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Impact of T-Shape Drain Doping Engineering on the Analog/RF and High-Frequency Noise Parameters of Junctionless Si/ Si0.7Ge0.3 FET: A Numerical Simulation Study 无结硅/硅0.7锗0.3场效应晶体管的T形漏极掺杂工程对模拟/射频和高频噪声参数的影响:数值模拟研究
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-11 DOI: 10.1007/s12633-024-03155-w
Rayhaneh Ejlali, Mahdi Vadizadeh, Saeed Haji-Nasiri, Alireza Kashaniniya, Arash Dana

Decreased carrier mobility in the junctionless field-effect transistors (JLFETs) channel limits their performance for applications in high-frequency electronics. This paper presents a drain doping technique based on CMOS technology is offered for the first time to improve the analog/RF performance and high-frequency noise parameters of a CONV-shell doped channel- JLFET (CONV-SDCHJLFET). The proposed device is called DG-JLFET with T-shape drain doping (DG-JLFET with TSDD), in which two main drain regions (regions d1 and d2) are crucial to achieve the desired results. By fine-tuning various influencing factors within these two regions, the DG-JLFET with TSDD achieves a transconductance (gmmax) of 4.41 mS/um, a cut-off frequency (fT) of 813 GHz, a minimum noise figure (NFmin) of 0.6 dB and an available associated gain (Gma) of 19.92 dB. gmmax, fT, NFmin, and Gma of the SDCh-JLFET increased by 78%, 30%, 53%, and 19.2%, respectively, compared to the CONV-SDCHJLFET with similar dimensions. This device is excellent for analog/RF applications and performs well in high-frequency noise, making it an ideal choice for demanding next-generation telecommunications applications.

无结场效应晶体管(JLFET)沟道中载流子迁移率的降低限制了其在高频电子产品中的应用性能。本文首次提出了一种基于 CMOS 技术的漏极掺杂技术,用于改善 CONV 壳掺杂沟道 JLFET(CONV-SDCHJLFET)的模拟/射频性能和高频噪声参数。所提出的器件被称为具有 T 型漏极掺杂的 DG-JLFET (DG-JLFET with TSDD),其中两个主要漏极区(d1 区和 d2 区)对实现预期效果至关重要。通过微调这两个区域内的各种影响因素,带 TSDD 的 DG-JLFET 实现了 4.41 mS/um 的跨导 (ggmax)、813 GHz 的截止频率 (fT)、0.与具有类似尺寸的 CONV-SDCHJLFET 相比,SDCh-JLFET 的 gmmax、fT、NFmin 和 Gma 分别提高了 78%、30%、53% 和 19.2%。该器件非常适合模拟/射频应用,在高频噪声方面表现出色,是要求苛刻的下一代电信应用的理想选择。
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引用次数: 0
Performance Analysis and Design Comparison of Junctionless TFET: a Review Study 无结 TFET 的性能分析和设计比较:回顾研究
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-11 DOI: 10.1007/s12633-024-03167-6
Aradhana Mohanty, Md Akram Ahmad, Pankaj Kumar, Raushan Kumar

Many research is underway in the semiconductor industry. Conventional MOSFETs are getting replaced with emerging devices such as junctionless field-effect-transistor (JLTFET) to increase the efficiency and performance of the devices. The incorporation of junctionless mechanism in JLTFET has significantly reduced fabrication complexity because of independency with the pn junction formed at source and drain regions. JLTFET has shown promising electrical behavior with the improvement in the ON-state current, reduction in ambipolar conduction, and reduced short channel effects. The significant enhancement in OFF-state current resulting in improved ION/IOFF drain current ratio which in turn result in comparatively steeper subthreshold slope. In this review paper, the significance of JLTFET has been analysed in terms of its working principle and considering its electrical behavior such as architectural, dielectric, semiconductor material, oxide thickness, gate workfunction, source workfunction engineering and its performance at higher temperature.

半导体行业正在进行多项研究。传统的 MOSFET 正被无结场效应晶体管(JLTFET)等新兴器件所取代,以提高器件的效率和性能。在 JLTFET 中加入无结机制后,由于源极和漏极区域形成的 pn 结无关,因此大大降低了制造复杂性。JLTFET 显示出良好的电气性能,改善了导通态电流,减少了极性传导,并降低了短沟道效应。关态电流的显著增强改善了离子/漏极电流比,进而导致陡峭的阈下斜率。本文从 JLTFET 的工作原理出发,分析了 JLTFET 的重要意义,并考虑了其电气特性,如结构、电介质、半导体材料、氧化物厚度、栅极工作函数、源极工作函数工程及其在较高温度下的性能。
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引用次数: 0
Understanding the Effects of Heat Transfer on the Purification of Metallurgical Silicon by Directional Solidification in Cast Furnaces 了解传热对在铸造炉中通过定向凝固提纯冶金硅的影响
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-08 DOI: 10.1007/s12633-024-03143-0
Moyses L. Lima, Marcelo A. Martorano, Denir P. Nascimento, João B. Ferreira Neto

Experiments on directional solidification were carried out to investigate how purification of metallurgical-grade silicon in cast furnaces is affected by changes in heat extraction from and heat supply to their melts. A reference condition analogous to that in the block-casting process was established using top/side heaters to supply heat and a water-cooled base to extract heat from the bottom of a graphite-clay crucible. This condition was modified by (a) changing the crucible bottom material to graphite, (b) increasing the length of the resulting ingot from 100 to 130 mm, and (c) turning off the heaters. Temperatures were measured within the melt and in the furnace environment. The grain macro-microstructures and the macrosegregation of impurities of the ingots were revealed. The cooling rates and solid–liquid interface velocity calculated with a mathematical model increase relative to the reference experiment when the graphite crucible bottom is used or when the top/side heaters are absent. The vertical temperature gradients also increase with the graphite bottom, but significantly decrease without the heaters. Most of the ingots exhibit a purified lower region of columnar grains with straight boundaries, free from intermetallic particles, and an upper region with mixed long and short columnar grains with serrated boundaries, precipitated particles, and higher impurity concentrations. Changing the crucible bottom material from graphite-clay to graphite increases the length of the purified region from 70 (reference condition) to 97 mm, whereas turning off the heaters completely eliminates this region. Although the graphite crucible bottom (with the top/side heaters) yields the longest purified region, the graphite-clay bottom (also with the heaters) gives the lowest impurity concentrations.

进行了定向凝固实验,以研究冶金级硅在铸造炉中的提纯如何受到熔体取热和供热变化的影响。建立了一个与块状铸造工艺类似的参考条件,使用顶部/侧面加热器供热,水冷底座从石墨-粘土坩埚底部抽取热量。对这一条件进行了修改:(a) 将坩埚底部材料改为石墨;(b) 将铸锭长度从 100 毫米增加到 130 毫米;(c) 关闭加热器。测量了熔体内部和熔炉环境中的温度。结果显示了铸锭的晶粒宏观微观结构和杂质的宏观聚集。使用石墨坩埚底部或不使用顶部/侧面加热器时,用数学模型计算出的冷却速率和固液界面速度相对于参考实验有所增加。使用石墨坩埚底时,垂直温度梯度也会增加,但在没有加热器的情况下,垂直温度梯度会明显降低。大多数铸锭的下部区域为纯化的柱状晶粒,边界平直,不含金属间微粒;上部区域为长短柱状混合晶粒,边界呈锯齿状,有沉淀微粒,杂质浓度较高。将坩埚底部材料从石墨-粘土改为石墨后,纯化区的长度从 70 毫米(参考条件)增加到 97 毫米,而关闭加热器则完全消除了这一区域。虽然石墨坩埚底部(带顶部/侧面加热器)产生的净化区域最长,但石墨粘土底部(也带加热器)产生的杂质浓度最低。
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引用次数: 0
Facile Synthesis of Hierarchical SiOx/NiO/Carbon Nanotube Structure as Negatrode Materials for Lithium-Ion Batteries 作为锂离子电池负极材料的分层氧化硅/氧化镍/碳纳米管结构的简单合成
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-03 DOI: 10.1007/s12633-024-03166-7
Qilun Xiong, Tingting Jiang, Zhuo Hu, Yingke Zhou

Silicon oxide has become promising negative electrode materials for lithium-ion batteries due to its high specific capacity, abundant reserve, and moderate lithiation potential. However, the cyclic stability and high-rate capacity are unsatisfied due to the large volume change during charging/discharging and poor electrical conductivity of both silicon and silicon oxides. Herein, a novel hierarchical structure composed of SiOx, NiO and carbon nanotubes (CNTs) is proposed and prepared in a facile ball-milling and hydrothermal method. The interlaced CNTs network and NiO nanoparticles coated outside the SiOx particles act as highly conductive porous shell and prevent crack and pulverization of SiOx. Benefiting from this structure, the SiOx/NiO/CNTs composites demonstrate excellent rate capacity and cyclic performance of 916.3 mAh g−1 after 200 cycles at 0.5 A g−1.

氧化硅具有比容量高、储量丰富和锂化电位适中等优点,已成为锂离子电池的理想负极材料。然而,由于硅和硅氧化物在充放电过程中体积变化大、导电性差,其循环稳定性和高倍率容量并不能令人满意。本文提出了一种由氧化硅、氧化镍和碳纳米管(CNTs)组成的新型分层结构,并通过简便的球磨和水热法制备了这种结构。交错的 CNTs 网络和包覆在 SiOx 颗粒外的 NiO 纳米颗粒起到了高导电性多孔外壳的作用,防止了 SiOx 的开裂和粉碎。得益于这种结构,SiOx/NiO/CNTs 复合材料在 0.5 A g-1 的条件下循环 200 次后,显示出卓越的速率容量和 916.3 mAh g-1 的循环性能。
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引用次数: 0
Smart Window Based Photonic Crystal 基于光子晶体的智能窗口
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-02 DOI: 10.1007/s12633-024-03158-7
Bendib Sarra, Benziane Tassaadit, Houairi Kenza

This study proposes energy-efficient smart windows based on one-dimensional photonic crystal structures that operate without an external power source and discuss the design and analysis of the proposed smart window which is composed of SiO2/Vo2 layers, their interaction with light and heat, the effect of the incident waves angles and their potential to reduce energy consumption and radiation exposure. The proposed window proves the performance of blocking harmful rays of ultraviolet and infra-red region even the temperature, polarization and the incident wave angles change and transmitting visible light except the green color that the window appears with, which adds a beauty view to it.

本研究提出了基于一维光子晶体结构、无需外部电源即可运行的节能智能窗,并讨论了由二氧化硅/二氧化物层组成的智能窗的设计和分析、它们与光和热的相互作用、入射波角度的影响及其降低能耗和辐射暴露的潜力。事实证明,即使温度、偏振和入射波角度发生变化,所提出的窗户也能阻挡紫外线和红外线等有害光线,并能透过可见光,只是窗户呈现的绿色给人一种美感。
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引用次数: 0
Effect of in-situ Incorporated Silica Particles on Properties of Polyurethane Elastomer 原位掺入二氧化硅颗粒对聚氨酯弹性体性能的影响
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-02 DOI: 10.1007/s12633-024-03162-x
Neetu Tripathi, Ajit Shankar Singh, Jeetendra Kumar Banshiwal, Prashant Pandey, Dibyendu S. Bag

This study explores the in-situ incorporation of silica (SiO2) microparticles into a hard-soft segmented polyurethane (PU) matrix to enhance its properties for potential coating applications. The structural characterization of the material was conducted using Fourier Transform Infrared (FTIR) spectroscopy, X-ray Diffraction (XRD), and Field Emission Scanning Electron Microscopy (FE-SEM) studies. In the FTIR spectra, the C = O absorption peaks in urethane at 1707 and 1726 cm−1 for PU-Neat film shift to 1702 and 1716 cm−1 in PU-SiO2, indicating H-bonding between polyurethane and SiO2. The optical, thermal, and mechanical properties of the material were evaluated through transmittance, haze measurement, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and mechanical analysis. The results demonstrated that adding SiO2 microparticles significantly improved the thermal stability, and the glass transition temperature (Tg) increased from 2.52 °C to 3.0 °C due to the incorporation of SiO2 particles, as analyzed from DSC; these results are supported by DMA findings. The silica-incorporated polyurethane demonstrated significantly higher resistance to scratching, with a threshold load of 1800 g compared to PU-Neat (1000 g). The PU-SiO2 composite exhibited a higher maximum decomposition temperature (Tmax, 393.9 °C) and increased tensile strength (21.21 MPa) compared to neat PU. Enhanced thermal conductivity (1913.91 W/cm.oC) and mechanical properties were attributed to the uniform dispersion of silica microparticles within the matrix, as confirmed by FE-SEM analysis. These findings indicate that SiO2-incorporated polyurethane composites are promising candidates for hard coating applications requiring enhanced durability and performance under mechanical stress.

本研究探讨了将二氧化硅(SiO2)微粒原位掺入硬软分段聚氨酯(PU)基质中,以增强其性能,从而实现潜在的涂层应用。利用傅立叶变换红外光谱(FTIR)、X 射线衍射(XRD)和场发射扫描电子显微镜(FE-SEM)研究了该材料的结构特征。在傅立叶红外光谱中,聚氨酯-Neat 薄膜中位于 1707 和 1726 cm-1 的 C = O 吸收峰转移到了聚氨酯-SiO2 中的 1702 和 1716 cm-1,表明聚氨酯和 SiO2 之间存在 H 键。通过透射率、雾度测量、热重分析(TGA)、差示扫描量热法(DSC)、动态力学分析(DMA)和力学分析,对材料的光学、热学和力学性能进行了评估。结果表明,加入二氧化硅微粒后,热稳定性明显提高,经 DSC 分析,由于加入了二氧化硅微粒,玻璃化转变温度(Tg)从 2.52 °C 上升到 3.0 °C;这些结果得到了 DMA 分析结果的支持。与聚氨酯-Neat(1000 克)相比,掺入二氧化硅的聚氨酯表现出更高的抗划伤性,阈值载荷为 1800 克。与纯聚氨酯相比,聚氨酯-二氧化硅复合材料的最大分解温度(Tmax,393.9 °C)更高,拉伸强度(21.21 兆帕)更大。经 FE-SEM 分析证实,热导率(1913.91 W/cm.oC)和机械性能的提高归因于二氧化硅微粒在基体中的均匀分散。这些研究结果表明,二氧化硅掺杂聚氨酯复合材料有望用于要求提高耐久性和机械应力性能的硬涂层应用。
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引用次数: 0
Physiological and Biochemical Underpinnings Drive Yield Enhancement in Indian Mustard (Brassica juncea) by Ortho Silicic Acid under Field Conditions 在田间条件下,正硅酸提高印度芥菜(Brassica juncea)产量的生理和生化基础
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-10-01 DOI: 10.1007/s12633-024-03130-5
Kiran, Vinod Goyal, Anita Kumari, Shweta Mehrotra, Ram Avtar, Christian O. Dimkpa

Mustard (Brassica juncea) is a major oilseed and medicinal crop and its consumption has considerably increased with growing human population, leading to greater demand than supply. Increasing production and productivity of oilseed brassica to meet out the projected demand of edible oils, crop management strategies need to be fabricated and implemented. The two varieties of mustard, RH 725 and RH 0749 display superior performance for yield and are recommended for farmers’ fields in north India. The present study evaluated the efficacy of silicon applied in the form of orthosilicic acid (OSA) for improving the physiological and biochemical performances, growth, and yield of recommended mustard varieties under field conditions, as a function of variety, stage, dose, and application time. OSA was applied as a foliar spray at 20, 30, and 40 ppm during vegetative and flowering stages to analyse its influence on plant growth, physiology, enzymatic and non-enzymatic antioxidant enzymes, and yield attributes. Application of OSA at 30 ppm at vegetative stage and 20 ppm at flowering stage, increased activity of antioxidant enzymes, superoxide dismutase (SOD), catalase (CAT), ascorbate peroxidase (APX), and peroxidase (POX) and metabolites, ascorbic acid and glutathione; and decreased the levels of hydrogen peroxide (H2O2), malondialdehyde (MDA), and relative stress injury (RSI), as compared to the respective untreated controls. The increase in antioxidant enzyme activity and ascorbic acid and glutathione content and protein content was greater in RH 0749 than RH 725. Photosynthetic rate, stomatal conductance, transpiration rate, and chlorophyll fluorescence and protein content improved with the application of 20 ppm OSA, where RH 0749 responded more at the vegetative stage whereas RH 725 showed better responses at flowering stage. The growth and yield related attributes also enhanced with the foliar application of 20 ppm and 30 ppm OSA in both the varieties. RH 725 displayed an increase of 15% and RH 0749 displayed an increase of 18% in seed yield with 20 ppm OSA. Single foliar application of OSA could yield pronounced effects on growth, physiological and biochemical responses and yield of Brassica varieties. The present study indicates the ability of OSA in low dosesto modulate crop physiological and biochemical responses under field conditions can contribute to bridging the productivity gap of brassica to meet consumer demand for establishing a sustainable cropping system.

Graphical Abstract

Diagrammatic overview of Brassica juncea varieties subjected to OSA treatments during the vegetative and flowering stages for the experiment. 20 ppm OSA was found to be optimum dosage for improving crop productivity, according to the analysis of specific growth, physio-biochemical and yield parameters.

芥菜(Brassica juncea)是一种主要的油籽和药用作物,随着人口的增长,芥菜的消费量大大增加,导致供不应求。为了提高油菜籽的产量和生产率,满足食用油的预期需求,需要制定和实施作物管理策略。RH 725 和 RH 0749 这两个芥菜品种在产量方面表现优异,被推荐用于印度北部的农田。本研究评估了在田间条件下以正硅酸(OSA)形式施用硅对改善推荐芥菜品种的生理生化性能、生长和产量的效果,以及硅对品种、阶段、剂量和施用时间的作用。在植物生长期和开花期以 20、30 和 40 ppm 的剂量叶面喷施 OSA,分析其对植物生长、生理、酶和非酶抗氧化酶以及产量属性的影响。与未经处理的对照组相比,在植株生长期施用 30 ppm 和在开花期施用 20 ppm 的 OSA 可提高抗氧化酶、超氧化物歧化酶 (SOD)、过氧化氢酶 (CAT)、抗坏血酸过氧化物酶 (APX) 和过氧化物酶 (POX) 以及代谢产物抗坏血酸和谷胱甘肽的活性;降低过氧化氢 (H2O2)、丙二醛 (MDA) 和相对胁迫损伤 (RSI) 的水平。与 RH 725 相比,RH 0749 的抗氧化酶活性、抗坏血酸和谷胱甘肽含量以及蛋白质含量的增加幅度更大。施用 20 ppm OSA 后,光合速率、气孔导度、蒸腾速率、叶绿素荧光和蛋白质含量都有所提高,其中 RH 0749 在植株期的反应更大,而 RH 725 在开花期的反应更好。叶面喷施 20ppm 和 30ppm OSA 后,这两个品种的生长和产量相关属性也有所提高。施用 20ppm OSA 后,RH 725 的种子产量增加了 15%,RH 0749 的种子产量增加了 18%。单次叶面喷施 OSA 可对甘蓝品种的生长、生理生化反应和产量产生明显影响。本研究表明,在田间条件下,低剂量的 OSA 能够调节作物的生理和生化反应,有助于缩小芸苔属植物的产量差距,满足消费者对建立可持续种植系统的需求。根据对特定生长、生理生化和产量参数的分析,发现 20 ppm OSA 是提高作物产量的最佳剂量。
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引用次数: 0
A New Approach to the Recycling of Silicon Production Waste (Microsilica) as a Raw Material for Metallurgical Processing 回收硅生产废料(微硅石)作为冶金加工原料的新方法
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-09-28 DOI: 10.1007/s12633-024-03163-w
Alibek Baisanov, Nina Vorobkalo, Aidana Baisanova, Azat Mussin, Symbat Sharieva, Amir Makishev

This paper proposes a new approach on the processing of silicon production waste (microsilica) as a raw material for metallurgical processing. It is known from practice that the granulometric composition of microsilica does not allow its use in metallurgical processing. The authors of this work propose its use together with a reductant as part of a briquetted charge. In this work, the optimal composition of the charge mixture for briquetting is determined. The main focus is on assessing the strength characteristics of the briquettes and analyzing their efficiency in the silicon smelting process. The strength of the briquettes was studied by the dropping method. As a result, in terms of strength and other characteristics, it is highly advisable to use briquettes consisting of 65% of microsilica and 35% special coke screenings. The obtained batches of high-strength briquettes were tested for the smelting of metallurgical grade silicon in a large-scale laboratory ore-thermal furnace to replace the traditional charge mixtures (high-quality quartzites, petroleum coke, wood chips, etc.) with briquettes. It was established that the briquetted monocharge ensures more intensive reduction processes and improves melting conditions compared to the traditional charge. This leads to higher silicon recovery rates, which was confirmed by tests, during which the maximum recovery rate reached 83.1% with a 30% replacement of the charge with briquettes. The batch of metallurgical silicon with 95-96% of Si content was obtained.

本文提出了一种将硅生产废料(微硅石)作为冶金加工原料的新方法。众所周知,微硅酸的粒度组成不允许用于冶金加工。这项工作的作者建议将微硅石与还原剂一起用作压块炉料的一部分。在这项工作中,确定了用于压块的炉料混合物的最佳成分。主要重点是评估压块的强度特性,并分析其在硅冶炼过程中的效率。采用滴落法研究了压块的强度。结果表明,就强度和其他特性而言,使用由 65% 的微硅石和 35% 的特殊焦炭筛分组成的压块是非常可取的。在大型实验室矿热炉中进行了冶炼冶金级硅的试验,用煤球替代传统的炉料混合物(优质石英岩、石油焦、木屑等),获得了一批高强度煤球。结果表明,与传统炉料相比,压块单炉料可确保更密集的还原过程,并改善熔化条件。这将提高硅的回收率,测试证实了这一点,在测试过程中,用压块替代 30% 的炉料,最高回收率达到 83.1%。这批冶金硅的含硅量为 95-96%。
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引用次数: 0
Morphological and Electrical Features of Porous Silicon Prepared by Metal-Induced Chemical Etching 金属诱导化学蚀刻法制备的多孔硅的形态和电气特性
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-09-27 DOI: 10.1007/s12633-024-03151-0
Hyo Han Kim, Sang Ho Lee, Hyun Soon Park

Porous silicon (PS) was produced by the metal-induced chemical etching of p-type Si wafers. Patterned platinum dots (~ 300 μm) were deposited on a Si wafer by DC magnetron sputtering for 15 s. When the H2O2 fraction in the etchants consisting of HF and H2O2 was increased from 0.3 to 24%, the etching behavior changed from “pore formation” to “electropolishing.” The etching reaction activation energy also changed from 0.20 to 0.36 eV in the ln J–K(current–etchant temperature) relationships. The etched morphologies exhibited different structures, such as nano-scaled sponge-like and 3D micro-scaled pore structures, according to the H2O2 ratio. The etched layers contained a Si quantum structure, amorphous Si phase, and SiOx. These phase ratios changed according to the etching behavior. The Si nanocrystallite size changed from ~ 3.0 to 4.6 nm, emitting optical features in the band gap range of 1.73 to 1.88 eV. The fluorescence region varied according to the H2O2 contents. The fluorescence preferentially occurred at the interface between the metal circle and Si wafer in the case of etched PS by an etchant containing a lower hydrogen peroxide ratio. In contrast, the fluorescence increased in the non-coated region from 19.5 to 24.0%.

多孔硅(PS)是通过对 p 型硅晶片进行金属诱导化学蚀刻制得的。当 HF 和 H2O2 组成的蚀刻剂中 H2O2 的比例从 0.3% 增加到 24% 时,蚀刻行为从 "孔隙形成 "转变为 "电抛光"。在 ln J-K(电流-蚀刻剂温度)关系中,蚀刻反应活化能也从 0.20 eV 变为 0.36 eV。根据 H2O2 比例的不同,蚀刻形态呈现出不同的结构,如纳米级海绵状结构和三维微尺度孔隙结构。蚀刻层包含硅量子结构、无定形硅相和 SiOx。这些相的比例随蚀刻行为而变化。硅纳米晶的尺寸从 ~ 3.0 纳米变为 4.6 纳米,在 1.73 至 1.88 eV 的带隙范围内发出光学特征。荧光区域随 H2O2 含量的变化而变化。在使用过氧化氢比率较低的蚀刻剂蚀刻 PS 的情况下,荧光优先出现在金属圆和硅晶片的界面上。相反,非涂层区域的荧光从 19.5% 增加到 24.0%。
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引用次数: 0
Enhanced Optoelectronic and Electrical Properties of Silicon Nanowires by Electrodeposited ZnO Nanoparticles for Efficient Diode Performance 通过电沉积氧化锌纳米粒子增强硅纳米线的光电性能,实现高效二极管性能
IF 2.8 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2024-09-27 DOI: 10.1007/s12633-024-03156-9
Lamia Bouaziz, Amina Lamouchi, Mokhtar Karyaoui, Radhouane Chtourou

In this paper, Zinc Oxide nanoparticles (ZnO NPs) have been successfully synthesized for the first time by electrochemical deposition on silicon nanowires (SiNWs) produced using silver-assisted chemical etching method. The as-prepared nanowires were pre-coated with ZnO seed layer to initialize the uniform growth of ZnO nanoparticles from aqueous solutions using the electrochemical deposition. The SEM images showed a homogenous distribution of dense ZnO nanoparticles on silicon nanowires. X-ray diffraction pattern indicated that the electrodeposited ZnO NPs have hexagonal wurtzite structure. Current–voltage characteristics pointed that ZnO NPs significantly improved the diode parameters such as ideality factor (n), series resistance (({R}_{s})), energy barrier (({varphi }_{b})) and saturation current (({I}_{s})). As a result, a rectifying behavior of the ZnO NPs/SiNWs structure has been exhibited by a factor of 2.7 compared to pure SiNWs structures. The values of the saturation current ({I}_{s}) and the series resistance ({R}_{s}) of these heterostructures decrease indicating an improvement in junction quality which can be due to the reduction of dangling bonds and surface defects. Significantly, ZnO nanoparticles @SiNWs increased the minority carrier lifetime from 9.11 (mu s) to 14.89 (mu s) and consequently reduced the surface recombination activities, further revealing the efficient surface passivation role of ZnO nanoparticles. Good anti-reflectance abilities up to 10% and 15% are observed for pure SiNWs and SiNWs/ZnO NPs, respectively, as compared to 40% for bare Silicon. Based on these findings, SiNWs/ZnO NPs can be considered as potential candidate for optoelectronic devices, photovoltaics and nanoelectronics.

本文首次在银辅助化学蚀刻法制备的硅纳米线(SiNWs)上通过电化学沉积成功合成了氧化锌纳米粒子(ZnO NPs)。在制备的纳米线上预先涂覆了氧化锌种子层,以便利用电化学沉积从水溶液中初始化出均匀生长的氧化锌纳米粒子。扫描电镜图像显示,硅纳米线上均匀分布着致密的氧化锌纳米粒子。X 射线衍射图样表明,电沉积的 ZnO 纳米粒子具有六方菱面体结构。电流-电压特性表明,氧化锌纳米粒子明显改善了二极管的各项参数,如理想系数(n)、串联电阻(({R}_{s}))、能垒(({varphi }_{b}))和饱和电流(({I}_{s}))。因此,与纯 SiNWs 结构相比,ZnO NPs/SiNWs 结构的整流性能提高了 2.7 倍。这些异质结构的饱和电流值({I}_{s})和串联电阻值({R}_{s})都有所下降,表明结质量有所改善,这可能是由于悬空键和表面缺陷的减少。值得注意的是,氧化锌纳米粒子 @SiNWs 使少数载流子寿命从 9.11 (mu s) 延长到 14.89 (mu s) ,从而降低了表面重组活动,进一步揭示了氧化锌纳米粒子的高效表面钝化作用。纯 SiNWs 和 SiNWs/ZnO NPs 的良好抗反射能力分别高达 10%和 15%,而裸硅的抗反射能力仅为 40%。基于这些发现,SiNWs/ZnO NPs 可被视为光电器件、光伏和纳米电子学的潜在候选材料。
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