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Integrated attrition model of mechanical-thermal-reaction for CaCO3/CaO thermochemical energy storage 用于 CaCO3/CaO 热化学储能的机械-热反应综合磨损模型
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-27 DOI: 10.1016/j.applthermaleng.2024.124247

Fluidized bed reactors have become a pivotal trend in the future development of thermochemical energy storage. However, high temperatures and chemical reactions exacerbate particle attrition in fluidized bed reactors, affecting particle cyclic stability and reducing energy storage efficiency. This study conducted experiments under three different temperature conditions to compare and investigate the attrition mechanisms of CaCO3/CaO particles. The contributions of mechanical forces from collisions, thermal stress due to uneven cooling and heating, and chemical stress from cyclic reactions to particle attrition are analyzed. The edge effects caused by sphericity dominate the attrition behavior during the initial period of fluidization. High-temperature thermal stress significantly weakens the attrition resistance of the particles, while repeated chemical cycling degrades the internal skeletal structure of the particles, lowering the fracture threshold. Based on fitting experimental data, a comprehensive numerical model for predicting particle attrition has been developed and improved by incorporating factors such as edge effects from sphericity, thermally induced stress, and chemically driven fragmentation. Through validation, the model effectively predicts particle attrition behavior in thermochemical storage process, providing a simulation tool for in-depth research on particle stability in thermochemical energy storage field.

流化床反应器已成为热化学储能未来发展的重要趋势。然而,高温和化学反应会加剧流化床反应器中颗粒的损耗,影响颗粒的循环稳定性,降低储能效率。本研究在三种不同温度条件下进行了实验,以比较和研究 CaCO3/CaO 颗粒的损耗机制。分析了碰撞产生的机械力、冷却和加热不均产生的热应力以及循环反应产生的化学应力对颗粒损耗的影响。在流化的初始阶段,由球形性引起的边缘效应在损耗行为中占主导地位。高温热应力会大大削弱颗粒的抗损耗能力,而反复的化学循环会降低颗粒的内部骨架结构,从而降低断裂阈值。在拟合实验数据的基础上,我们建立并改进了一个用于预测颗粒损耗的综合数值模型,其中纳入了球度边缘效应、热应力和化学驱动破碎等因素。通过验证,该模型能有效预测热化学储能过程中的颗粒损耗行为,为深入研究热化学储能领域的颗粒稳定性提供了模拟工具。
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引用次数: 0
PCM-based passive cooling solution for Li-ion battery pack, a theoretical and numerical study 基于 PCM 的锂离子电池组被动冷却解决方案的理论和数值研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-27 DOI: 10.1016/j.applthermaleng.2024.124262

We propose in this study a novel cooling solution for Li-ion battery packs based on Phase Change Materials (PCM) and metallic fins placed around each cell. Discharging and charging processes both melt the PCM. To complete the thermal management of the batteries, an intermediary sequence is added for the PCM solidification. During a short timeframe between batteries charging and discharging, a liquid coolant flows through one small channel located within each fin. A numerical model and a theoretical analysis allow to predict the thermal behavior of the battery cells and the PCM liquid fraction changes in time. It is shown that the combination of a passive cooling solution brought by the PCM with the fast period of liquid cooling for the PCM solidification is an effective solution to control the temperature evolution within the battery cells during discharge and charge. The only external energy consumption foreseen comes from the laminar flow of the coolant for solidification during a very short period of time. The findings indicate that the proposed PCM-liquid cooling integration reduces the total energy consumption by 54.9 % (from 0.4406 kJ to 0.1963 kJ) for the 2C discharging-2C charging cycle compared to traditional liquid-cooling strategy.

在这项研究中,我们提出了一种新型的锂离子电池组冷却解决方案,它基于相变材料(PCM)和放置在每个电池周围的金属鳍片。放电和充电过程都会融化 PCM。为了完成电池的热管理,还增加了 PCM 固化的中间过程。在电池充电和放电之间的短暂时间内,液态冷却剂流经位于每个鳍片内的一个小通道。通过数值模型和理论分析,可以预测电池单元的热行为和 PCM 液体成分随时间的变化。结果表明,将 PCM 带来的被动冷却解决方案与 PCM 固化的快速液体冷却期相结合,是在放电和充电过程中控制电池单元内部温度变化的有效解决方案。预计唯一的外部能源消耗来自冷却剂在极短时间内凝固时的层流。研究结果表明,在 2C 放电-2C 充电循环中,与传统的液体冷却策略相比,所提出的 PCM 液体冷却集成技术可将总能耗降低 54.9%(从 0.4406 kJ 降至 0.1963 kJ)。
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引用次数: 0
Research on the division of heat dissipation spaces for multiple heat sources based on the adiabatic characteristic of heat flow lines 基于热流线绝热特性的多热源散热空间划分研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-27 DOI: 10.1016/j.applthermaleng.2024.124263

Due to the pressing need for compact layouts, the spacing between high-power devices is gradually decreasing, making the mutual influence between multiple heat sources unavoidable. Therefore, this paper proposes a method based on the adiabatic characteristics of heat flow lines and their convergence positions to evaluate the rationality of the thermal space design of each heat source. This method has been validated for applicability in one-dimensional, two-dimensional, and three-dimensional multi-heat-source conjugate convection heat transfer. Heat flow lines have significant advantages in describing energy flow, as they align with the direction of the temperature gradient. In thermal spaces with adiabatic boundaries or mutual influences between multiple heat sources, heat flow lines converge at certain positions. The relationship between adiabatic boundaries and heat flow line convergence positions has been studied, and a more interpretative decoupling scheme for multi-heat-source systems has been proposed. The main feature of this scheme is the separation of each heat source in the same steady-state thermal space and assigning adiabatic boundaries to the solid partition surfaces, allowing efficient observation of the thermal conditions of individual heat sources and targeted layout optimization. Results indicate that this method can utilize changes in heat flow line convergence positions to assess current thermal conditions and can be used to compare the thermal performance of different shaped heat sinks. Simulation results show that under the same mass conditions, thin-fin heat sinks perform 47 % better than thick-fin heat sinks, providing a more comprehensive and intuitive assessment compared to metrics such as thermal resistance and average temperature. The proposed method offers new ideas for multi-heat-source layout optimization, heat flow control, multi-heat-source partitioned simulation, and abnormal heating detection in multiple heat sources.

由于紧凑布局的迫切需要,大功率器件之间的间距逐渐减小,使得多个热源之间的相互影响不可避免。因此,本文提出了一种基于热流线绝热特性及其汇聚位置的方法,以评估各热源热空间设计的合理性。该方法在一维、二维和三维多热源共轭对流传热中的适用性得到了验证。热流线与温度梯度方向一致,在描述能量流动方面具有显著优势。在具有绝热边界或多个热源相互影响的热空间中,热流线会在某些位置汇聚。我们对绝热边界与热流线汇聚位置之间的关系进行了研究,并提出了一种更具解释性的多热源系统解耦方案。该方案的主要特点是在同一稳态热空间中分离每个热源,并为实体分区表面分配绝热边界,从而可以有效观察各个热源的热状况,并有针对性地进行布局优化。结果表明,这种方法可以利用热流线汇聚位置的变化来评估当前的热条件,并可用于比较不同形状散热器的热性能。仿真结果表明,在相同质量条件下,薄鳍散热器的性能比厚鳍散热器高 47%,与热阻和平均温度等指标相比,能提供更全面、更直观的评估。所提出的方法为多热源布局优化、热流控制、多热源分区仿真以及多热源异常加热检测提供了新思路。
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引用次数: 0
Economic and life cycle analysis of a photovoltaic thermal application system based on phase change thermal storage 基于相变蓄热的光伏热应用系统的经济和生命周期分析
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1016/j.applthermaleng.2024.124261

Based on the photovoltaic (PV) system, phase change materials (PCMs), thermoelectric generators (TEGs), and cooling water are combined to form a photovoltaic thermal application (PV-PCM/TEG-T) system. The system is also compared with the PV and photovoltaic phase change thermal (PV-PCM-T) systems for environmental and economic analyses. The environmental analyses shows that the environmental impacts of the three systems are mainly concentrated in the production phase, with the aluminum frames and PV panels being the primary sources of the environmental effects, while the addition of paraffin wax and TEG have relatively minor environmental impacts. Economic analyses shows that the system generates electricity for 0.076 $/kW h, with the purchase of TEGs being the main capital expenditure. At the same time, the energy payback time of this system is 17.5 % shorter than that of the PV system and 6.9 % shorter than that of the PV-PCM-T system. The life cycle conversion efficiency is 55 % higher than that of the PV system and 23.9 % higher than that of the PV-PCM-T system, which provides better energy saving. In addition, with the continuous development of TEG manufacturing technology, the PV-PCM-TEG-T system will have better economic benefits and application potential.

在光伏(PV)系统的基础上,将相变材料(PCM)、热电发电机(TEG)和冷却水结合起来,形成光伏热应用(PV-PCM/TEG-T)系统。该系统还与光伏和光伏相变热能(PV-PCM-T)系统进行了环境和经济分析比较。环境分析表明,三种系统对环境的影响主要集中在生产阶段,铝框和光伏板是环境影响的主要来源,而添加石蜡和 TEG 对环境的影响相对较小。经济分析表明,该系统的发电成本为 0.076 美元/千瓦时,购买 TEG 是主要的资本支出。同时,该系统的能源投资回收期比 PV 系统短 17.5%,比 PV-PCM-T 系统短 6.9%。生命周期转换效率比光伏系统高 55%,比 PV-PCM-T 系统高 23.9%,节能效果更好。此外,随着 TEG 制造技术的不断发展,PV-PCM-TEG-T 系统将具有更好的经济效益和应用潜力。
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引用次数: 0
Fast and accurate modelling of twin-screw compressors: A generalised low-order approach 双螺杆压缩机的快速准确建模:通用低阶方法
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1016/j.applthermaleng.2024.124238

Twin-screw compressors (TSC) are commonly used in heat pump processes due to their robustness and flexibility. They exhibit two core properties, i.e. the swept volume and the built-in volume ratio (BVR), which heavily influence their capacity limits and off-design efficiency. This work presents a new low-order model (i.e. a polynomial model), which can accurately predict a TSC’s behaviour. The model uses the external pressure ratio and volumetric compressor inlet flow rate to calculate isentropic efficiency and compressor speed. The input parameters are normalised with a reference flow rate (calculated from the swept volume) and the BVR, respectively. This results in a generalised model of low numerical cost, which can be used for explorative studies independent of the specific machine size and BVR. A gain in computational speed by a factor of 375 is achieved compared to a semi-empiric reference model. The model displays very good predictive accuracy when used to predict the performance of machines with similar BVRs, but different sizes. A mean deviation from the manufacturer data of 4.29 %, 0.88 °C and 1.38 % for the shaft power, the outlet temperature and the compressor speed can be observed, respectively. When there is a difference in size and BVR, the prediction accuracy is still reasonable but significantly declines for small and very large pressure ratios. Nevertheless, the proposed new approach extends the state-of-the-art by introducing a low-order model, which combines the advantages of low computational cost, high accuracy, physically correct predictions over a wide operational range and scalability to different machine capacities and BVRs. The validation for different fluids indicates a good general prediction accuracy relatively independent of the used fluid.

双螺杆压缩机(TSC)因其坚固性和灵活性而常用于热泵工艺中。双螺杆压缩机有两个核心特性,即扫气容积和内置容积比(BVR),这两个特性严重影响了双螺杆压缩机的产能极限和非设计效率。本研究提出了一种新的低阶模型(即多项式模型),可以准确预测 TSC 的行为。该模型使用外部压力比和压缩机入口容积流量来计算等熵效率和压缩机速度。输入参数分别以参考流量(根据扫气容积计算)和 BVR 进行归一化处理。这就产生了一个数值成本较低的通用模型,可用于探索性研究,与具体的机器尺寸和 BVR 无关。与半经验参考模型相比,计算速度提高了 375 倍。该模型用于预测具有相似 BVR 但尺寸不同的机器性能时,显示出非常高的预测精度。轴功率、出口温度和压缩机转速与制造商数据的平均偏差分别为 4.29 %、0.88 °C和 1.38 %。当尺寸和 BVR 存在差异时,预测精度仍然合理,但在压力比很小和很大的情况下,预测精度会明显下降。尽管如此,所提出的新方法通过引入一个低阶模型扩展了最先进的方法,该模型结合了低计算成本、高精度、大运行范围内的物理预测正确性以及对不同机器容量和 BVR 的可扩展性等优点。对不同流体的验证表明,相对于所使用的流体,该模型具有良好的通用预测精度。
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引用次数: 0
Effect of thermoelectric subcooling on COP and energy consumption of a propane heat pump 热电过冷对丙烷热泵 COP 和能耗的影响
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1016/j.applthermaleng.2024.124242

The building sector has an important impact on the environment, being responsible for 30 % of the total greenhouse gas emissions. Knowing that the energy consumption devoted to HVAC systems accounts for 50 % of the total energy consumption of buildings, it is paramount to develop environmentally friendly technologies able to provide green space heating to the building sector. To that purpose, this manuscript presents a computational study on propane vapor compression heat pumps which include thermoelectric subcooling to boost their operation. The combination of these technologies has been proven in the past to be very beneficial for refrigeration systems and this study concludes for the first time that propane heat pumps can highly benefit from thermoelectric subcooling. The widely conducted research includes the following parameters: ambient temperatures from −20 to 15 °C, voltage supplies to the thermoelectric modules from 0.5 to 10 VDC, number of thermoelectric subcooling blocks from 1 to 8 and two water inlet temperatures, 40 and 55 °C to study their influence on heating capacity, compressor and thermoelectric power consumptions, subcooling degree, propane mass flow, compressor capacity, COP, energy consumption and SCOP of the combined heat pump. The obtained results are very conclusive, COP enhancements up to 12.29 % are achieved when a thermoelectric subcooler with 16 modules is included in a propane heat pump already provided with an internal heat exchanger for an ambient temperature of −20 °C and a water inlet temperature of 55 °C. Additionally, improvements in Seasonal COP up to 9.98 % are achieved if the above-mentioned technologies integration between a vapor compression heat pump and a thermoelectric subcooler substitutes a conventional propane heat pump with an internal heat exchanger for space heating a single-story two-family house.

建筑行业对环境有着重要影响,其温室气体排放量占总排放量的 30%。暖通空调系统的能耗占建筑物总能耗的 50%,因此,开发能够为建筑行业提供绿色空间供热的环保技术至关重要。为此,本手稿介绍了一项关于丙烷蒸汽压缩热泵的计算研究,其中包括热电过冷技术,以促进热泵的运行。这些技术的结合在过去已被证明对制冷系统非常有益,而本研究首次得出结论,丙烷热泵可以从热电过冷中获得巨大收益。广泛开展的研究包括以下参数:-20 至 15 °C 的环境温度、0.5 至 10 VDC 的热电模块供电电压、1 至 8 个热电过冷块的数量以及 40 和 55 °C 两种进水温度,以研究它们对组合热泵的加热能力、压缩机和热电功耗、过冷度、丙烷质量流量、压缩机容量、COP、能耗和 SCOP 的影响。所得结果非常有说服力,在环境温度为 -20 °C 和进水温度为 55 °C 的丙烷热泵中加入 16 个模块的热电过冷却器后,COP 可提高 12.29%。此外,如果将蒸汽压缩热泵和热电过冷却器之间的上述技术整合在一起,取代传统的带内部热交换器的丙烷热泵,用于单层两户住宅的空间供暖,则季节性 COP 可提高到 9.98%。
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引用次数: 0
Coupling study of onboard power generation system of Magnetohydrodynamics enhanced Brayton Cycle 磁流体力学增强型布雷顿循环车载发电系统的耦合研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-26 DOI: 10.1016/j.applthermaleng.2024.124250

Closed cycle power generation systems offer a possible solution to meet the high electricity needs of hypersonic vehicles, but the power generation is limited by the finite cold source and cycle temperature. Introducing two-phase flow liquid metal (LM) MHD power generation based on Closed-Brayton-Cycle (CBC) is a potential solution that can enhance the thermal-electricity conversion process at the system level. However, it is difficult to reflect the complex coupling relationship between the power generation system and the vehicles propulsion system and the limitations of finite cold sources by relying only on ideal system analysis, especially the contradiction between the void fraction and the mass flow of working fluid after the introduction of LMMHD power generation. The study utilizes a multi-dimensional model to evaluate the performance of the CBC enhanced by multi-stage LMMHD generators coupled with hydrocarbon fuel scramjet. The multi-stage mixing-separation LMMHD generator is proposed to decouple the void fraction of the MHD channel and the wall cooling process, and control the void fraction by change number of stages. The calculation result indicate that the void fraction significantly affects the overall power generation performance, including output power, performance boundary, etc. Increasing the void fraction is beneficial, and the optimal void fraction is 0.65. At the same Mach number, the fuel cooling capacity available to the system increases with the fuel equivalence ratio, resulting in higher total power output. The maximum Mach number for thermal protection of the combustor walls alone may surpass 9.5. For gas void fractions of 0.35/0.5/0.65, the maximum power generation reaches 182.8/167.1/156.9 kW, respectively. The novel system is compared with other advanced thermal-electricity conversion cycles under nearly the same conditions and demonstrated clear performance advantages.

闭式循环发电系统为满足高超音速飞行器的高电力需求提供了一种可能的解决方案,但其发电量受到有限冷源和循环温度的限制。引入基于闭式布雷顿循环(CBC)的两相流液态金属(LM)MHD 发电是一种潜在的解决方案,可以在系统层面增强热电转换过程。然而,仅靠理想系统分析难以反映发电系统与飞行器推进系统之间复杂的耦合关系和有限冷源的局限性,尤其是引入 LMMHD 发电后空隙率与工作流体质量流量之间的矛盾。该研究利用多维模型评估了由多级 LMMHD 发电机与碳氢化合物燃料扰流喷射器耦合增强的 CBC 的性能。提出的多级混合分离 LMMHD 发电机将 MHD 通道的空隙率与壁面冷却过程解耦,并通过改变级数控制空隙率。计算结果表明,空隙率对输出功率、性能边界等整体发电性能有显著影响。提高空隙率是有益的,最佳空隙率为 0.65。在相同的马赫数下,系统可用的燃料冷却能力随燃料等效比的增加而增加,从而获得更高的总输出功率。仅对燃烧器壁进行热保护的最大马赫数就可能超过 9.5。气体空隙率为 0.35/0.5/0.65 时,最大发电量分别达到 182.8/167.1/156.9 千瓦。在几乎相同的条件下,该新型系统与其他先进的热电转换循环系统进行了比较,显示出明显的性能优势。
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引用次数: 0
Measurement and prediction of void fraction and pressure drop during air drying process of wet particle packed bed 湿颗粒填料床空气干燥过程中空隙率和压降的测量与预测
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-25 DOI: 10.1016/j.applthermaleng.2024.124236

This study aimed at development of a pressure drop prediction method at a drying process by flowing air through a wet particle packed bed saturated with distilled water. At first, the pressure drop measurement during the drying process of the wet particle packed bead of glass sphere was carried out, and a method for predicting the pressure difference of the bed was proposed by investigating the effect of liquid saturation on the bed void fraction. It was clarified that the effect could be predicted by a simple model by considering liquid bridges formed between particles. Next, the liquid saturation when the measured pressure difference suddenly decreased was investigated as the residual saturation. The value was like that of past research. Finally, considering the effect of liquid saturation on the bed void fraction and the influence of the residual saturation on the relative permeability of liquid phase, more than 90 % of all pressure drop data could be predicted with an error of less than ±15 %. Furthermore, in the range where the gas-phase velocity was large, it was important to predict the pressure difference considering the change of the bed void fraction and the residual saturation.

本研究旨在开发一种通过空气流过饱和蒸馏水的湿颗粒填料床进行干燥过程的压降预测方法。首先,对玻璃球湿颗粒填料干燥过程中的压降进行了测量,并通过研究液体饱和度对床层空隙率的影响,提出了预测床层压差的方法。通过考虑颗粒之间形成的液桥,可以用一个简单的模型预测这种影响。接着,将测量到的压差突然减小时的液体饱和度作为残余饱和度进行了研究。该值与过去的研究结果相同。最后,考虑到液体饱和度对床层空隙率的影响以及残余饱和度对液相相对渗透性的影响,所有压降数据中 90% 以上都可以预测,误差小于 ±15%。此外,在气相速度较大的范围内,考虑床层空隙率和残余饱和度的变化来预测压差非常重要。
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引用次数: 0
A comparative analysis of ammonia and supercritical carbon dioxide in horizontal microchannels 水平微通道中氨气和超临界二氧化碳的比较分析
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-25 DOI: 10.1016/j.applthermaleng.2024.124255

Supercritical carbon dioxide (sCO2) and ammonia (NH3) can be used as coolants in high power-density microelectronics. sCO2 at the micro scale provides enhanced heat transfer solutions for a range of microelectronics cooling applications·NH3 can also potentially provide appropriate cooling solutions as it has favorable thermophysical properties at high pressure, and it can be used as an energy carrier as it contains Hydrogen atoms. Near its critical and pseudocritical condition sCO2 exhibits abrupt changes in its thermophysical properties and at similar pressures liquid NH3 too has adequate properties that make it a good coolant. While sCO2 is non-toxic, NH3 is a toxic substance and should only be used in closed loop micro heat exchangers.

The current study compares the convective heat transfer performance of supercritical carbon dioxide (sCO2) and ammonia for microchannel cooling. A total of 144 numerical cases inside a square microchannel of hydraulic diameter of 200 µm with a total length of 52 mm and a heated length of 50 mm at constant surface temperatures in laminar flow conditions were examined. Two scenarios were investigated, in one the inlet mass flux was kept constant at 100, 150, and 200 kg/m2s, and in the second the pressure drop across the microchannel was maintained at 200, 400, and 600 Pa. Both scenarios were investigated at pressures of 8 and 10 MPa and at surface temperatures of 32, 40, 50, 60, 70, and 80 °C. In all cases the inlet temperature of both fluids was kept at 21 °C. At the same mass flux, NH3 yielded a higher average heat transfer coefficient (havg) but at the same pressure drop, sCO2 resulted in higher havg at certain surface temperatures. The havg for NH3 didn’t show significant variation but for sCO2 it showed significant change with surface temperature, and this was due to the significant change in the thermophysical properties of sCO2. The havg showed a mixed behavior with respect to the pumping power. The coefficient of performance (COP) was as high as 600,000 for sCO2 and it was significantly higher than that for NH3. Near the pseudocritical region, the COP for sCO2 witnessed a significant improvement, more than double, for 8 MPa compared to 10 MPa.

超临界二氧化碳(sCO2)和氨气(NH3)可用作高功率密度微电子的冷却剂。微尺度的 sCO2 可为一系列微电子冷却应用提供更强的传热解决方案--NH3 也有可能提供适当的冷却解决方案,因为它在高压下具有良好的热物理性质,而且由于含有氢原子,可用作能量载体。在接近临界和假临界状态时,sCO2 的热物理性质会发生突然变化,而在类似压力下,液态 NH3 也具有使其成为良好冷却剂的适当特性。目前的研究比较了用于微通道冷却的超临界二氧化碳(sCO2)和氨的对流传热性能。在层流条件下,在表面温度恒定、水力直径为 200 微米、总长度为 52 毫米、加热长度为 50 毫米的正方形微通道内,共研究了 144 个数值案例。研究了两种情况:一种情况是入口质量流量保持恒定,分别为 100、150 和 200 kg/m2s;另一种情况是微通道压降保持在 200、400 和 600 Pa。这两种情况都是在压力为 8 和 10 兆帕以及表面温度为 32、40、50、60、70 和 80 °C 时进行研究的。在所有情况下,两种流体的入口温度都保持在 21 °C。在相同的质量通量下,NH3 的平均传热系数(havg)更高,但在相同的压降下,sCO2 在某些表面温度下的平均传热系数更高。NH3 的哈夫格变化不大,但 sCO2 的哈夫格随表面温度变化很大,这是由于 sCO2 的热物理性质发生了显著变化。havg 在泵送功率方面表现不一。sCO2 的性能系数 (COP) 高达 600,000,明显高于 NH3。在接近伪临界区时,sCO2 的 COP 显著提高,8 兆帕比 10 兆帕提高了一倍多。
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引用次数: 0
Enhancement of battery thermal management effect by a novel MOF based composite phase change material 利用基于 MOF 的新型复合相变材料增强电池热管理效果
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-25 DOI: 10.1016/j.applthermaleng.2024.124257

The introduction of phase change materials (PCMs) into battery thermal management systems (BTMS) can effectively enhance the cooling performance, safety and practical thermal management applications of lithium-ion batteries (LIBs). However, further study is needed to address the low heat conductivity and rapid phase change leakage of PCMs. This study proposed a metal–organic framework based shape-stabilized composite PCM (MOF/expanded graphite (EG) /multi-walled carbon nanotube (MWCNT) /paraffin wax (PW)) to construe battery cooling system, and its effect of battery thermal management is experimentally tested under various conditions. The results show the CPCM reveals a superior thermal management effect under varying ambient temperatures and discharge multipliers and outperforms natural convection. Even in the harsh environment of 40 °C and 3 C, the maximum temperature (Tmax) and Tmax difference (ΔTmax) of the CPCM-cooled module are 61.38 and 2.67 °C, which are 22 and 9 °C below the natural air-cooled module. Remarkably, the ΔTmax of the CPCM-cooled battery module in discharge decreases with the temperature rise at the discharge rate of 3 C, which is the exact opposite to the case of the air-cooled module. Moreover, the ΔTmax of CPCM-cooled module is 1.69, 1.84, 2.67 °C, all below the safe 5 °C at high temperatures (40 °C) as the discharge rate increases. The designed MOF-CPCM cooling system can effectively improve the temperature uniformity and thermal safety of the battery in harsh environments. Therefore, this novel MOF-based CPCM shows great promise in BTM.

在电池热管理系统(BTMS)中引入相变材料(PCM)可有效提高锂离子电池(LIB)的冷却性能、安全性和实际热管理应用。然而,针对 PCMs 的低导热性和快速相变泄漏问题还需要进一步研究。本研究提出了一种基于金属有机框架的形状稳定复合 PCM(MOF/膨胀石墨(EG)/多壁碳纳米管(MWCNT)/石蜡(PW))来构建电池冷却系统,并在各种条件下对其电池热管理效果进行了实验测试。结果表明,在不同的环境温度和放电倍率下,CPCM 的热管理效果均优于自然对流。即使在 40 ℃ 和 3 ℃ 的恶劣环境下,CPCM 冷却模块的最高温度(Tmax)和最高温度差(ΔTmax)也分别为 61.38 ℃ 和 2.67 ℃,比自然风冷模块低 22 ℃ 和 9 ℃。值得注意的是,CPCM 冷却电池模块放电时的ΔTmax 随放电速率为 3 C 时的温度升高而降低,这与风冷模块的情况正好相反。此外,随着放电速率的增加,CPCM 冷却模块的 ΔTmax 分别为 1.69、1.84、2.67 °C,在高温(40 °C)下均低于安全值 5 °C。所设计的 MOF-CPCM 冷却系统可有效改善电池在恶劣环境下的温度均匀性和热安全性。因此,这种基于 MOF 的新型 CPCM 在 BTM 中大有可为。
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Applied Thermal Engineering
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