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Nuclear Structure of Ce Nuclei within Interacting Boson Model-2 相互作用玻色子模型-2中Ce原子核的核结构
Pub Date : 2021-12-22 DOI: 10.9734/ajr2p/2021/v5i330165
Ali N. Sabbar, S. N. Abood
Using the Interacting Boson Model-2 (IBM-2), we determined the most appropriate Hamiltonian for the current calculations of energy levels and electromagnetic transition probability values of 124-138Ce nuclei with a mass around A=140  in this study. We estimated energy levels and electromagnetic values and mixing ratios (E2/M1)  for a number of transitions in 124-138Ce isotopes using the best fitted values of parameters in the IBM-2 Hamiltonian. When the results were compared to the experimental data, they were found to be in good agreement.
利用相互作用玻色子模型-2 (IBM-2),我们确定了当前计算质量在a =140左右的124-138Ce原子核能级和电磁跃迁概率值的最合适的哈密顿量。我们利用IBM-2哈密顿量参数的最佳拟合值估计了124-138Ce同位素中若干跃迁的能级、电磁值和混合比(E2/M1)。将计算结果与实验数据进行比较,发现两者吻合得很好。
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引用次数: 0
Magnetic Characterization of Co and Zn Nano Ferrites: Property Consideration for Oil-Spill Clean Up Co和Zn纳米铁氧体的磁性表征:对溢油清理性能的考虑
Pub Date : 2021-12-20 DOI: 10.9734/ajr2p/2021/v5i330164
A. Musa, M. A. Muhammad, N. M. Maharaz, A. Gidado
Nano-magnetic particles are significantly finding applications in environmental remediation. This work studied the magnetic properties of Co and Zn nano-ferrites, CoFe2O4 and ZnFe2O4 respectively, with considerations for the properties that are desirable for oil spill cleanup. The ferrite nanoparticles were synthesized by the glycol-thermal method at 200 ºC for 6 hours using a stirred pressure reactor. Single phase spinel crystal structures were obtained for both samples as determined by an X-ray diffraction (XRD) machine. The high-resolution transmission electron microscope and surface electron microscope images showed nano structures. The magnetic properties and magnetic hyperfine parameters were determined using a lakeshore vibrating sample magnetometer and 57Fe Mössbauer spectroscopy. The XRD peaks were consistent with that of a single phase spinel structure. No impurity phase was detected. The nano-ferrites have crystallite sizes of about 10 nm and 17 nm for CoFe2O4 and ZnFe2O4. The nano almost-spherical nature of the samples was also confirmed from their morphology studies. The saturation magnetization of CoFe2O4 and ZnFe2O4 were about 50 emu/g and 30 emu/g respectively. They both exhibited superparamagnetic properties with a component of para-magnetism observed in ZnFe2O4 nano-ferrites. CoFe2O4 nano-ferrites exhibited better desired property for oil spill cleanup. The ZnFe2O4 nano-ferrites showed tendencies of slow response to magnetic field, however, it is more environmentally friendly. The magnetic hyperfine parameters and the isomer shift values for CoFe2O4 and ZnFe2O4 showed strong internal magnetic fields and the obtained values are consistent with spinel structure. The oxidation state of Fe was observed to be Fe3+. Due to the low coercivity and high magnetization values, these particles could be considered as potential candidates for oil spill cleanup. These desirable magnetic properties will improve the recyclability of the nanoparticles using low applied magnetic fields.
纳米磁性粒子在环境修复中的应用越来越广泛。本文研究了Co和Zn纳米铁氧体CoFe2O4和ZnFe2O4的磁性能,并考虑了它们在油污清理方面的性能。在搅拌压力反应器中,采用乙二醇-热法制备铁酸盐纳米颗粒,温度200℃,反应时间6小时。用x射线衍射仪(XRD)测定了两种样品的单相尖晶石晶体结构。高分辨率透射电子显微镜和表面电子显微镜图像显示纳米结构。采用湖滨振动样品磁强计和57Fe Mössbauer光谱法测定了样品的磁性能和磁超细参数。XRD峰与单相尖晶石结构相一致。未检测到杂质相。CoFe2O4和ZnFe2O4的纳米铁氧体晶粒尺寸分别为10 nm和17 nm。样品的纳米近球形性质也从它们的形态学研究中得到证实。CoFe2O4和ZnFe2O4的饱和磁化强度分别约为50 emu/g和30 emu/g。它们都表现出超顺磁性,在ZnFe2O4纳米铁氧体中观察到一个顺磁性成分。CoFe2O4纳米铁氧体具有较好的油污清除性能。ZnFe2O4纳米铁氧体表现出对磁场响应缓慢的趋势,但对环境更友好。CoFe2O4和ZnFe2O4的磁超细参数和异构体位移值均表现出较强的内部磁场,且得到的值与尖晶石结构一致。观察到Fe的氧化态为Fe3+。由于低矫顽力和高磁化值,这些颗粒可以被认为是石油泄漏清理的潜在候选者。这些理想的磁性能将提高纳米颗粒在低外加磁场下的可回收性。
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引用次数: 0
Assessment of Activity Concentration of Radionuclides in Soil and Cassava Food Crop from Solid Mineral Mining Site in Ishiagu, Ivo L.G.A of Ebonyi State, Nigeria 尼日利亚Ebonyi州Ivo L.G.A Ishiagu固体矿物矿区土壤和木薯粮食作物放射性核素活性浓度评估
Pub Date : 2021-12-14 DOI: 10.9734/ajr2p/2021/v5i330163
C. Mgbeokwere, C. Ononugbo, A. Bubu
The assessment of activity of concentration of radionuclides in soil and food crops from solid mineral mining sites at Ishiagu, in Ivo L.G.A of Ebonyi State was carried out using the necessary measuring instruments. Samples of soil and cassava crop collected from around the mining sites. The samples were analysed using gamma ray spectrometry. The average activity concentration of 226Ra, 232Th and 40K in soil samples were 12.37,16.08, and 144.29 Bqkg-1 while those for cassava were 2.81, 16.80, and 205.41 Bqkg-1. The soil/plant radionuclide transfer ratio estimated are 0.62, 2.43 and 2.51 for 226Ra, 232Th and 40K, respectively. All the radiological risk parameters estimated are relatively low. The result of this work showed that the obtained results for all samples were lower than the international accepted limit. Hence, from radiological health standpoint, the obtained values of effective doses may not pose significant threat to both human and the environment. 
使用必要的测量仪器对埃邦伊州伊沃L.G.A的石岩古固体矿物采矿地点的土壤和粮食作物中放射性核素浓度的活度进行了评估。从矿区周围采集的土壤和木薯作物样本。这些样品是用伽马射线能谱法分析的。土壤样品中226Ra、232Th和40K的平均活性浓度分别为12.37、16.08和144.29 Bqkg-1,而木薯样品的平均活性浓度分别为2.81、16.80和205.41 Bqkg-1。226Ra、232Th和40K的土壤/植物放射性核素转移比分别为0.62、2.43和2.51。所有估计的辐射风险参数都相对较低。结果表明,所有样品的检测结果均低于国际公认的标准。因此,从放射健康的角度来看,所获得的有效剂量值可能不会对人类和环境构成重大威胁。
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引用次数: 1
Theoretical Study of Solvent Effects on the Electronic and Thermodynamic Properties of Tetrathiafulvalene (TTF) Molecule Based on DFT 基于DFT的溶剂对四噻吩(TTF)分子电子和热力学性质影响的理论研究
Pub Date : 2021-12-13 DOI: 10.9734/ajr2p/2021/v5i230162
R. Muhammad, N. M. Mahraz, A. Gidado, A. Musa
Tetrathiafulvalene () is an organosulfur compound used in the production of molecular devices such as switches, sensors, nonlinear optical devices and rectifiers. In this work, a theoretical study on the effects of solvent on TTF molecule was investigated and reported based on Density Functional Theory (DFT) as implemented in Gaussian 03 package using B3LYP/6-31++G(d,p) basis set. Different solvents were introduced as a bridge to investigate their effects on the electronic structure. The HUMO, LUMO, energy gap, global chemical index, thermodynamic properties, NLO and DOS analysis of the TTF molecule in order to determine the reactivity and stability of the molecule were obtained. The results obtained showed that the solvents have effects on the electronic and non-linear-optical properties of the molecule. The optimized bond length revealed that the molecule has strong bond in gas phase with smallest bond length of about 1.0834Å than in the rest of the solvents. It was observed that the molecule is more stable in acetonitrile with HOMO-LUMO gap and chemical hardness of 3.6373eV and 1.8187eV respectively. This indicates that the energy gap and chemical hardness of TTF molecule increases with the increase in polarity and dielectric constant of the solvents. The computed results agreed with the results in the literature. The thermodynamics and NLO properties calculation also indicated that TTF molecule has highest value of specific heat capacity (Cv), total dipole moment () and first order hyperpolarizability () in acetonitrile, while acetone has the highest value of entropy and toluene has a slightly higher value of zero point vibrational energy (ZPVE) than the rest of the solvents. The results show that careful selection of the solvents and basis sets can tune the frontier molecular orbital energy gap of the molecule and can be used for molecular device applications.
四thiafulvalene()是一种有机硫化合物,用于生产分子器件,如开关、传感器、非线性光学器件和整流器。本文采用B3LYP/6-31++G(d,p)基集,基于密度泛函理论(DFT),研究了溶剂对TTF分子的影响。引入了不同的溶剂作为桥梁,研究了它们对电子结构的影响。获得了TTF分子的HUMO、LUMO、能隙、总化学指数、热力学性质、NLO和DOS分析,以确定分子的反应性和稳定性。结果表明,溶剂对分子的电子性质和非线性光学性质都有影响。优化后的键长表明,该分子在气相中键长较强,在其他溶剂中键长最小,约为1.0834Å。结果表明,该分子在乙腈中更稳定,具有HOMO-LUMO间隙,化学硬度分别为3.6373eV和1.8187eV。这表明TTF分子的能隙和化学硬度随着溶剂极性和介电常数的增大而增大。计算结果与文献结果一致。热力学和NLO性质计算也表明,TTF分子在乙腈中具有最高的比热容(Cv)、总偶极矩()和一阶超极化率(),而丙酮的熵值最高,甲苯的零点振动能(ZPVE)略高于其他溶剂。结果表明,精心选择溶剂和基组可以调节分子的前沿分子轨道能隙,并可用于分子器件应用。
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引用次数: 1
Assessment of Outdoor Gamma Exposure Level of Some Swampy Agricultural Soils of Nasarawa West, Nigeria 尼日利亚纳西拉瓦西部一些沼泽农业土壤室外伽马暴露水平评估
Pub Date : 2021-11-24 DOI: 10.9734/ajr2p/2021/v5i230160
Abdullahi A. Mundi, I. Mustapha, Rabo Maikeffi
In this study, assessment of outdoor background exposure levels in some selected swampy agricultural soil in Nasarawa West, Nigeria has been conducted. An in-situ measurement of outdoor background exposure rate (in mRhr-1) for a total of fifty farms (ten each from Keffi (KF), Kokona (KK), Karu (KR), Toto (TT), and Nasarawa (NS))  were  done  using  a  well  calibrated  portable  halogen-quenched  Geiger  Muller  (GM)  detector (Inspector alert Nuclear radiation monitor SN:3544). A geographical positioning system (GPS) was used at an elevation of 1.0 m above ground level to obtain the geographical location.  The radiological hazard parameters were evaluated using the measured outdoor background exposure rates.  The values obtained were compared with recommended permissible limits to ascertain the radiological hazard status of the swampy agricultural farms.  The  mean  values  of  the  outdoor  background  exposure  levels (0.23, 0.038, 0.028, 0.022, and 0.039 mRh-1), absorbed dose rates (458.49, 334.95, 188.79, 194.01,  and 343.65 nGyh-1) and excess lifetime cancer risk (1.968, 1438, 0.810, 0.832, and 1.475)  each for KF, KK, KR, TT, and NS respectively, are higher than the  recommended  safe  limits  of  0.013  mRh-1,  84.0  nGyh-1,  0.00029 respectively  as  recommended by UNSCEAR and ICRP. On the other hand, the mean annual effective dose equivalent (AEDE) values (0.563, 0.410, 0.232, 0.238, and 0.421 mSvy-1 for KF, KK, KR, TT, and NS respectively) are below the recommended permissible limits of 1.00 mSvy-1 for general public exposure. Generally, the study revealed that swampy agricultural soils in Nasarawa west are radiologically safe with little contamination which could be attributed to the geological formation and partly due to human activity in the area.
在本研究中,对尼日利亚纳西拉瓦西部一些选定的沼泽农业土壤的室外本底暴露水平进行了评估。使用校准好的便携式卤素淬盖革穆勒(GM)探测器(检查员警报核辐射监测仪SN:3544)对总共50个农场(Keffi (KF)、Kokona (KK)、Karu (KR)、Toto (TT)和Nasarawa (NS)各10个)的室外本底暴露率(mRhr-1)进行了现场测量。利用地理定位系统(GPS)在距地面1.0 m的高度获取地理位置。利用测量的室外本底暴露率对辐射危害参数进行评价。将所得值与推荐允许限值进行比较,以确定沼泽农田的放射性危害状况。KF、KK、KR、TT和NS的室外背景暴露水平(0.23、0.038、0.028、0.022和0.039 mRh-1)、吸收剂量率(458.49、334.95、188.79、194.01和343.65 nGyh-1)和过量终身癌症风险(1.968、1438、0.810、0.832和1.475)的平均值均高于UNSCEAR和ICRP建议的0.013 mRh-1、84.0 nGyh-1和0.00029的安全限值。另一方面,KF、KK、KR、TT和NS的平均年有效剂量当量(AEDE)值(分别为0.563、0.410、0.232、0.238和0.421毫西维-1)低于一般公众暴露的建议允许限值1.00毫西维-1。总的来说,研究表明,纳萨拉瓦西部的沼泽农业土壤在放射学上是安全的,污染很少,这可归因于地质构造,部分原因是该地区的人类活动。
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引用次数: 0
Holographic Dark Energy and Dark Matter Interaction in Anisotropic Bianchi Type-V Universe 各向异性Bianchi v型宇宙中的全息暗能量和暗物质相互作用
Pub Date : 2021-11-23 DOI: 10.1134/S0202289319010049
D. Gemici-Deveci, E. Aydiner
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引用次数: 0
Numerical Simulation of One Step Block Method for Treatment of Second Order Forced Motions in Mass-Spring Systems 处理质量-弹簧系统二阶强迫运动的一步块法数值模拟
Pub Date : 2021-10-01 DOI: 10.9734/ajr2p/2021/v5i230157
J. Sabo, T. Kyagya, W. J. Vashawa
This paper discuss the numerical simulation of one step block method for treatment of second order forced motions in mass-spring systems of initial value problems. The one step block method has been developed with the introduction of off-mesh point at both grid and off- grid points using interpolation and collocation procedure to increase computational burden which may jeopardize the accuracy of the method in terms of error. The basic properties of the one step block method was established and numerical analysis shown that the one step block method was found to be consistent, convergent and zero-stable. The one step block method was simulated on three highly stiff mathematical problems to validate the accuracy of the block method without reduction, and obviously the results shown are more accurate over the existing method in literature.
本文讨论了处理初值问题质量-弹簧系统二阶强迫运动的一步块法的数值模拟。一步分块法在网格点和离网格点都引入了离网格点,采用插值和配置的方法增加了计算量,从而在误差方面影响了方法的准确性。建立了一步块法的基本性质,数值分析表明,一步块法具有一致性、收敛性和零稳定性。通过对3个高硬性数学问题的一步分块法进行仿真,验证了分块法无约简的精度,结果明显优于文献中已有的分块法。
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引用次数: 0
Numerical Study of Transparent Conductive Oxide (TCO) Layer on the Performance of Methyl-Ammonium Tin Iodide (CH3NH3SnI3) Perovskite Solar Cells Using SCAPS 透明导电氧化物(TCO)层对甲基铵碘化锡(CH3NH3SnI3)钙钛矿太阳能电池性能的影响
Pub Date : 2021-09-30 DOI: 10.9734/ajr2p/2021/v5i130156
Faruk Sani, S. Abdullahi
Substrates used in perovskite solar cells as front contact are usually transparent conductive oxide (TCO) to allow light to pass through the device. The dominating TCO employed in perovskite solar cells are indium-doped tin oxide (ITO) and fluorine-doped tin oxide (FTO). However, it is imperative to investigate alternative TCOs due to the scarcity of indium metal, relatively low electrical conductivity and high leakage current in ITO and FTO. In this study, simulation has been carried out using Solar Capacitance Simulator (SCAPS) to investigate the efficiency of methyl-ammonium tin iodide (CH3NH3SnI3) based solar cells including various TCOs such as boron-doped zinc oxide (BZO), molybdenum trioxide (MoO3) and zinc oxide (ZnO). TCO parameters such as thickness, donor concentration and operating temperature were varied to study their influence on device performance. The best device performance was achieved using MoO3 with power conversion efficiency of 25.83 % and Jsc, Voc and FF of 32.44 mA/cm2, 0.979 V and 81.38 % respectively. The work shows the potential of fabricating an improved CH3NH3SnI3 perovskite solar cell with MoO3 as front contact.
在钙钛矿太阳能电池中用作前触点的衬底通常是透明的导电氧化物(TCO),以允许光通过器件。钙钛矿太阳能电池中使用的主要TCO是铟掺杂氧化锡(ITO)和氟掺杂氧化锡(FTO)。然而,由于ITO和FTO中铟金属的稀缺性,相对较低的电导率和高泄漏电流,研究替代tco势在必行。在本研究中,利用太阳能电容模拟器(SCAPS)对含掺杂硼氧化锌(BZO)、三氧化钼(MoO3)和氧化锌(ZnO)等不同tco的甲基铵碘化锡(CH3NH3SnI3)基太阳能电池的效率进行了模拟研究。研究了TCO厚度、供体浓度、操作温度等参数对器件性能的影响。使用MoO3的器件性能最佳,功率转换效率为25.83%,Jsc、Voc和FF分别为32.44 mA/cm2、0.979 V和81.38%。这项工作显示了用MoO3作为前触点来制造改进的CH3NH3SnI3钙钛矿太阳能电池的潜力。
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引用次数: 0
Design Analysis and Implementation of Automatic Fire Extinguishing System Using ATmega16 Microcontroller as Control ATmega16单片机控制的自动灭火系统设计分析与实现
Pub Date : 2021-09-24 DOI: 10.9734/ajr2p/2021/v5i130155
Rilwanu Bello, Bashir Abdullahi Sama, Nura Gambo, Yusuf M. Ahijo
Aim: The aim of this research is to design an automatic fire detection and control. Methodology: The system consists of two sensors, microcontroller, buzzer and a pump/sprinkler. An LM35 integrated chip has been used as temperature sensor while MQ-2 gas sensor has been used as smoke sensor. All sensors are connected to the microcontroller through an input/output port. The controlling software for the whole system was designed in C programming language. The popular high performance, low power 8-bit microcontroller from the AVR family microcontrollers has been used. The system was finally tested by introducing fire parameters (smoke and temperature) close to the smoke and temperature detectors respectively. When the parameters go above the set level in the detectors, audio alarm, light indicator and pump/sprinkler were activated. The measured temperature of the system was compared with the reference temperature.   Results: The result showed that there was a mean deviation of 1.550C between the measured values and reference values which served as the control.   Conclusion: The constructed system is compact and easy to install. The constructed fire control device is quite cheap and affordable to every category of person.
目的:设计一种火灾自动探测与控制系统。方法:该系统由两个传感器、微控制器、蜂鸣器和泵/喷头组成。温度传感器使用LM35集成芯片,烟雾传感器使用MQ-2气体传感器。所有传感器都通过输入/输出端口连接到微控制器上。整个系统的控制软件用C语言进行了设计。采用了AVR系列微控制器中流行的高性能、低功耗8位微控制器。最后通过在烟雾探测器和温度探测器附近分别引入火灾参数(烟雾和温度)对系统进行了测试。当探测器中的参数超过设定水平时,声音报警、指示灯和泵/喷头被激活。将系统的实测温度与参考温度进行了比较。结果:作为对照的参考值与实测值的平均偏差为1.550C。结论:该系统结构紧凑,安装方便。所建造的消防控制装置相当便宜,对每个类别的人都负担得起。
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引用次数: 1
Design Analysis of 7.5KW Stand Alone Solar Photovoltaic Power System for an Intermediate Household 某中等户用7.5KW独立太阳能光伏发电系统设计分析
Pub Date : 2021-09-22 DOI: 10.9734/ajr2p/2021/v5i130154
Rilwanu Bello, Taufiq Suleiman, Usman Atiku Kende, Mohammed Abulrasheed
Aim: Design Analysis of 7.5KW Stand-alone Solar Photovoltaic Power System for an Intermediate Household. Methodology: A design analysis of standalone 7.5KW PV system was carried out using PV modeling equations based on load estimated. The analyzed data of the solar photovoltaic components was used to determine the estimated output power of 7.5KW. Therefore, a number of modeling equations and methodologies for designing a PV system based on application have been developed and simplified in order to ensure the optimum performance of the system. The analyzed solar powered 7.5KW system was achieved by designing 24 solar panels of 335W each, 16 deep cycle battery of 200A each, and a pulse width modulation (PWM) charge controller of 60A to monitor the output of the battery for safety operation. The battery will be connected to the inverter circuit (DC-AC) to generate 220V alternating current in its output via a step-up transformer. In this paper, design analysis of a standalone PV system enables of producing power to a household with approximate consumption of 7.5KW was conducted.   Results: The standalone PV system along with the cost implications was analysed and designed. In this analysis a sequential design plan of an independent standalone solar powered photovoltaic structure was analysed and overviewed to supply continuous and uninterrupted power to a typical utility with maximum power consumption of 7500W (7.5KVA). The calculated/computed values of all the components yield a result that can serve the purpose. Based on the design analysis, the result implies that the estimate consumption of 7.5KW in a day requires 24 PV panels of 335 Watts each, 16 (12V, 200Ah) batteries, 10KW inverter, (12V, 60A) charge controller and copper wire of cross-sectional area (1.688mm2) for installation.   Conclusion: In Nigeria, to generate a solar power of 7.5KVA requires almost $15,585.70 which is equivalent to N 5,965,426.66.
目的:某中等家庭7.5KW独立太阳能光伏发电系统设计分析。方法:采用基于负荷估算的光伏建模方程,对单机型7.5KW光伏系统进行设计分析。利用太阳能光伏组件的分析数据,确定估算输出功率为7.5KW。因此,开发和简化了一些基于应用的光伏系统设计建模方程和方法,以确保系统的最佳性能。设计了24块335W的太阳能电池板,16块200A的深循环电池,以及60A的脉宽调制(PWM)充电控制器来监控电池的输出以保证电池的安全运行,从而实现了所分析的7.5KW太阳能供电系统。电池将连接到逆变电路(DC-AC),通过升压变压器在其输出中产生220V交流电。本文对一个独立的光伏发电系统进行了设计分析,该系统可以为一个家庭提供大约7.5KW的电力。结果:分析和设计了独立光伏系统及其成本影响。在这个分析中,分析和概述了一个独立的独立太阳能光伏结构的顺序设计方案,为一个最大功耗为7500W (7.5KVA)的典型公用事业提供连续和不间断的电力。所有组件的计算值产生一个可以服务于目的的结果。根据设计分析结果可知,预计一天7.5KW的用电量需要24块335瓦的光伏板,16节(12V, 200Ah)电池,10KW逆变器,(12V, 60A)充电控制器,安装截面积为1.688mm2的铜线。结论:在尼日利亚,产生7.5KVA的太阳能发电需要近15,585.70美元,相当于5,965,426.66奈拉。
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引用次数: 1
期刊
Asian Journal of Research and Reviews in Physics
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