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Proanthocyanidin-rich extract from Pinus radiata bark: Mild-alkaline extraction and characterization 从松树树皮中提取富含原花青素的提取物:弱碱性提取和特征描述
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-09 DOI: 10.15376/biores.19.1.146-159
S. Mun
This study assessed the efficacy of mild-alkaline extraction from P. radiata bark in obtaining proanthocyanidin (PA)-rich extracts. When the bark was treated with three types of bases—Na2CO3, NaHCO3, and NaOH—at varying concentrations, the extract yields increased with higher concentrations. When the pH of the extracts exceeded 7, the PA content and antioxidant activity were remarkably reduced. This result suggests that the pH holds a greater effect in the alkaline extraction of the bark rather than the type of base used. Among the bases used, NaHCO3 was selected and the extraction conditions of pine bark were examined at a concentration where the pH of the extract did not exceed 7. The extraction time during mild-alkaline extraction using 0.2% NaHCO3 was reduced compared to water-only extraction at the same temperature. Moreover, the extract yields were over 10% higher than those of water extraction, and the dried extracts exhibited good solubility in water. The mild-alkaline extracts were characterized using FT-IR and 13C NMR spectroscopic techniques, and acidic alcoholysis. Analyses of the spectra of the mild-alkaline extracts showed similarities to that of pure PA and hot water extract. This result indicated that PA in the bark was not significantly affected during mild-alkaline extraction.
本研究评估了从鼠李树皮中进行弱碱性萃取以获得富含原花青素(PA)的提取物的效果。用三种不同浓度的碱--Na2CO3、NaHCO3 和 NaOH--处理树皮时,提取物的产量随着浓度的升高而增加。当提取物的 pH 值超过 7 时,PA 的含量和抗氧化活性明显降低。这一结果表明,在树皮的碱性提取过程中,pH 值的影响比所用碱的类型更大。在所使用的碱中,选择了 NaHCO3,并在提取物 pH 值不超过 7 的浓度下考察了松树皮的提取条件。此外,提取物的产量比水提取高出 10%以上,干燥后的提取物在水中具有良好的溶解性。利用 FT-IR 和 13C NMR 光谱技术以及酸性醇解对弱碱性提取物进行了表征。对弱碱性提取物光谱的分析表明,它们与纯 PA 和热水提取物的光谱相似。这一结果表明,树皮中的 PA 在弱碱性提取过程中没有受到明显影响。
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引用次数: 0
Developing physical softness models for facial tissue products 为面巾产品开发物理柔软度模型
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-08 DOI: 10.15376/biores.19.1.116-133
Ji Min Lee, Y. Ko, Byoung-Geun Moon, Y. Lee, Soon Wan Kweon, H. Kim
A series of physical softness models were developed for facial tissue products. To this end, subjective softness data were obtained by panelists by means of round-robin pair-comparison methods. Overall softness was found to mainly consist of bulk and surface softness. Bulk softness was determined by measuring the tensile modulus (TM) from tensile testing. In contrast, the surface softness considered the mean absolute deviation (RMAD) from the roughness average (Ra) and the mean absolute deviation (FMAD) from the average coefficient of friction (), respectively, which were determined by profilometry. The developed models exhibited strong correlations with subjective softness. In particular, surface softness was found to contribute more to the overall softness than bulk softness. Overall, the developed models can serve as guidance for developing tissue products.
为面巾产品开发了一系列物理柔软度模型。为此,小组成员通过循环配对比较法获得了主观柔软度数据。研究发现,整体柔软度主要由体积柔软度和表面柔软度组成。体积柔软度是通过拉伸测试测量拉伸模量(TM)来确定的。而表面软度则分别考虑了粗糙度平均值(Ra)的平均绝对偏差(RMAD)和摩擦系数平均值(FMAD)的平均绝对偏差(FMAD),它们都是通过轮廓仪测定的。所开发的模型与主观软度有很强的相关性。尤其是表面柔软度对整体柔软度的贡献要大于整体柔软度。总之,所开发的模型可作为开发卫生纸产品的指导。
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引用次数: 0
Emissions and combustion characteristics of torrefied wood pellets 焙烧木质颗粒的排放和燃烧特性
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-08 DOI: 10.15376/biores.19.1.134-145
J. Fuwape, Emmanuel Uchechukwu Opara
The influence of torrefaction temperature on the durability, combustion characteristics, and emissions of CO, CO2, NOX, and particulate matter (PM) from biomass pellets was studied. The pellets were torrefied under inert conditions at 225, 250, and 300 °C for 60 min. Physical properties, such as weight loss, fines percentage, pellet durability index (PDI), and water absorption, were evaluated using ISO standards. The weight loss increased with higher torrefaction temperatures. Torrefied pellets had lower water absorption than untreated pellets. Fines percentage increased with torrefaction temperature while PDI decreased. Torrefied pellets at 300 °C had the lowest PDI (82.7%), while 225 °C had the highest (98.0%). The energy density and heating values increased with torrefaction temperature from 22.0 MJ/kg at 225 °C to 29.9 MJ/kg at 300 °C compared to 18.9 MJ/kg for untorrefied pellets. There were reductions in CO, CO2, and NOX emissions with an increase in torrefaction temperature while PM slightly reduced. This study found that torrefied biomass pellets had lower CO2 emissions than raw pellets.
研究了热解温度对生物质颗粒的耐久性、燃烧特性以及一氧化碳(CO)、二氧化碳(CO2)、氮氧化物(NOX)和颗粒物(PM)排放的影响。颗粒在 225、250 和 300 °C 的惰性条件下进行了 60 分钟的热解。采用 ISO 标准对重量损失、细粒百分比、颗粒耐久性指数 (PDI) 和吸水性等物理特性进行了评估。温度越高,重量损失越大。与未经处理的球团相比,经过热处理的球团吸水性更低。细粒百分比随热解温度的升高而增加,而 PDI 则下降。300 °C 下的热解颗粒的 PDI 最低(82.7%),而 225 °C 下的 PDI 最高(98.0%)。能量密度和发热值随着热解温度的升高而增加,从 225 °C 时的 22.0 兆焦/千克增至 300 °C 时的 29.9 兆焦/千克,而未经热解的颗粒为 18.9 兆焦/千克。随着烘干温度的升高,一氧化碳、二氧化碳和氮氧化物的排放量也有所减少,而可吸入颗粒物则略有减少。这项研究发现,经过热处理的生物质颗粒的二氧化碳排放量低于未经热处理的颗粒。
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引用次数: 0
Rice waste feedstocks: A review of alternatives for their conversion into high-value added products 稻米废料原料:将其转化为高附加值产品的替代品综述
IF 1.5 4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-08 DOI: 10.15376/biores.19.1.sanoja-lopez
K. A. Sanoja-López, Nikolt S. Loor-Molina, Rafael Luque
The increase in global population, expected daunting energy demands, and scarcity of resources has driven the search for new sustainable sources of materials, energy, and chemicals. In this context, biomass valorization has emerged as a promising technology to obtain high-value products in recent years. This research focuses on the valorization of rice production waste including straw, husk, and bran, due to their abundance, underutilization, and potential in generating a wide range of valuable products such as biofuels and materials. A systematic review was conducted regarding the valorization of rice production waste. The characteristics of biomass obtained from post-harvest rice production were explored, as well as the primary products derived from each of the discussed biomass feedstocks. Furthermore, the economic viability of the obtained products in their respective fields of application was evaluated, providing a solid foundation for future research and industrial applications. Different rice waste materials studied hold significant potential to obtain high‑value products including silica, adsorbent materials, biofuels, and various bioactive compounds.
全球人口的增长、预期的巨大能源需求以及资源的稀缺促使人们寻找新的可持续材料、能源和化学品来源。在此背景下,生物质增值成为近年来获得高价值产品的一项前景广阔的技术。本研究的重点是水稻生产废弃物(包括稻草、稻壳和麸皮)的价值化,因为这些废弃物数量丰富、利用率低,而且具有生产生物燃料和材料等多种有价值产品的潜力。我们对水稻生产废弃物的价值化进行了系统回顾。研究探讨了从水稻收获后生产中获得的生物质的特点,以及从所讨论的每种生物质原料中提取的主要产品。此外,还评估了所获产品在各自应用领域的经济可行性,为今后的研究和工业应用奠定了坚实的基础。所研究的不同水稻废料具有获得高价值产品的巨大潜力,包括二氧化硅、吸附材料、生物燃料和各种生物活性化合物。
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引用次数: 0
Improved drainage of LNFC-reinforced recycled pulp and mechanical properties of end papers by the zeolite-chitosan microparticle drainage aid system 沸石-壳聚糖微粒助排水体系改善了lnfc增强再生纸浆的疏水性和终纸的力学性能
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-07 DOI: 10.15376/biores.19.1.84-102
Homa Sayadi Milani, Mehdi Rahmaninia, Bin Li
Good drainage of the pulp suspension is vitally important for stable papermaking. Although the addition of lignocellulosic nanofibers (LNFC) in pulp could highly reinforce the end paper sheets, the application of LNFC could diminished the pulp drainage. To solve this problem, the impact of the zeolite-chitosan and bentonite-chitosan microparticle drainage aid systems on the LNFC-reinforced recycled pulp was systematically investigated. Results indicated that the mentioned microparticle systems improved the drainage and retention especially in applying 1% chitosan with 0.3% zeolite. In mechanical properties, applying the microparticle systems, not only did not deteriorate these properties, but also improved most of them, especially in treatment containing zeolite-chitosan. It seems that the improved pulp drainage and the mechanical properties of the end papers was due to successful mission of microparticle system and synergistic interactions of pulp fibres, LNFC, chitosan, and zeolite, which could also lead to denser and more uniform structure of handsheets.
浆液悬浮液的良好排水对稳定造纸至关重要。虽然在纸浆中添加木质纤维素纳米纤维(LNFC)可以提高纸浆的末端强度,但LNFC的使用会减少纸浆的排水。为解决这一问题,系统研究了沸石-壳聚糖和膨润土-壳聚糖微颗粒助排水体系对lnfc增强再生纸浆的影响。结果表明,在1%壳聚糖和0.3%沸石的混合作用下,微颗粒体系的疏水性和保持性都有所提高。在力学性能方面,应用微颗粒体系不仅不会使材料的力学性能恶化,而且大部分性能都得到了改善,特别是在沸石-壳聚糖处理下。纸浆排水性和最终纸的力学性能的改善似乎是由于微粒系统的成功使命和纸浆纤维、LNFC、壳聚糖和沸石的协同作用,也可能导致手纸结构更致密、更均匀。
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引用次数: 0
Effects of corn stalks returning on soil microbial carbon use efficiency and corn yield in semi-arid cropland 玉米秸秆还田对半干旱农田土壤微生物碳利用效率和玉米产量的影响
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-07 DOI: 10.15376/biores.19.1.103-115
Yue Meng, Kaikuo Wu, Ping Gong, Zhe Zhang, Mei Han, Zhanbo Wei, Lingli Wang, Na Lv, Wei Bai, Lili Zhang
Soil microbial carbon use efficiency (CUE) is a key parameter controlling the short-term carbon (C) cycle in terrestrial ecosystems. The effect of urea application (156 kg N ha-1) and corn stalks returning (9.0 tons ha-1) on soil microbial CUE and corn yield in semi-arid cropland was studied using the 18O-labeled water approach during a one-year experiment. In semi-arid cropland, applying urea reduced soil microbial CUE by 44%, while the soil microbial CUE was increased significantly by 34% after returning corn stalks to the field. The application of urea increased the total nitrogen content of soil by 23%, and corn stalks returning further increased nitrate nitrogen (NO3–-N) by 45%, dissolved organic carbon (DOC) by 53%, and dissolved organic nitrogen (DON) by 122%. Compared with no fertilization, urea application increased the corn height by 4% and the corn yield by 21%. Corn stalks returning combined with urea reduced the corn stalks by 37% compared with no fertilizer. There was no significant difference in corn yield between corn stalks returning combined with urea and single urea application. Therefore, corn stalks returning combined with urea may be an effective agronomic measure to increase soil carbon sequestration, improve soil fertility, maintain corn yield, restore soil fertility, and improve production capacity.
土壤微生物碳利用效率(CUE)是控制陆地生态系统短期碳循环的关键参数。在为期1年的试验中,采用180标记水法研究了尿素(156 kg N hm -1)和玉米秸秆还田(9.0 t hm -1)对半干旱农田土壤微生物CUE和玉米产量的影响。在半干旱农田,施用尿素使土壤微生物CUE降低了44%,而玉米秸秆还田后土壤微生物CUE显著提高了34%。施尿素使土壤全氮含量增加23%,玉米秸秆还田使硝态氮(NO3—N)增加45%,溶解有机碳(DOC)增加53%,溶解有机氮(DON)增加122%。与不施肥相比,施尿素可使玉米株高提高4%,玉米产量提高21%。与不施肥相比,玉米秸秆还田与尿素结合减少了37%的玉米秸秆。玉米秸秆还田配施尿素与单施尿素对玉米产量无显著影响。因此,玉米秸秆还田配施尿素可能是增加土壤固碳、提高土壤肥力、保持玉米产量、恢复土壤肥力、提高生产能力的有效农艺措施。
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引用次数: 0
Selection and processing of natural fibers and nanocellulose for biocomposite applications: A brief review 生物复合材料中天然纤维和纳米纤维素的选择和加工:综述
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-07 DOI: 10.15376/biores.19.1.palanisamy
Sivasubramanian Palanisamy, Thulasi Mani Murugesan, Murugesan Palaniappan, Carlo Santulli, Nadir Ayrilmis, Azeez Alavudeen
In this study the recent developments in raw materials, manufacturing processes, and applications of natural fiber composites (NFCs) were reviewed. Natural fibers can represent a substitute for man-made fibers (including glass, aramid, and carbon) in a variety of biocomposite applications. Physical and chemical properties of the natural fibers are given and compared with the synthetic fibers. Advantages and disadvantages of NFCs in comparison with synthetic fibers such as glass and carbon fibers have been proposed. Criteria are described for the selection and processing of natural fibers for polymer composites used in different sectors such as automotive and building industries. The nanocellulose production methods, unique properties, and its recent industrial application in various sectors are given. This short review on NFCs considers their chemical, physical, and mechanical characteristics, as well as their various applications.
本文综述了近年来天然纤维复合材料在原料、制造工艺和应用方面的研究进展。在各种生物复合材料的应用中,天然纤维可以代替人造纤维(包括玻璃纤维、芳纶纤维和碳纤维)。给出了天然纤维的物理化学性能,并与合成纤维进行了比较。与合成纤维如玻璃纤维和碳纤维相比,提出了nfc的优点和缺点。标准描述的选择和加工的天然纤维的聚合物复合材料用于不同的部门,如汽车和建筑行业。介绍了纳米纤维素的生产方法、独特的性能及其在各领域的工业应用。本文简要介绍了nfc的化学、物理和机械特性,以及它们的各种应用。
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引用次数: 0
Effect of different stabilizers and rebaudioside A (reb A) sweetener on quality characteristics of low-calorie orange marmalade 不同稳定剂及雷鲍迪苷A (reb A)甜味剂对低热量橘子果酱品质特性的影响
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-06 DOI: 10.15376/biores.19.1.66-83
Şeyda Öztürk, Cemalettin Baltacı
Low-calorie orange marmalade was produced using sugar and reb A (0.08%) or reb A-sugar free recipes with pectin (1%) and agar agar (AA) (1%) stabilizers. The physical, chemical, and sensory properties of the marmalades were evaluated. AA stabilizers increased the viscosity of the marmalades compared to pectin, but they did not affect samples with reb A. Low-calorie samples had higher L* and b* values and lower a* values than sugar-containing samples. Total sugar content in reb A samples was 8.30 to 9.28 g/100 g, and it was lower in agar samples produced in parallel with pectin. The hydroxymethyl furfural (HMF) value was lower in sugar-free recipes (3.03 to 3.62) than in sugar-containing samples. Pectin-reb A samples had favorable taste, while AA-reb A samples favored consistency among reb A-containing samples.
采用糖加莱布A(0.08%)或不含莱布A(1%)的配方,添加果胶(1%)和琼脂(1%)稳定剂,制备低热量的橙汁果酱。对果酱的物理、化学和感官特性进行了评价。与果胶相比,AA稳定剂增加了果酱的粘度,但对含reb a的样品没有影响。低热量样品的L*和b*值高于含糖样品,a*值低于含糖样品。reb A样品的总糖含量为8.30 ~ 9.28 g/100 g,与果胶平行生产的琼脂样品的总糖含量较低。无糖配方中羟甲基糠醛(HMF)值(3.03 ~ 3.62)低于含糖样品。果胶-reb A样品具有较好的口感,而AA-reb A样品在含reb A样品中具有较好的一致性。
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引用次数: 0
Effect of processing temperature and polymer types on mechanical properties of bamboo fiber composites 加工温度和聚合物类型对竹纤维复合材料力学性能的影响
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-03 DOI: 10.15376/biores.19.1.41-52
Takumi Takeuchi, Panuwat Luengrojanaku, Hiroshi Ito, Sarawut Rimdusit, Shinichi Shibata
Bamboo fiber was extracted after alkaline treatment, and the mechanical properties of fibers and polymer composites were measured. The results showed that the strength of bamboo fiber was higher when the diameter was smaller. Smaller diameter bamboo fibers were dense, while larger diameter ones were composed of vascular bundles, which contained inside voids and outside parts having insufficient lignification. Tensile tests were conducted on bamboo fibers after heating at constant temperatures, and a significant decrease in mechanical properties was observed at heating temperatures above 250 °C. Bamboo fibers were compounded with PE, PA12, ABS, PA6, and biobased PC (Durabio), and injection-molded to prepare the composite specimens for flexural testing. The composite of polyethylene with 30 wt% bamboo exhibited considerably high flexural modulus compared to pure PE. Nevertheless, a large plastic deformation, which was equivalent to that of pure PE was observed. In other polymer composites, those flexural moduli increased, and degree of plastic deformation decreased dramatically, leading to brittleness. For PA6, which was molded above 250 °C, the increment in flexural modulus by fibers was less than the other composites due to the thermal decomposition of the fibers.
对碱处理后的竹纤维进行提取,并对纤维和聚合物复合材料的力学性能进行测定。结果表明,竹纤维直径越小,其强度越高。直径较小的竹纤维致密,而直径较大的竹纤维由维管束组成,维管束内部有空隙,外层木质化不足。对竹纤维进行恒温加热后的拉伸试验,在250℃以上的加热温度下,观察到其力学性能明显下降。将竹纤维与PE、PA12、ABS、PA6和生物基PC (Durabio)复合,注塑成型,制备复合材料试件进行抗弯试验。与纯PE相比,聚乙烯与30%竹子的复合材料具有相当高的弯曲模量。然而,观察到与纯PE相当的大塑性变形。在其他聚合物复合材料中,弯曲模量增加,塑性变形程度急剧下降,导致脆性。对于250℃以上成型的PA6,由于纤维的热分解作用,纤维对其弯曲模量的增量小于其他复合材料。
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引用次数: 0
Producing structural grade hardwood lumber as a raw material for cross-laminated timber: Yield and economic analysis 生产结构级硬木木材作为交叉层压木材的原料:产量和经济分析
4区 农林科学 Q2 MATERIALS SCIENCE, PAPER & WOOD Pub Date : 2023-11-03 DOI: 10.15376/biores.19.1.23-40
Sailesh Adhikari, Brian Bond, Henry Quesada
The economic feasibility of producing structural-grade hardwood lumber (SGHL) that qualifies as a raw material for structurally rated cross-laminated timber (CLT) was examined. 126 yellow poplar logs from diameters 12 to 15 inches were selected and divided into test and control samples. A log yield study was then conducted of the yield and revenue generated when producing lumber graded with National Hardwood Lumber Association (NHLA) rules, SGHL rules, and a mix of both rules (NHLA and SGHL-graded lumber). Producing mix-grade lumber added approximately 27% more revenue than producing NHLA-grade lumber on average if sawmills adopt a cant sawing method. Mix-grade lumber production resulted in 32% of the total volume produced as SGHL and the remaining 68% as NHLA lumber. As a result, 2 Common and lower-grade lumber board footage was reduced to only 29% in test samples and remained converted into SGHL compared to more than 85% of 2 Common and lower-grade lumber boards for control samples. 95% of the SGHL produced as mixed-graded lumber with NHLA-grade lumber met the specifications required to produce structural CLT, and the remaining 5% can be utilized to produce non-structural grade CLTs if they meet the minimum requirement of the materials for CLT production.
研究了生产结构级硬木木材(SGHL)的经济可行性,该木材可作为结构级交叉层压木材(CLT)的原料。选取直径为12 ~ 15英寸的黄杨原木126根,分为试验样品和对照样品。然后,对按照国家硬木木材协会(NHLA)规则、SGHL规则以及两种规则(NHLA和SGHL分级木材)分级的木材生产过程中产生的产量和收入进行了原木产量研究。如果锯木厂采用斜锯法,生产混合级木材比生产nhla级木材平均增加约27%的收入。混合级木材产量占SGHL木材总产量的32%,其余68%为NHLA木材。结果,在测试样品中,普通和低级木材板的长度减少到只有29%,并且仍然转化为SGHL,而在控制样品中,普通和低级木材板的比例超过85%。与nhla级木材混合分级生产的SGHL中,95%符合生产结构CLT所需的规格,其余5%如果满足CLT生产材料的最低要求,则可用于生产非结构级CLT。
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引用次数: 0
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