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Research on the effect of different gas release conditions on the explosive boiling of overheated water containing NaCl 不同气体释放条件对含氯化钠的过热水爆炸沸腾的影响研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124266

High-pressure storage tanks are widely used for transportation due to their convenience. However, sometimes the tanks themselves or the stored medium may become contaminated with impurities. NaCl is one of the most commonly encountered impurities. The pressure response curves of 1.0 mol/L NaCl solution and pure water within a 17L square stainless steel vertical storage tank are being investigated. The experimental results indicate that the pressure rebound is most pronounced when the medium inside the tank releases gas phase. Unlike pure water, NaCl solution still exhibits pressure rebound during pure liquid phase release. High-speed imaging reveals that the addition of NaCl impurities reduces the nucleation radius of bubbles, sharply increases their quantity, and exacerbates boiling phenomena. As the rupture area increases, the remaining liquid level of 1.0 mol/L NaCl is much lower compared to pure water. At the 70 % leakage position, the pressure recovery ratio of both liquids is the highest. After adding NaCl impurities, under all operating conditions, the pressure recovery ratio and pressure rise ratio exceed those observed under pure water conditions. This indicates that the presence of NaCl exacerbates the boiling of superheated liquids and increases the possibility of tank rupture.

高压储罐因其便利性而被广泛用于运输。然而,有时储罐本身或储存的介质可能会受到杂质污染。氯化钠是最常见的杂质之一。我们正在研究 1.0 mol/L NaCl 溶液和纯水在 17L 方形不锈钢立式储罐中的压力响应曲线。实验结果表明,当储罐内的介质释放出气相时,压力反弹最为明显。与纯水不同,氯化钠溶液在释放纯液相时仍会出现压力反弹。高速成像显示,NaCl 杂质的加入减小了气泡的成核半径,急剧增加了气泡的数量,并加剧了沸腾现象。随着破裂面积的增大,1.0 mol/L NaCl 的剩余液面比纯水低得多。在 70% 的泄漏位置,两种液体的压力恢复比最高。加入 NaCl 杂质后,在所有工作条件下,压力恢复比和压力上升比都超过了在纯水条件下观察到的值。这表明,氯化钠的存在加剧了过热液体的沸腾,增加了储罐破裂的可能性。
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引用次数: 0
Exploiting the waste heat in a proton exchange membrane fuel cell with a capacitive salinity/heat engine 利用质子交换膜燃料电池中的余热与电容盐度/热量引擎
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124277

For fully utilizing the low-grade waste heat (LGWH) of the proton exchange membrane fuel cell (PEMFC), a novel coupled system primarily involving a PEMFC and a capacitive salinity/heat engine (CSHE) is proposed. Based on thermodynamic and electrochemical theories, mathematical formulas of the power output, efficiency, and exergy efficiency are deduced accounting for the significant irreversible losses within the coupled system. The superiority is expounded by contrasting the generic performance characteristics of the sub-systems and the coupled system. In addition, numerical results demonstrate that the maximal power output density and its corresponding efficiency and exergy efficiency of the coupled system enhanced by 11.43%, 12.75%, and 9.96%, respectively, over the PEMFC alone under the same operating conditions. Furthermore, the impacts of some parameters, for instance, proton exchange membrane (PEM) thickness, the PEMFC working temperature and working pressure, electric charge density ratio, charging cut-off voltage, and Stern layer distance, on the coupled system performance are meticulously discussed. The results of the study may supply a reference for the design and operation of such a salinity gradient energy recovery system and create a new pathway for recycling LGWH from PEMFC.

为了充分利用质子交换膜燃料电池(PEMFC)的低品位余热(LGWH),我们提出了一种新型耦合系统,主要包括质子交换膜燃料电池(PEMFC)和电容性盐/热发动机(CSHE)。根据热力学和电化学理论,推导出了功率输出、效率和放能效率的数学公式,并考虑了耦合系统内的重大不可逆损失。通过对比子系统和耦合系统的一般性能特征,阐述了其优越性。此外,数值结果表明,在相同的工作条件下,耦合系统的最大功率输出密度及其相应的效率和放能效率比单独的 PEMFC 分别提高了 11.43%、12.75% 和 9.96%。此外,还详细讨论了质子交换膜(PEM)厚度、PEMFC 工作温度和工作压力、电荷密度比、充电截止电压和斯特恩层距离等参数对耦合系统性能的影响。研究结果可为此类盐度梯度能量回收系统的设计和运行提供参考,并为 PEMFC 回收 LGWH 开辟了一条新途径。
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引用次数: 0
Numerical study on the combined application of multiple phase change materials and gradient metal foam in thermal energy storage device 多相变材料和梯度金属泡沫在热能储存装置中的联合应用数值研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124267

Latent heat thermal energy storage (LHTES) offers significant energy-saving benefits, but its application is limited due to the low thermal conductivity of phase change material (PCM). To address this issue, this article studied the combined application of metal foam structures with different porosity gradients and multiple PCMs with different melting points through numerical simulation to accelerate the melting of PCM and enhance system efficiency. The results showed that the application of multiple PCMs improved the heat transfer performance of the system, reducing the complete melting time by 9.18% compared to using a single PCM with uniform metal foam. Based on the multi-PCM storage system with an average porosity of 0.90, this article designed metal foam structures with one-dimensional and two-dimensional porosity gradients and explored their impacts. The results indicated that in the structure with a one-dimensional porosity gradient along the heat flow direction, the positive gradient decreased thermal resistance, further reducing the complete melting time by 6.18%, while the negative gradient increased it by 19.78%. However, the temperature non-uniformity was lowest with the negative gradient and highest with the positive gradient. The optimal two-dimensional porosity gradient multi-PCM storage model not only reduced thermal resistance but also effectively solved the issue of uneven melting, reducing the complete melting time by 17.96% and increasing the energy storage efficiency by 20.16% compared to the single PCM system with uniform porosity. Furthermore, the article conducted a dimensionless analysis of the optimal structure and different gradient structures, establishing formulas for the liquid fraction concerning modified Fourier number, modified Stefan number, and modified Rayleigh number.

潜热热能储存(LHTES)具有显著的节能优势,但由于相变材料(PCM)的热传导率较低,其应用受到限制。针对这一问题,本文通过数值模拟研究了不同孔隙率梯度的金属泡沫结构和多种不同熔点的 PCM 的组合应用,以加速 PCM 的熔化,提高系统效率。结果表明,多 PCM 的应用提高了系统的传热性能,与使用单一 PCM 和均匀金属泡沫相比,完全熔化时间缩短了 9.18%。基于平均孔隙率为 0.90 的多 PCM 存储系统,本文设计了具有一维和二维孔隙率梯度的金属泡沫结构,并探讨了它们的影响。结果表明,在沿热流方向具有一维孔隙率梯度的结构中,正梯度降低了热阻,使完全熔化时间进一步缩短了 6.18%,而负梯度则增加了 19.78%。然而,负梯度的温度不均匀性最低,正梯度的温度不均匀性最高。最优的二维孔隙率梯度多 PCM 储能模型不仅降低了热阻,还有效地解决了不均匀熔化的问题,与孔隙率均匀的单一 PCM 系统相比,完全熔化时间缩短了 17.96%,储能效率提高了 20.16%。此外,文章还对最佳结构和不同梯度结构进行了无量纲分析,建立了有关修正傅里叶数、修正斯特凡数和修正瑞利数的液体分数公式。
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引用次数: 0
Comparative study of an innovative coldly integrated pumped thermal electricity storage system: Thermo-economic assessment and multi-objective optimization 创新型冷集成抽水蓄能系统的比较研究:热经济评估和多目标优化
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124295

Energy storage is an important means of solving the instability of renewable energy sources. As a novel energy-storage technology, thermally integrated pumped thermal electricity storage systems have gained considerable attention owing to their capacity to enhance the power-to-power efficiency of pumped thermal electricity storage systems by integrating low-grade heat sources. However, previous studies have predominantly focused on the integration of low-grade heat sources during the charging phase. In this paper, a novel coldly integrated pumped thermal electricity storage system that integrates liquefied natural gas on the discharge side is proposed. Seawater and R1233zd(E) were utilised as the system’s heat source and working fluid, respectively. The performance of the proposed system was compared with that of a previous thermally integrated pumped thermal electricity storage system that used geothermal energy as the heat source on the charge side. System models were constructed in MATLAB, and thermodynamic and economic comparative analyses were conducted. The Genetic Algorithm was adopted for the multi-objective optimisation of the two systems. The results indicate that, within given temperature ranges for thermal and cold storage temperatures, the proposed system exhibits a higher power-to-power efficiency and has a lower levelised cost of storage compared to the existing system. The optimal power-to-power efficiency and levelised cost of storage solutions obtained via multi-objective optimisation were 1.45, 0.297 $·kWh−1 and 0.807, 0.411 $·kWh−1 for the coldly integrated and thermally integrated pumped thermal electricity storage systems, respectively. The proposed system outperformed the thermally integrated pumped thermal electricity storage system under comparison in terms of thermodynamic and economic performance. The findings of this study shed light on the design and performance of coldly integrated pumped thermal electricity storage systems.

储能是解决可再生能源不稳定性的重要手段。作为一种新型储能技术,热集成抽水蓄能系统通过集成低品位热源,提高了抽水蓄能系统的功率效率,因而备受关注。然而,以往的研究主要集中在充电阶段低品位热源的集成上。本文提出了一种新型冷集成抽水蓄能系统,该系统在排放侧集成了液化天然气。系统的热源和工作流体分别为海水和 R1233zd(E)。将拟议系统的性能与之前的热集成抽水蓄能系统的性能进行了比较,后者在充电侧使用地热能作为热源。在 MATLAB 中构建了系统模型,并进行了热力学和经济学比较分析。采用遗传算法对两个系统进行多目标优化。结果表明,在给定的热存储和冷存储温度范围内,与现有系统相比,建议的系统具有更高的功率效率和更低的平准化存储成本。通过多目标优化获得的最佳功率效率和平准化储能成本分别为:冷集成和热集成抽水蓄能系统的 1.45、0.297 美元-千瓦时-1 和 0.807、0.411 美元-千瓦时-1。在热力学和经济性能方面,拟议系统优于热集成抽水蓄能系统。本研究的结果为冷集成抽水蓄能系统的设计和性能提供了启示。
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引用次数: 0
Flow boiling in dimpled plate heat exchangers with different geometric parameters: Analysis of asymmetric channels 具有不同几何参数的凹陷板式热交换器中的流动沸腾:不对称通道分析
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124265

The evaporators of heat pumps extract heat from the environment. To improve the heat pump performance in cold environments, evaporators must operate with small temperature drops of the heat source, which requires large flow rates of the secondary fluid. This paper discusses dimpled plate heat exchangers (DPHEs) with flexible flow section areas. The flow boiling of R410A is measured in six channels. The flow section area ratios of neighboring channels are 0.86–2.83. To analyze outlet superheat, the two-phase and dryout zones are distinguished using infrared measurement. The dryout zone is a function of the superheat and mass flux, which is quantified. The heat transfer coefficients (HTCs) increase with increasing mass fluxes and heat fluxes. Compared with experimental results from a large scope, the present data fall into the combined regimes of convective boiling and nucleate boiling. Smaller hydraulic diameters slightly enhance the heat transfer. The experimental HTCs are accurately predicted by a correlation of chevron plate heat exchangers (CPHEs). The performances of the DPHEs and CPHE are compared for small temperature drops in cold environments. The DPHEs have superior performance by mitigating the unbalance of mass fluxes. The typical overall heat transfer coefficient is improved by 62%. The improvement depends on the flow section area ratios.

热泵的蒸发器从环境中提取热量。为了提高热泵在寒冷环境中的性能,蒸发器必须在热源温度下降较小的情况下运行,这就要求二次流体的流速较大。本文讨论了具有灵活流通截面面积的凹陷板式热交换器(DPHE)。在六个通道中测量了 R410A 的流动沸点。相邻通道的流通截面面积比为 0.86-2.83。为了分析出口过热度,使用红外线测量来区分两相区和干燥区。干燥区是过热度和质量通量的函数,可以量化。传热系数(HTC)随着质量通量和热通量的增加而增加。与大范围的实验结果相比,目前的数据属于对流沸腾和成核沸腾的综合状态。水力直径越小,传热效果越好。通过雪佛龙板式热交换器(CPHE)的相关性,可以准确预测实验中的 HTC。比较了 DPHE 和 CPHE 在寒冷环境中的小温降性能。DPHE 通过缓解质量通量的不平衡而具有更优越的性能。典型的整体传热系数提高了 62%。这种改善取决于流动截面的面积比。
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引用次数: 0
Investigation on heat transfer of supercritical CO2/Xe mixture crossing pseudo-critical temperature cooled in a horizontal circular tube 水平圆管中冷却的超临界 CO2/Xe 混合物跨越伪临界温度的传热研究
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124245

Supercritical CO2/Xe mixture has a potential application prospect in the Brayton cycle system from the perspective of thermodynamic. Supercritical cooler is one of the key components there. However, the cooling heat transfer characteristics and mechanism of supercritical CO2/Xe mixture is still unclear, which restricts the development and design of supercritical cooler. The heat transfer of supercritical CO2/Xe mixture crossing Tpc cooled in a horizontal tube with inner diameter 8 mm is numerically explored in this study. The influences of operating parameters on supercritical mixture heat transfer are thoroughly examined. Buoyancy effect is evaluated through the buoyancy criterion Gr/Re2. Further, the mechanism of supercritical CO2/Xe mixture cooling heat transfer is revealed. It is found that heat transfer enhancement may occur during supercritical CO2/Xe cooled process, and heat transfer is weakened when mass fraction of Xe increases. Considering the bulk specific heat and buoyancy dominating jointly the behavior of supercritical cooling heat transfer, a modified Dittus-Boelter correlation is newly developed to predict heat transfer coefficient of supercritical CO2 and its mixture with Xe. The correlation matches well with the experimental and numerical data, and the average relative deviations of the new correlation are 18.27 % and 14.14 %, respectively. The investigation provides insight into the characteristics and mechanism of supercritical CO2/Xe mixture cooling heat transfer. The correlation can provide significant theoretical guidance for accurate design and optimization of supercritical cooler.

从热力学角度看,超临界 CO2/Xe 混合物在布雷顿循环系统中具有潜在的应用前景。超临界冷却器是其中的关键部件之一。然而,超临界 CO2/Xe 混合气的冷却传热特性和机理尚不清楚,制约了超临界冷却器的开发和设计。本研究以数值方法探讨了在内径为 8 毫米的水平管中冷却的超临界 CO2/Xe 混合物穿过 Tpc 的传热问题。深入研究了运行参数对超临界混合物传热的影响。通过浮力准则 Gr/Re2 评估了浮力效应。此外,还揭示了超临界 CO2/Xe 混合冷却传热的机理。研究发现,在超临界 CO2/Xe 冷却过程中,传热可能会增强,而当 Xe 的质量分数增加时,传热会减弱。考虑到体积比热和浮力共同主导超临界冷却传热行为,新开发了一种改进的 Dittus-Boelter 相关性来预测超临界 CO2 及其与 Xe 混合气体的传热系数。该相关性与实验数据和数值数据匹配良好,新相关性的平均相对偏差分别为 18.27 % 和 14.14 %。该研究深入揭示了超临界 CO2/Xe 混合气冷却传热的特征和机理。该相关性可为超临界冷却器的精确设计和优化提供重要的理论指导。
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引用次数: 0
Multi-objective adaptive energy management strategy for fuel cell hybrid electric vehicles considering fuel cell health state 考虑燃料电池健康状况的燃料电池混合动力电动汽车多目标自适应能量管理策略
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-30 DOI: 10.1016/j.applthermaleng.2024.124270

This study proposes a multi-objective adaptive energy management strategy for fuel cell hybrid electric vehicles considering fuel cell health state. By integrating rule-based control with multi-objective optimization methods, the strategy aims to improve system efficiency, extend the lifespan of proton exchange membrane fuel cells (PEMFC), and reduce operating costs. Based on a comprehensive model of PEMFC output characteristics and lifetime degradation, this study introduces an optimized point line (OPL) strategy. This strategy dynamically adjusts operating constraints according to the state of health (SOH) of the PEMFC, ensuring optimal vehicle performance throughout its lifecycle. To optimize the OPL strategy parameters, a particle swarm optimization algorithm with compression factor was employed, enhancing the strategy’s optimization efficiency, adaptability, and robustness to better handle various real-world operating conditions. The strategy was evaluated under US06 and WLTC driving cycles and compared with traditional power following (PF) and point line (PL) strategies. Results show that compared to the PL strategy, the OPL strategy achieved a 36.4% and 34.2% reduction in operating costs under US06 and WLTC cycles, respectively. Moreover, PEMFC lifetime degradation decreased by 44.9% and 39.4% in these cycles. In high-power regions, the average operating efficiency of PEMFC improved by 2%. The strategy demonstrated good adaptability to different driving conditions, providing an effective solution for optimizing the performance and durability of fuel cell hybrid electric vehicles.

本研究为燃料电池混合动力电动汽车提出了一种考虑燃料电池健康状态的多目标自适应能量管理策略。通过将基于规则的控制与多目标优化方法相结合,该策略旨在提高系统效率、延长质子交换膜燃料电池(PEMFC)的使用寿命并降低运营成本。基于 PEMFC 输出特性和寿命衰减的综合模型,本研究引入了优化点线(OPL)策略。该策略可根据 PEMFC 的健康状况(SOH)动态调整运行约束条件,确保车辆在整个生命周期内的最佳性能。为了优化 OPL 策略参数,采用了带有压缩因子的粒子群优化算法,从而提高了该策略的优化效率、适应性和鲁棒性,以更好地处理各种实际运行条件。该策略在 US06 和 WLTC 驾驶循环下进行了评估,并与传统的功率跟随 (PF) 和点线 (PL) 策略进行了比较。结果表明,与点线策略相比,OPL 策略在 US06 和 WLTC 循环下分别降低了 36.4% 和 34.2% 的运营成本。此外,在这些周期中,PEMFC 的寿命衰减分别减少了 44.9% 和 39.4%。在大功率区域,PEMFC 的平均运行效率提高了 2%。该策略对不同驾驶条件具有良好的适应性,为优化燃料电池混合电动汽车的性能和耐用性提供了有效的解决方案。
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引用次数: 0
Operation Scheme analysis of a multipurpose small modular reactor under cogeneration condition based on a once-through steam generator dynamic model 基于一次通过蒸汽发生器动态模型的多用途小型模块化反应堆热电联产条件下的运行方案分析
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-29 DOI: 10.1016/j.applthermaleng.2024.124264

Highly flexible load requirements and cogeneration economy need to challenge the operation of a multipurpose small modular reactor cogeneration plant with once-through steam generators. Therefore, the present study develops a once-through steam generator dynamic model to analyze the multipurpose small modular reactor operation scheme under cogeneration conditions at different power levels. The once-through steam generator dynamic model is derived based on conversation equations using the moving boundary method. It is verified with RELAP5 results and open literature and the maximum relative error is 3.21 %. Three operation schemes are proposed for multipurpose small modular reactor cogeneration operation: Scheme 1 with constant steam pressure and average coolant temperature, Scheme 2 with constant steam temperature and pressure, and Scheme 3 with constant steam temperature and pure sliding steam pressure. Steady-state and dynamic characteristics with three operation schemes are simulated and investigated at three power levels: 100 %, 70 % and 30 %. The steady-state results show that Scheme 1 is more favorable for the primary loop, while Scheme 2 is beneficial to the secondary loop, and Scheme 3 can improve the thermal efficiency at low power level. The transient findings indicate that disturbances from the reactor side have a significant impact on the once-through steam generator and the minimum settling time is 3.3 s. Consequently, steam temperature control of once-through steam generator is achieved by regulating the control rods for Schemes 2 and 3, while steam pressure is suggested to be controlled by the feedwater valve for Scheme 1. For cogeneration conditions at 70 % power level, Scheme 2 can achieve the highest steam flow of turbine, the highest steam flow of steam extraction and the smallest steam specific volume, which are 87.88 kg·s−1, 28.96 kg·s−1, and 0.0503 m3·kg−1, respectively. Scheme 2 is recommended for high power levels under cogeneration operation. In contrast, Scheme 1 is more suitable for the condensing unit operation for low power levels.

高度灵活的负荷要求和热电联产的经济性需要对采用一次通过式蒸汽发生器的多用途小型模块化反应堆热电联产电厂的运行提出挑战。因此,本研究建立了一个蒸汽发生器动态模型,用于分析不同功率等级热电联产条件下多用途小型模块化反应堆的运行方案。一次通过式蒸汽发生器动态模型是基于会话方程并使用移动边界法推导出来的。该模型与 RELAP5 结果和公开文献进行了验证,最大相对误差为 3.21%。针对多用途小型模块化反应堆热电联产运行提出了三种运行方案:方案 1:恒定蒸汽压力和平均冷却剂温度;方案 2:恒定蒸汽温度和压力;方案 3:恒定蒸汽温度和纯滑动蒸汽压力。模拟并研究了三种运行方案在三种功率水平(100%、70% 和 30%)下的稳态和动态特性。稳态结果表明,方案 1 更有利于一次回路,方案 2 有利于二次回路,而方案 3 则能在低功率水平下提高热效率。瞬态结果表明,来自反应堆侧的扰动对一次蒸汽发生器的影响很大,最小稳定时间为 3.3 秒。因此,在方案 2 和 3 中,一次蒸汽发生器的蒸汽温度控制可通过调节控制棒来实现,而在方案 1 中,建议通过给水阀门来控制蒸汽压力。在 70% 功率等级的热电联产条件下,方案 2 可实现最大的汽轮机蒸汽流量、最大的抽汽蒸汽流量和最小的蒸汽比容,分别为 87.88 kg-s-1、28.96 kg-s-1 和 0.0503 m3-kg-1。建议将方案 2 用于热电联产的高功率运行。相比之下,方案 1 更适合低功率等级的冷凝机组运行。
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引用次数: 0
A free-energy based multiple-distribution-function lattice Boltzmann method for multi-component and multi-phase flows 基于自由能的多分布函数晶格玻尔兹曼方法用于多组分和多相流
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-29 DOI: 10.1016/j.applthermaleng.2024.124241

This study presents the development of a multiple-distribution-function lattice Boltzmann model (MDF-LBM) for the accurate simulation of multi-component and multi-phase flow. The model is based on the diffuse interface theory and free energy model, which enable the derivation of hydrodynamic equations for the system. These equations comprise a Cahn-Hilliard (CH) type mass balance equation, which accounts for cross diffusion terms for each species, and a momentum balance equation. By establishing a relationship between the total chemical potential and the general pressure, the momentum balance equation is reformulated in a potential form. This potential form, together with the CH type mass balance equation, is then utilized to construct the MDF-LBM as a coupled convection–diffusion system. Numerical simulations demonstrate that the proposed MDF-LBM accurately captures phase behavior and ensures mass conservation. Additionally, the calculated interface tension exhibits good agreement with experimental data obtained from laboratory studies.

本研究提出了一种多分布函数晶格玻尔兹曼模型(MDF-LBM),用于精确模拟多组分和多相流。该模型以扩散界面理论和自由能模型为基础,从而推导出系统的流体力学方程。这些方程包括一个卡恩-希利亚德(Cahn-Hilliard,CH)型质量平衡方程和一个动量平衡方程,前者考虑了每个物种的交叉扩散项。通过建立总化学势和总压力之间的关系,动量平衡方程被重新表述为化学势形式。然后,利用这种势能形式和 CH 型质量平衡方程,将 MDF-LBM 构建成一个耦合对流-扩散系统。数值模拟证明,所提出的 MDF-LBM 准确地捕捉到了相行为并确保了质量守恒。此外,计算得出的界面张力与实验室研究获得的实验数据非常吻合。
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引用次数: 0
Comparison between pool boiling system of graphene quantum dots and nitrogen-doped graphene quantum dots suspended in binary base fluids 悬浮在二元基液中的石墨烯量子点和掺氮石墨烯量子点的池沸腾体系比较
IF 6.1 2区 工程技术 Q2 ENERGY & FUELS Pub Date : 2024-08-29 DOI: 10.1016/j.applthermaleng.2024.124259

Using nanofluids instead of conventional heat transfer fluids as a passive method is a well-established and widely used technique by researchers to increase the rate and thermal performance of engineering equipment. In this study, the hydrothermal method with a bottom-up approach was used for the synthesis of graphene quantum dots and nitrogen-doped graphene quantum dots. Then, nanofluid samples were prepared in a two-step process, by adding nanoparticles to binary base fluids of deionized water and ethylene glycol in volume concentrations of (50:50) and (60:40), in four concentrations of 100, 200, 500, and 1000 ppm. In order to better understand the boiling heat transfer mechanism and measure its characteristics such as critical heat flux and heat transfer coefficient, an experimental system was designed and built. Nanofluids based on graphene quantum dots have unique features such as compatibility with the environment, economic efficiency, high stability and suitable heat transfer capability. For this reason, their selection in the pool boiling heat transfer process, in addition to saving energy, is introduced as one of the most effective options for improving CHF and HTC. The tests were performed under saturated conditions, atmospheric pressure, and on a vertical flat and polished copper thermal plate. Prepared nanofluids GQDs and N: GQDs based on DI-water maintained their apparent stability for two months. For GQDs nanofluids at an optimal concentration of 500 ppm with a volume ratio of (60:40) DI-water and EG, compared to DI-water, the greatest increase in CHF and HTC is 90.69, 85.011 % and for N: GQDs at a concentration of 500 with a volume ratio (50:50) DI-water and EG, 75.37 and 78.17 % compared to DI-water.

使用纳米流体替代传统传热流体作为一种被动方法,是一种行之有效且被研究人员广泛使用的技术,可提高工程设备的速率和热性能。本研究采用自下而上的水热法合成了石墨烯量子点和氮掺杂石墨烯量子点。然后,分两步制备纳米流体样品,将纳米粒子加入体积浓度为(50:50)和(60:40)的去离子水和乙二醇二元基液中,浓度分别为 100、200、500 和 1000 ppm。为了更好地了解沸腾传热机理并测量其特征,如临界热通量和传热系数,设计并构建了一个实验系统。基于石墨烯量子点的纳米流体具有与环境相容、经济高效、高稳定性和合适的传热能力等独特特点。因此,在池沸腾传热过程中选择它们,除了可以节约能源外,还是改善 CHF 和 HTC 的最有效选择之一。测试是在饱和条件、大气压力和垂直平面抛光铜导热板上进行的。基于去离子水制备的纳米流体 GQDs 和 N:GQDs 在两个月内保持了明显的稳定性。与去离子水相比,最佳浓度为 500 ppm、体积比为(60:40)去离子水和 EG 的 GQDs 纳米流体的 CHF 和 HTC 分别增加了 90.69% 和 85.011%,浓度为 500、体积比为(50:50)去离子水和 EG 的 N: GQDs 纳米流体的 CHF 和 HTC 分别增加了 75.37% 和 78.17%。
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Applied Thermal Engineering
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