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Mechanistic investigation on the Hg0 elimination ability of MnOx–CeOx nanorod adsorbents: effects of Mn/Ce molar ratio MnOx-CeOx 纳米棒吸附剂消除 Hg0 能力的机理研究:Mn/Ce 摩尔比的影响
Pub Date : 2024-01-22 DOI: 10.1007/s42768-023-00181-z
Shujie Gao, Xiaoxiang Wang, Yaolin Wang, Kai Zhu, Changxing Hu, Dong Ye

Mercury pollution is created by coal combustion processes in multi-component systems. Adsorbent injection was identified as a potential strategy for capturing Hg0 from waste gases, with adsorbents serving as the primary component. The hydrothermal approach was used to synthesize a series of MnOx–CeOx nanorod adsorbents with varying Mn/Ce molar ratios to maximize the Hg0 capture capabilities. Virgin CeOx had weak Hg0 elimination activity; <8% Hg0 removal efficiency was obtained from 150 °C to 250 °C. With the addition of MnOx, the amount of surface acid sites and the relative concentration of Mn4+ increased. This ensured the sufficient adsorption and oxidation of Hg0 while overcoming the limitations of restricted adsorbate-adsorbent interactions caused by the lower surface area, endowing MnOx–CeOx with increased Hg0 removal capacity. When the molar ratio of Mn/Ce reached 6/4, the adsorbent’s Hg0 removal efficiency remained over 92% at 150 °C and 200 °C. As the molar ratio of Mn/Ce grew, the adsorbent’s Hg0 elimination capacity declined due to decreased surface area, weakened acidity, and decreased activity of Mn4+; <75% Hg0 removal efficiency was reached between 150 °C and 250 °C for virgin MnOx. Throughout the overall Hg0 elimination reactions, Mn4+ and Oα were in charge of oxidizing Hg0 to HgO, with Ce4+ acting as a promoter to aid in the regeneration of Mn4+. Because of its limited adaptability to flue gas components, further optimization of the MnOx–CeOx nanorod adsorbent is required.

Graphical abstract

汞污染是由多组分系统中的燃煤过程造成的。吸附剂注入被认为是一种从废气中捕获 Hg0 的潜在策略,吸附剂是其中的主要成分。研究人员采用水热法合成了一系列具有不同 Mn/Ce 摩尔比的 MnOx-CeOx 纳米棒吸附剂,以最大限度地提高捕获 Hg0 的能力。原始 CeOx 的除汞活性较弱;在 150 °C 至 250 °C 的温度范围内,除汞效率为 8%。随着 MnOx 的加入,表面酸性位点的数量和 Mn4+ 的相对浓度都有所增加。这保证了 MnOx-CeOx 对 Hg0 的充分吸附和氧化,同时克服了因表面积较小而导致的吸附剂与吸附剂之间相互作用受限的问题,从而提高了 MnOx-CeOx 对 Hg0 的去除能力。当 Mn/Ce 的摩尔比达到 6/4 时,吸附剂在 150 °C 和 200 °C 下的 Hg0 去除率保持在 92% 以上。随着 Mn/Ce 摩尔比的增加,由于表面积减小、酸性减弱和 Mn4+ 活性降低,吸附剂的 Hg0 消除能力下降;原始 MnOx 的 Hg0 消除效率在 150 °C 至 250 °C 之间达到 75%。在整个 Hg0 消除反应中,Mn4+ 和 Oα 负责将 Hg0 氧化为 HgO,Ce4+ 则作为促进剂帮助 Mn4+ 的再生。由于 MnOx-CeOx 纳米棒吸附剂对烟气成分的适应性有限,因此还需要进一步优化。
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引用次数: 0
Photovoltaic waste management in sub-Saharan Africa: current practices in Burkina Faso 撒哈拉以南非洲的光伏废物管理:布基纳法索的现行做法
Pub Date : 2024-01-22 DOI: 10.1007/s42768-023-00184-w
Kodami Badza, Yrebegnan Moussa Soro, Marie Sawadogo

Sub-Saharan Africa is witnessing a proliferation of photovoltaic (PV) waste due to the increasing number of solar PV power plants. PV waste (panels, batteries, electrical cables, mounting structures, and inverters) consists of elements such as mercury, cadmium, chromium, lead, copper, aluminum, fluorinated compounds, and plastics that are toxic to human health and the environment if a proper management system is not available. Although many studies worldwide have focused on PV waste management, very few have been conducted in sub-Saharan Africa. This study aims to investigate the current PV waste management system in Burkina Faso, determine stakeholder profiles, and propose strategies to enhance the existing system. Documentary research, interviews, questionnaires, and field visits were used in the methodology. The survey showed that young people, mainly under 30 years of age and with a primary education, dominate (70%) in terms of PV waste collection and repair activities, while the more technical recycling and export activities are carried out mainly (88%) by stakeholders older than 40 years and with a secondary education (60%). Among the older stakeholders, 100% are aware of the hazardous nature of PV waste, whereas 36% are young people. From an environmental perspective, the main source of contamination observed is the release of lead-rich sulfuric acids into water and soil during the collection and repair phases. During the recycling of batteries and electrical cables, toxic fumes are emitted into the air, and recycling residues rich in toxic substances are landfilled. To reduce risks to human health and the environment when managing PV waste, the introduction of legislation, the multiplication of collection points and appropriate infrastructures, the training and awareness-raising of stakeholders, and the extended responsibility of manufacturers are recommended. Studies on the economic feasibility of setting up formal management structures are needed to complete this work.

Graphical abstract

由于太阳能光伏发电厂的数量不断增加,撒哈拉以南非洲地区的光伏废物正在激增。光伏废物(电池板、电池、电缆、安装结构和逆变器)由汞、镉、铬、铅、铜、铝、氟化合物和塑料等元素组成,如果没有适当的管理系统,这些元素会对人类健康和环境造成危害。尽管全世界有许多研究都关注光伏废物管理,但在撒哈拉以南非洲地区进行的研究却寥寥无几。本研究旨在调查布基纳法索目前的光伏废物管理系统,确定利益相关者的情况,并提出加强现有系统的策略。研究方法包括文献研究、访谈、问卷调查和实地考察。调查显示,在光伏废物收集和维修活动方面,以 30 岁以下、受过初等教育的年轻人为主(70%),而技术性更强的回收和出口活动主要由 40 岁以上、受过中等教育的利益相关者开展(88%)(60%)。在年龄较大的利益相关者中,100% 意识到光伏废物的危险性,而年轻人则占 36%。从环境角度来看,所观察到的主要污染源是在收集和维修阶段向水和土壤中释放的富含铅的硫酸。在回收电池和电缆的过程中,有毒气体会排放到空气中,富含有毒物质的回收残留物会被填埋。为降低光伏废物管理对人类健康和环境造成的风险,建议出台相关法律,增加收集点和适当的基础设施,对利益相关者进行培训和宣传,并扩大制造商的责任。为完成这项工作,需要对建立正式管理结构的经济可行性进行研究。
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引用次数: 0
Rapid and real-time detection of municipal sludge moisture content based on microwave reflection principle 基于微波反射原理的市政污泥含水率快速实时检测
Pub Date : 2024-01-22 DOI: 10.1007/s42768-023-00179-7
Yan Zhang, Yanhong Jiao, Jun Li, Long Deng, Binqi Rao, Hao Xu, Peng Xu, Lijiang Hu, Chunping Li

The moisture content (MC) of municipal sludge is the key factor affecting sludge treatment and disposal technologies, while the vast majority of existing measurement methods are off-line and time-consuming. To realize rapid online detection for the MC of sludge, a detection method based on the microwave reflection principle is proposed: experiments are carried out and the MC computation model of the sludge is derived using the resonant frequency and the permittivity ((varepsilon^{prime})). The results reveal that the detection accuracy of granular sludge with a thickness of 10 mm is higher. The theoretical model between the MC and the real part of (varepsilon^{prime}) is developed, and the relationship between the resonant frequency and (varepsilon^{prime}) is expressed by a cubic polynomial. The average error and the root mean square error (RMSE) of sludge are 2.06% and 2.49%, respectively. The prediction model for the MC of sludge is also given, and the determination coefficient and RMSE are 0.981 and 2.06%, respectively.

Graphical abstract

市政污泥的含水率(MC)是影响污泥处理和处置技术的关键因素,而现有的测量方法绝大多数都是离线测量,耗时较长。为了实现污泥含水率的快速在线检测,本文提出了一种基于微波反射原理的检测方法:通过实验,利用共振频率和介电常数(((varepsilon^{prime}))推导出污泥的含水率计算模型。结果表明,厚度为 10 毫米的颗粒状污泥的检测精度更高。建立了 MC 与 (varepsilon^{prime})实部之间的理论模型,并用三次多项式表示了共振频率与 (varepsilon^{prime})之间的关系。污泥的平均误差和均方根误差(RMSE)分别为 2.06% 和 2.49%。同时给出了污泥 MC 的预测模型,其判定系数和均方根误差分别为 0.981% 和 2.06%。
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引用次数: 0
Evaluation of the efficiency of urban solid waste management in Brazil by data envelopment analysis and possible variables of influence 通过数据包络分析和可能的影响变量评估巴西城市固体废物管理的效率
Pub Date : 2024-01-22 DOI: 10.1007/s42768-023-00175-x
Isabel das Mercês Costa, Marta Ferreira Dias, Margarita Robaina

This article has the general objective of estimating the efficiency of urban solid waste management in 940 Brazilian municipalities through Data Envelopment Analysis (DEA) technique and has specific objectives: (i) to estimate efficiency scores; (ii) to compare the performance between different groups of municipalities; and (iii) to analyze the profile of efficient municipalities from the perspective of the guidelines of Law 12,305/2010 and socio-economic and environmental indicators. The technique used was DEA with output-oriented and variable scale to return modeling. The results showed higher efficiency scores in the municipalities with populations above 500,000 inhabitants. The score variation ranged from 0.5 (municipalities with populations <10,000 inhabitants) to 0.9 (municipalities with more than 500,000 inhabitants). Of the sample set, only 12.34% of the municipalities were considered efficient, and when analyzing the efficient group, it was found that adherence to legislation was not a major factor in achieving efficiency.

Graphical abstract

本文的总体目标是通过数据包络分析(DEA)技术估算巴西 940 个市镇的城市固体废物管理效率,具体目标包括:(i) 估算效率得分;(ii) 比较不同市镇组之间的绩效;(iii) 从第 12305/2010 号法律准则以及社会经济和环境指标的角度分析高效市镇的概况。使用的技术是以产出为导向的 DEA 和可变规模回报模型。结果显示,人口在 50 万以上的城市效率得分较高。得分差异从 0.5(人口为 10,000 人的城市)到 0.9(人口超过 500,000 人的城市)不等。在样本集中,只有 12.34% 的市政当局被认为是高效率的,在对高效率群体进行分析时发现,遵守立法并不是实现高效率的主要因素。
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引用次数: 0
A quantitative analysis of the US materials flow methodology and comparison to the EU methodology for MSW statistics 对美国材料流方法的定量分析以及与欧盟都市固体废物统计方法的比较
Pub Date : 2024-01-15 DOI: 10.1007/s42768-023-00171-1
Demetra Tsiamis, Fabio Poretti, Stefano Consonni, Marco J. Castaldi

The European Union (EU) and the United States (US) determine municipal solid waste (MSW) statistics differently. The EU applies a site-specific methodology that directly measures waste whereas the US employs a materials flow methodology that estimates MSW statistics indirectly based on production and recovery data from industries. This study dissects the materials flow methodology and presents quantitative materials flow Sankey diagrams for the primary MSW materials to highlight data gaps that can be addressed to improve the methodology’s accuracy. Private industry plastics data were applied to the materials flow methodology, and the results were within 10% of the plastics statistics reported by the US Environmental Protection Agency (US EPA). Drawbacks to the methodologies include EU measurement inaccuracies due to double-counting and not accounting for residual waste in the US. The latter may partially explain why landfilling tonnages reported by the US EPA were approximately 60% less than the tonnages reported by the Waste to Energy Research and Technology Council (WTERT) in its national MSW survey that applied the EU methodology in the US. Unlike the EU, there is no US national policy that requires states to measure and report state-level waste data to the US EPA. Future improvements in US MSW statistics rely heavily on the implementation of national policies to homogenize the measurement and collection of waste data from states.

欧盟(EU)和美国(US)确定城市固体废物(MSW)统计数据的方法不同。欧盟采用针对具体地点的方法直接测量废物,而美国则采用材料流方法,根据各行业的生产和回收数据间接估算城市固体废物统计数据。本研究对材料流方法进行了剖析,并为主要的都市固体废物材料提供了定量材料流桑基图,以突出可用于提高该方法准确性的数据缺口。私营企业的塑料数据被应用于材料流方法,其结果与美国环境保护局(US EPA)报告的塑料统计数据相差不超过 10%。该方法的缺点包括:由于重复计算和未考虑美国的残余废物,导致欧盟的测量不准确。后者可以部分解释为什么美国环保局报告的填埋吨数比废物变能源研究与技术委员会(WTERT)在其全国 MSW 调查中报告的吨数少约 60%,而后者在美国采用的是欧盟的方法。与欧盟不同,美国没有要求各州测量并向美国环保局报告州级废物数据的国家政策。未来美国 MSW 统计数据的改进在很大程度上有赖于国家政策的实施,以统一各州对废物数据的测量和收集。
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引用次数: 0
Towards a sustainable geoliner construction in landfills by potential blending of fly ash with kaolin clay alternative: a review with an insight to Indian scenario 通过粉煤灰与高岭土替代品的潜在混合,在垃圾填埋场建造可持续的土工碾磨机:对印度情况的回顾与展望
Pub Date : 2024-01-10 DOI: 10.1007/s42768-023-00178-8
Kshitij Kumar, Biswajit Paul

Electricity generated through coal-based Thermal Power Plants (TPPs) has played a pivotal role in shaping modern civilization, revolutionizing industries, and improving the quality of life for billions of people worldwide. These TPPs contribute to about 37%–40% of the global energy requirements. Energy production, in turn, has a direct impact on the economy of any country. Apart from this boon to humankind, these TPPs combusting coal as their primary fuel also have specific environmental impacts, the major ones being water, air, and soil pollution due to unscientific disposal of high-quantity fly ash produced yearly. If we can put this ash to good use, it may assist us in mitigating the pollution caused by it. Although there are many conventional uses of fly ash, such as a pozzolanic material in the cement industry, more pathways need to be discovered to balance the high generation quantities with consumption. Therefore, a detailed description of its use in potential geoliner applications is presented in this article. A geoliner or a landfill liner acts as a virtually impenetrable layer to mitigate the leachate penetration into the underneath subsoil and groundwater, thus preventing contamination. There are presently some studies that support the use of only fly ash in such applications. Nevertheless, the properties of the geoliners using it are not so good to significantly mitigate environmental degradation owing to its high permeability and low densification tendency. The bentonite conventionally used has limited deposits and is mined intensively for its use as a natural sealant. Their deposits must also be conserved, and an alternative material that may serve similar application benefits, like bentonite, must be selected. The desired aim can be fulfilled if we blend this combustion residue with other suitable materials (such as kaolinite clay) with low permeability. Thus, the article focuses on the possibilities of blending fly ash with different clays for geoliner construction to improve the individual properties of fly ash. This will contribute to developing a scope for future scientific research in deploying these blends in natural membrane materials for various industries. Different types of geoliners that are designed to contain the disposed-off waste are also explained in detail. Additionally, a glimpse of the global fly ash market is put forward to depict its importance for various industries in this technologically advancing world. This article profoundly observes an overall environmental management aspect regarding waste utilization.

Graphical abstract

煤炭火力发电厂(TPPs)产生的电力在塑造现代文明、革新工业以及改善全球数十亿人的生活质量方面发挥了关键作用。这些火力发电厂约占全球能源需求的 37%-40%。能源生产反过来又对任何国家的经济产生直接影响。除了给人类带来福音之外,这些以煤炭为主要燃料的火力发电厂也会对环境造成特定的影响,其中最主要的是由于不科学地处理每年产生的大量粉煤灰而造成的水、空气和土壤污染。如果我们能够很好地利用这些粉煤灰,或许可以帮助我们减轻粉煤灰造成的污染。尽管粉煤灰有许多传统用途,如水泥工业中的一种混合材料,但仍需要探索更多的途径来平衡高产生量和高消耗量。因此,本文将详细介绍粉煤灰在地质焚烧炉中的潜在用途。土工衬垫或垃圾填埋场衬垫是一个几乎无法穿透的层,可减少渗滤液渗入底土和地下水,从而防止污染。目前有一些研究支持在此类应用中只使用粉煤灰。然而,由于粉煤灰的高渗透性和低致密化倾向,使用粉煤灰的土工格室的性能并不理想,无法显著缓解环境退化问题。传统使用的膨润土储量有限,且因用作天然密封剂而被大量开采。因此,必须保护这些矿藏,并选择与膨润土具有类似应用优势的替代材料。如果我们将这种燃烧残渣与其他合适的低渗透性材料(如高岭石粘土)混合在一起,就能达到预期目的。因此,本文重点探讨了将粉煤灰与不同粘土混合用于土工筑路的可能性,以改善粉煤灰的各种特性。这将有助于为未来将这些混合物应用于各行业的天然膜材料的科学研究拓展范围。此外,还详细介绍了设计用于容纳废弃废物的不同类型的土工衬垫。此外,文章还对全球粉煤灰市场进行了概述,以说明在这个技术不断进步的世界中,粉煤灰对各行各业的重要性。本文深刻观察了废物利用的整体环境管理方面。
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引用次数: 0
Novel energy recovery from an integrated municipal solid waste and leachate treatment system 从城市固体废物和沥滤液综合处理系统中回收新型能源
Pub Date : 2023-12-31 DOI: 10.1007/s42768-023-00177-9
Siti Salwa Khamis, Hadi Purwanto, Hamzah Mohd Salleh, Alya Naili Rozhan, Mohamed Abdur Rahman, Mahammadsalman Warimani, Noor Alam

Population growth, waste generation, and massive waste mismanagement have led to environmental catastrophe. Management of municipal solid waste (MSW) requires an efficient and sustainable integrated system. The integrated thermal processing of MSW is one of the best waste management techniques. In this study, energy analysis of MSW is carried out based on the material and energy balance of 2000 kg wet MSW, which contains 50% leachate. Once the leachate is removed, the dry MSW is sent for carbon content enhancement in carbonization to produce MSW-based char. Thereafter, the combustion of MSW-based char provided high heat and syngas to be used in a hydrothermal process for MSW leachate treatment. The result shows that the char fuel of MSW produces a sufficient amount of energy, 13501.29 MJ (84.55%), in the form of synthetic gas by-product, which has a big potential as an energy source. The novelty of the proposed integrated thermal system is to produce 84.55% synthetic gas by-product, which is used for electricity production, cooking, food, and heat energy for industrial purposes. The proposed applications of this paper offer insightful information for policymaking regarding novel MSW techniques, which are economical, energy-efficient, and environmentally friendly. Thus, it increases the effectiveness of MSW utilization.

Graphical abstract

人口增长、废物产生和大规模废物管理不善导致了环境灾难。城市固体废物(MSW)的管理需要一个高效、可持续的综合系统。对城市固体废物进行综合热处理是最好的废物管理技术之一。在这项研究中,根据含有 50% 渗滤液的 2000 千克湿城市固体废物的物质和能量平衡,对城市固体废物进行了能量分析。去除沥滤液后,干燥的城市固体废弃物被送去碳化以提高碳含量,从而产生以城市固体废弃物为基础的炭。此后,城市固体废物焦炭的燃烧可提供高热量和合成气,用于水热法处理城市固体废物渗滤液。结果表明,城市固体废弃物炭燃料以合成气副产品的形式产生了 13501.29 兆焦耳(84.55%)的充足能量,作为一种能源具有很大的潜力。所提议的综合热能系统的新颖之处在于能产生 84.55% 的合成气副产品,可用于发电、烹饪、食品和工业热能。本文提出的应用为有关新型 MSW 技术的政策制定提供了具有洞察力的信息,这些技术既经济又节能环保。因此,它提高了城市固体废物的利用效率。
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引用次数: 0
Sustainable food waste management using modified fuzzy improved analytic hierarchy process: a study of Malaysia 利用改进的模糊层次分析法进行可持续的食物垃圾管理:对马来西亚的研究
Pub Date : 2023-12-27 DOI: 10.1007/s42768-023-00176-w
Chun Yuan Choo, Syariza Abdul-Rahman, Abdul Malek Yaakob, Emy E. A-Jalil

Food waste generation is a pressing issue that requires urgent attention and concerted efforts worldwide. The staggering amount of food wasted each year not only wastes valuable resources but also exacerbates environmental, economic, and social challenges. Food Waste Management (FWM) consists of a complex array of criteria and sub-criteria, and treatments which seems interdependent. There is a need to evaluate the FWM with the help of important criteria and sub-criteria and treatments to address this challenge. In this study, we identified four important criteria, 21 sub-criteria, and four alternatives of FWM for the case of Malaysia using the integrated approach of literature review and expert opinions. Further, we employed the approach of Modified Fuzzy Improved Analytical Hierarchy Process (IAHP) to corroborate the interrelationships among the identified criteria and sub-criteria, and their associated treatments. This study undertakes linear normalization methods to transform data into comparable numerical values and the Geometric Mean method to handle uncertainty in human judgments. Moreover, the Centroid method is employed to convert fuzzy weights into crisp sets for ease of interpretation. The results indicate that environmental is the most essential criterion, followed by social, economic, and technical. In addition, air and water pollution is identified as the most critical sub-criteria. Black Soldier Fly is discovered as the most sustainable FWM treatment, since it performs the best while meeting all the criteria and sub-criteria assessed. Sensitivity analysis demonstrates that the outputs from the proposed method are robust and reliable. The finding suggests a proper and robust approach to help decision-makers select suitable FWM treatments to tackle various criteria and alternatives especially when handling inconsistent and uncertain judgments during evaluation.

食物浪费是一个紧迫的问题,亟需全世界的关注和共同努力。每年浪费的食物数量惊人,不仅浪费了宝贵的资源,还加剧了环境、经济和社会挑战。食物垃圾管理(FWM)包括一系列复杂的标准和次级标准,以及似乎相互依存的处理方法。有必要借助重要的标准、次级标准和处理方法来评估食物垃圾管理,以应对这一挑战。在本研究中,我们采用文献综述和专家意见相结合的方法,针对马来西亚的情况,确定了四个重要标准、21 个次级标准和四个 FWM 替代方案。此外,我们还采用了修正模糊改进分析层次过程(IAHP)的方法,以证实所确定的标准和次级标准之间的相互关系及其相关处理方法。本研究采用线性归一化方法将数据转换为可比较的数值,并采用几何平均法处理人类判断中的不确定性。此外,为了便于解释,还采用了中心点法将模糊权重转换为清晰集。结果表明,环境是最基本的标准,其次是社会、经济和技术标准。此外,空气和水污染被认为是最关键的次级标准。黑兵蝇被认为是最具可持续性的 FWM 处理方法,因为它在满足所有评估标准和次级标准的同时表现最佳。敏感性分析表明,拟议方法的输出结果是稳健可靠的。这一发现提出了一种适当而稳健的方法,可帮助决策者选择合适的 FWM 处理方法,以应对各种标准和替代方案,尤其是在评估过程中处理不一致和不确定的判断时。
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引用次数: 0
Enhancing mechanisms of N-doped biomass carbon on the vanadium-based catalyst for furan degradation at low temperature 掺杂 N 的生物质碳对钒基催化剂在低温下降解呋喃的促进机制
Pub Date : 2023-12-21 DOI: 10.1007/s42768-023-00172-0
Ling Wang, Minghui Tang, Hongxian Li, Jiamin Ding, Juan Qiu, Shengyong Lu

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) have attracted widespread concern due to their high toxicity, and their difficult manipulation in laboratories has made the research process tough. Thus, in our work, furan is selected as the model compound owing to the same structure of a central oxygenate ring. Although catalytic oxidation is regarded as an effective and applicable method for the abatement of PCDD/Fs, the synthesis of low-temperature catalysts is still a challenging problem in practical applications. Considering this situation, we prepared a novel V2O5/TiO2 catalyst modified with N-doped hierarchical porous carbon (NHPC) via a wet impregnation method. The V/T-1%NHPC catalyst could achieve expectant low-temperature performances with 50% furan conversion at 150 °C and a complete conversion at 200 °C, which decreased 23 °C and 40 °C compared to the V/T catalyst respectively. Moreover, the addition of NHPC presented lifting chemical stability during long-time test. The addition of NHPC in V/T catalysts decreased the formation of crystalline V2O5 and increased the percentages of V5+ and Olat, which improved the utilization of vanadium ions and the catalytic activity. Simultaneously, the higher binding energy shift of Olat implied more reaction possibility with other oxidise reactants. Importantly, this work proved the lifting catalytic activity by the interaction between catalysts and NHPC, and proposed the promoting effects of the N element. The results showed that the content of the pyridinic N and graphitic N in NHPC changed after combining with V/T catalyst, which played crucial roles in the excellent catalytic performance. Overall, this work provides comprehensive research of the V/T-1%NHPC catalyst toward furan oxidation at low temperature and explain the effects of N-doped biomass carbon in catalytic activity clearly, which gave a new thought to design low-temperature catalysts in PCDD/Fs degradation. Besides, the internal functional mechanisms of N species are worth further exploration in future studies.

Graphical abstract

多氯二苯并对二恶英和多氯二苯并呋喃(PCDD/Fs)因其剧毒性而受到广泛关注,其在实验室中的操作难度也使研究过程变得艰难。因此,在我们的工作中,由于呋喃具有相同的中心含氧环结构,因此被选为模型化合物。虽然催化氧化法被认为是一种有效且适用的多氯二苯并对二恶英/多氯二苯并呋喃减排方法,但在实际应用中,低温催化剂的合成仍然是一个具有挑战性的问题。考虑到这一情况,我们通过湿法浸渍制备了一种新型 V2O5/TiO2 催化剂,并用掺杂 N 的分层多孔碳(NHPC)对其进行了修饰。V/T-1%NHPC 催化剂可实现预期的低温性能,在 150 °C 时呋喃转化率为 50%,在 200 °C 时完全转化,与 V/T 催化剂相比分别降低了 23 °C 和 40 °C。此外,NHPC 的添加在长期试验中表现出了较高的化学稳定性。在 V/T 催化剂中添加 NHPC 可减少结晶 V2O5 的形成,增加 V5+ 和 Olat 的比例,从而提高钒离子的利用率和催化活性。同时,Olat 较高的结合能转移意味着与其他氧化反应物发生反应的可能性更大。重要的是,这项工作证明了催化剂与 NHPC 之间的相互作用可提高催化活性,并提出了 N 元素的促进作用。结果表明,NHPC 与 V/T 催化剂结合后,NHPC 中吡啶 N 和石墨 N 的含量发生了变化,这对催化剂的优异催化性能起到了关键作用。总之,本研究对 V/T-1%NHPC 催化剂在低温下的呋喃氧化作用进行了全面研究,清楚地解释了掺杂 N 的生物质碳对催化活性的影响,为设计低温降解 PCDD/Fs 的催化剂提供了新思路。此外,N物种的内部功能机理也值得在今后的研究中进一步探讨。
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引用次数: 0
Three-stage pyrolysis–steam reforming–water gas shift processing of household, commercial and industrial waste plastics for hydrogen production 家用、商用和工业废塑料三段式热解-蒸汽重整-水煤气变换处理制氢
Pub Date : 2023-11-28 DOI: 10.1007/s42768-023-00173-z
Rayed Alshareef, Robert Sait-Stewart, Mohamad A. Nahil, Paul T. Williams

Five common single plastics and nine different household, commercial and industrial waste plastics were processed using a three-stage (i) pyrolysis, (ii) catalytic steam reforming and (iii) water gas shift reaction system to produce hydrogen. Pyrolysis of plastics produces a range of different hydrocarbon species which are subsequently catalytically steam reformed to produce H2 and CO and then undergo water gas shift reaction to produce further H2. The process mimics the commercial process for hydrogen production from natural gas. Processing of the single polyalkene plastics (high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP)) produced similar H2 yields between 115 mmol and 120 mmol per gram plastic. Even though PS produced an aromatic product slate from the pyrolysis stage, further stages of reforming and water gas shift reaction produced a gas yield and composition similar to that of the polyalkene plastics (115 mmol H2 per gram plastic). PET gave significantly lower H2 yield (41 mmol per gram plastic) due to the formation of mainly CO, CO2 and organic acids from the pyrolysis stage which were not conducive to further reforming and water gas shift reaction. A mixture of the single plastics typical of that found in municipal solid waste produced a H2 yield of 102 mmol per gram plastic. Knowing the gas yields and composition from the single plastics enabled an estimation of the yields from a simulated waste plastic mixture and a ‘real-world’ waste plastic mixture to be determined. The different household, commercial and industrial waste plastic mixtures produced H2 yields between 70 mmol and 107 mmol per gram plastic. The H2 yield and gas composition from the single waste plastics gave an indication of the type of plastics in the mixed waste plastic samples.

Graphical abstract

五种常见的单一塑料和九种不同的家用,商业和工业废塑料采用三段式(i)热解,(ii)催化蒸汽重整和(iii)水煤气变换反应系统进行处理,以产生氢气。塑料的热解产生一系列不同的碳氢化合物,这些碳氢化合物随后被催化蒸汽重整生成H2和CO,然后进行水气转换反应进一步生成H2。这个过程模仿了从天然气中生产氢气的商业过程。单聚烯烃塑料(高密度聚乙烯(HDPE),低密度聚乙烯(LDPE)和聚丙烯(PP))的加工产生的氢气产量相似,在每克塑料115至120毫摩尔之间。尽管PS在热解阶段产生芳香产物板岩,但在重整和水气转换反应的后续阶段,其产气率和组成与聚烯烃塑料相似(每克塑料115 mmol H2)。PET的H2产率较低(41 mmol / g塑料),这主要是由于热解阶段主要生成CO、CO2和有机酸,不利于进一步重整和水煤气转移反应。在城市固体废物中发现的典型的单一塑料混合物产生的H2产率为每克塑料102毫摩尔。了解了单一塑料的气体产量和成分,就可以估计模拟废塑料混合物和“现实世界”废塑料混合物的产量。不同的家用、商业和工业废塑料混合物产生的H2产率在每克塑料70至107 mmol之间。单个废塑料的H2产率和气体组成表明了混合废塑料样品中塑料的类型。图形抽象
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Waste Disposal & Sustainable Energy
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