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Friction Stir Processing of Aluminium 5052 Surface Composites Reinforced with Micro and Nano SiC Particles: A Comparative Analysis 微纳米碳化硅增强铝5052表面复合材料搅拌摩擦加工的对比分析
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-15 DOI: 10.1007/s12633-025-03385-6
Shazman Nabi, Sandeep Rathee, Mohammad Farooq Wani

Surface composites (SCs) of aluminium-magnesium (Al–Mg) alloys reinforced with nano and micro silicon carbide (SiC) particles were fabricated using friction stir processing (FSP). The SCs were fabricated by multi-pass (five passes) FSP using a H13 steel tool. An investigation of the microstructural evolution, mechanical properties, wear behaviour, and corrosion resistance was conducted. The study revealed that nano-SiC reinforced SCs outclassed the micro-SiC reinforced as well as base metal (BM) counterparts in all domains. The ultimate tensile strength (337 MPa) and yield strength (315 MPa) of nano-SiC reinforced were 25.2% and 26.5% higher than BM (269 MPa and 249 MPa) and 13.5% and 11.3% higher than micro-SiC reinforced SC (287 MPa and 263 MPa), respectively. The wear rate in nano-SiC reinforced SC reduced significantly by about 16.67%, 14.73%, and 14.43% compared to BM and by 4.76%, 7.4%, and 7.78% compared to micro-SiC reinforced SC at 15N, 20N, and 25N loads, respectively. The nano-SiC reinforced SC showed 60% better corrosion resistance compared to BM and 50% better than micro-SiC reinforced SC. These improvements in reinforced SCs are attributed to various reasons: grain refinement due to FSP, uniform distribution of hard ceramic particles within the Al matrix, and the reduction in wear and corrosion-prone sites due to multiple FSP passes that minimise the agglomeration of reinforcement particles. This enhancement in the properties of nano-SiC-reinforced Al–Mg SCs makes them suitable for various applications in marine, automobile, and aerospace engineering domains.

Graphical Abstract

采用搅拌摩擦法(FSP)制备了纳米和微碳化硅(SiC)增强铝镁(Al-Mg)合金表面复合材料。sc采用H13钢刀具,采用多道次(五道次)FSP制备。研究了合金的显微组织演变、力学性能、磨损性能和耐蚀性。研究表明,纳米sic增强SCs在所有领域都优于微sic增强和贱金属(BM)。纳米sic增强SC的极限抗拉强度(337 MPa)和屈服强度(315 MPa)分别比BM (269 MPa和249 MPa)高25.2%和26.5%,比微sic增强SC (287 MPa和263 MPa)高13.5%和11.3%。在15N、20N和25N载荷下,纳米sic增强SC的磨损率与BM相比分别显著降低了16.67%、14.73%和14.43%,与微sic增强SC相比分别降低了4.76%、7.4%和7.78%。与BM相比,纳米sic增强SC的耐腐蚀性提高了60%,比微sic增强SC提高了50%。增强SC的这些改进归功于各种原因:FSP使晶粒细化,Al基体内硬陶瓷颗粒分布均匀,以及由于多次FSP通道减少了增强颗粒的团聚,从而减少了磨损和腐蚀易发部位。纳米sic增强Al-Mg - SCs性能的增强使其适用于船舶、汽车和航空航天工程领域的各种应用。图形抽象
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引用次数: 0
Deepfake Detection Utilizing Enhanced Silicon-Based Physically Unclonable Functions Integrated with Photonic Crystal Fiber Sensor 利用增强硅基物理不可克隆功能与光子晶体光纤传感器集成的深度假检测
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-14 DOI: 10.1007/s12633-025-03377-6
V. Suresh Babu, M. Sathya, R. Uma Maheshwari, K. J. Subha

This study introduces an advanced silicon-based physically unclonable function (PUF) integrated with Photonic Crystal Fiber (PCF) sensors, aimed at enhancing the robustness and reliability in deepfake detection devices. Leveraging the inherent unpredictability of silicon-based Physical Unclonable Functions (PUFs), combined with the sensitivity of PCF sensors, we propose a novel system for secure, accurate deepfake image detection utilizing hybrid Convolutional Neural Networks (CNN) and Long Short-Term Memory (LSTM) networks. The proposed architecture demonstrates significant improvement, achieving an average detection accuracy of 98.6%, surpassing existing models by 7.3%. Additionally, our integrated approach exhibits enhanced robustness, reducing false-positive rates by 15% and false negatives by 13.2% compared to conventional methods. Experimental evaluations confirm that the integration of silicon-based PUFs with PCF sensors not only strengthens the resilience against adversarial attacks but also enhances reliability under varying environmental conditions. This work offers a promising pathway toward advanced, secure, and high-performance deepfake detection solutions, suiTable for real-world deployment in cybersecurity applications.

本研究介绍了一种先进的硅基物理不可克隆功能(PUF)与光子晶体光纤(PCF)传感器集成,旨在提高深度假检测设备的鲁棒性和可靠性。利用硅基物理不可克隆函数(puf)固有的不可预测性,结合PCF传感器的灵敏度,我们提出了一种利用混合卷积神经网络(CNN)和长短期记忆(LSTM)网络进行安全、准确的深度假图像检测的新系统。该模型的平均检测准确率达到98.6%,比现有模型高出7.3%。此外,与传统方法相比,我们的综合方法显示出更高的稳健性,将假阳性率降低15%,假阴性率降低13.2%。实验评估证实,硅基puf与PCF传感器的集成不仅增强了对对抗性攻击的弹性,而且提高了在不同环境条件下的可靠性。这项工作为先进、安全和高性能的深度伪造检测解决方案提供了一条有前途的途径,适合在网络安全应用中实际部署。
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引用次数: 0
Design, Investigation and Performance Analysis of an Optimized Dopingless Nanosheet Field-Effect Transistor Based Biosensor (Bio-DLNSFET) 一种优化的无掺杂纳米片场效应晶体管生物传感器(Bio-DLNSFET)的设计、研究与性能分析
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-12 DOI: 10.1007/s12633-025-03379-4
Abhishek Chauhan, Ashish Raman

In this paper, a biosensor based on vertically stacked Dopingless Nanosheet FET (Bio-DLNSFET) is proposed and analyzed. The performance analysis of the proposed biosensor is carried out in terms of sensitivity and various analog/dc parameters. The device utilizes charge plasma technique to induce the charge carriers. A cavity is introduced under the gate region which shows good drain current (2.43E-05 A), low off current (1.33E-13 A), high Ion/Ioff ratio (1.83E + 08), lower SS (60.9 mV/Dec) and good sensitivity making it suitable for sensing applications. Further analysis is carried out by applying different types of biomolecules represented by their dielectric constants (k = 1, 2.1, 3.57, 8, 12 and 20). Biosensor shows good sensitivity and parametric variation for different biomolecules. Sensing ability of the biosensor is evaluated for different levels of biomolecules in the cavity. Biosensor shows detection of biomolecules from 50% of cavity filling. The effect of temperature along with positive and negative charge densities of biomolecules on the performance of the biosensor is further evaluated.

本文提出并分析了一种基于垂直堆叠无掺杂纳米片FET (Bio-DLNSFET)的生物传感器。从灵敏度和各种模拟/直流参数方面对所提出的生物传感器进行了性能分析。该装置利用电荷等离子体技术诱导载流子。在栅极区域下引入一个腔体,具有良好的漏极电流(2.43E-05 A),低关断电流(1.33E-13 A),高离子/ off比(1.83E + 08),低SS (60.9 mV/Dec)和良好的灵敏度,适用于传感应用。采用介电常数k = 1、2.1、3.57、8、12和20表示的不同类型生物分子进行进一步分析。生物传感器对不同的生物分子具有良好的灵敏度和参数变异性。评估了该传感器对腔内不同水平生物分子的传感能力。生物传感器显示从50%的空腔填充物中检测生物分子。进一步研究了温度以及生物分子的正负电荷密度对传感器性能的影响。
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引用次数: 0
Engineering Zeolite Frameworks for Radiation Shielding: Interplay between Topological Density and Structural Compactness for Optimized Attenuation 用于辐射屏蔽的工程沸石框架:优化衰减的拓扑密度和结构紧凑性之间的相互作用
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-11 DOI: 10.1007/s12633-025-03376-7
Z. Y. Khattari

This study systematically evaluates the radiation shielding performance of silicon-based zeolite frameworks (FAU, LTA, CHA, AST, MOR, FER, RHO) by correlating their topological density (TD), structural compactness, and compositional parameters with photon attenuation metrics. The RHO framework emerges as the most effective shield, achieving exceptional MAC (47.914 cm2/g) and LAC (148.064 cm⁻1) values at 15 keV, attributed to its high density (ρ = 3.09 g/cm3), balanced topological parameters (TD₁₀ = 641, TD = 0.533), and moderate accessible volume (20.63%). Its superior performance is further underscored by the highest effective atomic number (Zeff = 40.82 at 15 keV), reflecting optimized photon interaction efficiency. In contrast, the AST framework, with low density (ρ = 0.217 g/cm3), excessive porosity (TD = 0.625, zero accessible volume), and poor atomic packing, exhibits the weakest attenuation (MAC = 6.488 cm2/g, LAC = 1.409 cm⁻1). The interplay of topological parameters reveals that intermediate TD values (e.g., RHO, FAU) enhance shielding by balancing atomic packing and density, while high porosity (e.g., AST) diminishes performance. Notably, RHO maintains its advantage at higher energies (e.g., 5.0 MeV: MAC = 0.034 cm2/g, LAC = 0.106 cm⁻1, Zeff = 17.03), whereas FAU’s moderate density (ρ = 0.388 g/cm3) and accessible volume (27.42%) make it suitable for multifunctional applications. These insights underscore the importance of harmonizing topological compactness, accessible volume, and density in designing zeolite-based shields, with RHO serving as a benchmark for high-performance radiation protection in nuclear and medical applications.

本研究通过将硅基沸石骨架(FAU、LTA、CHA、AST、MOR、FER、RHO)的拓扑密度(TD)、结构紧凑度和成分参数与光子衰减指标相关联,系统地评估了它们的辐射屏蔽性能。RHO框架是最有效的屏蔽体,在15 keV时,由于其高密度(ρ = 3.09 g/cm3),平衡的拓扑参数(TD₁₀= 641,TD = 0.533)和适中的可访问体积(20.63%),实现了卓越的MAC (47.914 cm2/g)和LAC (148.064 cm⁻1)值。其最高的有效原子序数(在15 keV时Zeff = 40.82)进一步强调了其优越的性能,反映了优化的光子相互作用效率。相比而言,密度低(ρ = 0.217 g/cm3)、孔隙度高(TD = 0.625,零可达体积)、原子堆积性差的AST框架,其衰减最弱(MAC = 6.488 cm2/g, LAC = 1.409 cm⁻1)。拓扑参数的相互作用表明,中间TD值(如RHO, FAU)通过平衡原子堆积和密度来增强屏蔽,而高孔隙率(如AST)会降低屏蔽性能。值得注意的是,RHO在高能量下保持其优势(例如,5.0 MeV: MAC = 0.034 cm2/g, LAC = 0.106 cm - 1, Zeff = 17.03),而FAU的中等密度(ρ = 0.388 g/cm3)和可访问体积(27.42%)使其适合多功能应用。这些见解强调了在设计沸石基屏蔽时协调拓扑紧凑性、可访问体积和密度的重要性,RHO可作为核和医疗应用中高性能辐射防护的基准。
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引用次数: 0
Influence of Fe2O3 on Radiation Shielding, and Mechanical Properties of La2O3-SiO2-B2O3-MgO- Fe2O3 Glasses Fe2O3对La2O3-SiO2-B2O3-MgO- Fe2O3玻璃辐射屏蔽及力学性能的影响
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-10 DOI: 10.1007/s12633-025-03373-w
Dalal Abdullah Aloraini, Aljawhara Almuqrin, Badriah Albarzan, E. A. Abdel Wahab, Kh. S. Shaaban

Glass samples with the formula 75B2O3-10SiO2-5La2O3-(10-x)MgO-xFe2O3, (0 ≤ x ≤ 5 mol%), were manufactured to investigate the effect of substituting Fe2O3 for MgO. The density increases from 3.19 to 4.32 g/cm3 while the molar volume decreases from 24.62 to 19.56 m3/mol. Mechanical properties, including longitudinal (VL) and shear (VT) wave velocities and elastic moduli, improved consistently with higher Fe2O3 content. In terms of γ-radiation shielding, increasing Fe2O3 content resulted in higher linear attenuation coefficient (LAC) values, primarily because of the increase in density. At 0.015 MeV, the LAC (cm−1) values are highest, ranging from 43.94 (LMBSFe-0) to 69.811 (LMBSFe-5) while, At 15 MeV, values decrease sharply to 0.074 (LMBSFe-0) and 0.1 (LMBSFe-5). At 0.015 MeV, mean free path decreased from 0.02276 for (LMBSFe-0) to 0.01432 for (LMBSFe-5) (cm) while, At 15 MeV, decreased from 13.5882 for (LMBSFe-0) to 10.04991 for (LMBSFe-5). The decrease in MFP with higher Fe2O3 content reduces photon penetration and enhances glass shielding capability. Therefore, LMBSFe-5 exhibited the best γ-ray shielding performance among the studied compositions.

制备了配方为75B2O3-10SiO2-5La2O3-(10-x)MgO- xfe2o3(0≤x≤5 mol%)的玻璃样品,考察了用Fe2O3取代MgO的效果。密度由3.19 g/cm3增加到4.32 g/cm3,摩尔体积由24.62减小到19.56 m3/mol。随着Fe2O3含量的增加,材料的纵向波速(VL)和剪切波速(VT)以及弹性模量等力学性能得到了持续改善。在屏蔽γ辐射方面,Fe2O3含量的增加导致线性衰减系数(LAC)值的增加,这主要是由于密度的增加。在0.015 MeV时,LAC (cm−1)值最高,为43.94 (LMBSFe-0) ~ 69.811 (LMBSFe-5);在15 MeV时,LAC值急剧下降,分别为0.074 (LMBSFe-0)和0.1 (LMBSFe-5)。在0.015 MeV下,平均自由程由(LMBSFe-0)的0.02276减小到(LMBSFe-5)的0.01432 (cm),而在15 MeV下,平均自由程由(LMBSFe-0)的13.5882减小到(LMBSFe-5)的10.04991。随着Fe2O3含量的增加,MFP的降低降低了光子的穿透性,增强了玻璃的屏蔽能力。因此,LMBSFe-5具有最佳的屏蔽γ射线的性能。
{"title":"Influence of Fe2O3 on Radiation Shielding, and Mechanical Properties of La2O3-SiO2-B2O3-MgO- Fe2O3 Glasses","authors":"Dalal Abdullah Aloraini,&nbsp;Aljawhara Almuqrin,&nbsp;Badriah Albarzan,&nbsp;E. A. Abdel Wahab,&nbsp;Kh. S. Shaaban","doi":"10.1007/s12633-025-03373-w","DOIUrl":"10.1007/s12633-025-03373-w","url":null,"abstract":"<div><p>Glass samples with the formula 75B<sub>2</sub>O<sub>3</sub>-10SiO<sub>2</sub>-5La<sub>2</sub>O<sub>3</sub>-(10-<i>x</i>)MgO-<i>x</i>Fe<sub>2</sub>O<sub>3</sub>, (0 ≤ <i>x</i> ≤ 5 mol%), were manufactured to investigate the effect of substituting Fe<sub>2</sub>O<sub>3</sub> for MgO. The density increases from 3.19 to 4.32 g/cm<sup>3</sup> while the molar volume decreases from 24.62 to 19.56 m<sup>3</sup>/mol. Mechanical properties, including longitudinal (V<sub>L</sub>) and shear (V<sub>T</sub>) wave velocities and elastic moduli, improved consistently with higher Fe<sub>2</sub>O<sub>3</sub> content. In terms of γ-radiation shielding, increasing Fe<sub>2</sub>O<sub>3</sub> content resulted in higher linear attenuation coefficient (LAC) values, primarily because of the increase in density. At 0.015 MeV, the LAC (cm<sup>−1</sup>) values are highest, ranging from 43.94 (LMBSFe-0) to 69.811 (LMBSFe-5) while, At 15 MeV, values decrease sharply to 0.074 (LMBSFe-0) and 0.1 (LMBSFe-5). At 0.015 MeV, mean free path decreased from 0.02276 for (LMBSFe-0) to 0.01432 for (LMBSFe-5) (cm) while, At 15 MeV, decreased from 13.5882 for (LMBSFe-0) to 10.04991 for (LMBSFe-5). The decrease in MFP with higher Fe<sub>2</sub>O<sub>3</sub> content reduces photon penetration and enhances glass shielding capability. Therefore, LMBSFe-5 exhibited the best γ-ray shielding performance among the studied compositions.</p></div>","PeriodicalId":776,"journal":{"name":"Silicon","volume":"17 11","pages":"2705 - 2714"},"PeriodicalIF":3.3,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructural and Mechanical Improvements in A356 Composites on Incorporating Polymer Derived Ceramics Through Ultrasonication at Semi-solid and Liquid State 半固态和液态超声改善聚合物衍生陶瓷A356复合材料的组织和力学性能
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-10 DOI: 10.1007/s12633-025-03371-y
Arulpandian Palanisamy, Nagaraj Chelliah Machavallavan, Dhanasekar Ramalingam, Kumaravel Sundaram

This research investigates the fabrication of in-situ A356 matrix composites reinforced with polymer-derived ceramics via ultrasonication at semi-solid (620 °C) and liquid-state (720 °C) temperatures. A fixed volume percentage of 2.5% cross-linked polymer was injected into the molten A356 using ultrasonic-assisted stir casting. Microstructural analysis revealed a significant grain refinement in the composite fabricated at 620 °C, with grain sizes approximately 30% smaller compared to the 720 °C composite and the as-cast A356. XRD analysis of the composite synthesized at 620 °C did not manifest an Mg2Si peak, implying the likelihood of this phase formation only at temperatures surpassing 650 °C. The 620 °C composite also exhibited a 44% increase in hardness compared to the 720 °C composite. While the yield strength of the 720 °C composite showed a marginal improvement, the 620 °C composite demonstrated a substantial 20% increase in yield strength without a noticeable reduction in ductility, attributed to the uniform dispersion of SiOC particles. This study highlights the benefits of combining ultrasonication and semi-solid processing for enhancing the microstructure and mechanical properties of A356-SiOC composites.

本研究研究了在半固态(620℃)和液态(720℃)温度下通过超声法制备聚合物衍生陶瓷原位增强的A356基复合材料。采用超声辅助搅拌铸造的方法,将固定体积百分比为2.5%的交联聚合物注入A356熔体中。显微组织分析显示,在620℃下制备的复合材料晶粒细化明显,与720℃的复合材料和铸态A356相比,晶粒尺寸缩小了约30%。在620°C合成的复合材料的XRD分析没有出现Mg2Si峰,这意味着只有在超过650°C的温度下才有可能形成这种相。与720°C复合材料相比,620°C复合材料的硬度也提高了44%。720°C复合材料的屈服强度略有提高,而620°C复合材料的屈服强度提高了20%,但延展性没有明显降低,这归功于SiOC颗粒的均匀分散。本研究强调了超声和半固态加工相结合对提高A356-SiOC复合材料的微观结构和力学性能的好处。
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引用次数: 0
Comprehensive Analysis of Silane Coatings on Carbon Steel: From Microscopy to Quantum Chemistry 碳钢表面硅烷涂层的综合分析:从显微到量子化学
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-09 DOI: 10.1007/s12633-025-03378-5
Kaixuan Zhang, Yongjuan Geng, Shaochun Li, Dongshuai Hou, Muhan Wang, Ang Liu, Yu Zhou, Yancen Liu, Meng Wang, Zhonglin Xiao, Xiaoyu Zhang

In the realm of eco-friendly metal pretreatment methods as a substitute for chromates, silanes have emerged as a prominent option for augmenting the adhesion of polymer coatings onto the surfaces of carbon steel. However, there exists a notable dearth of research at the nanoscale, delving into the interaction between silanes and carbon steel surfaces. To address this gap, silane coatings were applied on the carbon steel surface via an electrodeposition process. A comprehensive investigation was conducted to elucidate the interfacial bonding characteristics and corrosion inhibition mechanism between silanes and hydroxylated carbon steel surfaces using an array of analytical techniques, including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FT-IR), Raman spectroscopy, molecular dynamics (MD) simulations, and density functional theory (DFT) calculations. The results revealed that the silane layer achieved stable adsorption, with a contact angle of 91.29°, forming a robust interface with the passivation layer on the carbon steel surface. The hydrogen bonding interactions between the silanol groups in the silane molecules and the hydroxyl groups within the passivation film on the carbon steel surface were identified as the primary mechanism responsible for this adsorption. This integrated approach combining experimental and computational methods provides new insights into the interfacial bonding and corrosion inhibition behavior of silane coatings, thereby offering a scientific foundation for their practical application in metal protection systems.

在替代铬酸盐的环保金属预处理方法领域,硅烷已成为增强聚合物涂层在碳钢表面粘附性的重要选择。然而,在纳米尺度上研究硅烷与碳钢表面相互作用的研究明显缺乏。为了解决这一差距,硅烷涂层通过电沉积工艺应用于碳钢表面。利用扫描电镜(SEM)、x射线光电子能谱(XPS)、傅里叶变换红外光谱(FT-IR)、拉曼光谱、分子动力学(MD)模拟和密度泛函理论(DFT)计算等一系列分析技术,对硅烷与羟基化碳钢表面的界面键合特征和缓蚀机理进行了全面研究。结果表明,硅烷层吸附稳定,接触角为91.29°,与钝化层在碳钢表面形成牢固的界面。硅烷分子中的硅醇基团与碳钢表面钝化膜中的羟基之间的氢键相互作用被确定为这种吸附的主要机制。这种实验与计算相结合的方法为硅烷涂层的界面结合和缓蚀行为提供了新的见解,从而为其在金属保护系统中的实际应用提供了科学依据。
{"title":"Comprehensive Analysis of Silane Coatings on Carbon Steel: From Microscopy to Quantum Chemistry","authors":"Kaixuan Zhang,&nbsp;Yongjuan Geng,&nbsp;Shaochun Li,&nbsp;Dongshuai Hou,&nbsp;Muhan Wang,&nbsp;Ang Liu,&nbsp;Yu Zhou,&nbsp;Yancen Liu,&nbsp;Meng Wang,&nbsp;Zhonglin Xiao,&nbsp;Xiaoyu Zhang","doi":"10.1007/s12633-025-03378-5","DOIUrl":"10.1007/s12633-025-03378-5","url":null,"abstract":"<div><p>In the realm of eco-friendly metal pretreatment methods as a substitute for chromates, silanes have emerged as a prominent option for augmenting the adhesion of polymer coatings onto the surfaces of carbon steel. However, there exists a notable dearth of research at the nanoscale, delving into the interaction between silanes and carbon steel surfaces. To address this gap, silane coatings were applied on the carbon steel surface via an electrodeposition process. A comprehensive investigation was conducted to elucidate the interfacial bonding characteristics and corrosion inhibition mechanism between silanes and hydroxylated carbon steel surfaces using an array of analytical techniques, including scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier-transform infrared spectroscopy (FT-IR), Raman spectroscopy, molecular dynamics (MD) simulations, and density functional theory (DFT) calculations. The results revealed that the silane layer achieved stable adsorption, with a contact angle of 91.29°, forming a robust interface with the passivation layer on the carbon steel surface. The hydrogen bonding interactions between the silanol groups in the silane molecules and the hydroxyl groups within the passivation film on the carbon steel surface were identified as the primary mechanism responsible for this adsorption. This integrated approach combining experimental and computational methods provides new insights into the interfacial bonding and corrosion inhibition behavior of silane coatings, thereby offering a scientific foundation for their practical application in metal protection systems.</p></div>","PeriodicalId":776,"journal":{"name":"Silicon","volume":"17 11","pages":"2673 - 2689"},"PeriodicalIF":3.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145143010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multiplexer Based All-Optical NOR, NAND, XNOR and XOR Gates Using Silicon Microring Resonator: Design and Analysis 基于硅微环谐振器的全光NOR、NAND、XNOR和XOR门的多路复用器:设计与分析
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-07-09 DOI: 10.1007/s12633-025-03372-x
Selvakumarasamy Kathirvelu, Somasundaram Kasiviswanathan, Chidambarathanu Krishnan, Sultan Mahaboob Basha, Manjur Hossain

Proposed manuscript designs and analyzes the all-optical NOR, NAND, XNOR and XOR gates using silicon microring resonator based 2:1 multiplexer. Growing demand for ultra-fast terahertz data transfer and processing has driven the field to consider large-scale optical integrated circuits as a substitute to traditional CMOS technology. In addition, energy-efficient networks are becoming more essential. MATLAB is used to design and analyze the architecture at almost 260 Gbps. Different key performance parameters are assessed such as contrast ratio of 18.8 dB, extinction ratio of 15.8 dB and amplitude modulation of 0.11 dB at a very low pump power of 1.96 mW which is satisfactory for the proposed design. Processing of digital signals and communication systems can benefit greatly from the demonstrated multiplexer-based circuits' compact architecture and faster reaction times. To make practical use of the design, optimal design parameters are selected.

基于2:1多路复用器的硅微环谐振器设计并分析了全光NOR、NAND、XNOR和XOR门。对超快速太赫兹数据传输和处理的需求不断增长,促使该领域考虑大规模光学集成电路作为传统CMOS技术的替代品。此外,节能网络正变得越来越重要。利用MATLAB设计和分析了近260 Gbps的架构。在非常低的泵浦功率1.96 mW下,对对比度18.8 dB、消光比15.8 dB和调幅0.11 dB等关键性能参数进行了评估,使设计满意。数字信号和通信系统的处理可以从演示的基于多路复用器的电路的紧凑结构和更快的反应时间中受益匪浅。为使设计能实际应用,选择了最优设计参数。
{"title":"Multiplexer Based All-Optical NOR, NAND, XNOR and XOR Gates Using Silicon Microring Resonator: Design and Analysis","authors":"Selvakumarasamy Kathirvelu,&nbsp;Somasundaram Kasiviswanathan,&nbsp;Chidambarathanu Krishnan,&nbsp;Sultan Mahaboob Basha,&nbsp;Manjur Hossain","doi":"10.1007/s12633-025-03372-x","DOIUrl":"10.1007/s12633-025-03372-x","url":null,"abstract":"<div><p>Proposed manuscript designs and analyzes the all-optical NOR, NAND, XNOR and XOR gates using silicon microring resonator based 2:1 multiplexer. Growing demand for ultra-fast terahertz data transfer and processing has driven the field to consider large-scale optical integrated circuits as a substitute to traditional CMOS technology. In addition, energy-efficient networks are becoming more essential. MATLAB is used to design and analyze the architecture at almost 260 Gbps. Different key performance parameters are assessed such as contrast ratio of 18.8 dB, extinction ratio of 15.8 dB and amplitude modulation of 0.11 dB at a very low pump power of 1.96 mW which is satisfactory for the proposed design. Processing of digital signals and communication systems can benefit greatly from the demonstrated multiplexer-based circuits' compact architecture and faster reaction times. To make practical use of the design, optimal design parameters are selected.</p></div>","PeriodicalId":776,"journal":{"name":"Silicon","volume":"17 11","pages":"2691 - 2703"},"PeriodicalIF":3.3,"publicationDate":"2025-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145143013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tunable Performance of Amorphous In-Zn-O Thin Film Transistors via Silicon Doping for Logic Circuit Integration 基于硅掺杂的非晶In-Zn-O薄膜晶体管在逻辑电路集成中的可调性能
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-06-27 DOI: 10.1007/s12633-025-03359-8
Sunjin Lee, Tae Ho Kim, Sang Ji Kim, Sang Yeol Lee

The effect of silicon (Si) content in the indium-zinc-oxide (IZO) system on the electrical characteristics of thin-film transistors (TFTs) has been investigated depending on various Si ratios. The SiInZnO (SIZO) TFTs exhibited excellent performance, with field-effect mobility exceeding 28cm(^2)V(^{-1})s(^{-1}), a subthreshold slope of 0.506 V-decade(^{-1}), and an on/off current ratio over 10(^{8}). As Si content increased, the number of defect states decreased, resulting in enhanced threshold voltage stability and reduced subgap states, improving both mobility and bias stability. Amorphous Oxide Semiconductor(AOS) electrical properties are affected by oxygen vacancies(V(_{o})) in the channel layer. These findings suggest that SIZO TFTs are promising for next-generation flexible electronics. NOT, NAND, and NOR logic circuits have been implemented simply by modulating the Si ratio on the channel layer, an excellent voltage gain was obtained using SIZO TFTs.

研究了不同硅比下铟锌氧化物(IZO)体系中硅(Si)含量对薄膜晶体管(TFTs)电学特性的影响。SiInZnO (SIZO) tft表现出优异的性能,场效应迁移率超过28cm (^2) V (^{-1}) s (^{-1}),亚阈值斜率为0.506 V-decade (^{-1}),通断电流比超过10 (^{8})。随着Si含量的增加,缺陷态的数量减少,导致阈值电压稳定性增强,子隙态减少,提高了迁移率和偏置稳定性。非晶氧化物半导体(AOS)的电学性能受通道层氧空位(V (_{o}))的影响。这些发现表明,SIZO tft在下一代柔性电子产品中很有前景。通过简单地在通道层上调制Si比率,实现了NOT, NAND和NOR逻辑电路,使用SIZO tft获得了良好的电压增益。
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引用次数: 0
Fractional-order Photo-thermoelastic Model for Laser-induced Dynamic Response in Sandwich Laminated Semiconductor Composites 激光诱导夹层半导体复合材料动态响应的分数阶光热弹性模型
IF 3.3 3区 材料科学 Q3 CHEMISTRY, PHYSICAL Pub Date : 2025-06-27 DOI: 10.1007/s12633-025-03365-w
Chenlin Li, Jiaxi Zhou, Tianhu He

Laser heating technology as new hyperfine-precision approach which has been widely applied in the micro-machining of the sandwich laminated semiconductor composites (SLSC), where the memory-dependency of the strain and heat transport significantly increases. To accurately predict the micro-scale transient impact response of SLSC subjected to the non-Gaussian laser beam, a new Cattaneo-photo-thermoelastic model is established in this work based on memory-dependent strain and heat transport evolution laws with Atangana-Baleanu and Tempered-Caputo fractional derivatives. This model aims to analyze the influences of memory dependent thermal transport and strain as well as the parameters ratios of inner/outer layer materials on the photo-thermoelastic response and wave propagations in SLSC. The time-domain solutions of the one-dimensional multi-variables partial differential equations are solved via semi-analytical technique based on Laplace transformation. Dimensionless numerical results reveal that the decrease of the memory-dependent parameters of heat transport and strain lower the thermal wave propagation speed and reduce harmful stress and deformation in the SLSC. And the properly selecting parameters of laser intensity, pulse duration and semiconductor parameters ratios maximally improve the photo-thermo-mechanical impact responses and photo-thermal waves.

激光加热技术作为一种新的超精密加工方法,在夹层半导体复合材料的微加工中得到了广泛的应用,其应变和热输运的记忆依赖性显著增强。为了准确预测SLSC在非高斯光束作用下的微尺度瞬态冲击响应,本文基于记忆依赖的应变和热输运演化规律,利用Atangana-Baleanu和tempere - caputo分数阶导数建立了新的cattaneo -光热弹性模型。该模型旨在分析记忆相关热输运和应变以及内层/外层材料参数比对SLSC光热弹性响应和波传播的影响。采用基于拉普拉斯变换的半解析方法求解一维多变量偏微分方程的时域解。无因次数值计算结果表明,热传递和应变记忆参数的减小降低了热波传播速度,减小了SLSC中的有害应力和变形。合理选择激光强度、脉冲持续时间和半导体参数比值等参数,可以最大程度地改善光-热-机械冲击响应和光-热波。
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