sum gains data envelope analysis model 中国各省2030年可再生能源电力消费分配:零和收益数据包络分析模型研究
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-02-19 DOI: 10.1016/j.egycc.2025.100182
Lingling Mu, Jianping Wang, Yidan Gu
Ensuring grid stability and meeting emissions reduction goals hinge on the effective allocation of renewable energy electricity consumption. Guided by principles of fairness, efficiency, feasibility, and sustainability, this study crafted a holistic indicator system and employed the Zero-Sum Gains Data Envelope Analysis (ZSG-DEA) model to analyze China's provincial renewable electricity consumption allocations for 2030. The findings indicate that the initial renewable electricity allocation efficiency is already optimal in nine provinces, but falls below 0.5 in Shanxi, Xinjiang, and Inner Mongolia. However, after three iterations of the ZSG-DEA model, all regions attain optimal efficiency. Eastern coastal regions lead in renewable electricity consumption, exceeding 100 billion kWh, while certain provinces consume less than 70 billion kWh of non-hydroelectricity due to area size. Compared to the initial allocation, there is an observed increase in consumption of non-hydroelectricity in the eastern coastal regions. Conversely, iterative adjustments have led to a notable decrease of up to 40 % in the non-hydroelectricity allocated to regions with favorable wind and solar power generation conditions. It is recommended that regions with rapid economic growth and high electricity demand in China's east should be given priority for renewable electricity allocation. Additionally, it is suggested to improve the excess consumption trading market and the green certificate trading market to provide supplementary means to achieve renewable electricity consumption targets and optimize renewable electricity allocation efficiency.
确保电网稳定和实现减排目标取决于可再生能源电力消费的有效分配。在公平性、效率性、可行性和可持续性原则的指导下,本研究精心设计了一个整体指标体系,并采用零和收益数据包络分析(ZSG-DEA)模型对中国 2030 年各省可再生能源电力消费分配进行了分析。研究结果表明,9 个省份的初始可再生能源电力分配效率已经达到最优,但山西、新疆和内蒙古的初始可再生能源电力分配效率低于 0.5。然而,经过三次 ZSG-DEA 模型迭代后,所有地区都达到了最优效率。东部沿海地区的可再生能源电力消费居首位,超过 1000 亿千瓦时,而某些省份由于面积大小,非水电消费不足 700 亿千瓦时。与初始分配相比,东部沿海地区的非水电消费量有所增加。相反,经过反复调整,风能和太阳能发电条件好的地区分配到的非水电量明显减少,降幅高达 40%。建议中国东部经济增长快、电力需求大的地区应优先分配可再生能源电力。此外,建议完善超额消纳交易市场和绿色证书交易市场,为实现可再生能源电力消纳目标和优化可再生能源电力配置效率提供辅助手段。
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引用次数: 0
Solar assisted generation of plasmonic silver photocatalyst for wastewater remediation and green hydrogen production 太阳能辅助制备等离子体银光催化剂用于废水修复和绿色制氢
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-02-17 DOI: 10.1016/j.egycc.2025.100180
Preeti Kumari, Aditya Kumar
The present study aims to develop sustainable technologies to address the imperative problems of water pollution and energy crisis. This research involves the solar-driven synthesis of a plasmonic silver photocatalyst with properties that aid in environmental and energy applications. The structural, optical, and catalytic properties of the developed photocatalyst are investigated using several analytical techniques, including XRD, XPS, UV-Vis, FESEM, HRTEM, and Raman spectroscopy. The developed photocatalyst is capable of degradation of organic pollutants present in wastewater. The photodegradation capability of photocatalyst is assessed through a comprehensive study of the reaction kinetics involved and the determination of quantum efficiency. Moreover, the photocatalyst also contributes to transition to a green economy via hydrogen production through water splitting. Although the solar-to-hydrogen efficiency of the silver photocatalyst is not appreciable but it paves out way for the development of an efficient photocatalyst by doping or using it as a co-catalyst with semiconductor materials. Thus, the entire study contributes significantly to the development of a clean and sustainable future and takes a step towards the transformation to a renewable energy-based economy.
本研究旨在开发可持续技术,以解决水污染和能源危机等紧迫问题。这项研究涉及利用太阳能合成一种具有有助于环境和能源应用特性的等离子体银光催化剂。研究人员使用多种分析技术,包括 XRD、XPS、UV-Vis、FESEM、HRTEM 和拉曼光谱,对所开发的光催化剂的结构、光学和催化特性进行了研究。所开发的光催化剂能够降解废水中的有机污染物。光催化剂的光降解能力是通过对反应动力学的综合研究和量子效率的测定来评估的。此外,光催化剂还能通过分水制氢促进向绿色经济过渡。虽然银光催化剂的太阳能转化为氢气的效率不高,但它为通过掺杂或使用银光催化剂作为半导体材料的辅助催化剂来开发高效光催化剂铺平了道路。因此,整个研究极大地促进了清洁和可持续未来的发展,并为向以可再生能源为基础的经济转型迈出了一步。
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引用次数: 0
Green hydrogen production via a photocatalyst-enabled optical fiber system: A promising route to net-zero emissions 通过光催化光纤系统生产绿色氢:一条实现净零排放的有希望的途径
IF 5.8 Q2 ENERGY & FUELS Pub Date : 2025-01-30 DOI: 10.1016/j.egycc.2025.100175
Han Fu , Zhenhua Pan , Yen-Jung Sean Lai , Jirapat Ananpattarachai , Michael Serpa , Nora Shapiro , Zhe Zhao , Paul Westerhoff
Achieving zero emissions is a critical goal in combating climate change. Hydrogen is a versatile energy carrier contributing to this objective. Green hydrogen production via photocatalytic (PC) and photoelectrochemical (PEC) water splitting is promising due to its potential to utilize renewable energy (direct solar, photovoltaics, wind, hydropower). However, current PC and PEC water splitting systems face challenges such as low light utilization efficiency and high operational costs related to both catalyst selection and reactor designs. This study presents a novel photocatalytic hydrogen production system, POF-STO, by attaching a modified strontium titanate (STO) onto thin polymer optical fibers (POF). Light launched from 365 nm LED into the POF lumen is side-emitted and excites STO in a porous layer on the POF surface. This PC system improves upon our previous PEC-POF-ITO/g-C3N4 system, which required dual nanoparticles of indium tin oxide (ITO) to make the POF optoelectrodes conductive plus graphitic carbon nitride (g-C3N4) photocatalysts. Our innovative inside-out light delivery mechanism with the POF ensures efficient photon confinement and energy transfer to the STO surface, maximizing light utilization. The chemically stable STO with up to 7-fold H2 production rates than the PEC-POF-ITO/g-C3N4 system was observed. Our POF-STO system produced stable H2 production rates in both acidic and alkaline environments, with <10 % reduction in hydrogen generation when using tap water and seawater. Eliminating complex electrical setups, potentiostats, electrodes, and aqueous electrolytes significantly reduces system costs. Using bundles with multiple POF-STOs and utilizing heat from LEDs allowed operation at higher water temperatures, further increasing H2 production efficiency. Compared with other reactor designs, the POF-STO emerges as an innovative approach with potential to achieve ambitious global net-zero emission goals.
实现零排放是应对气候变化的关键目标。氢是一种多功能的能量载体,有助于实现这一目标。通过光催化(PC)和光电化学(PEC)水分解的绿色制氢是有前途的,因为它有利用可再生能源(直接太阳能、光伏、风能、水力发电)的潜力。然而,目前的PC和PEC水分解系统面临着诸如催化剂选择和反应器设计相关的低光利用率和高运行成本等挑战。本研究提出了一种新型光催化制氢体系POF-STO,该体系将改性钛酸锶(STO)附着在薄聚合物光纤(POF)上。从365 nm LED发射到POF流明的光是侧发射的,并在POF表面的多孔层中激发STO。这种PC系统改进了我们之前的PEC-POF-ITO/g-C3N4系统,该系统需要双纳米氧化铟锡(ITO)和石墨化碳氮化(g-C3N4)光催化剂来使POF光电极具有导电性。我们创新的POF由内到外的光传输机制确保了高效的光子约束和能量传递到STO表面,最大限度地提高了光利用率。结果表明,该体系的H2产率是PEC-POF-ITO/g-C3N4体系的7倍。我们的POF-STO系统在酸性和碱性环境下都能产生稳定的氢气产量,在使用自来水和海水时,产氢量减少了10%。消除了复杂的电气装置、电位器、电极和水溶液电解质,大大降低了系统成本。使用带有多个pof - sto的束,并利用led的热量,可以在更高的水温下运行,进一步提高H2的生产效率。与其他反应堆设计相比,POF-STO是一种创新的方法,有可能实现雄心勃勃的全球净零排放目标。
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Energy and climate change
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