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Thermal runaway behaviors in 18,650 LiFePO4 batteries under high C-rate charge/discharge operations 18650磷酸铁锂电池在高倍率充放电条件下的热失控行为
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.applthermaleng.2026.129760
Ina Jeong , Seongpil An , Changwoo Kang
The thermal behaviors of the LiFePO4 battery are examined to understand how C-rate and convective heat transfer rate (h) influence thermal stability. A heat generation model, including side reaction heat, is utilized for numerical simulations. Temperature behaviors and the onset of thermal runaway are studied under different C-rates and convective heat transfer coefficients. The thermal stability is categorized into three levels to assess battery safety. When thermal runaway occurs, the onset time and peak temperature are analyzed to evaluate stability. The contributions from each heat source are also measured. Side reactions start above 8C during charging and above 10C during discharging, while thermal runaway happens above 10C and 12C for charging and discharging, respectively. Higher C-rates and lower convective heat transfer coefficients reduce thermal safety. Furthermore, electro-thermal heat is the main heat source before thermal runaway, whereas the heat from reaction between the cathode and electrolyte dominates afterward until the maximum temperature is reached.
研究了LiFePO4电池的热行为,以了解c率和对流换热率(h)对热稳定性的影响。采用含副反应热的产热模型进行数值模拟。研究了不同c -速率和对流换热系数下的温度行为和热失控的发生。热稳定性分为三个级别,以评估电池的安全性。当发生热失控时,分析了热失控的发生时间和峰值温度来评价系统的稳定性。还测量了每个热源的贡献。充电时在8C以上开始副反应,放电时在10C以上开始副反应,充电时在10C以上发生热失控,放电时在12C以上发生热失控。较高的c率和较低的对流换热系数降低了热安全性。此外,在热失控之前,电热是主要热源,而在达到最高温度之前,阴极和电解质之间的反应产生的热量占主导地位。
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引用次数: 0
Numerical study and multi-objective optimization of helium-cooled printed circuit heat exchangers with ribs 带肋板的氦冷印刷电路换热器的数值研究及多目标优化
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.applthermaleng.2026.129781
Shiyu Lai , Tieyu Gao , Xiangrui Meng , Zhihui Zhang , Jianying Gong , Lulu Zhu
The fourth-generation nuclear systems are vital to global energy transition and sustainable development. This study introduces rib structures into a helium-cooling printed circuit heat exchanger to investigate the effects of rib arrangements on thermal-hydraulic characteristics by numerical simulation combined with a multi-objective optimization algorithm. Based on previous operating conditions, the Reynolds number ranges from 450 to 5300, the inlet temperatures of the hot and cold channels are 823.15 K and 473.15 K, and the system pressure is 3 MPa. Results show that, the transverse ribs exhibit the optimal thermal performance, followed by the hybrid and longitudinal configurations. Distinct mechanisms are observed: smaller vortices dominate around the longitudinal ribs, whereas in the transverse channel, persistent large vortices (T₃) form a heart-shaped high turbulence kinetic energy region and exhibit an enhanced field synergy effect. To further identify the optimal rib parameters, the correlations between rib dimensions (l, w and h) and Nusselt number and friction factor are established. Four optimized configurations (A-D) are obtained using a multi-objective optimization algorithm. The rib geometry exhibits an evolutionary trend, and the concept of a flow rate dominance region is proposed to describe the optimal balance among different thermal objectives. Moreover, the performance of the optimized configurations is examined to extend the evaluation to a broader flow range (10–80 kg/h), showing stable and significant enhancement. Configuration C demonstrates the best overall performance with the PEC increased by 97.35%, while configuration D achieves the highest heat exchanger effectiveness improvement of 18.07%, together with a system efficiency gain of 41.21% and a compactness enhancement of 29.18%. These findings elucidate that the thermal-hydraulic characteristics of helium in PCHE ribbed channels, providing a methodological guidance for high efficiency heat exchanger designs.
第四代核系统对全球能源转型和可持续发展至关重要。将肋部结构引入氦冷却印刷电路换热器中,通过数值模拟结合多目标优化算法研究肋部布置对换热器热工特性的影响。根据之前的工况,雷诺数范围为450 ~ 5300,冷热通道入口温度分别为823.15 K和473.15 K,系统压力为3mpa。结果表明,横向肋的热性能最佳,其次是混合肋和纵向肋。观察到不同的机制:较小的涡在纵向肋周围占主导地位,而在横向通道中,持续的大涡(T₃)形成了一个心形的高湍流动能区域,并表现出增强的场协同效应。为了进一步确定最优肋形参数,建立肋形尺寸(l、w、h)与努塞尔数和摩擦因数之间的关系。采用多目标优化算法得到了四种优化构型(a - d)。肋的几何形状呈演化趋势,提出了流量优势区概念来描述不同热目标之间的最优平衡。此外,将优化配置的性能测试扩展到更宽的流量范围(10-80 kg/h),显示出稳定且显著的增强。配置C整体性能最佳,PEC提高97.35%,配置D换热器效率提高最高,达到18.07%,系统效率提高41.21%,紧凑度提高29.18%。这些发现阐明了氦在PCHE肋状通道中的热水力特性,为高效换热器的设计提供了方法指导。
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引用次数: 0
Dynamic mathematical characterization of electro-thermo-mechanical coupling behaviors in lithium-ion batteries 锂离子电池电-热-机械耦合行为的动态数学表征
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.applthermaleng.2026.129791
Muyao Wu , Changpeng Tan , Li Wang
The strong cross-coupling among electrical, thermal, and mechanical behaviors in lithium-ion batteries pose significant challenges to accurate dynamic mathematical characterization. The core innovation lies in developing an incremental integration of existing electro, thermal, mechanical models, to dynamically characterize of electro-thermal-mechanical coupling behaviors of lithium-ion batteries. The electrical behaviors are captured by a first-order RC equivalent circuit model, the thermal behaviors are captured by a lumped-parameter thermal model, and the mechanical behaviors are captured by an equivalent strain model based on the solid-state diffusion theory and the thermal expansion theory. The coupling model parameters are identified online via the Forgetting Factor Recursive Least Squares. Experimental results under FUDS and WLTC, across various ambient temperatures and battery aging levels indicate that, the Mean Absolute Error (MAE) and Root Mean Square Error (RMSE) of the voltage estimation results remain below 20 mV and 35 mV, the MAE and RMSE of the temperature estimation results remain below 0.1 °C and 0.15 °C, the MAE and RMSE of the strain estimation results remain below 2.5με and 3.0με. Furthermore, the more innovation conclusion is that, the thermal resistance exhibits an overall increasing trend as the battery aging, but no clear dependence of it on the ambient temperature is identified. The dynamic temperature strain coefficient shows a notable dependence on the battery aging level, the average standard deviations of the it for fresh and aged batteries are 0.12με and 0.25με, respectively, representing a more than twofold difference. In contrast, the dynamic SOC strain coefficient does not demonstrate such a trend.
锂离子电池的电、热和机械行为之间的强交叉耦合对精确的动态数学表征提出了重大挑战。核心创新在于开发现有电、热、力学模型的增量集成,以动态表征锂离子电池的电热-机械耦合行为。电学行为采用一阶RC等效电路模型,热行为采用集总参数热模型,力学行为采用基于固态扩散理论和热膨胀理论的等效应变模型。通过遗忘因子递推最小二乘法在线辨识耦合模型参数。在FUDS和WLTC下,不同环境温度和电池老化水平下的实验结果表明,电压估计结果的平均绝对误差(MAE)和均方根误差(RMSE)保持在20 mV和35 mV以下,温度估计结果的平均绝对误差(MAE)和均方根误差(RMSE)保持在0.1°C和0.15°C以下,应变估计结果的平均绝对误差(MAE)和RMSE保持在2.5με和3.0με以下。更具有创新性的结论是,随着电池老化,热阻整体呈增加趋势,但与环境温度没有明显的依赖关系。动态温度应变系数对电池的老化程度有显著的依赖性,新鲜电池和老化电池的平均标准差分别为0.12με和0.25με,相差2倍以上。相比之下,动态有机碳应变系数没有表现出这种趋势。
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引用次数: 0
Melting performance of gradient-porosity metal foam composite phase change materials: A pore-scale numerical study 梯度孔隙率金属泡沫复合相变材料的熔化性能:孔隙尺度数值研究
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.applthermaleng.2026.129783
Jie Li , Xiaobing Sun , Yiming Li , Minggao Liu , Xiaoqin Sun , Quan Zhang
Embedding metal foam into phase change materials is an effective approach to enhance the thermal performance of latent heat thermal energy storage systems. However, heat transfer mismatches caused by coupling between conduction and natural convection remain a challenge. Unlike most existing studies focusing on uniform or one-dimensional porosity-gradient structures, this work investigates the effect of the inclination angle of the porosity-gradient interface on melting behavior and heat transfer performance. A three-dimensional pore-scale numerical simulation is employed to analyze the melting process of gradient-porosity metal foam composite PCMs. The effects of the inclination angle (θ), porosity gradient magnitude (Δε), and thermal energy storage temperature difference (ΔT) are evaluated. The results show that melting performance first improves and then deteriorates with increasing inclination angle, with optimal performance at θ = 30°. Compared with a uniform-porosity structure, this configuration reduces the total melting time by 12.16% and increases the thermal energy storage rate by 11.66% by suppressing melting dead zones and improving the balance between heat conduction and natural convection. The effect of porosity gradient depends strongly on interface orientation: a moderate gradient (Δε = 0.12) is optimal for θ = 0° and 30°, whereas smaller gradients are preferable at θ = 90°. Increasing ΔT consistently accelerates melting, for the optimal structure (θ = 30°, Δε = 0.12), increasing ΔT from 25 K to 40 K reduces melting time by 29.06% and enhances the energy storage rate by 55.14%. Overall, this study provides new insight into pore-scale heat transfer regulation in gradient-porosity LHTES structures and offers practical guidance for optimal design.
在相变材料中嵌入金属泡沫是提高潜热蓄热系统热性能的有效途径。然而,由传导和自然对流耦合引起的传热失配仍然是一个挑战。与大多数现有的研究集中在均匀或一维孔隙度梯度结构不同,这项工作研究了孔隙度梯度界面的倾角对熔化行为和传热性能的影响。采用三维孔隙尺度数值模拟方法对梯度孔隙度金属泡沫复合材料的熔化过程进行了分析。评价了倾角(θ)、孔隙度梯度大小(Δε)和储热温差(ΔT)对储热效果的影响。结果表明:随着倾角的增大,熔化性能先提高后降低,在θ = 30°时熔化性能最佳;与均匀孔隙结构相比,该结构抑制了熔化死区,改善了热传导和自然对流之间的平衡,使总熔化时间缩短了12.16%,储热率提高了11.66%。孔隙度梯度的影响很大程度上取决于界面取向:当θ = 0°和30°时,孔隙度梯度适中(Δε = 0.12)是最优的,而当θ = 90°时,孔隙度梯度越小越好。对于最优结构(θ = 30°,Δε = 0.12),将ΔT从25 K增加到40 K可使熔化时间缩短29.06%,使储能率提高55.14%。总体而言,本研究为研究梯度孔隙度LHTES结构的孔尺度传热规律提供了新的思路,并为优化设计提供了实践指导。
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引用次数: 0
Operational flexibility enhancement for the compressed air energy storage system integrated with molten salt thermal energy storage 压缩空气储能系统与熔盐热储能集成的操作灵活性增强
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-12 DOI: 10.1016/j.applthermaleng.2026.129777
Chaocheng Zhao , Guangtao Ni , Wei Han , Ming Liu , Zhenzhen Wang , Junjie Yan
Compressed air energy storage (CAES) is a promising technology for large-scale energy storage, where operational flexibility is critical for accommodating high penetration of intermittent renewable energy in modern power grids. This study systematically investigates a CAES system integrated with molten salt thermal storage, with particular emphasis on flexibility enhancement and efficiency improvement under partial-load and off-design conditions. An intrinsically flexible CAES configuration featuring four operation modes—corresponding to high, upper-middle, lower-middle, and low power output—is proposed, and key design parameters are optimized to improve energy efficiency during partial-load operation. When the pressure of the air storage cavern drops below the design value, rated output power is maintained through air injection. This enables full-load operation and high round-trip efficiency (RTE) even under low cavern pressure conditions, significantly enhancing operational flexibility and extending the effective operating pressure range of the cavern. Off-design thermodynamic models are developed, and air consumption together with exergy loss distribution are employed to evaluate system performance. The results demonstrate that the air injection location plays a critical role in the upper-middle power operation mode. When the injection point is located at the outlet of expander E1, the system can sustain rated output power at 50% of the design cavern pressure, achieving a minimum average air consumption of 48.34 kg/s and a maximum RTE of 59.23%. At this condition, the exergy loss of the combustion chamber is also minimized to 32.01 MW, and the lowest air consumption coincides with the highest RTE. By contrast, the air injection location has a less pronounced influence on the lower-middle power operation mode. The system remains capable of full-load operation at 60% of the design cavern pressure. The minimum average air consumption of 30.45 kg/s occurs when the injection point is located at 8 MPa, whereas the maximum RTE of 78.74% is achieved at the outlet of expander E4. In this case, the minimum air consumption does not correspond to the maximum RTE.
压缩空气储能(CAES)是一种很有前途的大规模储能技术,在这种技术中,操作灵活性对于适应现代电网中间歇性可再生能源的高渗透至关重要。本研究系统地研究了与熔盐储热集成的CAES系统,特别强调了在部分负荷和非设计条件下灵活性的增强和效率的提高。提出了具有高、上、中、下、低输出四种运行模式的CAES结构,并对关键设计参数进行了优化,提高了部分负荷运行时的能效。当储气腔压力降至设计值以下时,通过注气维持额定输出功率。即使在较低的洞穴压力条件下,也能实现满负荷运行和高往返效率(RTE),显著提高了操作灵活性,扩大了洞穴的有效工作压力范围。建立了非设计热力学模型,并采用风量和火用损失分布来评价系统性能。结果表明,喷气位置对中上功率工况起着至关重要的作用。当喷射点位于膨胀机E1出口处时,系统在设计洞室压力的50%下可维持额定输出功率,平均耗气量最小为48.34 kg/s, RTE最大为59.23%。在此条件下,燃烧室的火用损失也最小,为32.01 MW,最低的耗气量与最高的RTE重合。相比之下,空气喷射位置对中低功率运行模式的影响较小。该系统仍能在60%的设计腔室压力下满负荷运行。喷射点位于8 MPa时,平均耗气量最小,为30.45 kg/s,而膨胀机E4出口处的RTE最大,为78.74%。在这种情况下,最小空气消耗量不对应于最大RTE。
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引用次数: 0
Experimental investigation of azimuthal instability characteristics in a hydrogen annular combustor 氢环形燃烧室方位角不稳定性的实验研究
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-11 DOI: 10.1016/j.applthermaleng.2026.129769
Jianchen Wang , Lichuan Zhang , Meng Han , Haoqi Ren , Chi Zhang , Quanhong Xu
This study experimentally investigates self-excited azimuthal instabilities in a full-scale annular reverse-flow combustor for micro gas turbines, featuring arrayed micro-tubes designed for hydrogen micro-diffusion flames. The results characterize a distinct instability region (Φ ≈ 0.26–0.41) where pressure pulsation amplitudes initially rise and subsequently fall, reaching a peak of approximately 1.9 kPa. The dominant instability frequency (≈ 0.9–1.3 kHz) exhibits a strong linear correlation with the square root of the adiabatic flame temperature, which, supported by Helmholtz solver results, confirms that the resonance mechanism comprises both 1 A (azimuthal) and 1 L (longitudinal) components. Although the instability physically manifests as a mixed 1A1L mode, this study focuses on the azimuthal dynamics and modal transitions inherent to the annular architecture. A prominent feature is the path-dependent hysteresis observed in modal symmetry breaking. Specifically, the instability onset during the ascending path is marked by a transition from ST to CW, while the cessation during the descending path involves a transition from CCW to ST. This path dependence suggests that intrinsic nonlinear dynamics play a critical role in mode selection, potentially overriding fixed geometrical asymmetries in the developed instability regime. Additionally, transient analysis identifies distinct dynamic states within the high-amplitude region: a quasi-stable state during ascension and a large-amplitude periodic switching state during descension. The latter provides experimental evidence of slow-fast dynamic coupling, where a low-frequency physical process (≈ 11 Hz) periodically modulates the high-frequency acoustic oscillations (≈ 1.17 kHz). These findings, likely influenced by the specific hydrogen flame characteristics and intrinsic convective timescales, provide an experimental data and reference for the investigation of azimuthal combustion instabilities and modal transitions in hydrogen annular combustors.
实验研究了微型燃气轮机全尺寸环形回流燃烧室的自激方位不稳定性,该燃烧室采用为氢微扩散火焰设计的阵列微管。结果表明,在一个明显的不稳定区域(Φ≈0.26-0.41),压力脉动振幅先上升后下降,达到约1.9 kPa的峰值。主导不稳定频率(≈0.9 ~ 1.3 kHz)与绝热火焰温度的平方根呈较强的线性相关,亥姆霍兹解算结果证实了共振机制由1个a(方位角)和1个L(纵向)分量组成。虽然不稳定性在物理上表现为混合1A1L模式,但本研究侧重于环形结构固有的方位动力学和模态转换。模态对称性破缺的一个显著特征是路径相关的迟滞。具体来说,上升路径的不稳定开始标志着从ST到CW的转变,而下降路径的停止涉及从CCW到ST的转变。这种路径依赖表明,内在的非线性动力学在模式选择中起着关键作用,潜在地超越了发达不稳定状态中固定的几何不对称。此外,瞬态分析确定了高振幅区域内不同的动态状态:上升时的准稳定状态和下降时的大振幅周期性切换状态。后者提供了慢速动态耦合的实验证据,其中低频物理过程(≈11 Hz)周期性地调制高频声学振荡(≈1.17 kHz)。这些结果可能受到氢火焰特性和固有对流时间尺度的影响,为研究氢环形燃烧器的方位角燃烧不稳定性和模态过渡提供了实验数据和参考。
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引用次数: 0
Conformable sensing and adaptive vortex generating for active flow control of AUV propulsion systems 水下航行器推进系统主动流动控制的一致性感知与自适应涡生成
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-11 DOI: 10.1016/j.applthermaleng.2026.129752
Mingxuan Hao , Fan Zhang , Nanpei Li , Zelinlan Wang , Yixiao Liu , Zhihong Rao , Jinghui Ling , Kai Chen , Ruiqi Wang , Dongliang Guo , Junfeng Li , YongAn Huang
The optimal hydrodynamic performance of autonomous underwater vehicles in complex flow fields is critically dependent on the dynamic power density of their propulsion motors, demanding active regulation of heat dissipation guided by advanced thermal monitoring and intelligent cooling technologies. To meet this demand, an intelligent flexible sensing system deployed on motor surfaces for active flow control is introduced, which integrates precise flow-field sensing with adaptive hydrodynamic regulation. By acquiring regional coolant flow information via flexible dual-mode sensing skins, the system generates real-time actuation commands to adjust the angle of attack of vortex generator arrays, thereby enhancing local heat transfer through the induction of longitudinal vortices. Compared to the conventional forced undisturbed water-cooling baseline (flat wall, no vortex generator arrays), the proposed approach achieves up to a 25.4% improvement in cooling efficiency at a flow velocity of 6 m/s while maintaining precise and intelligent thermal control. This closed-loop sensing-actuation paradigm offers an intelligent, shape-adaptive solution for AUV thermal management and demonstrates strong potential for broader application in autonomous flow control within complex fluidic environments.
自主水下航行器在复杂流场中的最佳流体动力性能严重依赖于其推进电机的动态功率密度,这就要求在先进的热监测和智能冷却技术的指导下主动调节散热。为了满足这一需求,介绍了一种部署在电机表面的用于主动流量控制的智能柔性传感系统,该系统将精确的流场传感与自适应流体动力调节相结合。该系统通过柔性双模传感皮肤获取区域冷却剂流动信息,生成实时驱动命令,调整涡发生器阵列的攻角,从而通过诱导纵向涡增强局部换热。与传统的强制不受干扰水冷基线(平壁,无涡发生器阵列)相比,该方法在保持精确和智能的热控制的同时,在6 m/s流速下的冷却效率提高了25.4%。这种闭环传感驱动模式为AUV热管理提供了一种智能的、形状自适应的解决方案,并在复杂流体环境中的自主流动控制方面展示了强大的应用潜力。
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引用次数: 0
Convection-radiation synergistically enhanced mini-channel heat exchanger via high infrared emissivity coating for high-altitude low-pressure environments 基于高红外发射率涂层的对流辐射协同增强型小型通道换热器,适用于高空低气压环境
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-11 DOI: 10.1016/j.applthermaleng.2026.129716
Shen Gao , Yue Ren , Yanxing Zhao , Jiayu Zhang , Yunxiao Wang , Kun Wang , Yong Li , Jiangtao Li , Maoqiong Gong
Effective thermal management is vital for the stable operation and long-endurance flight of high-altitude platforms, but the low-pressure environment severely limits heat dissipation. To address this challenge, a novel mini-channel tube bundle heat exchanger (MCTBHE) coated with a high infrared emissivity coating was proposed. The coating, primarily composed of graphite sheets and SiO₂, exhibited a high mid-infrared emissivity (ε = 0.93). Heat dissipation performance of the proposed exchanger was experimentally evaluated in a low-pressure wind tunnel, with the pressure reduced to 5.5 kPa. The results indicated that the high infrared coating synergistically enhanced the convective and radiative heat dissipation performance of the MCTBHE. Compared with the uncoated counterpart, the coated exchanger achieved a 7.8% higher heat transfer coefficient and a 4% improvement in overall thermohydraulic performance, despite a 10.5% increase in pressure drop. Notably, under low-pressure conditions, its heat transfer coefficient was 2.6 times that of conventional designs reported in the literature while maintaining comparable resistance. This study contributes to the experimental understanding of MCTBHEs under low-pressure conditions and demonstrates the potential of coating-based approaches for improving thermal management in high-altitude platforms.
有效的热管理对高空平台的稳定运行和长时间飞行至关重要,但低压环境严重限制了其散热。为了解决这一问题,提出了一种新型的小通道管束换热器(MCTBHE),该换热器表面涂有高红外发射率涂层。该涂层主要由石墨片和sio2组成,具有较高的中红外发射率(ε = 0.93)。在低压风洞中对该换热器的散热性能进行了实验评估,实验压力降至5.5 kPa。结果表明,高红外涂层协同增强了MCTBHE的对流散热和辐射散热性能。与未包覆换热器相比,包覆换热器的传热系数提高了7.8%,整体热工性能提高了4%,但压降提高了10.5%。值得注意的是,在低压条件下,其传热系数是文献中报道的传统设计的2.6倍,同时保持相当的阻力。该研究有助于对低压条件下MCTBHEs的实验理解,并展示了基于涂层的方法改善高空平台热管理的潜力。
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引用次数: 0
Numerical investigation of the effects of flame holding geometry on the flame dynamics in a hydrogen industrial burner 持焰几何形状对氢工业燃烧器火焰动力学影响的数值研究
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-10 DOI: 10.1016/j.applthermaleng.2026.129750
Long Zhang, Tianze Yu, Jian Zhang, Hua Zhou
The effects of flame holding chamber on the flame dynamics are numerically investigated at 100% and 50% loads in a hydrogen industrial burner under the framework of large eddy simulation and non-adiabatic flamelet generated manifold model. For combustion characteristics, the flame holding chamber is beneficial for maintaining consistency in the flow field under different loads and can form a high-temperature corner recirculation zone to promote mixing and ignition. At 50% load, the temperature in the corner recirculation zone surrounded by the flame holding chamber and swirling shear layer is about 100 K higher than other areas in the calculation domain. Chemical eigenvalue analysis shows that unstable combustion is mainly concentrated in the shear layer, with the dominant species being H, and the dominant elementary reactions being R10 (HO2+HH2+O2) and R11 (HO2+HOH+OH). For combustion instability, removing the flame holding chamber can effectively alleviate pressure fluctuations and weaken combustion instability. At 100% load, the pressure fluctuation range decreases by 34%, and the FFT amplitude decreases by 80%. Singular spectrum analysis further indicates that removing the flame stabilization chamber significantly suppresses pressure fluctuations in the dominant SSA modes. The above results provide guidance for the on-site application of hydrogen industrial burners. For the scenario of long-term rated load operation (chemical furnace, metallurgical heating furnace, etc.), the application of flame holding chamber can be omitted, thereby mitigating the combustion instability. For operation scenarios requiring frequent load adjustment (civil heating furnace, drying furnace, etc.), the application of flame holding chamber should be considered to enhance the thermal intensity and flame stability in the combustion chamber during load switching.
在大涡模拟和非绝热小火焰生成流形模型的框架下,数值研究了持焰室对工业氢燃烧器100%和50%负荷下火焰动力学的影响。燃烧特性方面,保燃室有利于保持不同负荷下流场的一致性,并可形成高温转角再循环区,促进混合和点火。在负荷为50%时,保燃室和旋切层包围的转角再循环区温度比计算域内其他区域高约100 K。化学特征值分析表明,不稳定燃烧主要集中在剪切层,优势物质为H,优势元素反应为R10 (HO2+H⇔H2+O2)和R11 (HO2+H⇔OH+OH)。对于燃烧不稳定,取消保焰室可以有效缓解压力波动,减弱燃烧不稳定。负载为100%时,压力波动幅度减小34%,FFT幅值减小80%。奇异谱分析进一步表明,去除稳焰室显著抑制了主要SSA模态的压力波动。上述结果为氢工业燃烧器的现场应用提供了指导。对于长期额定负荷运行的场景(化工炉、冶金加热炉等),可以省去火焰保持室的应用,从而减轻了燃烧的不稳定性。对于需要频繁调整负荷的运行场景(民用加热炉、烘干炉等),应考虑采用保焰室,以增强负荷切换时燃烧室的热强度和火焰稳定性。
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引用次数: 0
Preparation of VO2 nanorod-modified phase change microcapsules for enhancing building's fire safety and energy management VO2纳米棒改性相变微胶囊的制备及其对建筑消防安全和能源管理的促进作用
IF 6.9 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2026-01-10 DOI: 10.1016/j.applthermaleng.2026.129774
Ying Wang , Yutong Yang , Yuxin Zhang , Jiayi Han , Jiaji Cheng , Yapeng Wang , Shaoxiang Li
This study proposes the incorporation of vanadium dioxide (VO2) nanorods with high thermal conductivity, flame retardancy, and thermally induced phase change properties into the shell layer of microcapsules, targeting the issues of poor thermal conductivity, flammability, and limited energy storage in practical applications of organic phase change microcapsules. Based on this, a modified phase change material microcapsule (V-MPCM) containing capric acid@PMMA doped with VO2 nanorods was prepared through in-situ polymerization, establishing a channel-shell-core structure. Data indicate excellent thermal stability of V-MPCM. To develop functional coatings, V-MPCM was incorporated into an epoxy resin (EP) matrix, yielding V-MPCM/EP composite coatings. Compared to existing studies, this work achieves a core breakthrough by integrating three functions—heat storage, flame retardancy, and intelligent photothermal regulation—overcoming the single-function limitation of traditional phase change materials. Results demonstrate the coating's excellent temperature regulation capability, with stable performance maintained after 100 solidification-melting cycles. Compared to pure EP, the V-MPCM/EP coating reduces peak heat release rate and total heat release rate by 12% and 24.9%, respectively. Simultaneously, it exhibits infrared reflection functionality above 68 °C, with light reflectance increased by 61%, effectively blocking solar radiation transmission into building interiors. This research provides a viable approach for developing highly efficient, energy-saving, and reliable functional coatings for buildings.
针对有机相变微胶囊在实际应用中存在导热性差、易燃性差、储能能力有限等问题,本研究提出将具有高导热性、阻燃性和热致相变性能的二氧化钒(VO2)纳米棒掺入微胶囊的壳层中。在此基础上,通过原位聚合法制备了掺杂VO2纳米棒的癸烷acid@PMMA改性相变材料微胶囊(V-MPCM),建立了通道-壳-核结构。数据表明,V-MPCM具有良好的热稳定性。为了开发功能性涂层,将V-MPCM掺入环氧树脂(EP)基体中,得到V-MPCM/EP复合涂层。与已有研究相比,本工作突破了传统相变材料单一功能的局限,实现了储热、阻燃、智能光热调节三大功能的集成,实现了核心突破。结果表明,该涂层具有良好的温度调节能力,在100次凝固-熔化循环后仍能保持稳定的性能。与纯EP相比,V-MPCM/EP涂层的峰值放热率和总放热率分别降低了12%和24.9%。同时,在68°C以上具有红外反射功能,光反射率提高61%,有效阻挡太阳辐射透射到建筑内部。本研究为开发高效、节能、可靠的建筑功能涂料提供了可行的途径。
{"title":"Preparation of VO2 nanorod-modified phase change microcapsules for enhancing building's fire safety and energy management","authors":"Ying Wang ,&nbsp;Yutong Yang ,&nbsp;Yuxin Zhang ,&nbsp;Jiayi Han ,&nbsp;Jiaji Cheng ,&nbsp;Yapeng Wang ,&nbsp;Shaoxiang Li","doi":"10.1016/j.applthermaleng.2026.129774","DOIUrl":"10.1016/j.applthermaleng.2026.129774","url":null,"abstract":"<div><div>This study proposes the incorporation of vanadium dioxide (VO<sub>2</sub>) nanorods with high thermal conductivity, flame retardancy, and thermally induced phase change properties into the shell layer of microcapsules, targeting the issues of poor thermal conductivity, flammability, and limited energy storage in practical applications of organic phase change microcapsules. Based on this, a modified phase change material microcapsule (V-MPCM) containing capric acid@PMMA doped with VO<sub>2</sub> nanorods was prepared through in-situ polymerization, establishing a channel-shell-core structure. Data indicate excellent thermal stability of V-MPCM. To develop functional coatings, V-MPCM was incorporated into an epoxy resin (EP) matrix, yielding V-MPCM/EP composite coatings. Compared to existing studies, this work achieves a core breakthrough by integrating three functions—heat storage, flame retardancy, and intelligent photothermal regulation—overcoming the single-function limitation of traditional phase change materials. Results demonstrate the coating's excellent temperature regulation capability, with stable performance maintained after 100 solidification-melting cycles. Compared to pure EP, the V-MPCM/EP coating reduces peak heat release rate and total heat release rate by 12% and 24.9%, respectively. Simultaneously, it exhibits infrared reflection functionality above 68 °C, with light reflectance increased by 61%, effectively blocking solar radiation transmission into building interiors. This research provides a viable approach for developing highly efficient, energy-saving, and reliable functional coatings for buildings.</div></div>","PeriodicalId":8201,"journal":{"name":"Applied Thermal Engineering","volume":"289 ","pages":"Article 129774"},"PeriodicalIF":6.9,"publicationDate":"2026-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145974996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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Applied Thermal Engineering
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