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Modelling catalyst regeneration in an industrial FCC unit 工业催化裂化装置催化剂再生模拟
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.294.305
K. Dagde, Y. Puyate
Predictive models for process parameters during regeneration of spent catalyst in an industrial fluid catalytic cracking (FCC) unit are presented. The models adopt a twophase theory where the dense region of the regenerator is divided into a bubble-phase and an emulsion-phase. The bubble-phase is modelled as a plug flow reactor, while the emulsion-phase is modelled as a continuous stirred tank reactor (CSTR). Profiles for regenerator-temperature, quantity of coke burnt, and flue gas composition, at different operating conditions are also presented. Model-predictions are compared with plant data and good agreement is obtained. Simulation results indicate that inlet-air velocity and catalyst-bed height have significant influence on the performance of the rege nerator. The model-estimated optimum operating conditions of the regenerator are regeneratortemperature of about 1000 K, inlet-air velocity of about 13.5 m/s, and catalyst-bed height of 13 m.
提出了工业流体催化裂化装置废催化剂再生过程中工艺参数的预测模型。该模型采用两相理论,其中再生器致密区分为气泡相和乳化相。将气泡相模拟为塞流反应器,将乳化相模拟为连续搅拌槽式反应器。还介绍了不同工况下蓄热器温度、焦炭燃烧量和烟气成分的变化情况。将模型预测结果与实际数据进行了比较,得到了很好的一致性。仿真结果表明,进气速度和催化床高度对回热发生器的性能有显著影响。模型估计再生器的最佳运行条件为再生器温度约为1000 K,进气速度约为13.5 m/s,催化床高度为13 m。
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引用次数: 8
Comparison of seismic processing and interpretation tradeoffs between Kirchoff and finite-difference migrations, using poststack migrated data in the west Niger Delta, Nigeria 利用尼日利亚西尼日尔三角洲叠后偏移数据比较Kirchoff和有限差分偏移在地震处理和解释方面的权衡
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.272.276
E. Uko, C. L. Eze, G. Alaminiokuma
The Kirchoff and Finite-Difference migrations were carried out on seismic data from the western part of the Niger Delta of Nigeria. The survey for the acquisition of the data was oriented southwest-north-east, at an angle of 45.4490 o . The KIRCH and FXMIG seismic migration programs were used to process and display the seismic sections. The sections were interpreted for diffractions, faults, and structures. It was observed that the dipping structures were incorrectly positioned downdip from the true reflection point. Prior to migration, the dipping structures were steeper and longer. For both Kirchoff and Finite-Difference migrations, there was proper imaging of the dipping structures. The structures were accurately moved updip and diffractions collapsed. The faulting pattern is a growth fault system as is generally the case in the Niger Delta basin. The reflectors became shorter, anticlines more clearly defined, and reflection events terminating at fault planes. Finite-Difference migration is preferred because it is faster, handles velocity variation and noise better, and events appearance is sufficiently distinctive for the interpreter to find traps, seals and reservoirs.
对尼日利亚尼日尔三角洲西部的地震资料进行了Kirchoff偏移和有限差分偏移。采集数据的调查方向为西南-东北,角度为45.4490°。利用KIRCH和FXMIG地震偏移程序对地震剖面进行处理和显示。这些剖面被解释为衍射、断层和结构。观察到倾斜构造在真实反射点的下倾位置不正确。在运移前,倾斜构造较陡、较长。对于基尔霍夫偏移和有限差分偏移,都有适当的倾斜构造成像。结构被精确地向上移动,衍射崩溃。断裂模式与尼日尔三角洲盆地一般为生长断裂系统。反射面变短,背斜更清晰,反射事件终止于断层面。有限差分偏移是首选,因为它更快,可以更好地处理速度变化和噪声,并且事件的外观足够独特,可以帮助解释人员找到圈闭、密封和储层。
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引用次数: 1
On Nigerian agricultural survey: Production and consumption pattern( 1994/95 - 2005/06 ) 尼日利亚农业调查:生产和消费模式(1994/95 - 2005/06)
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.257.260
O. Halid
Agriculture had been the main-stay of Nigerian economy before the ‘oil-boom’. Upon the discovery of oil, lesser attention has been given to the agricultural sector. As a result, this paper considered the production of certain important food crops which are highly cultivated by various states of the federation over a period of 1994/95-2005/06. The data layout is identical to that of the RCBD so that ANOVA technique was used to check variability in production and farm gate price for different states and harvesting seasons. A post mortem analytic technique namely the DMRT was also used to check for particular significance.
在“石油繁荣”之前,农业一直是尼日利亚经济的主要支柱。在发现石油后,对农业部门的关注较少。因此,本文考虑了联邦各州在1994/95-2005/06期间高度种植的某些重要粮食作物的生产。数据布局与RCBD相同,因此使用方差分析技术来检查不同状态和收获季节的生产和农场门口价格的变异性。死后分析技术,即DMRT也被用来检查特别的意义。
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引用次数: 0
A New Family of Non-Standard Finite Difference Schemes for the Logistic Equations Logistic方程的一类新的非标准差分格式
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.277.284
A. Obayomi, B. Olabode
This paper proposed a new family of Non-standard finite difference schemes for the Logistic equations. The technique of non-local approximation and renormalization of the denominator function was employed. The new schemes were found to possess desirable stability properties and also preserve all the monotonic properties of the logistic equations.
本文提出了一类新的Logistic方程非标准有限差分格式。采用了非局部逼近和分母函数的重整化技术。新格式不仅具有良好的稳定性,而且保持了logistic方程的单调性。
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引用次数: 1
Phytochemical and antioxidant properties of some Nigerian medicinal plants 尼日利亚一些药用植物的植物化学和抗氧化特性
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.328.332
O. Olutayo, I. Doyinsola
Medicinal plants are of great importance to the health of individuals and communities. The medicinal value of these plants lies in some chemical substances that produce a definite physiological action on the human body. The most important of these are alkaloids, tannins, glycoside, saponins, steroids, terpenoids, flavonoids, phlobatannins, resins, balsam, volatile oils and cardiac glycosides. The distribution of these moieties in six medicinal plants extracts belonging to different families were assessed and compared. The radical scavenging activities of the plant extracts against 2, 2 – Diphenyl -1picrylhydrazyl radical (DPPH) (Sigma Aldrich) were determined by UV spectrophotometer at 517 nm. Also, the significance of the plants in traditional medicine and importance of the distribution of these chemicals constituents were discussed with respect to the role of these plants in ethno medicinal usage in Nigeria.
药用植物对个人和社区的健康非常重要。这些植物的药用价值在于某些化学物质对人体产生一定的生理作用。其中最重要的是生物碱、单宁、糖苷、皂苷、类固醇、萜类、黄酮类、白丹宁、树脂、香脂、挥发油和心脏苷。对不同科6种药用植物提取物中这些成分的分布进行了评价和比较。采用517 nm紫外分光光度法测定了植物提取物对2,2 -二苯基-1吡啶肼基自由基(DPPH) (Sigma Aldrich)的清除活性。此外,还讨论了这些植物在传统医学中的意义和这些化学成分分布的重要性,以及这些植物在尼日利亚民族医药使用中的作用。
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引用次数: 23
On some models based on first order differential equations 基于一阶微分方程的一些模型
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.288.293
R. Ogunrinde, J. Sunday
This paper presents some models based on first order differential equations. Such models include population growth, drug distribution in the body and dating archaeological samples models. The paper also discusses the formulations, solutions and applications of such models. Keyword: Models, Growth, Decay, Drug Distribution, and First order INTRODUCTION Over the last few decades, mathematics has broken out into a whole new range of applications in the social sciences, biology, medicine, management, e.t.c. and it seems, almost every field of human endeavor, providing qualitative, if not quantitative models where none had existed or even been contemplated before. Mathematical techniques now play an important role in planning, managerial decision-making, and economics, which has probably been longest quantified of the social sciences (c.f. Burghes etal, 1980). The underlying theme in all applications of mathematics to real situations is the process of mathematical modeling. By this we mean the method of translating a real problem from its initial context into a mathematical description, that is, the mathematical models. This mathematical problem is then solved, and the resulting mathematical solutions must be translated back into the original context. The theory of ordinary differential equations. Equations: On a more practical level, it could be claimed that the spread of modern industrial civilization, for better or for worse, is partly a result of man’s ability to solve the differential equations which govern so many of our industrial processes, be they chemical or engineering (c. f. Burghes et al, 1980) A first order ordinary differential equation is a relation between the derivative of an unknown function x (t), where t is a real variable, the function x itself, the independent variable t, and given function of t. Denoting dt dx by  . x (by convention differentiation with respect to t is denoted by a dot, and not by a prime), we assume that in some domain D we can express  x as a function of t and x , namely   x t f x , .   (1) where f is a given function on the subject D (assumed open and connected) of 2 R taking values in R . A function   t x   which when substituted in (1) reduces it to an identity for each t in some interval (a,b) is called a solution of (1) over the interval (a,b). If f is continuous on D, each solution   t x   will define a smooth curve in D called an integral curve of the equation. Through each point   x t, of D there will pass an integral curve whose gradient at that point is given by   x t f , . Which curve we choose as our solution will depend on the initial data given. This is illustrated in Fig. 1 below.
本文提出了一些基于一阶微分方程的模型。这些模型包括人口增长、体内药物分布和考古样本测年模型。本文还讨论了这些模型的公式、解和应用。在过去的几十年里,数学在社会科学、生物学、医学、管理等领域的应用已经突破了一个全新的范围,似乎几乎在人类努力的每个领域,提供了定性的,如果不是定量的模型,以前没有存在过,甚至没有考虑过。数学技术现在在规划、管理决策和经济学中发挥着重要作用,经济学可能是社会科学中量化时间最长的(c.f. Burghes etal, 1980)。数学在实际情况中的所有应用的基本主题是数学建模的过程。我们指的是将实际问题从其初始环境转化为数学描述的方法,即数学模型。然后解决这个数学问题,并且必须将得到的数学解翻译回原来的上下文中。常微分方程理论。方程:在一个更实际的层面上,它可能会宣称,现代工业文明的传播,不管是好是坏,一部分是由于人的能力来解决微分方程支配我们的许多工业过程,无论是化学或工程(c f。城镇等,1980)一阶常微分方程是一个未知函数的导数之间的关系x (t),其中t是一个真正的变量,函数x本身,独立变量t,并给出t的函数,将dt / dx表示为。x(根据惯例,关于t的微分用一个点来表示,而不是一个素数),我们假设在某个定义域D中,我们可以将* x表示为t和x的函数,即x t f x,。·(1)其中f是2r的给定函数D(假设是开放的和连接的),取R中的值。一个函数t x ,当代入(1)时,将其简化为某个区间(A,b)内每个t的单位,称为(1)在区间(A,b)上的解。如果f在D上连续,每个解t x 将在D上定义一条光滑曲线,称为方程的积分曲线。通过每个点x t (D)会经过一条积分曲线,该点的梯度为x t f (D)。我们选择哪条曲线作为解取决于给出的初始数据。如下图1所示。
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引用次数: 1
Comparative analysis of sonic and neutron-density logs for porosity determination in the South-eastern Niger Delta Basin, Nigeria 声波测井与中子密度测井在尼日利亚尼日尔三角洲盆地东南部孔隙度测定中的对比分析
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.261.271
O. Horsfall, E. Uko, Iyeneomie Tamunobereton-ari
A comparative analysis of porosity values computed from sonic and neutron-density logs obtained from the same well is here presented. The aim is to identify the more reliable logging tool between sonic and neutron-density in the estimation of porosity values in a formation. Two wells from different parts of Niger Delta were logged for Transit times, bulk density and hydrogen index of the formation as a function of depth. The analysis of sonic, density and neutron porosity values shows a conventional trend of decrease in porosity with depth. Sonic porosity values of well A, and well B varies from 1 to 17%, and 27 to 60% respectively while Neutron-Density Porosity values of well A, and well B varies from 24 to 45%, and 21 to 37% respectively. The Coefficient of Variation for sonic porosity data are 56%, and 23%of well A, and well B respectively , similarly the Coefficient of Variation for Neutron-Density porosity data are 15%, and 14% of well A, and well B respectively. Coefficient of variation of Neutron-density log derived porosities is less than sonic log derived porosities; therefore Neutron-density log derived porosity is more reliable tool for porosity data estimation than sonic log derived porosity. Neutron and density logging tool is here recommended for determination of a reliable porosity value of a formation.
本文对同一口井的声波测井和中子密度测井计算的孔隙度值进行了对比分析。目的是在声波和中子密度之间确定更可靠的测井工具,以估计地层的孔隙度值。对尼日尔三角洲不同地区的两口井进行了测井,测量了地层的传输时间、体积密度和氢指数与深度的关系。声波、密度和中子孔隙度值的分析表明,孔隙度随深度的增加而减小。A井和B井的声波孔隙度值分别为1 ~ 17%和27 ~ 60%,而A井和B井的中子密度孔隙度值分别为24 ~ 45%和21 ~ 37%。A井和B井声波孔隙度数据的变异系数分别为56%和23%,A井和B井中子密度孔隙度数据的变异系数分别为15%和14%。中子密度测井孔隙度的变异系数小于声波测井孔隙度;因此中子密度测井孔隙度比声波测井孔隙度估算更可靠。这里推荐使用中子和密度测井工具来确定地层的可靠孔隙度值。
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引用次数: 11
Application of matlab ordinary differential equation function solver (ode45) in modelling and simulation of batch reaction kinetics 常微分方程函数求解器(ode45)在间歇反应动力学建模与仿真中的应用
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.285.287
C. Anyigor, J. Afiukwa
This study presents the simulation of modelled chemical reaction in a batch reactor using the Matlab ordinary differential equation function solver (ODE45). Modelling and optimisation of actual batch reaction rate constants under isothermal condition was implemented on a set of experimental data. The data was simulated using hypothetical isothermal rate constants, 1 2 with the initial concentration profile of the reaction: and respectively between reaction time of minutes. The Process model developed was employed to optimise the rate constant (K) at which maximum yield of the desired product was achieved. Results showed maximum product yield, ‘D’ at 1= with a reaction by-product, ‘E’ at 2 = within 40 minutes reaction time. This study is intended to benefit industrial operations which aim at achieving optimum yield of a reaction process in a record time.
本研究利用Matlab常微分方程函数求解器(ODE45)对间歇式反应器中的模拟化学反应进行了模拟。利用一组实验数据,对等温条件下实际间歇反应速率常数进行了建模和优化。数据采用假设的等温速率常数进行模拟,1 2与反应的初始浓度分布:和反应时间之间分别为分钟。所开发的过程模型用于优化速率常数(K),在此速率常数(K)下达到所需产品的最大产量。结果表明,在40分钟的反应时间内,反应副产物D值为1,反应副产物E值为2。本研究旨在为工业操作提供参考,目的是在创纪录的时间内实现反应过程的最佳产率。
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引用次数: 3
Synthesis of zeolites and their applications as Ion exchange to remove water hardness 沸石的合成及其离子交换去除水硬度的应用
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.317.327
M. Elkarim, S. Ahmed
In this study fifteen types of natural zeolites and synthetic zeolites and clay (Bentonite, Kaolinte) were used. Nine types of synthetic zeolites (K-fledspar, clay and trona) were synthesized by using local crude materials , also the column that was used for treating hard water was prepared from natural zeolite, synthetic zeolite and clay. The sample of red sea water was collected from segala areaat eastern side the of Port Sudan city. The study was investigated to determine the concentration of metals that causes hardness (Ca, Mg).The location of samples was taken from segala area at eastern shore of Red Sea of Port Sudan this area is the main source for Red sea water to the desalination plant, which supplies the city with drinking water. The analysis was investigated to determine the other parameters of water. Hydrogen ion concentration pH was measured using pH meter, TDS concentration was determined by TDS meter. So the concentration of cation metals especially those who caused water hardness (Ca, Mg) were determined by using titration by E.D.T.A and other solutions. They synthetic zeolite, natural zeolite and clay which used in this study were identified a long with XRD and IR.Mainly, this study was concentrated on treatment of metals which causes water hardness (Ca,Mg). The treatment process for synthetic zeolite and natural zeolite were recorded and all analysis results of elements in this study were analyzed, and the synthetic and natural zeolite was found to be better than clay and Albite was found to be the best type in this study .
本研究使用了15种天然沸石及合成沸石和粘土(膨润土、高岭土)。以当地原料为原料,合成了九种类型的合成沸石(k - flespar、粘土和trona),并以天然沸石、合成沸石和粘土为原料制备了用于处理硬水的沸石柱。红海海水样本是从苏丹港市东侧的塞加拉地区采集的。该研究是为了确定导致硬度的金属(Ca, Mg)的浓度。样本的位置取自苏丹港红海东岸的segala地区,该地区是向为城市提供饮用水的海水淡化厂提供红海水的主要来源。通过分析确定了水的其他参数。用pH计测定氢离子浓度pH,用TDS计测定TDS浓度。因此,用edta滴定法和其他溶液测定了阳离子金属的浓度,特别是引起水硬度的阳离子金属(Ca, Mg)的浓度。用XRD和IR对合成沸石、天然沸石和粘土进行了鉴定。本文主要研究了引起水硬度的金属(Ca,Mg)的处理。记录了合成沸石和天然沸石的处理过程,并对本研究中所有元素的分析结果进行了分析,发现合成沸石和天然沸石的处理效果优于粘土,而钠长石是本研究的最佳类型。
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引用次数: 2
The potential of removing toxic elements from red sea water by using functionalised natural zeolite and synthetic zeolite 功能化天然沸石和合成沸石去除红海水中有毒元素的潜力
Pub Date : 2013-06-01 DOI: 10.5251/AJSIR.2013.4.3.306.316
M. Elkarim, Saif Elmajed
In this study five types of natural Zeolites and synthetic zeolites were used .Three types of synthetic zeolites (K-fledspar, clay and trona) were synthezied by using local crude materials by certain ratios, and the natural zeolite which used were collected from different states of Sudan , also the column that was used for treating hard water was prepared for natural zeolite, synthetic zeolite. The sample of red sea water was collected from Segala area at eastern side the of Port Sudan city, This area is the main source of Red sea water to the desalination plant, which supply the city with drinking water , study was investigated to determine the concentration of heavy metals, such as (Cu, pb, Fe, Cd, Zn and Co) . The routine analysis was investigated to determine the other parameters of water.TDS concentration was determined by TDS meter. Concentration of heavy metals was measured by Atomic absorption. The synthetic zeolite and the natural zeolite which that were identified a long with XRD and IR. Also we were concentrated on remove the heavy metals from water during treatment process by synthetic zeolite and natural zeolite . Analysis results of elements in this study were analyzed, and the synthetic and natural zeolite were found to be better and Albite was found to be the best type in this study.
本研究使用了5种天然沸石和合成沸石,用当地原料按一定比例合成了3种合成沸石(K-fledspar, clay, trona),所使用的天然沸石是从苏丹不同国家收集的,并为天然沸石、合成沸石制备了用于处理硬水的色谱柱。在苏丹港市东侧的Segala地区采集了红海水样本,该地区是为该市提供饮用水的海水淡化厂的主要红海水源,研究了该地区的重金属(Cu, pb, Fe, Cd, Zn和Co)的浓度。通过常规分析确定了水的其他参数。用TDS仪测定TDS浓度。采用原子吸收法测定重金属浓度。用XRD和IR对合成沸石和天然沸石进行了较长时间的鉴定。并对合成沸石和天然沸石在处理过程中对水中重金属的去除进行了研究。对本研究的元素分析结果进行了分析,发现合成沸石和天然沸石表现较好,其中钠长石是本研究的最佳类型。
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引用次数: 2
期刊
American Journal of Scientific and Industrial Research
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