In this study Cross-linked PVA/Pullulan film was prepared. Cross-linking reaction done by addi-tion of gluteraldehyde at different reaction time (10,30and 60) min. Chemical interaction, me-chanical, thermal properties, water solubility and film morphology was studied for cross-linked PVA/Pullulan, PVA and Pullulan only. Thus FTIR investigated formation of hydrogen bonding between pullulan and PVA with (GA). Tensile strength, tensile modulus and elongation (%) at break for PVA/Pullulan film was improved with addition of (GA) as the reaction time proceed equivalent with increasing PVA content
{"title":"Affect the Cross Linking Degree and Polymer Composition on the Mechanical Properties of Poly (vinyl alcohol)/ Pullu-lan Films","authors":"S. A. Soud","doi":"10.23851/MJS.V28I2.504","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.504","url":null,"abstract":"In this study Cross-linked PVA/Pullulan film was prepared. Cross-linking reaction done by addi-tion of gluteraldehyde at different reaction time (10,30and 60) min. Chemical interaction, me-chanical, thermal properties, water solubility and film morphology was studied for cross-linked PVA/Pullulan, PVA and Pullulan only. Thus FTIR investigated formation of hydrogen bonding between pullulan and PVA with (GA). Tensile strength, tensile modulus and elongation (%) at break for PVA/Pullulan film was improved with addition of (GA) as the reaction time proceed equivalent with increasing PVA content","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82663587","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Dual polarization weather radar has now become a widely used as instrument in meteorological offices around the world because of its capability in distinguishing different precipitation type and in improving the accuracy of quantitative precipitation estimation. The aim of this work is to estimate the polarimetry radar variables for radars of different frequency bands and study their behavior with rainfall rates. Calculations of polarimetry radar variables were made on the basis of several assumptions. The results showed that factors at horizontal and vertical polarization, ZH,V, ranges between 20 dBz respectively, and more than 55 dBz for light rain and extreme heavy rain respectively, and radar reflectivity factor at horizontal ZH is greater than radar reflectivity factor at vertical ZV for all rainfall rates. The differential reflectivity, ZDR, also increases with increasing rainfall rates since it is the difference between ZH and Zv. Calculations of specific differential attenuation indicated that X band radars are seriously atten-uated by rain and C band radars are less affected by rain. The specific differential attenuation, S band radars is very small. In addition to this feature, the results showed that the differential phase shift between return signals of horizontal and vertical polarizations for S band radars is much less than those for C and X band radars, and also, the results showed that the co-polarization correlation coefficient for S band the radars is much higher than those of C and X bands. In order to investigate the accuracy of the calculated polarimetric weather radar variables per-formed in this research, real radar measurements were used for this purpose. Results indicated that the range of values for calculated polarimetric radar variables are very consistent with range of values for measured variables
{"title":"Estimation of Dual Polarization Weather Radar Variables","authors":"Dalia A. Mahmood","doi":"10.23851/MJS.V28I2.492","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.492","url":null,"abstract":"Dual polarization weather radar has now become a widely used as instrument in meteorological offices around the world because of its capability in distinguishing different precipitation type and in improving the accuracy of quantitative precipitation estimation. The aim of this work is to estimate the polarimetry radar variables for radars of different frequency bands and study their behavior with rainfall rates. \u0000Calculations of polarimetry radar variables were made on the basis of several assumptions. The results showed that factors at horizontal and vertical polarization, ZH,V, ranges between 20 dBz respectively, and more than 55 dBz for light rain and extreme heavy rain respectively, and radar reflectivity factor at horizontal ZH is greater than radar reflectivity factor at vertical ZV for all rainfall rates. The differential reflectivity, ZDR, also increases with increasing rainfall rates since it is the difference between ZH and Zv. \u0000Calculations of specific differential attenuation indicated that X band radars are seriously atten-uated by rain and C band radars are less affected by rain. The specific differential attenuation, S band radars is very small. In addition to this feature, the results showed that the differential phase shift between return signals of horizontal and vertical polarizations for S band radars is much less than those for C and X band radars, and also, the results showed that the co-polarization correlation coefficient for S band the radars is much higher than those of C and X bands. \u0000In order to investigate the accuracy of the calculated polarimetric weather radar variables per-formed in this research, real radar measurements were used for this purpose. Results indicated that the range of values for calculated polarimetric radar variables are very consistent with range of values for measured variables","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75417489","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cadmium oxide nanoparticles CdO NPS has been prepared by laser ablation in ethanol at 600 pulses and 600 mJ as laser energy. The structural, optical, and morphological properties of the cadmium oxide CdO thin film deposited on a glass substrate have been studied. X-ray diffrac-tometer (XRD 6000, Shimadzu, X-ray, diffractometer) with Cukα radiation at a wavelength of ( = 0.154056 nm) was utilized to investigate the structural properties of CdO NPs. The optical absorption of colloidal CdO NPs was measured using a spectrophotometer (Cary, 100 cans plus, UV-Vis-NIR, Split Beam Optics, Dual detectors) in the range of (200–900) nm. The morpholo-gy of the CdO NPs was investigated by using AFM (AA 3000 Scanning Probe Microscope). The thickness of the films was measured using ellipsometer (Angstrom sun Technologies Ins).
{"title":"Structural, Optical, and Morphological Properties of the Cadmium Oxide Thin Film Taif S. Almaadhede","authors":"Taif S. Almaadhede","doi":"10.23851/MJS.V28I2.515","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.515","url":null,"abstract":"Cadmium oxide nanoparticles CdO NPS has been prepared by laser ablation in ethanol at 600 pulses and 600 mJ as laser energy. The structural, optical, and morphological properties of the cadmium oxide CdO thin film deposited on a glass substrate have been studied. X-ray diffrac-tometer (XRD 6000, Shimadzu, X-ray, diffractometer) with Cukα radiation at a wavelength of ( = 0.154056 nm) was utilized to investigate the structural properties of CdO NPs. The optical absorption of colloidal CdO NPs was measured using a spectrophotometer (Cary, 100 cans plus, UV-Vis-NIR, Split Beam Optics, Dual detectors) in the range of (200–900) nm. The morpholo-gy of the CdO NPs was investigated by using AFM (AA 3000 Scanning Probe Microscope). The thickness of the films was measured using ellipsometer (Angstrom sun Technologies Ins).","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76415679","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Titanium dioxide (TiO2) nanostructures were synthesized via the hydrolysis of TiCl4 in alcohol / water solution/with sodium hydroxide solution in the ice-bath (0-5 ◦C). The particles were char-acterized by using X-ray diffraction technique (XRD), spectroscopy of Ultra Violet-Visible (UV / Visible) and infrared (FT-IR), atomic force microscope (AFM) and scanning electron micro-scope (SEM) analysis were used in order to gain information about the material, morphology, size and the shape of the particles
{"title":"Preparation and Characterization of TiO2 Nanostructure by TiCl4 Hydrolysis with Additive NaOH","authors":"R. Rasheed","doi":"10.23851/MJS.V28I2.506","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.506","url":null,"abstract":"Titanium dioxide (TiO2) nanostructures were synthesized via the hydrolysis of TiCl4 in alcohol / water solution/with sodium hydroxide solution in the ice-bath (0-5 ◦C). The particles were char-acterized by using X-ray diffraction technique (XRD), spectroscopy of Ultra Violet-Visible (UV / Visible) and infrared (FT-IR), atomic force microscope (AFM) and scanning electron micro-scope (SEM) analysis were used in order to gain information about the material, morphology, size and the shape of the particles","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87615030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reaction of cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared lig-and, of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complex-es were characterized and their structures elucidated using different techniques. These showed that all complexes are octahedral geometries. The kinetics of the formation of these complexes have been investigated using stopped-flow spectrophotometry. These studies revealed that the reactions are completed on the second’s timescale with 1st-order dependence (either on the con-centration of metal salt or on the concentration of CHTSC).
{"title":"Synthesis, Characterization and Kinetic Study of Monomeric Complexes of Cyclohexane-1, 2- bis (Thiosemicarbazone) with Cobalt (II), Nickel (II) and Copper (II)","authors":"A. Ali","doi":"10.23851/mjs.v28i2.499","DOIUrl":"https://doi.org/10.23851/mjs.v28i2.499","url":null,"abstract":"Cyclohexane-1,2-bis(thiosemicarbazone) (CHTSC) was synthesized via the condensation reaction of cyclohexane-1,2-dione and thiosemicarbazide. Series of metal complexes of the prepared lig-and, of general formula [M(CHTSC)(NO3)2], were reported. The prepared coordination complex-es were characterized and their structures elucidated using different techniques. These showed that all complexes are octahedral geometries. The kinetics of the formation of these complexes have been investigated using stopped-flow spectrophotometry. These studies revealed that the reactions are completed on the second’s timescale with 1st-order dependence (either on the con-centration of metal salt or on the concentration of CHTSC).","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75563827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This study was conducted on the number of pregnant women suffering from symptoms of preeclampsia who live in different areas in Baghdad city. These areas were suffering from air pol-lution by different pollutants in high rates and it was chosen from among these pollutants lead metal which is a high percentage of air pollution where it was observed by measuring the level of lead in blood serum which taken from pregnant women by 40 pregnant women suffering from symptoms of preeclampsia and 20 pregnant women don't suffering from any abnormal symptoms during pregnancy period and classified as control group , so we found marked a significant rise in lead level in comparison with control group reaching ratio of lead in blood of pregnant women which suffering from symptoms of preeclampsia 38.44 mg/dl ± 3.0 mg/dl in comparison with con-trol group which 14.56 mg/d l± 2.50 mg/dl,this increase may refer to the amount of lead which found in the air and in excess of the normal limit which exposed pregnant women like all people through the overcrowding of roads and use fuel non-environmentally friendly through breathing which effect on pregnant women health, it has been shown on symptoms of preeclampsia from measuring systolic and diastolic blood pressure and measuring of urea in blood, T-test was used at possibility of(0.001)to see the difference between infected samples and control group, therefore this study suggested that a lead is one of the causes of preeclampsia because live in polluted and unhealthy environment. (pt space line
{"title":"Lead Level in Pregnant Women Suffering from Pre- Ec-lampsia in Baghdad City- Iraq","authors":"A. H. Al-Shammery","doi":"10.23851/MJS.V28I2.493","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.493","url":null,"abstract":"This study was conducted on the number of pregnant women suffering from symptoms of preeclampsia who live in different areas in Baghdad city. These areas were suffering from air pol-lution by different pollutants in high rates and it was chosen from among these pollutants lead metal which is a high percentage of air pollution where it was observed by measuring the level of lead in blood serum which taken from pregnant women by 40 pregnant women suffering from symptoms of preeclampsia and 20 pregnant women don't suffering from any abnormal symptoms during pregnancy period and classified as control group , so we found marked a significant rise in lead level in comparison with control group reaching ratio of lead in blood of pregnant women which suffering from symptoms of preeclampsia 38.44 mg/dl ± 3.0 mg/dl in comparison with con-trol group which 14.56 mg/d l± 2.50 mg/dl,this increase may refer to the amount of lead which found in the air and in excess of the normal limit which exposed pregnant women like all people through the overcrowding of roads and use fuel non-environmentally friendly through breathing which effect on pregnant women health, it has been shown on symptoms of preeclampsia from measuring systolic and diastolic blood pressure and measuring of urea in blood, T-test was used at possibility of(0.001)to see the difference between infected samples and control group, therefore this study suggested that a lead is one of the causes of preeclampsia because live in polluted and unhealthy environment. (pt space line","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73856003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
This research describes preparation of new four compounds (A2-A5) having 1,3-oxazepine and Tetrazole rings. The first step involves reaction of benzidine (A1) with aromatic aldehyde (cinnamaldehyde) in ethanol as a solvent in the presence of acid as catalyst to yield the Schiff base (A2), Schiff base (A2) was condensed with maleic anhydride and phthalic anhydride in dry benzene to give a seven-membered heterocyclic ring derivative (A3, A4), In addition, we synthesis novel tetrazole derivative (A5) from the reaction of Schiff base (A2) with sodium azide in tetrahydrofuran. The structure of synthesized compounds were identified by spectral methods [FTIR, ¹H-NMR, and ¹³C-NMR] and measurement physical properties. The photo stabilization of poly (vinyl chloride) films by compounds (A1-A5) was studied. The Photostabilization activities of these compounds were determined by monitoring the carbonyl and hydroxyl indexes values with irradiation time. The changes in viscosity average molecular weight of PVC with irradiation time were studied by using tetrahydrofuran as a solvent. The influence of concentrations additives (range 0.1-0.5wt) on the rate of photodegradation and Photostabilization course was studied. Therefore, we found that was an increase Photostabilization rates with increasing concentrations of additives. In addition, Studying the effect of film thickness and the results showed that an increase in film thickness would reduce the rate of photolysis. The results indicated that Photostabilisation proportion of plastic in the presence of additives follow the trend: (PVC blank) > PVC+A1> PVC+A2 > PVC+A5> PVC+A4> PVC+A3. According to the results obtained, it proposed mechanisms depending on the structure of the additive.
{"title":"Synthesis and Identification of Heterocyclic Compounds (Oxazepine, Tetrazole) Derived from Benzidine as Photostabilizing for Poly vinyl chloride","authors":"O. A. Nief","doi":"10.23851/MJS.V28I2.521","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.521","url":null,"abstract":"This research describes preparation of new four compounds (A2-A5) having 1,3-oxazepine and Tetrazole rings. The first step involves reaction of benzidine (A1) with aromatic aldehyde (cinnamaldehyde) in ethanol as a solvent in the presence of acid as catalyst to yield the Schiff base (A2), Schiff base (A2) was condensed with maleic anhydride and phthalic anhydride in dry benzene to give a seven-membered heterocyclic ring derivative (A3, A4), In addition, we synthesis novel tetrazole derivative (A5) from the reaction of Schiff base (A2) with sodium azide in tetrahydrofuran. The structure of synthesized compounds were identified by spectral methods [FTIR, ¹H-NMR, and ¹³C-NMR] and measurement physical properties. The photo stabilization of poly (vinyl chloride) films by compounds (A1-A5) was studied. The Photostabilization activities of these compounds were determined by monitoring the carbonyl and hydroxyl indexes values with irradiation time. The changes in viscosity average molecular weight of PVC with irradiation time were studied by using tetrahydrofuran as a solvent. The influence of concentrations additives (range 0.1-0.5wt) on the rate of photodegradation and Photostabilization course was studied. Therefore, we found that was an increase Photostabilization rates with increasing concentrations of additives. In addition, Studying the effect of film thickness and the results showed that an increase in film thickness would reduce the rate of photolysis. The results indicated that Photostabilisation proportion of plastic in the presence of additives follow the trend: (PVC blank) > PVC+A1> PVC+A2 > PVC+A5> PVC+A4> PVC+A3. According to the results obtained, it proposed mechanisms depending on the structure of the additive.","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80793292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The paper presents the production of porcelain for the ceramic by inexpensive natural raw materi-als, the principal raw materials of porcelain composition was selected consisting of 50% kaolin, 25% feldspar, 25% silica, the sample synthesized were characterize by X-ray diffraction (XRD) technique, than study the effect additives at different concentration form titanium oxide (𝑇𝑖𝑂2 )at (2, 5, 10, 15, 20) wt% on some physical and dielectric properties of porcelain. The samples are prepared by the conventional manufacturing method. The physical and dielectric properties of porcelain show that change considerably with the sub-stituent sample. It was found that the increase of the titanium oxide (𝑇𝑖𝑂2 ) additives of all our sample produce increasing in dielectric constant and bulk density, while decreasing with open porosity and dielectric loss tangent.
{"title":"Studying the Effect of Titania Additions on some properties of Porcelain","authors":"A. Saadon","doi":"10.23851/MJS.V28I2.513","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.513","url":null,"abstract":"The paper presents the production of porcelain for the ceramic by inexpensive natural raw materi-als, the principal raw materials of porcelain composition was selected consisting of 50% kaolin, 25% feldspar, 25% silica, the sample synthesized were characterize by X-ray diffraction (XRD) technique, than study the effect additives at different concentration form titanium oxide (𝑇𝑖𝑂2 )at (2, 5, 10, 15, 20) wt% on some physical and dielectric properties of porcelain. The samples are prepared by the conventional manufacturing method. The physical and dielectric properties of porcelain show that change considerably with the sub-stituent sample. It was found that the increase of the titanium oxide (𝑇𝑖𝑂2 ) additives of all our sample produce increasing in dielectric constant and bulk density, while decreasing with open porosity and dielectric loss tangent.","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"72668297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The retarding force of the charged particles when interacts with matter causing loss of particle energy, this physical phenomenon in nuclear physics called stopping power. it has a lot of important applications such as in nuclear medicine and privation effects of radiations. The charge particles are alpha and beta particles. in this paper we studies the stopping power, collision and the stopping power of radioactivity of nuclear elements and to find the relationship between stopping power collision and stopping power of radioactivity, with arrange of CSDA range for the low energy electrons data of element F. the CSDA range he CSDA range it is an average distant length of the moving charge particles when it is path slows to stop. By using approximation of CSDA range we can calculate the rate of the loss in the energy at any point along the path of the travel by assuming these energies loss at points of the track are equal to whole stopping power loss. The CSDA range can be found by reciprocal integration of the total stopping power. from the Figures (3),(4),(5) and(6)we can get good results
{"title":"Study Stopping Power Collision in one of Nuclear Element","authors":"S. G. Hassan","doi":"10.23851/mjs.v28i2.519","DOIUrl":"https://doi.org/10.23851/mjs.v28i2.519","url":null,"abstract":"The retarding force of the charged particles when interacts with matter causing loss of particle \u0000energy, this physical phenomenon in nuclear physics called stopping power. it has a lot of important \u0000applications such as in nuclear medicine and privation effects of radiations. The charge \u0000particles are alpha and beta particles. in this paper we studies the stopping power, collision and \u0000the stopping power of radioactivity of nuclear elements and to find the relationship between stopping \u0000power collision and stopping power of radioactivity, with arrange of CSDA range for the \u0000low energy electrons data of element F. the CSDA range he CSDA range it is an average distant \u0000length of the moving charge particles when it is path slows to stop. By using approximation of \u0000CSDA range we can calculate the rate of the loss in the energy at any point along the path of the \u0000travel by assuming these energies loss at points of the track are equal to whole stopping power \u0000loss. The CSDA range can be found by reciprocal integration of the total stopping power. from \u0000the Figures (3),(4),(5) and(6)we can get good results","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90047242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
The workcontains a theoretical treatment of the preparedligand(3-{[(Z)-(4-nitrophenyl) methyli -dene]amino}-2-thioxoimidazolidin-4-one)[L] and their metal complexes[S1-S6]in the gas phase. Hyperchem-8 program has been used to determined structural geometries of ligand and their met-al complexes. The electrostatic potential(Ep)of the ligand was calculated,furthermore binding en-ergy(ΔEb),the heat of formation(ΔHf),vibration spectra and bond length for the ligand and their metal co -mplexes were calculated by PM3methods at 298K°. The theoretically calculateddata were agreed with those found experimentally. The antibacterial activity for free ligand and its metal complexes(S1-S6)were studied against two selected micro-organisms [(Staphylococcusau-reus) as gram positive]and [(Escherichiacoli)as gram negative]. The minimal inhibitory concen-trations(MIC)have been also studied to determine the low concentration for inhibition. The anti-biotics (Amoxcillin and Ampicillin) have been chosen to compare their activity with those of the new compounds. Furthermore the antif -ungal activity against two microorganisms (Candidaalbi-cans) and (Aspergillusflavus) were studied for all compounds. The results showed great activity of the complexes relative to that of free ligand.
{"title":"Theoretical Study and Biological Activity of Co(II), Ni(II), Cu(II),Pd(II),Pt(IV) and Cd(II) Complexes with2-Thioxoimidazolidin-4-one Derivative","authors":"S. Abdullah","doi":"10.23851/MJS.V28I2.501","DOIUrl":"https://doi.org/10.23851/MJS.V28I2.501","url":null,"abstract":"The workcontains a theoretical treatment of the preparedligand(3-{[(Z)-(4-nitrophenyl) methyli -dene]amino}-2-thioxoimidazolidin-4-one)[L] and their metal complexes[S1-S6]in the gas phase. Hyperchem-8 program has been used to determined structural geometries of ligand and their met-al complexes. The electrostatic potential(Ep)of the ligand was calculated,furthermore binding en-ergy(ΔEb),the heat of formation(ΔHf),vibration spectra and bond length for the ligand and their metal co -mplexes were calculated by PM3methods at 298K°. The theoretically calculateddata were agreed with those found experimentally. The antibacterial activity for free ligand and its metal complexes(S1-S6)were studied against two selected micro-organisms [(Staphylococcusau-reus) as gram positive]and [(Escherichiacoli)as gram negative]. The minimal inhibitory concen-trations(MIC)have been also studied to determine the low concentration for inhibition. The anti-biotics (Amoxcillin and Ampicillin) have been chosen to compare their activity with those of the new compounds. Furthermore the antif -ungal activity against two microorganisms (Candidaalbi-cans) and (Aspergillusflavus) were studied for all compounds. The results showed great activity of the complexes relative to that of free ligand.","PeriodicalId":7515,"journal":{"name":"Al-Mustansiriyah Journal of Sciences","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-04-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83362853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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