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Finite element analysis of thermal stress in Cu2O coating synthesized on Cu substrate 铜基合成Cu2O涂层热应力的有限元分析
Q3 Materials Science Pub Date : 2022-06-01 DOI: 10.5604/01.3001.0016.0753
O. Shorinov
The paper aims to find the magnitude and nature of thermal residual stresses that occur during cooling of a copper sample with a thermally synthesized oxide layer of Cu2O.Thermo-mechanical analysis was performed by the finite element method using Ansys Software. The results of thermal analysis were used to study the resulting stress-strain state of the thin film/coating system after cooling.Based on the modeling results, the paper determined the most stress-strain areas of the sample with a coating, which are the free edges of the interfaces between the copper substrate and the Cu2O oxide layer.The main limitations of the study are the use of certain simplifications in the condition setup, for instance, uniform cooling of the thin film/coating system, homogeneity and isotropy of substrate and thin film materials, invariance of their properties with temperature changes, etc.The results obtained can be used to control the stress-strain state of the thin film/coating system and prevent deformations and destruction of thin-film structures during their production and operation of products with them.The study of new promising methods for the formation of oxide nanostructures, for instance in a plasma environment, requires a sufficient theoretical basis in addressing the origin and development of stresses.
本文旨在找出具有热合成Cu2O氧化物层的铜样品在冷却过程中产生的热残余应力的大小和性质。使用Ansys软件通过有限元方法进行了热机械分析。热分析的结果用于研究冷却后薄膜/涂层系统的应力-应变状态。基于建模结果,本文确定了涂层试样的最大应力-应变区域,即铜基底与Cu2O氧化物层之间界面的自由边缘。该研究的主要局限性是在条件设置中使用了某些简化,例如,薄膜/涂层系统的均匀冷却、基底和薄膜材料的均匀性和各向同性、它们的性质随温度变化的不变性,所获得的结果可用于控制薄膜/涂层系统的应力-应变状态,并防止薄膜结构在其产品的生产和操作过程中的变形和破坏。研究新的有前景的氧化物纳米结构形成方法,例如在等离子体环境中,需要有足够的理论基础来解决应力的起源和发展。
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引用次数: 1
The influence of workpiece speed on microhardness and residual stresses in vacuum-carburised 20MnCr5 steel using the single-piece flow method 采用单件流法研究工件速度对真空渗碳20MnCr5钢显微硬度和残余应力的影响
Q3 Materials Science Pub Date : 2022-06-01 DOI: 10.5604/01.3001.0016.0754
J. Sawicki, B. Januszewicz, M. Sikora, B. Witkowski
To determine the impact of selected conditions of abrasive treatment on the value and distribution of microhardness and residual stresses in layers carburised by a continuous single-piece flow method.Reference pieces were low pressure carburised at 920°C and then heat-treated in a 4D Quench heat treatment chamber at a pressure of 7 bar and tempered at 190ºC for 3 hours. In the next stage, samples were ground at various vw piece speeds, introducing grinding fluid into the cutting zone using the WET spraying method or using the MQL method at a minimum flow rate. The distribution of microhardness and residual stresses generated in the technological outer layer of the pieces following heat and chemical treatment and the grinding process was measured.Results of the tests indicated that the vw piece speed and method used to supply cooling and lubricating fluid to the grinding zone had an impact on selected parameters of the technological outer layer of flat samples made of 20MnCr5 steel. The process of grinding using an electrocorundum grinding wheel results in a deterioration of residual stresses in the material. For each of the three analysed vw piece speeds, reduced changes in material microhardness prior to cutting occur in the outer layer of samples ground using GF supplied at a minimum flow rate using the MQL method.Environmental considerations and having to conform to increasingly stringent regulations related to environmental protection and employee safety motivate researchers and businesses to entirely eliminate or reduce the use of grinding fluids in the grinding process and, therefore, to optimise grinding technology.Modern manufacturing industry requires the grinding process, which follows heat and chemical treatment, to be performed with the highest possible efficiency. However, retaining high parameters of the technological outer layer in comparison to the sample material following vacuum carburisation (before grinding) is extremely difficult. An optimised configuration of parameters of the grinding process and method of supplying grinding fluids enables meeting the current and future high expectations of the industry in this regard.The tests have enabled us to determine the impact of the applied vw workpiece speed and method of supplying grinding fluid on microhardness and residual stresses. Generally speaking, grinding with an electrocorundum grinding wheel results in a deterioration of residual stresses. For both methods of supplying GF (WET and MQL), the distribution of microhardness in the material of the samples ground with the highest workpiece speed (18.0 m/min) indicated no significant differences with regard to the distribution of microhardness in the material of the samples following heat and chemical treatment.
确定磨料处理条件对连续单片流渗碳层显微硬度值和残余应力分布的影响。参考件在920℃下进行低压渗碳,然后在4D淬火热处理室中以7 bar的压力进行热处理,并在190℃下回火3小时。在下一阶段,以不同的vw片速度对样品进行研磨,使用湿喷涂方法或使用最小流量的MQL方法将磨削液引入切削区。测量了热处理、化学处理和磨削加工后工艺外层的显微硬度和残余应力分布。试验结果表明,工件速度和向磨削区提供冷却润滑液的方式对20MnCr5钢平面试样工艺外层的选择参数有影响。使用电刚玉砂轮磨削的过程会导致材料中残余应力的恶化。对于三种分析的大众片速度中的每一种,在使用MQL方法以最小流速提供的GF研磨样品的外层,在切割前材料显微硬度的变化都减少了。环境方面的考虑,以及必须遵守与环境保护和员工安全相关的日益严格的法规,促使研究人员和企业在磨削过程中完全消除或减少磨削液的使用,从而优化磨削技术。现代制造业要求在热处理和化学处理之后的研磨过程以尽可能高的效率进行。然而,与真空渗碳(研磨前)后的样品材料相比,保持技术外层的高参数是非常困难的。优化的研磨工艺参数配置和提供研磨液的方法能够满足当前和未来行业在这方面的高期望。这些试验使我们能够确定施加的大众工件速度和提供磨削液的方法对显微硬度和残余应力的影响。一般来说,使用电刚玉砂轮磨削会导致残余应力的恶化。对于两种提供GF的方法(WET和MQL),以最高工件速度(18.0 m/min)研磨的样品材料的显微硬度分布与热处理和化学处理后的样品材料的显微硬度分布没有显著差异。
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引用次数: 1
Ultraviolet disinfection of activated carbon from microbiological contamination 紫外线消毒活性炭去除微生物污染
Q3 Materials Science Pub Date : 2022-05-01 DOI: 10.5604/01.3001.0016.0680
A. Semenov, Y. Hmelnitska
This article aims to investigate the effectiveness of the use of ultraviolet radiation or a combination of ultraviolet radiation and ozonation in the inactivation of microorganisms in activated carbon "Silcarbon".Several experimental studies where ultraviolet light, a combination of UV radiation, and ozonation were used have been performed to disinfect "Silcarbon" from microbiological contaminants.Experimental results have shown that with pulsed xenon lamps and low-pressure mercury ozone lamps, satisfactory results can be obtained in which the total amount of yeast and mould fungi range from 50 CFU/g to 75 CFU/g.It is advisable to continue the study of powder materials, including drugs, on the content of microbiological contaminants to assess their compliance with regulatory requirements.The application of the proposed approach to the inactivation of microorganisms allows one to obtain a safe sorbent on the content of microbiological indicators and can be successfully used in any other field to disinfection powder materials using different modes of UV irradiation.The originality of the article's results proposes a method of disinfection of the sorbent "Silcarbon" from moulds and yeasts for therapeutic purposes in medicine.
本文旨在探讨利用紫外线辐射或紫外线辐射与臭氧氧化相结合对活性炭“硅碳”中微生物的灭活效果。已经进行了几项实验研究,其中使用紫外线、紫外线辐射组合和臭氧化对“硅碳”进行了消毒,使其免受微生物污染物的污染。实验结果表明,在脉冲氙灯和低压汞臭氧灯下,酵母和霉菌的总量在50 CFU/g ~ 75 CFU/g之间,均可获得满意的结果。建议继续研究粉末材料,包括药物,微生物污染物的含量,以评估其是否符合法规要求。将所提出的方法应用于微生物的灭活,可以获得微生物指示剂含量的安全吸附剂,并且可以成功地用于任何其他领域,使用不同模式的紫外线照射消毒粉末材料。文章结果的独创性提出了一种从霉菌和酵母中为医学治疗目的消毒吸附剂“硅碳”的方法。
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引用次数: 0
Investigating the capability of low-cost FDM printers in producing microfluidic devices 研究低成本FDM打印机生产微流体设备的能力
Q3 Materials Science Pub Date : 2022-05-01 DOI: 10.5604/01.3001.0016.0670
K.B. Haouari, Mustapha Ouardouz
This paper aims to investigate the possibilities of using 3D printing by fused deposition modelling (FDM) technology for developing micro-fluidic devices by printing a benchmark test part. A low-cost desktop printer is evaluated to compare the minimum possible diameter size, and accuracy in the microchannel body.The parts were designed using SolidWorks 2016 CAD software and printed using a low-cost desktop FDM printer and Polylactic acid (PLA) filament.Desktop 3D printers are capable of printing open microchannels with minimum dimensions of 300 µm width and 200 µm depth.Future works should focus on developing new materials and optimizing the process parameters of the FDM technique and evaluating other 3D printing technologies and different printers.The paper shows the possibility of desktop 3D printers in printing microfluidic devices and provides a design of a benchmark part for testing and evaluating printing resolution and accuracy.
本文旨在研究通过打印基准测试零件,使用熔融沉积建模3D打印技术开发微流体器件的可能性。评估了一种低成本的台式打印机,以比较微通道主体中可能的最小直径尺寸和精度。这些零件使用SolidWorks2016 CAD软件进行设计,并使用低成本的台式FDM打印机和聚乳酸(PLA)细丝进行打印。台式3D打印机能够打印最小尺寸为300µm宽和200µm深的开放式微通道。未来的工作应侧重于开发新材料,优化FDM技术的工艺参数,并评估其他3D打印技术和不同的打印机。本文展示了台式3D打印机在打印微流体设备中的可能性,并提供了一个测试和评估打印分辨率和准确性的基准部件的设计。
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引用次数: 2
Experimental investigations and finite element modelling of a suggested prosthetic foot 一种建议的假足的实验研究和有限元建模
Q3 Materials Science Pub Date : 2022-05-01 DOI: 10.5604/01.3001.0016.0675
M. J. Jweeg, A. Hassan, M.M. Almudhaffar
To design and manufacture a dynamic cheap prosthetic foot compatible with amputees' requirements by introducing a natural fibre called kenaf (scientific name Hibiscus cannabinus L).In two cases, four suggested designs were analysed using the finite elements method (FEM) with a commercial ANSYS R1 program. The first case was a heel strike. The second was toe-off by subjecting force equal to 70 kg for both cases to select the optimal design.The foot found the tensile strength, flexural strength, impact stress, and fatigue test according to ISO 10328 standards successfully.The selected design was analysed again using the ANSYS R1 program for weights 60, 70, and 80 kg for two sequences, one containing kenaf, to study how such additive could affect the mechanical properties and estimate the proper quality weight of the foot. The winner's design was then produced and tested in a fatigue foot tester according to ISO 10328 standards.The results showed that the sequence containing the natural fibres kanaf material improved the deformation by 20% for both cases (from 7.47 to 8.92 mm for the heel strike case for a weight of 80 kg for the sequence without and with kanaf, respectively), and the damping ratio increased by 50% (0. 188 and 0.273 for the sequence without and with kenaf, respectively), which means an increase in the stored energy and higher stability. Also, the mechanical properties like maximum tensile strength, flexural strength, impact stress, and natural frequency were modified.This paper develops an analytical and practical study to design and produce a dynamic cheap prosthetic foot made from natural fibres, which are characterized as renewable, cheap, recyclable, and environmentally friendly materials with good mechanical properties. Authors believe it is the first time to use natural kenaf fibres in the prosthetic foot manufacturing field.
采用红麻(学名Hibiscus cannabinus L)作为天然纤维,设计和制造符合截肢患者需求的动态廉价假肢足。在两种情况下,采用商业ANSYS R1程序对四种建议设计进行了有限元分析。第一个案例是脚跟撞击。第二种方法是在两种情况下分别施加70 kg的力,以选择最优设计。根据ISO 10328标准成功进行了拉伸强度、弯曲强度、冲击应力和疲劳测试。采用ANSYS R1程序对所选设计再次进行分析,分别对重量为60kg、70kg和80kg的两个序列进行分析,其中一个序列含有红麻,以研究这种添加剂对足部力学性能的影响,并估计出合适的质量重量。获胜者的设计随后根据ISO 10328标准在疲劳脚测试仪中进行生产和测试。结果表明,含有天然纤维红麻材料的序列在两种情况下都使变形量提高了20%(在重量为80 kg的情况下,不含红麻和含红麻的序列分别从7.47 mm提高到8.92 mm),阻尼比提高了50%(0。不含麻和含麻的序列分别为188和0.273),这意味着存储能量增加,稳定性更高。同时,对材料的最大抗拉强度、抗折强度、冲击应力、固有频率等力学性能进行了改进。本文从分析和实践的角度出发,设计和生产了一种动态的廉价假肢足,其材料为天然纤维,具有可再生、廉价、可回收、环保的特点,具有良好的机械性能。作者认为,这是首次将天然红麻纤维应用于假肢足制造领域。
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引用次数: 1
Hyperelastic modelling of rubber with multi-walled carbon nanotubes subjected to tensile loading 多壁碳纳米管橡胶在拉伸载荷作用下的超弹性建模
Q3 Materials Science Pub Date : 2022-04-01 DOI: 10.5604/01.3001.0016.0027
M. J. Jweeg, D. A. Alazawi, Q. H. Jebur, M. Al-Waily, N. Yasin
This study thoroughly examined the application of inverse FE modelling and indentation tensile tests to identify nanotubes' rubber material properties.Carbon nanotubes with various percentages of multi-walled carbon nanotubes exposed to high tensile stress were used to enhance the mechanical qualities of natural rubber (NR).In this work, carbon nanotubes have been added to natural rubber. By using a solvent casting technique, toluene was used to make nanocomposites. 0.2%, 0.4%, 0.6%, 0.8%, and 1%. In this article, rubber and multi-walled carbon nanotubes interact in practical ways. Mechanical features of carbon nanotubes in NR have been researched. The results will lead to rubber products with improved mechanical qualities compared to present nanocomposite rubber containing various percentages of multi-walled carbon nanotubes exposed to large tensile test loading. The relative fitness error for significant stresses is reasonable with a second or third-order deformation model in numerical results.Non-linear finite element analysis is widely used to optimise complicated elastomeric components' design and reliability studies. However, accurate numerical results cannot be achieved without using rubber or rubber nanocomposite materials with reliable strain energy functions.The indentation tensile tests of rubber samples have been simulated and confirmed using a parametric FE model. An inverse materials parameter identification algorithm was used to calculate the hyperelastic material properties of rubber samples evaluated in uniaxial tensile. Using ABAQUS FE software, material parameters and force-displacement data may be automatically updated and extracted.The numerical data for the inverse method of material property prediction has been successfully established by developing simulation spaces for various material characteristics. The force-displacement curve can be represented using technical methods. The results demonstrate that the inverse FE modelling process might be simplified by using these curve fitting parameters and plot equations to build a mathematical link between curve coefficients and material properties. The first, second, and third-order deformation models were tested using FE simulations for the tensile test.
本研究深入研究了反向有限元建模和压痕拉伸试验在确定纳米管橡胶材料性能方面的应用。采用不同比例的多壁碳纳米管暴露在高拉伸应力下,以提高天然橡胶(NR)的机械质量。在这项工作中,碳纳米管被添加到天然橡胶中。采用溶剂铸造技术,以甲苯为原料制备纳米复合材料。0.2%, 0.4%, 0.6%, 0.8%, 1%在这篇文章中,橡胶和多壁碳纳米管在实际中相互作用。研究了碳纳米管在NR中的力学特性。研究结果将导致橡胶制品的机械质量比目前含有不同百分比的多壁碳纳米管的纳米复合橡胶暴露在大拉伸试验载荷下有所改善。数值结果表明,采用二阶或三阶变形模型对显著应力的相对适应度误差是合理的。非线性有限元分析广泛应用于复杂弹性体构件的优化设计和可靠性研究。然而,如果不使用具有可靠应变能函数的橡胶或橡胶纳米复合材料,则无法获得准确的数值结果。采用参数化有限元模型对橡胶试样的压痕拉伸试验进行了模拟和验证。采用材料参数反识别算法,计算了单轴拉伸橡胶试样的超弹性材料性能。利用ABAQUS有限元软件,可以自动更新和提取材料参数和力位移数据。通过建立各种材料特性的模拟空间,成功地建立了材料性能预测逆方法的数值数据。力-位移曲线可以用技术方法表示。结果表明,利用这些曲线拟合参数和绘图方程建立曲线系数与材料性能之间的数学联系,可以简化有限元反建模过程。一阶、二阶和三阶变形模型采用有限元模拟进行拉伸试验。
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引用次数: 4
The microstructure and thermal properties of Yb2SiO5 coating deposited using APS and PS-PVD methods 研究了APS法和PS-PVD法沉积Yb2SiO5涂层的显微组织和热性能
Q3 Materials Science Pub Date : 2022-04-01 DOI: 10.5604/01.3001.0016.0025
P. Rokicki, M. Góral, T. Kubaszek, K. Dychtoń, M. Drajewicz, M. Wierzbińska, K. Ochał
The new ceramic material for Enviromental Barrier Coatings (EBC) on ceramic material was developed.The ytterbium monosilicate was deposited using two methods: atmospheric plasma spray (APS) and plasma spray physical vapour deposition (PS-PVD).Obtained coating was characterized by dense structure and columns typically formed in PS-PVD process were not observed. In comparison with APS-deposited coating, in this method, both elements segregation and formation of ytterbium oxide occurred.The further research for production of columnar coatings will be necessary.Developed coatings migh be used for next generations of ceramic materials used for gas turbine and jet engine blades and vanes as a high temperature and corrosion protection.The first time the ytterbium monosilicate was produced bot by APS and LPPS methods.
开发了一种新型陶瓷材料,用于陶瓷材料上的环境屏障涂层(EBC)。采用大气等离子体喷涂(APS)和等离子体喷涂物理气相沉积(PS-PVD)两种方法制备了单硅酸镱涂层,所得涂层结构致密,未观察到PS-PVD过程中典型形成的柱状物。与APS沉积涂层相比,该方法同时发生了元素偏析和氧化镱的形成。有必要对柱状涂层的生产进行进一步的研究。开发的涂层可用于燃气轮机和喷气发动机叶片的下一代陶瓷材料,作为高温和腐蚀防护材料。首次采用APS法和LPPS法合成了单硅酸镱。
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引用次数: 0
Influence of the artificial defect on the flexible pipeline twist angle 人为缺陷对柔性管道扭曲角的影响
Q3 Materials Science Pub Date : 2022-04-01 DOI: 10.5604/01.3001.0016.0026
S. Nazarenko, R. Kovalenko, O. Kolienov, D. Saveliev, V. Miachyn, V. Demianyshyn
To establish the dependence of the change in the values of the twisting angle of the flexible pipeline on the internal water pressure and the defect length, which is directed along and across the axis of the sleeve.Experimental studies were conducted in two stages. At the first stage, the methodology and plan of the experiment were developed, the factors and their values were determined, and experimental studies were conducted. The limits of variation in the area of factor spaces were established based on the basic analysis of a priori information. The length of the defect was 0, 50 and 100 mm. The pressure values in the sleeve were 0.2, 0.4 and 0.6 MPa. Adequacy of the obtained regression equations was checked using Fisher's test. At the second stage, the analysis of the research results was carried out and the numerical values of the factors that most affect the change in the value of the twisting angle of the sleeve were established.According to the results of experimental studies, the dependences of the change in the twisting angle of the flexible pipeline on the internal water pressure and the length of the defect were obtained. It was established that the dependence of the previously mentioned factors is close to linear. The largest discrepancy in the maximum sleeve twist angle – 21% was observed at pressure values of 0.4 MPa.The research was limited to only two factors: the defect length and the pressure in the middle of the sleeve. Such factors as the degree of wear of the sleeve, the type of sleeve and the number of defects on the test sample were not taken into account.The obtained results can be used during the development of a new method of testing flexible pipelines, which will allow to establish hidden defects in them.For the first time, the dependence of the influence of the size and direction of the defect on the reinforcing frame of the pressure fire hose on the value of its twist angle at constant internal pressure indicators was established.
建立柔性管道扭曲角度值的变化对内部水压和缺陷长度的依赖性,缺陷长度沿套筒轴线和穿过套筒轴线定向。实验研究分两个阶段进行。在第一阶段,制定了实验的方法和计划,确定了影响因素及其值,并进行了实验研究。在对先验信息进行基本分析的基础上,建立了因子空间面积变化的极限。缺陷的长度分别为0、50和100毫米。套筒中的压力值分别为0.2、0.4和0.6兆帕。使用Fisher检验检验所获得的回归方程的充分性。在第二阶段,对研究结果进行了分析,并确定了影响套筒扭转角度值变化最大的因素的数值。根据实验研究结果,得到了柔性管道扭曲角度的变化与内部水压和缺陷长度的关系。已经确定,上述因素的相关性接近线性。在0.4 MPa的压力值下,观察到最大套筒扭曲角的最大差异–21%。研究仅限于两个因素:缺陷长度和套筒中间的压力。没有考虑套筒的磨损程度、套筒类型和试样上缺陷的数量等因素。所获得的结果可用于开发一种测试柔性管道的新方法,该方法将允许在管道中建立隐藏的缺陷。首次建立了在恒定内压指标下,压力消防软管加强架上缺陷的大小和方向对其扭曲角值的影响关系。
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引用次数: 1
Prediction of brittle fracture propagation behaviour of hydroxyapatite (HAp) coating in artificial femoral stem component 羟基磷灰石(HAp)涂层人工股骨假体脆性断裂扩展行为的预测
Q3 Materials Science Pub Date : 2022-03-01 DOI: 10.5604/01.3001.0015.9851
C. Sheng, Nagentrau Muniandy, N. H. Ibrahim
Purpose: This study addresses the brittle fracture propagation behaviour modelling of hydroxyapatite (HAp) coating in artificial femoral stem component.Design/methodology/approach: A simple two dimensional flat-on-flat contact configuration finite element model consisting contact pad (bone), Ti-6Al-4V substrate and HAp coating is employed in static simulation. The HAp coating is modelled as elastic layer with pre-microcrack which assumed to be initiated due to stress singularity.Findings: The study revealed that reducing coating thickness, pre-microcrack length and artificial femoral stem elastic modulus along with increasing bone elastic modulus will result in significant stress intensity factor (SIF) to promote brittle fracture propagation behaviour.Research limitations/implications: The influence of coating thickness, pre-microcrack length, bone and artificial femoral stem elastic modulus on fracture behaviour is examined under different stress ratio using J-integral analysis approach.Practical implications: The proposed finite element model can be easily accommodating different Hap coating thickness, pre-microcrack length, bone and artificial femoral stem elastic modulus to perform detailed parametric studies with minimal costly experimental works.Originality/value: Limited research focussing on brittle fracture propagation behaviour of HAp coating in artificial femoral stem component. Thus, present study analysed the influence of coating thickness, pre-microcrack length, bone and artificial femoral stem elastic modulus on stress intensity factor (SIF) of HAp coating.
目的:本研究探讨羟基磷灰石(HAp)涂层在人工股骨干假体中的脆性骨折扩展行为模型。设计/方法/方法:在静态模拟中采用了一个简单的二维平面接触配置有限元模型,该模型由接触垫(骨)、Ti-6Al-4V基底和HAp涂层组成。HAp涂层被建模为具有预微裂纹的弹性层,该预微裂纹假设是由于应力奇异性引起的。研究结果:研究表明,随着骨弹性模量的增加,减少涂层厚度、微裂纹前长度和人工股骨干弹性模量将导致显著的应力强度因子(SIF),从而促进脆性骨折的扩展行为。研究局限性/意义:使用J积分分析方法,研究了涂层厚度、微裂纹前长度、骨和人工股骨干弹性模量对不同应力比下骨折行为的影响。实际意义:所提出的有限元模型可以很容易地适应不同的Hap涂层厚度、微裂纹前长度、骨骼和人工股骨干弹性模量,以最低成本的实验工作进行详细的参数研究。独创性/价值:有限的研究集中在人工股骨干组件中HAp涂层的脆性断裂扩展行为上。因此,本研究分析了涂层厚度、微裂纹前长度、骨和人工股骨干弹性模量对HAp涂层应力强度因子(SIF)的影响。
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引用次数: 0
Anodic growth of copper oxide nanostructures in glow discharge 辉光放电中氧化铜纳米结构的阳极生长
Q3 Materials Science Pub Date : 2022-03-01 DOI: 10.5604/01.3001.0015.9850
A. Breus, S. Abashin, I. Lukashov, O. Serdiuk
Purpose: Application of plasma glow discharge to copper oxide nanostructure growth is studied. The simplicity of the proposed technique may be beneficial for the development of new plasma reactors for large-scale production of diverse metal oxide nanostructures.Design/methodology/approach: Copper sample was placed on anode of a setup designed to ignite plasma glow discharge. The proposed approach allows eliminating the negative effects of ion bombardment, like sputtering and generation of defects on a surface of the growing nanostructures, but preserves the advantages of thermal growth. The growth process was explained in terms of thermal processes interaction occurring on a surface of the anode with the glow discharge plasma.Findings: Plasma treatment resulted in generation of reach and diverse nanostructures that was confirmed by SEM images. Nanowire-like, flower-like, anemone-like nanostructures and nanodisks composed into the nanoassemblies are observed; the nanostructures are associated with microbabbles on CuO layer. These findings allow concluding about the possible implementation of the proposed method in industry.Research limitations/implications: The main limitation is conditioned by the lack of heat supplied to the anode, and absence of independent control of the heat and ion fluxes; thus, the additional heater should be installed under the anode in order to expand the nomenclature of the nanospecies in the future studies.Practical implications: High-productivity plasma process in copper oxide nanostructures synthesis was confirmed in this research. It may be applied for field emitter and supercapacitor manufacturing.Originality/value: Oxide nanostructure synthesis is conducted by use of a simple and well-known glow discharge technique in order to expand the production yield and diversity of nanostructure obtained in the processes of thermal growth.
目的:研究等离子体辉光放电在氧化铜纳米结构生长中的应用。该技术的简单性可能有助于开发用于大规模生产各种金属氧化物纳米结构的新型等离子体反应器。设计/方法/方法:将铜样品放置在用于点燃等离子体辉光放电装置的阳极上。提出的方法可以消除离子轰击的负面影响,如溅射和在生长的纳米结构表面产生缺陷,但保留了热生长的优点。根据阳极表面与辉光放电等离子体发生的热过程相互作用来解释生长过程。结果:等离子体处理导致了纳米结构的产生,并通过扫描电镜图像证实了这一点。观察到纳米线状、花状、海葵状纳米结构和纳米圆盘组成的纳米组件;纳米结构与CuO层上的微泡有关。这些发现使我们能够对所建议的方法在工业上的可能实施作出结论。研究局限/启示:主要局限于缺乏向阳极提供的热量,以及缺乏对热和离子通量的独立控制;因此,为了在未来的研究中扩大纳米物种的命名范围,应该在阳极下安装额外的加热器。实际意义:本研究证实了等离子体法制备氧化铜纳米结构的高生产率。可应用于磁场发射极和超级电容器的制造。原创性/价值:为了扩大热生长过程中获得的纳米结构的产量和多样性,利用一种简单而广为人知的辉光放电技术进行氧化物纳米结构的合成。
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引用次数: 1
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Archives of materials science and engineering
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