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Land-Cover Removal and Gully Development in Southeast Nigeria: A 30-Year Analysis with Pixel and OBIA Approaches in Juxtaposition 尼日利亚东南部土地覆盖去除和沟壑发展:用像素和OBIA方法并列的30年分析
Pub Date : 2020-06-09 DOI: 10.3844/ajessp.2020.34.47
S. Iro
In this study a study of gully erosion in southeast Nigeria is presented. The study of gully development on a regional scale is currently undermined by the inherent costs associated with consistent field monitoring and the lack of historic measurements to perform time series analysis. As a result, there are very few studies which implement long term analyses of gullies in the region as a collective. Consequently, the building of knowledge of the role of environmental changes on the development of gullies is inhibited. Remote sensing methodologies, via the Landsat archive, are used as low economic data source that assisted in the analyses of gullies over the time period 1986 to 2015. The Landsat data is used to establish land cover changes over the time period, via pixel and object-based classification, to identify its role in gully development. The use of classification for this purpose identifies this study as a first of its kind in Nigeria. Aiming to link environmental characteristics and land cover changes with gully development and erosion rates at multiple current locations. In terms of the correlation between vegetation area and gully/openland development, Pixel based classification produced a correlation of r = -0.9 (p<0.05). A similar strength of correlation was exhibited for OBIA with r = -0.9 (p<0.05) with both results indicating a very strong and significant negative correlation between the amount of vegetated area and Gully/open-land development over the study period 1986-2015.
在这项研究中,对尼日利亚东南部的沟壑侵蚀进行了研究。目前,在区域范围内对沟壑发展的研究由于持续实地监测的固有费用和缺乏进行时间序列分析的历史测量而受到损害。因此,很少有研究将该地区的沟壑作为一个集体进行长期分析。因此,对环境变化对沟壑发育作用的认识的建立受到了抑制。通过Landsat存档的遥感方法被用作低经济数据源,协助分析1986年至2015年期间的沟渠。Landsat数据用于通过像素和基于目标的分类来确定土地覆盖在一段时间内的变化,以确定其在沟壑发展中的作用。为此目的使用分类方法,这一研究在尼日利亚尚属首次。旨在将当前多个地点的环境特征和土地覆盖变化与沟壑发育和侵蚀速率联系起来。在植被面积与沟壑/空地发育的相关性方面,基于Pixel的分类产生了r = -0.9 (p<0.05)的相关性。OBIA的相关系数为-0.9 (p<0.05),两者均表明1986-2015年植被面积与沟壑区/开阔地开发呈显著负相关。
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引用次数: 2
Comparative Effects and Phytotoxicity of Photo Fenton Solutions and Acid Rains on Cucumber (Cucumis Sativus) Plants: Treats and Console 光Fenton溶液和酸雨对黄瓜(cucumsativus)植物的比较效应和毒性:处理和对照
Pub Date : 2020-05-21 DOI: 10.3844/ajessp.2020.21.33
F. Eissa, S. Bandai, N. Zidan, I. Oguntimehin, H. Sakugawa
The Eco-physiological assessments of variable parameters known to be essential for proper plant growth and health were determined in cucumber plants exposed to short term treatments in 42 days using two broad classification types; Photo Fenton solution generating OH radicals and simulated acids. Solutions containing different classification of scavengers of OH radicals and mannitol were employed as Controls. Results indicated that the acid rain and photo Fenton solution both decreased the photosynthetic rate (Amax), stomatal conductance (gs), photochemical efficiency of PSII in the dark (Fv/Fm), SPAD chlorophyll and they imparted severe foliar injuries on cucumber leaves. The acids treatments have the highest negative impact followed by the photo Fenton Solution. The mechanisms of phytotoxicity of the two solutions may be through OH radical and other Reactive Oxygen Species (ROS) generation. The addition of mannitol, catechin hydrate and tea solutions to the acids and photo Fenton solution mixtures all mitigated the negative effects of the duo on the cucumber plants. Mannitol at dosage applied in the present study can be adjudged to be the best in the amelioration of the negative effects of the fumigants. Future plant protection from deleterious impacts of atmospheric and hydrospheric pollutants can employ mannitol as scavengers of ROS.
在短期处理42天的黄瓜植株中,采用两种分类方法对已知对植物正常生长和健康至关重要的可变参数进行了生态生理评估;照片芬顿溶液产生OH自由基和模拟酸。以含有不同种类OH自由基清除剂和甘露醇的溶液为对照。结果表明,酸雨和光Fenton溶液均降低了黄瓜叶片的光合速率(Amax)、气孔导度(gs)、PSII在黑暗中的光化学效率(Fv/Fm)和SPAD叶绿素,并对黄瓜叶片造成了严重的叶片损伤。酸处理的负面影响最大,其次是光芬顿溶液。两种溶液的植物毒性机制可能是通过OH自由基和其他活性氧(ROS)的产生。甘露醇、水合儿茶素和茶溶液加入到酸和光Fenton溶液混合物中,均减轻了这两种物质对黄瓜植株的负面影响。本研究使用的甘露醇剂量在改善熏蒸剂的副作用方面效果最好。未来的植物保护免受大气和水圈污染物的有害影响可以使用甘露醇作为活性氧的清除剂。
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引用次数: 0
Determining Causes of Gully Erosion and Associated Rates of Change in South-east Nigeria, Using a Remote Sensing and GIS Methodology 利用遥感和地理信息系统方法确定尼日利亚东南部沟壑侵蚀的原因和相关的变化率
Pub Date : 2020-05-01 DOI: 10.3844/AJESSP.2020.96.111
S. Iro
In this work a study of gully erosion in southeast Nigeria is presented. The study of gully development on a regional scale is currently undermined by the inherent costs associated with consistent field monitoring and the lack of historic measurements to perform time series analysis. The analysis of study area topography at 30m resolution reveals 85% of the surveyed gullies develop on concave slopes with high values of 6 plan curvatures and >50 inclines. Results also reveal high association with ferralsols soils. Statistical analysis to determine significance of variables on the proportional yearly gully change in metre squared per square metre were conducted via principle component analysis. The analysis of this work was restricted to the time periods 2006/7, 2009/10, and 2014/15. The approach did not report any existence of one singular driver of erosion across the studied years and multiple sites confirming the complexity of gullies. The PCA showed that the level of variance explained in the yearly gully change variable was most similar in PC1 (representing the component with the highest eigenvalue) to Vegetation loss, Vegetation loss and slope in the respective years.The study offers a method of monitoring gully development from early stage to maturity and exemplifies the complexity and variability of erosion drivers in the SE Nigeria region. It presents a verified approach to local and regional monitoring of gullies, enacted through use of low budget/computing cost remote sensing and classification technologies, and serves to embolden civilian and governmental efforts to manage the societal and environmental menace of gully erosion.
在这项工作中,对尼日利亚东南部的沟侵蚀进行了研究。目前,在区域范围内对沟壑发展的研究由于持续实地监测的固有费用和缺乏进行时间序列分析的历史测量而受到损害。研究区30m分辨率地形分析显示,85%的沟发育在6个平面曲率值高、坡度>50的凹坡上。结果还显示与铁矾土高度相关。通过主成分分析确定各变量对每平方米沟面积年变化比例的显著性。这项工作的分析仅限于2006/7、2009/10和2014/15期间。该方法没有报告在研究的年份中存在任何单一的侵蚀驱动因素,也没有多个地点证实沟壑的复杂性。主成分分析表明,各年份沟谷变化变量在PC1(代表特征值最高的分量)中解释的方差水平与植被损失、植被损失和坡度最相似。该研究提供了一种监测沟沟从早期到成熟发育的方法,并举例说明了尼日利亚东南部地区侵蚀驱动因素的复杂性和可变性。它通过使用低预算/计算成本遥感和分类技术,提出了一种经过验证的地方和区域沟壑监测方法,并有助于鼓励民间和政府努力管理沟壑侵蚀的社会和环境威胁。
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引用次数: 5
Computational Analysis of Environmental Risk Conditioners 环境风险调节器的计算分析
Pub Date : 2020-05-01 DOI: 10.3844/ajessp.2020.85.95
Barbara Carla Coelho Batista, João Victor Dutra Balboa, C. Dima, Jordan Henrique de Souza, Marcelo Caniato Renhe, Gislaine dos Santos, L. C. Campos
The intense urbanization process since the 1970s, coupled with the lack of adequate housing and social policies, has led large urban centers to disordered occupations and situations of geotechnical risk. These occupations were not implemented in a technically correct manner from the point of view of civil engineering, considering landscaping, drainage and paving, as well as edification. Areas at risk are regions where it is not recommended to build houses or facilities because they are very exposed to natural disasters, such as landslides and floods. In Brazil, the main institution responsible for monitoring areas at risk is the Civil Defense. There is a large database with history of occurrences of risk areas served by the Municipal Civil Defense, in Juiz de Fora city, Minas Gerais state - Brazil, from 1996 to 2017. Some important information contained in this database are the physical aspects of the soil, such as slope, geolocation, amplitude, curvature and accumulated flow, as well as processed data from the sliding risk susceptibility methodologies. The objective of this work is to apply machine learning techniques to identify, from the mentioned database, the susceptibility to the risk of environmental disasters in regions that have not yet participated in events attended by the municipal civil defense. This database is large and unbalanced, thus it is necessary to apply data analysis methodologies so that the machine learning model can correctly identify the standards with the least human intervention. In this study, areas were classified according to risk susceptibility. After the whole process, it was possible to analyze the performance of the algorithms and select some of them, which obtained the best results, with an accuracy of around 80%.
20世纪70年代以来强烈的城市化进程,加上缺乏适当的住房和社会政策,导致大城市中心出现无序的职业和岩土工程风险。从土木工程的角度来看,这些职业并没有以技术上正确的方式实施,考虑到景观美化,排水和铺路,以及教育。有风险的地区是不建议建造房屋或设施的地区,因为这些地区非常容易受到山体滑坡和洪水等自然灾害的影响。在巴西,负责监测危险地区的主要机构是民防部门。有一个大型数据库,其中包含1996年至2017年巴西米纳斯吉拉斯州Juiz de Fora市市民防局服务的风险区域的历史。该数据库中包含的一些重要信息是土壤的物理方面,如坡度、地理位置、振幅、曲率和累积流量,以及从滑动风险敏感性方法处理的数据。这项工作的目的是应用机器学习技术,从上述数据库中识别尚未参加市政民防活动的地区对环境灾害风险的易感性。该数据库庞大且不平衡,因此有必要应用数据分析方法,使机器学习模型能够在最少人为干预的情况下正确识别标准。在本研究中,根据风险易感性对区域进行了分类。在整个过程之后,可以对算法的性能进行分析,并从中选择一些算法,得到了最好的结果,准确率在80%左右。
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引用次数: 0
Seasonal Variation of Heavy Metal Concentrations in Farm Soils of Sreepur Industrial Area of Gazipur, Bangladesh: Pollution Level Assessment 孟加拉国加齐浦尔斯里普尔工业区农田土壤重金属浓度的季节变化:污染水平评估
Pub Date : 2020-04-01 DOI: 10.3844/ajessp.2020.68.78
Md. Billal Hossain, Md. Nurul Islam, M. S. Alam, Md Zakir Hossen
A study was conducted to measure the seasonal variation of different heavy metal contents in farm soils of Sreepur Upazila of Gazipur district and to assess their pollution level. Industrial affected and non-affected soil samples were collected from 5 locations in three seasons viz. pre-monsoon (April), monsoon (August), and dry season (January), thus a total of 30 soil samples were analyzed for this study. Concentrations of different heavy metals (Cd, Pb, Cr, Ni, Cu, and Zn) in soil samples were determined by an Atomic Absorption Spectrophotometer (AAS). The mean total concentration of Cd, Pb, Cr, Ni, Cu and Zn in industrial affected soils were trace, 12.05, 101.10, 51.32, 20.79 and 55.40 mg kg-1, respectively in the pre-monsoon, trace, 28.54, 40.96, 22.70, 2.46 and 7.72 mg kg-1, respectively in the monsoon and 0.27, 10.49, 39.45, 20.69, 1.85 and 4.11 mg kg-1, respectively in the dry season. All heavy metal concentrations in industrial affected soil samples were higher than the corresponding non-affected sites. The study results revealed that Cd contents in the dry season and Pb contents in the monsoon season for industrial affected soils were higher compared to the average earth’s crust abundance value. The geoaccumulation index (Igeo) values for Pb of industrial affected soils ranged from 0.30-0.85 in the monsoon that means Igeo class 1, indicating unpolluted/moderately polluted soil quality. Furthermore, the calculated Igeo value for one industrial affected location revealed moderate soil pollution by Cr in the pre-monsoon season and unpolluted/moderately polluted soil quality by Ni and Cd in the pre-monsoon and the dry season, respectively. The measured pollution load index (PLI) values were also higher in all industrially polluted sites than corresponding non-polluted sites in three seasons, which indicates pollution load due to anthropogenic sources.
对加济浦尔地区Sreepur Upazila农田土壤中不同重金属含量的季节变化进行了测定,并对其污染程度进行了评价。在季风前(4月)、季风期(8月)和旱季(1月)3个季节,从5个地点采集了受工业影响和未受工业影响的土壤样本,共30份土壤样本进行了研究。采用原子吸收分光光度法(AAS)测定了土壤样品中不同重金属Cd、Pb、Cr、Ni、Cu和Zn的含量。工业影响土壤Cd、Pb、Cr、Ni、Cu和Zn的平均总浓度在季风前期分别为微量、12.05、101.10、51.32、20.79和55.40 mg kg-1,季风期分别为微量、28.54、40.96、22.70、2.46和7.72 mg kg-1,旱季分别为0.27、10.49、39.45、20.69、1.85和4.11 mg kg-1。工业污染土壤样品中重金属浓度均高于相应的非污染场地。研究结果表明,与地壳丰度平均值相比,工业影响土壤的旱季Cd含量和季风季Pb含量较高。季风期工业污染土壤Pb的地质积累指数(Igeo)值在0.30 ~ 0.85之间,为1级,表明土壤质量未受污染/中度污染。此外,一个工业影响地点的Igeo值计算结果显示,季风前季节土壤受Cr中度污染,季风前和旱季土壤受Ni和Cd中度污染。在3个季节中,所有工业污染场地的污染负荷指数(PLI)均高于相应的非污染场地,反映了人为污染源的污染负荷。
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引用次数: 3
Landslide Susceptibility Analysis Using Numerical and Neural Network, Near Kedarnath, Uttarakhand, India 基于数值和神经网络的滑坡易感性分析,印度北阿坎德邦克达尔纳特附近
Pub Date : 2020-03-09 DOI: 10.3844/ajessp.2020.8.20
V. Singh, T. Ansari, V. Vishal, T. Singh
The major concern in hilly regions is the stability of those slopes, which have been proclaimed due to unplanned excavation and uneven blasting during road widening and development activity. These slopes again become more vulnerable under dynamic loading and/or various types of human involvement, heavy rainfall and seismic activity. Failure of these slopes leads to loss of property and human being, disruption of traffics and environmental degradation. The Kedarnath area is the most vulnerable hilly terrain due to its inferred locality. To analyze the vulnerability near Kedarnath, the field observation was done to collect the geological and geotechnical details of three vulnerable locations. The present article illustrates the collective analysis of numerical simulation and artificial intelligence (ANN) models for the chosen vulnerable soil slopes. Numerical modeling was done to compute safety factor, stress distribution and maximum displacement using LEM and FEM modules. Further, the machine learning technique, ANN was also functionate to predict the stability based on geotechnical data’s and numerical simulation results. The numerical analysis for the homogenous finite slopes shows that slopes are stable, critically stable and also prone to failure during rainy season. The ANN model evaluate that, the FoS by numerical modeling displays 98% validation to predictive neural networking system. The simulation result could be effectively applied to lessen/decrease the effect of regularity for the landslides in the area of particular morphology.
丘陵地区的主要问题是这些斜坡的稳定性,这些斜坡是由于道路拓宽和发展活动期间未经计划的开挖和不均匀的爆破而被宣布的。这些斜坡在动力载荷和/或各种人类活动、强降雨和地震活动下变得更加脆弱。这些斜坡的破坏导致财产和人员的损失,交通中断和环境退化。Kedarnath地区是最脆弱的丘陵地形,因为它的推断位置。为了分析Kedarnath附近的易损性,进行了野外观测,收集了三个易损点的地质和岩土细节。本文阐述了数值模拟和人工智能(ANN)模型对所选脆弱土坡的集体分析。采用LEM和FEM进行数值模拟,计算安全系数、应力分布和最大位移。此外,基于岩土力学数据和数值模拟结果,运用机器学习技术,人工神经网络进行稳定性预测。对均质有限边坡的数值分析表明,边坡在雨季是稳定的、临界稳定的,但也容易破坏。通过对人工神经网络模型的数值模拟,对预测神经网络系统的有效性达到98%。模拟结果可以有效地应用于特定形态区域的滑坡中,减轻规律性的影响。
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引用次数: 0
Background Gamma Radiation in Nigerian Market Environment 尼日利亚市场环境中的本底伽马辐射
Pub Date : 2020-03-01 DOI: 10.3844/ajessp.2020.48.54
C. Ononugbo, U. Anekwe
Human exposure to ionizing radiation from natural sources is an unending and unpreventable phenomenon on earth. Radiation profile and exposure risks for some major markets in Port Harcourt metropolis have been ascertained using radiation exposure rate meter (Radalert-100). The exposure rate measured at mile 3 market and its environs ranged from 0.001±0.0001 to 0.022±0.003 mRh-1 with mean value of 0.014±0.002 mRh-1 while that measured at mile 1 ranged from 0.011±0.001 to 0.018±0.003 mRh-1 with mean value of 0.014±0.002 mRh-1. The exposure rate measured at Rumu-Okoro market ranged from 0.010±0.0001 to 0.018±0.003 mRh-1. The exposure rates measured at the three markets are relatively equal but slightly higher than the recommended safe value of 0.013 mRh-1. The mean absorbed doses estimated from the exposure rates for Mile 3, Mile 1 and Rumu-Okoro are 119.2, 113.68 and 114.8 nGyh-1 respectively, while their mean equivalent doses are 1.15, 1.19 and 1.11 mSvy-1 respectively. The annual effective dose calculated gave mean values of 0.14, 0.16 and 0.168 mSvy-1. These values are lower than the stipulated safe value of 1.0 mSvy-1. The excess lifetime cancer risk estimated exceeded the recommended values in all the sampling points. From the radiation profile of the sampled markets, no immediate radiation risk is expected though there could be a long term effects on the sellers in those markets.
人类受到自然来源的电离辐射是地球上一个无休止和不可预防的现象。使用辐射暴露率计(Radalert-100)确定了哈科特港大都会一些主要市场的辐射概况和暴露风险。3英里市场及其周围的暴露率范围为0.001±0.0001 ~ 0.022±0.003 mRh-1,平均值为0.014±0.002 mRh-1; 1英里市场的暴露率范围为0.011±0.001 ~ 0.018±0.003 mRh-1,平均值为0.014±0.002 mRh-1。Rumu-Okoro市场的暴露率范围为0.010±0.0001 ~ 0.018±0.003 mRh-1。在三个市场测量的暴露率相对相等,但略高于建议的安全值0.013 mRh-1。根据暴露率估算的Mile 3、Mile 1和Rumu-Okoro的平均吸收剂量分别为119.2、113.68和114.8 nGyh-1,其平均等效剂量分别为1.15、1.19和1.11 mSvy-1。计算出的年有效剂量平均值分别为0.14、0.16和0.168 mSvy-1。这些数值低于规定的安全值1.0 msv -1。在所有的采样点中,估计的终生癌症风险都超过了推荐值。从抽样市场的辐射情况来看,预计不会立即出现辐射风险,但这些市场的卖家可能会受到长期影响。
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引用次数: 2
Absorption of Food Along the Guts of Parachanna obscura and Clarias gariepinus 暗色伞蛾和克拉丽蝇肠道对食物的吸收
Pub Date : 2020-02-26 DOI: 10.3844/ajessp.2020.1.7
E. Idowu, Adewumi A. Adejoke, J. B. Edward, Dolapo Odeyemi, F. A. Ola-Oladimeji, Akintayo Joshua Oluwaseun
The knowledge of feeding habit and absorption of food in the gut of fish is important for fish farmers to boost their production and meet the ever increasing demand for man consumption. The carbohydrate, protein and lipid contents of the food ingested and their absorption in the intestine of Parachanna obscura and Clarias gareipinus inhabiting Ogbese River in Ekiti State were investigated. For Parachanna obscura, total protein of the ingested food was 64.54%, total carbohydrate 20.20% while the total lipid in the stomach content was 6.12% of organic matter. The total percentages of the food absorbed were 76.4% protein, 35.9% carbohydrate and 25.2% lipid. For Clarias gariepinus, total protein of the ingested food was 60.87%, total carbohydrate 30.42% while total lipid in the stomach content was 3.30% of organic matter. The total percentages of the food absorbed were 68.0% protein, 45.8% carbohydrate and 24.5% lipid. In both fish species the absorption of protein, carbohydrate and lipid occurred mostly in the fore-gut (the first one-third of the intestine). In Parachanna obscura, the foregut had the highest percentage absorption (59% protein, 24% carbohydrate and 15% lipid), while the hindgut had the lowest percentage absorption (4% protein, 4.6% carbohydrate and 3.3% lipid). In Clarias gariepinus, the foregut had the highest percentage absorption (41% protein, 34% carbohydrate and 14% lipid) while the hindgut had the lowest percentage absorption (4.1% protein, 3.6% carbohydrate and 3.3% lipid). The nutrients contents (protein, carbohydrate and lipid) of the food in Parachanna obscura were significantly different (P>0.05) from the nutrients (protein, carbohydrate and lipid) in the food of Clarias gariepinus. This will provide base-line information useful in artificial food formulation and culture of suitable live organisms for the species during culture of either species.
了解鱼类的摄食习惯和肠道对食物的吸收对养鱼户提高产量和满足不断增长的人类消费需求非常重要。研究了栖息在埃基蒂州Ogbese河的黑腹伞蛾(Parachanna obscura)和gareipinus对食物的碳水化合物、蛋白质和脂肪含量及其在肠道中的吸收情况。对暗色伞蛾,总蛋白质占总蛋白质的64.54%,总碳水化合物占总碳水化合物的20.20%,胃中总脂肪占有机物的6.12%。蛋白质、碳水化合物和脂肪的总吸收量分别为76.4%、35.9%和25.2%。饲料中总蛋白质占60.87%,总碳水化合物占30.42%,胃中总脂肪占有机质的3.30%。蛋白质、碳水化合物和脂肪的总吸收量分别为68.0%、45.8%和24.5%。在这两种鱼类中,蛋白质、碳水化合物和脂肪的吸收主要发生在前肠(肠的前三分之一)。暗色伞的前肠吸收率最高(蛋白质59%,碳水化合物24%,脂肪15%),后肠吸收率最低(蛋白质4%,碳水化合物4.6%,脂肪3.3%)。其中,前肠吸收率最高(蛋白质41%、碳水化合物34%、脂肪14%),后肠吸收率最低(蛋白质4.1%、碳水化合物3.6%、脂肪3.3%)。暗箱伞食物的营养物质(蛋白质、碳水化合物和脂肪)含量与鸡尾Clarias gariepinus食物的营养物质(蛋白质、碳水化合物和脂肪)含量差异显著(P>0.05)。这将为人工食品配方和培养适合该物种的活生物体提供有用的基线信息。
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引用次数: 0
Decalin Dissolving Method for Recover of Styrene –Butadiene Rubber from Scrap Tires 废轮胎中回收苯乙烯-丁二烯橡胶的十氢化萘溶解法
Pub Date : 2019-10-11 DOI: 10.3844/AJESSP.2019.145.153
A. M. Sultan, F. H. Jabrail
Decalin, a hydrocarbon industrial solvent was used for the recovery of Styrene- Butadiene Rubber (SBR) from grind scrap truck tires using chemical dissolving method. The applied technique is easy, simple and depends on available materials. The method depends mainly on steeping the scrap tires grind into decalin at 50?C for one month. Then the process was followed by boiling of the formed thick black solution (198°C) for two hours. The formed elastic rubber material will be reclaimed by precipitation in methanol. The recovered rubber was characterized using FTIR spectroscopy and XRD analyses.  The pattern of the recovered material shows broad maxima of SBR with the absence of XRD peaks of carbon black and almost all the other tire manufacturing additives. The thermal characteristics of the reclaimed rubber have been investigated by TGA, DTG and DSC analyses and were found to be close to those of thermal properties of SBR polymer. The SEM image has shown non-crystalline morphological surface of the recovered rubber with cohesive elastomeric properties.
以碳氢化合物工业溶剂十氢化萘为原料,采用化学溶解法从磨碎的废轮胎中回收苯乙烯-丁二烯橡胶。应用的技术是容易的,简单的,取决于可用的材料。该方法主要依靠将磨碎的废轮胎浸泡在50?租一个月。然后将形成的黑色浓溶液(198℃)煮沸2小时。形成的弹性橡胶材料将在甲醇中沉淀回收。利用FTIR光谱和XRD分析对回收的橡胶进行了表征。回收材料的XRD谱图显示SBR的最大值较宽,没有炭黑和几乎所有其他轮胎添加剂的XRD峰。利用热重分析(TGA)、差热分析(DTG)和差热分析(DSC)对再生橡胶的热特性进行了研究,发现再生橡胶的热特性与SBR聚合物的热特性接近。扫描电镜(SEM)图像显示,回收橡胶的非结晶形态表面具有内聚弹性体性能。
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引用次数: 2
Gadolinium at Low Concentration Suppresses both Osteoclastic and Osteoblastic Activities in the Scales of Goldfish 低浓度钆抑制金鱼鳞片破骨细胞和成骨细胞活性
Pub Date : 2019-09-20 DOI: 10.3844/AJESSP.2019.137.144
N. Suzuki, Kazuki Watanabe, Aika Sekimoto, M. Urata, M. Zanaty, T. Sekiguchi, Yoichiro Kitani, H. Matsubara, A. Srivastav, A. Hattori
For determining the effect of environmental pollutants on fish bone metabolism, we have developed an in vitro bioassay system using teleost scales that has osteoclasts, osteoblasts and bone matrix as markers: alkaline phosphatase (ALP) for osteoblasts and tartrate-resistant acid phosphatase (TRAP) for osteoclasts. Using this bioassay, the influence of gadolinium (Gd) on osteoclasts and osteoblasts of goldfish scales was examined in the present study. Gd sensitively inhibited TRAP activity. Even Gd at 10-13 M suppressed TRAP activity at 6 hours of incubation. At 18 hours of incubation, this inhibition occurred only at 10-7 and 10-6 M. After 36 hours of incubation, Gd did not influence TRAP activity. In osteoblasts, ALP activity was also suppressed by Gd in the range of 10-10 to 10-6 M for 6 to 18 hours of incubation. At 36 and 64 hours of incubation, ALP activity was significantly suppressed by Gd (36 hours: 10-9 to 10-6 M; 64 hours: 10-7 and 10-6 M). At 96 hours of incubation, however, Gd did not influence ALP activity. This is the first report to indicate the toxicity of Gd on fish bone metabolism using TRAP and ALP enzyme activities. The toxicity of Gd to osteoblasts is comparable to that of tributyltin, an aquatic environmental pollutant used as a biocide in anti-fouling paint. Gd is used in Magnetic Resonance Imaging (MRI) for clinical diagnoses. To avoid the toxicity of Gd ions, chelated forms, known as Gd-based contrast agents, are used for MRI diagnosis. Without a specific recycling process, these compounds are quickly released by urinary excretion and released into environmental waters. Therefore, it is possible that anthropogenic Gd influences aquatic animals. Considering our present data together with that of anthropogenic Gd pollution, we should conduct a Gd risk assessment to protect the ecosystem in the aquatic environment.
为了确定环境污染物对鱼骨代谢的影响,我们开发了一种体外生物测定系统,使用硬骨鱼鳞片,以破骨细胞、成骨细胞和骨基质为标记:碱性磷酸酶(ALP)用于成骨细胞,抗酒石酸酸性磷酸酶(TRAP)用于破骨细胞。采用生物测定法,研究了钆(Gd)对金鱼鳞片破骨细胞和成骨细胞的影响。Gd敏感地抑制TRAP活性。即使是10-13 M的Gd也能抑制6小时的TRAP活性。在孵育18小时时,这种抑制作用仅发生在10-7和10-6 m。孵育36小时后,Gd不影响TRAP活性。在成骨细胞中,Gd在10-10 ~ 10-6 M范围内抑制ALP活性,持续6 ~ 18小时。在孵育36和64 h时,Gd显著抑制ALP活性(36 h: 10-9 ~ 10-6 M;64小时:10-7 M和10-6 M)。然而,在96小时孵育时,Gd不影响ALP活性。这是第一次用TRAP和ALP酶活性研究Gd对鱼骨代谢的毒性。Gd对成骨细胞的毒性与三丁基锡相当,三丁基锡是一种水生环境污染物,用作防污涂料中的杀菌剂。Gd在磁共振成像(MRI)中用于临床诊断。为了避免Gd离子的毒性,被称为Gd基造影剂的螯合形式被用于MRI诊断。没有特定的回收过程,这些化合物很快通过尿液排泄释放到环境水体中。因此,可能是人为的Gd影响了水生动物。考虑到我们现有的数据和人为污染的数据,我们应该进行Gd风险评估,以保护水生环境的生态系统。
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引用次数: 3
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American Journal of Environmental Sciences
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