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Exploring the potential antibacterial mechanism of the goose eggshell-derived CaO nanoparticles for deactivation of pharmaceutical wastages and bacteria 探讨鹅蛋壳制备的氧化钙纳米颗粒对药物废物和细菌失活的潜在抑菌机制
Q3 Materials Science Pub Date : 2025-10-01 Epub Date: 2025-08-27 DOI: 10.1016/j.jciso.2025.100151
Priyanshu Kumar Singh , J. Sunil
Environmental contamination caused by pharmaceutical residues and textile dye effluents poses significant challenges due to their chemical stability, toxicity, and resistance to conventional treatment methods. This study investigates the green synthesis of calcium oxide (CaO) NPS derived from goose eggshells via thermal decomposition at 900 °C, and evaluates their efficacy in photocatalytic degradation and antibacterial applications. Comprehensive characterization using XRD, FTIR, FESEM, UV–Vis studies confirmed the successful formation of phase-pure, highly crystalline CaO NPS with an average particle size of 47.9 nm and a direct optical bandgap of 3.41 eV. The photocatalytic performance of the synthesized CaO Nanoparticles (NPs) was assessed through the degradation of Safranin dye (a model cationic dye) and the pharmaceutical compound Paracetamol under natural sunlight. The NPS achieved degradation efficiencies of 97.43 % for Safranin and 91.25 % for Paracetamol, following pseudo-first-order kinetics. The degradation rate constant for Safranin (2.896 × 10−2 min−1) was higher than that for Paracetamol (1.551 × 10−2 min−1), likely due to more favourable adsorption and stronger electrostatic interactions between the cationic dye molecules and the negatively charged CaO surface. In addition to their photocatalytic properties, the CaO NPS demonstrated significant antibacterial activity, particularly against Gram-positive Staphylococcus aureus, with a maximum zone of inhibition of 19.4 mm. The enhanced antibacterial performance is attributed to the nanoscale size, high surface reactivity, and the alkaline nature of CaO, which collectively disrupt bacterial membrane integrity. Overall, this work underscores the potential of bio-waste-derived CaO NPS as an environmentally sustainable, cost-effective, and multifunctional material for the dual purpose of wastewater remediation and microbial control.
由于药物残留和纺织染料废水的化学稳定性、毒性和对常规处理方法的抗性,它们对环境污染构成了重大挑战。本研究以鹅蛋壳为原料,在900℃下进行热分解绿色合成氧化钙(CaO) NPS,并评价其光催化降解和抗菌性能。通过XRD、FTIR、FESEM、UV-Vis等综合表征,成功制备出相纯、高结晶的CaO NPS,平均粒径为47.9 nm,直接光学带隙为3.41 eV。通过在自然光照下对红色素(一种模型阳离子染料)和药物化合物扑热息痛的降解,评价了合成的CaO纳米颗粒(NPs)的光催化性能。NPS对红花素的降解效率为97.43%,对扑热息痛的降解效率为91.25%,符合准一级动力学。红花素的降解速率常数为2.896 × 10−2 min−1,高于扑热息痛的降解速率常数(1.551 × 10−2 min−1),这可能是由于阳离子染料分子与带负电的CaO表面之间具有更有利的吸附和更强的静电相互作用。除了光催化性能外,CaO NPS还表现出显著的抗菌活性,特别是对革兰氏阳性金黄色葡萄球菌,其最大抑制区为19.4 mm。增强的抗菌性能归因于CaO的纳米级尺寸、高表面反应性和碱性,这些因素共同破坏了细菌膜的完整性。总的来说,这项工作强调了生物废物来源的CaO NPS作为一种环境可持续、成本效益高的多功能材料的潜力,可用于废水修复和微生物控制的双重目的。
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引用次数: 0
Effect of pH on photocatalytic degradation of methylene blue in water by facile hydrothermally grown TiO2 nanoparticles under natural sunlight pH对自然光照下易水热生长TiO2纳米颗粒光催化降解水中亚甲基蓝的影响
Q3 Materials Science Pub Date : 2025-10-01 Epub Date: 2025-08-26 DOI: 10.1016/j.jciso.2025.100150
Uttama Kumar Saint , Suresh Chandra Baral , Dilip Sasmal , P. Maneesha , Sayak Datta , Farzana Naushin , Somaditya Sen
Each year, the production of synthetic dye wastewater reaches a trillion tons. This poses a significant global challenge of water scarcity. Hence, wastewater must be treated to reverse to useable water and prevent water scarcity. Failing to achieve this reversal increases ecotoxicological risks and human health. Textile wastewater contains harmful dyes. Photocatalytic degradation of these dye-contaminated wastewater is one of the major pathways in achieving reversal. However, this process is time-consuming, requires high-power lamps, and is expensive. Here, we report the effect of TiO2 nanostructures prepared by facile hydrothermal synthesis on the dye degradation of one of the most common industrial textile dyes, methylene blue (MB), under natural sunlight. The impact of particle size on the photocatalytic activity and photocarrier migration rate was thoroughly examined. The size and surface morphology of the TiO2 nanostructures depended on the concentration of the precursor during synthesis. Also, the effect of the pH of the dye solution on adsorption and photocatalytic degradation has been evaluated. With several optimized conditions, almost complete dye degradation was achieved within 40 min under the direct illumination of natural sunlight. The enhanced photocatalytic performance could correlate to the synergetic effect of a higher charge transfer mechanism, good catalytically active surface area availability (386 m2/g), and several optimized parameters that affect the reaction efficacy. Additionally, repeated use of NPs (five times) without sacrificing performance confirmed their stability and sustainability as a promising candidate for large-scale industrial textile wastewater remedies.
每年,合成染料废水的产量达到一万亿吨。这构成了水资源短缺的重大全球挑战。因此,必须对废水进行处理,使其转化为可用的水,防止缺水。如果不能实现这种逆转,就会增加生态毒理学风险和人类健康。纺织废水中含有有害染料。光催化降解这些染料污染废水是实现逆转的主要途径之一。然而,这个过程耗时,需要大功率灯,而且价格昂贵。在这里,我们报道了通过易水热合成制备的TiO2纳米结构对天然日光下最常见的工业纺织品染料之一亚甲基蓝(MB)的染料降解的影响。研究了粒径对光催化活性和光载流子迁移速率的影响。合成过程中前驱体的浓度决定了TiO2纳米结构的大小和表面形貌。同时,考察了染料溶液pH对吸附和光催化降解的影响。经过几个优化条件,在自然光直接照射下,染料在40分钟内几乎完全降解。光催化性能的增强可能与较高的电荷转移机制、良好的催化活性表面积(386 m2/g)以及影响反应效果的几个优化参数的协同作用有关。此外,在不牺牲性能的情况下重复使用NPs(五次)证实了它们的稳定性和可持续性,是大规模工业纺织废水补救的有希望的候选者。
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引用次数: 0
Green approach to La2O3/ZnO nanocomposites synthesis via Jatropha curcas latex: Implications in photocatalysis 利用麻疯树乳胶合成La2O3/ZnO纳米复合材料的绿色途径:在光催化中的意义
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-05-05 DOI: 10.1016/j.jciso.2025.100140
Amit Sharma, Sahil Singh, Khyati Sharma, Kamal Thakur, Khushbu Choudhary, Aastha Patial, Tamana, Vikas Dhiman
This study presents a comprehensive investigation into the synthesis of zinc oxide (ZnO) nanoparticles and lanthanum oxide (La2O3)/ZnO nanocomposites using Jatropha curcas latex, emphasizing a sustainable green chemistry methodology. Characterization techniques, including X-ray diffraction (XRD), photoluminescence (PL) spectroscopy, scanning electron microscopy (SEM), and zeta sizer analysis, were employed to elucidate the crystalline structure, optical properties, morphology, and stability of the synthesized materials. The photocatalytic efficacy of the synthesized nanomaterials was rigorously evaluated for the solar-driven photocatalytic removal of methylene blue (MB) dye. Through systematic optimization, an optimal dosage of 3 mg/mL for the La2O3/ZnO nanocomposite was identified, demonstrating a significant enhancement in degradation efficiency over ZnO nanoparticles. Under these optimized conditions, the La2O3/ZnO catalyst achieved up to 87.71 % removal of MB (initial concentration of 10 mg/L in 100 mL) within 120 min of exposure to natural sunlight. Additionally, under UV irradiation, the MB solution exhibited an exceptional 95.16 % photodegradation, with an estimated rate constant of 0.03224 min−1 after 90 min of treatment with the La2O3/ZnO nanocomposite. To further assess the performance and applicability of the photocatalysts, recyclability studies, scavenger studies, and hot filtration tests were conducted, confirming the potential of eco-friendly La2O3/ZnO nanocomposites as effective agents for sustainable environmental remediation strategies. This research not only advances the field of photocatalysis but also contributes to the development of sustainable materials for pollution mitigation.
本研究以麻疯树乳胶为原料合成氧化锌纳米粒子和氧化镧/氧化锌纳米复合材料,强调可持续的绿色化学方法。表征技术包括x射线衍射(XRD)、光致发光(PL)光谱、扫描电镜(SEM)和zeta浆料分析,以阐明合成材料的晶体结构、光学性质、形貌和稳定性。对合成的纳米材料的光催化效果进行了严格的评价,用于太阳能光催化去除亚甲基蓝(MB)染料。通过系统优化,确定了La2O3/ZnO纳米复合材料的最佳用量为3 mg/mL,表明其降解效率明显高于ZnO纳米颗粒。在此优化条件下,La2O3/ZnO催化剂在自然光照120 min内对MB(初始浓度为10 mg/L / 100 mL)的去除率高达87.71%。此外,在UV照射下,MB溶液的光降解率高达95.16%,经La2O3/ZnO纳米复合材料处理90 min后,降解率约为0.03224 min−1。为了进一步评估光催化剂的性能和适用性,进行了可回收性研究、清除剂研究和热过滤试验,证实了La2O3/ZnO纳米复合材料作为可持续环境修复策略的有效剂的潜力。这项研究不仅推动了光催化领域的发展,也为可持续材料的发展做出了贡献。
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引用次数: 0
Effect of pH and concentration on physicochemical, adsorption kinetics and rheology properties of quinoa protein: Functional correlations pH和浓度对藜麦蛋白理化、吸附动力学和流变性能的影响:功能相关性
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-03-11 DOI: 10.1016/j.jciso.2025.100131
José Fernando Solanilla-Duque, Diego Fernando Roa-Acosta, Jesús Eduardo Bravo-Gómez
In the present manuscript protein isolates and hydrolysates have countless applications in the food industry due to their functional (solubility, emulsifying power, adsorption capacity, foaming capacity) and nutritional properties [1]. In the present manuscript, the interfacial, rheological, and functional properties of the quinoa protein isolate (QPI) at pH 5 and pH 7 were studied. Dilatational module behavior versus surface pressure was evaluated, using the Frumkin-Lucassen model for QPI, which showed a good fit in the first part of the curve (before achieving a plateau) evidencing the formation of the first interfacial layer. Moreover, the gel formation from QPI was evaluated at different concentrations (5, 10 and 15 % (w/w)). Rheological measurements indicated that higher protein concentrations at pH 5 resuts in a raise in the gel point temperature. It was also found that QPI showed better emulsifying and foaming capacity at pH 5 than at pH 7. An increase in the QPI concentration in the emulsion formulation produces greater thermal stability. The results obtained show the feasibility of using a quinoa protein isolate as an ingredient in functional foods (Modified (enriched or enhanced) foods, conventional foods, medicinal foods and foods for dietetic use.).
在目前的手稿中,蛋白分离物和水解物由于其功能(溶解度、乳化力、吸附能力、发泡能力)和营养特性在食品工业中有无数的应用。在本文中,研究了藜麦分离蛋白(QPI)在pH 5和pH 7下的界面、流变学和功能特性。使用QPI的Frumkin-Lucassen模型评估了膨胀模态与表面压力的关系,该模型在曲线的第一部分(在达到平台之前)显示出良好的拟合,证明了第一界面层的形成。此外,研究了不同浓度(5%、10%和15% (w/w))下QPI的凝胶形成情况。流变学测量表明,在pH值为5时,较高的蛋白质浓度会导致凝胶点温度升高。QPI在ph5条件下的乳化发泡性能优于ph7条件。在乳液配方中增加QPI浓度会产生更大的热稳定性。研究结果表明,将藜麦分离蛋白作为功能性食品(改良(强化或强化)食品、常规食品、药用食品和营养食品)的成分是可行的。
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引用次数: 0
Selective flotation of carbonate minerals 碳酸盐矿物的选择性浮选
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-04-24 DOI: 10.1016/j.jciso.2025.100137
Manas Barai , Tanmay Dutta , Anuttam Patra
This study explores the selective flotation of carbonate minerals-dolomite, magnesite, and calcite using amino acid-based single- and double-headed collectors. The separation efficiency was evaluated using microflotation experiments, ζ potential measurements, UV–Vis spectroscopy, FTIR spectroscopy, and molecular modelling. The study aimed to understand how the molecular architecture of collectors influences their adsorption behaviour on mineral surfaces, leading to selective flotation.
Flotation recoveries were measured at both natural and pH 10.5 conditions. The monocarboxylate collector (C12GlyNa) demonstrated high but non-selective recovery across all three minerals. In contrast, the double-headed collector, disodium N-dodecyl aminomalonate (C12MalNa2), exhibited strong selectivity, particularly for magnesite, due to optimal geometric matching between its head groups and the Mg-Mg atomic distances on the mineral surface. The amount of collector adsorbed was determined by UV–Vis analysis, while FTIR confirmed surface adsorption through characteristic alkyl stretching bands. ζ potential measurements supported these findings, showing that increased adsorption led to greater negative charge development on mineral surfaces. Molecular modelling further revealed that selective adsorption occurs when the collector's head group spacing aligns with metal-metal distances on the mineral surface, enabling effective electrostatic interactions.
These results highlight the potential for designing tailored collectors based on molecular recognition principles, offering a pathway for more efficient and selective flotation of carbonate minerals.
本研究探讨了利用氨基酸基单头和双头捕收剂对白云石、菱镁矿和方解石等碳酸盐矿物的选择性浮选。采用微浮选实验、ζ电位测量、紫外可见光谱、红外光谱和分子模型对分离效率进行了评价。该研究旨在了解捕收剂的分子结构如何影响它们在矿物表面的吸附行为,从而导致选择性浮选。测定了自然和pH 10.5条件下的浮选回收率。单羧酸盐捕收剂(C12GlyNa)在所有三种矿物中表现出高但非选择性的回收率。相比而言,双头捕收剂n -十二烷基氨基丙酸二钠(C12MalNa2)表现出较强的选择性,特别是对菱镁矿,由于其头基与矿物表面Mg-Mg原子距离之间的最佳几何匹配。通过UV-Vis分析确定了捕收剂的吸附量,而FTIR通过特征烷基拉伸带证实了表面吸附。ζ电位测量支持这些发现,表明增加的吸附导致更大的负电荷发展在矿物表面。分子模型进一步表明,当收集器的头部基团间距与矿物表面的金属-金属距离一致时,会发生选择性吸附,从而实现有效的静电相互作用。这些结果突出了基于分子识别原理设计定制捕收剂的潜力,为更有效和选择性地浮选碳酸盐矿物提供了途径。
{"title":"Selective flotation of carbonate minerals","authors":"Manas Barai ,&nbsp;Tanmay Dutta ,&nbsp;Anuttam Patra","doi":"10.1016/j.jciso.2025.100137","DOIUrl":"10.1016/j.jciso.2025.100137","url":null,"abstract":"<div><div>This study explores the selective flotation of carbonate minerals-dolomite, magnesite, and calcite using amino acid-based single- and double-headed collectors. The separation efficiency was evaluated using microflotation experiments, ζ potential measurements, UV–Vis spectroscopy, FTIR spectroscopy, and molecular modelling. The study aimed to understand how the molecular architecture of collectors influences their adsorption behaviour on mineral surfaces, leading to selective flotation.</div><div>Flotation recoveries were measured at both natural and pH 10.5 conditions. The monocarboxylate collector (C<sub>12</sub>GlyNa) demonstrated high but non-selective recovery across all three minerals. In contrast, the double-headed collector, disodium <em>N</em>-dodecyl aminomalonate (C<sub>12</sub>MalNa<sub>2</sub>), exhibited strong selectivity, particularly for magnesite, due to optimal geometric matching between its head groups and the Mg-Mg atomic distances on the mineral surface. The amount of collector adsorbed was determined by UV–Vis analysis, while FTIR confirmed surface adsorption through characteristic alkyl stretching bands. ζ potential measurements supported these findings, showing that increased adsorption led to greater negative charge development on mineral surfaces. Molecular modelling further revealed that selective adsorption occurs when the collector's head group spacing aligns with metal-metal distances on the mineral surface, enabling effective electrostatic interactions.</div><div>These results highlight the potential for designing tailored collectors based on molecular recognition principles, offering a pathway for more efficient and selective flotation of carbonate minerals.</div></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"18 ","pages":"Article 100137"},"PeriodicalIF":0.0,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143894967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Entropy analysis of Hall-effect-driven TiO2−CoFe2O4/ engine oil-based hybrid nanofluid flow between spinning porous disks with thermal convective boundaries 霍尔效应驱动的TiO2−CoFe2O4/机油混合纳米流体在具有热对流边界的旋转多孔盘之间流动的熵分析
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-03-25 DOI: 10.1016/j.jciso.2025.100134
Sk Enamul , Surender Ontela
The applications of fluid dynamics and heat transfer between coaxial double-rotating disks are diverse and crucial across various engineering and scientific fields. This study is motivated by the growing need for efficient thermal management in advanced engineering applications, such as cooling systems, energy storage, and magnetohydrodynamic technologies. The research focuses on the heat transfer characteristics and entropy analysis of the flow of a second-grade hybrid nanofluid between two spinning porous disks, incorporating the effects of Hall currents, viscous dissipation, and thermal convective boundaries. The hybrid nanofluid consists of titanium dioxide and cobalt ferrite nanoparticles suspended in engine oil. The governing equations are transformed into non-dimensional forms using a similarity transformation and solved with the semi-analytical homotopy analysis method. Results reveal the effects of parameters on velocity, temperature profiles, Nusselt number, skin friction, entropy generation, and the Bejan number graphically. Notably, the temperature profile improves with increases in the Brinkman number and the thermal Biot number of the lower disk. In contrast, skin friction decreases with higher titanium dioxide volume fraction, porosity parameter, and magnetic field parameter. The heat transfer rate increases with a higher nanoparticle shape factor and magnetic field parameter. These findings offer significant implications for optimizing the thermal performance of nanofluids, particularly in advanced cooling systems, thermal energy storage, and magnetohydrodynamic applications where enhanced heat transfer and efficient thermal management are critical.
在不同的工程和科学领域中,流体动力学和同轴双旋转盘之间的传热的应用是多种多样的,也是至关重要的。这项研究的动机是在先进的工程应用中对高效热管理的日益增长的需求,如冷却系统、能量存储和磁流体动力学技术。考虑霍尔电流、粘性耗散和热对流边界的影响,研究了二级混合纳米流体在两个旋转多孔圆盘之间的传热特性和熵分析。混合纳米流体由悬浮在发动机油中的二氧化钛和钴铁氧体纳米颗粒组成。利用相似变换将控制方程转化为无量纲形式,并用半解析同伦分析法求解。结果显示了参数对速度、温度分布、努塞尔数、表面摩擦、熵产和贝让数的影响。值得注意的是,温度分布随着布林克曼数和下盘热Biot数的增加而改善。二氧化钛体积分数、孔隙度参数和磁场参数越高,表面摩擦力越小。纳米颗粒形状因子和磁场参数越高,传热速率越高。这些发现为优化纳米流体的热性能提供了重要的意义,特别是在先进的冷却系统、热能储存和磁流体力学应用中,增强的传热和有效的热管理是至关重要的。
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引用次数: 0
Heat transfer optimization in magnetohydrodynamic buoyancy-driven convective hybrid nanofluid with carbon nanotubes over a slippery rotating porous surface 磁流体动力浮力驱动的碳纳米管对流混合纳米流体在光滑旋转多孔表面上的传热优化
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-03-24 DOI: 10.1016/j.jciso.2025.100132
Thirupathi Thumma , Surender Ontela , Devarsu Radha Pyari , S.R. Mishra , Subhajit Panda
Hybrid nanofluids containing carbon nanotubes possess the potential to augment thermal conductivity and are also employed in heat management applications. These nanofluids combine two kinds of nanostructures (single-wall and multi-wall) and have better energy conversion, cooling, and heat transmission qualities. Because of their tiny size and strength, carbon nanotubes (CNT) are used to increase machinery and components lubrication and boost system energy storage and charging cycle effectiveness of lithium-ion batteries. Therefore, a mathematical model is formulated to study the hydromagnetic CNT hybrid nanofluid mixed convective flow past an elongating porous surface in the occurrence of external heat source, thermal linear radiation, viscous and Joule dissipation. The nanoparticle diameter and interfacial layer effects are explored by incorporating the Gharesim dynamic viscosity model and Hamilton–Crosser thermal conductivity model. The partial differential equations (PDEs) defining the considered fluid flow are transformed into ordinary differential Equations (ODEs) utilizing predefined similarity transformations. The numerical Runge-Kutta method and shooting procedure are employed to obtain the outcomes. The current study establishes that the liquid momentum is controlled for the slip flow, thus with the slip condition, the amount of retardation is much higher in comparison with the no-slip condition, and the temperature of the hybrid nanofluid has been raised by a greater heat source coefficient and radiation factor. Further, the sensitivity and optimization analysis of the heat transmission rate is carried out using RSM with face-centered central composite design model of experiments. Sensitivity analysis reveals that the highest evaluated value 0.006330 of heat transmission rate is identified at the uncoded values ϕSWCNT=0.01,ϕMWCNT=0.01,N=0.10 and the least value −0.002590 is identified at the uncoded values of ϕSWCNT=0.01,ϕMWCNT=0.03,N=0.10
含有碳纳米管的混合纳米流体具有增强导热性的潜力,也被用于热管理应用。这些纳米流体结合了两种纳米结构(单壁和多壁),具有更好的能量转换、冷却和传热性能。由于其微小的尺寸和强度,碳纳米管(CNT)被用于增加机械和部件的润滑,提高锂离子电池的系统能量储存和充电循环效率。为此,建立了一个数学模型,研究了在外加热源、热线性辐射、粘性和焦耳耗散的情况下,液磁碳纳米管混合纳米流体通过细长多孔表面的混合对流流动。结合Gharesim动态黏度模型和Hamilton-Crosser热导率模型,探讨了纳米颗粒直径和界面层效应。利用预定义的相似变换,将定义所考虑流体流动的偏微分方程(PDEs)转换为常微分方程(ode)。采用数值龙格-库塔法和射击程序进行计算。本研究发现,滑移流动控制了液体动量,因此在滑移条件下,滞阻量比无滑移条件下要大得多,并且混合纳米流体的温度被更大的热源系数和辐射因子所提高。在此基础上,采用面心中心复合设计实验模型,对传热率进行了灵敏度分析和优化设计。灵敏度分析表明,在未编码的条件下,传热率的最大值为0.006330;在未编码的条件下,传热率的最小值为- 0.002590;而在未编码的条件下,则为- 0.006330
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引用次数: 0
Consolidation of carbonates using hydrolysed polyacrylamide: Effect of temperature, pressure, salinity, and nanoparticle crosslinking 用水解聚丙烯酰胺固结碳酸盐:温度、压力、盐度和纳米颗粒交联的影响
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-03-28 DOI: 10.1016/j.jciso.2025.100135
Jin Hau Lew , Omar K. Matar , Erich A. Müller , Adrielle Sousa Santos , Myo Thant Maung Maung , Paul F. Luckham
This paper discusses a comprehensive three-part experimental study on the consolidation of calcium carbonate (CaCO3) via hydrolysed polyacrylamide (HPAM). The first part involves the consolidation ability of HPAM on CaCO3 investigated under room conditions. The setups in this work are dilute (1:25 mass ratio of CaCO3 to HPAM) and concentrated (1:2 mass ratio) colloidal systems, and an incubation of Iceland spar calcite crystal in dilute HPAM solution. UV–Vis absorption, zeta potential, oscillatory rheology in the form of storage modulus (G’), unconfined compression stress (UCS), and atomic force microscopy (AFM) force mapping, reveal positive interactions and increased consolidation with higher HPAM dosage, up to an optimum level. The second part explores the impact of reservoir conditions, namely salinity and temperature, on the consolidating ability of HPAM. Salinity tests indicate a higher polymer dosage requirement under increased salt concentration to maintain optimum CaCO3 consolidation, while temperature tests show a reduction in peak mechanical strength of consolidated CaCO3 samples. In the final part, the preservation of the effectiveness of deploying HPAM in reservoir conditions by crosslinking it with silica nanoparticles (SiONP) is explored. The results from G′ and UCS analyses demonstrate that CaCO3 consolidated by crosslinked HPAM retains peak mechanical strength even when treated with brine and subjected to continuous heating for three days. This extensive investigation into the consolidation of CaCO3 by HPAM provides valuable insights into the potential use of HPAM for strengthening reservoir rocks, with the novel approach of crosslinking showing promise for preserving its usability in challenging reservoir conditions.
本文对水解聚丙烯酰胺(HPAM)对碳酸钙(CaCO3)的固结进行了三部分实验研究。第一部分研究了室温条件下HPAM对CaCO3的固结能力。本研究设置了稀释(CaCO3与HPAM的质量比为1:25)和浓缩(质量比为1:2)的胶体体系,并在稀释的HPAM溶液中孵育冰岛石方解石晶体。UV-Vis吸收、zeta电位、振荡流变以存储模量(G’)、无侧限压缩应力(UCS)和原子力显微镜(AFM)力图的形式显示出正向相互作用,并随着HPAM剂量的增加而增加固结,达到最佳水平。第二部分探讨了储层条件,即矿化度和温度对HPAM固结能力的影响。盐度测试表明,在盐浓度增加的情况下,为了保持最佳的CaCO3固结,聚合物用量要求更高,而温度测试表明,固结CaCO3样品的峰值机械强度降低。最后,探讨了通过与二氧化硅纳米颗粒(SiONP)交联来保持HPAM在储层条件下的有效性。G′和UCS分析的结果表明,通过交联HPAM固结的CaCO3即使经过卤水处理并连续加热3天,也能保持峰值机械强度。这项对HPAM固结CaCO3的广泛研究,为HPAM加固储层岩石的潜在用途提供了有价值的见解,新型交联方法有望在具有挑战性的储层条件下保持其可用性。
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引用次数: 0
Enhanced corrosion resistance of aluminum 6061 alloy using Ti-based thin films and plasma nitriding 采用ti基薄膜和等离子渗氮增强6061铝合金的耐蚀性
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-04-28 DOI: 10.1016/j.jciso.2025.100139
Margono , Djarot B. Darmadi , Femiana Gapsari , Teguh Dwi Widodo , Bayu Mahdi Kartika
The corrosion resistance of aluminum alloys is a critical factor limiting their application in aggressive environments, particularly those containing chloride ions. Aluminum 6061, despite its high strength-to-weight ratio, suffers from localized corrosion in such conditions. In this study, Ti, Ti-Ni, and Ti-Ni-N thin films were deposited on aluminum 6061 alloy using the DC sputtering method, followed by plasma nitriding for the Ti-Ni-N film. The results showed that the Ti-Ni film exhibited the best corrosion resistance of 3.64 × 10−4 mm/year, with the lowest icorr of 2.80 × 10−4 A/cm2 and the highest protection efficiency, due to the formation of a stable passive layer. The Ti-Ni-N film also demonstrated enhanced hardness of 392.4 HV, though with slightly higher surface roughness of 5.76 μm. This research contributes to the development of more durable coatings for aluminum alloys, providing improved corrosion resistance in chloride-rich environments.
铝合金的耐腐蚀性是限制其在腐蚀性环境中应用的关键因素,特别是在含有氯离子的环境中。尽管铝6061的强度重量比很高,但在这种条件下会受到局部腐蚀。本研究采用直流溅射法在6061铝合金上沉积Ti、Ti- ni和Ti- ni - n薄膜,然后对Ti- ni - n薄膜进行等离子渗氮处理。结果表明,Ti-Ni膜的耐蚀性能最佳,为3.64 × 10−4 mm/年,icorr最低,为2.80 × 10−4 A/cm2,由于形成了稳定的钝化层,其防护效率最高。Ti-Ni-N膜的硬度达到392.4 HV,但表面粗糙度略高,为5.76 μm。这项研究有助于开发更耐用的铝合金涂层,在富含氯化物的环境中提供更好的耐腐蚀性。
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引用次数: 0
Colloidal structure, energy extensivity and Monte Carlo sampling properties of improved short-range interaction models for surfactant-coated magnetic nanoparticles 表面活性剂包覆磁性纳米颗粒改进的短程相互作用模型的胶体结构、能量延展性和蒙特卡罗采样特性
Q3 Materials Science Pub Date : 2025-07-01 Epub Date: 2025-05-13 DOI: 10.1016/j.jciso.2025.100138
Aimê Gomes da Mata Kanzaki , Tiago de Sousa Araújo Cassiano , João Valeriano , Fabio Luis de Oliveira Paula , Leonardo Luiz e Castro
The standard DLVO theory offers a limited description of ionic-surfacted magnetic colloids in near aggregation regimes. Correcting the electrical double layer term for ionic surfactants is not enough to successfully simulate the systems. The correction of the van der Waals energy divergence at short interparticle distances is fundamental for proper Monte Carlo sampling of nanoparticles’ configurations. We compare different short-range interaction models and show that a more detailed model leads to Monte Carlo simulations that better match theoretical expectations. Studying the energy scaling with the number of particles, we observe a slight deviation from energy extensivity across all models, small but still detectable via Akaike’s information criterion. The more detailed model predicts a strong effect of particle-size dispersity on the transition between overall attraction and repulsion. More precise modeling can significantly affect numerical predictions, in particular, the effect of particle-size dispersity on the spatial structure of colloids with high volume fraction. This emphasizes the importance of nailing down better models for describing complex colloidal dispersions.
标准DLVO理论提供了一个有限的描述离子表面的磁性胶体在近聚集制度。修正离子表面活性剂的双电层项不足以成功地模拟系统。在粒子间距离较短的情况下,范德华能量散度的校正是对纳米粒子结构进行适当的蒙特卡罗采样的基础。我们比较了不同的短程相互作用模型,并表明更详细的模型导致蒙特卡罗模拟更好地符合理论期望。通过研究粒子数量的能量尺度,我们观察到所有模型的能量广泛性都有轻微的偏差,虽然很小,但通过赤池的信息准则仍然可以检测到。更详细的模型预测,颗粒大小的分散性对整体吸引力和排斥力之间的转变有很强的影响。更精确的模拟可以显著影响数值预测,特别是粒径分散性对高体积分数胶体空间结构的影响。这强调了确定更好的模型来描述复杂胶体分散的重要性。
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