Absorption heat pump systems using conventional LiBr/H2O are limited by crystallization issues. To address these issues, a combination of LiBr fine particle slurries formed by zeolite seeds was prepared under supersaturated conditions. The water vapor absorption performance of slurry in a lab-scale of 2 columns setup of absorber and evaporator is examined for higher temperature generation by recovering waste heat of 60 °C in this present study. The experiment was conducted to bridge the theoretical prediction in the previous study and practical application. The results showed that higher crystal concentration significantly enhances the absorption rate and maximum temperature. The slurry with 0.2996 kg-LiBr crystal/kg-slurry achieved a maximum temperature of 122 °C, exceeding the homogeneous solutions with a temperature of only 107 °C. As a result, the absorbed water vapor increased from 0.042 kg to 0.045 kg while the maximum absorption rate also increased from 0.00037 kg/s to 0.00055 kg/s. These improvements validated the self-condensation effect, in which the dissolution of crystals maintains saturation and allows temperatures to exceed the adiabatic limit. The relationship between absorption rate and pressure difference was illustrated by developing the piecewise linear correlation. To reproduce the transient temperature and the concentration under both adiabatic and non-adiabatic conditions, a comprehensive heat balance model is proposed, which includes sensible and latent heat, crystal dissolution, and heat losses. Both experimental and simulation comparisons demonstrate that slurries offer a better absorption rate and higher temperature output than homogeneous solutions. The models also predicted that the adiabatic equilibrium temperature of slurry becomes as high as 146 °C. The present study highlights the potential of utilizing the self-condensation mechanism of fine particle crystal slurries as advanced working fluids to enhance heat transfer in the absorption heat pump systems.
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